This disclosure relates generally to the field of optical and decorative coatings, such as multi-colored dielectric coating for electronic devices, and to the manufacturing of such optical coating.
Mirrors are generally fabricated by applying metallic coating on one side of a transparent substrate, such as glass. The general function of the coating is to reflect light at the entire visible spectrum (i.e., white light). In some applications it is desired to reflect light, but to maintain the transparency of the glass. Since metallic coating is opaque, in such cases a dielectric coating, generally referred to as dielectric mirror or Bragg mirror, is utilized. The coating is generated by applying multiple interleaved layers of high and low refractive index dielectric materials. The reflections from the low-index layers have exactly half a wavelength in path length difference, but there is a 180-degree difference in phase shift at a low-to-high index boundary, compared to a high-to-low index boundary, which means that these reflections are also in phase. In the case of a mirror at normal incidence, each of the layers has a thickness of a quarter wavelength.
In general, dielectric mirrors have been used in panel glass to replace standard mirrors and enable more complex mirror applications. See, e.g., U.S. Publication 2015/0287957. Dielectric mirrors can be used to provide privacy when viewing from one direction, but enable see-through when viewing from the other direction, to enable transmission of images, such as a TV positioned behind the mirror, etc. See, e.g., U.S. Pat. No. 9,977,157. Since proper selection of the thickness and material of the layers can be tailored to reflect radiation at different wavelengths, it has also been suggested to use dielectric mirror as thermal barrier. See, e.g., U.S. Publication 2014/0083115. Finally, dielectric mirrors have also been suggested to be used to obscure elements from user's view. See, e.g., U.S. Pat. No. 9,727,178.
The trend in mobile devices, such as cellphones and tablets, is to decrease thickness while presenting a monolithic casing. Making the casing out of milled metal proved sometimes problematic, as it can interfere with wireless transmission and reception. Also, metallic casing prevents wireless charging of the device. Thus, a trend developed for making the casing out of glass, which is transparent to electromagnetic radiation. However, while glass may present a monolithic appearance, there's a need to provide an opaque appearance of glass to obscure the innards of the device.
The following summary of the disclosure is included in order to provide a basic understanding of some aspects and features of the invention. This summary is not an extensive overview of the invention and as such it is not intended to particularly identify key or critical elements of the invention or to delineate the scope of the invention. Its sole purpose is to present some concepts of the invention in a simplified form as a prelude to the more detailed description that is presented below.
Disclosed embodiments enable colorful dielectric coating of glass, thereby presenting different colors to the user and obscuring the innards of the device. Disclosed aspects provide methods and systems for imparting multi-color dielectric coating onto glass, thereby presenting an attractive appearance to mobile devices, while being transparent to electromagnetic radiation.
In the disclosed embodiments the multi-color dielectric coating is formed using interleaved layers of dielectric material, having alternating refractive index, to create reflections at selected wavelengths, thus appearing as different colors. Etching of selected layers at selected locations changes the color appearance of the etched locations, thus generating a coating having multiple colors. The thicknesses of the layers are chosen such that the path-length differences for reflections from different high-index layers are integer multiples of the wavelength for which the coating is designed.
One aspect involves a method for forming a multi-color dielectric coating on a mobile device casing, the method comprising the steps of alternatingly depositing transparent dielectric coating layers of high refractive index and low refractive index, the thickness and number of the dielectric coating layers selected so as to reflect light at a selected wavelength thereby appearing as a first color; and etching a designed shape in at least one of the dielectric coating layers to thereby cause the dielectric coating layer to reflect light at a different wavelength within the designed shape, so as to appear as a different color. The etching may be performed in between the deposition of the dielectric coating layers, or after all of the dielectric coating layers have been deposited. The etching may be performed by holding the casing stationary in front of a mask, continuously transporting the casing in front of the mask to thereby generate a striped designed shape, or stepping the casing in front of the mask to thereby generate a repeated design shape. The etching may be performed by placing a mask on one side of an extraction grid and placing the casing on the opposite side of the extraction grid, such that the mask is between the plasma and the extraction grid.
According to one aspect, each layer is deposited to a thickness of a quarter of a wavelength of a first color. Then the deposited layer is etched to generate a desired design having a thickness of a quarter wavelength of a second color. Thus, all of the layers are first deposited to have a first thickness corresponding to a quarter of a wavelength of a first color, but each layer is partially etched to reduce its thickness to a second thickness at the location of the design or pattern, wherein the second thickness corresponds to a quarter wavelength of a second color.
In general aspects, a processing system for forming a multi-color coating on a substrate is provided, the system comprising: a deposition processing section having paired vapor transport deposition chambers comprising a first chamber configured to deposit a first refractive index dielectric coating and a second chamber configured to deposit a second refractive index dielectric coating, having lower refractive index than the first refractive index dielectric material; an etching section configured to perform etching of at least one of the layers formed by the deposition processing section; and a buffer section configured to enable different transport speeds between the deposition processing section and the etching section. The system may further include a parking station, configured to enable parking of substrate carriers in vacuum environment.
Disclosed embodiments include a method for forming a multi-color coating, comprising: providing a transparent substrate; forming a plurality of transparent layers over the substrate by alternatingly forming a first refractive index layer having a first refractive index and a second refractive index layer having a second refractive index, a plurality of times, the thickness and number of layers configured to generate a reflection of light appearing as a first color; transporting the substrate to an etch chamber and etching at least one of the transparent layers through a mask, the depth of the etching configured to generate a reflection of light appearing as a second color different from the first color. The thickness of each of the first refractive index layer and the second refractive index layer may be set to a quarter of the wavelength of the first or second color. Alternatively, the first and second refractive index layers are formed to have a thickness corresponding to a quarter wavelength of the first color, and the first and second refractive index layers are etched to have a thickness corresponding to a quarter wavelength of the second color.
Other aspects and features of the invention would be apparent from the detailed description, which is made with reference to the following drawings. It should be appreciated that the detailed description and the drawings provides various non-limiting examples of various embodiments of the invention, which is defined by the appended claims.
The accompanying drawings, which are incorporated in and constitute a part of this specification, exemplify the embodiments of the present invention and, together with the description, serve to explain and illustrate principles of the invention. The drawings are intended to illustrate major features of the exemplary embodiments in a diagrammatic manner. The drawings are not intended to depict every feature of actual embodiments nor relative dimensions of the depicted elements, and are not drawn to scale.
Embodiments of the inventive multi-color dielectric coating and its processing will now be described with reference to the drawings. Different embodiments or their combinations may be used for different applications or to achieve different results or benefits. Depending on the outcome sought to be achieved, different features disclosed herein may be utilized partially or to their fullest, alone or in combination with other features, balancing advantages with requirements and constraints. Therefore, certain benefits will be highlighted with reference to different embodiments, but are not limited to the disclosed embodiments. That is, the features disclosed herein are not limited to the embodiment within which they are described, but may be “mixed and matched” with other features and incorporated in other embodiments.
Disclosed embodiments include systems and methods for forming multi-color coating using dielectric transparent layers. In the context of this disclosure, dielectric coating comprises an arrangement of interleaved dielectric layers of different refractive index, configured to reflect selected wavelength(s) of light. By properly selecting the refractive indexes and the thickness and number of the layers, the dielectric coating can be tailored to reflect white light, or only selected wavelengths so that the item appears to be colored. For example, when the layers are selected to constructively reflect at 600 nm wavelength, the item would appear yellow, while when the layers are configured to constructively reflect at 700 nm the item would appear red, although each of the layers is individually transparent. In the first example, each of the layers would be of thickness of, e.g., 150 nm (a quarter of 600 nm), while in the second example, each layer may be of thickness of 175 nm. Thus, in one example, each of the layers is first deposited to a thickness of 175 nm, and to generate a design at different color, each layer may be etched to a thickness of 150 nm at the design area, thereby providing a yellow design over a red background.
The high refractive index layers can be made of one or combinations of the following (stoichiometric and non-stoichiometric) optical films: NbOx, ZrO, Y—ZrO, AlN, SiN, ZrN, TiO, CrO, CrN, CrTiO, and CrTiN. The low refractive index layers can be made from one or combinations of the following films: SiOx, AlO, SiON, SiAlO. In this context, it should be appreciated that the terms low refractive index and high refractive index are not used as quantitative measurement, but rather as relative descriptors enabling distinction between the alternating layers. What is important in the dielectric coating context is not the specific values of the refractive index, but that the low refractive index layers have a refractive index value that is sufficiently lower than that of the high refractive index to bring about the required optical effect.
According to disclosed embodiments, the multi-color coating can be formed on a variety of crystalline or non-crystalline substrates, such as glass (including treated glass, such as Gorilla Glass®), sapphire, and plastic. The coating is especially beneficial for mobile device enclosures or casings. They provide attractive colored films on the casing without creating electrical/magnetic field (EMF) interference, which could degrade wireless transmission/reception and wireless charging functions required for today's mobile devices.
As can be understood, the thickness and uniformity of all of the layers forming the dielectric coating is critical to present the desired color. Thus, in disclosed embodiments the layers are formed in a vapor transport system which deposits the alternating layers of high and low refractive index material. To create the multi-color appearance, the coated substrate is transported into an etching chamber and the coating is partially etched to create design of two or more colors. The etching may be performed through a mask to create the desired design. The mask may be placed in contact or proximal to the substrate so as to generate a defined boundary between the two colors. Conversely, the mask may be placed at a distance from the substrate configured to generate a gradient or gradual boundary between the two colors. Further, the substrate may be stationary or in motion with respect to the mask, so as to generate different design effects.
Thus, in one aspect a mobile device encasing is provided, comprising: a rear panel made of dielectric material transparent to electromagnetic radiation; a plurality of dielectric layers provided over the rear panel, the plurality of dielectric layers being made up of an interlaced series of dielectric layers having a first refractive index and dielectric layers having a second refractive index, higher than the first refractive index; wherein a first part of the rear panel has n number of the plurality of dielectric layers designed to reflect light at a first wavelength, and a second part of the rear panel has m number of the plurality of dielectric layers designed to reflect light at a second wavelength.
In another aspect, a mobile device encasing is provided, comprising: a rear panel made of dielectric material transparent to electromagnetic radiation; a plurality of dielectric layers provided over the rear panel, the plurality of dielectric layers being made up of an interlaced series of dielectric layers having a first refractive index and dielectric layers having a second refractive index, higher than the first refractive index; wherein a first part of the rear panel has each of the plurality of dielectric layers having thickness of a quarter of a first wavelength, and a second part of the rear panel has each of the plurality of dielectric layers having thickness of a quarter of a second wavelength.
Various methods and systems for achieving the multi-color dielectric coatings will now be described.
In order to generate a pattern on the substrates, a mask needs to block part of the etchant species from reaching the substrate in areas where no etching is desired. In general, when using masks in the prior art, sometimes referred to as shadow masks, the mask is positioned on the substrate to be etched. However, such an arrangement causes the mask itself to also continuously be etched. This is undesirable, especially since particles etched from the mask can fall on the substrate and will be easily visibly detectable to a user. Therefore, in the embodiment of
In the embodiment of
In the embodiment of
As shown in
Thus, in one aspect, a method for fabricating a rear panel for a mobile device is provided, comprising: obtaining a plate made of dielectric material transparent to electromagnetic radiation; placing the plate inside a deposition system and operating the deposition system to deposit over the plate a plurality of n number of dielectric layers, the plurality of dielectric layers being made up of an interlaced series of dielectric layers having a first refractive index and dielectric layers having a second refractive index, higher than the first refractive index, wherein the n number of the plurality of dielectric layers is designed to reflect light at a first wavelength; and transporting the plate into an etch chamber and etching a section of the plate so that only m number of the plurality of dielectric layers remain in the section, the m number of dielectric layers designed to reflect light at a second wavelength.
Also, a method for fabricating a rear panel for a mobile device is provided, comprising: obtaining a plate made of dielectric material transparent to electromagnetic radiation; placing the plate inside a deposition system and operating the deposition system to deposit over the plate a plurality of dielectric layers, the plurality of dielectric layers being made up of an interlaced series of dielectric layers having a first refractive index and dielectric layers having a second refractive index, higher than the first refractive index, wherein each of the plurality of dielectric layers has a thickness designed to reflect light at a first wavelength; and transporting the plate into an etch chamber and etching a section of the plate so that at the section each the plurality of dielectric layers has thickness designed to reflect light at a second wavelength.
For either method, the etching step may be performed by applying potential source to an extraction grid so as to extract etchant species from a plasma and accelerate the etchant species towards the plate. A mask may be inserted between the plasma and the extraction grid.
The system 400 includes a transport chamber 430, which is divided into two parts 430a and 430b, by partition 403. The carriers travel in one direction in one part, and in the opposite direction in the second part, as shown by line-dot arrows. A turntable 406 transport carriers between the two parts of the transport chamber 430. In the moment illustrated in
Attached to the transport chamber 430 is a pair of deposition chambers 420 and 422; chamber 420 including a target of high refractive index material and chamber 422 having a target of low refractive index material. Also attached to the transport chamber 430 is at least one etch chamber;
In the architecture of the system 400 of
For example, when carriers 1, 2, 3, and 4 have been loaded into the system, they first traverse the high n deposition chamber 420 to deposit a first layer in a pass-by mode. As soon as carrier 1 finishes the deposition of the first layer, it is accelerated in the buffer area 446 to enter the etch chamber 435 and start the etch process. When carrier 2 finishes deposition of the first layer, if carrier 1 is still in etch processing, then carrier 2 is placed in idle in buffer area 446, until carrier 1 exits etch process in chamber 435, at which point carrier 2 can be accelerated and placed in position for etch processing. In this manner the transport speed of each carrier can be controlled independently to enable static, pass-by and step-wise processing of the substrates, as selected by the user in controller 450.
Moreover, once carriers 1-4 complete processing of a high n and a low n layers, if the operator selects to deposit another high n layer, carriers 1-4 can be transported into exchange chamber 442. Then, carriers 5-8 are moved by turntable 406 onto part 430b, and then carriers 1-4 can be moved back into part 430a. This exchange process can be performed multiple times to thereby form as many high n and low n layers as needed. Also, the exchange can be performed several times while skipping the etching process until a number of layers has been formed, and only then the carrier can enter the etching process. Thus, as can be seen, the system 400 provide flexibility in the number of layers formed, i.e., the background color, and the type of etch that can be performed, i.e., providing different design shapes and colors. All this flexibility can be controlled by the controller 450 without the need to change any hardware and using only one pair of deposition chambers and at least one etcher.
Another embodiment is depicted in
When the substrates on a carrier are required to be etched, the carrier is moved into buffer chamber 502, and thence to etch chamber 503. Etch chamber 503 is a linear processing chamber, meaning the carriers are transported on a linear track, as opposed to deposition chamber wherein the carriers are rotated on a rotational carousel. Thus, in the system of
Optionally, turntable 506 is provided at the end of the linear transport chamber 503, so as to enable exchanging substrates between etchers 522 and 535. Alternatively, or in addition, an exchange chamber similar to chamber 442 of
Thus, in one aspect, a system for fabricating a multi-color rear panel for a mobile device is provided, comprising: a vacuum sealable transport enclosure having transport mechanism configured for transporting glass plates; a first sputtering chamber mounted onto the sealable transport enclosure and having a sputtering target made of a first dielectric material having a first refractive index; a second sputtering chamber mounted onto the sealable transport enclosure and having a sputtering target made of a second dielectric material having a second refractive index; and an etch chamber mounted onto the sealable transport enclosure and having a plasma compartment and an extraction grid assembly configured to extract etch specimen from the plasma and accelerate the etch specimen through a window formed in the sealable transport enclosure.
Incidentally, the carousel 507 is shown to have a generally circular shape and rotating in a generally circular motion. However, the carousel and rotation may also be in an oval, elongated oval, oblong, etc., such that the terminology carousel and rotation are intended to cover such construction. Such an example is provided in
In the example of
Optionally, in order to make the system more modular, turntable 506 is added and is configured to transfer substrate carriers into optional alternate etch chamber 637a and/or 637b, and/or to optional cluster chamber 638a and/or 638b. cluster chamber 638a and/or 638b may be, e.g., a metrology tool to measure, e.g., the thickness of the deposited layers.
In disclosed embodiments the dielectric layers are made of metal oxides, nitrides or oxynitrides. Some examples include: YsZ, AlxOy, AlN, SixNy, AlSiO, and SiON. In some embodiment, the various layers are formed using ion beam assisted deposition (MAD), such that the target material is made of the metal to be deposited and the oxygen or nitrogen are ion implanted during deposition. Thus, the sputtering process is performed in metal mode (also referred to as Metamode) wherein the target is sputtered as a (non-oxidized) metal, typically by Argon ions, and the very thin film that is formed on the substrate (˜1 nm typically) is converted into an oxide or nitride by hitting the deposited metal with O2 or N2 ion beam. For example, the target for the sputtering may be made of pure silicon or aluminum, while the ion beam includes O2 or N2, with or without argon, to form layers of SiO, SiN, AlO, etc. Also, in preferred embodiments the ratio of ion current to atom arrival rate is less than 0.5, and the ions have potential energy no higher than 600 eV.
In some embodiments, the refractive index of any layer can be changed by alloying the material. For example, MgO can be used to alloy a high refractive index material such as ZrOx or a low index material such as AlOx. The alloying can be done by adding about 8-10% of MgO, which will lower the crystallization temperature of the layer. In another example, about 10-12% of chromium can be alloyed with titanium to improve toughness. Anatase, one of the three mineral forms of titanium dioxide, has a high refractive index of 2.4, but has low hardness, and is therefore a good candidate for alloying. Titanium itself can be used as alloying agent to change refractive index. Tantalum can be alloying agent to change properties of high refractive index material, while Boron can be alloying agent to change the properties of a low refractive index material.
It should be understood that processes and techniques described herein are not inherently related to any particular apparatus and may be implemented by any suitable combination of components. Further, various types of general purpose devices may be used in accordance with the teachings described herein. The present invention has been described in relation to particular examples, which are intended in all respects to be illustrative rather than restrictive. Those skilled in the art will appreciate that many different combinations will be suitable for practicing the present invention.
Moreover, other implementations of the invention will be apparent to those skilled in the art from consideration of the specification and practice of the invention disclosed herein. Various aspects and/or components of the described embodiments may be used singly or in any combination. It is intended that the specification and examples be considered as exemplary only, with a true scope and spirit of the invention being indicated by the following claims.
This application claims priority from U.S. Provisional Application No. 62/685,215, filed Jun. 14, 2018, the disclosure of which is incorporated herein by reference in its entirety.
Number | Date | Country | |
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62685215 | Jun 2018 | US |