The present disclosure relates to multi-layer blow molded extrusions, for example, using two or more different materials.
Blow molding is a manufacturing process that may be used to form hollow polymer components. There are three main types of blow molding: extrusion blow molding, injection blow molding, and injection stretch blow molding. In general, extrusion blow molding includes melting plastic and extruding the molten plastic into a hollow tube, which may be called a parison. The parison may then be closed in a cooled mold. Then, air may be introduced (e.g., blown) into the parison, causing it to inflate and take the shape of interior of the mold. The molded component may then be ejected.
In at least one embodiment, a structural component is provided. The component may include a hollow main body including a first layer and a second layer surrounding the first layer, the second layer having a higher tensile modulus than the first layer. At least one hollow protrusion may extend from the hollow main body and include proximal and distal portions. The proximal portion may include the first layer surrounded by the second layer and the distal portion may include only the first layer.
In one embodiment, the structural component is an air duct and the at least one hollow protrusion is configured to communicate with ducts in a passenger compartment of a vehicle. In another embodiment, the second layer has a tensile modulus that is at least 100% greater than the first layer. The first layer may have a higher elongation at break than the second layer. In one embodiment, the first layer has an elongation at break that is at least 100% greater than the second layer. The distal portion may include only the first layer. The first layer may extend through an opening in the second layer. The distal portion may define an opening that is in fluid communication with the hollow main body.
In at least one embodiment, a method is provided. The method may include extruding concentric first and second materials to form a hollow, multi-layer parison; positioning the parison within a closed mold defining a mold cavity having a main body and at least one protrusion extending thereform; and introducing pressurized air into an interior of the parison to expand the parison to fill the mold cavity. The first material may tear when expanding into the protrusion and the second material may fill the protrusion.
In one embodiment, the first material has a higher tensile modulus than the second material. The first material may be extruded around the second material to form the hollow, multi-layer parison. The second material may extend through the tear in the first material to fill the protrusion. In another embodiment, the second material is extruded around the first material to form the hollow, multi-layer parison. The second material may extend around the tear in the first material to fill the protrusion. In one embodiment, a distal portion of the protrusion may include only the second material. The method may further include trimming the distal portion to form an opening in the protrusion.
In at least one embodiment, a structural component is provided. The component may include a hollow main body including a first layer of a first material and a second layer of a second material surrounding the first layer. At least one hollow protrusion may extend from the hollow main body and include proximal and distal portions. The proximal portion may include the first layer surrounded by the second layer and the distal portion may include only one of the first and second layers.
In one embodiment, the second material has a higher tensile modulus than the first material and the distal portion includes only the first layer, the first layer extending through an opening in the second layer. In another embodiment, the first layer has a higher tensile modulus than the second layer and the distal portion includes only the second layer. The second layer may extend around an opening in the first layer.
As required, detailed embodiments of the present invention are disclosed herein; however, it is to be understood that the disclosed embodiments are merely exemplary of the invention that may be embodied in various and alternative forms. The figures are not necessarily to scale; some features may be exaggerated or minimized to show details of particular components. Therefore, specific structural and functional details disclosed herein are not to be interpreted as limiting, but merely as a representative basis for teaching one skilled in the art to variously employ the present invention.
Blow molding, for example, extrusion blow molding, may be used to create a variety of components. As described in the Background, extrusion blow molding generally includes melting plastic and extruding the molten plastic into a hollow tube, called a parison. The parison may then be closed in a cooled mold. Air may then be blown into the parison, causing it to inflate and take the shape of interior of the mold. Extrusion blow molding may be used to form components or parts for vehicles.
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The air duct may include one or more protrusion 24 extending from the main body 22. The protrusions 24 may form openings 26 that communicate with the ducts in the passenger compartment. The communication may be direct or through intermediate components. In the embodiment shown, the air duct 20 may include one or more end protrusions 28, which are located at or near the ends 30 of the main body 22. These protrusion(s) may communicate with ducts adjacent to the vehicle doors. As shown, there is one end protrusion 28 at each end 30 of the main body, however, there may be protrusion(s) 28 at only one end 30 or there may be multiple protrusions 28 at one or both ends 30.
There may also be one or more middle or central protrusions 32. The central protrusions may be in addition to, or instead of, the end protrusions 28. As used herein, middle/central may refer to a position away from the ends 30, for example, in the middle 75%, 50%, 33%, or 25% of the main body 22. These protrusion(s) may communicate with centrally located ducts, such as those included in or adjacent to the center console or entertainment/climate console. As shown, there are two central protrusions 32, however, there may be only a single central protrusion or three or more central protrusions. In the embodiment shown, the central protrusions 32 may be in close proximity to each other.
The end protrusions 28 and central protrusions 32 may define openings 26 that are configured to communicate with various ducts in the passenger compartment. The openings 26 may have any suitable shape. In the embodiment shown, the central protrusions 32 and one of the end protrusions 28 have a rectangular opening, while the remaining end protrusion 28 has an irregular shaped opening. However, each protrusion may have any suitable shape, such as rectangular, circular, elliptical, oval, irregular, or others. The ends 30 of the main body 22 may be closed, such that there is no air flow therethrough. The main body 22 may include an inlet (not shown) for receiving air from the HVAC unit. The inlet may be formed as one or more openings in the main body 22 or it may include one or more protrusions (e.g., similar to those protrusions 24).
In order to provide both air distribution and structural support functions, the air duct 20 may require both good mechanical properties (e.g., high tensile modulus) and good stretching properties (e.g., high elongation). As described above, these two characteristics are typically not available in a single material. To test the ability of a single material to form a structural member that also includes relatively precise features (e.g., the protrusions in air duct 20), air ducts similar to air duct 20 were blow molded from two different types of materials. The first material was a relatively low tensile modulus material and the second was a relatively high tensile modulus material. As described in greater detail below, the high modulus material was not able to form well-defined shapes. Accordingly, it may be difficult or impossible to form a structural air duct, such as air duct 20, using a single material.
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As indicated in the Figures and description above, the high tensile modulus material by itself was not able to form a structural air duct having well-defined protrusions extending from a main body. The low tensile modulus material was able to form the desired shape, but does not have the mechanical properties to act as a structural component (e.g., that may replace a cross car beam). It has been discovered, however, that a combination of materials may be able to form an air duct that has sufficient mechanical properties to be a structural component, while also fulling filling one or more cavities of a blow mold to form well-defined protrusions and/or other sharp features.
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The molten material 54 may be transferred to a die head 56, which may also be referred to as an extruder. An air system 58 may be at least partially incorporated into the die head 56. The air system may include an air hose 60 that may be at least partially external to the die head 56. The air hose 60 may transport air, such as pressurized air, to a blow pin 62. The blow pin 62 may be at least partially disposed within the die head 56. The blow pin 62 may have a cylindrical portion 64 that extends from within the die head 56 and out of the bottom of the die head 56. The external portion 66 of the cylindrical portion 64 may be referred to as the parison-forming portion. The molten material 54 may flow from a cavity within the die head 56 down and around the outside of the blow pin 62. An opening 68 in the bottom of the die head 56 may allow the molten material 54 to exit the die head 56, where it may flow down the external portion 66 of the blow pin 62. Once the molten material reaches the end of the external portion 66, it may continue to flow downward and may retain a hollow shape corresponding to the shape of the external portion 66. If the external portion 66 is cylindrical, as shown, then the molten material may have a substantially hollow cylindrical shape.
Once the molten material 54 flows past the end of the blow pin 62, it may be referred to as a parison 70. The parison 70 may continue to flow downward (e.g., due to gravity) until it extends past a bottom height of the mold 80, which may be in an open position. The mold 80 may have multiple parts. In the example shown, the mold 80 includes two halves 82, however, there may be three or more parts that cooperate together. The parts of the mold 80 may cooperate to form a mold cavity 74, which may correspond to the desired shape of the molded component. The mold parts may include cooling channels 76 therein, which may transport coolant (e.g., water) to and from the mold 80 to cool it.
In the embodiment shown, when the parison 70 has extended downward such that its distal end is at or below a bottom height of the mold 80, the mold halves 82 may close together to form the cavity 74. This may be referred to as open mold extrusion. In other embodiments, the mold halves 82 may already be closed prior to the parison 70 being extruded. This may be referred to as closed mold extrusion. After the mold 80 has been closed (or as it is closing), air may be delivered into the hollow interior of the parison 70. The air may be delivered through a channel or passage 78 in the blow pin 62. The air may be delivered under pressure (e.g., over ambient or atmospheric pressure). For example, the pre-blow pressure may be between 2 and 3 bar and the final pressure may be about 8 bar. However, these values are merely examples and are not intended to be limiting. The pressure from the air causes the parison to expand outward until it fills the cavity 74. If the mold 80 is actively cooled, the coolant may be circulated through the passage(s) to cool the mold and the blow molded polymer. Active cooling is not required. Instead, the mold may be passively cooled or uncooled. Once the newly formed component is cooled, the mold 80 may be opened and the component is ejected. The process may then be repeated to produce additional components.
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The system 100 may include components that are similar to those described with respect to system 50. However, modifications may be made to the system in order to incorporate two (or more) materials into the parison and, ultimately, the blow molded part. Individual components of the system 100 that are similar in form and function to system 50 may be described in reduced detail, and the description from system 50 may be applied. The system 100 may include two screw and barrel assemblies, a first screw and barrel assembly 102 and a second screw and barrel assembly 104. The screw and barrel assemblies may have any design known in the art, such as single screw, dual-screw, or others.
Each screw and barrel assembly may be configured to receive a pre-compounded material or to compound two or more ingredients/components to form a compounded material, as described above for screw and barrel assembly 52. In the embodiment shown, each screw and barrel assembly has a hopper 106 that is configured to receive a material to be extruded and feed it into the screw and barrel assembly. The material may be a pre-compounded material, such as pellets, that includes a base polymer and, optionally, one or more reinforcing materials or additives. In other embodiments, the material may include the base polymer and optional additives, but no reinforcing fibers. The fibers may be added in a separate step (e.g., downstream) or there may not be any reinforcing material.
In one embodiment, the first screw and barrel assembly 102 may be configured to receive and extrude a first material 108 and the second screw and barrel assembly 104 may be configured to receive and extrude a second material 110. The first material 108 may be a structural material having a high tensile modulus. In one embodiment, the first material 108 is a fiber reinforced composite including a base polymer and a plurality of reinforcing fibers. The fibers may be any type of reinforcing fiber having a higher tensile modulus than the base polymer, such as glass fibers, carbon fibers, aramid fibers, other fibers, or combinations thereof. If the first material 108 is a structural material, it may have a relatively high fiber content. In one embodiment, the first material 108 may have a fiber content of at least 20 wt. %, such as at least 30, 35, or 40 wt. %. For example, the first material 108 may have a fiber content of 10 to 60 wt. %, or any sub-range therein, such as 20 to 60 wt. %, 20 to 50 wt. %, 30 to 60 wt. %, 30 to 50 wt. %, 35 to 45 wt. %, or about 40 wt. % (e.g., ±5 wt. %). In one embodiment, the fiber type of the first material 108 may be predominantly (>50%) or completely (100%) carbon fiber.
The second material 110 may be an elastic material having high elongation properties. The second material 110 may include fiber reinforcement or it may be a non-reinforced material (e.g., no fibers or “neat”). In embodiments where the second material 110 includes reinforcing fiber, the fibers may be any type of reinforcing fiber having a higher tensile modulus than the base polymer, such as glass fibers, carbon fibers, aramid fibers, other fibers, or combinations thereof. If the second material 110 is an elastic material, it may have a relatively low fiber content or no fiber content. In one embodiment, the second material 110 may have a fiber content of at most 40 wt. %, such as at most 30, 20, 10, or 5 wt. %. For example, the second material 110 may have a fiber content of 0 to 40 wt. %, or any sub-range therein, such as 1 to 40 wt. %, 1 to 30 wt. %, 1 to 20 wt. %, 1 to 15 wt. %, 5 to 25 wt. %, 5 to 20 wt. %, 5 to 15 wt. %, or 5 to 10 wt. %. In one embodiment, the fiber type of the second material 110 may be predominantly (>50%) or completely (100%) glass fiber. In another embodiment, the fiber type of the second material 110 may not include carbon fiber.
The base polymers of the first and second materials may be the same or they may be different. The base polymer for each material may be any suitable polymer for forming a fiber reinforced polymer composite and/or a polymer that is blow-moldable. Non-limiting examples of suitable base polymers may include polyamides (e.g., nylons), polyolefins (e.g., polypropylene or polyethylene), ABS, PPS, PBT, PEEK, PEI, polysulfones, polycarbonates, PET, EVA, polyesters, phenolics, acetals, polystyrenes, PVC, other blow-moldable polymers. Particular non-limiting examples of polyamides may include PA6, PA66, of polyphthalamide (PPA). Particular non-limiting examples of polyolefins may include low density polyethylene (LDPE), medium density polyethylene (MDPE), high density polyethylene (HDPE), ethylene copolymers, such as ethylene vinyl acetate (EVA), and propylene copolymers. If the base polymers are different, the base polymer for the structural material may have a higher tensile modulus that the elongation material.
In embodiments where the first and second materials have different base polymers, a third or additional material may be included that provides a transition between the different base polymers and may allow materials that don't typically bond well to each other to be used together. This third material may be referred to as a tie layer, since it may tie together the different materials. The third material may have properties that are similar to the first material or the second material, or they may be intermediate. The third material may tear with the structural material or may expand with the elastic material (discussed in more detail, below). The third material may comprise a relatively small portion of the total parison material (e.g., <5 or 10 wt. %), since its primary purpose may be only to provide an interface between two dissimilar materials.
Accordingly, the first material 108 may be a structural material and the second material 110 may be an elastic material. The first material 108 may have a higher tensile modulus (e.g., Young's modulus or elastic modulus) than the second material 110. In one embodiment, the first material 108 may have a tensile modulus of at least 10 GPa, for example, at least 25 GPa, 50 GPa, 75 GPa, 100 GPa, or 150 GPa. In another embodiment, the second material 110 may have a tensile modulus of at most 25 GPa, for example at most 10 GPa, 5 GPa, 2 GPa, or 1 GPa. The tensile modulus of the first material 108 may be at least 50%, 100%, 200%, 500%, 750%, or 1,000% greater than that of the second material 110. In one embodiment, the tensile modulus of the first material 108 may be from 200 to 1,500% greater than the second material 110, for example, 250 to 1,250% or 400 to 1,000% greater.
The second material 110 may have higher elongation properties than the first material 108 (e.g., elongation at break, such as percent strain). In one embodiment, the elongation at break (e.g., tensile) of the first material 108 may be at most 5%, for example, at most 3% or at most 1%. In another embodiment, the elongation at break of the first material 108 may be from 0.1 to 5%, or any sub-range therein, such as 1 to 5% or 1 to 3%. In one embodiment, the elongation at break of the second material 110 may be at least 5%, for example, at least 7%, 10%, or 20%. In another embodiment, the elongation at break of the second material 110 may be from 10 to 150%, or any sub-range therein, such as 20 to 100%. The elongation at break of the second material 110 may be at least 50%, 100%, 200%, 500%, or 1,000% greater than that of the first material 108.
As described above, the first material 108 and the second material 110 may be introduced into the screw and barrel assemblies 102 and 104, respectively. They may be introduced in a fully formulated state (e.g., with the target composition) or may be compounded within the screw and barrel assembly. Each screw and barrel assembly may have one or more screws 112, which may rotate and shear, mix, and heat the material. The screw and barrel assemblies may also include one or more heaters 114 to provide supplemental heating to the material as it is extruded.
Once the materials 108 and 110 have been melted, they may be transferred to the die head 116 (also called an extruder). The die head 116 may include a multi-chambered vessel or tank 118 that may receive and keep separate the molten materials. The vessel 118 may have a first chamber 120 that is configured to receive the first material 108 in a molten state from the first screw and barrel assembly 102 and a second chamber 122 that is configured to receive the second material 110 in a molten state from the second screw and barrel assembly 104. While the vessel 118 is described as part of the die head 116, it may also be a separate component that is disposed intermediate the screw and barrel assemblies and the die head 116.
From the vessel 118, the molten materials 108 and 110 may be transferred into a body 124 of the die head 116. The body 124 may be similar to the die head 56 in the system 50. The body 124 may collect the materials 108 and 110 into separate cavities 126 and 128, respectively. Accordingly, the first and second materials 108 and 110 may still remain separated. An air system 130 may be included in the system 100, which may be similar to the air system 58 in the system 50. The air system 130 may include an air hose 132 that is connected to a source of air, such as pressurized air. In addition, the air system 130 may include a blow pin that extends within the die head 116 and extends outward therefrom. The blow pin is not shown in
The die head 116 may be configured such that the molten first material 108 in cavity 126 and the molten second material 110 in cavity 128 may be dispensed from the die head to form a multi-material parison 134. The parison 134 may have a hollow shape that corresponds to the shape of the blow pin, such as a hollow cylinder. In the embodiment shown, the parison may have an inner layer 136 of the second material 110 and an outer layer 138 of the first material 108. However, in other embodiments, the layers may be reversed such that the first material 108 is on the inside and the second material 110 is on the outside. If the parison 134 is cylindrical, the inner and outer layers may be concentric. Once the parison 134 extends past the blow pin, the inner and outer layers may come in contact with each other. For example, an outer surface of the inner layer 136 and an inner surface of the outer layer 138 may form a continuous contact surface such that there is no gap between the inner and outer layers.
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The 3D blow molding systems and methods disclosed above and shown in
If there are multiple materials, the ordering of the materials in the parison may be similar to the two-layer parison. For example, the material with the highest tensile modulus may be on the outside, a material with an intermediate modulus may be in the middle, and the material with the lowest modulus may be on the inside. Accordingly, during a blow molding operation, the outer layer (highest modulus) may tear first at a first elongation. The middle layer may then extend through the tear in the outer layer and then tear second at a second, greater elongation. The inner layer may then expand through the tears in both the middle and the outer layers to fill the mold cavity and provide the well-defined shape described above.
In another embodiment, the middle layer may not tear, and may also stretch to fill the cavity in a well-defined shape. Accordingly, the protrusion may have a dual-layer construction (middle layer and inner layer) that is well-defined. The middle layer may have properties that are intermediate to those of the inner and outer layers, for example, a tensile modulus and elongation at break that are between those of the inner and outer layers. This may be accomplished by using an intermediate fiber content between the two, by using a different fiber type or fiber blend, by using a different polymer base, or a combination thereof. The base polymer of the middle layer may be the same or different from the inner and/or outer material, and may be chosen from the group described with reference to the two-layer embodiments.
As described above, in embodiments where the first, second, and/or third materials have different base polymers, an additional material may be included that provides a transition between the different base polymers and may allow materials that don't typically bond well to each other to be used together. This additional material may be referred to as a tie layer or material, since it may tie together the different materials. The additional material may have properties that are similar to the first material, the second material, or the third material, or they may be intermediate. The additional material may tear with the structural material(s) or may expand with the elastic material(s).
In the 3D blow molding systems and methods disclosed above and shown in
While the embodiments disclosed above have been described in the context of air ducts, one of ordinary skill in the art will understand that the same principles may be applied in other areas. The disclosed systems and methods may be used to form blow molded articles for use in any application. The articles may include multiple materials, such as two, three, or more materials, in order to take advantage of the properties of each type of material. Materials with high and low tensile moduli may be combined to form structural materials that also include well-defined shapes in areas where mechanical properties are less critical.
While exemplary embodiments are described above, it is not intended that these embodiments describe all possible forms of the invention. Rather, the words used in the specification are words of description rather than limitation, and it is understood that various changes may be made without departing from the spirit and scope of the invention. Additionally, the features of various implementing embodiments may be combined to form further embodiments of the invention.