1. Field of the Invention
This invention relates generally to fuel cell systems, and more specifically to the management of multiple gas flow streams entering a solid oxide fuel cell system.
2. Related Art
Fuel cells can generate electricity be reacting a fuel (hydrogen, hydrocarbon) and an oxidant on opposite electrodes of an electrochemical cell. Portable fuel cell systems can operate utilizing a raw fuel contained onboard. Raw fuel requires further processing prior to utilization by the electrochemical cell. Raw fuel can be refined through a process that includes filtering the raw fuel through a filter and reforming the raw fuel by reacting the raw fuel with an oxidant at an onboard reformer to partially oxidize the fuel. Once the raw fuel is processed, the fuel is suitable for use in a fuel cell system, that is, as a fuel that can be utilized by the electrochemical cell.
The process of transforming raw fuel into a fuel suitable for use in a fuel cell requires several large, heavy and costly components, including pumps, blowers, fans, filters, reformers, and sensors, each of which contribute significantly to the volume, weight, and overall cost of a fuel cell system. Included among these are components that deliver and control air flow to the anode and to the cathode of the fuel cell. The anode air flow stream is supplied to the onboard reformer and the anode air flow stream flow rate is manipulated to control an air-to-fuel ratio to reform fuel by partial oxidation. To achieve the desired air-to-fuel ratio, most fuel cell systems include anode air processing components such as an air filter, controllable actuators, feedback control sensors, and various air delivery components. Similarly, fuel cell systems often also include fuel processing components such as a fuel filter, controllable actuators, feedback control sensors, regulators, heating elements and expansion chambers. These fuel delivery components are used to deliver fuel to proper locations within the fuel cell system where the fuel can mix with the anode air flow stream prior to delivery to the onboard reformer. Typical fuel cell systems further include components to direct reformed fuel from the onboard reformer to the fuel cell anode, thereby providing fuel for electrochemical fuel cell reactions.
Reducing the volume, weight, and/or cost of a fuel cell system are goals shared by many in the fuel cell industry, as well as the desire to create more efficient fuel cell systems. Therefore, there is a need for robust fuel cell systems with onboard reforming that is easy to manufacture, low cost, and that a have high power to volume ratio and a high power to weight ratio.
According to one aspect of this invention, a fuel cell system includes a fuel cell stack configured to generate electricity by reacting oxygen and a gaseous fuel. The fuel cell stack includes an anode portion and a cathode portion. An air/fuel handling plate at least partially defines an anode air chamber, a cathode air chamber, and a fuel flow path. The anode air chamber is configured to route air to the anode portion of the fuel cell stack. The cathode air chamber is configured to route air to the cathode portion of the fuel cell stack. The fuel flow path is configured to route gaseous fuel to the anode portion of the fuel cell. A unitary, multi-stream flow sensor is coupled to the air/fuel handling plate. The multi-stream flow sensor has an anode air flow sensing unit operatively disposed in the anode air chamber, a fuel flow sensing unit operatively disposed in the fuel flow path, and a cathode air flow sensing unit operatively disposed in the cathode air chamber.
The multi-stream flow sensor may be used to determine the flow rate of air passing through the cathode air chamber simultaneously with the flow rate of air passing through the anode air chamber and the flow rate of fuel passing through the fuel path so that appropriate control strategies can be implements to make the fuel cell operate with maximum efficiency. For example, the flow rates of any one (or more) of the three gaseous flows can be manipulated to improve operating efficiency or achieve other desirable operating characteristics of the system. Utilizing a single, multi-stream flow sensor at a strategic location in the air/fuel handling plate provides significant cost reduction advantages compared to traditional systems utilizing several independent flow sensors each with separate mounting requires and electrical connection demands.
According to another aspect of this invention, an air/fuel handling plate is provided for a fuel cell system. The air/fuel handling plate includes an anode air chamber, a cathode air chamber, and a fuel flow path. The anode air chamber is configured to route air to the anode portion of a fuel cell stack. The cathode air chamber is configured to route air to the cathode portion of a fuel cell stack. And the fuel flow path is configured to route gaseous fuel to the anode portion of a fuel cell. A unitary, multi-stream flow sensor is coupled to the air/fuel handling plate. The multi-stream flow sensor has at least two sensing units operatively disposed, one each, in the anode air chamber, the fuel flow path, and/or the cathode air chamber.
According to a still further aspect of this invention, a method is contemplated for routing air and fuel gases to a solid oxide fuel cell system. The method comprises the steps of: providing a fuel cell stack configured to generate electricity by reacting oxygen and a gaseous fuel, the fuel cell having an anode portion and a cathode portion; routing air to the anode portion of the fuel cell stack through an anode air chamber; routing air to the cathode portion of the fuel cell stack through a cathode air chamber; routing gaseous fuel to the anode portion of the fuel cell stack through a fuel flow path; the routing step including converging the respective flows of cathode air, anode air and fuel in generally parallel, side-by-side flow paths; and simultaneously sensing the mass flow rates of the air and fuel in each of the anode air chamber, cathode air chamber and fuel flow path with a multi-stream flow sensor disposed in the converging region.
These and other features and advantages of the present invention will become more readily appreciated when considered in connection with the following detailed description and appended drawings, wherein:
Referring to the figures wherein like numerals indicate like or corresponding parts throughout the several views, an exemplary fuel cell system is generally shown at 10 in
The balance of plant subsystem 14 includes an integrated air/fuel handling plate, generally indicated at 16, a rechargeable battery (not shown), a power electronics system 20, an exhaust blower 24, anode air/fuel delivery system 28, a user interface (not shown), heat management systems, environmentally sealed air, power and lines with wall pass-through openings (not shown). The rechargeable battery 18 can be any battery suitable for hybridization with the fuel cell stack 12 through the power electronics system 20. The rechargeable battery 18 can comprise any of several rechargeable battery technologies including, for example, nickel-cadmium, nickel-metal hydride, lithium-ion, and lithium-sulfur technologies, as well as suitable battery technologies that may be developed in the future. In alternative embodiments, other reversible energy storage technologies such as ultra-capacitors can be utilized in addition to or instead of the rechargeable battery 18. Further in alternate embodiments, multiple energy storage devices can be utilized within a fuel cell system 10.
The power electronics system 20 may include an electrically conductive network configured to route power between the fuel cell stack 12 and the battery 18, and also from the energy conversion devices (fuel cell stack 12 and the battery 18) to a user interface panel (not shown). Power levels within the power system 20 can be controlled utilizing power conversion members (not shown) controlled by a suitable control system 22.
The exhaust blower 24 is configured to drive exhaust gases away from the fuel cell stack 12 in an exhaust flow path direction. In an exemplary embodiment, the exhaust blower 24 is configured to draw heat away from the integrated air/fuel handling plate 16. In an alternate embodiment, the integrated air/fuel handling plate 16 is positioned to intersect the exhaust flow path substantially perpendicular to the exhaust flow path direction such that the exhaust gases provide preheating to air within the integrated air/fuel handling plate 16. An anode air blower 26 is configured to motivate anode air at controlled flow rates to the fuel cell stack 12. The anode air blower 26 is part of an anode air/fuel delivery system 28 that also includes a fuel valve and an air fuel mixing point. The fuel valve may be incorporated into the air/fuel handling plate 16. Fuel is delivered at controlled flow rates to the anode air/fuel delivery system 28 and is mixed with controlled amounts of air such that desired amounts of fuel along with a desired ratio of air to fuel is delivered to onboard reformers 30 (
Referring to
The air/fuel handling plate 16 may include a sandwich of upper and/or lower plates or covers, as needed, that are fastened together with suitable gaskets or seals to enclose the anode air chamber 34 and cathode air chamber 32 into air-handling plenums. Portions of the power electronics system 20 are mounted to the air/fuel handling plate 16 proximate the anode chamber 34 and the cathode chamber 32. By mounting the power electronics 20 proximate the air flow passageways, heat can be transferred away from the power electronics system 20 and to the air in the anode air chamber 34 and the cathode air chamber 32 thereby providing benefits of removing heat from the power electronics system 20 and preheating the anode air stream and cathode air stream prior to providing the anode air flow stream and the cathode air flow streams to the fuel cell stack 12.
The balance of plant subsystem 14 is preferably mechanically isolated from the fuel cell stack 12 with resilient members 46. The anode air/fuel delivery system 28 may include a resilient tube-like member 48 extending between the anode blower 26 and the air/fuel handling plate 16. As perhaps best shown in
The fuel feed tubes 56 are disposed partially within the fuel cell tubes 58. The onboard fuel reformer 30 is positioned within each of the fuel cell tubes 58 proximate an electrochemically active region of the fuel cell tubes 58. Anode air and unreformed fuel is routed through the fuel feed tube 56 to the onboard fuel reformer 30 where the fuel is reformed and the resulting reformed fuel is heated during the exothermic reformation reactions (for an exemplary fuel cell system having an internal onboard fuel reformer, reference is made to U.S. Pat. No. 7,547,484, granted Jun. 16, 2009, the entire disclosure of which is hereby incorporated by reference and relied upon.) In alternate embodiments, the fuel can be reformed utilizing endothermic reactions and the fuel cell tubes can be heated to operating temperatures utilizing alternate heating devices such as an internal combustor or a resistance heating device.
The fuel cell tubes 58 each comprise an anode layer, an electrolyte layer, and a cathode layer at the active portion that generates electromotive force at the active portion at operating temperatures in the range of 700 to 850 degrees Celsius. However, only the active portion of the fuel cell tube 58 contains the anode layer, the electrolyte layer, and the cathode layer, and therefore, only a portion of each fuel cell tube 58 requires high operating temperatures for generating electromotive force.
The insulated body 62 comprises composite insulation material that can maintain the fuel cell stack 12 at the operating temperatures. The recuperator 64 transfers heat between the exhaust gases generated within the fuel cell stack 12 and the cathode air stream inlet to the fuel cell stack 12. In an alternate embodiment, heat exchangers can be utilized to transfer heat between other fluid streams.
Referring now to
As perhaps best shown in
The multi-stream flow sensor 66 utilizes a single electric circuit board 80 (
In the preferred embodiment, the anode air chamber 34, fuel flow path 68 and cathode air chamber 32 are arranged in the air/fuel handling plate 16 as side-by-side plenums. The anode and cathode air chambers 32, 34 are disposed in parallel toward the outer edges of the handling plate 16, with the fuel flow path 68 extending in parallel in the region between the air chambers 32, 34. The sensor port 72 bridges all three of these plenums 32, 34, 68 in a central, converging region of their respective paths, with the three flow sensing units 74, 76, 78 being linearly aligned with one another. When viewed from the top, as in
The multi-stream flow sensor 66 integrates multiple gas flow stream sensing into a unitary housing, utilizing a single circuit board 80, so that a single electrical connector port 82 and can be easily coupled within the fuel cell system 10. As a direct result, the robustness of the fuel cell assembly 10 is increased while manufacturing cost is decreased. In alternate designs, other flow sensor features may be incorporated, including, for example, various mechanical and electromagnetic flow sensors, temperature-based flow sensors, ultrasonic flow sensors, and coriolis flow sensors can be utilized to measure air and fuel flow rates. Further, exemplary housing components can include various plastic and metal components selected for manufacturability, end-use environment and cost.
The multi-stream flow sensor 66 works in concert with the control system 22 to determine a flow rate of air passing through the cathode air chamber 32 simultaneously with a flow rate of air passing through the anode air chamber 34 and a flow rate of fuel passing through the fuel path 68. Utilizing a single, multi-stream flow sensor 66 at a strategic location 72 in the air/fuel handling plate 16 provides significant cost reduction advantages compared to traditional systems utilizing several independent flow sensors each with separate mounting requires and electrical connection demands.
From the foregoing disclosure and detailed description of certain embodiments, it will be apparent that various modifications, additions and other alternative embodiments are possible without departing from the true scope and spirit of the invention. The embodiments discussed were chosen and described to provide illustrations of the principles of the invention and its practical application to thereby enable one of ordinary skill in the art to use the invention in various embodiments and with various modifications as are suited to the particular use contemplated. All such modifications and variations are within the scope of the invention as determined by the following claims when interpreted in accordance with the breadth to which they are fairly, legally, and equitably entitled.
This application claims priority to Provisional Patent Application No. 61/306,525 filed Feb. 21, 2010, the entire disclosure of which is hereby incorporated by reference and relied upon.
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Number | Date | Country | |
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61306525 | Feb 2010 | US |