Patent Application
20210189622
The present invention generally relates to a multipurpose machine, for universal use and relative methods for dyeing woven fabrics, knitted fabrics and warp yarns with an alternating stages batch system and with any dye, in particular with indigo and other vat dyes in an inert environment. More specifically, the present invention relates to an extremely advantageous and economical multipurpose machine for the ecological dyeing of denim fabrics and clothing in general with indigo and other vat dyes, using low and/or high concentration baths and at low or high temperatures.
Denim is the particular fabric used to make jeans, which being produced in about five billion pairs annually make this fabric quantitatively the most used in the world. Jeans had their origin in California as a work garment for the masses. The next stages of their development took them to the east of the United States and then to Europe and the rest of the world. Workwear turned into leisurewear, and from then on has continued to evolve and be refined.
Jeans dominate and win over all other types of trousers, not only because of their practicality and availability in a wide range of qualities and prices, but above all for their symbolic value and for the aura of meaning they carry.
First of all, because of history: as a poor, rebellious, rough, male American garment, thus something free and brave, it's part of their folk memory. Then there is that particular blue: a colour that in Western culture speaks of optimism and calm, nobility and work. But in jeans there is a particular colouring, worked in such a way as to dye progressively, which can therefore be positively changed over time, unlike any other fabric, and thus inviting inscriptions, tears, discolouration, coloured patches and embroideries. Another important factor is the denim fabric: strong, tenacious, able to withstand any ill-treatment, but natural, yielding, able to adapt to the body, and also having memory.
The success of the combination of denim and blue jeans is due to the particular construction of this fabric, of which only the warp is dyed with indigo, while the weft is raw cotton. Indigo is one of the oldest dyes, not easy to apply to cotton, for which it has little affinity, but it has a unique characteristic that, after washing, makes the fabric and consequently the garment shiny and pleasing over time. As far as we aware, no other dye has this property. The above-mentioned special feature, together with the impression of a worn garment, which is highlighted by abrasion in the most exposed areas and which creates a plastic effect on the body of the wearer, is responsible for the charm of blue jeans, which are and will remain the most sold ready-made garment in the world, made and treated in many ways.
Unfortunately jeans have an unfortunate record throughout the clothing sector: that of the garment that gives rise to the worst environmental and social impact. The cycle for the creation of blue jeans, from the cultivation of cotton to the point of sale, requires very high consumption of water and energy, as well as the use of chemicals in different stages of production, which then end up in the environment or in contact with consumers.
One of the characteristics of indigo dye, which makes it unique, is the special method of dyeing required for its application to cotton yarn. Due to its relatively small molecule and low affinity for cellulose fibre, to be applied this dye not only must be chemically reduced in alkaline solution (leuco), but also needs to undergo a plurality of impregnations interspersed with wringing out and subsequent oxidation in air. In practice, a medium or dark colour shade is obtained only by subjecting the yarn to initial dyeing (impregnation, squeezing, oxidation) followed immediately by more over-dyeing steps, the more numerous of which the darker the shades and the higher the required colour-fastness.
This particular method of dyeing, typical of indigo dye, highlights the enormous importance of complying with certain basic parameters relating to dipping and oxidation times. This allows the dye to impregnate and be evenly distributed in the cortical or surface layer of the yarn (“ring dyeing”) and, after being perfectly squeezed, to be completely oxidised before entering the next tank, so as to be able to “accumulate”, i.e. intensify the colour shade. Unfortunately, in addition to these parameters, continuous dyeing with indigo is also influenced by many other factors relating to the different physical-chemical contexts of each individual dyeworks, as well as the environmental conditions where such plant is installed, such as the temperature and relative humidity of the air, windyness, altitude, etc. In addition, the different dyeing conditions (such as number of tanks, their capacity, pick-up, type and speed of circulation of the dye bath, type and precision of automatic dosing systems for indigo, sodium hydrosulphite and caustic soda, etc.) and the different dye bath conditions (such as temperature, concentration, pH, Redox potential, etc.) not only have a decisive influence on the results of dyeing (such as greater or lesser intensity of dyeing, fastness, depth of penetration, etc.), but also contribute significantly to determining the final appearance of jeans after the various washing and finishing treatments to which they are normally subjected. It should also be stated that, unlike other groups of dyes for which affinity for cotton increases with increasing temperature, for indigo, affinity and intensity of colour, the latter due to greater depth of penetration of the dye, increase with decreasing temperature.
It is therefore clear that the most important operation governing the entire production cycle of denim fabrics is the continuous dyeing of warp yarns with indigo dye and/or other vat dyes before they are placed in a loom for the production of fabric. Classic denim is in fact made by weaving pre-dyed cotton yarns. In particular, only the warp is dyed, while the weft is used untreated.
The continuous indigo dyeing of warps for denim fabrics is mainly carried out according to two systems, namely the so-called “rope” system and the so-called “loop” or “slasher” systems, in lines of considerable complexity, length and cost. The two systems mentioned above, although substantially different, in the case of indigo dyeing nevertheless have the same common feature—use of the same dyeing method, consisting essentially of three operational stages that are repeated several times: impregnation of the yarn with leuco, squeezing to eliminate the excess dye bath and oxidation of the dye by exposing the dyed yarn to air.
Typically and traditionally, in both the rope and slasher systems the indigo dyeing of warps for denim fabrics is carried out in open low-temperature tanks. In detail, in the two systems, the systems for the continuous dyeing with indigo normally comprise 3-4 pre-treatment tanks, 8-10 dyeing tanks and 3-4 final washing tanks. All the tanks are equipped with a squeezing unit to eliminate the excess dye and wash baths, while the dyeing tanks are also equipped with groups of rollers for oxidising the yarn in air.
The dyeing tanks are of an open type, each having a capacity ranging between 1,000 and 4,000 litres, drawing in about 4-11 metres of yarn. These quantities of dye bath determine the total volume of bath circulating in the plant, which can therefore vary from about 10,000 to 40,000 litres. The dye bath present in each tank is continuously recirculated to ensure uniformity of concentration in each tank. This recirculation is normally carried out by various known piping systems, with high-flow and low-head centrifugal pumps to avoid harmful turbulence. Movement of the dye bath causes the surface part of the bath itself, which is in contact with the air, to be continuously replaced. Moreover, as the tanks are open at the top, this movement of the dye bath causes oxidation. Oxidation of the dye bath results in continuous depletion of the reducing agents present in it, i.e. sodium hydrosulphite and caustic soda, said depletion increasing the higher the temperature of the dye bath.
However, it is the multiple oxidation stages that contribute much more than mentioned above to impoverishing these components (sodium hydrosulphite and caustic soda) in the dye bath with which the yarn is impregnated. These oxidation stages are an integral part of the dyeing cycle and in practice comprise exposing about 30-40 metres of yarn impregnated with leuco to air between one tank and another of the 8-10 dyeing tanks in the plant. Overall, the yarn is therefore exposed to air for several hundred metres throughout the dyeing plant.
On the basis of the above, there is a need to continuously replenish the dye bath with the quantities of sodium hydrosulphite and caustic soda destroyed by the above oxidations, so that the dye bath is constantly maintained under optimum chemical conditions for best dyeing performance and to guarantee constant and reproducible results. These continuous additions to the dye bath constitute a significant economic cost, increase the salinity of the dye bath itself, with consequent dyeing problems, and also give rise to significant pollution of the final wash water.
Of course dye must also be continuously and constantly added to the dye bath, in the concentrated leuco condition, in the quantities necessary to obtain the desired colour shade. Various systems can be used for the automatic continuous dosing of indigo dye, sodium hydrosulphite and caustic soda, such as dosing pumps, weighing systems, volumetric systems, weight-related systems, etc., all of which are in any case known as they are normally used in other textile processes. Logically, the larger the volume of the dye bath, the longer it will take to bring a new dye bath to the chemical/dye balance needed to achieve the same colour shade consistently. The response time to possible corrective measures will also be long, and this does not help achieve quality.
Another special feature of indigo dye is the fact that dye baths with this dye are never replaced, except to change the intensity of the dye. As already mentioned, indigo dye baths are instead continuously reused with the addition of sodium hydrosulphite, caustic soda and dye to maintain their chemical/dyeing balance constant. Each dyeing plant therefore has a particular number of containers with the total capacity of all the dyeing tanks, equal to the number of blue variants in production. These containers are used to store and reuse dye baths.
For qualitative purposes it is of the utmost importance to be able to maintain the physical-chemical conditions of the dye bath constant for as long as it takes to dye an entire batch of yarn. The average time is between 15 and 30 hours, depending on the length of the yarn and the dyeing rate. Unfortunately, despite continuous mechanical and hydraulic improvements to dyeing plants and the aid of sophisticated control and dosing systems, because of the large volumes involved, as well as the many causes described above which individually or in conjunction with each other can help to create undesirable changes in the conditions of the dye bath, continuous dyeing with indigo remains a complex operation. Of the various stages in the production cycle, the dyeing stage is therefore the one that predominantly contributes to determining the quality of the final fabric, its grading and therefore the higher or lower selling price.
In addition to the above, in the slasher dyeing system, the length of the yarn fed into the dyeing line, which can reach about 500-600 metres, makes it difficult to control the plant. In the slasher system there is also an economic disadvantage due to the quantity of yarn lost at each batch change. In this operating condition, in fact, all the amount of yarn constituting the tail of the batch, the dyeing of which is finished and which remains in the plant after it has stopped, must be considered lost, as it is not uniformly dyed. Similarly the same quantity of yarn that constitutes the start of the next batch and which, connected to the tail yarn, also replaces it in the draw-in to the dyeing plant (at low speed for technical and safety reasons), is not uniformly dyed and must therefore be disposed of.
Unfortunately, economic crises, great competition, various social, political and ecological problems, relocations of production, generational changes and changes in fashion, together with general impoverishment with a consequent reduction in purchasing power and other reasons, are contributing to an inevitable fall in income and therefore require substantial changes in the denim production chain. Moreover, identical jeans with a uniform appearance and without any particular need for finishing, contrast, etc., have become an important fashion product, which requires continuous diversification in the production of denim fabric, made in different weights, in different weaves, with yarns of various counts, cotton or blends and other fibres, in many shades of colour, etc. For these reasons denim producers are therefore forced not only to maximise and continuously diversify the number of fabric types on offer, but also to produce them faster, in ever shorter runs and at ever lower prices, with significant erosion of profitability.
Never before has innovation and cost reduction been more essential to maintain or gain market positions in the sector and to recover from competitive disadvantages in such a globalised context. These are innovations not so much in the product or the materials themselves, but in methods of production. Also, instead of the classic rhythm of work based on times and seasonal collections, new and fast operational flexibility is needed to adapt, in real time, to the ever increasing needs of the market, of fashion, etc. All this because the “brands” buying the fabric in turn want to avoid long delays between the presentation of collections and the delivery of ready-made garments at points of sale, as these long times may entail a series of errors in assessing the product, colours and trends, while it is essential to reach the market at the right time with the right product.
For denim producers the only way to lower costs and reduce delivery times to a minimum is to change part of their output into raw fabric, to be kept always ready in the warehouse so that they only have to finish it, dyeing it immediately from time to time in the lengths and colours expressly requested by customers. In the light of the above it is clear that denim producers are now faced with imperative economic and business needs to change the production system, to increase operational flexibility, to add the possibility of dyeing raw denim to shorten delivery times, reduce costs and waste, and to be able to recover defective batches, as well as to make innovations in their conventional dyeing machinery to reduce energy, water and chemical consumption, to minimise waste, in other words to do everything that can help the presentation of a new product, at a lower cost, more economically, but at the same time ecologically and respecting environmental sustainability, a subject of increasing attention throughout the world. With regard to ecology, an international law enforcing a reduction in consumption and compliance with specific rules for the protection of health and the environment is not unlikely; indeed it is now required, or considered hopefully to be close, by many consumer-protection bodies.
In the specific sector of the continuous dyeing of warps for denim fabrics with indigo, machines have already been developed to meet most of the above requirements. The dyeing machines operating in this new and original working condition, i.e. in an inert environment (e.g. due to the presence of nitrogen), make it possible to eliminate many of the problems of the traditional dyeing system, in comparison with which they have the advantage of not only being able to halve the number of dyeing tanks, but also of drastically reducing the consumption of caustic soda and sodium hydrosulphite (by 50% to 80%). Also, as there is better fixing of the dye to the yarn, there is also a significant saving of wash water. Furthermore, in an inert environment (e.g. under nitrogen) the chemical reduction of indigo is total and complete and the leuco is broken down into nanoscale particles that increase its dyeing capacity. This increased dyeing capacity of leuco permits better penetration and better fixing of the dye to the fibre in comparison with the traditional dyeing system, with advantageous dyeing results in terms of colour-fastness, intensity and brightness, differences that qualitatively improve the final fabric. Moreover, experience gained with the above new technology has shown that in dyeing with sulphur-based dyes, which is the most expensive in energy terms, in particular for black, there is a higher colour yield, which can be visually evaluated to be around 40%, with much better fixing and with better brightness compared to dyeing in traditional machines.
Dyeing machines according to the known art, operating in an inert environment, are described for example in U.S. Pat. No. 6,355,073 B1 and US 2005/028303 A1. Document GB 1,107,035 A describes a so-called “jigger” dyeing machine, the operation of which will be explained in more detail below.
To sum up, there are two major improvements to be made in the denim production sector. The first, the most useful and by now almost essential, is the possibility of having a new dyeing machine operating in both the traditional way and in accordance with the concept and all the advantages of dyeing machines operating in an inert, simple, practical and multi-purpose environment which, for a modest investment in comparison with traditional continuous dyeing lines with indigo and other vat dyes, can dye raw denim and even warp yarns in an alternating stage batch system, in an ecological and economic way. The second improvement would be to replace the present classic continuous dyeing lines for fabrics and warp yarns with indigo and other vat dyes in air, with new dyeing lines in an inert environment, with all the inherent economic, ecological and qualitative advantages.
Unfortunately, for the social and economic reasons already mentioned, it is very unlikely, if not impossible, that the approximately one thousand continuous lines for dyeing yarn fabrics and warps with indigo and other vat dyes in air that are in operation in the world, even if largely obsolete, but very large, very expensive and complex in terms of plant engineering, will be replaced in a reasonably short time with new lines operating in an inert environment, meeting current needs. And it is equally unlikely, if not impossible, that denim producers will consider installing special long, complex, demanding and above all expensive continuous dyeing lines, because of the new requirement of being able to dye only some of output reserved as raw fabrics. It is instead logical to think of meeting the urgent need to reduce costs and consumption, as well as increasing operational flexibility at the same time, with a much more concrete and feasible solution comprising placing a new fabric dyeing machine alongside their current continuous warp dyeing machines. This new dyeing machine will operate in batch mode in alternate stages, preferably in an inert environment, i.e. in an economic and ecological way. This new dyeing machine will be short, simple, practical and multipurpose, but above all considerably cheaper than a continuous dyeing line.
The object of this invention is therefore to be able to provide both a machine and a multipurpose dyeing module with a system of alternating batch stages, using any dye, in particular indigo and other vat dyes in an inert environment, with a diversifiable structure, of universal application, which can be used independently, for dyeing raw (“ready to dye”) fabrics, for dyeing any other woven and knitted fabric and also warp yarns, wound on any type of support or in appropriate containers. In particular the multipurpose dyeing module according to the present invention can be used independently for batch dyeing the increasingly requested small lengths of denim fabric with indigo and other vat dyes in alternating stages in an inert environment, for over-dyeing dyed denim and for dyeing woven and knitted fabrics and warp yarns. Alternatively, these fabrics may also be dyed with all other classes of dyes.
Another object of the present invention is to provide a multipurpose dyeing module that is able to operate in an inert environment, enabling a significant reduction in the normal consumption of sodium hydrosulphite and caustic soda in the batch dyeing of fabrics and warp yarns with indigo and other vat dyes.
Another object of the present invention is to provide a multipurpose dyeing module in an inert environment that enables fabrics and warp yarns to be dyed with indigo and other vat dyes in a discontinuous way, under the most technologically optimum conditions, and that enables diffusion and fixation of the dye to the fibre to be increased with a reduction in the consumption of wash water, so as to contribute to the sustainability of production.
These objects according to the present invention are accomplished by creating appropriate different versions of a multipurpose dyeing machine or module for universal use according to different needs, which can be matched to different demands, for the dyeing of woven and knitted fabrics and warp yarns, as set out in claim 1.
Further features of the invention are revealed by the dependent claims, which are an integral part of this description.
For denim producers the availability of this new multipurpose dyeing machine would enable them to reduce the normal quantity of finished denim fabric stored in the warehouse (which with changing fashion is likely to quickly become unsaleable, except through a significant price reduction), replacing it with an equal quantity of raw denim, and as a consequence to achieve:
The multipurpose dyeing machine according to the present invention is the result of a combination between the dyeing process in an inert environment, reworking of the more than one-hundred-year-old conventional fabric dyeing technology on a “jigger”, with which it only shares the fact of having a similar alternating movement of the fabric, and the particular system of feeding/circulating/dosing the bath typical of continuous lines for dyeing with indigo and other vat dyes.
The “jigger” is in principle a “roll to roll” machine, i.e. a machine where the fabric processed unrolls from one roll to wind onto another roll, with the actual processing taking place between the two rolls. This machine comprises two winder/unwinder rolls, the distance between centres of which determines the maximum winding diameter of the fabric, placed on top of a small tank with a short length drawn in. The fabric to be processed is initially wound onto one of the two rolls and then passed through the dye bath several times, slashing, unrolling and rewinding onto the other roll and then vice versa, an operation that is carried out in contact with the air. After dyeing the fabric is washed in the same number of steps to eliminate any excess unfixed dye. Finally, the fabric has to be unloaded from the machine and dewatered to eliminate excess water, and then proceeds to the subsequent processes of drying and finishing.
Substantially the multipurpose dyeing machine according to the present invention comprises a number of known elements placed upstream or downstream of an original and new multipurpose module of universal applicability for dyeing fabrics of all kinds, as well as warp yarns, with indigo and other vat dyes in an inert environment through a batch system with alternating stages. In practice the operation of this new machine comprises unwinding the fabric, preferably already prepared for dyeing, from a first roll, passing it through the multipurpose dyeing module in the prescribed manner and, after oxidising it, rolling it up onto the second winder and then possibly repeating the operating cycle in the opposite direction for the number of times necessary to obtain the required result.
The multipurpose dyeing machine according to the present invention differs substantially from a “jigger” in many aspects, in design, construction and operation, as well as in that it works in an inert environment. Dyeing with indigo and other vat dyes in an inert environment is ecological and economic, as it enables production costs to be reduced through saving time, energy, chemicals and water, as well as through greater functional flexibility, also ensuring results of unparalleled quality, with a high degree of dye penetration and fixation which is unattainable in traditional air dyeing. Like the known type of machines operating in an inert environment, this machine can work with low and/or high temperature baths and also with low and/or high concentrations of dye, a characteristic that helps to determine the number of dyeing stages and therefore the variations in production capability. It should be noted that in addition to use in the important sector of fabric dyeing this machine also adds the possibility of use for dyeing small batches of warp yarn that may be dried if necessary and in any case sized separately.
It should be noted that, with regard to warp yarn dyeing alone, this new machine can also be supplemented with at least two additional motorised stations (one on the right and one on the left) for winding/unwinding another two rolls of warp yarn, so as to be able to dye two warps at the same time, one overlapping the other. This particular working arrangement not only doubles production capacity, but also increases quality since the greater compactness of the yarn belt allows more efficient and uniform squeezing, with consequent elimination of the problematic defective dyeing between the centre and the selvedges.
The construction of the multipurpose dyeing machine according to the present invention is simple, economical, rational and functional. This machine is of universal application and adds the new dyeing technology in an inert environment, with all its strengths and advantages, to the possible traditional dyeing technology of fabrics and warps with indigo and other vat dyes in air. All this without the consumption of inert gas during the operating stages, but only in the initial stage of inerting. It should be noted that the special construction and functional feature of this machine, apart from operating in an inert environment, comprises being able to perform several consecutive dyeing operations with indigo, as in traditional continuous dyeing machines, so that the dye can accumulate to achieve darker colour shades and greater colour-fastness, operations that are not possible with the traditional “jigger”, as the “jigger” has no intermediate squeezing and oxidation systems between one dyeing operation and the next. Specifically, this is a new machine that helps to make batch dyeing of fabrics and warps with indigo and other vat dyes undoubtedly the most responsive to all current and future technological and economic needs, as well as the greatest requirements for environmental sustainability. It should also be noted that this machine is the shortest ever machine for dyeing fabrics and warps with indigo and other vat dyes.
The characteristics and advantages of a machine for the batch dyeing of fabrics and yarns, using alternating stages and any dye, in particular in an inert environment and with indigo and other vat dyes, according to the present invention will be more apparent from the following description by way of example and without limitation, with reference to the attached diagrammatical drawings in which:
It should be noted that the following description and the attached figures do not illustrate many components, accessories and instrumentation normally supplied for this type of dyeing machine, such as devices for spreading and guiding fabrics, inerting, feeding, unloading, heating, automatic dosing, level adjustments, etc., as these are well known to those skilled in the art.
A multipurpose dyeing machine according to the present invention is shown with reference to the figures. The dyeing machine comprises in sequence at least one dyeing module 10 within which the following components are present in sequence:
The first treatment tank 14, the central tank 16 and the second treatment tank 18 are preferably enclosed by a hermetically sealed covering shell 22, located above the dyeing module 10. The first treatment tank 14 and the second treatment tank 18 have preferably the same shape and the same dimensional and capacity characteristics. In addition, the first treatment tank 14 and the second treatment tank 18 are preferably symmetrical to a plane of symmetry P lying in the central tank 16 and arranged perpendicularly to the direction of the forward movement of the textile support 100. The dyeing machine is therefore equipped with moving means configured to move the textile support 100 forward alternately in both directions, that is either from the first squeezing device 12 to the second squeezing device 20 sequentially through the first treatment tank 14, the central tank 16 and the second treatment tank 18, or from the second squeezing device 20 to the first treatment tank 12 sequentially through the second treatment tank 18, the central tank 16 and the first treatment tank 14.
In the embodiment in
The means for moving the textile support 100 may comprise at least one pair of motorised stations 36, 38 for controlled winding/unwinding of the fabric or yarn 100 onto/off the respective rolls. In particular, with reference to the embodiment in
Each of the first treatment tank 14, the central tank 16 and the second treatment tank 18 is internally equipped with a plurality of return rollers 54, configured to position the textile support 100, which is in discontinuous movement, in a plurality of vertical planes parallel to each other. In particular at least some of these return rollers 54 can be moved in a vertical direction to change the way the textile support 100 is drawn into the dyeing module 10, as will be more particularly specified below.
In the embodiment in
This embodiment, having one more multipurpose dyeing module 10 than the previous embodiments in
The embodiment in
In the embodiment in
Regardless of the form of construction, in comparison with traditional “jiggers” the multipurpose dyeing machine according to the present invention is further equipped with:
As a consequence, always in comparison with a traditional “jigger”, the multipurpose dyeing machine according to the present invention makes it possible to obtain the following operating advantages:
The multipurpose dyeing module 10 in
The multipurpose dyeing module 10 in
The multipurpose dyeing module 10 in
Finally, the multipurpose dyeing module 10 in
It will therefore be seen that the multipurpose dyeing machine with an alternating stage batch system for fabrics and warp yarns according to the present invention has accomplished the objects set out above. The multipurpose dyeing machine with an alternating stage batch system for fabrics and warp yarns, preferably with indigo and other vat dyes, according to the present invention accomplishes the objects mentioned in the preamble of the description. It should be noted that in order to have maximum flexibility in the final result, in terms of ring dyeing and the dye's depth of penetration and fixation, in addition to the known physical/chemical variables, the above machine is also designed to vary the bath-fibre contact time by reducing the level of the dyeing tanks and/or the length of the immersed fabric and/or yarn, by changing the draw-in, including in the diffusion/fixing area. The multipurpose dyeing machine according to the present invention also offers the possibility of dyeing small batches of fabric and yarn, i.e. the small batches of yarn that are increasingly in demand on the market. It should also be noted that, for the sake of simplicity of explanation, both in the preamble and in the description the term ‘rolls’ has been used indiscriminately for both fabrics and warp yarns. In the case of yarns, it is in fact intended that they may also be presented flat, on one or more reels, bobbins, etc., or as ropes, as one or more “balls”, or even in layers, in appropriate containers. The multipurpose dyeing machine with an alternating stage batch system for fabrics and warp yarns according to the present invention conceived in this way is in any event susceptible of numerous modifications and variations, all falling within the same inventive concept; moreover, all details may be replaced by technically equivalent elements. In practice, any materials as well as any shapes and dimensions may be used, depending on technical needs. The scope of protection of the invention is therefore defined by the appended claims.
| Number | Date | Country | Kind |
|---|---|---|---|
| 102018000008544 | Sep 2018 | IT | national |
| Filing Document | Filing Date | Country | Kind |
|---|---|---|---|
| PCT/IB2019/056439 | 7/29/2019 | WO | 00 |
