Multiple tub mobile blender

Abstract
An improved oil and gas well servicing apparatus for blending and delivering a slurry of fracturing fluid and particulate matter at constant flow rate and pressure to a downhole pump is disclosed. Multiple blending tubs are mounted on a trailer or skid and are manifolded together in a slurry discharge manifold. The slurry discharge manifold combines the slurry discharged by the blending tubs and incorporates pipe sections of equal length to connect the blending tubs to the manifold. It is believed that the slurry discharge manifold and equal length piping provide balanced pressure drop between the individual blending tubs and creates a constant outlet pressure from the slurry discharge manifold. A fluid intake manifold may also be included to distribute fracturing fluid to the blending tubs. Hose connectors on each of the manifolds are provided on both sides of the apparatus for convenient operation from either side. A conveyer system delivers particulate matter, such as sand, to a distribution bin located above the blending tubs. A source of fracturing fluid may be attached to a hose connector on the fluid intake manifold. The blending tubs utilize a variable drive means placed above each blending tub and suspending an impeller in the blending tub and rotating it about a vertical axis. Thus, a plenum space is provided between the impeller and the bottom of the tub. A tangential outlet is located adjacent to the plenum space and carries the slurry out of the blending tub and into the slurry discharge manifold.
Description




FIELD OF THE INVENTION




The present invention relates to a blending apparatus. Specifically, the present invention relates to a blending apparatus used in well fracturing operations. More specifically, the present invention relates to a blending apparatus having multiple mixing tubs.




BACKGROUND OF THE INVENTION




To increase the production of an oil, gas, geothermal, or other type of well, the producing zone of the geological formation surrounding the well is fractured to allow the desired fluids to flow more freely through the formation and into the well. Fluid is pumped into the formation under high pressure to fracture the producing zones. However, if fracturing fluid is pumped into the formation during the fracturing operation without some accompanying solid, the geological formation pressures will cause the fractured areas of the formation to close when the pumping of fracturing fluid stops, thus restricting the flow of the oil or gas.




A slurry of particulate material, such as sand blended with the fracturing fluid, may be forced into the fissures in the geological formation to keep the formation open after the slurry has been pumped into the well. Well servicing equipment incorporates blending apparatus to mix the particulate material with the fracturing fluid. The blender discharges the slurry to a high pressure, downhole pump that injects it into the well and into the producing zones. It is important that the discharge pressure of the blender remains constant to prevent the downhole pump from cavitating, a condition in which inlet fluid flow is reduced or air is passed through the pump and downhole pressure is lost. When cavitation occurs in the downhole pump, the fracturing operation fails.




It is desirable to use multiple blending tubs in the blending and fracturing operations. Multiple blending tubs increase the flow rate and provide a failsafe backup system in the event that one of the tubs fails. However, because of cavitating and other downhole pump problems, it has been difficult to use multiple tubs simultaneously. It is crucial to a cost effective fracturing operation that a high flow rate of slurry is reliably delivered at a relatively constant pressure to the downhole pumping equipment.




FORMATION DISCLOSURE STATEMENT




The Stegemoeller patents (U.S. Pat. No. 4,490,047, U.S. Pat. No. 4,802,141, U.S. Pat. No. 4,850,701 and U.S. Pat. No. 4,913,554) disclose a structure which combines a single mixing tub mounted on a vehicle and having in conjunction an engine for driving hydraulic pumps, additive tanks for use in producing the slurry mixture from the mixing tub, and a control station for operating and monitoring the operation of the system. Throughout these patents, there is considerable discussion concerning the shape and size of the mixing tub. However, there is no teaching in any of the Stegemoeller et al. patents of manifolding multiple blending tubs together to provide a constant outlet pressure.




The Cooper patent (U.S. Pat. No. 4,159,180) discloses a mixing tub mounted on an articulated truck bed. The purpose behind this mechanism is to allow the mixing tub to be rolled off of the truck chassis so that it is resting upon the ground. It is stated that this lower position for the mixing tub allows the tub to be charged with conventional loading equipment instead of having to provide a loading mechanism on the truck itself. The entire system is returned to the truck chassis for transportation purposes. The Cooper patent teaches a single mixing tub and does not disclose the use of multiple tubs.




The Althouse patent (U.S. Pat. No. 4,453,829) discloses a type of mixing tub which utilizes a special impeller for the mixing and blending of the ingredients to form the outlet slurry. This embodiment uses a relatively flat casing with a first impeller having a slinger and a second impeller fastened to a vertical shaft. The second impeller is positioned beneath the slinger portion. The slinger has a toroidal shape which is stated to provide a good pressure balance within the fluid composition for circulating and mixing within the casing. The mixing tub utilizes a reverse centrifugal pump. This mixing tub is used in the servicing of oil wells. The Althouse patent does not teach the use of multiple blending tubs.




The Paulus et al. patent (U.S. Pat. No. 3,050,159) and the Ross et al. patent (U.S. Pat. No. 3,295,698) disclose mobile mixing systems. Both of these patents, however, are directed to batch plants usually for the mixing and pouring of concrete. The Paulus et al. patent discloses a self-erecting portable mixing plant which is transported to the site on a trailer type structure. Upon reaching the site, the structure is erected or elevated into position with the mixer and loading distribution bin elevated to a considerable height to allow the contents of the mixer to be dumped directly into a hauling vehicle. The Ross et al. patent also shows a trailer mounted batch plant whereby a concrete silo is erected into a vertical position with conveyers used for automatically charging a portable mixer with the proper ingredients for concrete. These last two patents are not directly on point, but disclose various types of trailer mounted structures which are used for mixing purposes. These references do not disclose multiple tubs manifolded together to allow the use of two or more tubs simultaneously.




SUMMARY OF THE INVENTION




The present invention provides an improved well servicing apparatus for blending and delivering a slurry of fracturing fluid and particulate matter at a constant flow rate and pressure to a downhole pump. Multiple blending tubs are mounted on a trailer, skid, or other type of supporting vehicle or structure and are manifolded together with a slurry discharge manifold. Pipe sections of equal length connect the blending tubs to the slurry discharge manifolds. The slurry discharge manifold and equal length pipe sections provide balanced pressure between the individual blending tubs. Connections to the manifold are provided on both sides of the support structure for convenient operation from either side. A fluid intake manifold on either or both sides of the apparatus may be included to deliver fracturing fluid to the blending tubs. A source of fracturing fluid, such as a tanker truck, is attached to one or more connections on the fluid intake manifold. A conveyer system delivers particulate matter, such as sand, to a distribution bin located above the blending tubs.




Each blending tub may be cylindrically shaped and powered by a rotating impeller attached to and suspending from a vertical drive shaft. Particulate matter is fed by gravity through the distribution bin into an opening in the top surface of each blending tub. Fracturing fluid is introduced into the blending tub from a tangential inlet located on the upper portion of the blending tub. A plenum space is provided in the tub directly below the rotating impeller. As the fracturing fluid and particulate matter gravitate downward through the tub, they are mixed to form a slurry which exits through a tangential discharge outlet located on the lower portion of the tub adjacent to the plenum. Control valves are located near the inlet and outlet of each blending tub. These valves are used primarily to isolate a blending tub when it is not in use.




Because the inlet and outlet piping to the individual tubs are identical on each tub, the pressure drop in these pipes are relatively the same. This characteristic allows the tubs to automatically balance the pressure within the tubs and manifolds and thus provide a constant outlet pressure to the downhole pump. This self-balancing of the pressures within the tubs and thus the outlet manifold is a critical and unique feature of the present invention.




The start up operation of the blending tubs proceeds as follows. The slurry is mixed in one blending tub with the impeller rotating at 600 rpm or more and the inlet and outlet valves open. The suction pump is operated to provide a pressure of between approximately 25 psi and 38 psi. The impeller of the second tub is brought up to a speed of approximately 600 rpm or more before being filled with fracturing fluid and introducing particulate matter. Once the fracturing fluid and particulate matter begin mixing, the inlet and outlet control valves are opened. The outlet pressures of the two tubs balance and equalize in the outlet manifold, thus providing constant pressure to the downhole pump.




Other features and advantages of the present invention will become apparent from the following detailed description of the invention when it is considered in conjunction with the accompanying drawings.











BRIEF DESCRIPTION OF THE DRAWINGS





FIGS. 1 and 2

are perspective views of opposite sides of the present invention mounted on a trailer;





FIG. 3

is a perspective view of the blending tubs and piping for the fluid intake manifold and slurry discharge manifold;





FIG. 4

is a plan view of the blending tub, drive unit, and associated inlet and outlet pipe sections;





FIG. 5

is a partial side view of the blending tub, distribution bin, and drive unit, showing the lower cavity area;





FIG. 6

is a diagram in schematic form illustrating the fluid intake manifold and slurry discharge manifold; and





FIG. 7

is a perspective view of an alternative embodiment of the apparatus shown mounted on a skid.











DETAILED DESCRIPTION OF THE INVENTION




As shown in

FIGS. 1 and 2

, blending tubs


12


,


14


are mounted on a trailer


10


or skid


150


(FIG.


7


). A conveyer system


18


may be used to deliver particulate matter, such as sand, from a hopper


16


to a distribution bin


24


located above the blending tubs


12


,


14


. The conveyer system


18


may incorporate a plurality of augers


20


, each enclosed by a cylindrical sleeve, and capable of feeding particulate matter from a hopper


16


to the distribution bin


24


through a positive displacement screw. The augers


20


may be powered simultaneously or separately, depending on the required amount of particulate matter. The speed of each auger


20


may be independently controlled, thus providing adjustment and control over the amount of particulate matter that is fed to each of the blenders. A slidable or otherwise movable baffle may be provided within the distribution bin


24


for diverting and controlling the flow of particulate matter to the individual blending tubs


12


,


14


.




Two large diesel engines


26


may be used to power the apparatus. Each engine


26


powers a separate hydraulic pump


28


and reservoir


32


, which drives an individual blending tub, and one or more augers


20


in the conveyor system


18


. The hydraulic pumps


28


may drive the drive unit


38


and suction pump


36


individually or in combination. While hydraulic power systems are used in the preferred embodiment of the present invention, it is to be understood that other types of power systems, including electric motors or internal combustion engines, may be used to power the apparatus.




The main control system


30


, located in a cab in the central area of the trailer


10


, controls the auger speeds, suction pump speed, and control valves, as well as the rotary drive units


78


connected to the impellers


74


in the blending tubs


12


,


14


. A suitable computer may be used to control the operation of the system so that a desired slurry density is achieved. While the main control system


30


is located on deck


22


, it may be remotely located.





FIGS. 3 and 6

illustrate the manifold systems that connect the blending tubs


12


,


14


.




The fluid intake manifold


34


includes a hydraulic suction pump


36


, hydraulic drive unit


38


, left intake bank


40


, right intake bank


48


, T-junction


56


, main intake pipe


58


, and a Y-junction


60


. The suction pump


36


, powered by the drive unit


38


, supplies fracturing fluid to the blending tubs


12


,


14


through the main intake pipe


58


, and includes a speed control for controlling the combined rate of fluid flow to the blending tubs


12


,


14


. The left and right intake banks


40


,


48


are positioned on both sides of the apparatus to allow convenient positioning of one or more sources of fracturing fluid. Water, diesel fuel, gelled solution, or other suitable solutions may be used for the fracturing fluid. Hose connectors


42


and shut off valves


44


are included with the left intake bank


40


. Hose connectors


50


and shut off valves


52


are included with the right intake bank


48


. The T-junction


56


connects the left intake bank


40


and right intake bank


48


with the pump


36


and the main intake pipe


58


. Bank valves


46


,


54


allow the left and right intake banks


40


,


48


, respectively, to be operated separately or in combination. The Y-junction


60


connects the main intake pipe


58


to equal length pipe sections


64


,


70


, which deliver the fracturing fluid to the blending tubs


12


,


14


, respectively. Pipe section


64


connects to tangential inlet


66


on blending tub


12


and pipe section


70


connects to tangential inlet


72


on blending tub


14


. Pipe section


64


includes control valve


62


and pipe section


70


includes control valve


68


. Control valves


62


,


68


allow the blending tubs


12


,


14


to be operated separately or in combination.




The blending tubs


12


,


14


may be cylindrically shaped, with a closed bottom surface and a partially open top surface.

FIGS. 4 and 5

show the blending tub


12


. Blending tub


14


may be configured similar to blending tub


12


. As shown in

FIGS. 4 and 5

, the blending tub


12


includes a horizontally rotating impeller


74


. A drive shaft


76


protrudes vertically upward through the top of the tub and connects to a hydraulic drive unit


78


. Particulate matter is fed by gravity through the distribution bin


24


and into an opening in the top surface of the blending tub


12


. Sand, glass beads, walnut shells, poly abrasive or other suitable materials may be used as the particulate matter. Fracturing fluid is introduced into the blending tub


12


by a tangential inlet


66


located in the upper portion of the blending tub


12


. A plenum space


86


is provided in the blending tub


12


below the rotating impeller


74


. As the fracturing fluid and particulate matter gravitate downward through the blending tub


12


, they are mixed into a slurry and exit through a tangential discharge outlet


88


located on the lower portion of the blending tub


12


.




The impeller


74


comprises an upper ring


80


and a lower disk


82


sharing a common axis of rotation defined by the drive shaft


76


. The impeller


74


may be positioned horizontally. The open area surrounded by the upper ring


80


allows the drive shaft


76


to connect to the lower disk


82


. The upper ring


80


and lower disk


82


are connected to each other by a plurality of blade me


84


mounted perpendicularly between the upper ring


80


and lower disk


82


at the periphery. The upper ring


80


, lower disk


82


and blade members


84


are constructed of hardened steel or other suitable material capable of withstanding the abrasive and erosive characteristics of the slurry. The diameter of the impeller


74


is smaller than the inner diameter of the tub and allows sufficient clearance for the fluid and particulate matter to pass. The impeller


74


is suspended by the drive shaft


76


approximately eight to ten inches above the bottom of the tub, thus creating the plenum space


86


at the bottom of the tub under the impeller


74


. It is believed that a buoyancy factor created within the plenum space


86


helps balance the individual tub pressures in the slurry discharge manifold


100


.




The slurry discharge manifold


100


carries the slurry from the blending tubs


12


,


14


. Slurry exits the blending tub


12


from tangential outlet


88


and blending tub


14


from tangential outlet


94


. Tangential outlets


88


,


94


are connected to equal length pipe sections


90


and


96


, respectively. Pipe section


90


includes control valve


92


, and pipe section


96


includes control valve


98


. Control valves


92


,


98


, in combination with control valves


62


,


68


, allow the blending tubs


12


,


14


to be operated separately or in combination. The slurry discharge manifold


100


includes Y-junction


102


, main discharge pipe


104


, left discharge bank


112


and right discharge bank


118


. Y-junction


102


connects the pipe sections


90


and


96


to the main discharge pipe


104


. The main discharge pipe


104


is connected to a second Y-junction


106


and control valves


108




110


, where the slurry may be distributed between the left discharge bank


112


and right discharge bank


118


, respectively. Left discharge bank


112


includes hose connectors


116


controlled by shut off valves


114


. Right discharge bank


118


includes hose connectors


120


controlled by shut off valves


122


. The pressure from the blending tubs is sufficient to carry the slurry through the slurry discharge manifold


100


. A cross-over valve


124


connects the main intake pipe


58


and the main discharge pipe


104


. The cross-over valve


124


allows the tubs to be completely bypassed and delivers fracturing fluid directly to the left and right discharge banks


112


,


118


.




It appears that the equal length pipe sections


90


and


96


are critical to producing the constant and balanced outlet pressure. This is apparently true in the manifolding together of any number of blending tubs. Thus, alternative embodiments of the present invention may incorporate numerous additional blending tubs. Additionally, the provision of the plenum


86


in the bottom area of the tub below the impeller


74


with the outlet pipe connected to the tub in this lower area also contributes to and enhances the balancing of the outlet pressure from each tub to provide the constant outlet pressure necessary for downhole fracturing operations.




The base structure may incorporate a chassis which can be mounted or built on a semi-trailer, skid frame, vessel, or other structure. The complete apparatus may be constructed for operation in any type of environment where well servicing is required.




Operation




The operation of both blending tubs


12


,


14


is performed as follows. A source of fracturing fluid is connected to one or more of the intake hose connectors


42


,


50


. Upon startup of the deck engines


26


, the hydraulic pumps


28


are activated. The suction pump


36


is activated, and the fracturing fluid is drawn into the fluid intake manifold


34


. To balance the inlet pressure against the pressure of the tubs, the slurry is mixed in the blending tub


12


with the impeller rotating at approximately 600 rpm or greater and the inlet control valve


62


and outlet control valve


92


open. The conveyor augers


20


are activated, and particulate matter is transported from the hopper


16


to the distribution bin


24


. The particulate matter is then distributed to the blending tub


12


.




The slurry is passed through the slurry discharge manifold


100


and one or more of the discharge hose connectors


116


,


120


to a connected downhole pumping apparatus. The second tub


14


is operated at approximately the speed of the first tub before being filled with fracturing fluid and introducing the particulate matter. Once the fracturing fluid and particulate matter begin mixing, the inlet and outlet control valves


68


and


98


are opened on the second blending tub. The outlet pressures of the blending tubs


12


,


14


balance and equalize in the discharge manifold


100


, thus providing constant pressure to the downhole pump. The resulting constant outlet pressure from the tubs prevents the slurry from overflowing or exiting the tops of the blending tubs. The discharge pressure from the discharge manifold


100


is approximately


5


PSI greater than the pressure in the intake manifold


34


.




In the preferred embodiment of the invention, the slurry is mixed to a density of up to approximately 22 pounds of particulate matter per gallon of fracturing fluid. The discharge flow rate per blending tub is approximately 40 barrels per minute, with a combined flow rate of 80 barrels per minute for both blending tubs operated simultaneously. The discharge pressure is approximately 50-60 psi. Both blending tubs


12


,


14


remain in operation without the use of throttle valves, and no leveling of the blending tubs is required.




An apparatus that balances the pressures of multiple blending tubs while maintaining a constant balanced output pressure has been illustrated and described in detail. It is to be understood that details of the present invention may be modified without departing from the spirit thereof.



Claims
  • 1. A multiple tub blending apparatus for producing slurry for use in well servicing operations, said blending apparatus comprising:(a) a plurality of blending tubs, each of said tubs having a fracturing fluid inlet means and a particulate matter inlet means, an outlet means, and a mixing means for producing a slurry of fracturing fluid and particulate matter, said fluid and matter inlet means being connected to a source of fracturing fluid and a source of particulate matter, respectively; (b) a single discharge manifolding means for combining the discharges from the multiple blending tubs, balancing simultaneously the outlet pressures of said blending tubs and delivering a slurry of fracturing fluid and particulate matter from said blending tubs at a constant outlet pressure, said discharge manifolding means further including a discharge manifold pipe and individual pipe sections having approximately equal length for connecting the discharge manifold pipe to the outlet means of each of said blending tubs, said equal length pipe sections have approximately equal pressure drop which produces a substantially balanced and constant outlet pressure in said blending tub outlet means; and (c) connector means for connecting said discharge manifold pipe of the discharge manifolding means to a downhole pump apparatus, wherein the constant outlet pressure of the discharge manifolding means supports and stabilizes the inlet pressure of the downhole pump during well servicing operations.
  • 2. The blending apparatus as defined in claim 1, further including an intake manifold means for delivering fracturing fluid to said blending tubs, said intake manifold means being connected to said source of fracturing fluid and said inlet means of said blending tubs.
  • 3. The blending apparatus as defined in claim 1, wherein said blending tub includes a plenum space substantiality beneath said mixing means.
  • 4. The blending apparatus as defined in claim 3, wherein said plenum space is proximate to the outlet means of said blending tub.
  • 5. The blending apparatus as defined in claim 1, wherein said mixing means is an impeller which rotates about a vertical axis and is suspended from above.
  • 6. The blending apparatus as defined in claim 1, wherein each of said blending tubs includes a control valve on each of said inlet means and said outlet means.
  • 7. The blending apparatus as defined in claim 1, further comprising a loading means for depositing particulate matter in one or more of said blending tubs.
  • 8. The blending apparatus as defined in claim 7, wherein the loading means for depositing particular matter in one or more of said blending tubs is an auger type conveyor means.
  • 9. The blending apparatus as defined in claim 1, wherein said apparatus is mounted on a vehicle.
  • 10. The blending apparatus as defined in claim 1, further comprising a control means for controllably operating the charging and discharging of fracturing fluid and particulate matter in one or more of the blending tubs.
  • 11. The blending apparatus as defined in claim 1, wherein said mixing means includes an impeller which rotates about a vertical axis and is suspended from above, and said blending tub includes a plenum space substantially beneath said impeller.
  • 12. The blending apparatus as defined in claim 1, wherein said mixing means is an impeller which rotates about a vertical axis and is suspended from above, and wherein said blending tub includes a plenum space substantially beneath said impeller and proximate to the outlet means of said blending tub.
  • 13. The blending apparatus as defined in claim 1, further including an intake manifolding means for delivering fracturing fluid to said blending tubs, said intake manifolding means being connected between said source of fracturing fluid and said inlet means of said blending tubs, and the inlet means on each blending tub is connected to said inlet manifolding means by pipe sections having approximately the same length to provide substantially equal inlet pressures in said blending tubs during well servicing operations.
  • 14. A multiple blending tub apparatus for providing a slurry of fracturing fluid and particulate matter at a high flow rate for use in well servicing operations, said blending apparatus comprising a single discharge manifolding means for combining the discharges from multiple blending tubs, simultaneously balancing the outlet pressures of said blending tubs and delivering a slurry of fracturing fluid and particulate matter from said blending tubs at a constant outlet pressure, said apparatus including a plurality of blending tubs each having a centrifugal impeller spaced above the bottom of the tub forming a plenum space and a tangential outlet means adjacent to the plenum space for the discharge from each tub.
  • 15. The blending apparatus as defined in claim 14, further including separate pipe sections for connecting said blending tubs to said manifolding means, each of said pipe sections having approximately the same length to provide substantially equal pressures in said blending tubs during well servicing operations.
  • 16. The blending apparatus as defined in claim 14, further including an intake manifold means connected to a source of fracturing fluid, said intake manifold means delivers said fracturing fluid to said blending tubs.
  • 17. A dual tub blending apparatus for use in well servicing operations, said blending apparatus comprising:a) a pair of blending tubs, each of said tubs having a particulate matter inlet means, a fluid inlet means, a slurry outlet means, and a mixing means, the particulate matter inlet means including a distribution bin for storing the particulate matter and feeding the particulate matter to the individual blending tubs as needed, said bin being filled by a loading means which maintains an adequate supply of particulate matter in said bin; b) said fluid inlet means on each tub being connected by pipe sections having approximately the same length to an inlet manifold pipe which is connected to a source of fracturing fluid which is used in the well servicing operations; c) said slurry outlet means including a pair of individual pipe sections having approximately the same length connected to a slurry discharge manifold pipe for combining the discharges from the pair of blending tubs, balancing the outlet pressures of said blending tubs and delivering a slurry of fracturing fluid and particulate matter from said blending tubs at a constant outlet pressure to said discharge manifold pipe; d) said blending tubs each having an impeller which rotates about a vertical axis and is suspended from above leaving an open plenum space below said impeller, said slurry outlet means for each tub being attached to the tub in the general area adjacent to said plenum space; and e) connector means for connecting said slurry discharge manifold pipe to an inlet of a downhole pump apparatus, wherein the slurry constant outlet pressure from the discharge manifold pipe supports and stabilizes the inlet pressure of the downhole pump during well servicing operations.
  • 18. In a multiple blending tub apparatus for use in well servicing operations, each of said blending tubs comprising:a) a cylindrical tub having a side wall, an enclosed bottom and a partially open top; b) a particulate matter inlet means provided through said top; c) a fluid inlet means positioned in the side wall of said tub; d) a slurry outlet means positioned in the side wall and below the fluid inlet means; e) said tub having a centrally positioned impeller which rotates about a vertical axis and is suspended from above leaving an open plenum space between said impeller and the bottom of the tub, said impeller being driven by a suitable drive means; and f) the particulate matter is introduced into the tub through the top of the tub and into the impeller, wherein the particulate matter is mixed with a fluid entering the tub through the fluid inlet means producing a slurry of fluid and particulate matter which descends into the open plenum space and is discharged through the slurry outlet means which is adjacent the plenum space, whereby the outlet flow of the slurry is stabilized and balanced by said open plenum space.
REFERENCE TO RELATED PATENTS

This application claims the benefit of U.S. provisional patent application Ser. No. 60/077,170, filed Mar. 6, 1998.

US Referenced Citations (13)
Number Name Date Kind
2660415 Hawes Nov 1953
3050159 Paulus et al. Aug 1962
3295698 Ross et al. Jan 1967
4159180 Cooper et al. Jun 1979
4239396 Arribau et al. Dec 1980
4448535 West May 1984
4453829 Althouse, III Jun 1984
4490047 Stegemoeller et al. Dec 1984
4802141 Stegemoeller et al. Jan 1989
4850701 Stegemoeller et al. Jul 1989
4850702 Arribau et al. Jul 1989
4913554 Bragg et al. Apr 1990
4915505 Arribau et al. Apr 1990
Provisional Applications (1)
Number Date Country
60/077170 Mar 1998 US