Patent Application
20070186424
1. Technical Field
This invention relates generally to shaving devices, and more specifically to razor blades having multi-layer coatings.
2. Background Information
A razor blade is typically formed of a suitable substrate material, such as stainless steel. A cutting edge is provided to the razor blade, typically by grinding and honing. The cutting edge has a wedge-shaped configuration with a sharpened tip having a radius less than about 1000 angstroms, e.g., about 200-500 Angstroms. Hard carbon coatings such as amorphous diamond or diamond-like carbon (DLC) material are often used to improve hardness, strength, corrosion resistance and shaving ability. The hard carbon coating maintains the required strength of the ultimate tip while permitting more acutely angled wedge shapes with consequently lower cutting forces to be used. A polytetrafluoroethylene (PTFE) outer layer can be used to provide friction reduction. The adhesion of a hard carbon material such as amorphous diamond or DLC to a stainless steel substrate can be promoted by providing an undercoat layer of an adhesion promoting material between the substrate and the hard carbon layer. It is known in the art to provide a layer of chromium or niobium containing materials as an adhesion promoting layer. This is described in U.S. Pat. No. 6,684,513 to Clipstone et al. In practice, a magnetron target (as will be discussed later in the instant application) to provide a niobium layer costs about 50% more than a target for a chromium layer and is consequently not preferred for reasons of manufacturing cost. The use of chromium is well known in the art, it promotes adequate adhesion and it provides a good solution to this problem.
Under extreme shaving conditions, the sharpened tip of the razor blade can undergo small elastic deformations. If the sharpened tip has a hard coating, these deformations can result in micro cracks in the outer surface of the hard coating. If the hard coating is intimately bonded to the substrate or to an undercoat, which is in turn intimately bonded to the substrate, the crack in the hard coating can propagate through to the substrate resulting in premature failure of the sharpened tip of the razor blade. This can result in an unpleasant shaving experience. Titanium is tougher and more elastic than chromium and can advantageously act to arrest the propagation of micro cracks into the substrate. Some comparative pertinent properties of titanium and chromium are listed in the following table:
Based on the foregoing, it is the object of the present invention to provide a cutting edge of a razor blade with a layer of a titanium containing material as an adhesion promoter for a subsequent layer of a hard carbon containing material.
In one aspect, the invention features, in general, a razor blade including a substrate with a cutting edge defined by a sharpened tip and adjacent facets. A layer of titanium containing material is on the cutting edge. A layer of hard carbon material is coated on the titanium containing material and an outer layer of PTFE is provided. The titanium containing material may include titanium or one or more compounds selected from: titanium alloyed with a carbide forming metal, titanium aluminum nitride, titanium oxide, titanium carbide, titanium carbonitride and titanium nitride. The titanium containing material may further include a composition of titanium with any one of the aforementioned materials. The layer of titanium containing material can be at least 50 Angstroms thick. The hard carbon material may be diamond-like carbon (DLC) or amorphous diamond and can be less than 2000 Angstroms thick. The PTFE can be DRYFILM LW1200 available from DUPONT.
In another aspect, the invention features, in general, a safety razor including a handle and a housing that includes at least one razor blade, supra. The housing can also include at least four razor blades, supra.
In a further aspect, the invention features, in general, a method of making a razor blade by providing a substrate with a cutting edge defined by a sharpened tip and adjacent facets. A layer of titanium containing material is applied to the cutting edge by a physical vapor deposition (PVD) process. The PVD process can be a sputtering process or a cathodic arc deposition process. A layer of hard carbon material is coated on the titanium containing material. An outer layer of PTFE is provided. A sputtering process to deposit the titanium containing material may include two stages. In a first stage, at least a first bias voltage more positive than −700 volts is applied to the razor blade and the razor blade is in a first atmosphere that includes Argon at a pressure less than 50 milliTorr. In a second stage the titanium containing material is implanted with carbon to form a partial titanium carbide layer. In this second stage the razor blade is in a second atmosphere that includes Argon at a pressure less than 30 milliTorr. In this second stage a second bias voltage more positive than −1500 volts is applied to the razor blade. Subsequent layers of hard carbon material and PTFE are applied by well known processes.
Embodiments of the invention may include one or more of the following advantages. The use of a titanium containing material on the cutting edge of a razor blade promotes adhesion of the hard carbon material. The cutting edge of the razor blade has improved resistance to failure by crack propagation. The razor blade has excellent shaving characteristics.
The above features and advantages of the present invention will be more fully understood with reference to the following detailed description when taken in conjunction with the accompanying drawings.
Referring to now to the drawings, and in particular
At least one carrier with recoiled substrate is loaded vertically (that is, with the axis of its coils horizontal) within a vacuum chamber. The vacuum chamber includes a target preferably comprising titanium, and two cathodic arc sources. The target may also comprise titanium alloyed with any carbide forming metal that comprises at least 51% titanium by atomic percent. Suitable process equipment including a vacuum chamber is manufactured by IONBOND. The vacuum chamber may alternately be constructed to have one or more stacks of razor blades loaded therein.
The process steps performed within the vacuum chamber are as follows:
In a first step, the vacuum chamber is sealed and evacuated to about 20 microTorr and a rate of rise test performed to ensure the chamber has no vacuum leaks.
The following glow discharge step removes minor contamination that might remain on the cutting edges. Oxygen is introduced into the chamber to a pressure of 15 to 45 milliTorr. A bias voltage of −500 Volts is applied to the substrate and this is increased to −1000 Volts and held for about 2 minutes. In all process steps herein where a bias voltage is cited, this is preferably a pulsed square wave, pulsed from 0 Volts to the specified bias voltage at 25 kHz and a duty cycle of 62%. Other wave forms and frequencies may be employed. One of skill in the art will understand that the hard carbon material, infra, is a semi-conductor and requires a pulsed DC bias rather than a pure DC bias to avoid creating a static charge on the substrate. The oxygen supply is closed and argon is introduced into the chamber while the substrate is held at about −1000 Volts. The vacuum chamber is then evacuated to 50 microTorr.
The glow discharge step is followed by a magnetron sputtering step that cleans the surface of the target and subsequently deposits the titanium containing material on the cutting edges. A shutter is closed which masks the target. Argon is introduced into the chamber to a pressure of 2 to 20 milliTorr. The power on the target is set to a power density of about 14 W/cm2 to 28 W/cm2. These conditions are held for 1-3 minutes as a pre-sputter step to clean the surface of the target. The shutter is then opened, exposing the target to the cutting edges so that the titanium containing material may be deposited on the cutting edges. A high bias voltage of −200 to −700 Volts, preferably about −500 Volts, is applied to the substrate for about one minute. This high bias step is necessary to achieve adequate bonding of the titanium containing material to the sharpened tip of the cutting edge. The bias voltage is then reduced to a low bias setting of −20 to −60 volts for about 2 to 5 minutes. A minimum thickness of titanium containing material of 50 Angstroms is deposited on the cutting edge.
The magnetron sputtering step is followed by a preferred a-Diamond or amorphous diamond step that deposits a hard carbon material of amorphous diamond on the titanium containing material. The hard carbon material may also be Diamond-like Carbon (DLC). Two cathodic arc sources are preferably situated such that each carbon beam is approximately normal to one of each facet of the cutting edge. This is the optimum arrangement that will provide hardest coating. Suitable coatings however are achieved with a narrower angle of about 60 degrees between the two carbon beams. Argon is introduced into the chamber to a pressure of 20 microTorr to 9 milliTorr. The cathodic arc sources are set at about 50 to 65 Amps with an initial bias voltage of about −500 to −1000 Volts applied to the substrate. The initial phase of this a-Diamond step implants carbon in the titanium containing material layer to form a partial titanium carbide layer. This partial carbide layer is necessary to ensure adequate adhesion of the hard carbon material to the titanium containing material layer. This step is continued to deposit a hard carbon layer 200 to 1500 Angstroms thick, with a preferred thickness of 200 to 800 Angstroms.
The vacuum chamber is vented and the substrate removed. In a subsequent process, well known to one of skill in the art, an outer layer of polytetrafluoroethylene (PTFE) is deposited. A suitable PTFE is DRYFILM LW1200 manufactured by DUPONT, having a molecular weight of about 40,000. The DRYFILM LW1200 is preferably diluted with alcohol as disclosed in U.S. Patent Application Ser. No. 60/741,144, hereby incorporated in its entirety by reference. One of skill in the art will understand other PTFE materials may be employed.
A razor blade 10 is manufactured generally to the processes described herein. Individual razor blades may be in stack form or the coiled substrate may subsequently uncoiled and cut to a convenient length to form a single razor blade.
Referring now to
In use, the cutting edge portion of the razor blade 10 has improved resistance to failure by crack propagation compared to known cutting edges of razor blades having chromium coatings between their substrate and hard carbon coatings. The use of a titanium containing material on the cutting edge of a razor blade promotes adhesion of the hard carbon material. The razor blade has excellent shaving characteristics.
It is to be understood that the present invention is by no means limited to the particular construction herein disclosed and/or shown in the drawings, but also comprises any modifications or equivalents within the scope of the disclosure.
This application claims the benefit of U.S. Provisional Patent Application Ser. No. 60/772,379 filed Feb. 10, 2006, which is hereby incorporated herein in its entirety.
| Number | Date | Country | |
|---|---|---|---|
| 60772379 | Feb 2006 | US |
