Claims
- 1. A multi-layered laminate comprising a polyolefin layer, a saponified ethylene/vinyl acetate copolymer layer, a transparent resin composition layer as an intermediate layer, wherein the transparent resin composition comprises,
- from 65 to 99.9 parts by weight of a polyolefin component which is a polyolefin which is at least partially graft modified with a polyolefin modifier which is an unsaturated carboxylic acid or the anhydride thereof, the polyolefin component having the unsaturated carboxylic acid or anhydride content of from 0.002 to 5 wt. % and the polyolefin being a homopolymer or a copolymer of an .alpha.-olefin having from 2 to 12 carbon atoms;
- from 35 to 0.1 parts by weight of a saponified ethylene/vinyl acetate copolymer having an ethylene content of from 25 to 75 mol % and a degree of saponification of at least 96%; and
- from 0.5 to 200 parts by weight per 100 parts by weight of the saponified ethylene/vinyl acetate copolymer of a plasticizer for the saponified ethylene/vinyl acetate.
- 2. The laminate of claim 1, wherein the polyolefin component has an .alpha.-olefin content of at least 70% by weight.
- 3. The laminate of claim 1, wherein the polyolefin modifier is acrylic acid or maleic anhydride.
- 4. The laminate of claim 3, wherein the polyolefin modifier is maleic anhydride.
- 5. The laminate of claim 1, wherein the unsaturated carboxylic acid or anhydride content is from 0.004 to 1 wt. %.
- 6. The laminate of claim 1, wherein the saponified ethylene/vinyl acetate copolymer has the ethylene content of from 26 to 45 mol % and the degree of saponification of at least 98%.
- 7. The laminate of claim 1, wherein the saponified ethylene/vinyl acetate copolymer has a melt flow rate measured according to ASTM-D569-59 (190.degree. C., 2160 g load) of from 0.1 to 20 g/10 min.
- 8. The laminate of claim 1, wherein the saponified ethylene/vinyl acetate copolymer has a melting point higher than that of the polyolefin component.
- 9. The laminate of claim 1, wherein the plasticizer is selected from the group consisting of glycerine, triethanolamine, polyethylene glycol and polyethylene glycol glyceryl ether.
- 10. The laminate of claim 1, comprising from 70 to 99 parts by weight of the polyolefin component, from 30 to 1 parts by weight of the saponified ethylene/vinyl acetate copolymer, and from 1 to 100 parts by weight per 100 parts by weight of the saponified ethylene/vinyl acetate copolymer of the plasticizer.
- 11. The laminate of claim 9, wherein the amount of the plasticizer is from 1 to 50 parts by weight per 100 parts by weight of the saponified ethylene/vinyl acetate copolymer.
- 12. The laminate of claim 1, wherein the polyolefin component is a mixture of an unmodified polypropylene and an amount of polypropylene modified by graft modification with the polyolefin modifier such that the unsaturated carboxylic acid or anhydride content of the mixture is within the recited range.
- 13. The laminate of claim 1, which further comprises another resin layer.
Priority Claims (1)
Number |
Date |
Country |
Kind |
59-68228 |
Apr 1984 |
JPX |
|
Parent Case Info
This application is a continuation of application Ser. No. 06/715,204, filed on Mar. 22, 1985, now abandoned.
US Referenced Citations (7)
Foreign Referenced Citations (8)
Number |
Date |
Country |
42-1032 |
Jan 1967 |
JPX |
0014683 |
Feb 1977 |
JPX |
0062362 |
May 1977 |
JPX |
0127450 |
Oct 1980 |
JPX |
0131033 |
Oct 1980 |
JPX |
0155042 |
Dec 1980 |
JPX |
0122950 |
Jul 1983 |
JPX |
1206257 |
Sep 1970 |
GBX |
Non-Patent Literature Citations (1)
Entry |
Patent Abstracts of Japan, vol. 8, No. 7 (C-204)[1444], Jan. 12, 1984; & JP-A-58 176 252 (Asahi Kasei Kogyo K.K.) 15-10-1983. |
Continuations (1)
|
Number |
Date |
Country |
Parent |
715024 |
Mar 1985 |
|