Multi-stage processes for coating substrates with liquid basecoat and powder topcoat

Information

  • Patent Grant
  • 6221441
  • Patent Number
    6,221,441
  • Date Filed
    Wednesday, May 26, 1999
    25 years ago
  • Date Issued
    Tuesday, April 24, 2001
    23 years ago
Abstract
Processes for coating metal or polymeric substrates are provided which include the steps of: (a) applying a liquid basecoating composition to a surface of the substrate; (b) exposing the basecoating composition to air having a temperature ranging from about 10° C. to about 50° C. for a period of at least about 5 minutes to volatilize at least a portion of volatile material from the liquid basecoating composition, the velocity of the air at a surface of the basecoating composition being less than about 0.5 meters per second; (c) applying infrared radiation and hot air simultaneously to the basecoating composition for a period of at least about 2 minutes, the velocity of the air at the surface of the basecoating composition being less than about 4 meters per second, the temperature of the metal substrate being increased at a rate ranging from about 0.4° C. per second to about 1.2° C. per second to achieve a peak substrate temperature ranging from about 120° C. to about 165° C., such that a dried basecoat is formed upon the surface of the substrate; and (d) applying a powder topcoating composition over the dried basecoat.
Description




FIELD OF THE INVENTION




The present invention relates to drying of liquid basecoats for automotive coating applications and, more particularly, to multi-stage processes for drying a liquid basecoat which include a combination of infrared radiation and convection drying for subsequent powder topcoat application.




BACKGROUND OF THE INVENTION




Today's automobile bodies are treated with multiple layers of coatings which not only enhance the appearance of the automobile, but also provide protection from corrosion, chipping, ultraviolet light, acid rain and other environmental conditions which can deteriorate the coating appearance and underlying car body.




The formulations of these coatings can vary widely. However, a major challenge that faces all automotive manufacturers is how to rapidly dry and cure these coatings with minimal capital investment and floor space, which is valued at a premium in manufacturing plants.




Various ideas have been proposed to speed up drying and curing processes for automobile coatings, such as hot air convection drying. While hot air drying is rapid, a skin can form on the surface of the coating which impedes the escape of volatiles from the coating composition and causes pops, bubbles or blisters which ruin the appearance of the dried coating.




Other methods and apparatus for drying and curing a coating applied to an automobile body are disclosed in U.S. Pat. Nos. 4,771,728; 4,907,533; 4,908,231 and 4,943,447 in which the automobile body is heated with radiant heat for a time sufficient to set the coating on Class A surfaces of the body and subsequently cured with heated air.




U.S. Pat. No. 4,416,068 discloses a method and apparatus for accelerating the drying and curing of refinish coatings for automobiles using infrared radiation. Ventilation air used to protect the infrared radiators from solvent vapors is discharged as a laminar flow over the car body.

FIG. 15

is a graph of temperature as a function of time showing the preferred high temperature/short drying time curve


122


versus conventional infrared drying (curve


113


) and convection drying (curve


114


). Such rapid, high temperature drying techniques can be undesirable because a skin can form on the surface of the coating that can cause pops, bubbles or blisters, as discussed above.




U.S. Pat. No. 4,336,279 discloses a process and apparatus for drying automobile coatings using direct radiant energy, a majority of which has a wavelength greater than 5 microns. Heated air is circulated under turbulent conditions against the back sides of the walls of the heating chamber to provide the radiant heat. Then, the heated air is circulated as a generally laminar flow along the inner sides of the walls to maintain the temperature of the walls and remove volatiles from the drying chamber. As discussed at column 7, lines 18-22, air movement is maintained at a minimum in the central portion of the inner chamber in which the automobile body is dried.




A rapid, multi-stage drying process for automobile coatings is needed which inhibits formation of surface defects and discoloration in the coating, particularly for use with liquid basecoats to be overcoated with powder topcoat.




SUMMARY OF THE INVENTION




The present invention provides a process for coating a metal substrate, comprising the steps of: (a) applying a liquid basecoating composition to a surface of the metal substrate; (b) exposing the basecoating composition to air having a temperature ranging from about 10° C. to about 50° C. for a period of at least about 5 minutes to volatilize at least a portion of volatile material from the liquid basecoating composition, the velocity of the air at a surface of the basecoating composition being less than about 0.5 meters per second; (c) applying infrared radiation and hot air simultaneously to the basecoating composition for a period of at least about 2 minutes, the velocity of the air at the surface of the basecoating composition being less than about 4 meters per second, the temperature of the metal substrate being increased at a rate ranging from about 0.4° C. per second to about 1.2° C. per second to achieve a peak metal temperature of the substrate ranging from about 120° C. to about 165° C., such that a dried basecoat is formed upon the surface of the metal substrate; and (d) applying a powder topcoating composition over the dried basecoat.




Another aspect of the present invention is a process for coating a metal substrate, comprising the steps of: (a) applying a liquid basecoating composition to a surface of the metal substrate; (b) applying infrared radiation and warm air simultaneously to the basecoating composition for a period of at least about 2 minutes, the velocity of the air at the surface of the basecoating composition being less than about 4 meters per second, the temperature of the metal substrate being increased at a rate ranging from about 0.05° C. per second to about 0.3° C. per second to achieve a peak metal temperature ranging from about 30° C. to about 60° C., such that a pre-dried basecoat is formed upon the surface of the metal substrate; (c) applying infrared radiation and hot air simultaneously to the basecoating composition for a period of at least about 2 minutes, the velocity of the air at the surface of the basecoating composition being less than about 4 meters per second, the temperature of the metal substrate being increased at a rate ranging from about 0.4° C. per second to about 1.2° C. per second to achieve a peak metal temperature of the substrate ranging from about 120° C. to about 165° C., such that a dried basecoat is formed upon the surface of the metal substrate; and (d) applying a powder topcoating composition over the dried basecoat.




Yet another aspect of the present invention is a process for coating a polymeric substrate, comprising the steps of: (a) applying a liquid basecoating composition to a surface of the polymeric substrate; (b) exposing the basecoating composition to air having a temperature ranging from about 10° C. to about 50° C. for a period of at least about 5 minutes to volatilize at least a portion of volatile material from the liquid basecoating composition, the velocity of the air at a surface of the basecoating composition being less than about 0.5 meters per second; (c) applying infrared radiation and hot air simultaneously to the basecoating composition for a period of at least about 2 minutes, the velocity of the air at the surface of the basecoating composition being less than about 4 meters per minute, the temperature of the polymeric substrate being increased at a rate ranging from about 0.4° C. per second to about 1.2° C. per second to achieve a peak polymeric substrate temperature ranging from about 120° C. to about 165° C., such that a dried basecoat is formed upon the surface of the polymeric substrate; and (d) applying a powder topcoating composition over the dried basecoat.




Another aspect of the present invention is a process for coating a polymeric substrate, comprising the steps of: (a) applying a liquid basecoating composition to a surface of the polymeric substrate; (b) applying infrared radiation and warm air simultaneously to the basecoating composition for a period of at least about 2 minutes, the velocity of the air at the surface of the basecoating composition being less than about 4 meters per second, the temperature of the substrate being increased at a rate ranging from about 0.05° C. per second to about 0.3° C. per second to achieve a peak substrate temperature ranging from about 30° C. to about 60° C., such that a pre-dried basecoat is formed upon the surface of the polymeric substrate; (c) applying infrared radiation and hot air simultaneously to the basecoating composition for a period of at least about 2 minutes, the velocity of the air at the surface of the basecoating composition being less than about 4 meters per second, the temperature of the polymeric substrate being increased at a rate ranging from about 0.4° C. per second to about 1.2° C. per second to achieve a peak polymeric substrate temperature ranging from about 120° C. to about 165° C., such that a dried basecoat is formed upon the surface of the polymeric substrate; and (d) applying a powder topcoating composition over the dried basecoat.











BRIEF DESCRIPTION OF THE DRAWINGS




The foregoing summary, as well as the following detailed description of the preferred embodiments, will be better understood when read in conjunction with the appended drawings. In the drawings:





FIG. 1

is a flow diagram of a process for drying liquid basecoat for powder topcoating according to the present invention;





FIG. 2

is a side elevational schematic diagram of a portion of the process of

FIG. 1

; and





FIG. 3

is a front elevational view taken along line


3





3


of a portion of the schematic diagram of FIG.


2


.











DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS




Referring to the drawings, in which like numerals indicate like elements throughout, there is shown in

FIG. 1

a flow diagram of a multi-stage process for coating a substrate according to the present invention.




This process is suitable for coating metal or polymeric substrates in a batch or continuous process. In a batch process, the substrate is stationary during each treatment step of the process, whereas in a continuous process the substrate is in continuous movement along an assembly line. The present invention will now be discussed generally in the context of coating a substrate in a continuous assembly line process, although the process also is useful for coating substrates in a batch process.




Useful substrates that can be coated according to the process of the present invention include metal substrates, polymeric substrates, such as thermoset materials and thermoplastic materials, and combinations thereof. Useful metal substrates that can be coated according to the process of the present invention include ferrous metals such as iron, steel, and alloys thereof, non-ferrous metals such as aluminum, zinc, magnesium and alloys thereof, and combinations thereof. Preferably, the substrate is formed from cold rolled steel, electrogalvanized steel such as hot dip electrogalvanized steel or electrogalvanized iron-zinc steel, aluminum or magnesium.




Useful thermoset materials include polyesters, epoxides, phenolics, polyurethanes such as reaction injected molding urethane (RIM) thermoset materials and mixtures thereof. Useful thermoplastic materials include thermoplastic polyolefins such as polyethylene and polypropylene, polyamides such as nylon, thermoplastic polyurethanes, thermoplastic polyesters, acrylic polymers, vinyl polymers, polycarbonates, acrylonitrile-butadiene-styrene (ABS) copolymers, ethylene propylene diene monomer (EPDM) rubber, copolymers and mixtures thereof.




Preferably, the substrates are used as components to fabricate automotive vehicles, including but not limited to automobiles, trucks and tractors. The substrates can have any shape, but are preferably in the form of automotive body components such as bodies (frames), hoods, doors, fenders, bumpers and/or trim for automotive vehicles.




The present invention first will be discussed generally in the context of coating a metallic automobile body. One skilled in the art would understand that the process of the present invention also is useful for coating non-automotive metal and/or polymeric components, which will be discussed below.




Prior to treatment according to the process of the present invention, the metal substrate can be cleaned and degreased and a pretreatment coating, such as CHEMFOS 700 zinc phosphate or BONAZINC zinc-rich pretreatment (each commercially available from PPG Industries, Inc. of Pittsburgh, Pa.), can be deposited upon the surface of the metal substrate. Alternatively or additionally, an electrodepositable coating composition can be electrodeposited upon at least a portion of the metal substrate. Useful electrodeposition methods and electrodepositable coating compositions include conventional anionic or cationic electrodepositable coating compositions, such as epoxy or polyurethane-based coatings discussed in U.S. Pat. Nos. 5,530,043; 5,760,107; 5,820,987 and 4,933,056, which are incorporated herein by reference.




Referring now to

FIG. 1

, which presents a flow chart of the process of the present invention, a liquid basecoating composition is applied to a surface of the metal substrate (automobile body


16


) in a first step


10


, preferably over an electrodeposited coating as described above. The liquid basecoating can be applied to the surface of the substrate in step


10


by any suitable coating process well known to those skilled in the art, for example by dip coating, direct roll coating, reverse roll coating, curtain coating, spray coating, brush coating and combinations thereof. The method and apparatus for applying the liquid basecoating composition to the substrate is determined in part by the configuration and type of substrate material.




The liquid basecoating composition comprises a film-forming material or binder, volatile material and optionally pigment. Preferably, the basecoating composition is a crosslinkable coating composition comprising at least one thermosettable film-forming material, such as acrylics, polyesters (including alkyds), polyurethanes and epoxies, and at least one crosslinking material. Thermoplastic film-forming materials such as polyolefins also can be used. The amount of film-forming material in the liquid basecoat generally ranges from about 40 to about 97 weight percent on a basis of total weight solids of the basecoating composition.




Suitable acrylic polymers include copolymers of one or more of acrylic acid, methacrylic acid and alkyl esters thereof, such as methyl methacrylate, ethyl methacrylate, hydroxyethyl methacrylate, butyl methacrylate, ethyl acrylate, hydroxyethyl acrylate, butyl acrylate and 2-ethylhexyl acrylate, optionally together with one or more other polymerizable ethylenically unsaturated monomers including vinyl aromatic compounds such as styrene and vinyl toluene, nitriles such as acrylontrile and methacrylonitrile, vinyl and vinylidene halides, and vinyl esters such as vinyl acetate. Other suitable acrylics and methods for preparing the same are disclosed in U.S. Pat. No. 5,196,485 at column 11, lines 16-60, which are incorporated herein by reference.




Polyesters and alkyds are other examples of resinous binders useful for preparing the basecoating composition. Such polymers can be prepared in a known manner by condensation of polyhydric alcohols, such as ethylene glycol, propylene glycol, butylene glycol, 1,6-hexylene glycol, neopentyl glycol, trimethylolpropane and pentaerythritol, with polycarboxylic acids such as adipic acid, maleic acid, fumaric acid, phthalic acids, trimellitic acid or drying oil fatty acids.




Polyurethanes also can be used as the resinous binder of the basecoat. Useful polyurethanes include the reaction products of polymeric polyols such as polyester polyols or acrylic polyols with a polyisocyanate, including aromatic diisocyanates such as 4,4′-diphenylmethane diisocyanate, aliphatic diisocyanates such as 1,6-hexamethylene diisocyanate, and cycloaliphatic diisocyanates such as isophorone diisocyanate and 4,4′-methylene-bis(cyclohexyl isocyanate).




Suitable crosslinking materials include aminoplasts, polyisocyanates, polyacids, polyanhydrides and mixtures thereof. Useful aminoplast resins are based on the addition products of formaldehyde, with an amino- or amido-group carrying substance. Condensation products obtained from the reaction of alcohols and formaldehyde with melamine, urea or benzoguanamine are most common. Useful polyisocyanate crosslinking materials include blocked or unblocked polyisocyanates such as those discussed above for preparing the polyurethane. Examples of suitable blocking agents for the polyisocyanates include lower aliphatic alcohols such as methanol, oximes such as methyl ethyl ketoxime and lactams such as caprolactam. The amount of the crosslinking material in the basecoat coating composition generally ranges from about 5 to about 50 weight percent on a basis of total resin solids weight of the basecoat coating composition.




The liquid basecoating composition comprises one or more volatile materials such as water, organic solvents and/or amines. Nonlimiting examples of useful solvents included in the composition, in addition to any provided by other coating components, include aliphatic solvents such as hexane, naphtha, and mineral spirits; aromatic and/or alkylated aromatic solvents such as toluene, xylene, and SOLVESSO 100 commercially available from Imperial Oil, Toronto, Canada; alcohols such as ethyl, methyl, n-propyl, isopropyl, n-butyl, isobutyl and amyl alcohol, and m-pyrol; esters such as ethyl acetate, n-butyl acetate, isobutyl acetate and isobutyl isobutyrate; ketones such as acetone, methyl ethyl ketone, methyl isobutyl ketone, diisobutyl ketone, methyl n-amyl ketone, and isophorone, glycol ethers and glycol ether esters such as ethylene glycol monobutyl ether, diethylene glycol monobutyl ether, ethylene glycol monohexyl ether, propylene glycol monomethyl ether, propylene glycol monopropyl ether, ethylene glycol monobutyl ether acetate, propylene glycol monomethyl ether acetate, and dipropylene glycol monomethyl ether acetate. Useful amines include alkanolamines. The solids content of the liquid basecoating composition generally ranges from about 15 to about 60 weight percent, and preferably about 20 to about 50 weight percent.




The basecoating composition can further comprise one or more pigments or other additives such as UV absorbers, rheology control agents or surfactants. Useful metallic pigments include aluminum flake, bronze flakes, coated mica, nickel flakes, tin flakes, silver flakes, copper flakes and combinations thereof. Other suitable pigments include mica, iron oxides, lead oxides, carbon black, titanium dioxide and colored organic pigments such as phthalocyanines. The specific pigment to binder ratio can vary widely so long as it provides the requisite hiding at the desired film thickness and application solids.




Suitable waterborne basecoats for color-plus-clear composites include those disclosed in U.S. Pat. Nos. 4,403,003; 5,401,790 and 5,071,904, which are incorporated by reference herein. Also, waterborne polyurethanes such as those prepared in accordance with U.S. Pat. No. 4,147,679 can be used as the resinous film former in the basecoat, which is incorporated by reference herein. Suitable film formers for organic solvent-based base coats are disclosed in U.S. Pat. No. 4,220,679 at column 2, line 24 through column 4, line 40 and U.S. Pat. No. 5,196,485 at column 11, line 7 through column 13, line 22, which are incorporated by reference herein.




The thickness of the basecoating composition applied to the substrate can vary based upon such factors as the type of substrate and intended use of the substrate, i.e., the environment in which the substrate is to be placed and the nature of the contacting materials. Generally, the thickness of the basecoating composition applied to the substrate ranges from about 10 to about 38 micrometers, and more preferably about 12 to about 30 micrometers.




Referring now to

FIG. 1

, after applying the basecoat, the process of the present invention includes a second step


12


of exposing the basecoating composition to low velocity air having a temperature ranging from about 10° C. to about 50° C., and preferably about 20° C. to about 40° C., for a period of at least about 5 minutes (preferably about 5 to about 10 minutes) to volatilize at least a portion of the volatile material from the liquid basecoating composition and set the basecoat.




As used herein, the term “set” means that the basecoat is tack-free (resists adherence of dust and other airborne contaminants) and is not disturbed or marred (waved or rippled) by air currents which blow past the basecoated surface. The velocity of the air at a surface of the basecoating composition is less than about 0.5 meters per second, and preferably ranges from about 0.3 to about 0.5 meters per second.




The volatilization or evaporation of volatile components from the basecoat surface can be carried out in the open air, but is preferably carried out in a first drying chamber


18


in which air is circulated at low velocity to minimize airborne particle contamination as shown in FIG.


2


. The automobile body


16


is positioned at the entrance to the first drying chamber


18


and slowly moved therethrough in assembly-line manner at a rate which permits the volatilization of the basecoat as discussed above. The rate at which the automobile body


16


is moved through the first drying chamber


18


and the other drying chambers discussed below depends in part upon the length and configuration of the drying chamber 18, but preferably ranges from about 3 meters per minute to about 7.3 meters per minute for a continuous process. One skilled in the art would understand that individual dryers can be used for each step of the process or that a single dryer having a plurality of individual drying chambers or sections (shown in

FIG. 2

) configured to correspond to each step of the process can be used, as desired.




The air preferably is supplied to the first drying chamber


18


by a blower


20


or dryer, shown in phantom in

FIG. 2. A

non-limiting example of a suitable blower is an ALTIVAR 66 blower that is commercially available from Square D Corporation. The air can be circulated at ambient temperature or heated, if necessary, to the desired temperature range of about 10° C. to about 50° C. Preferably, the basecoating composition is exposed to air for a period ranging from about 5 to about 10 minutes before the automobile body


16


is moved to the next stage of the drying process.




Referring now to

FIGS. 1 and 2

, the process can further comprise an additional (optional) step


22


(which can be used after step


12


above or in lieu thereof) of applying infrared radiation and low velocity warm air simultaneously to the basecoating composition for a period of at least about 2 minutes such that the temperature of the metal substrate is increased at a rate ranging from about 0.05° C. per second to about 0.3° C. per second to achieve a peak metal temperature ranging from about 30° C. to about 60° C. and form a pre-dried basecoat upon the surface of the metal substrate. By controlling the rate at which the metal temperature is increased and peak metal temperature, flaws in the appearance of the basecoat and topcoat, such as pops and bubbles, can be minimized.




The infrared radiation applied preferably includes near-infrared region (0.7 to 1.5 micrometers) and intermediate-infrared region (1.5 to 20 micrometers) radiation, and more preferably ranges from about 0.7 to about 4 micrometers. The infrared radiation heats the Class A (external) surfaces


24


of the coated substrate which are exposed to the radiation and preferably does not induce chemical reaction or crosslinking of the components of the basecoating. Most non-Class A surfaces are not exposed directly to the infrared radiation but will be heated through conduction through the automobile body and random scattering of the infrared radiation.




Referring now to

FIGS. 2 and 3

, the infrared radiation is emitted by a plurality of emitters


26


arranged in the interior drying chamber


27


of a combination infrared/convection drying apparatus


28


. Each emitter


26


is preferably a high intensity infrared lamp, preferably a quartz envelope lamp having a tungsten filament. Useful short wavelength (0.76 to 2 micrometers), high intensity lamps include Model No. T-3 lamps such as are commercially available from General Electric Co., Sylvania, Phillips, Heraeus and Ushio and have an emission rate of between 75 and 100 watts per lineal inch at the light source. Medium wavelength (2 to 4 micrometers) lamps also can be used and are available from the same suppliers. The emitter lamp is preferably generally rod-shaped and has a length that can be varied to suit the configuration of the oven, but generally is preferably about 0.75 to about 1.5 meters long. Preferably, the emitter lamps on the side walls


30


of the interior drying chamber


27


are arranged generally vertically with reference to ground


32


, except for a few rows


34


(preferably about 3 to about 5 rows) of emitters


26


at the bottom of the interior drying chamber


27


which are arranged generally horizontally to ground


32


.




The number of emitters


26


can vary depending upon the desired intensity of energy to be emitted. In a preferred embodiment, the number of emitters


26


mounted to the ceiling


36


of the interior drying chamber


27


is about 24 to about 32 arranged in a linear side-by side array with the emitters


26


spaced about 10 to about 20 centimeters apart from center to center, and preferably about 15 centimeters. The width of the interior drying chamber


27


is sufficient to accommodate the automobile body or whatever substrate component is to be dried therein, and preferably is about 2.5 to about 3.0 meters wide. Preferably, each side wall


30


of the chamber


27


has about 50 to about 60 lamps with the lamps spaced about 15 to about 20 centimeters apart from center to center. The length of each side wall


30


is sufficient to encompass the length of the automobile body or whatever substrate component is being dried therein, and preferably is about 4 to about 6 meters. The side wall


30


preferably has four horizontal sections that are angled to conform to the shape of the sides of the automobile body. The top section of the side wall


30


preferably has 24 parallel lamps divided into 6 zones. The three zones nearest the entrance to the drying chamber


27


are operated at medium wavelengths, the three nearest the exit at short wavelengths. The middle section of the side wall is configured similarly to the top section. The two lower sections of the side walls each preferably contain 6 bulbs in a 2 by 3 array. The first section of bulbs nearest the entrance is preferably operated at medium wavelength and the other two sections at short wavelengths.




Referring to

FIG. 2

, each of the emitter lamps


26


is disposed within a trough-shaped reflector


38


that is preferably formed from polished aluminum. Suitable reflectors include aluminum or integral gold-sheathed reflectors that are commercially available from BGK-ITW Automotive, Heraeus and Fannon Products. The reflectors


38


gather energy transmitted from the emitter lamps


26


and focus the energy on the automobile body


16


to lessen energy scattering.




Depending upon such factors as the configuration and positioning of the automobile body


16


within the interior drying chamber


27


and the color of the basecoat to be dried, the emitter lamps


26


can be independently controlled by microprocessor (not shown) such that the emitter lamps


26


furthest from a Class A surface


24


can be illuminated at a greater intensity than lamps closest to a Class A surface


24


to provide uniform heating. For example, as the roof


40


of the automobile body


16


passes beneath a section of emitter lamps


26


, the emitter lamps


26


in that zone can be adjusted to a lower intensity until the roof


40


has passed, then the intensity can be increased to heat the deck lid


42


which is at a greater distance from the emitter lamps


26


than the roof


40


.




Also, in order to minimize the distance from the emitter lamps


26


to the Class A surfaces


24


, the position of the side walls


30


and emitter lamps


26


can be adjusted toward or away from the automobile body as indicated by directional arrows


44


,


46


, respectively, in FIG.


3


. One skilled in the art would understand that the closer the emitter lamps


26


are to the Class A surfaces


24


of the automobile body


16


, the greater the percentage of available energy which is applied to heat the surfaces


24


and coatings present thereon. Generally, the infrared radiation is emitted at a power density ranging from about 10 to about 25 kilowatts per square meter (kW/m


2


) of emitter wall surface, and preferably about 12 kW/m


2


for emitter lamps


26


facing the sides


48


of the automobile body


16


(doors or fenders) which are closer than the emitter lamps


26


facing the hood and deck lid


42


of the automobile body


16


, which preferably emit about 24 kW/m


2


.




A non-limiting example of a suitable combination infrared/convection drying apparatus is a BGK combined infrared radiation and heated air convection oven, which is commercially available from BGK Automotive Group of Minneapolis, Minn. The general configuration of this oven will be described below and is disclosed in U.S. Pat. Nos. 4,771,728; 4,907,533; 4,908,231; and 4,943,447, which are hereby incorporated by reference. Other useful combination infrared/convection drying apparatus are commercially available from Durr of Wixom, Mich., Thermal Innovations of Manasquan, N.J., Thermovation Engineering of Cleveland, Ohio, Dry-Quick of Greenburg, Ind. and Wisconsin Oven and Infrared Systems of East Troy, Wis.




Referring now to

FIGS. 2 and 3

, the preferred combination infrared/convection drying apparatus


28


includes baffled side walls


30


having nozzles or slot openings


50


through which air


52


is passed to enter the interior drying chamber


27


at a velocity of less than about 4 meters per second. During this step, the velocity of the air at the surface


54


of the basecoating composition is less than about 4 meters per second, preferably ranges from about 0.3 to about 4 meters per second and, more preferably, about 0.7 to about 1.5 meters per second.




The temperature of the air


52


generally ranges from about 25° C. to about 50° C., and preferably about 30° C. to about 40° C. The air


52


is supplied by a blower 56 or dryer and can be preheated externally or by passing the air over the heated infrared emitter lamps


26


and their reflectors


38


. By passing the air


52


over the emitters


26


and reflectors


38


, the working temperature of these parts can be decreased, thereby extending their useful life. Also, undesirable solvent vapors can be removed from the interior drying chamber


27


. The air


52


can also be circulated up through the interior drying chamber


27


via the subfloor


58


. Preferably, the air flow is recirculated to increase efficiency. A portion of the air flow can be bled off to remove contaminants and supplemented with filtered fresh air to make up for any losses.




The automobile body


16


is heated by the infrared radiation and warm air to a peak metal temperature ranging from about 25° C. to about 60° C., and preferably about 30° C. to about 50° C. As used herein, “peak metal temperature” means the target instantaneous temperature to which the metal substrate (automobile body


16


) must be heated. The peak metal temperature for a metal substrate is measured at the surface of the coated substrate approximately in the middle of the side of the substrate opposite the side on which the coating is applied. The peak temperature for a polymeric substrate is measured at the surface of the coated substrate approximately in the middle of the side of the substrate on which the coating is applied. It is preferred that this peak metal temperature be maintained for as short a time as possible to minimize the possibility of crosslinking of the basecoat.




Referring now to

FIGS. 1 and 2

, the process of the present invention comprises a next step


60


of applying infrared radiation and hot air simultaneously to the basecoating composition on the metal substrate (automobile body


16


) for a period of at least about 2 minutes. The temperature of the metal substrate is increased at a rate ranging from about 0.4° C. per second to about 1.2° C. per second to achieve a peak metal temperature of the substrate ranging from about 120° C. to about 165° C. A dried basecoat


62


is formed thereby upon the surface of the metal substrate.




By controlling the rate at which the metal temperature is increased and peak metal temperature, the combination of steps


12


and


60


can provide liquid basecoat and powder topcoat composite coatings with a minimum of flaws in surface appearance, such as pops and bubbles. Also, high film builds can be achieved in a short period of time with minimum energy input and the flexible operating conditions can decrease the need for spot repairs.




The dried basecoat that is formed upon the surface of the automobile body


16


is dried sufficiently to enable application of the topcoat such that the quality of the topcoat will not be affected adversely by further drying of the basecoat. For waterborne basecoats, “dry” means the almost complete absence of water from the basecoat. If too much water is present, the topcoat can crack, bubble or “pop” during drying of the topcoat as water vapor from the basecoat attempts to pass through the topcoat.




This drying step


60


can be carried out in a similar manner to that of step


22


above using a combination infrared radiation/convection drying apparatus, however the heating rate ranges from about 0.4° C. per second to about 1.2° C. per second and peak metal temperature of the substrate ranges from about 120° C. to about 165° C. Preferably, the heating rate ranges from about 0.5° C. per second to about 1.1° C. per second and the peak metal temperature of the substrate ranges from about 132° C. to about 155° C.




The infrared radiation applied preferably includes near-infrared region (0.7 to 1.5 micrometers) and intermediate-infrared region (1.5 to 20 micrometers) radiation, and more preferably ranges from about 0.7 to about 4 micrometers.




The hot drying air preferably has a temperature ranging from about 50° C. to about 110° C., and more preferably about 95° C. to about 110° C. The velocity of the air at the surface of the basecoating composition in drying step


60


is less than about 4 meters per second, and preferably ranges from about 1 to about 4 meters per second. The drying period preferably ranges from about 2 to about 6 minutes.




Drying step


60


can be carried out using any conventional combination infrared/convection drying apparatus such as the BGK combined infrared radiation and heated air convection oven which is described in detail above.




The individual emitters


26


can be configured as discussed above and controlled individually or in groups by a microprocessor (not shown) to provide the desired heating and infrared energy transmission rates.




The process of the present invention can further comprise an additional curing step


64


in which hot air


66


is applied to the dried basecoat


62


after step


60


to achieve and hold a peak metal temperature ranging from about 110° C. to about 135° C. for a period of at least about 6 minutes and cure the basecoat. Preferably, a combination of hot air convection drying and infrared radiation is used simultaneously to cure the dried basecoat. As used herein, “cure” means that any crosslinkable components of the dried basecoat are substantially crosslinked.




This curing step


64


can be carried out using a hot air convection dryer, such as are discussed above or in a similar manner to that of step


22


above using a combination infrared radiation/convection drying apparatus, however the peak metal temperature of the substrate ranges from about 110° C. to about 135° C. and the substrate is maintained at the peak metal temperature for at least about 6 minutes, and preferably about 6 to about 20 minutes.




The hot drying air preferably has a temperature ranging from about 110° C. to about 140° C., and more preferably about 120° C. to about 135° C. The velocity of the air at the surface of the basecoating composition in curing step


64


can range from about 4 to about 20 meters per second, and preferably ranges from about 10 to about 20 meters per second.




If a combination of hot air and infrared radiation is used, the infrared radiation applied preferably includes near-infrared region (0.7 to 1.5 micrometers) and intermediate-infrared region (1.5 to 20 micrometers), and more preferably ranges from about 0.7 to about 4 micrometers. Curing step


64


can be carried out using any conventional combination infrared/convection drying apparatus such as the BGK combined infrared radiation and heated air convection oven which is described in detail above. The individual emitters


26


can be configured as discussed above and controlled individually or in groups by a microprocessor (not shown) to provide the desired heating and infrared energy transmission rates.




Referring now to

FIG. 1

, the process of the present invention can further comprise a cooling step


66


in which the temperature of the automobile body


16


having the dried and/or cured basecoat thereon from steps


60


and/or


64


is cooled, preferably to a temperature ranging from about 20° C. to about 30° C. and, more preferably, about 20° C. to about 25° C. Cooling the basecoated automobile body


16


can facilitate application of the powder topcoat by reducing hot air eddy currents which can disturb even deposition of the powder. The basecoated automobile body


16


can be cooled in air at a temperature ranging from about 15° C. to about 25° C., and preferably about 15° C. to about 20° C. for a period ranging from about 3 to about 6 minutes. Alternatively or additionally, the basecoated automobile body


16


can be cooled by exposure to chilled, saturated air blown onto the surface of the substrate at about 4 to about 10 meters per second to prevent cracking of the coating.




After the basecoating on the automobile body


16


has been dried (and cured and/or cooled, if desired), a powder topcoating composition is applied over the dried basecoat in a powder topcoating step


68


. The powder topcoat can be applied by electrostatic spraying using a gun or bell at 60 to 80 kV, 80 to 120 grams per minute to achieve a film thickness of about 50-90 microns, for example.




Preferably the powder topcoating composition is a crosslinkable coating comprising at least one thermosettable film-forming material and at least one crosslinking material such as are described above. The topcoating composition can include additives such as are discussed above, but generally not pigments. Suitable powder topcoats are described in U.S. Pat. No. 5,663,240 (incorporated by reference herein) and include epoxy functional acrylic copolymers and polycarboxylic acid crosslinking agents. The amount of the topcoating composition applied to the substrate can vary based upon such factors as the type of substrate and intended use of the substrate, i.e., the environment in which the substrate is to be placed and the nature of the contacting materials.




In a preferred embodiment, the process of the present invention further comprises a curing step


70


(shown in

FIG. 1

) of curing the powder topcoating composition after application over the dried basecoat. The thickness of the dried and crosslinked composite coating is generally about 0.2 to 5 mils (5 to 125 micrometers), and preferably about 0.4 to 4 mils (10 to 100 micrometers). The powder topcoating can be cured by hot air convection drying and, if desired, infrared heating, such that any crosslinkable components of the powder topcoating are crosslinked to such a degree that the automobile industry accepts the coating process as sufficiently complete to transport the coated automobile body without damage to the topcoat. The powder topcoating can be cured using any conventional hot air convection dryer or combination convection/infrared dryer such as are discussed above. Generally, the powder topcoating is heated to a temperature of about 140° C. to about 155° C. for a period of about 25 to about 30 minutes to cure the powder topcoat.




Alternatively, if the basecoat was not cured prior to applying the powder topcoat, both the basecoat and the powder topcoating composition can be cured together by applying hot air convection and/or infrared heating using apparatus such as are described in detail above to cure both the basecoat and the powder coating composition. To cure the basecoat and the powder coating composition, the substrate is generally heated to a temperature of about 140° C. to about 155° C. for a period of about 25 to about 30 minutes to cure the powder topcoat.




Another aspect of the present invention is a process for coating a polymeric substrate. The process includes steps similar to those used for coating a metal substrate above. A liquid basecoating composition is applied to a surface of the polymeric substrate as described above. The basecoating composition is exposed to air having a temperature ranging from about 10° C. to about 50° C. for a period of at least about 5 minutes to volatilize at least a portion of volatile material from the liquid basecoating composition. The velocity of the air at a surface of the basecoating composition is less than about 0.5 meters per second, and preferably ranges from about 0.3 to about 0.5 meters per second. The apparatus used to volatilize the basecoat can be the same as that used to volatilize the basecoat for the metal substrate.




The process can further comprise an additional (optional) step (which can be used after the volatilization step above or in lieu thereof) of applying infrared radiation and low velocity warm air simultaneously to the basecoating composition for a period of at least about 2 minutes such that the temperature of the metal substrate is increased at a rate ranging from about 0.05° C. per second to about 0.3° C. per second to achieve a peak metal temperature ranging from about 30° C. to about 60° C. and form a pre-dried basecoat upon the surface of the metal substrate.




Infrared radiation and hot air are applied simultaneously to the basecoating composition for a period of at least about 2 minutes and preferably about 2 to about 3 minutes. The velocity of the air at the surface of the basecoating composition is less than about 4 meters per second, and preferably ranges from about 1.5 to about 2.5 meters per second. The temperature of the polymeric substrate is increased at a rate ranging from about 0.4° C. per second to about 1.2° C. per second to achieve a peak polymeric substrate temperature ranging from about 120° C. to about 165° C., such that a dried basecoat is formed upon the surface of the polymeric substrate. The apparatus used to dry the basecoat can be the same combined infrared/hot air convection apparatus such as is discussed above for treating the metal substrate. The basecoat can be cured, if desired, before the powder topcoating is applied.




The basecoated polymeric substrate is preferably cooled to a temperature of about 20° C. to about 25° C. before the powder topcoating composition is applied over the dried basecoat. Suitable powder topcoating compositions and methods of applying the same are discussed in detail above for coating the metal substrate.




The present invention will be described further by reference to the following examples. The following examples are merely illustrative of the invention and are not intended to be limiting. Unless otherwise indicated, all parts are by weight.




EXAMPLE 1




In this example, steel test panels were coated with a liquid basecoat and powder clearcoat as specified below to evaluate drying processes according to the present invention. The test substrates were cold rolled steel panels commercially available from ACT Laboratories, Hiollsdale, Mich., size 30.48 cm by 45.72 cm (12 inch by 18 inch) electrocoated with a cationically electrodepositable primer commercially available from PPG Industries, Inc. as ED-5000. Commercial waterborne basecoat (HWB 83542 W-1 Stone White which is commercially available from PPG Industries, Inc. of Pittsburgh, Pa.) was spray applied to each of panels 1 and Controls 1-5 (1 coat automated bell spray) at 65% relative humidity and 23° C. to give a dry film thickness as specified in Table 1 below. For Control panel 6, HWB 90394 Bright White basecoat (commercially available from PPG) was applied. The basecoat coatings on the panels were dried as specified in Tables 1A and 1 B using a BGK combined infrared radiation and heated air convection oven, which is commercially available from BGK-ITW Automotive Group of Minneapolis, Minn. The panels were then topcoated with PCC10106 powder topcoat (commercially available from PPG) and cured for 30 minutes at 143° C. using hot air convection only to give an overall film thickness as specified in Table 1B.














TABLE 1A













Run No.
















1




Control 1




Control 2




Control 3




















H




V




H




V




H




V




H




V



















Dry Film




1.4-1.6




1.4-1.6




1.4-1.6




1.4-1.6






Thickness BC






(mil)






FLASH STEP






Time (sec)




30




30




30




30






SET STEP






Time (sec)




180




30




30




60






IR Watt




2-3




2-3




2-3




2-3






Density






(kW/sq. m)






Average Air




87° C. (188° F.)




35° C. (95° F.)




60° C. (140° F.)




57° C. (134° F.)






Temp.






Air Flow Rate




2.0




0.64




2.0




1.3






(m/sec)



















Peak Metal




48° C.




59° C.




23° C.




23° C.




30° C.




37° C.




28° C.




32° C.






Temp.




(118° F.)




(138° F.)




(73° F.)




(73° F.)




(86° F.)




(99° F.)




(82° F.)




(90° F.)






Peak Metal




0.14° C.




0.2° C.




0




0




0.24° C.




0.48° C.




0.08° C.




0.16° C.






Heating Rate




(0.25° F.)




(0.36° F.)






(0.43° F.)




(0.86° F.)




(0.15° F.)




(0.28° F.)






(degrees per






second)

















Control 4




Control 5




Control 6




















H




V




H




V




H




V




















Dry Film




1.4-1.6




1.7-1.8




1.5







Thickness BC







(mil)







FLASH STEP







Time (sec)




30




30




300







SET STEP







Time (sec)




180




180




120







IR Watt




2-3




2-3












Density







(kW/sq. m)







Average Air




81° C. (177° F.)




104° C.




(73° F.)







Temp.





(220° F.)







Air Flow Rate




0.64




2.0




0.5







(m/sec)



















Peak Metal




37° C.




44° C.




41° C.




54° C.

















Temp.




(99° F.)




(111° F.)




(106° F.)




(129° F.)







Peak Metal




0.08° C.




0.12° C.




0.1° C.




0.17° C.

















Heating Rate




(0.14° F.)




(0.21° F.)




(0.18° F.)




(0.31° F.)







(degrees per







second)

























TABLE IB













Run No.
















1




Control 1




Control 2




Control 3




















H




V




H




V




H




V




H




V




















DRYING











STEP















Time (sec)




180




180




180




180



















IR Watt




16.5




21




16.5




21




16.5




8.4




16.5




8.4






Density






(kW/sq. m)















Average Air




108° C. (227° F.)




73° C. (164° F.)




73° C. (164° F.)




68° C. (154° F.)






Temp.










Air Flow Rate




1.5-2.5




1.5-2.5




1.5-2.5




1.5-2.5






(m/sec)



















Peak Metal




145° C.




161° C.




110° C.




138° C.




107° C.




111° C.




99° C.




99° C.






Temp.




(293° F.)




(322° F.)




(230° F.)




(280° F.)




(225° F.)




(232° F.)




(210° F.)




(210° F.)






Peak Metal




0.54° C.




0.57° C.




0.48° C.




0.64° C.




0.43° C.




0.41° C.




0.39° C.




0.37° C.






Heating Rate




(0.97° F.)




(1.02° F.)




(0.87° F.)




(1.15° F.)




(0.77° F.)




(0.74° F.)




(0.71° F.)




(0.66° F.)






(degrees per






second)






Total Dry Film




2.2-2.8




2.5-2.7




3.2-4.1




2.8-3.8




2.2-2.3




1.8-2.7




1.4-2.3




1.6-2.5






Thickness (mil)


















Control 4




Control 5




Control 6


















H




V




H




V




H




V

















DRYING







STEP
















Time (sec)




180




180




120



















IR Watt




16.5




8.4




16.5




21




16.5




21







Density







(kW/sq. m)
















Average Air




87° C. (188° F.)




107° C. (225° F.)




71-104° C.







Temp.






(160-220° F.)







Air Flow Rate




1.5-2.5




1.5-2.5




1.5-2.5







(m/sec)



















Peak Metal




106° C.




109° C.




124° C.




157° C.




126° C.












Temp.




(223° F.)




(228° F.)




(255° F.)




(315° F.)




(259° F.)







Peak Metal




0.38° C.




0.36° C.




0.46° C.




0.57° C.




0.85° C.












Heating Rate




(0.69° F.)




(0.65° F.)




(0.83° F.)




(1.03° F.)




(1.53° F.)







(degrees per







second)


















Total Dry Film




1.6-2.1




2-2.4




2.1-2.4




2.2-2.6




3.0-5.0







Thickness (mil)















The appearance and physical properties of the coated panels were evaluated using the following tests: foil solids and appearance (number of pops, Orange Peel rating and overall rating). The weight percent of foil solids for each sample was determined by measuring the non-volatile coating deposited on a 75 mm by 100 mm foil sheet attached to the sprayed panel. The foil was removed from the panel after the drying process and weighed, then baked until nonvolatiles only are present according to ASTM Method 2369-D at a temperature of 110° C. The number of pops on the surface of the coating of each sample was determined by visual inspection of the entire panel surface. The orange peel rating, specular gloss and Distinction of Image (“DOI”) were determined by scanning a 9375 square mm sample of panel surface using an Autospect QMS BP surface quality analyzer device that is commercially available from Perceptron. The Overall Appearance rating was determined by adding 40% of the Orange Peel rating, 20% of the Gloss rating and 40% of the DOI rating. The following Table 2 provides the measured properties.




As shown in Table 2, the coated substrates dried according to the process of the present invention (Run No. 1) generally exhibited less popping, superior orange peel resistance and better overall appearance than the Control panels in which the coatings were not dried by a process according to the present invention.















TABLE 2













Foil




Appearance

















Horizontal




Solids





Orange Peel




Overall






Run No.




or vertical




(%)




Pops




Rating




Rating



















1




H




98




NONE




71




67







V




99




edges




46




58






CONTROL 1




H




96




many




36




35







V




99




micro




54




56






CONTROL 2




H




96




micro




58




62







V




98




on edge




41




52






CONTROL 3




H




95




severe




16




26







V




96




severe




21




38






CONTROL 4




H




97




many




50




56







V




98




many




28




39






CONTROL 5




H




98




edges




61




64







V




99




low ½*




49




59






CONTROL 6









92.6




micro




25




27











*large number of pops on lower half of panel only due to high film thickness which exceeded 1.6 mil recommended maximum.













EXAMPLE 2




In this example, steel test panels were coated with a liquid basecoat and powder clearcoat as specified below to evaluate drying processes according to the present invention. The test substrates were ACT cold rolled steel panels size 30.48 cm by 45.72 cm (12 inch by 18 inch) electrocoated with a cationically electrodepositable primer commercially available from PPG Industries, Inc. as ED-5000. Each test panel was coated a layer of about 1.2-1.6 mils of Alpine White AF2009300 primer (commercially available from Mehnert and Veck). The primer was heated in a conventional air convection oven for 17 minutes to a peak metal temperature of 155° C. (311° F.). Commercial waterborne basecoat (Alpine White III (300) which is commercially available from BASF Corp. of Parsippany, N.J.) was spray applied (1 coat automated spray at 65% relative humidity and 25+/−3° C. to give a dry film thickness of about 0.8 to 1.0 mils. The basecoat coatings on the panels were dried as specified in Table 3A using a combined infrared radiation and heated air convection oven, which is commercially available from BGK-ITW Automotive Group of Minneapolis, Minn. The panels were then topcoated with 2.6-2.8 mils of PCC10106 powder topcoat (commercially available from PPG Industries, Inc.) and cured for 4.5 minutes ramp to hold for 24 minutes at 145° C. (293° F.) using hot air convection to give an overall film thickness as specified in Table 3B.














TABLE 3A













Run No.




























Control




Control







1




2




3




4




5




6




7




1




2
























FLASH STEP















Time (sec)




30




30




30




30




30




30




30




150




30






SET STEP











Infrared




Infrared














only




only






Time (sec)




180




180




180




180




120




60




60




120




120






IR Wall Density




2-3




2-3




2-3




2-3




2-3




2-3




2-3




6-8




6-8






(kw/sq. m)






Average Air




87° C.




102° C.




107° C.




91° C.




88° C.




73° C.




71° C.




88° C.




88° C.






Temp.




(188° F.)




(215° F.)




(225° F.)




(195° F.)




(190° F.)




(164° F.)




(160° F.)




(190° F.)




(190° F.)






Air Flow Rate




1.5-2.5




1.5-2.5




1.5-2.5




1.5-2.5




1.5-2.5




1.5-2.5




1.5-2.5




1.5-2.5




1.5-2.5






(m/sec)






Peak Metal




46° C.




51° C.




53° C.




44° C.




38° C.




36° C.




34° C.




75° C.




60° C.






Temp.




(115° F.)




(124° F.)




(127° F.)




(111° F.)




(100° F.)




(97° F.)




(93° F.)




(167° F.)




(140° F.)






Peak Metal




0.12° C./s




0.14° C./s




0.17° C./s




0.12° C./s




0.13° C./s




0.23° C./s




0.18° C./s




0.41° C./s




0.31° C./s






Heating Rate




(0.22° F./s)




(0.25° F./s)




(0.31° F./s)




(0.22° F./s)




(0.24° F./s)




(0.42° F./s)




(0.33° F./s)




(0.73° F./s)




(0.55° F./s)






degrees per second
























TABLE 3B













Run No.





















1




2




3




4




5




6




7




Control 1




Control 2
























DRYING











Convection




Convection






STEP











only




only






Time (sec)




180




180




120




60




180




180




180




180




180






IR Watt




16.5/21




16.5/21




16.5/21




16.5/21




16.5/21




16.5/21




16.5/21




N/A




N/A






Density






(kw/sq. m)






Horizontal/






Vertical






Average Air




93° C.




93° C.




93° C.




93° C.




93° C.




93° C.




93° C.




66-71° C.




66-71° C.






Temp.




(200° F.)




(200° F.)




(200° F.)




(200° F.)




(200° F.)




(200° F.)




(200° F.)




(150-160° F.)




(150-160° F.)






Air Flow Rate




1.5-2.5




1.5-2.5




1.5-2.5




1.5-2.5




1.5-2.5




1.5-2.5




1.5-2.5




1.5-2.5




1.5-2.5






(m/sec)






Peak Metal




(161° C.)




(145° C.)




(128° C.)




(92° C.)




(135° C.)




(141° C.)




(134° C.)




(69° C.)




(64° C.)






Temp.




(322° F.)




(293° F.)




(262° F.)




(198° F.)




(275° F.)




(286° F.)




(273° F.)




(157° F.)




(147° F.)






Peak Metal




(0.64° C./s)




(0.52° C./s)




(0.62° C./s)




(0.81° C./s)




(0.54° C./s)




(0.58° C./s)




(0.56° C./s)




Lost heat




(0.02° C./s)






Heating Rate




(1.15° F./s)




(0.94° F./s)




(1.12° F./s)




(1.45° F./s)




(0.97° F./s)




(1.05° F./s)




(1.00° F./s)




−0.06° F./s




(0.04° F./s)






degrees per






second






Total Dry Film




0.8-1.0




0.8-1.0




0.8-1.0




0.8-1.0




0.8-1.0




0.8-1.0




0.8-1.0




0.8-1.0




0.8-1.0






Thickness (mil)






Total Drying




6.5




6.5




5.5




4.5




5.5




4.5




4.5




7.5




5.5






Time (min)






Final weight %




99.26




99.05




98.81




94.85




98.90




99.30




99.18




95.07




94.15






solids














The appearance of the coated panels was evaluated using the following tests. Smoothness of the cured powder clearcoats over the basecoat was measured using a Byk Wavescan in which results are reported as long wave and short wave numbers where lower values mean smoother films. Specular gloss at 20° and Distinction of Image (DOI) were measured using an Autospect QMS-BP from Perceptron where higher numbers indicate better performance. Popping was determined by visual observation and rated on a scale of 0 to 5, with 0 indicating no popping and 5 indicating severe popping. The color of the test panel was evaluated at a 45° angle using an X-RITE calorimeter. The Delta L value indicates lightness/darkness. The Delta a value indicates red/green. The Delta b value indicates blue/yellow. The delta E value indicates total color variance. The test results are set forth in Table 4 below in which each reported value represents the results of an average of values for 5 test panels for each run.














TABLE 4













Run No.





















1




2




3




4




5




6




7




Control 1




Control 2
























BYK Long wave




3.9




2.38




2.82




2.9




2.6




2.26




2.74




6.54




5.94






BYK Short wave




12.66




10.42




15.14




18.74




11.68




9.66




12.46




23.62




26.02






Gloss of topcoat at




65.24




71.9




68.42




64.26




69.44




71.78




69.82




57.52




54.44






20°






DOI of topcoat




70.96




75.98




73.32




70.4




75.38




76.12




74.84




66




62.3






Orange Peel




64.66




76.78




73.78




74.1




75.5




76.1




73.32




65.54




66.1






Overall




67.3




75.5




72.5




70.64




74.26




75.26




73.4




64.08




62.24






appearance






Popping




1




1




1




1




1




1




1




1




1






COLOR






Delta L




−0.598




−0.652




−0.684




−1.17




−0.612




−0.63




−0.68




−2.1825




−2.392






Delta a




0.018




−0.048




−0.002




−0.154




−0.026




−0.062




−0.068




−0.112




−0.142






Delta b




−0.144




0.078




0.158




1.026




0.042




0.15




0.276




1.676




2.13






Delta E




0.62




0.67




0.71




1.574




0.618




0.654




0.756




2.8




3.21














As shown in Table 4, coated substrates dried according to the process of the present invention (Run Nos. 1-7) exhibited less waviness and better gloss, distinctness of image and less yellowing and color shift as indicated by Δb, ΔE and ΔL values than the Control panels 1 and 2 in which the coatings were not dried by a process according to the present invention.




EXAMPLE 3




In this example, steel test panels were coated with a liquid basecoat and powder clearcoat as specified below to evaluate drying processes according to the present invention. The test substrates were ACT cold rolled steel panels size 30.48 cm by 45.72 cm (12 inch by 18 inch) electrocoated with a cationically electrodepositable primer commercially available from PPG Industries, Inc. as ED-5000. Each test panel was coated a layer of about 1.1-1.2 mils of AF 204 7328 gray primer (commercially available from Mehnert & Veck). The primer was heated in a conventional air convection oven for 17 minutes to a peak metal temperature of 155° C. (311° F.). Commercial water-borne basecoat (354 Titan Silver which is commercially available from BASF Corp. of Parsippany, N.J.) was spray applied (1 coat at 65% relative humidity and 25+/−3° C. to give a dry film thickness of about 0.2 to 0.6 mils. The basecoatings on the panels were dried as specified in Table 5A using a combined infrared radiation and heated air convection oven, which is commercially available from BGK-ITW Automotive Group of Minneapolis, Minn. The panels were then topcoated with 2.6-2.8 mils of PCC10106 powder topcoat (commercially available from PPG Industries, Inc.) and cured for 4.5 minutes ramp to hold for 24 minutes at 145° C. (293° F.) using hot air convection to give an overall film thickness as specified in Table 5B.




The appearance of the coated panels was evaluated using the tests discussed above in Example 2. The test results are set forth in Table 6 below in which each reported value represents the results of an average of values for 5 test panels for each run.














TABLE 5A













Run No.




























Control




Control







1




2




3




4




5




6




7




1




2
























FLASH STEP















Time (sec)




30




30




30




30




30




30




30




150




30






SET STEP











Infrared




Infrared














only




only






Time (sec)




180




180




180




180




120




60




60




120




120






IR Watt Density




2-3




2-3




2-3




2-3




2-3




2-3




2-3




6-8




6-8






(kw/sq. m)






Air Temp




88° C.




93° C.




88° C.




88° C.




82° C.




82° C.




85° C.




88° C.




88° C.







(190° F.)




(200° F.)




(190° F.)




(190° F.)




(180° F.)




(180° F.)




(185° F.)




(190° F.)




(190° F.)






Air Flow Rate




1.5-2.5




1.5-2.5




1.5-2.5




1.5-2.5




1.5-2.5




1.5-2.5




1.5-2.5




1.5-2.5




1.5-2.5






(m/sec)






Peak Metal




47° C.




46° C.




45° C.




45° C.




34° C.




34° C.




39° C.




74° C.




65° C.






Temp.




(117° F.)




(115° F.)




(113° F.)




(113° F.)




(93° F.)




(93° F.)




(102° F.)




(165° F.)




(149° F.)






Peak Metal




0.12° C./s




0.12° C./s




0.11° C./s




0.12° C./s




0.11° C./s




0.12° C./s




0.11° C./s




0.32° C./s




0.32° C./s






Heating Rate




(0.22° F./s)




(0.21° F./s)




(0.19° F./s)




(0.21° F./s)




(0.19° F./s)




(0.22° F./s)




(0.20° F./s)




(0.58° F./s)




(0.57° F./s)






degrees per second
























TABLE 5B













Run No.





















1




2




3




4




5




6




7




Control 1




Control 2
























DRYING











Convection




Convection






STEP











only




only






Time (sec)




180




180




120




60




180




180




180




180




180






IR Watt




16.5-21




16.5-21




16.5-21




16.5-21




16.5-21




16.5-21




16.5-21




N/A




N/A






Density






(kw/sq. m))






Ave. Air




93° C.




93° C.




93° C.




93° C.




93° C.




93° C.




93° C.




66-71° C.




66-71° C.






Temp.




(200° F.)




(200° F.)




(200° F.)




(200° F.)




(200° F.)




(200° F.)




(200° F.)




(150-160° F.)




(150-160° F.)






Air Flow Rate




1.5-2.5




1.5-2.5




1.5-2.5




1.5-2.5




1.5-2.5




1.5-2.5




1.5-2.5




1.5-2.5




1.5-2.5






(m/sec)






Peak Metal




133° C.




133° C.




114° C.




89° C.




125° C.




125° C.




135° C.




74° C.




66° C.






Temp.




(271° F.)




(271° F.)




(237° F.)




(192° F.)




(257° F.)




(257° F.)




(275° F.)




(165° F.)




(151° F.)






Peak Metal




0.48° C./s




0.48° C./s




0.57° C./s




0.73° C./s




0.51° C./s




0.51° C./s




0.53° C./s




Lost heat




0.006° C./s






Heating Rate




(0.86° F./s)




(0.87° F./s)




(1.03° F./s)




(1.32° F./s)




(0.91° F./s)




(0.91° F./s)




(0.96° F./s)




(−0.02° F./s)




(0.0l° F./s)






degrees per






second






Total Dry Film




0.6-0.8




0.6-0.8




0.6-0.8




0.6-0.8




0.6-0.8




0.6-0.8




0.6-0.8




0.6-0.8




0.6-0.8






Thickness (mil)






Total Drying




6.5




6.5




5.5




4.5




5.5




4.5




4.5




7.5




5.5






Time (min)






Final weight %




99.38




91.7




98.96




96.80




98.12




99.36




98.93




93.30




90.15






solids
























TABLE 6













Run No.





















1




2




3




4




5




6




7




Control 1




Control 2
























BYK Long wave




2.92




2.54




2.46




2.08




2.66




2.475




2.56




2.98




2.36






BYK Short wave




14.44




14.84




17.14




19.04




16.46




14.65




14.16




23.5




21.48






Gloss of topcoat at 20°




58.84




58.58




53.62




53.04




59.1




57.22




60.22




46.88




51.16






DOI of topcoat




65.2




65.14




61.06




60.18




65.46




63.96




66.46




55.14




58.66






Orange Peel




70.06




69.56




69.4




73.28




71.84




69.68




71.86




67.84




71.20






Overall Appearance




65.86




65.62




62.9




63.98




66.74




64.92




67.38




58.56




62.18






Popping




1




1




1




1




1




1




1




1




1












COLOR




25° ANGLE




















Delta L




−5.488




4.974




−3.874




−2.52




−6.012




−6.026




−5.792




−0.128




−6.56






Delta a




0.524




0.566




0.562




0.62




0.51




0.594




0.564




0.602




0.598






Delta b




0.348




0.296




0.148




0.246




0.32




0.128




0.258




0.4




0.328






Delta E




5.524




5.018




3.928




2.612




6.044




6.056




5.824




0.85




3.688












COLOR




45° ANGLE




















Delta L




−1.262




−1.174




−2.038




−2.366




−1.17




−1.09




−1.42




−2.662




−2.456






Delta a




0.37




0.378




0.38




0.47




0.366




0.354




0.386




0.44




0.476






Delta b




0.326




0.33




0.3




0.414




0.348




0.282




0.39




0.552




0.394






Delta E




1.358




1.282




2.098




2.448




1.458




1.332




1.254




2.756




2.538












COLOR




75° ANGLE




















Delta L




1.542




1.288




0.106




−0.564




1.924




1.74




1.718




−2.164




−0.088






Delta a




0.454




0.482




0.498




0.538




0.442




0.44




0.462




0.6




0.51






Delta b




0.218




0.214




0.226




0.372




0.196




0.092




0.224




0.442




0.356






Delta E




1.636




1.408




0.886




0.884




1.994




1.812




1.802




2.296




0.656














As shown in Table 6, the coated substrates dried according to the process of the present invention (Run No. 1) generally exhibited lower values for BYK short wave, superior gloss and distinctness of image and than the Control panels 1 and 2 in which the coatings were not dried according to the present invention.




The processes of the present invention provide rapid coating of metal and polymeric substrates, can eliminate or reduce the need for long assembly line ovens can drastically reduce overall processing time. Less popping and good flow and appearance of the basecoat, even at higher thicknesses, provides more operating latitude when applying the basecoat which can lower repairs.




It will be appreciated by those skilled in the art that changes could be made to the embodiments described above without departing from the broad inventive concept thereof. It is understood, therefore, that this invention is not limited to the particular embodiments disclosed, but it is intended to cover modifications that are within the spirit and scope of the invention, as defined by the appended claims.



Claims
  • 1. A process for coating a metal substrate, comprising the steps of:(a) applying a liquid basecoating composition to a surface of the metal substrate; (b) applying air having a first air temperature ranging from about 10° C. to about 50° C. to the basecoating composition for a first period of at least about 5 minutes to volatilize at least a portion of volatile material from the liquid basecoating composition, a first velocity of the air at a surface of the basecoating composition ranging from about 0.3 to about 0.5 meters per second; (c) applying a first infrared radiation and hot air having a second air temperature ranging from about 50° C. to about 110° C. simultaneously to the basecoating composition for a second period of at least about 2 minutes, a second velocity of the air at the surface of the basecoating composition being less than about 4 meters per second, a first temperature of the metal substrate being increased at a first rate ranging from about 0.4° C. per second to about 1.2° C. per second to achieve a first peak metal temperature of the substrate ranging from about 120° C. to about 165° C., such that a dried basecoat is formed upon the surface of the metal substrate; and (d) applying a powder topcoating composition over the dried basecoat.
  • 2. The process according to claim 1, wherein the metal substrate is selected from the group consisting of iron, steel, aluminum, zinc, magnesium, alloys and combinations thereof.
  • 3. The process according to claim 1, wherein the metal substrate is an automotive body component.
  • 4. The process according to claim 1, wherein the volatile material of the liquid basecoating composition comprises water.
  • 5. The process according to claim 1, wherein the volatile material of the liquid basecoating composition is selected from the group consisting of organic solvents and amines.
  • 6. The process according to claim 1, wherein the air has a temperature ranging from about 20° C. to about 40° C. in the step (b).
  • 7. The process according to claim 1, wherein the first period ranges from about 5 to about 10 minutes in the step (b).
  • 8. The process according to claim 1, wherein the first infrared radiation is emitted at a wavelength ranging from about 0.7 to about 20 micrometers in the step (c).
  • 9. The process according to claim 8, wherein the wavelength ranges from about 0.7 to about 4 micrometers.
  • 10. The process according to claim 1, wherein the first infrared radiation is emitted at a power density ranging from about 10 to about 40 kilowatts per square meter of emitter wall surface in the step (c).
  • 11. The process according to claim 1, wherein the second period ranges from about 2 to about 6 minutes in the step (c).
  • 12. The process according to claim 1, wherein the second velocity ranges from about 1 to about 4 meters per second in the step (c).
  • 13. The process according to claim 1, wherein the first temperature of the metal substrate is increased at a second rate ranging from about 0.5° C. per second to about 1.1° C. per second in step (c).
  • 14. The process according to claim 1, wherein the first peak metal temperature of the metal substrate ranges from about 132° C. to about 155° C. in the step (c).
  • 15. The process according to claim 1, further comprising an additional step (b′) of applying a second infrared radiation and warm air having a temperature ranging from about 25° C. to about 50° C. simultaneously to the basecoating composition for a third period of at least about 2 minutes between the steps (b) and (c), a third velocity of the air at the surface of the basecoating composition being less than about 4 meters per second, a second temperature of the metal substrate being increased at a third rate ranging from about 0.05° C. per second to about 0.3° C. per second to achieve a second peak metal temperature ranging from about 30° C. to about 60° C., such that the pre-dried basecoat is formed upon the surface of the metal substrate.
  • 16. The process according to claim 1, further comprising an additional step (c′) of applying hot air having a temperature ranging from about 110° C. to about 140° C. to the dried basecoat to achieve a third peak metal temperature ranging from about 110° C. to about 135° C. for a fourth period of at least about 6 minutes after the step (c), such that a cured basecoat is formed upon the surface of the metal substrate.
  • 17. The process according to claim 16, wherein the additional step (c′) further comprises applying a third infrared radiation to the dried basecoat simultaneously while applying the hot air.
  • 18. The process according to claim 16, further comprising an additional step (c″) of cooling the metal substrate having the dried basecoat thereon to a third temperature of about 20° C. to about 30° C. between the steps (c) and (d).
  • 19. The process according to claim 1, further comprising an additional step (f) of curing the powder topcoating composition after application over the dried basecoat.
  • 20. The process according to claim 19, wherein the additional step (f) further comprises curing the basecoating composition and the powder coating composition after application of the powder topcoating composition over the dried basecoat.
  • 21. A process for coating a metal substrate having an electrodeposited coating thereon, comprising the steps of:(a) applying a liquid basecoating composition to a surface of the metal substrate; (b) applying a first infrared radiation at a power density of about 25 kilowatts per meter square or less and warm air having a first air temperature ranging from about 25° C. to about 50° C. simultaneously to the basecoating composition for a first period of at least about 2 minutes, a first velocity of the air at the surface of the basecoating composition ranging from about 0.3 to about 4 meters per second, a first temperature of the metal substrate being increased at a first rate ranging from about 0.05° C. per second to about 0.3° C. per second to achieve a first peak metal temperature ranging from about 30° C. to about 60° C., such that a pre-dried basecoat is formed upon the surface of the metal substrate; (c) applying a second infrared radiation and hot air having a second air temperature ranging from about 50° C. to about 110° C. simultaneously to the basecoating composition for a second period of at least about 2 minutes, a second velocity of the air at the surface of the basecoating composition ranging from about 1 to about 4 meters per second, a second temperature of the metal substrate being increased at a second rate ranging from about 0.4° C. per second to about 1.2° C. per second to achieve a second peak metal substrate temperature ranging from about 120° C. to about 165° C., such that a dried basecoat is formed upon the surface of the metal substrate having the electrodeposited coating thereon; and (d) applying a powder topcoating composition over the dried basecoat.
  • 22. A process for coating a polymeric substrate, comprising the steps of:(a) applying a liquid basecoating composition to a surface of the polymeric substrate; (b) applying air having a first air temperature ranging from about 10° C. to about 50° C. to the basecoating composition for a first period of at least about 5 minutes to volatilize at least a portion of volatile material from the liquid basecoating composition, a first velocity of the air at a surface of the basecoating composition ranging from about 0.3 to about 0.5 meters per second; (c) applying infrared radiation and hot air having a second air temperature ranging from about 50° C. to about 110° C. simultaneously to the basecoating composition for a second period of at least about 2 minutes, a second velocity of the air at the surface of the basecoating composition being less than about 4 meters per minute, a first temperature of the polymeric substrate being increased at a rate ranging from about 0.4° C. per second to about 1.2° C. per second to achieve a peak polymeric substrate temperature ranging from about 120° C. to about 165° C., such that a dried basecoat is formed upon the surface of the polymeric substrate; and (d) applying a powder topcoating composition over the dried basecoat.
  • 23. The process according to claim 22, further comprising an additional step (c″) of cooling the polymeric substrate having the dried basecoat thereon to a second temperature of about 20° C. to about 30° C. between the steps (c) and (d).
  • 24. The process according to claim 22, further comprising an additional step (e) of curing the powder topcoating composition after application over the dried basecoat.
  • 25. A process for coating a polymeric substrate, comprising the steps of:(a) applying a liquid basecoating composition to a surface of the polymeric substrate; (b) applying a first infrared radiation at a first power density of about 25 kilowatts per square meter or less and warm air having a first air temperature ranging from about 10° C. to about 50° C. simultaneously to the basecoating composition for a first period of at least about 2 minutes, a first velocity of the air at the surface of the basecoating composition ranging from about 0.3 to about 4 meters per second, a first temperature of the substrate being increased at a first rate ranging from about 0.05° C. per second to about 0.3° C. per second to achieve a first peak substrate temperature ranging from about 30° C. to about 60° C., such that a pre-dried basecoat is formed upon the surface of the polymeric substrate; (c) applying a second infrared radiation at a second power density of about 25 kilowatts per square meter or less and hot air having a second air temperature ranging from about 50° C. to about 110° C. simultaneously to the basecoating composition for a second period of at least about 2 minutes, a second velocity of the air at the surface of the basecoating composition ranging from about 1.5 to about 4 meters per second, a second temperature of the polymeric substrate being increased at a second rate ranging from about 0.4° C. per second to about 1.2° C. per second to achieve a second peak polymeric substrate temperature ranging from about 120° C. to about 165° C., such that a dried basecoat is formed upon the surface of the polymeric substrate; and (d) applying a powder topcoating composition over the dried basecoat.
CROSS-REFERENCE TO RELATED APPLICATIONS

This patent application is related to U.S. patent application Ser. No. 09/320,265 entitled “Multi-Stage Processes for Coating Substrates with Liquid Basecoat and Liquid Topcoat”; U.S. patent application Ser. No. 09/320,483 entitled “Processes for Coating a Metal Substrate with an Electrodeposited Coating Composition and Drying the Same”; U.S. patent application Ser. No. 09/320,484 entitled “Processes For Drying and Curing Primer Coating Compositions”; and U.S. patent application Ser. No. 09/320,522 entitled “Processes For Drying Topcoats And Multicomponent Composite Coatings On Metal And Polymeric Substrates”, all of Donaldson J. Emch and each filed concurrently with the present application.

US Referenced Citations (70)
Number Name Date Kind
RE. 34730 Salatin et al. Sep 1994
1998615 Groven Apr 1935
2377946 Leary Jun 1945
2387516 Kaminski Oct 1945
2472293 Groven Jun 1949
2478001 Miskella Aug 1949
2498339 Miskella Feb 1950
2876135 Levine Mar 1959
3151950 Newman et al. Oct 1964
3455806 Spoor et al. Jul 1969
3591767 Mudie Jul 1971
3731051 Ellersick May 1973
3749657 Le Bras et al. Jul 1973
3953643 Cheung et al. Apr 1976
3953644 Camelon et al. Apr 1976
3998716 Masar et al. Dec 1976
4259566 Kobayashi Mar 1981
4265936 Prohaska, Jr. May 1981
4336279 Metzger Jun 1982
4349724 Ellersick Sep 1982
4389970 Edgerton Jun 1983
4390564 Kimble Jun 1983
4403003 Backhouse Sep 1983
4416068 Nilsson et al. Nov 1983
4423312 Wiedenfeld et al. Dec 1983
4461094 Schnalke Jul 1984
4535548 Hyde Aug 1985
4546553 Best Oct 1985
4594266 Lemaire et al. Jun 1986
4731290 Chang Mar 1988
4771728 Bergman, Jr. Sep 1988
4820555 Kuwajima et al. Apr 1989
4822685 Perez et al. Apr 1989
4891111 McCollum et al. Jan 1990
4894261 Gulbins et al. Jan 1990
4907533 Nelson et al. Mar 1990
4908231 Nelson et al. Mar 1990
4933056 Corrigan et al. Jun 1990
4943447 Nelson et al. Jul 1990
4971837 Martz et al. Nov 1990
4988537 Tanimoto et al. Jan 1991
5050232 Bergman et al. Sep 1991
5075132 Ogasawara Dec 1991
5137972 Cook Aug 1992
5196485 McMonigal et al. Mar 1993
5323485 Josefsson et al. Jun 1994
5335308 Sorensen Aug 1994
5338578 Leach Aug 1994
5340089 Heath et al. Aug 1994
5401790 Poole et al. Mar 1995
5407747 Sammel et al. Apr 1995
5425970 Lahrmann et al. Jun 1995
5427822 Bracciano Jun 1995
5453295 Sammel et al. Sep 1995
5486384 Bastian et al. Jan 1996
5492731 Temple et al. Feb 1996
5551670 Heath et al. Sep 1996
5556527 Igarashi et al. Sep 1996
5612095 Brock et al. Mar 1997
5614271 Shibuya et al. Mar 1997
5635302 Budde et al. Jun 1997
5654037 Moore et al. Aug 1997
5698310 Nakamura et al. Dec 1997
5709909 Leibfarth et al. Jan 1998
5716678 Rockrath et al. Feb 1998
5760107 Valko et al. Jun 1998
5820933 Carroll Oct 1998
5820987 Kaufman et al. Oct 1998
5871809 Liedtke et al. Feb 1999
5888592 Biallas et al. Mar 1999
Foreign Referenced Citations (5)
Number Date Country
19642970 Apr 1997 DE
0038127 Mar 1981 EP
0148718 Nov 1984 EP
2091859 Aug 1982 GB
WO 9840170 Sep 1998 WO
Non-Patent Literature Citations (9)
Entry
“Infrared Flash Oven” Brochure, BGK Automotive Group 1989, no month.
“Heated Flash Technical Specifications”, General Motors NAO Paint General Technical Specifications Document No. 34909 (Jan. 14, 1997).
“Specifications for Heated Flash Off for Water-Borne Basecoat Applications”, Ford Motor Co. Body and Assembly Operations Sec. 240 (Jan. 15, 1995).
“The Proof Is In The Heating”, Industrial Energy Efficiency Centre, U.K., HQ41D (April 25, 1995).
R. Hampshire “The Use of Radiant Heat Transfer in the Curing of Coatings on Complex Geometrics and Problematic Substrates”, Interfinish 1996 World Congress, Birmingham, UK (Sep. 1996).
W. Veenstra et al., “IRK Halogen Infrared Radiators in the Industrial Heating Process”, Philips Lighting, Eindhoven, Netherlands no date.
“Powder Coatings”, Blasdel Equipment Infrared Ovens http://blasdelent,com/powder.html (Mar. 12, 1999).
“Gas Infrared Ovens”, Thermovation Engineering Inc. http://www.thomasregister.com/olc/thermovation/gas.htm (Mar. 12, 1999).
“Combination Ovens for Curing of Powder Coatings”, IUT no date.