1. Field of the Invention
The present invention relates to a multiple tube type separation membrane module used to separate specific components from a fluid such as a solution, a mixed gas, and the like.
2. Description of the Related Art
Multiple tube type separation membrane modules as equipment for separating components in solutions or mixed gases are known. The separation membrane element used in the multiple tube type separation membrane module is made by composing a membrane of zeolite and the like having fine pores approximately as large as the molecules of substances to be separated around a porous tube.
The covers 4a and 4b have outlets 8a and 8b for components permeating the membrane, respectively. When a fluid F1 is supplied from the fluid inlet 6 as well as the insides of the covers 4a and 4b being sucked from the outlets 8a and 8b for membrane-permeable-components, the fluid F2 from the fluid F1 comes out through the tubular separation membrane elements 3 and flows out from the outlets 8a and 8b, and the remaining fluid F3 flows out from the outlet 7. Since the multiple tube type separation membrane module densely holds the separation membrane elements 3 in the cylindrical shell 1, a large total area of the separation membranes is provided in the shell and a large fluid processing capacity is available, although the shell is compact. However, the processing capabilities of the tubular separation membrane elements 3 are not fully effective, and the processing capacity of the multiple tube type separation membrane module is far less than what calculated as the sum of the processing capacity of the individual membrane elements 3. It is contemplated that this is because (a) although the flow direction of fluid can be effectively regulated by the baffles, diffusion rate of membrane permeating components from the fluid to the surface of the tubular separation membrane is low due to the insufficient turbulence of the fluid in the vicinities of the tubular separation membrane resulting from the difficulty to sufficiently increase the flow velocity of the fluid with the buffles, and (b) the shell has a dead space to which the fluid is not distributed and the separation membranes in the dead space do not contribute to the separation.
Accordingly, an object of the present invention is to provide a multiple tube type separation membrane module which enables full use of the processing capacity of individual tubular separation membrane element in the module.
As a result of diligent studies in view of the above object, the inventors have conceived the present invention by discovering that the processing capacity of the multiple tube type separation membrane module having plurality of tubular separation membrane elements for separating membrane-permeable-components from a fluid is improved, when the tubular separation membrane elements are surrounded by tubular materials to form narrow spaces there-between, since the fluid passes through the spaces at a high speed promoting turbulence of the fluid in the vicinity of the tubular separation membrane elements as well as the fluid is uniformly distributed to the overall separation membranes.
That is, a multiple tube type separation membrane module of the present invention includes plurality of tubular separation membrane elements having sealed ends and open ends; outside pipes surrounding the tubular separation membrane elements with spaces formed therebetween and having first openings on the sealed ends side of the tubular separation membrane elements as well as second openings in the vicinities of the open ends of the tubular separation membrane elements; means for inlet communicating with the first openings of the outside pipes; first means for outlet communicating with the open ends of the tubular separation membrane elements; and second means for outlet communicating with the second openings of the outside pipes, wherein a fluid flowing from the first openings of the outside pipes through the means for inlet flows in the spaces between the tubular separation membrane elements and the outside pipes, components separated from the fluid by the tubular separation membrane elements flows out from the first means for outlet through the open ends of the tubular separation membrane elements, and the remaining fluid flows out from the second means for outlet.
A preferable example of the present invention is a multiple tube type separation membrane module having a shell provided with an outlet; first support plate fixed to an end of the shell; second support plate fixed to the other end of the shell; plurality of outside pipes supported by the first and second support plates and extending in the lengthwise direction of the shell; tubular separation membrane elements disposed in the respective outside pipes; first cover attached to the first support plate; and second cover attached to the second support plate, wherein the outside pipes have first openings formed on the first cover side through which a fluid flows as well as second openings formed on the second cover side through which the remaining fluid flows out after the completion of separation processing, the tubular separation membrane elements have sealed ends on the first cover side as well as open ends on the second cover side, and the spaces between the outside pipes and the tubular separation membrane elements are opened on the first cover side and sealed on the second cover side, thereby components separated by the tubular separation membrane elements from the fluid flowing from the first openings of the outside pipes into the spaces between the outside pipes and the tubular separation membrane elements flows out into the second cover from the open ends of the tubular separation membrane elements, and the remaining fluid flows out from the outlet of the shell through the second openings.
A partition may be attached to the first cover to form a first chamber and a second chamber on both sides of the partition. A fluid flowed into the first chamber may pass through the spaces between the outside pipes having first openings in the first chamber and the tubular separation membrane elements, flow out from the second openings of the outside pipes, flow into the outside pipes having first openings in the second chamber from the second openings, pass through the spaces between the outside pipes and the tubular separation membrane elements, and flow into the second chamber.
It is preferable that the sealed ends of the tubular separation membrane elements are fixed in the outside pipes keeping the spaces by pins disposed to either the outside pipes or the sealed ends. The inside diameter of the outside pipes is preferably 1.1 to 2 times the outside diameter of the tubular separation membrane elements.
It is preferable that the tubular separation membrane elements are hollow ceramic tubes around which separation membranes having fine pores approximately as large as molecules of substances to be separated are formed. The separation membranes are preferably composed of zeolite.
The cylindrical shell 1 has an outlet 7 projecting outward through which non-permeable fluid F3 is discharged. The non-permeable fluid outlet 7 is disposed at a position near to the support plate 2b fixed to the other end of the cylindrical shell 1. The cover 4a has an inlet 6 projecting outward through which fluid F1 is supplied, and the cover 4b has an outlet 8 projecting outward through which membrane-permeable fluid F2 (separated component) is discharged. Further, the covers 4a and 4b have flanges gastightly engaged with the support plates 2a and 2b fixed to both ends of the cylindrical shell 1, respectively.
The support plate 2a fixed to the one end of the cylindrical shell 1 has plurality of openings 21a, and the support plate 2b fixed to the other end of the cylindrical shell 1 has plurality of openings 21b. Each of the openings 21a of the support plate 2a is correctly positioned to face the corresponding opening 21b of the support plate 2b. The extreme ends 131 of the outside pipes 13 are fixed to the openings 21a of the support plate 2a, and the rear ends 132 of the same outside pipes 13 are fixed to the openings 21b of the support plate 2b corresponding to the openings 21a, thereby the outside pipes 13 are supported by the support plates 2a and 2b. The outside pipes 13 have second openings (fluid passing ports) 133 at positions near to the support plate 2b.
Plurality of pins 34 are disposed on the inside surface of the outside pipe 13 at positions near to the support plate 2a, and seal member 9 abutt on the extreme ends of the pins 34. The pins 34 support the tubular separation membrane element 3 in which the seal member 9 is fitted. Note that the pins 34 may be disposed to the seal member 9. Further, a spacer having an opening may be interposed between the inside surface of the outside pipe 13 and the seal member 9. The tubular separation membrane element 3 supported by the pins 34 is free to slide in the outside pipe 13. Accordingly, when a fluid F1 having a high temperature flows into the outside tube 13, the tubular separation membrane element 3 can be prevented from being cracked due to the difference of the thermal expansion between the outside pipe 13 and the tubular separation membrane element 3.
The outside pipe 13 is fixed to the support plates 2a and 2b gastightly by welding. The support plate 2b is welded to the outside pipe 13 being cured to prevent the portion where the fixing member 10 is threaded into the outside pipe 13 from being deformed.
The outside pipe 13 may be provided with projections on the inside surface thereof. The projection can promote turbulence in the fluid F1 flowing in the outside pipe 13. The shape of the projection is not particularly limited, and the projection need not be formed integrally with the outside pipe 13. For example, a spring having the same outside diameter as the inside diameter of the outside pipe 13 may be disposed in the lengthwise direction of the outside pipe 13 coaxially therewith.
As shown in
Since the fluid F1 passes through the spaces between the outside pipes 13 and the tubular separation membrane elements 3, the flow velocity of the fluid F1 is increased and the fluid in the vicinity of the tubular separation membrane element 3 is made turbulent, thereby the diffusion of a membrane permeable substances in the fluid F1 to the vicinities of the tubular separation membrane elements 3 is accelerated. As a result, permeation rate of the fluid F2 through the tubular separation membrane elements 3 is increased, and processing capabilities there of are improved consequently. When the fluid F1 is a liquid, preferable flow velocity of the fluid F1 in the spaces between the outside pipes 13 and the tubular separation membranes element 3 is 0.2 to 2 m/s. Since resistance occurs against the flow of the fluid F1 passing through the spaces between the outside pipes 13 and the tubular separation membrane elements 3 by keeping the flow velocity of the fluid F1 within the above range, the fluid flowed into the cover 4a is uniformly dispersed in the spaces between the outside pipes 13 and the tubular separation membrane elements 3 and flows therethrough. As a result, the entire area of the membranes contributes to cause the component to pass therethrough, thereby the processing capacity of the multiple tube type separation membrane module is improved in its entirety. When the fluid F1 is a gas, preferable flow velocity of the fluid F1 is 2 to 20 m/s.
The side of fluid inlet 6 of the cover 4a is arranged as the first chamber 42 by the partition 41, and the opposite side thereof is arranged as the second chamber 43. A fluid outlet 7 extending outward is disposed to the second chamber 43 divided by the partition 41. Outside pipes are composed of first outside pipes 13a whose extreme ends 131 are fixed to the first chamber 42 and second outside pipes 13b whose extreme ends 131 are fixed to the second chamber 43.
The fluid F1 supplied to the cylindrical shell 1 from the fluid inlet 6 passes through the spaces between the first outside pipes 13a and the tubular separation membrane elements 3 and flows to second openings 133a of the first outside pipes 13a. At the same time, when the inside of cover 4b is vacuumed from membrane permeable fluid outlet 8 thereof, the insides of the tubular separation membrane elements 3, which open in the cover 4b, are also vacuumed likewise the embodiment shown in FIGS. 1 to 4. Accordingly, substances, which has permeability to the separation membranes of the tubular separation membrane elements 3, permeate the separation membranes and flows into the tubular separation membrane elements 3. The fluid F2 that permeated the tubular separation membrane elements 3 combines together in the cover 4b and flows out from the membrane-permeable fluid outlet 8.
In contrast, the primarily processed fluid F4, which does not permeate the tubular separation membrane elements 3 in the first outside pipes 13a, flows into the cylindrical shell 1 from the second openings 133a of the first outside pipes 13a. The primarily processed fluid F4, which fills the cylindrical shell 1, flows into the spaces between the outside pipes 13b and the tubular separation membrane elements 3 from second openings 133b of the second outside pipes 13b whose extreme ends 131 are fixed to the second chamber 43, passes through the spaces therebetween, combines in the second chamber 43 of the cover 4a, and flows out from the fluid outlet 7 disposed to the second chamber 43.
When the multiple tube type separation membrane module shown in
In any of the multiple tube type separation membrane modules, it is preferable to use a tubular porous support member which is composed of ceramics or metal and around which a separation membrane composed of zeolite and the like are formed as the tubular separation membrane element 3. When, for example, the fluid F1 composed of water and ethanol is separated, a tubular separation membrane element composed of a tubular support member, which is composed of porous ceramics and around which an A type zeolite membrane is formed, can be used. In this case, water becomes to compose the fluid F2 which permeates the tubular separation membrane element and ethanol becomes to compose the non-permeate fluid F3.
Tubular separation membrane elements 3 were made by forming zeolite membranes around tubular porous support members composed of α-alumina (length: 80 cm, outside diameter: 10 mm, inside diameter: 9 mm) , and a multiple tube type separation membrane module (length: 110 cm, outside diameter: 14 cm) similar to the embodiment shown in
Mixed stream composed of water and ethanol was separated likewise the Example 1 except that a multiple tube type separation membrane module (length: 110 cm, outside diameter: 14 cm, number of tubular separation membrane elements: 25) was assembled as shown in
The multiple tube type separation membrane module shown in
The flow-out rate of the water vapor as the membrane-permeable fluid F2 was 0.8 kg/h at the membrane-permeable component outlets 8a and 8b.
The multiple tube type separation membrane module of the present invention separates membrane-permeable-components (membrane-permeable-fluid) from a fluid by the tubular separation membrane elements wherein the fluid is caused to pass through the narrow spaces formed by surrounding the tubular separation membrane elements with the surrounding members. With the above arrangement, since a fluid flow is improved and the contact state between the fluid and the tubular separation membrane element is improved, the processing capabilities of the respective tubular separation membrane elements can be effectively exhibited. Further, the flow velocity of the fluid which permeates the tubular separation membrane elements is increased by increasing the flow velocity of the fluid in the vicinities of the tubular separation membrane elements, thereby the processing capacity of the multiple tube type separation membrane module can be greatly improved in its entirety.
Number | Date | Country | Kind |
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2002-294010 | Oct 2002 | JP | national |
Filing Document | Filing Date | Country | Kind | 371c Date |
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PCT/JP03/12678 | 10/2/2003 | WO | 4/6/2005 |