Patent Application
20240417563
The present invention refers to the field of the industry of road, airport, port, and railway pavements, including their relative infrastructures and structures.
In particular, the invention refers to the production of a multifunctional thin bituminous layer containing plastic material and/or a mixture of plastic materials and optionally graphene, which is used in a surface or interlayer treatment for making and maintenance of bituminous pavements, even more in particular road, airport, port, and railway bituminous pavements, including their infrastructures and structures.
Bituminous membranes are known in the art and may be laid onto architectural or infrastructural elements, such as road surfaces, for example in order to improve their water-proofing properties.
An example of bituminous membrane is disclosed in the Chinese patent application CN108129857 A.
Bituminous thin surface (“BTS”) treatments are known protection interventions in the maintenance of bituminous pavements, namely pavements based on bituminous conglomerate, and consist of inert materials which are variously selected, bound by bitumen, laid and rolled at temperatures of about 150° C.
In particular, in BTS, a layer or membrane of bituminous emulsion is laid to cover the old wearing course.
The thin layer of BTS can restore several surface deteriorations of limited seriousness, thereby providing a durable and friction-resistant surface on the existing pavement.
They are used because of their ability of sealing and modeling again the road pavement, eliminating surface defects (such as crumbling, deformations due to the rutting phenomenon, reduced adhesion). The reduced thickness allows to prevent milling of the wearing course, without making substantial unbalances to the superficial regulation of the platform water, just by refilling the existing surfaces, thereby extending their useful life, preserving their structural characteristics and improving their functional performance.
Therefore, the bituminous thin surface treatments allow to obtain a considerable economic saving, prolonging the useful life of road pavement.
However, the use of bituminous thin surface treatments is usually not recommended in the case of road pavements with a significant level of wear and deterioration and, often, the known technologies described above do not give the pavement the desired mechanical properties.
Also known are SAMI (“Stress-Absorbing Membrane Interlayer”), adhesive bituminous materials that function as a flexible waterproofing membrane laid inside the pavement, namely under the bituminous layers above them.
Therefore, SAMIs may be applied in road pavements ex-novo or, more commonly, on the occasion of interventions of maintenance of existing pavements, but, in any case, generally under the wearing course.
SAMIs prevent cracks and defects of the underlying old layers from propagating upwards, thereby redistributing stresses and deformations deriving from vehicular traffic downwards.
SAMIs are obtained from the combination of a bituminous emulsion modified with elastomeric polymers, such as styrene-butadiene-styrene (SBS) or styrene-butadiene rubber (SBR), and crushed aggregates with suitable morphological and mechanical characteristics.
At the state of the art, a known example of SAMI layer is Fibermat™, which represents a combination of layers based on a bituminous emulsion modified with elastomeric polymers, such as styrene-butadiene-styrene (SBS) or styrene-butadiene rubber (SBR), glass fiber and aggregates, respectively. In particular, a layer made of glass fiber is placed between two layers of bituminous emulsion, thereby ensuring a complete covering of the surface, a very high resistance, impermeability and higher fatigue resistance.
To avoid propagation of cracks upwards, a low stiffness of SAMI is required, but this involves undesired results.
In fact, when SAMIs are introduced in pavements that are already cracked and have to be asphalted again, membrane deformations may occur around the crack region, thereby sliding being locally dampened. Thus, SAMI gives the road package a low bending stiffness, thereby causing a greater deflection of the pavement and a greater transmission of loads to the underlying layers.
In the light of the above-disclosed prior art, the problem underlying the present invention is to produce a multifunctional thin bituminous layer that is characterized by excellent mechanical performance, including a suitable stiffness to reduce stresses in the structure in which the thin layer is applied and at the same time to ensure a suitable adhesion to the surface to which the thin layer is applied, thereby promoting an increase of load-bearing capacity and the prevention of imbalance formation.
Said problem was solved by providing a multifunctional thin bituminous layer, intended to be used as a layer with high mechanical performance in an infrastructure element, based on a bituminous mixture comprising bitumen, an additive composition, and inorganic inert materials, said additive composition comprising at least one polyolefin plastic material and optionally graphene,
According to the present invention, the expression “multifunctional thin bituminous layer based on a bituminous mixture” means a thin bituminous layer comprising a bituminous mixture which in turn comprises bitumen, an additive composition, inorganic inert materials and, optionally, further components.
Advantageously, the multifunctional thin bituminous layer according to the invention may be effectively used as a layer with high mechanical performance in an infrastructural element, for example for building road pavements or during operations for maintenance thereof.
In particular, it is possible to achieve said high mechanical performance without using nets or grids, since the multifunctional thin bituminous layer of the present invention absolutely lacks it.
According to the present invention, the expression “infrastructural element” in which the above-mentioned multifunctional thin bituminous layer may be used means a road, a parking area, a container yard area, a bridge deck, a viaduct, an airport runway, in particular an airstrip, a taxiway, a tarmac (or apron) or an airport junction, a heliport, a tramway or railway track, for example a mixed-use tramway track, a cycle path, a road intersection, a port quay or a port handling yard.
In particular, the present multifunctional thin bituminous layer is very suitable to be used in roads, namely in the construction or in the maintenance of road pavements.
More in particular, the present multifunctional thin bituminous layer is particularly suitable to be used in the construction or in the maintenance of road pavements and tramway or railway track, specifically on a layer of stabilized mixture of particles of different sizes, of cemented mix, of super-compacted, of cold-recycled, of extrados and intrados of the sub-ballast (i.e., the layer underlying the roadbed or ballast), of the base course, of the binder course or of the wearing course.
Preferably, the multifunctional thin bituminous layer containing graphene according to the invention has a thickness between 0.5 cm and 2 cm, more preferably between 0.8 cm and 1.5 cm.
Advantageously, indeed, especially with reference to applications when said infrastructural element is a road, such as a urban pavement, the multifunctional thin bituminous layer allows maintenance interventions with reduced thickness, high performance and waterproofing ability, so as not to modify the plans of surface runoff and to maintain the paths of rainwater when it is conveyed to a collector drain and, subsequently, to receiving bodies and water lines.
Preferably, said at least one polyolefin plastic material may be selected from polyethylene, polypropylene or any mixture of polyethylene and polypropylene.
Even more preferably, said at least one polyolefin plastic material is a mixture of polyethylene and polypropylene comprising a quantity of polyethylene between 25% and 75% by weight based on the total weight of the mixture.
In an equally preferred manner, said at least one polyolefin plastic material is a mixture of polyethylene and polypropylene comprising a quantity of polypropylene between 25% and 75% by weight based on the total weight of the mixture.
Preferably, said at least one polyolefin plastic material is recycled material.
Alternatively, said at least one polyolefin plastic material used in the additive composition according to the present invention is virgin material or a mixture of recycled material and virgin material.
According to a preferred embodiment of the multifunctional thin bituminous layer of the invention, said additive composition comprises at least one polyolefin plastic material and graphene.
According to the present invention, the term “graphene” means essentially a carbon material with two-dimensional structure of carbon monoatomic layers with hexagonal matrix, wherein each carbon atom is bound to other three carbon atoms by a covalent bond and bound to the atoms of the adjacent layers by Van Der Waals forces.
Preferably, the graphene optionally comprised in the above-mentioned additive composition may be selected from graphene nanoplatelets (GNP), graphene nanotubes, graphene nanoparticles, graphene films, graphene aerogels, graphene sheets, graphene oxide (GO) and functionalized graphene.
More preferably, the graphene optionally comprised in the above-mentioned additive composition is graphene nanoplatelets (GNP).
In particular, the graphene optionally comprised in the above-mentioned additive composition is graphene substantially devoid of any of its functionalized derivative, for example it is substantially devoid of graphene oxide, i.e. graphene partially functionalized with oxygen-containing groups; in any case, the graphene used in the context of the present invention may comprise traces of functionalized derivatives of graphene, i.e. equal to or less than 1%, optionally equal to or less than 0.5%, by weight of its total weight.
More in particular, from a morphological point of view and specifically in the case of graphene nanoplatelets, the graphene optionally comprised in the above-mentioned additive composition has a median diameter of the particles or medium value of the particle size distribution between 0.5 μm and 10 μm, more specifically between 1 μm and 8 μm, calculated by analyzing the particles sizes with laser diffraction according to the methodology ISO 13320-2020.
Specifically, the graphene used in the above-mentioned additive composition may have an apparent density between 2 g/dm3 and 100 g/dm3, more specifically between 10 g/dm3 and 70 g/dm3; at the same time, graphene used in said additive composition may have a superficial area between 10 m2/g and 300 m2/g.
Said superficial area is measured by means of a BET method by absorption of inert gas (nitrogen), in particular according to the procedure ISO 9277:2010.
According to a preferred embodiment, the graphene used in the multifunctional thin bituminous layer according to the present invention is recycled graphene.
Alternatively, the graphene used in the multifunctional thin bituminous layer according to the present invention is virgin graphene or a mixture of recycled graphene and virgin graphene.
Preferably, the above-mentioned additive composition may comprise an additional component selected from polyvinyl butyral (PVB), an acrylate compound, lignin, a sulphur compound, an inorganic salt or any combination thereof.
More preferably, said additional component is polyvinyl butyral (PVB).
Alternatively, said additional component is an acrylate compound, even more preferably, said acrylate compound is selected from polyethylacrylate (PEA), polymethylacrylate (PMA), polybutylacrylate (PBA) or any combination thereof.
According to a further alternative, said additional component is lignin.
Preferably, said additive composition further comprises a plasticizer and/or an adhesion enhancer or a combination thereof.
More preferably, the adhesion enhancer may be selected from cationic, anionic or amphoteric surfactants and/or silane compounds.
Even more preferably, said cationic surfactants may be selected from amine-, amide- and/or imine-based polymer compounds or polyphosphoric-based esters, such as, for example, phosphoric esters.
More preferably, the plasticizer may be selected from compounds derived from extracts of cashew nut shells, a dimeric acid, a compound derived from a dimeric acid, any combination between a dimeric acid and a derivative of dimeric acid, amine compounds, polyphosphoric compounds and/or silane compounds.
Preferably, the graphene included in the above-mentioned additive composition may be contained in a quantity between 0.005% and 1%, more preferably between 0.005% and 0.15%, even more preferably between 0.01% and 0.1%, by weight based on the total weight of the additive composition.
In equally preferred manner, the above-mentioned polyolefin plastic material comprised in the additive composition may be contained in a quantity between 45% and 99.995%, more preferably between 50% and 99.995%, by weight based on the total weight of the additive composition.
Preferably, said additive composition has a melt flow index (MFI), calculated according to the methodology ISO 1133 at a temperature of 190° C. with a load of 2.16 Kg, between 0.5 g/10 min and 5 g/10 min, more preferably between 1 g/10 min and 3 g/10 min and even more preferably between 1.5 g/10 min and 2.5 g/10 min.
In particular, due to the specific melt flow index which characterizes the additive composition, the latter is found to be capable of being effectively dispersed in the additional ingredients necessary for the formulation of the above-mentioned bituminous mixture, including bitumen and inorganic inert materials, resulting in an advantage in terms of convenience of production of the multifunctional thin bituminous layer based on the bituminous mixture itself and of its use, in particular allowing a favorable homogeneity and distribution of the additive composition in the bituminous mixture and allowing the multifunctional thin bituminous layer of the present invention to homogeneously give the infrastructural element in which it is applied improved mechanical characteristics.
Preferably, said additive composition is comprised in the above-mentioned bituminous mixture in a quantity between 0.05% and 15%, preferably between 4% and 8%, by weight based on the total weight of bitumen.
In the above-mentioned bituminous mixture, the inorganic inert materials comprise aggregates, optionally in combination with at least one filler.
In particular, in the above-mentioned bituminous mixture the aggregates comprise fine aggregates, said fine aggregates having a particle size lower than or equal to 2 mm and higher than 0.063 mm, as measured according to UNI EN 12697-2 standard method.
Preferably, in the above-mentioned bituminous mixture the aggregates further comprise coarse aggregates, said coarse aggregates having a particle size lower than or equal to 15 mm and higher than 2 mm, as measured according to UNI EN 12697-2.
According to the present invention, with the term “filler” it is intended an inorganic inert material having a particle size lower than or equal to 0.063 mm, as measured according to UNI EN 12697-2 standard method.
Preferably, in said bituminous mixture said inorganic inert materials comprise coarse aggregates, wherein said coarse aggregates are present in the bituminous mixture in a quantity between 0% and 90%, more preferably between 5% and 30%, by weight based on the total weight of the bituminous mixture, fine aggregates, wherein said fine aggregates are present in the bituminous mixture in a quantity between 5% and 95%, more preferably between 10% and 85%, by weight based on the total weight of the bituminous mixture, and at least one filler, wherein said at least one filler is present in the bituminous mixture in a quantity between 0% and 20%, more preferably between 1% and 15%, even more preferably between 5% and 12%, by weight based on the total weight of the bituminous mixture.
Preferably, in the above-mentioned bituminous mixture said inorganic inert materials have a particle size distribution wherein 100% of the particles have a particle size lower than or equal to 15 mm, as measured according to UNI EN 12697-2 standard method.
Alternatively, in the above-mentioned bituminous mixture said inorganic inert materials have a particle size distribution wherein 100% of the particles have a particle size lower than or equal to 8 mm, as measured according to UNI EN 12697-2 standard method.
More preferably, in the above-mentioned bituminous mixture said inorganic inert materials have a particle size distribution wherein between 10% and 30% of the particles have a particle size between 8 mm and 4 mm and between 70% and 90% of the particles have a particle size lower than or equal to 4 mm, as measured according to UNI EN 12697-2 standard method.
Even more preferably, in the above-mentioned bituminous mixture said inorganic inert materials have a particle size distribution wherein between 10% and 30% of the particles have a particle size between 8 mm and 4 mm, between 10% and 20% of the particles have a particle size between 4 mm and 2 mm and between 50% and 80% of the particles have a particle size lower than or equal to 2 mm, as measured according to UNI EN 12697-2 standard method.
Most preferably, in the above-mentioned bituminous mixture said inorganic inert materials have a particle size distribution wherein between 10% and 30% of the particles have a particle size between 8 mm and 4 mm, between 10% and 20% of the particles have a particle size between 4 mm and 2 mm, between 45% and 65% of the particles have a particle size between 2 mm and 0.063 mm, and between 5% and 12% of the particles have a particle size lower than or equal to 0.25 mm, as measured according to UNI EN 12697-2 standard method, as measured according to UNI EN 12697-2 standard method.
Optionally, the aggregates may be crushed stone materials, natural stone aggregates, recycled aggregates (mixed granular materials recovered from scrap waste or secondary raw materials, namely “SRM”), End Of Waste (“EOW”) aggregates, granulates of bituminous conglomerate, in particular reclaimed asphalt pavements (“RAP”), steel mill scrap, expanded clay, granular and crushed slags, artificial aggregates produces, for example, by high-temperature melting of certain minerals or rocks (for example bauxite or certain clays), sands and/or crushed sands.
The expression “recycled aggregates” means recovered aggregates intended to be reused for making embankments, road subgrades, draining and anti-freezing layers, yards, environmental reclamation, etc.
In particular, mix granular materials recovered from scrap waste or secondary raw materials is classified as an aggregate with sizes of d/D=0/125, obtained from the recovery by sorting and crushing of scraps of mainly tiling materials of construction; said aggregate has CE marking UNI EN 13242.
“End of Waste” identifies “a waste that is not a waste anymore”, i.e. a waste that underwent a recycling operation, in particular a process that concretely allows a waste to play again a useful role as a product.
In particular, the fine aggregates may be crushed sands.
Optionally, the above-mentioned filler is selected from a fraction of fine aggregates, rock powder, in particular calcareous rock, concrete, hydrated lime, hydraulic lime, asphalt powder, fly ash or any combination thereof.
Preferably, the bituminous mixture of the multifunctional thin bituminous layer according to the present invention may comprise an additional additive, wherein said additional additive may be selected from an anti-icing additive, an additive with sound-absorbing properties, a coloring agent (pigment), a photocatalytic agent, a photoluminescent agent or any combination thereof.
Preferably, said additive with sound-absorbing properties is tire powder deriving from “end-of-life” (EOL) tires.
In accordance with the present invention, the term “bitumen” generally means a material comprising a solid dispersing phase at room temperature, having a thermoplastic behavior, said dispersing phase includes high-molecular-weight organic compounds, mainly hydrocarbons with a number of carbon atoms higher than 25. In said dispersing phase can generally be dispersed traces of sulfur, nitrogen, oxygen, and metal such as nickel, iron and vanadium. In particular, bitumen may be bitumen as such (namely without elastomeric additives) or modified bitumen, i.e. bitumen may comprise, besides said dispersing phase, a polymeric modifying additive, for example an elastomeric additive, such as elastomeric rubber, wherein said elastomeric rubber may be styrene-butadiene rubber, styrene-butadiene-styrene rubber, styrene-isoprene-styrene rubber, styrene-ethylene/butadiene-styrene rubber or any mixture thereof.
Preferably, the bitumen comprised in the bituminous mixture of the multifunctional thin bituminous layer according to the present invention may be selected from bitumen as such with penetration according to the method according to the UNI EN Standard 1426-2015 equal to 70/100, equal to 50/70, equal to 35/50 or any combination thereof.
Preferably, the above-mentioned bituminous mixture comprises a bitumen quantity between 3% and 10% by weight based on the total weight of the bituminous mixture, more preferably between 6.5% and 8.5% by weight based on the total weight of the bituminous mixture.
All the percentages indicated in the text of the present application are to be understood as weight/weight percentages, unless otherwise specified.
Advantageously, as it will be appreciated below with reference to the detailed description, the multifunctional thin bituminous layer according to the present invention is particularly suitable for being used as a layer with high mechanical performance in an infrastructural element and has excellent mechanical performance, including a suitable stiffness to reduce stresses in the infrastructural element in which the thin layer is applied and at the same time to ensure a suitable adhesion to the surface to which the thin layer is applied, thereby promoting an increase of load-bearing capacity and the prevention of imbalance formation.
Consistently, a road pavement comprising the multifunctional thin bituminous layer according to the present invention has further a poor tendency to the onset of the rutting phenomenon, and the high mechanical properties that the multifunctional thin bituminous layer gives said road pavement cause a considerable increase of the useful life of the road pavement, as well as of the safety thereof, compared to a traditional road pavement.
In other words, the present multifunctional thin bituminous layer can be efficiently used as a SAMI or as a surface thin layer (BTS).
Advantageously, the multifunctional thin bituminous layer of the invention constitutes an effective barrier against the propagation of cracks coming from the lower layers (bottom-up cracks) or from the upper layers (top-down cracks) of the pavements; moreover, it has great resistance to tangential strains and to permanent vertical deformations caused by static and dynamic loads and redistributes the stresses in the whole pavement, that is, it counteracts the phenomenon of formation of waviness from rutting in the pavement.
Said multifunctional thin bituminous layer may be used as a layer having the following functions: anti-icing, waterproofing the underlying layers, anti-rising or anti-descending of the defects for both the new pavements and the pavements in maintenance, sound-absorbing and as a layer for dynamic dampening the vibrations and of the peaks of strain stresses.
In an advantageous way, the multifunctional thin bituminous layer may be used to hold off the interventions of ordinary and extraordinary maintenance, to repair mistakes occurring when the pavement is laid, to protect the decks and the pavement from the deteriorations of the underlying layers.
In a totally advantageous manner, said multifunctional thin bituminous layer, when used in combination with EOL-based additives, promotes the reduction of noise propagation (sound-absorbing) and has a function of damping vibrations.
Advantageous is also the ability of the multifunctional thin bituminous layer of damping the peaks of strain stresses both in general terms, in any type of pavements, and in particular situations, such as joints between the different structural elements with differential stiffness, such as for example the interface between rigid and bituminous pavements, at abutments of bridges and viaducts, between pavements and railway superstructure, between pavements and urban underground services.
At the same time, advantageously, it may be used, combined with coloring agents, as a multifunctional surface thin layer with specific characteristics of appearance and, depending on the color shade used, of reduction of urban heat islands.
Moreover, the present multifunctional thin bituminous layer is very effective as a waterproofing layer.
The multifunctional thin bituminous layer of the invention has also a low heat susceptibility, and therefore allows longer lasting applications when high operation temperatures are expected.
The present invention further refers to the use of the multifunctional thin bituminous layer as a layer with high mechanical performance in an infrastructural element, preferably in road surface treatments or as an intermediate layer placed inside road pavements.
The present invention also refers to an infrastructural element comprising the above-mentioned multifunctional thin bituminous layer.
Preferably, said infrastructural element is a road, a parking area, a container yard area, a bridge deck, a viaduct, an airport runway, more preferably an airstrip, a taxiway, a tarmac (or apron) or an airport junction, a heliport, a tramway or railway track, for example a mixed-use tramway track, a cycle path, a road intersection, a port quay or a port handling yard.
More in particular, when said infrastructural element is a road or a tramway or railway track, in the infrastructural element comprising the above-mentioned multifunctional thin bituminous layer, the latter is placed on a layer of stabilized mixture of particles of different sizes, of cemented mix, of super-compacted, of cold-recycled, of extrados and intrados of the sub-ballast, of the base course, of the binder course or of the wearing course.
More preferably, said infrastructural element is a road.
Even more preferably, the multifunctional thin bituminous layer is laid on the surface of the road pavement and/or is an intermediate layer placed inside the road pavement.
The present invention relates to a process for producing the multifunctional thin bituminous layer according to the present invention and its application to an infrastructural element, wherein said process comprises the following steps:
Preferably, the present process further comprises the following step:
More preferably, the compacting step may be carried out using rolling means.
In an equally preferred manner, the compacting step may be carried out at a temperature between 110° C. and 200° C.
Preferably, following the compacting step, the multifunctional thin bituminous layer thereby obtained is allowed to cool to room temperature.
Preferably, the step of adding to inorganic inert materials an additive composition and bitumen is carried out at a temperature between 165° C. and 185° C., more preferably between 170° C. and 180° C.
In an equally preferred manner, in the step of applying the bituminous mixture to an infrastructural element the bituminous mixture has a temperature between 130° C. and 200° C., more preferably between 150° C. and 180° C.
Preferably, the process according to the present invention comprises the following preliminary steps:
Preferably, said infrastructural element is a road, a parking area, a container yard area, a bridge deck, a viaduct, an airport runway, more preferably an airstrip, a taxiway, a tarmac (or apron) or an airport junction, a heliport, a tramway or railway track, for example a mixed-use tramway track, a cycle path, a road intersection, a port quay or a port handling yard.
More in particular, when said infrastructural element is a road or a tramway or railway track, in the infrastructural element comprising the above-mentioned multifunctional thin bituminous layer, the latter is placed on a layer of stabilized mixture of particles of different sizes, of cemented mix, of super-compacted, of cold-recycled, of extrados and intrados of the sub-ballast, of the base course, of the binder course or of the wearing course.
Preferably, in the step of applying the bituminous mixture to an infrastructural element, said multifunctional thin bituminous layer has a thickness between 0.5 cm and 2 cm, more preferably between 0.8 cm and 1.5 cm.
Preferably, in the above-mentioned process the inorganic inert materials are previously dried.
The characteristics and the advantages of the present invention will become clearer from some embodiments thereof, which are set forth hereinafter by way of non-limiting illustration.
The present invention relates to a multifunctional thin bituminous layer containing inorganic inert materials, selected on the basis of the particle size, bound by bitumen, and an additive composition comprising at least one polyolefin, preferably a polyolefin or a mixture of recycled polyolefins having a high modulus, as well as—according to a particular embodiment of the invention exemplified below.
According to a particular embodiment of the invention exemplified below the aggregates, in particular coarse aggregates, crushed by means of a grinding process were selected on the basis of the particle size equal to or lower than 8 mm, as measured according to UNI EN 12697-2 standard method, were hot-mixed with semisolid bitumen for road use to which was added a polyolefin plastic material and graphene. The final bituminous mixture was laid on site at a temperature of about 150° C. and the multifunctional thin bituminous layer thereby obtained was compacted with 10 t heavy rollers made of metal.
By way of example, a preferred example of preparation of a bituminous mixture comprising bitumen, an additive composition and inorganic inert materials and the subsequent laying of said bituminous mixture on a surface, thereby obtaining a multifunctional thin bituminous layer containing graphene, is reported below.
The bitumen used in some embodiments according to the present invention and comprised in said bituminous mixture, like bitumen as such with penetration according to the method according to the UNI EN Standard 1426-2015 equal to 50/70, was characterized by different parameters, such as penetration at 25° C., softening point, dynamic viscosity at 60° C. and solubility; after the Rolling Thin Film Oven Test (RTFOT), which allows to reproduce the phenomenon of short-term ageing on bitumen, i.e. the ageing the binder undergoes during the steps of mixing, transportation and laying on site of the bituminous conglomerate, through the parameters residual penetration, increase of the softening point and mass variation. The values of said parameters must comply with the Appendix ZA of UNI EN standard 12591, as can be observed in the table shown in
In the same way, the characteristics of the coarse and the fine aggregates were evaluated, said characteristics complying with the provisions of Appendix ZA of UNI EN Standard 13043 and being shown in the tables of
The characteristics of the filler were evaluated, as well (
In particular, the multifunctional thin bituminous layer of the present invention was applied to a road surface.
Afterward, the resulting mechanical properties of the road surface thereby modified were tested.
First, an additive composition previously obtained as described below, according to the recipe shown in Table 1, was provided:
The additive composition was prepared by grinding separately the mixture of polyethylene and polypropylene, the polyvinyl butyral and the graphene, and then by mixing the ground components in a mixer, together with the adhesion enhancer and the plasticizer, thereby obtaining a homogeneous mixture with particles having an average diameter of about 4 mm.
In particular, in the context of the present invention, the adhesion enhancers may be selected from cationic, anionic or amphoteric surfactants and/or silane compounds. Moreover, the surfactants may be amine-, amide- and/or imine-based polymer compounds or polyphosphoric-based esters, such as, for example, phosphoric esters.
As regards the plasticizers, in the context of the present invention, one may use compounds derived from extracts of cashew nut shells, a dimeric acid, a compound derived from a dimeric acid, any combination between a dimeric acid and a derivative of dimeric acid, amine compounds, polyphosphoric compounds and/or silane compounds.
The virgin graphene that was used had a median diameter of the particles between 1 μm and 8 μm, calculated by analyzing the particles sizes with laser diffraction according to the methodology ISO 13320-2020.
Afterward, using the additive composition thereby obtained, a bituminous mixture was prepared as described below according to the recipe shown in Table 2:
The multifunctional thin bituminous layer of the invention was prepared by means of the following procedure:
In particular, the particle size distribution of the inorganic inert materials used in the present example is showed at
The bituminous mixture thereby obtained was kept at a temperature of about 175° C. inside the mixer and, after transporting it to the application site using suitable transportation means, was subsequently applied on the laying surface.
The laying surface, namely an asphalt layer of a road pavement, was previously cleaned, by removing residues, in order to ensure a proper adhesion between layers.
The road pavement at issue was structured as follows (starting from the deepest layer contacting the ground, up to the wearing course, as shown in
The laying on site of the bituminous mixture was carried out, resulting in a finished layer that was perfectly shaped, devoid of crumbling, cracks and free of defects due to segregation of larger rock elements.
During laying, attention was paid in the formation of longitudinal joints, that were preferably obtained by well-timed juxtaposition of a strip of multifunctional thin bituminous layer to the previous one.
The temperature of the bituminous mixture during laying was maintained not lower than 150° C., in particular equal to about 170° C. Moreover, to ensure the best tamping of the mixture, rolling was carried out immediately after laying at a temperature higher than 145° C., in particular equal to about 150° C.
Compaction of the multifunctional thin bituminous layer was started directly after laying the bituminous mixture by means of compacting rollers and was completed without interruptions.
The multifunctional thin bituminous layer had a thickness of about 1 cm.
After cooling to room temperature, a draining wearing course with a thickness of about 5 cm was laid and then compacting rollers were used.
The compaction thereby occurred allowed to obtain an even thickening in every point and to prevent cracks and slidings in the layer just laid, so as to obtain a surface of the layers that is free of roughness and waviness.
Finally, lab tests were carried out in a test field on a road pavement containing the multifunctional thin bituminous layer of the invention.
The tests that were performed are:
Hereinafter, the results for each previously mentioned test are described.
Falling Weight Deflectometer (FWD) survey was carried out on the extrados of the binder course before and after laying the multifunctional thin bituminous layer. The results show a general improvement and an excellent stiffness of the binder course following laying the multifunctional thin bituminous layer.
In particular, the measurements were taken with a 1700 KPa stimulation and an air temperature between 12.5 and 19.7° C.
The results obtained are shown in the following Table 3.
The calculated values from Falling Weight Deflectometer (FWD) survey were measured by a falling weight deflectometer. Said instrument consists essentially of a known mass capable of generating on the subgrade an impulse-type load by falling on a set of springs mounted on a plate placed on the pavement, thereby making dynamic the induced stimulation. The system provides the use of seven accelerometer transducers (geophones), which are placed in line, capable of measuring the basin of the deflections, which are of the reversible viscous and elastic type. By a process of back analysis, it is possible to obtain the dynamic moduli of the various layers, including the subgrade, assigning different attempt values of the moduli of the layers and verifying which of these values produce the deflections that best approximate the measured ones.
The procedure used is compliant with the experimental methodology ASTM D4694-09 (2020) (Standard Test Method for Deflections with a Falling-Weight-Type Impulse Load Device).
It is important to observe from Table 3 that the high qualities of the multifunctional thin bituminous layer containing graphene not only allow to increase binder course stiffness, but also to better redistribute the stresses in the whole pavement, thereby improving the mechanical response of the materials of the lower layers. The gradient of stresses is maximal where there is contact between the stressed surface and the load; in other words, compared to a pavement with the multifunctional thin bituminous layer of the invention, a conventional road pavement was shown to have lower performance from the standpoint of the absorption of the applied stress, especially in its upper layers.
The multifunctional thin bituminous layer of the invention allows to rapidly spread and extinguish the strains where they are more intense. The lower layers can thereby work with lower stress ratios, showing more elastic responses and higher fatigue resistance.
ii) FWD Survey in Special Configuration at the Transition Between the Pavement with and without the Multifunctional Thin Bituminous Layer
The deflectometry tests performed were carried out with a special configuration of FWD so as to highlight the structural effect of the multifunctional thin bituminous layer laid on the binder in the test field. In particular, the measurements were taken with a 1700 KPa stimulation and an air temperature between 12.5 and 19.7° C.
To measure deflection, the bar holding the geophones, i.e. the sensors capable of receiving the waves propagating in the ground, and the load plate are placed in 14 measurement stations: 7 are placed on the binder layer without the multifunctional thin bituminous layer of the invention and 7 on the multifunctional thin bituminous layer of the invention.
More in particular, the values of FWD survey calculated in special configuration were measured according to the falling weight deflectometer technique as described above.
The basins of deflection with and without multifunctional thin bituminous layer of the invention were compared in 2 measurement stations and the results obtained, as shown in
The deflections reduce by 9.5% (Index D1 in the table shown in
The following moduli values were also found (Table 4):
Significant increases of the material moduli are thus found, in particular equal to about 22% in the case of the binder course before and after the application of the multifunctional thin bituminous layer according to the invention.
iii) Lab Tests on Core Boring Samples Before and After Laying the Multifunctional Thin Bituminous Layer
12 cores of 100 mm diameter and 160 mm length were drilled from both the road pavement before laying a multifunctional thin bituminous layer of the invention, and after laying the latter.
Indirect tensile strength (TS) test, Indirect Tensile Strength Ratio (ITSR) test and dynamic stiffness test were carried out on the cores using NAT equipment.
The results indicate a TS value of the cores without multifunctional thin bituminous layer of the invention of about 0.78 MPa and a value after laying the latter of 1.039 MPa with an increase of 33.2%. Also the ITSR index is increased by about 39%, as shown in the following Table 5:
The dynamic stiffness tests gave the following values (Table 6):
As shown in the previous table, the performance increase in terms of dynamic stiffness is 10.04%.
The permeability tests showed excellent impermeabilization values. 7 tests were carried out in situ, in different positions along the road pavement analyzed, on the binder course with and without the multifunctional thin bituminous layer of the invention, applied on the extrados of the binder course and before the application of the draining wearing course with the following results, shown in Table 7:
The multifunctional thin bituminous layer of the invention may thus be used, due to its high stiffness and ability of distribution of stresses from traffic load, as a layer for being superimposed on existing or newly produced bituminous layers that are to be structurally reinforced (asphalt base course, binder course, wearing course), as a SAMI, but also as a surface thin layer (BTS). The same properties are useful to extinguish more rapidly the actions on the underlying materials (subgrades, low bearing capacity pavement foundations, cement-treated base course) and to maintain the overall behavior of the road package in the elastic field.
The high resistance shown against tangential strains and permanent vertical deformations (ruts) may be applied in areas exposed to strong horizontal motions, such as accelerations and brakings (such as acceleration lanes, deceleration lanes, ramps, stops) or stimulated by static loads (such as traffic lights, bus stops).
Moreover, the excellent fatigue resistance is recommended in bridge decks, in architectural structures in general, in joints, in roads with strong heavy traffic.
The great waterproofing ability allows to seal the surface of decks, viaducts, structures and to rebuild flaws, during the construction, of bituminous layers, which can be too porous (on asphalt base course, binder course, wearing course) or to make an excellent waterproofing layer under the draining wearing course.
Moreover, the multifunctional thin bituminous layer may be used where it is desired to postpone renovation interventions for a few years, by modifying the heights of the road surface by a few centimeters, by sealing cracks, small flaws, disjunctions, crumbling, to coat patches, to fill ruts, to limit backwater, etc. In these cases, laying the multifunctional thin bituminous layer also limits the generation of the rolling noise and absorbs part of the total acoustic energy.
It is important to observe that the high qualities of the multifunctional thin bituminous layer of the invention not only allow to increase the stiffness of the overall layer between multifunctional thin bituminous layer—binder course, but also to better redistribute the stresses in the whole pavement, thereby improving the mechanical response also of the materials of the lower layers. The multifunctional thin bituminous layer of the invention allows to rapidly spread and extinguish the strains where they are more intense. The lower layers can thereby work with lower stress ratios, showing more elastic responses and higher fatigue resistance.
In conclusion, the multifunctional thin bituminous layer of the invention combines excellent mechanical performance, high environmental performance, related to the reduced consumption of raw materials and to the increased average life of the infrastructural element to which it is applied, as well as versatility, allowing to:
Moreover, it is possible to obtain the above-mentioned advantages, causing an increase of the total thickness of the infrastructural element of maximum 5 cm, preferably an increase between 1-3 cm, corresponding to the thickness of the multifunctional thin bituminous layer according to the invention.
| Number | Date | Country | Kind |
|---|---|---|---|
| 102021000027737 | Oct 2021 | IT | national |
| Filing Document | Filing Date | Country | Kind |
|---|---|---|---|
| PCT/EP2022/079903 | 10/26/2022 | WO |
