The invention relates to a nanoparticle filter apparatus for ambient air.
Vehicles produce soot (carbonaceous and metallic) particulate matter in a wide size range of 5 to 500 nanometre and more, mostly as exhaust fumes. Most of this, 90% in terms of mass, is above 300 nanometer and is filtered partially by vehicle exhausts and car air-conditioning systems on air intake to the vehicle cabin, but not all. In particular, so called nanoparticles in the size range 5 to 300 nanometer, which comprise the majority of the soot particles, 90% by number, are not filtered effectively. Such nanoparticles can be produced e.g., in South Los Angeles alone, at a rate of 13 tonnes per day by traffic.
Such nanoparticles, especially metallic ones, are now linked to a range of diseases, such as heart attacks, cancer, lung disease, and immune system diseases, and are considered a serious health problem. They pass rapidly (systemic in under 1 hour) into body cells, and are now considered a major trigger of heart attacks and other cardiovascular diseases.
Worse, they tend to accumulate within cars, school buses, lorry cabs and buildings close to main roads, typically four times but occasionally up to and over thirty times normal levels, so that road travelers and local residents are placed daily at high risk. Groups particularly seriously affected include professional drivers (trucks, taxis, buses, trams), ordinary commuters and schoolchildren (can have 50% of daily intake in a 30 minute commute), and those living and working within 400 metres of roads. In 2000, the California Air Resources Board (CARB) estimated that diesel particulate material was responsible for 70 percent of the state's risk of cancer from airborne toxics in California, USA. In 2004 alone, diesel pollution will cause an estimated 3,000 premature deaths in California. In addition, diesel exhaust will cause an estimated 2,700 cases of chronic bronchitis and about 4,400 hospital admissions for cardiovascular and respiratory illnesses every year. The cost of these health impacts (in California alone) is $21.5 billion per year.
By contrast, curve 13 shows levels in a quiet village street, where the baseline count is much higher, about 12,000 nanoparticle counts per cubic centimeter, with an average around 20,000 nanoparticle counts per cubic centimeter, and peak values over 30,000 nanoparticle counts per cubic centimeter. Curve 14 shows levels at a motorway roadside (service station) near heavy traffic with ‘heavy fume’. The baseline count is about 15,000 nanoparticle counts per cubic centimeter, the average is about 30,000 nanoparticle counts per cubic centimeter (10 times ‘normal’), and the peak value is almost 70,000 nanoparticle counts per cubic centimeter. It should also be noted that after a high peak, recovery to the baseline is slow and takes well over a minute.
Measurements made simultaneously outside and inside the car, in situations where the car is completely closed, and the air conditioning on full recirculation mode via its conventional filters (so new air intake to the vehicle cabin is minimized—there is always some, both via the air conditioning system and via leaks), show that the best possible result achievable on such a drive, using such conventional measures to exclude nanoparticles, is to reduce the average nanoparticle count (for a complete journey) inside the car to about one-sixth (˜17%) of the average count experienced outside the car during the same journey.
The existing filters clearly do not provide an effective filtering system since the above discussed values are readily measured values inside a modern car, even when all conventional precautions have been taken to exclude nanoparticles.
It is therefore an object of the invention to provide a new nanoparticulate filtration system.
Such a system according to the invention can especially be deployed in three ways:
As stand-alone or portable units in vehicles and in buildings
Such units are especially useful in school buses, private cars, trucks, taxis and other commercial vehicles, and such a system can also be used at home or in an office.
The invention will now be described in connection with the encompassed drawings. They show:
The technology according to the invention uses a combination technologies, and will also prove effective against other particulate pollutants e.g., cigarette smoke and pollen. A filter according to the invention also meets HEPA (high efficiency particulate air) filtration standards for larger particles: HEPA filter media are 99.97% efficient for removing particles above 0.3 microns (300 nanometres). These standards are created by the U.S. Atomic Energy Commission, and are the industry standards for particulate filtration in critical-environments.
The technology uses a small but (compared to conventional systems) extremely high back-pressure fan motor to draw air through a ‘thick’ pleated or other large-surface-area construction of the filter material in such a way that the nanoparticles are trapped in or on the filter material. The invention is based inter alia on three major factors—the method of filtration, filter materials selection, and blower/geometric design selection which in turn have certain consequences which also provide novelty: a further novelty arises from the way in which the filter assembly is deployed in a vehicle or other confined space.
(a) The method of filtration itself. Most conventional filtration is done using either the ‘sieve’ method, in which the pores are smaller then the minimum dimensions of the objects being removed from the flow stream, and so are physically impeded, or the ‘impact’ method, in which particles are provided with high velocity and encouraged to imbed upon impact in a ‘soft’ solid filter substrate material. In contrast, the present invention uses a filter medium where the pores are very much larger than the nanoparticles to be trapped, and uses a very slow velocity of air flow through the filter medium. This method of filtration is known, and is termed the ‘diffusion’ method. What happens is that, given sufficient time and ability to diffuse, the nanoparticles encounter the solid phase of the filter medium, and (although coatings may be used to enhance the effect) stick to the solid phase simply through van der Waals or other attractive/chemical forces—and the velocity of air flow is then insufficient to cause them (or at least the vast majority of particles captured in this way) to become subsequently de-attached. Consequently a high proportion of particles are trapped, per filter pass (fast cleaning) and yet the air flow is largely unimpeded and the filter does not become blocked. This method of filtration is not conventionally used because the need for a high residence time in the filter medium implies that the filter should be thick and the air velocity slow, and thus to clean a certain air flow volume in a certain time requires not only a large filter area but also a high back-pressure, of which conventionally used pumps or blowers are not capable.
(b) In the present invention, a very high back pressure of 1 mbar or above is preferred, as compared to conventional systems which typically use less that 1 mbar. This provides a phase velocity preferably of under 20 cm/s, and preferably under 10 cm/s, to the air stream.
(c) One consequence of the above is that the choice of high-performance nanoparticulate filter materials is not obvious to those skilled in the art of filtration, and most especially, is not necessarily a nanoporous material or indeed a conventional material already used for filtration, but may be a porous material used for other purposes, such as electromagnetic shielding.
(d) A second and more precisely stated aspect of this consequence is that, in order to maximise the trapping ability of the solid phase of the filter material, this material should not only have a high internal surface area, but should also be physically and geometrically thick (as ‘sieve’ systems ideally should not be), and encourage turbulent air flow within it (as ‘impact’ systems ideally should not be), to have the longest sensible achievable residence time of the nanoparticle-laden air inside the filter, to increase the probability of encounter with the solid phase. For a typical nanoparticle of size 100 nm under the conditions above the diffusion distance is about 40 microns per second, so thus a material with a pore size somewhat less than this, say 10 microns-100 times the nanoparticle size—still has a very good chance of trapping the nanoparticle provided the residence time in the filter is of the order of a second, in other words, that the path the particle takes through the filter is some ten centimetres long.
(e) The increase in physical thickness, and in geometric thickness (relating to the particle paths), is achieved e.g., by having highly pleated systems, such as we recommend, and in then also ensuring, preferably, that air flow through the pleated filter is not preferably through the minimum dimension, but obliquely, so that an even greater filter distance is encountered by the nanoparticles. In the system exemplified below this is achieved by having the air inside the filter moving as a slowly spinning vortex, so that the air encounters the pleated filter thickness almost tangentially.
(f) The establishment of, effectively, a very thick filter thickness in this way, naturally also has consequences for the fan blower to be used, which must not only set up flow shapes and velocities, such as the ‘slow vortex’ of the type we desire for the design example in
In experiments, materials of the ‘nanofibrous’ type, rather than ‘interpenetrating-network’ type materials, have proven effective, in contradiction to conventional views on filtration.
Prototype units consisting of a circumferential filter, radially pleated, with a blower enclosed within the filter to provide air flow from inside to outside, and of modest dimensions, have been created as shown in
The specifications of the prototypes made (as non-limiting exemplars of the invention) are:
The electronics are those used to control the blower, and to provide power from e.g., a car cigar-lighter. The filter is passive and is not electrically connected.
The specifications of the prototypes made (as non-limiting exemplars of the invention) are, to trap nanoparticles 20500 nm with a 95%+ efficiency, the exhaust velocity in the vehicle can be approx. 10 cm/s (or less)
The required back-pressures are those set by the blowers, but should be preferably at least 10 mPa and if possible 20 mPa or more. The preferred nanoparticle filter medium is thus the nanofibrous one noted above and of which
These apparently simple, yet sophisticated and novel designs, gives rise to an unexpectedly effective reduction in the nanoparticle count within enclosed volumes (e.g., a car interior) even with these modest sized systems.
Full-scale prototypes test the nanoparticle filters under a variety of actual route conditions, including ‘high-exposure’ urban and tunnel situations, in a test-car with the air conditioning turned on, in recirculation mode (so that there is some, but limited, external air entering the vehicle cabin).
As
Again please note that the reaction time of the system (versus the several-minute reaction time of the conventional air conditioning system alone, noted above) is much faster a high peak incident can be cleaned down in seconds.
The above measurements were all taken in situations where the air condition of the car is in recirculation mode (which can also be used as conventionally for heating/cooling) and new air from outside, amounting to 5-10% of the volume passing through the conventional air conditioning system, is added through our new filter.
This is a particularly promising mode of operation, since the air is cleaned before it reaches the vehicle cabin, and the average nanoparticle count (for a complete journey) inside the car can be reduced to about 2% of the average count experienced outside the car during the same journey. If new air is allowed to enter not via the new filter but via the conventional air-conditioning system (and leaks) then the filter, attempting to clean the dirty air in the cabin, can only maintain an average nanoparticle count (for a complete journey) inside the car of about 7% of the average count experienced outside the car during the same journey, which although better than the 17% achieved by the conventional air-conditioning alone, is still not ideal. (The new filter can maintain an average internal nanoparticle level of 75% of the external level if the conventional air-conditioning is switched to intake mode, being limited by the relative sizes of the air flows possible: this is thus only recommended if the external nanoparticle count is already low).
This mode, where the new air entering the cabin does so only via our new filter, looks promising, even with relatively low flow rates, and in itself represents a novel mode of operation. The ‘new’ air coming into the cabin sent through the nanoparticulate filter creates a slight overpressure inside the car (rather than vice-versa, as is usually encountered) so that the cabin is under positive pressure and thus tends to keep ‘dirty’ air from leaking in. The new filter in this format has to be modified with an additional element to capture the large soot particles, as these are now not taken out beforehand by the conventional air-conditioning system, but this is readily achievable, and indeed one adventitious benefit of the ‘vortex’ system as described above and in
To the above basic design various refinements can readily be added, such as:
The term highly probably (respectively, highly improbable) is defined as a percentage of more than 60% (less than 40%), preferably more than 80% (less than 20%), even more preferred more than 95% (less than 5%) and ideally more than 99% (less than 1%) of nanoparticles-attach and do not de-attach from the filter material.
The above description is considered showing not limiting embodiments. The scope of protection is solely defined by the attached claims.
Filing Document | Filing Date | Country | Kind | 371c Date |
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PCT/CH2007/000394 | 8/13/2007 | WO | 00 | 2/11/2009 |
Number | Date | Country | |
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60836957 | Aug 2006 | US |