Multilayer backing materials for composite armor

Abstract
A multilayer backing composite for armor plate systems. One embodiment provides a ceramic layer and a bonded multilayer backing layer bonded to the ceramic layer. The backing layer can be formed from at least two layers each of alternating elastomeric interstitial layers and UHMWPE layers having an areal density in the range of about 125 to 400 g/m2. The areal density of the stack can be in the range of about 4 to 15 lbs/ft2, and specifically about 6.98 lbs/ft2. In some embodiments, at least one of the at least two UHMWPE layers nearer to the ceramic layer of the stack can have a lower areal density than at least one layer further from the ceramic layer. The ceramic layer can be SiC and 0.280″ thick; each rubber layer can be about 0.01″; and each UHMWPE layer can be about 0.15″.
Description
FIELD

The present device and methods generally relate to composite armor systems, and specifically to multilayer backing materials for composite armor systems.


BACKGROUND

Body armor and armor plating are known in the art to protect against ballistic penetration. Armor plating can be made of various materials and compositions such as ceramics and composites. Each material has distinct advantages. For example, ceramic plating can provide an extremely hard surface, yet it can be heavy and brittle. Composites are a light weight alternative, but may not have the anti ballistic qualities of a ceramic plate.


For example, silicon carbide (SiC) can be bonded together using sintering to form a very hard ceramic plate. Also, ultra high molecular weight polyethylenes (UHMWPE) (also known as high-modulus polyethylene (HMPE) or high-performance polyethylene (HPPE)) are a type of thermoplastic polyethylene known in the art for antiballistic characteristics. One such UHMWPE, is sold under the trade name DYNEEMA by Royal DSM of the Netherlands, can be used in body armor or vehicle armor. Extremely long chains of polyethylene in an UHMWPE can effectively transfer load to a polymer backbone by strengthening intermolecular interactions thus providing excellent impact strength.


Attempts in the art have also included multilayered antiballistic structures, which can include a ceramic and composite (UHMWPE) layer (See generally, U.S. Pat. No. 5,340,633 to Van Der Loo et al.). The multilayered armor plate of Van Der Loo provides some weight and flex reduction, while maintaining effective antiballistic characteristics.


Despite these advances in the art, further improvements are possible and desired. For example, it is desirable to further reduce the weight of armor plating systems while maintaining effective antiballistic characteristics.


SUMMARY

Accordingly, there is provided herein embodiments of a multilayer backing composite for armor plate systems. One embodiment provides a bonded multilayer armor stack having a ceramic layer and a bonded multilayer backing layer bonded to the ceramic layer. The backing layer can be formed from at least two layers each of alternating elastomeric interstitial layers and UHMWPE layers having an areal density in the range of about 125 to 400 g/m2. In one embodiment 4 layers of alternating rubber interstitial layers and UHMWPE layers is provided. The areal density of the stack can be in the range of about 4 to 15 lbs/ft2, and specifically about 6.98 lbs/ft2.


In some embodiments, at least one of the at least two UHMWPE layers nearer to the ceramic layer of the stack can have a lower areal density than at least one layer further from the ceramic layer. Also, the ceramic layer can be SiC and 0.280″ thick; each rubber layer can be about 0.01″; and each UHMWPE layer can be about 0.15″. Also, the elastomeric interstitial layer can be a silica filled nitrile butadiene rubber (SFNBR). The backing layer can be bonded to the ceramic layer by an epoxy paste adhesive.


Methods to make the embodiments can include the steps of providing a UHMWPE panel on a surface, such as a glass topped table; applying a MEK activated side of rubber panel on one side of the UHMWPE panel; removing a poly backing from a second exposed side of the rubber layer; MEK activating the second exposed side of the rubber layer; applying a second UHMWPE panel to the MEK activated second exposed side; curing the bonded panels to form a multilayer backing panel; bonding the backing panel to the ceramic layer.


Methods of curing the multilayer backing panel can include the steps of: pressurizing the backing panel in an autoclave from about the range of 60 to 200 PSI; ramping the backing panel temperature at about 1 to 10° F./minute to about the range of 200 to 270° F.; holding the backing panel temperature for about 30 to 300 minutes; releasing pressure; and cooling the backing panel to the range of about ambient to 200° F.


In some embodiments the process can also include the step of forming the backing layer using the step of vacuum bagging the backing layer on a caul plate. The step of bonding the backing layer to the ceramic layer to form the armor stack can include the steps of wiping a first side of the ceramic layer with a solvent; applying an epoxy paste adhesive to a first side of a backing layer; smoothing the adhesive with a flat serrated edged rubber blade; applying the first side of the ceramic layer with the first side of the backing layer; and curing the formed armor stack for at least about 6 hours at ambient temperatures. Additional steps can include the step of forming the armor stack into a predetermined shape by applying force to the armor stack against a forming tool during the steps of pressurizing and temperature ramping of the backing panel. In specific embodiments the step of pressurizing the backing panel in an autoclave can be about 100 PSI; the step of ramping the backing panel temperature can be at about 5° F./minute to about 240° F.); and the step of holding the backing panel temperature can be for about 120 minutes.


Other features will become more apparent to persons having ordinary skill in the art to which pertains from the following description and claims.





BRIEF DESCRIPTION OF THE FIGURES

The foregoing features, as well as other features, will become apparent with reference to the description and Figures below, in which like numerals represent elements, and in which:



FIG. 1 is a cross-section of one embodiment of a present multilayer armor composite;



FIG. 2 is a is a cross-section of prior art armor composite;



FIG. 3 illustrates a ballistic test range schematic;



FIG. 4 illustrates a comparison high speed video image of backing samples of a multi-layer composite of the present embodiments (4A) and a single layer prior art backing (4B) approximately 200 μsec after ballistic impact;



FIG. 5 illustrates a comparison of cross sections of backing samples of a multi-layer composite of the present embodiments (5A) and a single layer prior art backing (5B) after ballistic impact; and



FIG. 6 illustrates a cross section of a backing sample of a multi-layer composite of the present embodiments after multiple ballistic impacts.





DETAILED DESCRIPTION

The present device and methods generally relate to composite armor systems, and specifically to multilayer backing materials for composite armor systems. For example, armor plating can include large scale body armor, such as for military troops. Examples include vest and plate combinations. Initial vests were designed for fragmentation threats (artillery and/or grenade fragments) pistol rounds (up to 9 mm) and the plate (sometimes referred to as a small arms protective insert (SAPI), providing protection against common military rifle ball round threats. As the threat spectrum increased, so did the need to increase the antiballistic effect of body armor. For example, an enhanced small arms protective inserts (ESAPI) provided further protection against small arms armor piercing threats. The increased protection came at the expense of increased weight, by about 40 percent. The increased weight reduced mobility and range of the person or vehicle using the ESAPI standard.


The present methods and embodiments can provide an armor plating stack that has a significantly lighter weight from use of lower density elastomeric interstitial layers, while providing the protection of an ESAPI system. When used on vehicles such as tanks or helicopters, advantages of the present systems and methods can include longer vehicle range and reduced fuel consumption. When used as body armor, fatigue can be reduced and also result in a longer range for the user (person).


Turning now to the Figures. FIG. 2 illustrates a prior art schematic of an armor stack generally indicated at 100. As shown in FIG. 2, the antiballistic structure can have a first ceramic layer 112, and a second layer of a high tensile strength composite material 116. An intermediate layer 114 can be provided, such as one having a flexural modulus which is higher than the flexural modulus of the composite material layer 116 and can be lower than the flexural modulus of the ceramic material layer 112. (See generally, Van Der Loo).


In mechanics, the flexural modulus can be the ratio of stress to strain in flexural deformation. In other words, the tendency of a material to bend. The modulus can be established from a slope of a stress-strain curve produced. It is an intensive property using units of force per area. In one formula, flexural modulus can be:

E(bend)=L3F/4wh3d.


The present embodiments and methods provide effective antiballistic characteristics with less weight than known in the art. As shown in FIG. 1, a cross section for an armor stack generally indicated at 10 shows multilayer backing materials for a composite armor system. A first ceramic layer 12 compositions can be made from a silicon carbide (SiC). Ceramic layer compositions can also include boron carbide (B4C), titanium diboride (TiB2), aluminium oxide (Al2O3), other carbides, borides, oxides, and combinations thereof. The ceramic layer can be formed from hot pressing, sintering, and the like.


As shown, the backing layers of ceramic layer 12 can be composite layers such as an ultra high molecular weight polyethylene (UHMWPE) 16. Composite 16 can include ultra high molecular weight polyalkene filaments (such as polyethylene or polypropylene) having the tensile modulus of at least 40 GPa and the tensile strength of at least 1 GPa in a matrix which at least partially surrounds the polyalkene filaments. For example, composite fibers based on UHMWPE available under the brand names DYNEEMA® HB2 (having an areal density of about 250-270 g/m2 and a ballistic rating having a V50 value of greater than or equal to about 765 m/sec) and DYNEEMA® HB50 (having an areal density of about 220-240 g/m2 and a ballistic rating having a V50 value of greater than or equal to about 780 m/sec) can be used. It is noted that suitable areal densities would include those found in any flexible and/or semi-rigid backing system ranging from about 125 to about 400 g/m2


It is also noted that composite layer types can include a variety of high tensile strength textile composites and combinations, preferably of a unidirectional nature. For example, fiberglass, such as E-glass, S-glass, and the like, and various combinations thereof can be used. In embodiments using E-glass, alumino-borosilicate glass with less than 1 wt % alkali oxides can be used. S-glass embodiments can be an alumina silicate glass without CaO but with high MgO content.


As shown, composite layer 16 can be stacked alternating with an interstitial layer 14. Interstitial layers 14, as shown, can be an elastomeric material, such as a rubber including a nitrile butadiene rubber (NBR) or an ethylene propylene diene monomer (M-class) rubber (EPDM). In one embodiment the rubber can be a silica filled nitrile butadiene rubber (SFNBR). In some embodiments, the composite layer (e.g., SiC tile) can be coated in various elastomeric configurations (i.e., either or both sides and/or various tile edges). Preferably, the tile is rubber coated on one side and preferably not on the strike face, and all edges with a thickness in the range of about 0.010 to 0.020 inches (10 to 20 mils). This configuration actually improves performance against ballistic impact. It is noted that performance degrades in embodiments where the tile is encapsulated in rubber or where the strike face tile side is rubber coated.


An advantageous rubber composition and methods for its manufacture, that can be used in fabricating the present multilayer backing material and the composite armor is described in Application of Gajiwala et al, U.S. application Ser. No. 12/879,827, filed on even date herewith, the complete disclosure of which is incorporated by reference. The described rubber compositions with nanoclay filler instead of silica, and cured with a sulfur-containing curative can be used in making our multilayer backing material and the armor.


As such the present armor stack 10, has less weight than the prior art armor stack 100. For example, as described, the areal density of the stack can be in the range of about 4 to about 15 lbs/ft2, and more particularly in a range of about 4 to about 8 lbs/ft2. Surprisingly, the armor stack 10, despite its lighter weight and less use of UHMWPE, exhibits comparable antiballistic characteristics than armor stack 100.


These comparable findings can be established using ballistic testing of subscale test articles manufactured using 4″×4″ silicon carbide (SiC) tiles mounted adhesively to a 12″×12″ backing plate. The SiC tile thickness can be fixed at 0.280″ for the test series and the backing material and construction varied to determine the effects of the backing system on the overall performance of the stack.


A number of exemplary backing material constructions can be produced for these test series such as those shown in Table 1. The number in parentheses indicate the number of layers used for the example. It is noted that embodiments can include at least two layers each of alternating elastomeric interstitial layers and UHMWPE layers, preferably 3 to 5 layers each, and most preferably 3 to 4 layers each.









TABLE 1







Material configuration and corresponding areal density











Calculated




Areal



Material Stack
Density (lbs/ft2)







0.280″ SiC/0.01″ Rubber/0.50″ UHMWPE
7.13



0.280″ SiC/0.02″ Rubber/0.50″ UHMWPE
7.18



0.280″ SiC/0.01″ Rubber (3)/0.15″ UHMWPE (3)
6.98



0.280″ SiC/0.02″ Rubber (3)/0.15″ UHMWPE (3)
7.16



0.280″ SiC/0.01″ Rubber (4)/0.11″ UHMWPE (4)
6.99



0.280″ SiC/0.02″ Rubber (4)/0.11″ UHMWPE (4)
7.20










For exemplary tests, sample UHMWPE panels 16 were obtained in a variety of thicknesses (0.11″, 0.15″ and 0.50″). It is noted that some embodiments of the products herein can vary in thickness and/or areal density among the UHMWPE layers within stack 10. Some testing suggests that performance can be maintained by decreasing areal density the closer the layer is to the strike plate. In this instance, and for illustrative purposes only, the UHMWPE panel was made from DYNEMA HB-2® in each layer. These panels were prepared by wiping them with isopropyl alcohol to remove any residual oils and contaminants that may have remained on the panels during manufacture or accumulated during shipping. Interstitial layers 14 (here shown as rubber sheets) were calendared from base material to 0.010″ thickness, laminated on poly backing and rolled. To use a 0.020″ thick rubber, two sheets of 0.010″ thick rubber were laminated together using a solvent such as an MEK (methyl ethyl ketone) spray to activate the rubber surfaces. In some instances the rubber/elastomer was used with silica filler and cured, in other instances the rubber was used with nanoclay filler and cured with sulfur-curative. A slight performance advantage can be found with nanoclay filled rubber. In all cases, the elastomer was laid up in the uncured (“green”) form and cured in an autoclave.


Armor stack fabrication occurred by a layered build up of the materials in sequence as shown in FIG. 1 and FIG. 2. It is noted that several possible embodiments can be realized using the present methods and systems. The following is for illustrative purposes only.


All ceramic layer 12 (SiC) tiles can have a rubber interstitial layer bonded to one ceramic tile face. This can be accomplished by cutting a rubber sheet to a 4.5″ square. This sheet can then be activated by spraying a solvent, such as MEK, on one surface. This surface can then be pressed to the SiC tile such that the SiC tile is centered on the rubber sheet. The remaining rubber extending beyond the SiC tile edge can then be folded up over the edges of the SiC tile. The remaining corners can next be pressed flat against the edges of the SiC tile. Bonding can be completed by vacuum bagging the tile and subjecting the vacuum bagged assembly to a pressure cure in an autoclave. An exemplary pressure cure can be as follows:

    • Pressurize the autoclave from about 60 PSI to about 200 PSI and preferably about 100 PSI.
    • Next, ramp temperature at about 5° F./minute to between about 200° F. to 320° F., and preferably to about 240° F.,
    • Next, hold temperature for between about 30 minutes to about 300 minutes, and preferably about 120 minutes,
    • Next, furnace cool to room temperature and release pressure below about 180° F. to ambient temperature.


      It is noted that ‘ambient’ temperature as used herein refers to ‘room’ temperature typically in the range of about 50 to 100° F., and preferably about 70° F.


Following an autoclave cure, the ceramic tiles (SiC) can be removed from the vacuum bagging and prepared for bonding to the ultra high molecular weight polyolefin (UHMWPO) backing, e.g., UHMWPE backing. For testing purposes prior art backing samples (such as shown in FIG. 2) can be produced to compare with the present backing embodiments (FIG. 1). The prior art backing samples can be produced by laying a 0.5″ thick UHMWPE panel on a surface, such as a glass topped table, and marking the area of the SiC tile in the center of the UHMWPE panel. A small amount of adhesive was placed in the approximate center of the UHMWPE panel then screed using, for example a flat serrated edged blade (such as a rubber or plastic blade), to ensure a uniform coating of adhesive over an area slightly larger than the marked tile area.


Coating the tile in rubber can be performed in the same manner as the rubber layer layup for the backing. As indicated above, it is preferred to cover only the rear and sides of the tile (i.e., not the strike face). For the present sample embodiments, the rubber-coated SiC tile was then placed in the center of the adhesive area, rubber side down and pressed firmly into place. The panel assemblies were then vacuum bagged and allowed to cure in ambient conditions overnight. Following the overnight cure, the panels were debagged, any flashing was trimmed, and the panels labeled for testing.


The layered backing samples illustrating the present embodiments can be produced by laying a 0.11″ or 0.15″ UHMWPE panel on a surface, such as a glass topped table. A sheet of either 0.01″ or 0.02″ rubber can be MEK activated on one side then placed on the top surface of the UHMWPE panel. A poly backing, if present, can then be removed from the rubber sheet. This exposed surface can then be MEK activated and a second UHMWPE panel of the same or substantially the same thickness as the first can be placed on the rubber surface, such that the outer surfaces of the UHMWPE panels are aligned. It is noted that variations of UHMWPE thickness are possible and still be within the scope of the present embodiments. This layer process can be repeated until the panels have either three layers of 0.15″ UHMWPE or four layers of 0.11″ UHMWPE separated by rubber layers. These panels can then be vacuum bagged on a caul plate and autoclave cured.


The autoclave cure can occur by a process as follows. First, the autoclave can be pressurized to the range of about 60 to about 200 PSI and preferably about 100 PSI. Next, the temperature can be ramped at about 1 to about 10° F./minute and preferably to about 5° F./minute to about the range of about 200 to about 270° F. and preferably about 240° F. Next, temperature can be held for about 30 to about 300 minutes and preferably about 120 minutes. Next, the furnace can be cooled to ambient temperature and the pressure released below in the range of ambient to about 200° F. and preferable about 180° F.


Following the autoclave cure, the panels can be removed from the vacuum bag. The cured panels can next be laid on a surface, such as a glass topped table, where the top surface can be wiped with isopropyl alcohol to remove any contaminants. The UHMWPE panel can then be marked in the center of the panel with an outline of the area of the SiC tile. A portion of an epoxy paste adhesive (such as one sold under the trade name HYSOL EA9392 by Henkel Corporation of Bay Point, Calif.) can be placed in the approximate center of the UHMWPE panel then spread using a flat serrated edged rubber blade to ensure a uniform coating of adhesive over an area slightly larger than the marked tile area. The rubber-coated SiC tile can then be placed in the center of the adhesive area, rubber side down and pressed firmly into place. The panel assemblies can then be vacuum bagged and allowed to cure in ambient conditions for at least 6 hours and preferably at least 12 hours. Following the overnight cure, the panels can be debagged and any flashing trimmed.


Optionally, stack 10 curing can be combined with hard tooling to add or subtract a curvature or other desired shape to the plate and/or stack to provide a desired part geometry for custom applications. These various shapes can be formed during the autoclave curing described herein. For example, stack 10 can be formed to various shapes by laying up flat or slightly curved UHMWPE plates and vacuum bagging the formed plates to a ‘hard tool’ (forming tool) and using the heat and pressure of the autoclave to shape the stack against the forming tool.


As described below, the present embodiments exhibited comparable, and in some cases improved, antiballistic characteristics over the heavier prior art samples. Ballistic testing was done in accordance with the U.S. Department of Defense Ballistic Test Method MIL-STD 662F. A schematic of the test range is shown in FIG. 3 and was adapted to the National Institute of Justice Ballistic Resistance of Body Armor Standard 0101.06.


Velocity calibration and yaw verification was done prior to testing by firing several projectiles through break screens and infrared screens to verify accuracy of the infrared screens. Yaw cards were used at the impact point during the velocity calibration to verify that the projectiles had a yaw of less than three degrees at the impact point. Counter chronographs (such as one sold under the tradename HP model no. 53131A by Hewlett-Packard) were used in this test series. Additionally, high speed video operating at 10,000 frames per second was taken of each impact event to record the back face (i.e., the exposed back layer of the UHMWPE backing) behavior of the armor samples during the impact event. The projective (‘threat round’) used for ballistic testing of these armor samples was a 7.62×51 mm, 160 grain, M993 armor piercing (AP) surrogate round (such as one supplied by New Lenox Ordnance of Dwight, Ill.) to simulate an aggressive 7.62 mm caliber armor piercing round. For example, the AP round M993 used was a WC-cored steel jacketed 128 grain 7.62 mm bullet that has been type certified for use in the M60 and M240 Medium Machine Guns and in the M24 Sniper Weapon System. The M993 has a nominal muzzle velocity of 2985±32 ft/sec and a nominal penetrative capability of 0.275″ of Rolled Homogenous Armor (RHA, MIL-A-46100) at 547 yards. Gun powder, such as one sold under the trade name VIHTAVUORI N140, was used in all tests. All projectiles were loaded into 7.62×63 mm cartridges just prior to testing and propellant loads were varied to maintain test velocities at 3200±50 fps. All test fires were done at a range of 25 feet and were completed using a universal receiver mounted with a 0.308″ (7.62 mm) caliber barrel and mounted on a custom Chesapeake Testing mount. The tested armor stacks were mounted on a picture frame mount with two degrees of freedom to allow movement of sample to correspond to the fixed aim point of the test barrel configuration.


Test results of 151 tests using the methods described above are shown in Table 2. In Table 2, the first two lines of data show two variations of prior art armor stacks with backing. Lines 3 through 6 show variations of a multi-layered backing according to the present embodiments showing 3 and 4 layers alternating rubber and UHMWPE.









TABLE 2







Summary of ballistic testing data











No. of




Material Stack
Tests
No. Pass
No. Fail





0.280″ SiC/0.01″ Rubber/0.50″ UHMWPE
19
14
 5


0.280″ SiC/0.02″ Rubber/0.50″ UHMWPE
24
12
12


0.280″ SiC/0.01″ Rubber (3)/
18
14
 4


0.15″ UHMWPE (3)





0.280″ SiC/0.02″ Rubber (3)/
27
13
14


0.15″ UHMWPE (3)





0.280″ SiC/0.01″ Rubber (4)/
31
17
14


0.11″ UHMWPE (4)





0.280″ SiC/0.02″ Rubber (4)/
12
 2
10


0.11″ UHMWPE (4)









From the data shown above, it is apparent that the 0.280″ SiC/0.01″ Rubber (3)/0.15″ UHMWPE (3) configuration shows equivalent ballistic performance to the 0.28070.01″ Rubber/0.50″ UHMWPE at a 2.1% decrease in areal density (see Table 1). Additionally, both 0.280″ SiC/0.01″ Rubber (3)/0.15″ UHMWPE (3) and 0.280″ SiC/0.01″ Rubber (4)/0.11″ UHMWPE (4) show equivalent or superior ballistic performance to the 0.280″ SiC/0.02″ Rubber/0.50″ UHMWPE configuration while providing a 2.8% and 2.6% reduction in areal density, respectively. While the reduction in areal density may not appear significant, current body armor design practice would suggest that any disruption of the monolithic UHMWPE backing would result in reduced ballistic performance.


In addition to the baseline ballistic performance, the backface deformation of the ballistic stack showed a marked difference in behavior from the multi-layered backing according to the present embodiments (4a) versus the prior art backing (4b). FIG. 4 shows high speed video images approximately 200 μsec after impact. Note the broader base of the deformation in the layered backing (4a) versus the prior art monolithic backing (4b). This suggests a more efficient transfer of energy to backing construct.


Similarly, FIG. 5 illustrates a comparison of cross sections of backing samples of a multi-layer composite of the present embodiments (5A) and a single layer prior art backing (5B) after comparable ballistic impacts. As shown, even though the layered stack is lighter in weight, there less fiber damage to the UHMWPE backing, especially to layers further from the strike plate. This is also shown in FIG. 6, which also illustrates a cross section of a backing sample of a multi-layer composite of the present embodiments after multiple ballistic impacts (See also the embedded ballistic object on the impact to the left). FIG. 6 shows not only no breach to the baking layer, but that the UHMWPE backing layer furthest from the strike plate had no fiber damage. FIG. 6 also shows decoupling of some of the layers after impact. This decoupling absorbs some of the ballistic impact so that impact is reduced with each successive layer.


Specifically, the images suggest that the layered backing of the present embodiments involves a broader area of the backing material in the impact event leading to an increase in efficiency of energy dissipation, which results in an increase in ballistic efficiency. Scaling this technology to full scale ballistic plates would result in reduced back-face deformation after impact which would decrease blunt force trauma inflicted on a soldier. The additional benefit of reduced armor stack weight, as discussed above, would provide an increase in user range. In other words, with a lighter overall weight, a user's fatigue would be reduced, thus allowing them to travel further or stand longer that would normally be found with use of a prior art ESAPI type antiballistic configuration.


While the embodiments and methods have been described in conjunction with specific embodiments, it is evident that many alternatives, modifications, and variations will be apparent to those skilled in the art in light of the foregoing description.

Claims
  • 1. A bonded multilayer armor stack, comprising: a ceramic layer; anda bonded multilayer backing layer bonded to the ceramic layer, wherein the backing layer is formed from at least two layers each comprised of alternating elastomeric interstitial layers and UHMWPE layers having an areal density in the range of about 125 to 400 g/m2.
  • 2. The armor stack of claim 1, wherein the backing layer is formed from four layers in which each of the four layers is comprised of alternating rubber interstitial layers and UHMWPE layers.
  • 3. The armor stack of claim 1, wherein the areal density of the stack is in the range of about 4 to 15 lbs/ft2.
  • 4. The armor stack of claim 3, wherein the areal density is about 6.98 lbs/ft2.
  • 5. The armor stack of claim 1, wherein at least one of the at least two UHMWPE layers nearer to the ceramic layer of the stack has a lower areal density than at least one layer further from the ceramic layer.
  • 6. The armor stack of claim 5, wherein the elastomeric interstitial layer is a silica filled nitrile butadiene rubber (SFNBR).
  • 7. The armor stack of claim 1, wherein the ceramic layer is SiC and 0.280″ thick; each rubber layer is about 0.01″; and each UHMWPE layer is about 0.15″.
  • 8. The armor stack of claim 1, wherein the elastomeric interstitial layer is a silica filled nitrile butadiene rubber (SFNBR).
  • 9. The armor stack of claim 1, wherein the backing layer is bonded to the ceramic layer by an epoxy paste adhesive.
  • 10. Armor comprising a plurality of bonded multilayer stacks according to claim 1.
  • 11. A bonded multilayer armor stack having an exposed strike face, said armor stack comprising: a ceramic layer having a rear face and a front face, said exposed strike face formed from at least a part of said front face; anda bonded multilayer backing layer bonded to the rear face of said ceramic layer, said backing layer comprised of least two further layers, said two further layers each comprising an alternating elastomeric interstitial layer and an ultra high molecular weight polyethylene layer, and having an areal density in the range of about 125 to 400 g/m2.
  • 12. The armor stack according to claim 11, wherein at least one of the at least two ultra high molecular weight layers nearer to the ceramic layer in the stack has a lower areal density than the at least one ultra high molecular weight polyethylene layer that further from the ceramic layer.
  • 13. The armor stack of claim 12, wherein the elastomeric interstitial layer is a silica filled nitrile butadiene rubber (SFNBR).
  • 14. The armor stack according to claim 11, wherein the elastomeric interstitial layer is a silica filled nitrile butadiene rubber (SFNBR).
  • 15. The armor stack according to claim 11, wherein in the bonded multilayer armor stack an adhesive bonds the rear face of said ceramic layer to said backing layer.
  • 16. Armor comprising a plurality of bonded multilayer stacks according to claim 11.
  • 17. A bonded multilayer armor stack having an exposed strike face, said armor stack comprising: a ceramic layer having a rear face, a front face, and at least one peripheral edge, said exposed strike face formed from at least a part of said front face;an elastomeric coating layer having a first face layer and a second face layer, wherein said rear face and, optionally, at least one said peripheral edge, of said ceramic layer is coated with one of the two faces of said elastomeric coating layer; anda bonded multilayer backing layer bonded to the other of the two faces of said elastomeric coating layer, said backing layer comprised of least two further layers, said two further layers each comprising, in alternating sub-layers, an elastomeric interstitial layer and an ultra high molecular weight polyethylene layer, and having an areal density in the range of about 125 to 400 g/m2.
  • 18. The armor stack according to claim 17, wherein in said multilayer backing layer said interstitial elastomeric layers comprise a rubber layer.
  • 19. The armor stack of claim 17, wherein at least one of the at least two ultra high molecular weight layers nearer to the ceramic layer in the stack has a lower areal density than the at least one ultra high molecular weight polyethylene layer that further from the ceramic layer.
  • 20. The armor stack of claim 19, wherein the elastomeric interstitial layer is a silica filled nitrile butadiene rubber (SFNBR).
US Referenced Citations (125)
Number Name Date Kind
373397 Guest Nov 1887 A
2870108 Nickerson Jan 1959 A
2964457 Kraus Dec 1960 A
3307530 Stack Mar 1967 A
3347047 Hartz et al. Oct 1967 A
3421970 Daly et al. Jan 1969 A
3562304 Tucker Feb 1971 A
3637576 Sutherland Jan 1972 A
3686868 Chase et al. Aug 1972 A
3723481 Bobear Mar 1973 A
3908061 Byme et al. Sep 1975 A
3928282 Lohr, Jr. et al. Dec 1975 A
3973397 Chase et al. Aug 1976 A
4066590 Eldred et al. Jan 1978 A
4072796 Reinhardt et al. Feb 1978 A
4297145 Wolff et al. Oct 1981 A
4369297 Bilow Jan 1983 A
4373048 Schubert et al. Feb 1983 A
4433020 Narukawa et al. Feb 1984 A
4492779 Junior et al. Jan 1985 A
4504532 Herring Mar 1985 A
4507165 Herring Mar 1985 A
4514541 Frances Apr 1985 A
4524169 Wolff et al. Jun 1985 A
4550130 Kishida et al. Oct 1985 A
4600732 Junior et al. Jul 1986 A
4640861 Binnersley et al. Feb 1987 A
4649701 Wendel Mar 1987 A
4663065 Herring May 1987 A
4666763 King et al. May 1987 A
4711086 Offe et al. Dec 1987 A
4785047 Jensen Nov 1988 A
4878431 Herring Nov 1989 A
4953476 Sayles Sep 1990 A
4956397 Rogowski et al. Sep 1990 A
4980233 McCullough, Jr. et al. Dec 1990 A
4997716 McCullough, Jr. et al. Mar 1991 A
4999238 Gawin Mar 1991 A
5007343 Marks Apr 1991 A
5019450 Cogswell et al. May 1991 A
5024818 Tibbetts et al. Jun 1991 A
5024860 Chang Jun 1991 A
5038561 Chase Aug 1991 A
5039572 Bobsein et al. Aug 1991 A
5122420 Baron et al. Jun 1992 A
5212944 Martin et al. May 1993 A
5213889 Cogswell et al. May 1993 A
5216057 Pratt et al. Jun 1993 A
5225457 Borowczak et al. Jul 1993 A
5276093 Kitagawa et al. Jan 1994 A
5340633 van der Loo et al. Aug 1994 A
5344689 Ide et al. Sep 1994 A
5352312 Guillot Oct 1994 A
5352507 Bresson et al. Oct 1994 A
5364905 Bauer et al. Nov 1994 A
5374415 Alig et al. Dec 1994 A
5391627 Araki et al. Feb 1995 A
5399599 Guillot Mar 1995 A
5409775 Harada et al. Apr 1995 A
5437920 Bauer et al. Aug 1995 A
5498649 Guillot Mar 1996 A
5547525 Bennett et al. Aug 1996 A
5565535 Costin et al. Oct 1996 A
5569716 Okamoto et al. Oct 1996 A
5594060 Alig et al. Jan 1997 A
5621045 Patel et al. Apr 1997 A
5629371 Kitagawa et al. May 1997 A
5661198 Inatani et al. Aug 1997 A
5721301 Takigawa Feb 1998 A
5762746 Hartwell et al. Jun 1998 A
5767221 Poulter et al. Jun 1998 A
5780538 Cohen et al. Jul 1998 A
5821284 Graham et al. Oct 1998 A
5830384 Stephens et al. Nov 1998 A
5840227 Bourdoncle et al. Nov 1998 A
5891561 Kinoshita et al. Apr 1999 A
5989459 Nguyen et al. Nov 1999 A
6287639 Schmidt et al. Sep 2001 B1
6489385 Fujii et al. Dec 2002 B1
6554936 Metcalf et al. Apr 2003 B1
6606852 Harvey et al. Aug 2003 B1
6691505 Harvey et al. Feb 2004 B2
6812276 Yeager Nov 2004 B2
7013998 Ray et al. Mar 2006 B2
7078453 Feeney et al. Jul 2006 B1
7250477 Guo et al. Jul 2007 B2
7267882 Breslin et al. Sep 2007 B2
7358314 Gajiwala et al. Apr 2008 B2
7767746 Gajiwala Aug 2010 B2
8026307 Miller Sep 2011 B2
8043696 Chen et al. Oct 2011 B2
8065947 Park et al. Nov 2011 B2
20020018847 Guillot Feb 2002 A1
20020142147 Sogabe et al. Oct 2002 A1
20020189233 Harvey et al. Dec 2002 A1
20040095658 Buretea et al. May 2004 A1
20040132894 Dias et al. Jul 2004 A1
20040157979 Harvey et al. Aug 2004 A1
20040237713 Breslin et al. Dec 2004 A1
20040241479 Domine et al. Dec 2004 A1
20050032937 Tsou et al. Feb 2005 A1
20050059754 Lunt et al. Mar 2005 A1
20050065264 Pazur Mar 2005 A1
20050101737 Pazur et al. May 2005 A1
20050142349 Irwin et al. Jun 2005 A1
20050202258 Swales et al. Sep 2005 A1
20050211930 DeMeo et al. Sep 2005 A1
20050266757 Roekens et al. Dec 2005 A1
20060074168 Nelson et al. Apr 2006 A1
20070049699 Nasreddine et al. Mar 2007 A1
20070254988 Gajiwala et al. Nov 2007 A1
20070261385 Gajiwala Nov 2007 A1
20080319119 Waddell et al. Dec 2008 A1
20090115108 Rodgers et al. May 2009 A1
20100036025 Rodgers et al. Feb 2010 A1
20100203304 Carbajal Aug 2010 A1
20100205929 Gajiwala Aug 2010 A1
20110192274 Fingerhut Aug 2011 A1
20110256341 Geva et al. Oct 2011 A1
20110296979 Howland Dec 2011 A1
20120065294 Gajiwala et al. Mar 2012 A1
20120077005 Chen et al. Mar 2012 A1
20120088072 Pawloski et al. Apr 2012 A1
20120160086 Carbajal Jun 2012 A1
20120164370 Carbajal Jun 2012 A1
Foreign Referenced Citations (16)
Number Date Country
0 116 453 Aug 1984 EP
0 172 957 Mar 1986 EP
0 172 957 Mar 1986 EP
0 446 573 Sep 1991 EP
0 446 573 Sep 1991 EP
1 475 405 Nov 2004 EP
1 512 718 Mar 2005 EP
2 554114 May 1985 FR
1301296 Dec 1972 GB
08-127674 May 1996 JP
0104198 Jan 2001 WO
0120966 Mar 2001 WO
0146279 Jun 2001 WO
02079307 Oct 2002 WO
2006066395 Jun 2006 WO
2007053640 May 2007 WO
Non-Patent Literature Citations (27)
Entry
“Basalt fiber”, Wikipedia, http://en.www.wikipedia.org/wiki/Basalt—fiber, Nov. 25, 2005, 1 page.
“Buss Kneader MKS Modular Series” Flexible systems featuring high process reliability for cost-effective compounding solutions, brochure, Buss (America), Inc. Bloomingdale, IL.
Buss Kneader Operating Principle, http:/www.busscompounding.com/Seiten/English/Buss%20Kneader/kneader1.htm, Dec. 31, 1999.
Chang, Karl K., Aramid Fibers, ASM International Handbook, vol. 21, p. 41.
Darmstadt, 1997, Elsevier Science Ltd., Effects of Surface Treatment on the Bulk Chemistry and Structure of Vapor Grown Carbon Fibers, p. 1581 (5 pages).
DuPont Dow Elastomers, “Novel IP Product Specification Information,” 1997, pp. 2-3.
DuPont Dow Elastomers, Introducing Nordel IP, Setting a New Standard in Predictability, “Delivering a New Standard of Performance,” (1997), pp. 1-6.
DuPont Dow Elastomers, Nordel IP NDR 4640, “Nordel IP Grade Comparison,” (1997), pp. 1-7.
DuPont Dow Elastomers, Nordel IP NDR-4520, “Nordel IP Grade Comparison,” (1997), pp. 1-5.
Hill, “Usage of Vapor Grown Carbon Fiber Composite with Phenolic Matrix in the Space Shuttle Usable Solid Rocket Motor Nozzle.” Online!: May 13, 1999, Mississippi State University, Retrieved from the Internet: URL: http://www.me.msstate.edu/STUDENT/ThesisHi11.htm Retrieved on May 14, 2003.
Ibarra et al., “The Effect of Oxidized Carbon Fiber Content on the Properties of Thermal Plastic Elastomer Composites,” Kautschuk and Gummi—Kunststoffe, Dr. Alfred Huthig Veriag GmbH; Heidelberg, DE; vol. 50, No. 6, Jun. 1, 1997, pp. 478-480, 482-484.
Kim et al, Structure and Properties of the Organoclay Filled NR/BR Nanocomposites, Macromolecular Research (2006), vol. 14, No. 2, pp. 187-193.
Kim et al., Formation of Polymer Nanocomposites with Various Organoclays, Journal of Applied Polymer Science (2005), vol. 96, pp. 1888-1896.
Libera et al., 2001, Pergamon, Hydrothermal synthesis of graphite tubes using Ni catalyst, pp. 1308 & 1317 (12 pages).
Patton et al., “Vapor Grown Carbon Fiber Composites with Epoxy and Poly(Phenylene Sulfide) Matrices”, Composites Part A: Applied Science and Manufacturing; Elsevier Science Publishers B.V.; Amsterdam, NL, vol. 30, No. 9, Sep. 1999, pp. 1081-1091.
Pennwalt, “Dialkyl Peroxides”, Product Bulletin, Buffalo, NY, 2 pages.
Product Description, Grades of Nordel IP Based on Insite Catalysis and Process Technology (1997) p. 3.
Product literature on Saret 633 and Saret 634 Metallic Coagents, 2 pages.
Product literature on RULCO-Treated Silica Products (Jun. 1999), p. 2.
Product literature, “Treated Fumed Silicas Product Guide,” for Cabot Products CAB-O-SIL Treated Fumed Silica (Jun. 1999).
Rajasekar et al., Development of Nitrile Butadiene Rubber-Nanoclay Composites with Epoxidized Natural Rubber as Compatibilizer, Materials and Design (2009), vol. 30, pp. 3839-3845.
Sutton, G.P., “Rocket Propulsion Element,” 1992, Wiley & Sons, NY, US, pp. 106-109.
Tarasen et al., Pyrograf III VGSF Nanofibers for Engineered Composites, 16 pages.
Das et al., Rubber Curing Chemistry Governing the Orientation of Layered Silicate, EXPRESS, Polymer Letters (2007), vol. 1, No. 11, pp. 717-723.
“Calendar,” Merriam-Webster, http://www.merriam-webster.com/dictionary/calendar (last visited Dec. 13, 2011).
Cloisite Nanoclays, “Cloisite and Nanofil Additives, 2006”. Retrived online—http://www.nanoclay.com/benefits2,asp.
“Closite Nanoclays”, Closite Nanofil Additives, 2006. Retrived online [Oct. 9, 2011]. Retrieved from internet—URL: http://www.nanoclay.com.
Related Publications (1)
Number Date Country
20120060676 A1 Mar 2012 US