The present invention relates to an apparatus for producing nanofibers and a nozzle head used for the same.
A conventional apparatus for producing nonwoven fabrics is disclosed in Patent Document 1. This apparatus for producing nonwoven fabrics comprises, as shown in
This melt blow unit 911 is provided a resin passage 912 for flowing the molten resin, and hot blast passages 913a and 913b. These hot blast passages 913a and 913b are provided on each side of the resin passage 912 with inclination toward the resin passage 912. The hot blast from the hot blast passages 913a and 913b is sprayed to the molten resin spun from the resin passage 912 thereby.
Patent Literature 1: JP2010-185153A
In the above-mentioned apparatus for producing nonwoven fabrics, however, the hot blast passages 913a and 913b of the hot blast passage 913 is formed with inclination toward a lower surface 911a. When the hot blast passages 913a and 913b are formed by a drill, the drill is obliquely contacted the lower surface 911a. Therefore, a top of the drill may slip on the lower surface 911a, and it is difficult to form the hot blast passages 913a and 913b precisely. In order to ensure the precision, it has been necessary to use electrochemical machining having a high cost.
The present invention was made in consideration of the above problems, and an object of the present invention is to provide an apparatus for producing nanofibers and a nozzle head use for the same which can manufacture by drilling and efficiently carry molten resin on a gas flow.
According to the present invention, there is provided an apparatus for producing nanofibers comprising a raw material discharge surface on which a raw material flow passage for discharging a liquid raw material is arranged, and a gas discharge surface which is arranged with an angle α (0<α≤90°) toward said raw material discharge surface and on which a gas flow passage for ejecting gas is arranged, wherein said raw material flow passage is orthogonal to said raw material discharge surface, said gas flow passage is orthogonal to said gas discharge surface, and said raw material flow passage and said gas flow passage are arranged so that said liquid raw material discharged from said raw material flow passage meets gas ejected from said gas flow passage.
According to the present invention, there is provided an apparatus for producing nanofibers comprising a raw material discharge surface on which a raw material flow passage for discharging a liquid raw material is arranged, a gas discharge surface which is arranged downwardly from said raw material discharge surface and on which a gas flow passage for ejecting gas is arranged, a connecting surface which is connected with said raw material discharge surface and said gas discharge surface, and is arranged with an angle β(0≤β<90°) toward said raw material discharge surface, wherein said raw material flow passage is orthogonal to said raw material discharge surface, said gas flow passage is orthogonal to said gas discharge surface, an opening of said gas flow passage contacts with said connecting surface, and said raw material flow passage and said gas flow passage are arranged so that said liquid raw material discharged from said raw material flow passage reaches to the opening of said gas flow passage along said connecting surface.
According to the present invention, there is provided a nozzle head used for an apparatus for producing nanofibers comprising: a raw material discharge surface on which a raw material flow passage for discharging a liquid raw material is arranged, and a gas discharge surface which is arranged with an angle α (0<α≤90°) toward said raw material discharge surface and on which a gas flow passage for ejecting gas is arranged, wherein said raw material flow passage is orthogonal to said raw material discharge surface, said gas flow passage is orthogonal to said gas discharge surface, and said raw material flow passage and said gas flow passage are arranged so that said liquid raw material discharged from said raw material flow passage meets gas ejected from said gas flow passage.
According to the present invention, there is provided a nozzle head used for an apparatus for producing nanofibers comprising: a raw material discharge surface on which a raw material flow passage for discharging a liquid raw material is arranged, a gas discharge surface which is arranged downwardly from said raw material discharge surface, and on which a gas flow passage for ejecting gas is arranged, a connecting surface which is connected with said raw material discharge surface and said gas discharge surface, and is arranged with an angle β (0≤β90°) toward said raw material discharge surface, wherein said raw material flow passage is orthogonal to said raw material discharge surface, said gas flow passage is orthogonal to said gas discharge surface, an opening of said gas flow passage contacts with said connecting surface, and said raw material flow passage and said gas flow passage are arranged so that said liquid raw material discharged from said raw material flow passage reaches to the opening of said gas flow passage along said connecting surface.
According to the present invention, a raw material flow passage is formed so as to be orthogonal to a raw material discharge surface, and a gas flow passage is formed so as to be orthogonal to a gas discharge surface. Therefore, the raw material flow passage is formed on the raw material discharge surface by drilling and the gas flow passage is formed on the gas discharge surface. It becomes possible to join directly or indirectly with an angle the liquid raw material discharged from the raw material flow passage to a gas flow ejected from the gas flow passage through a connecting surface connected to the raw material discharge surface and the gas discharge surface. It can be achieved to manufacture precisely by drilling and to carry efficiently the liquid raw material on the gas flow.
The preferred embodiment of the present invention will be described hereinafter. The present invention is easily applicable to a structure other than the description of embodiments of the present invention within a scope not inconsistent with an object of the invention.
According to the present invention, nanofibers are formed by supplying a liquid raw material to gas ejected under relatively high pressure. In the description, a term “gas” without specifying composition means gases consisting of any composition and a molecular structure. Additionally, in the description, a term “raw material” means all of materials applicable for forming the nanofibers. In the embodiments hereinafter, an explanation will be made for an example using synthetic resin as the “raw material”, but not limited to, various kinds of composition material will be usable.
A term “liquid raw material” in the description does not limit property of the material to liquid. The “liquid raw material”, for example, includes “solvent” which is prepared by dissolving in advance a solid raw material or a liquid raw material as a solute in a predetermined solvent so that a predetermined concentration is obtained. Additionally, “liquid raw material” also includes “molten raw material” which the solid raw material is molten. In short, the “liquid raw material” of the present invention needs property having viscosity enough to supply (eject, discharge) “raw material” from supply holes (ejection holes, discharge holes), and the “raw material” having such liquid property is described as “liquid raw material” in the present invention.
A basic concept of the present invention is, as shown in (I)
Additionally, as shown in (II)
Accordingly, the liquid raw material discharged from the raw material flow passage 25 is directly as shown in
In
Herein, the axis line P of the raw material flow passage 25 has an angle α against the axis line Q of the gas flow passage 26. The raw material supply tangent angle α is obtained from the following Equation
tan α=d/(b−a)
wherein
0≤θ<90°
The raw material supply tangent angle α should be determined by the distance “a”, the distance “b”, and the distance “d”, and moreover, should be determined by relation among the opening diameter “c” of the high-pressure gas, pressure and temperature of the ejected gas the gas flow passage 26.
Regarding an arrangement condition of the raw material flow passage 25 and the gas flow passage 26, it is also capable of forming nanofibers having an ununiformed diameter or fiber length by changing the number of passages, an arrangement interval, an arrangement distance (distance “a” from the gas ejection hole), an arrangement angle (angle α), and a diameter of the flow passage. According to types of the produced nanofibers, the arrangement condition of the raw material flow passage 25 and the gas flow passage 26 may be appropriately selected and changed.
Hereinafter, an apparatus for producing nanofibers according to a first embodiment of the present invention will be described referring to
The apparatus for producing nanofibers 1 of the first embodiment uses a solvent which is prepared by dissolving in advance a solid raw material or a liquid raw material as a solute in a predetermined solvent so that a predetermined concentration is obtained.
As shown in
As shown in
The nozzle head 20 comprises the raw material flow passage 25 orthogonal to the raw material discharge surface 22, and the gas flow passage 26 orthogonal to the gas discharge surface 23. The raw material flow passage 25 is communicated with a raw material supply passage 28 orthogonal to the back surface 27 in the nozzle head 20. The gas flow passage 26 is provided so as to linearly penetrate the gas discharge surface 23 and the back surface 27.
In the present embodiments, the raw material flow passage 25 has a cylindrical space (every cross sectional orthogonal to the axis line has the same circular shape), and the gas flow passage 26 also has the cylindrical space. The raw material discharge surface 22 has a width (a length in up and down direction of
An opening on the back surface 27 of the raw material supply passage 28 is connected with a hose 12, and a solvent provided from a solvent storage 11 is passed through the hose 12, the raw material supply passage 28 and the raw material flow passage 25, and discharged from the opening of the raw material flow passage 25 on the raw material discharge surface 22.
The opening on the back surface 27 of the gas flow passage 26 is connected with the gas ejection unit 13, and high-pressure gas supplied from the gas ejection unit 13 is passed through the gas flow passage 26 and discharged from the opening of the gas flow passage 26 on the gas discharge surface 23.
The such structure is only an example, and if there are provided the raw material flow passage 25 and the gas flow passage 26 orthogonal to the raw material discharge surface 22 and the gas discharge surface 23 which are arranged with an angle α (0<α≤90°), respectively, the stricture may be optional within a purpose of the present invention. In the present embodiment, the nozzle head 20 is directly connected with the hose 12 and the gas ejection unit 13. For example, however, a manifold block connected with the hose 12 and the gas ejection unit 13 may be provided on a side of the back surface 27 of the nozzle head 20. In such structure, the nozzle head 20 may be detachable to the manifold block, and the raw material and gas may be supplied to the nozzle head 20 from the hose 12 and the gas ejection unit 13 through the manifold block.
A description will be made of operation of the apparatus for producing nanofibers 1 and the nozzle head 20 according the present embodiments. The apparatus for producing nanofibers 1 is supplied with the solvent from the solvent storage 11 and discharges from the opening of the raw material flow passage 25 on the raw material discharge surface 22. The apparatus for producing nanofibers 1 is supplied with the high-pressure gas from the gas ejection unit 13 and ejects the same from the opening of the gas flow passage 26 on the gas discharge surface 23. The solvent discharged from the raw material flow passage 25 meets the gas flow ejected from the gas flow passage 26 with the angle α and is carried out in the front direction while being elongated, so that the nanofibers are manufactured.
According to the apparatus for producing nanofibers 1 and the nozzle head 20 of the above-mentioned embodiment, the raw material flow passage 25 is arranged so as to be orthogonal to the raw material discharge surface 22, and the gas flow passage 26 is arranged so as to be orthogonal to the gas discharge surface 23. Thereby, by drilling, the raw material flow passage 25 can be formed on the raw material discharge surface 22, and the gas flow passage 26 can be formed on the gas discharge surface 23. The solvent discharged from the raw material flow passage 25 directly meets the gas flow ejected from the gas flow passage 26 with the angle α.
It can be achieved to manufacture precisely by drilling and to carry efficiently the solvent on the gas flow.
The apparatus for producing nanofibers 1 of the present embodiment is capable of establishing the structure without using a complicated device, such as a heating cylinder, a motor, a screw and so on because the solvent which is prepared by dissolving the raw material in the solvent. Therefore, size of the apparatus becomes small and mounting space is saved. The structure of the apparatus becomes compact, so that it may be achieved to realize a portable the apparatus for producing nanofiber. The portable-type apparatus for producing nanofibers is configured to spray nanofibers toward a place where the nanofibers should be adhered and the nanofibers are formed. Use of the nanofibers may be expanded by using such portable-type apparatus.
The first portion 20a of the nozzle head 20H of the variation 8 is a rectangular parallelepiped which a one side is chamfered, the front surface 21 and the raw material discharge surface 22 (corresponding to the chamfered portion) are connected in order in the downward direction, and the raw material flow passage 25 is provided orthogonally to the raw material discharge surface 22. The second portion 20b is a rectangular parallelepiped, the gas discharge surface 23 is provided at the entire front surface, and the gas flow passage 26 is provided orthogonally to the gas discharge surface 23. When the first portion 20a and the second portion 20b are connected, the raw material discharge surface 22 and the gas discharge surface 23 are arranged with the angle α. The nozzle head 20H of the variation 8 has a structure which the first portion 20a and the second portion 20b are detachable, and has the same structure of the basic structure of the nozzle head 20 when these portions are not connected.
The first portion 20a of the nozzle head 20J of the variation 10 is configured so that a shape is rectangular parallelepiped, the front surface 21 is provided at the entire front surface thereof for facing the front side (a front side of a paper of
In Table 1, an outline of the basic structure and the structures of the variations 1 to 15 of the nozzle head 20 according to the Embodiment 1.
Hereinafter, an apparatus for producing nanofibers according to a second embodiment of the present invention will be described referring to
The apparatus for producing nanofibers 2 of the second embodiment (not illustrated) comprises the nozzle head 20U instead of the nozzle head 20, however, other structure is the same as of the apparatus for producing nanofibers 1 of the first embodiment in
The nozzle head 20U of the apparatus for producing nanofibers 2 of the second embodiment comprises the raw material discharge surface 22 facing the front side (front side of a paper of
The nozzle head 20U comprises the raw material flow passage 25 orthogonal to the raw material discharge surface 22, and the gas flow passage 26 orthogonal to the gas discharge surface 23. The raw material flow passage 25 is configured to linearly penetrate the raw material discharge surface 22 and a back surface. The gas flow passage 26 is also configured to linearly penetrate the gas discharge surface 23 and the back surface 27. The axis line P of the raw material flow passage 25 and the axis line Q of the gas flow passage 26 are provided so as to be on a plane.
The connecting surface 24 and the gas discharge surface 23 are arranged with an angle β (0≤β<90°), and the connecting surface 24 faces an oblique upward direction. In order words, a surface direction R of the connecting surface 24 and the axis line Q of the gas flow passage 26 has an angle α (α=90−β). The nozzle head 20U is configured to intersect the surface direction R and the axis line Q at a point in front of the nozzle head 20U with an angle α from a side direction (a front side to a back side of
According to the present embodiment, the raw material flow passage 25 and the gas flow passage 26 have cylindrical spaces (cross sections orthogonal to the axis lines are entirely same), respectively. Alternatively, the raw material flow passage 25 and the gas flow passage 26 may have the spaces in a square column shape. One part of the raw material flow passage 25 contacts with the connecting surface 24, and also one part of the gas flow passage 26 contacts with the connecting surface 24. The connecting surface 24 is provided with a raw material flow groove 24a linearly connecting the raw material flow passage 25 and the gas flow passage 26.
A description will be made of operation of the apparatus for producing nanofibers 1 and the nozzle head 20U according the present embodiments. The apparatus for producing nanofibers is supplied with the solvent from the solvent storage 11 and discharges from the opening of the raw material flow passage 25 on the raw material discharge surface 22. The apparatus for producing nanofibers is supplied with the high-pressure gas from the gas ejection unit 13 and ejects the same from the opening of the gas flow passage 26 on the gas discharge surface 23. The solvent discharged from the raw material flow passage 25 reaches at the opening of the gas flow passage 26 through the raw material flow groove 24a, meets the gas flow ejected from the gas flow passage 26 with the angle α, and is carried out in the front direction while being elongated, so that the nanofibers are manufactured.
According to the apparatus for producing nanofibers 2 and the nozzle head 20U of the above-mentioned embodiment, the raw material flow passage 25 is arranged so as to be orthogonal to the raw material discharge surface 22, and the gas flow passage 26 is arranged so as to be orthogonal to the gas discharge surface 23. Thereby, by drilling, the raw material flow passage 25 can be formed on the raw material discharge surface 22, and the gas flow passage 26 can be formed on the gas discharge surface 23. The solvent discharged from the raw material flow passage 25 directly meets the gas flow ejected from the gas flow passage 26 through the raw material flow groove 24a with the angle α. It can be achieved to manufacture precisely by drilling and to carry efficiently the solvent on the gas flow.
Hereinafter, an apparatus for producing nanofibers according to a third embodiment of the present invention will be described referring to
The apparatus for producing nanofibers 3 has a structure by using molten raw material prepared by melting a solid raw material.
The apparatus for producing nanofibers 3 according to the present embodiment comprises a hopper 62 for feeding a pellet-shaped resin (a granular synthetic resin having a fine particle) to be a material for the nanofibers into the apparatus for producing nanofibers 3, a heating cylinder 63 for heating and melting the resin supplied from the hopper 62, a heater 64 as a heating unit for heating the heating cylinder 63 from outside, a screw 65 which is rotatably stored in the heating cylinder 63 and functions as an extruding unit for moving the molten resin to the end of the heating cylinder 63 by rotating, a motor 66 as a driving unit for rotating the screw 65 through a connecting unit 69 (not shown in detail), and a cylindrical nozzle head 70 which is provided at the end of the heating cylinder 63. The nozzle head 70 is connected with a gas ejection unit (not illustrated) through a supply pipe 68. In the present embodiment, each structure such as the heating cylinder 63 and the nozzle head 70 is mainly made of metal, however, other materials may be applicable such as resin and glass in accordance with conditions of modes, such as kinds of resin as materials of the nanofibers or nanofiber products.
As shown in
The nozzle head 70 comprises a plurality of raw material flow passages 75 orthogonal to the raw material discharge surface 72, and the gas flow passage 76 orthogonal to the gas discharge surface 73. In the present embodiment, the number of the raw material flow passage 75 and the gas flow passage 76 is same (seven), and the raw material flow passage 75 and the gas flow passage 76 arranged in up and down direction correspond each other. In other words, there are a plurality (seven) of flow passage sets of one the raw material flow passage 75 and one gas flow passage 76. These sets are arranged in one direction so that the raw material flow passage 75 and the gas flow passage 76 become are arranged in two line in parallel.
In the present embodiments, the raw material flow passage 75 has a cylindrical space, and the gas flow passage 76 also has the cylindrical space. The raw material discharge surface 72 has a width (a length in up and down direction of
A plurality of the raw material flow passages 75 communicates with the heating cylinder 63, and the molten resin raw material supplied rom the heating cylinder 63 flow a plurality of the raw material flow passages 75 and is discharged from the opening of the plurality of raw material flow passages 75 on the raw material discharge surface 72.
A plurality of the gas flow passage 76 communicates with a gas supply pipe 68 in the nozzle head 70, and high-pressure gas supplied from the gas ejection unit flows the gas supply pipe 68 and a plurality of gas flow passages 76 and is ejected from the opening of the plurality of the gas flow passages 76 on the gas discharge surface 73.
The such structure is only an example, and if there are provided the raw material flow passage 75 and the gas flow passage 76 orthogonal to the raw material discharge surface 72 and the gas discharge surface 73 which are arranged with an angle α (0<α≤90°), respectively, the stricture may be optional within a purpose of the present invention.
A description will be made of operation of the apparatus for producing nanofibers 3 and the nozzle head 70 according the present embodiments. In the apparatus for producing nanofibers 3, the pellet-shaped raw material (resin) fed into the hopper 62 is supplied and melted in the heating cylinder 63 heated by the heater 64 and delivered to a front side of the heating cylinder 63 by the screw 65 rotated by the motor 66. The molten raw material (molten resin) arrived at the top of the heating cylinder 63 is discharged from the plurality of raw material flow passages 75 through the inside of the nozzle head 70. The high-pressure gas is ejected from the plurality of the gas flow passage 76 arranged in the nozzle head 70. The molten raw material discharged from the raw material flow passage 75 is meets the gas flow ejected from the gas flow passage 76 with the angle α, and is carried out in the front direction while being elongated, so that the nanofibers are manufactured.
According to the apparatus for producing nanofibers 3 and the nozzle head 70 of the above-mentioned embodiment, the raw material flow passage 75 is arranged so as to be orthogonal to the raw material discharge surface 72, and the gas flow passage 26 is arranged so as to be orthogonal to the gas discharge surface 73. Thereby, by drilling, the plurality of the raw material flow passage 75 can be formed on the raw material discharge surface 72, and the plurality of the gas flow passage 26 can be formed on the gas discharge surface 23. The molten raw material discharged from the raw material flow passage 75 directly meets the gas flow ejected from the gas flow passage 76 with the angle α. It can be achieved to manufacture precisely by drilling and to carry efficiently the solvent on the gas flow. Since the apparatus comprises a plurality of the raw material flow passages 75 and the gas flow passages 76, a large amount of nanofibers are manufactured efficiently in short time.
The first portion 70a of the nozzle head 70D of the variation 4 is prepared by cutting the cylinder taken along a radius, and one side corresponding to the radius is chamfered. The front surface 71 and the raw material discharge surface 72 (chamfered portion) are connected in order in a downward direction, and the plurality of raw material flow passages 75 orthogonal to the plurality of the raw material discharge surface 72 is provided. The second portion 70b is prepared by cutting the cylinder taken along a radius and becomes the cylinder as a whole by connecting the first portion 70a. The gas discharge surface 73 is provided at the entire front surface and the gas flow passage 76 orthogonal to the gas discharge surface 73 is provided. In a nozzle head 70D of the variation 4, the raw material discharge surface 72 and the gas discharge surface 73 are arranged with the angle α when the first portion 70a and the second portion 70b are connected. The nozzle head 70D of the variation 4 comprises these two portions may be connected detachably, and has the same structure as the nozzle head 70 of the basic structure other than connecting each other.
The nozzle head 70E of the variation 5 comprises a plurality of the raw material flow passage 75 which are orthogonal to the raw material discharge surface 72 and arranged at an equal interval in a circumferential direction, and the gas flow passage 76 orthogonal to a center of the gas discharge surface 73. The nozzle head 70E of the variation 5 comprises the plurality of (eight) raw material flow passages 75 are arranged around the gas flow passage 76. The nozzle head 70E of the variation 5 has a set of flow passage of the gas flow passage 76 and the plurality of the raw material flow passages 75 arranged round the gas flow passage 76.
In the nozzle head 70E of the variation 5, the raw material flow passage 75 has a cylindrical space and the gas flow passage 76 also has a cylindrical space. The raw material discharge surface 72 has a width (a length in a radius direction) same as that of a diameter of the raw material flow passage 75. The gas flow passage 76 is arranged with an interval from the raw material discharge surface 72. The axis line P of the raw material flow passage 75 and an axis line Q of the gas flow passage 76 are intersected at a point in front of the nozzle head 70B with an angle α.
The nozzle head 70G of the variation 7 comprises a plurality of the raw material flow passage 75 which are orthogonal to the raw material discharge surface 72 and arranged at an equal interval in a circumferential direction, and the plurality of the gas flow passages 76 which are orthogonal to the gas discharge surface 73 and arranged at an equal interval in a circumferential direction. The nozzle head 70G of the variation 7 comprises the plurality of (eight) raw material flow passages 75 and the gas flow passages 76, respectively. The nozzle head 70G of the variation 7 has eight sets of flow passage of one raw material flow passages 75 and one gas flow passage 76 corresponding thereto. A plurality of flow passage sets are arranged annularly so that the raw material flow passage 75 and the gas flow passage 76 are arranged on the circumference of two circles which become concentric.
In the nozzle head 70G of the variation 7, the raw material flow passage 75 has a cylindrical space and the gas flow passage 76 also has a cylindrical space. The raw material discharge surface 72 has a width (a length in a radius direction) larger (about two times) than the raw material flow passage 75. The plurality of the gas flow passages 76 are arranged with contacting with the raw material discharge surface 72, respectively. The axis line P of the raw material flow passage 75 and an axis line Q of the gas flow passage 76 are intersected at a point in front of the nozzle head 70G with an angle α.
In table 2, an outline of the basic structure and the structures of the variations 1 to 8 of the nozzle head 70 according to the Embodiment 3.
Though description is made of the embodiments of the present invention in detail, the present invention is not limited to the prescribed embodiments, and various modifications may be possible within a scope of the present invention.
For example, in the above embodiment, the horizontal apparatus for producing nanofibers is disclosed which the molten resin and the gas ejection hole are provided in a horizontal direction, however it is not limited to, and there is no problem to arrange the vertical apparatus and the nozzle head in the downward direction. Rather, such vertical apparatus is capable of efficiently preventing influence by the gravity.
In each embodiment and variation, positions of the raw material flow passage and the gas flow passage may be replaced each other. Specifically, in the nozzle head 20 of the embodiment 1, the position of the raw material discharge surface 22 may be replaced with the position of the gas discharge surface 23, the raw material discharge surface 22 and the front surface 21 are arranged in parallel, the gas discharge surface 23 is arranged with an angle α toward the raw material discharge surface 22. The raw material discharge surface 22 and the gas discharge surface 23 may be provided with the raw material flow passage 25 and the gas flow passage 26, respectively. The structure is not limited to any arrangement shown in figures of each embodiment. For example, the figures of each embodiment may be upside down and the raw material flow passage (the raw material discharge surface) and the gas flow passage (the gas discharge surface) may be replaced. Additionally, by rotating by 90° degrees, the raw material flow passage (the raw material discharge surface) and the gas flow passage (the gas discharge surface) may be arranged in horizontal direction.
The extruding means is described as the screw, an intermittent extrusion with a piston by supplying solution sequentially such as a die casting may be applicable.
The apparatus for producing nanofibers and the nozzle head according to the present invention preferably comprise a raw material temperature control function (not illustrated) in accordance with conditions of the liquid raw material and production of the nanofibers.
The apparatus for producing nanofibers and the nozzle head according to the present invention preferably comprises a gas temperature control function (not illustrated) for controlling a temperature of the gas at the gas exit.
Number | Date | Country | Kind |
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2017-101292 | May 2017 | JP | national |
Filing Document | Filing Date | Country | Kind |
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PCT/JP2018/019627 | 5/22/2018 | WO | 00 |