The subject matter disclosed herein relates to green (environmentally friendly) thermal, chemical and mechanical engineering and in particular to direct contact reactors, heat exchangers, mixing various gases, vapors and fluids, producing heat, energy recovery, condensing vapors, deaerating and pumping fluids and liquids.
Many utilities in the United States and around the world generate and supply district steam to buildings for space heating, cooling and domestic hot water purposes. The steam condensate is sometimes returned to the steam generating source or discharged to the city sewer system. In order to reduce the condensate temperature from 220 F to about 140 F (the city sewer requirement) the condensate is mixed with cold potable water. Such systems operate with substantial electric, heat and water losses and sewer discharge rate. The lost condensate must be made-up at the power or boiler plants with cold demineralized water treated in typical tray- or spray-type deaerators. In district steam systems with large condensate losses the water make-up rate can reach 100% of the feedwater flow. At these conditions the deaerators cannot provide the large heating, condensing and deaerating capacity. As a result of these conditions the deaerators experience water hammer and deteriorated heating and deaeration performance. This causes intensive corrosion of the power plant equipment and district steam piping.
Thermal deaeration of feedwater is widely used in power and boiler plants for removal of non-condensable gases from condensate such as oxygen and carbon dioxide. Typically the incoming condensate is heated in the deaerator with steam to the saturation temperature corresponding to the deaerator pressure. The non-condensable gases are removed from the deaerator with venting steam. Typically a small portion of condensate lost with steam (about 10%) in the utilization process is compensated with cold demineralized water which is also introduced to the deaerator. The temperature of the mixed condensate and the demineralized water stream entering the deaerator is typically increased in the deaerator by 20 to 40 F. In many district steam systems the condensate is not returned to the steam generating station and must be made-up with large amount of cold demineralized water with temperatures of 50 to 70 F. For the atmospheric pressure deaerator with saturation temperature of 220 F the temperature of the treated water must be increased in the deaerator by 150 to 170 F, causing water hammer conditions, reduction in the deaerator capacity and deterioration in quality of the deaerated feedwater.
Typical solutions to the above described problem are installation of large surface type heat exchangers where the cold demineralized water is heated to a temperature of about 180 to 200 F before entering the deaerator. This system requires large expensive heat exchangers and electric driven pumps. The tubing system of the heat exchangers is also subject to intensive corrosion caused by the released non-condensable gases. Because heat exchangers use indirect heat transfer through surfaces, they become plugged with scaling causing the reduction of heat transfer and efficiency.
Direct contact jet apparatus (JA) are also known and widely used, as Venturi heaters, de-superheaters, steam ejectors, jet exhausters and compressors, jet eductors and jet vacuum pumps. The JA consists of three principal parts: a converging (working) nozzle surrounded by a suction chamber, mixing nozzle and a diffuser. The working (motive) and injected (entrained) streams enter into the mixing nozzle where the velocities are equalized and the pressure of the mixture is increased. From the mixing nozzle the combined stream enters the diffuser where the pressure is further increased. The diffuser is so shaped that it gradually reduces the velocity and converts the energy to the discharge pressure with as little loss as possible. During this process the bubbles containing the non-condensable gases are collapse and the gases are dissolved in the liquid.
Methods for heating of liquid products in a steam-liquid injector are provided in U.S. Pat. Nos. 6,299,343; 5,205,648; 5,275,486; 5,544,961; 5,544,961; and, 4,847,043, for example.
While existing deaerators and deaerating devices may be suitable for their intended purpose, the art of deaerator devices, and systems utilizing the same, may be advanced with a deaerator device as herein disclosed.
An embodiment includes an energy saving deaerator device, having: a first incoming flow path that generally follows a central axis of the device from a conically shaped inlet having converging sidewalls, to an expansion chamber having diverging sidewalls, to a compression chamber having converging sidewalls, to an outlet, a first entry port of the compression chamber being defined by an outlet of the expansion chamber; a second incoming flow path having sidewalls that converge to form a ring shaped second entry port of the compression chamber, the ring shaped second entry port being disposed around and concentric with the first entry port; and, wherein the first and second incoming flow paths converge at the compression chamber, with both flow paths being directed toward the outlet, to form an outgoing flow path.
Another embodiment of the invention includes an energy saving deaerating system, having: a supply of feedwater; a supply of steam; an energy saving deaerator device configured to receive the feedwater and the steam, and deliver single-phase deaerated water at on outlet, the deaerator device according to the foregoing description; and, a receptacle for receiving the single-phase deaerated water.
Another embodiment of the invention includes an energy saving method for producing single-phase deaerated water, the method including: feeding a supply of feedwater to an energy saving deaerator device; feeding a supply of steam to the energy saving deaerator device; wherein the energy saving deaerator device is according to the foregoing description and is productive of the single-phase deaerated water at an outlet; and, delivering the single-phase deaerated water to a user or a storage receptacle.
Another embodiment of the invention includes a system that employs a green (environmentally friendly) deaerator device for mixing fluids, particularly water and condensate, supplied thereto at different temperatures, with gases particularly steam, and causes reaction, fracking, refractory for hydrocarbon processes, heating, condensing, deaeration and pumping at desired temperatures. It can be widely used in new and retrofit applications for fossil and nuclear power plants (including prevention of LOCA (loss of coolant accidents) similar to the Fukushima Daiichi nuclear disaster), boiler plants, production of liquid hydrocarbon for synthetic fuels, conversion of mixtures of carbon monoxide and hydrogen into liquid hydrocarbon (Bergius-Dyus and Fischer-Troesch processes), biogas, various industries, enhanced oil recovery, fracking, asphalt, emulsion and beer production facilities, steel mills and fertilizing plants, coal liquefaction and gasification, environmental processes (high efficient gas and particulate removal, smoke and flue gases cleaning and neutralizing reagents in wet scrubbers by direct contact of pollutants from various gas streams), heat, chemistry, water and chemical recovery and district energy systems.
These and other advantages and features will become more apparent from the following description taken in conjunction with the drawings.
The subject matter, which is regarded as the invention, is particularly pointed out and distinctly claimed in the claims at the conclusion of the specification. The foregoing and other features, and advantages of the invention are apparent from the following detailed description taken in conjunction with the accompanying drawings in which:
The detailed description explains embodiments of the invention, together with advantages and features, by way of example with reference to the drawings.
In an embodiment, the first entry port 216 (at “C”) is formed via a first housing section 104, and the second entry port 304 (at “B”) is formed via the first housing section 104 being nested within a second housing section 106 (best seen with reference to
The first incoming flow path 200 is configured to receive a first flowable medium 220, and the second incoming flow path 300 is configured to receive a second flowable medium 320. In a first embodiment, the first flowable medium 220 comprises steam, and the second flowable medium 320 comprises water. In a second embodiment, the first flowable medium 220 comprises water, and the second flowable medium 320 comprises steam. The flowable medium having the greater flow force is provided to the first incoming flow path 200. As such, in an embodiment, the first flowable medium 220 has a flow force greater than that of the second flowable medium 320.
The first flowable medium 220 and the second flowable medium 320 are combinable at the compression chamber 210 to form a two-phase flowable medium 410, and the compression chamber 210 is configured to compress the two-phase flowable medium 410 so that the outgoing flow path 400 comprises a single-phase deaerated flowable medium 420. In an embodiment, the two-phase flowable medium 410 in the compression chamber 210 comprises water and gas bubbles, and the compression chamber 210 is configured to compress the two-phase flowable medium 410 so that the gas bubbles are condensed and the outgoing flow path 400 comprises single-phase deaerated water (also herein referred to by reference numeral 420). In an embodiment, the two-phase flowable medium 410 in the compression chamber 210 flows at supersonic velocity, and the single-phase deaerated flowable medium 420 in the outgoing flow path 400 external of the deaerator device 100 flows at subsonic velocity. In an embodiment, the first flowable medium 220 has a first flow pressure, the second flowable medium 320 has a second flow pressure, and the single-phase deaerated flowable medium 420 has a third flow pressure that is less than the first flow pressure and less than the second flow pressure. In an embodiment, the first flowable medium 220 is one of feedwater or steam, the second flowable medium 320 is the other of the feedwater or steam, and the single-phase deaerated flowable medium 420 comprises single-phase deaerated water having a temperature greater than that of the feedwater.
While
The dimensions identified with letters A, B, C, D and E may be determined using the following equation (Eq.-1):
Where, Pd=discharged pressure after the device (at 420,
As used herein, terms such as critical section and critical velocity, refer to the cross section “A” in
In an embodiment, the outlet 214 of the deaerator device 100 has sidewalls that converge internally to the aforementioned dimension “E”, and then diverge to a dimension “G” as the flow exits the deaerator device 100, which serves to further control the rapid pressure drop and expansion of the fluid 420 as it exits the deaerator device 100.
As the fluid 420 expands on exit, a high suction force develops, resulting in the deaerator device 100 acting as a self-feeding suction jet suitable for receiving working fluids (220 for example) and injected fluids (320 for example) over a wide range of pressures, including a vacuum.
Reference is now made back to
Reference is now made to
The system 500 of
According to another embodiment and with reference now to
According to another embodiment and with reference now to
In an example embodiment, and with reference back to
Other embodiments of the deaerator device 100 or system utilizing the same will now be described in general terms.
According to an embodiment, the deaerator device 100 when utilized as disclosed herein allows preheating and breaking apart the liquid particles and releasing the non-condensable gases. At the entrance into the deaerator device the non-condensable gases are instantaneously released and removed with a venting steam, and the deaerating performance of the deaerator device is substantially improved allowing the exiting water to reach a desired concentration of oxygen (typically below 7 ppb) and free carbon dioxide level (close to zero).
According to another embodiment, the deaerator device 100 does not have a diffuser and the heating process in the device is completed at the two-phase stage at supersonic speed, at which point all non-condensable gases are released (deaerated) from the liquid and are present in the form of bubbles. The discharged deaerated liquid is then passed to a deaerator where the non-condensable bubbles are flashed out from the liquid and instantaneously removed with the venting steam. The remaining liquid practically contains a very small concentration of non-condensable gases, thus reducing drastically the deaerator duty for their removal. Therefore the final concentration of non-condensable gases in the liquid leaving the deaerator are substantially reduced. As a result the corrosion processes in a boiler are practically eliminated. The deaerator device 100 as herein disclosed also allows to reduce the dimensions and cost of the new downstream deaerators.
According to another embodiment, a system that utilizes a deaerator device 100 allows replacing a surface type heat exchanger with a green in-line two-phase compact direct contact deaerator device 100 where cold water is deaerated and heated with steam, as herein disclosed. During the heating the non-condensable gases are intensively released from the water in the form of micro bubbles. Upon entering a downstream deaerator the non-condensable gases are immediately released and removed from the system with the venting steam, and the deaerating performance is substantially improved allowing the water leaving the downstream deaerator to reach a desired concentration of oxygen (typically below 7 ppb) and free carbon dioxide level (close to zero). This allows to substantially reduce the heating and deaerating capacity of the conventional deaerator, thus reducing the size and cost of the deaerator.
According to another embodiment, cold demineralized make-up fluid of any temperature is introduced into the in-line deaerator device 100 where it is deaerated and heated in direct contact with gases or steam. During the treatment in the device the fluid is broken down to minute particles mixed with bubbles of released non-condensable gases. Upon entering a downstream deaerator the non-condensable gases are immediately released and removed with the venting steam and the deaerating performance is substantially improved allowing the deaerated water to reach a desired concentration of oxygen (typically below 7 ppb) and free carbon dioxide level (close to zero).
According to another embodiment, the deaerator device 100 as disclosed herein allows overcoming the limitation of existing deaerators by substantially increasing the heating and deaerating capability.
In the various systems disclosed herein, gas or steam enters into the deaerator device 100 through a large jet nozzle, inlet 202 for example (see
In view of all of the foregoing, it will be appreciated that an embodiment of the invention not only includes a deaerator device 100 as herein disclosed, and a system that utilizes the deaerator device, but also includes an energy saving method for producing single-phase deaerated water, which may also be heated in the process, using the deaerator device 100 as herein disclosed. The method generally includes: feeding a supply of feedwater to the deaerator device; feeding a supply of steam to the deaerator device; wherein the deaerator device has structure and performs as herein disclosed to produce single-phase deaerated water; and, delivering the single-phase deaerated water to a user or a storage receptacle, wherein the delivered single-phase deaerated water has a temperature greater than that of the feedwater.
In addition to all of the foregoing, further embodiments of the deaerator device 100 include the following:
Embodiment 1 includes a device in the form of a green (environmentally friendly) two-phase direct contact deaerator device having round, square, triangular, or elliptically shaped gas, liquid, two-phase or steam nozzles for heating, condensing, deaerating and pumping liquids, particularly water.
Embodiment 2 includes the device according to Embodiment 1, further including single or multiple inlets for gas, steam, two-phase fluids or liquids.
Embodiment 3 includes the device according to any of Embodiments 1-2, further including an arrangement where an inlet nozzle, or nozzles are aligned with a mixing nozzle or nozzles.
Embodiment 4 includes the device according to any of Embodiments 1-3, further including a mixing section, or sections where the gas or steam are mixed with liquids at supersonic velocity.
Embodiment 5 includes the device according to any of Embodiments 1-4, further having condensed the gas or steam and heated the liquid to a determined temperature, wherein the non-condensable gases are released from the liquid in the form of bubbles.
Embodiment 6 includes the device according to any of Embodiments 1-5, configured for collecting and pumping condensate from district heating system for generation of heat, electricity and domestic hot water in buildings and industries.
Embodiment 7 includes the device according to any of Embodiments 1-6, further including combining inlet gases, steam, liquids or multi-phase fluids of various pressures up to 600 psig and temperatures up to 700 F.
Embodiment 8 includes the device according to any of Embodiments 1-7, wherein the device is used for heating, condensing and deaerating different streams of gases and liquids.
Embodiment 9 includes the device according to any of Embodiments 1-8, further including providing outlet liquids with defined temperatures.
Embodiment 10 includes the device according to any of Embodiments 1-9, wherein the diameter of inlet gas or steam nozzle is greater than the diameter of the throat of the same nozzle by a factor proportional to the pressure, temperature and quantity parameters.
Embodiment 11 includes the device according to any of Embodiments 1-10, wherein the diameter of the exit gas or steam nozzle is greater than the gap between the exit gas nozzle and the body of the device by a factor proportional to the pressure, temperature and quantity parameters.
Embodiment 12 includes the device according to any of Embodiments 1-11, wherein the diameter of the inlet gas or steam nozzle is 30 percent greater than the diameter of the outlet of the steam or gas nozzle.
Embodiment 13 includes the device according to any of Embodiments 1-12, wherein the diameter of the outlet steam nozzle is equal to the diameter of the two-phase mixture exit from the device.
Embodiment 14 includes the device according to any of Embodiments 1-13, wherein the device is used as a scrubber for heating and cleaning various liquids and gases from particles and smoke.
Embodiment 15 includes the device according to any of Embodiments 1-14, wherein the device is used as a preheater in power plants and boiler rooms.
Embodiment 16 includes the device according to any of Embodiments 1-15, further including an outlet section for a two-phase mixture of liquid and bubbles of non-condensable gases discharged at subsonic velocity, at pressures lower than the pressures of the working and injected flows.
Embodiment 17 includes the device according to any of Embodiments 1-16, wherein the device is used at the inlet and the outlet of a centrifugal pump to prevent cavitation.
Embodiment 18 includes the device according to any of Embodiments 1-17, further including check valves at the inlet and outlet of centrifugal pumps to prevent cavitation.
Embodiment 19 includes the device according to any of Embodiments 1-18, wherein the device is used for cracking heavy crude oil.
Embodiment 20 includes the device according to any of Embodiments 1-19, wherein the device is installed inside of a vessel for mixing with different liquids and gases for heating and deaeration purposes.
Embodiment 21 includes the device according to any of Embodiments 1-20, wherein the device is used for fracking underground wells utilizing cavitation forces.
Embodiment 22 includes the device according to any of Embodiments 1-21, wherein the device is used for enhanced geothermal systems, enhanced oil recovery, or methanol production.
Embodiment 23 includes the device according to any of Embodiments 1-22, wherein the device is used in various chemical processes, food processing, petroleum, dairy, manufacturing, distilling/brewing, desalination, cleaning solutions, pasteurization, sterilization, heating water, waste heat recovery, exchanging heat, degreasing, heating slurries, laundering, cooking, pickling, or quenching and tempering.
Embodiment 24 includes the device according to any of Embodiments 1-23, wherein the device is used in new and retrofit applications for power plants, boiler plants, production of liquid hydrocarbon for synthetic fuels, or conversion of mixtures of carbon monoxide and hydrogen into liquid hydrocarbon (Bergius-Dyus and Fischer-Troesch processes).
Embodiment 25 includes the device according to any of Embodiments 1-24, wherein the device is used in biogas production, beer manufacturing, enhanced oil recovery, asphalt production facilities, steel mills and fertilizing plants, or coal liquefaction and gasification.
Embodiment 26 includes the device according to any of Embodiments 1-25, wherein the device is used in environmental processes: high efficient gas and particulate removal, smoke and flue gases cleaning, or neutralizing reagents in wet scrubbers by direct contact of pollutants from various gas streams.
Embodiment 27 includes the device according to any of Embodiments 1-26, wherein the device is used in various commercial, residential and industrial heating processes, chemicals recovery, or district energy systems.
Embodiment 28 includes the device according to any of Embodiments 1-27, wherein the device is used for deaeration of liquids in a vortex type deaerator to prevent noise during the movement in piping systems in various power systems, commercial, residential and industrial heating processes, or district energy systems.
Embodiment 29 includes the device according to any of Embodiments 1-28; further including an air eliminator in order to remove the non-condensable gases before the liquid enters the deaerator, to be used in various power generation, commercial, residential and industrial heating processes, or district energy systems.
Embodiment 30 includes the device according to any of Embodiments 1-29, wherein the device is used in production of emulsion in various power generation, commercial, residential and industrial heating processes, or district energy systems.
Embodiment 31 includes the device according to any of Embodiments 1-30, wherein the device is used in fossil and nuclear power plants for heating and deaeration of feedwater, or cooling the reactor during a loss of coolant accident (LOCA).
Embodiment 32 includes the device according to any of Embodiments 1-31, further including a transonic device, turbulized vortex gas eliminator/deaerator, control pump, and multifunctional control system, operating as a direct hydraulic loop with the existing heating system.
Embodiment 33 includes the device according to any of Embodiments 1-32, further including a highly turbulized heat exchanger, providing hydraulic separation from the existing heating system.
While the invention has been described in detail in connection with only a limited number of embodiments, it should be readily understood that the invention is not limited to such disclosed embodiments. Rather, the invention can be modified to incorporate any number of variations, alterations, substitutions or equivalent arrangements not heretofore described, but which are commensurate with the spirit and scope of the invention. Additionally, while various embodiments of the invention have been described, it is to be understood that aspects of the invention may include only some of the described embodiments. Accordingly, the invention is not to be seen as limited by the foregoing description, but is only limited by the scope of the appended claims.
Filing Document | Filing Date | Country | Kind |
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PCT/US2015/064963 | 12/10/2015 | WO | 00 |
Number | Date | Country | |
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62090311 | Dec 2014 | US |