Claims
- 1. A curl-resistant, cross-sectionally symmetrical, laminated multilayer film substrate for use in the production of banknotes, security papers and the like comprising:
- (a) an imbalanced biaxially oriented first layer having inner and outer sides, comprising at least about 50 weight percent of a high density polyethylene having a density of at least about 0.94, said first layer being oriented in at least a first direction to a degree which is at least three times less than the degree of orientation present in a second direction substantially normal to the first direction;
- (b) a balanced biaxially oriented second layer having inner and outer sides, comprising at least about 90 wt. % polypropylene, said second layer being oriented in at least a first direction at an orientation ratio of at least 4:1 and oriented in a second direction substantially normal to said first direction at an orientation ratio of at least 6:1;
- (c) an imbalanced biaxially oriented third layer having inner and outer sides, comprising at least about 50 weight percent of a high density polyethylene having a density of at least about 0.94, said third layer being oriented in at least a first direction to a degree which is at least three times less than the degree of orientation present in a second direction substantially normal to the first direction; and
- (d) a laminating adhesive resin disposed between the inner sides of (a) and (c), said second layer being laminated to said first and third layers so that the first direction of orientation of said third layer is substantially aligned with the first direction of orientation of said first layer and wherein (a) further comprises a coextruded propylene copolymer skin on its inner side.
- 2. The film substrate of claim 1 wherein both (a) and (c) further comprise a copolymer polypropylene skin on at least one side thereof.
- 3. The film substrate of claim 1 wherein both (a) and (c) further comprise copolymer polypropylene skins on both the inner and outer sides thereof.
- 4. The film substrate of claim 1 wherein (d) comprises a solventless adhesive.
- 5. The film substrate of claim 4 wherein (d) comprises polyurethane.
- 6. The film substrate of claim 1 wherein (d) comprises a component selected from the group consisting of low density polyethylene (LDPE) and linear low density polyethylene (LLDPE).
- 7. The film substrate of claim 1 further comprising (e) a security device between (a) and (c).
- 8. The film substrate of claim 7 wherein said security device is selected from the group consisting of optically variable devices (OVDs), magnetic devices, electronic devices, and rare earth element-containing devices.
- 9. The film substrate of claim 1 further comprising (e) a security device printed on layer (b) prior to laminating with laminating adhesive resin (d).
- 10. The film substrate of claim 3 wherein said copolymer polypropylene skins on said outer sides are externally coated with an opacifying coating.
- 11. The film substrate of claim 10 further comprising a clear window through the film substrate.
- 12. The film substrate of claim 1 in the form of a bank note.
- 13. The film substrate of claim 1 wherein said first direction is machine direction (MD) and said second direction is transverse direction (TD).
- 14. A curl-resistant, cross-sectionally symmetrical, laminated multilayer film substrate for use in the production of banknotes, security papers and the like comprising:
- (a) an imbalanced biaxially oriented first layer having inner and outer sides, comprising at least about 50 weight percent of a high density polyethylene having a density of at least about 0.94, said first layer being oriented in at least a first direction to a degree which is at least three times greater than the degree of orientation present in a second direction substantially normal to the first direction;
- (b) a balanced biaxially oriented second layer having inner and outer sides, comprising at least about 90 wt. % polypropylene, said second layer being oriented in at least a first direction at an orientation ratio of at least 4:1 and oriented in a second direction substantially normal to said machine direction at an orientation ratio of at least 6:1;
- (c) an imbalanced biaxially oriented third layer having inner and outer sides, comprising at least about 50 weight percent of a high density polyethylene having a density of at least about 0.94, said third layer being oriented in at least a first direction to a degree which is at least three times greater than the degree of orientation present in a second direction substantially normal to the first direction; and
- (d) a laminating adhesive resin disposed between the inner sides of (a) and (c), said second layer being laminated to said first and third layers so that the first direction of orientation of said third layer is substantially aligned with the first direction of orientation of said first layer and wherein (a) further comprises a coextruded propylene copolymer skin on its inner side.
- 15. The film substrate of claim 14 wherein said first direction is machine direction (MD) and said second direction is transverse direction (TD).
- 16. A curl-resistant, cross-sectionally symmetrical, laminated multilayer film substrate for use in the production of banknotes, security papers and the like comprising:
- (a) a first layer having inner and outer sides, comprising at least about 50 weight percent of an unoriented, blown high density polyethylene having a density of at least about 0.94;
- (b) a second layer having inner and outer sides, comprising at least about 90 wt. % polypropylene, said second layer being oriented in at least a first direction at an orientation ratio of at least 4:1 and oriented in a second direction substantially normal to said machine direction at an orientation ratio of at least 6:1;
- (c) a third layer having inner and outer sides, comprising at least about 50 weight percent of an unoriented, blown high density polyethylene having a density of at least about 0.94;
- (d) a laminating adhesive resin disposed between the inner sides of (a) and (c) and wherein (a) further comprises a coextruded propylene copolymer skin on its inner side.
RELATED APPLICATIONS
This application is related by subject matter to U.S. application Ser. Nos. 08/467,484, filed Jun. 6, 1995, which is a divisional of U.S. application Ser. No. 08/266,918, filed Jun. 27, 1994 and 08/762,089, Dec. 9, 1997, which is a divisional of U.S. application Ser. No. 08/601,886, filed Feb. 15, 1996, now U.S. Pat. No. 5,618,630, incorporated herein by reference.
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