Patent Application
20200040772
This disclosure relates to operating industrial facilities, for example, a natural gas liquid fractionation plant or other industrial facilities that include operating plants that generate heat, for example, a natural gas liquid fractionation plant.
Natural gas liquid (NGL) processes are chemical engineering processes and other facilities used in petroleum refineries to transform natural gas into products, for example, liquefied petroleum gas (LPG), gasoline, kerosene, jet fuel, diesel oils, fuel oils, and such products. NGL facilities are large industrial complexes that involve many different processing units and auxiliary facilities, for example, utility units, storage tanks, and such auxiliary facilities. Each refinery can have its own unique arrangement and combination of refining processes determined, for example, by the refinery location, desired products, economic considerations, or such factors. The NGL processes that are implemented to transform the natural gas into the products such as those listed earlier can generate heat, which may not be reused, and byproducts, for example, greenhouse gases (GHG), which may pollute the atmosphere. It is believed that the world's environment has been negatively affected by global warming caused, in part, due to the release of GHG into the atmosphere.
This specification describes technologies relating to cooling capacity generation, power generation or potable water production from waste heat in a natural gas liquid (NGL) fractionation plant.
The present disclosure includes one or more of the following units of measure with their corresponding abbreviations, as shown in Table 1:
Certain aspects of the subject matter described here can be implemented as a system. In an example implementation, the system includes a waste heat recovery heat exchanger network coupled to multiple heat sources of a Natural Gas Liquid (NGL) fractionation plant, the heat exchanger network configured to transfer at least a portion of heat generated at the multiple heat sources to a first buffer fluid and a second buffer fluid flowed through the first heat exchanger network. The system includes a first sub-system configured to generate power and sub-ambient cooling capacity, the first sub-system thermally coupled to the waste heat recovery heat exchanger. The system includes a second sub-system configured to generate potable water from brackish water, the second sub-system thermally coupled to the waste heat recovery heat exchanger.
In an aspect combinable with the example implementation, the system includes a control system connected to the heat exchanger network and the first sub-system or the heat exchanger network and the second sub-system or the heat exchanger network, the first sub-system and the second sub-system, the control system configured to flow fluids between the NGL fractionation plant, the heat exchanger network one or both of the first sub-system or the second sub-system.
In another aspect combinable with any of the previous aspects, the fluids include one or more of a NGL fractionation plant stream or a buffer fluid.
In another aspect combinable with any of the previous aspects, the multiple heat sources include a first multiple sub-units of the NGL fractionation plant, the first multiple sub-units including a propane dehydration section, a de-propanizer section, a butane de-hydrator section, and a de-butanizer section, second multiple sub-units of the NGL fractionation plant, the second multiple sub-units including a de-pentanizer section, an Amine-Di-Iso-Propanol (ADIP) regeneration section, a natural gas de-colorizing section, a propane vapor recovery section and a propane product refrigeration section and third multiple sub-units of the NGL fractionation a propane product sub-cooling section, a butane product refrigeration section, an ethane production section and a Reid Vapor Pressure (RVP) control section.
In another aspect combinable with any of the previous aspects, the heat exchanger network includes multiple heat exchangers.
In another aspect combinable with any of the previous aspects, the multiple heat exchangers includes a first subset including one or more of the multiple heat exchangers thermally coupled to the first multiple sub-units of the NGL fractionation plant.
In another aspect combinable with any of the previous aspects, the first subset includes a first heat exchanger thermally coupled to the propane dehydration section and configured to heat a first buffer stream using heat carried by a propane de-hydration outlet stream from the propane de-hydration section, a third heat exchanger thermally coupled to the butane de-hydrator section and configured to heat a second buffer stream using heat carried by a butane de-hydrator outlet stream, a fifth heat exchanger thermally coupled to the de-butanizer section and configured to heat a third buffer stream using heat carried by a de-butanizer overhead outlet stream from the de-butanizer section, and a sixth heat exchanger thermally coupled to the de-butanizer section and configured to heat a fourth buffer stream using heat carried by a de-butanizer bottoms outlet stream from the de-butanizer section.
In another aspect combinable with any of the previous aspects, the second subset includes a seventh heat exchanger thermally coupled to the de-pentanizer section and configured to heat a fifth buffer stream using heat carried by a de-pentanizer overhead outlet stream from the de-pentanizer section, an eighth heat exchanger thermally coupled to the ADIP regeneration section and configured to heat a sixth buffer stream using heat carried by an ADIP regeneration section overhead outlet stream, a ninth heat exchanger thermally coupled to the ADIP regeneration section and configured to heat a seventh buffer stream using heat carried by an ADIP regeneration section bottoms outlet stream, a tenth heat exchanger thermally coupled to the natural gas de-colorizing section and configured to heat an eighth buffer stream using heat carried by a natural gas de-colorizing section pre-flash drum overhead outlet stream, an eleventh heat exchanger thermally coupled to the natural gas de-colorizing section and configured to heat a ninth buffer stream using heat carried by a natural gas de-colorizer overhead outlet stream, a twelfth heat exchanger thermally coupled to the propane vapor recovery section and configured to heat a tenth buffer stream using heat carried by a propane vapor recovery compressor outlet stream, and a thirteenth heat exchanger thermally coupled to the propane product refrigeration section and configured to heat an eleventh buffer stream using heat carried by a propane refrigeration compressor outlet stream from the propane product refrigeration section.
In another aspect combinable with any of the previous aspects, the second subset includes a third subset including one or more of the multiple heat exchangers thermally coupled to the third multiple sub-units of the NGL fractionation plant.
In another aspect combinable with any of the previous aspects, the third subset includes a fourteenth heat exchanger thermally coupled to the propane product sub-cooling and configured to heat a twelfth buffer stream using heat carried by a propane main compressor outlet stream from the propane product sub-cooling section, a fifteenth heat exchanger thermally coupled to the butane product refrigeration section and configured to heat a thirteenth buffer stream using heat carried by a butane refrigeration compressor outlet stream from the butane product refrigeration section, a sixteenth heat exchanger thermally coupled to the ethane production section and configured to heat a fourteenth buffer stream using heat carried by an ethane dryer outlet stream, and a seventeenth heat exchanger thermally coupled to the RVP control section and configured to heat a fifteenth buffer stream using heat carried by a RVP control column overhead outlet stream.
In another aspect combinable with any of the previous aspects, the buffer stream is a first buffer stream of a first type. The multiple heat exchangers include a second heat exchanger thermally coupled to the de-propanizer section and configured to heat a second buffer stream of a second type different from the first type using heat carried by the de-propanizer overhead outlet stream, and a fourth heat exchanger thermally coupled to the de-butanizer section, the fourth heat exchanger configured to heat the second buffer stream of the second type using heat carried by the de-butanizer overhead outlet stream.
In another aspect combinable with any of the previous aspects, the first buffer stream of the first type includes oil and the second buffer stream of the second type includes water.
In another aspect combinable with any of the previous aspects, the system includes a first storage tank to store the first buffer stream and a second storage tank to store the second buffer stream.
In another aspect combinable with any of the previous aspects, the control system is configured to flow the first buffer stream or the second buffer stream or both from the respective storage tank to the heat exchanger network.
In another aspect combinable with any of the previous aspects, the first sub-system includes a modified Goswami cycle system configured to produce power and sub-ambient cooling capacity using at least a portion of heat carried by the first buffer stream.
In another aspect combinable with any of the previous aspects, the second sub-system includes a modified multi-effect-distillation (MED) system configured to produce potable water using at least a portion of heat carried by the third heat exchanger.
The details of one or more implementations of the subject matter described in this specification are set forth in the accompanying drawings and the detailed description. Other features, aspects, and advantages of the subject matter will become apparent from the description, the drawings, and the claims.
NGL Plant
Gas processing plants can purify raw natural gas or crude oil production associated gases (or both) by removing common contaminants such as water, carbon dioxide and hydrogen sulfide. Some of the substances which contaminate natural gas have economic value and can be processed or sold or both. Upon the separation of methane gas, which is useful as sales gas for houses and power generation, the remaining hydrocarbon mixture in liquid phase is called natural gas liquids (NGL). The NGL is fractionated in a separate plant or sometimes in the same gas processing plant into ethane, propane and heavier hydrocarbons for several versatile uses in chemical and petrochemical as well as transportation industries. The NGL fractionation plant uses the following processes or sections: fractionation, product treating, and natural gasoline processing. The fractionation processes or sections can include heat sources (also commonly referred to as streams) including, but not limited to, a propane condenser, a propane refrigerant condenser, a naphtha cooler, a de-pentanizer condenser, an amine-di-iso-propanol (ADIP) cooler, a regenerator overhead (OVHD) condenser, a Reid vapor pressure (RVP) column condenser, a de-propanizer condenser, a de-butanizer condenser, or combinations thereof. The product treating processes or sections can include the following non-limiting heat sources: a propane dehydrator condenser, a butane dehydrator condenser, a propane condenser, an air-cooled condenser, a regeneration gas cooler, and a butane condenser, or combinations thereof. The natural gasoline processing processes or sections can include, but are not limited to, a natural gasoline (NG) flash vapor condenser, a NG de-colorizer condenser, or combinations thereof.
Fractionation Section
Fractionation is the process of separating the different components of natural gas. Separation is possible because each component has a different boiling point. At temperatures less than the boiling point of a particular component, that component condenses to a liquid. It is also possible to increase the boiling point of a component by increasing the pressure. By using columns operating at different pressures and temperatures, the NGL fractionation plant is capable of separating ethane, propane, butane, pentane, or combinations thereof (with or without heavier associated hydrocarbons) from NGL fractionation feeds. De-ethanizing separates ethane from C2+ NGL, where C2 refers to a molecule containing two carbon atoms (ethane), and where C2+ refers to a mixture containing molecules having two or more carbon atoms, for example, a NGL containing C2, C3, C4, C5 can be abbreviated as “C2+ NGL”. De-propanizing and de-butanizing separate propane and butane, respectively, from C3+ NGL and C4+ NGL, respectively. Because the boiling points of heavier natural gases are closer to each other, such gases can be harder to separate compared to lighter natural gases. Also, a rate of separation of heavier components is less than that of comparatively lighter components. In some instances, the NGL fractionation plant can implement, for example, about 45 distillation trays in the de-ethanizer, about 50 trays in the de-propanizer, and about 55 trays in the de-butanizer.
The fractionation section can receive a feed gas containing C2+ NGL from gas plants, which are upstream plants that condition and sweeten the feed gas, and produce a sales gas, such as a C1/C2 mixture, where C1 is about 90%, as a final product. The C2+ NGL from gas plants can be further processed in the NGL fractionation plant for C2+ recovery. From feed metering or surge unit metering (or both), feed flows to the three fractionation modules, namely, the de-ethanizing module, the de-propanizing module and the de-butanizing module, each of which is described later.
De-Ethanizer Module (or De-Ethanizer Column)
The C2+ NGL is pre-heated before entering the de-ethanizer column for fractionation. The separated ethane leaves the column as overhead gas. The ethane gas is condensed by a closed-loop propane refrigeration system. After being cooled and condensed, the ethane is a mixture of gas and liquid. The liquid ethane is separated and pumped back to the top of the column as reflux. The ethane gas is warmed in an economizer and then sent to users. The bottoms product from the de-ethanizer reboiler is C3+ NGL, which is sent to the de-propanizer module.
De-Propanizer Module (or De-Propanizer Column)
From the de-ethanizer module, C3+ NGL enters the de-propanizer module for fractionation. The separated propane leaves the column as overhead gas. The gas is condensed using coolers. The propane condensate is collected in a reflux drum. Some of the liquid propane is pumped back to the column as reflux. The rest of the propane is either treated or sent to users as untreated product. The bottoms product from the depropanizer reboiler, C4+ is then sent to the de-butanizer module
De-Butanizer Module (or De-Butanizer Column)
C4+ enters the de-butanizer module for fractionation. The separated butane leaves the column as overhead gas. The gas is condensed using coolers. The butane condensate is collected in a reflux drum. Some of the liquid butane is pumped back to the column as reflux. The rest of the butane is either treated or sent to users as untreated product. The bottoms product from the debutanizer reboiler, C5+ natural gas (NG) goes on to a RVP control section (which may also be referred to as a rerun unit), which will be discussed in greater detail in a later section.
Product Treating Section
While ethane requires no further treatment, propane and butane products are normally treated to remove hydrogen sulfide (H2S), carbonyl sulfide (COS), and mercaptan sulfur (RSH). Then, the products are dried to remove any water. All exported product is treated, while untreated products can go to other industries. As described later, propane receives ADIP treating, MEROX™ (Honeywell UOP; Des Plaines, Ill.) treating, and dehydration. Butane receives MEROX treating, and dehydration.
ADIP Treating Section
ADIP is a solution of di-isopropanol amine and water. ADIP treating extracts H2S and COS from propane. The ADIP solution, through contact with the sour propane, absorbs the H2S and COS. The ADIP solution first contacts the sour propane in an extractor. In the extractor, the ADIP absorbs most of the H2S and some of the COS. The propane then passes through a mixer/settler train where the propane contacts with ADIP solution to extract more H2S and COS. This partially sweetened propane is cooled and then washed with water to recover the ADIP entrained with the propane. The propane is then sent to MEROX treating, which is described later. The rich ADIP that has absorbed the H2S and COS leaves the bottom of the extractor and is regenerated into lean ADIP for reuse. The regenerator column has a temperature and pressure that are suitable for acid gas removal. When the rich ADIP enters the regenerator, the entrained acid gases are stripped. As the acid gases leaves the regenerator as overhead, any free water is removed to prevent acid formation. The acid gases are then sent to flare. The lean ADIP leaves the extractor bottom and is cooled and filtered. Lean ADIP returns to the last mixer/settler and flows back through the system in the counter-current direction of the propane to improve contact between the propane and ADIP, which improves H2S and COS extraction.
C3/C4 MEROX Treating Section
MEROX treating removes mercaptan sulfur from C3/C4 product. Mercaptans are removed using a solution of sodium hydroxide (NaOH), also known by the commercial name caustic soda (hereinafter referred to as “caustic”) and MEROX. The MEROX catalyst facilitates the oxidation of mercaptans to disulfides. The oxidation takes place in an alkaline environment, which is provided by using the caustic solution. MEROX treating for C3 and C4 is similar. Both products are prewashed with caustic to remove any remaining traces of H2S, COS, and CO2. This prevents damage to the caustic that is used in MEROX treating. After prewashing, product flows to an extractor, where a caustic solution with MEROX catalyst contacts with the product. The caustic/catalyst solution converts the mercaptans into mercaptides. The sweetened product, which is lean on acid gases, leaves the extractor as overhead and any remaining caustic is separated. Caustic leaves the bottom of both product extractors rich with mercaptides. The rich caustic is regenerated into lean caustic for reuse. The C3/C4 extraction sections share a common caustic regeneration section, namely, an oxidizer. Before entering the bottom of the oxidizer, the rich caustic is injected with MEROX catalyst to maintain proper catalyst concentration, heated, and mixed with process air. In the oxidizer, the mercaptides are oxidized into disulfides. The mixture of disulfides, caustic, and air leave the oxidizer as overhead. The air, disulfide gases, and disulfide oil are separated from the regenerated caustic. The regenerated caustic is pumped to the C3/C4 extractor. Regenerated caustic with any residual disulfides is washed with NG in the NG wash settler.
C3/C4 Dehydration Section
Propane or butane products (or both) contain water when they leave MEROX treating. Dehydration removes moisture in such products through adsorption before the products flow to refrigeration and storage. The dehydration processes for C3 and C4 are similar. Both C3/C4 dehydration sections have two de-hydrators containing molecular sieve desiccant beds. One de-hydrator is in service while the other undergoes regeneration. Regeneration consists of heating the sieve beds to remove moisture, then cooling the beds before reuse. During drying, product flows up and through the molecular sieve bed, which adsorbs (that is, binds to its surface) moisture. From the top of the de-hydrator, dry C3/C4 products flow to refrigeration.
Natural Gasoline (NG) Processing Section
NG processing includes RVP control, de-colorizing and de-pentanizing sections.
RVP Control Section
A Reid vapor pressure (RVP) control section (or rerun unit) is a fractionator column that receives the C5+NG from the debutanizer bottom. The RVP control section collects a pentane product. The RVP control section can be used to adjust the RVP of the pentane product at a rerun fractionator overhead before the pentane product is sent to a pentane storage tank. RVP is a measure of the ability of a hydrocarbon to vaporize. RVP (sometimes called volatility) is an important specification in gasoline blending. The RVP control section stabilizes the RVP of NG by removing small amounts of pentane. Depending on operational requirements, the RVP control section can be totally or partially bypassed. NG from the debutanizer bottoms goes to the RVP column where a controlled amount of pentane is stripped and leaves the column as overhead gas. As in NGL fractionation, the overhead gas is condensed with coolers, and some of the condensate is pumped back to the column as reflux. The remaining pentane is cooled and sent to storage. If the RVP column bottoms product (NG) meets color specifications, it is sent to storage. If not, it is sent to decolorizing.
De-Colorizing Section
The de-colorizing section removes color bodies from NG. Color bodies are traces of heavy ends found in the de-butanizer bottoms product. Other impurities such as corrosion products from the pipeline may also be present. These must be removed for NG to meet the color specification. De-colorizer feed can be RVP column bottoms product or de-butanizer bottoms product, or a combination of both. Additional natural gasoline can also be supplied from other facilities to maintain a hexane plus (C6+) product supply. If de-colorizing is needed, NG first passes through a pre-flash-drum. A large portion of the lighter NG components vaporizes and leaves the drum as overhead. The heavier NG components remain along with the color bodies and are fed to the de-colorizer column, where the remaining color bodies are separated. The NG leaves the de-colorizer as overhead gas and is condensed and collected in the NG product drum, with some pumped back to the column as reflux. Overhead from the column and flash drum are joined and pumped to either the de-pentanizer (described later) or cooled and sent to storage in the feed product surge unit. The color bodies leave the de-colorizer as bottoms product and are pumped to the feed and surge unit to be injected into a crude line.
De-Pentanizing Section
De-pentanizing uses a fractionation column to produce a pentane overhead product and a C6+ bottoms product. Both the pentane product and the C6+ bottoms product are separately fed to storage or downstream the petrochemical plants. The feed to the de-pentanizer is the NG product stream from the de-colorizing section. Feed can be increased or decreased based on the demand for C6+ bottoms product. If the NGL fractionation plant NG production cannot meet demand, NG can be imported from oil refineries. The de-colorized NG is preheated before entering the de-pentanizer. The separated pentane leaves the column as overhead gas. The overhead condensers cool the overhead stream, and some is pumped back to the column as reflux. The remaining pentane is cooled and sent to storage. Light NG in the bottoms is vaporized and returned to heat the de-pentanizer. The remaining bottoms product is cooled and sent to storage as C6+.
Table 2 lists duty per train of major waste heat streams in an example of an NGL fractionation plant.
In Table 2, “Duty/train” represents each stream's thermal duty in millions Btu per hour (MMBtu/h) per processing train. A typical NGL fractionation plant includes three to four processing trains.
The systems described in this disclosure can be integrated with a NGL fractionation plant to make the fractionation plant more energy efficient or less polluting or both. In particular, the energy conversion system can be implemented to recover low grade waste heat from the NGL fractionation plant. Low grade waste heat is characterized by a temperature difference between a source and sink of the low grade heat steam being between 65° C. and 232° C. (150° F. and 450° F.). The NGL fractionation plant is an attractive option for integration with energy conversion systems due to a large amount of low grade waste heat generated by the plant and an absence of a need for deep cooling. Deep cooling refers to a temperature that is less than ambient that uses a refrigeration cycle to maintain.
The low grade waste heat from an NGL fractionation plant can be used for commodities such as carbon-free power generation, cooling capacity generation, potable water production from sea water, or combinations thereof. Low grade waste heat is characterized by a temperature ranging between 65° C. and 232° C. (150° F. to 450° F.). The waste heat can be used for the mono-generation, co-generation, or tri-generation of one or more or all of the commodities mentioned earlier. Low grade waste heat from the NGL fractionation plant can be used to provide in-plant sub-ambient cooling, thus reducing the consumption of power or fuel (or both) of the plant. Low grade waste heat from the NGL fractionation plant can be used to provide ambient air conditioning or cooling in the industrial community or in a nearby non-industrial community, thus helping the community to consume energy from alternative sources. In addition, the low grade waste heat can be used to desalinate water and produce potable water to the plant and adjacent community. An NGL fractionation plant is selected for low grade waste heat recovery because of a quantity of low grade waste heat available from the NGL fractionation plant as well as a cooling requirement of the plant to ambient temperature cooling (instead of deep cooling).
The energy conversion systems described in this disclosure can be integrated into an existing NGL fractionation plant as a retrofit or can be part of a newly constructed NGL fractionation plant. A retrofit to an existing NGL fractionation plant allows the carbon-free power generation, and fuel savings advantages offered by the energy conversion systems described here to be accessible with a reduced capital investment. For example, the energy conversion systems described here can produce one or more or all of substantially between 35 MW and 40 MW (for example, 37 MW) of carbon-free power, substantially between 100,000 and 150,000 m3/day (for example, 120,000 m3/day) of desalinated water, and substantially between 350 MM BTU/h and 400 MM BTU/h (for example, 388 MM BTU/h) of cooling capacity for in-plant or community utilization or both.
As described later, the systems for waste heat recovery and re-use from the NGL fractionation plant can include modified multi-effect distillation (MED) systems, customized Organic Rankine Cycle (ORC) systems, unique ammonia-water mixture Kalina cycle systems, customized modified Goswami cycle systems, mono-refrigerant specific vapor compression-ejector-expander triple cycle systems, or combinations of one or more of them. Details of each disclosure are described in the following paragraphs.
Heat Exchangers
In the configurations described in this disclosure, heat exchangers are used to transfer heat from one medium (for example, a stream flowing through a plant in a NGL fractionation plant, a buffer fluid or such medium) to another medium (for example, a buffer fluid or different stream flowing through a plant in the NGL fractionation plant). Heat exchangers are devices which transfer (exchange) heat typically from a hotter fluid stream to a relatively less hotter fluid stream. Heat exchangers can be used in heating and cooling applications, for example, in refrigerators, air conditions or such cooling applications. Heat exchangers can be distinguished from one another based on the direction in which fluids flow. For example, heat exchangers can be parallel-flow, cross-flow or counter-current. In parallel-flow heat exchangers, both fluid involved move in the same direction, entering and exiting the heat exchanger side-by-side. In cross-flow heat exchangers, the fluid path runs perpendicular to one another. In counter-current heat exchangers, the fluid paths flow in opposite directions, with one fluid exiting whether the other fluid enters. Counter-current heat exchangers are sometimes more effective than the other types of heat exchangers.
In addition to classifying heat exchangers based on fluid direction, heat exchangers can also be classified based on their construction. Some heat exchangers are constructed of multiple tubes. Some heat exchangers include plates with room for fluid to flow in between. Some heat exchangers enable heat exchange from liquid to liquid, while some heat exchangers enable heat exchange using other media.
Heat exchangers in a NGL fractionation plant are often shell and tube type heat exchangers which include multiple tubes through which fluid flows. The tubes are divided into two sets—the first set contains the fluid to be heated or cooled; the second set contains the fluid responsible for triggering the heat exchange, in other words, the fluid that either removes heat from the first set of tubes by absorbing and transmitting the heat away or warms the first set by transmitting its own heat to the fluid inside. When designing this type of exchanger, care must be taken in determining the correct tube wall thickness as well as tube diameter, to allow optimum heat exchange. In terms of flow, shell and tube heat exchangers can assume any of three flow path patterns.
Heat exchangers in NGL facilities can also be plate and frame type heat exchangers. Plate heat exchangers include thin plates joined together with a small amount of space in between, often maintained by a rubber gasket. The surface area is large, and the corners of each rectangular plate feature an opening through which fluid can flow between plates, extracting heat from the plates as it flows. The fluid channels themselves alternate hot and cold liquids, meaning that the heat exchangers can effectively cool as well as heat fluid. Because plate heat exchangers have large surface area, they can sometimes be more effective than shell and tube heat exchangers.
Other types of heat exchangers can include regenerative heat exchangers and adiabatic wheel heat exchangers. In a regenerative heat exchanger, the same fluid is passed along both sides of the exchanger, which can be either a plate heat exchanger or a shell and tube heat exchanger. Because the fluid can get very hot, the exiting fluid is used to warm the incoming fluid, maintaining a near constant temperature. Energy is saved in a regenerative heat exchanger because the process is cyclical, with almost all relative heat being transferred from the exiting fluid to the incoming fluid. To maintain a constant temperature, a small quantity of extra energy is needed to raise and lower the overall fluid temperature. In the adiabatic wheel heat exchanger, an intermediate liquid is used to store heat, which is then transferred to the opposite side of the heat exchanger. An adiabatic wheel consists of a large wheel with threads that rotate through the liquids—both hot and cold—to extract or transfer heat. The heat exchangers described in this disclosure can include any one of the heat exchangers described earlier, other heat exchangers, or combinations of them.
Each heat exchanger in each configuration can be associated with a respective thermal duty (or heat duty). The thermal duty of a heat exchanger can be defined as an amount of heat that can be transferred by the heat exchanger from the hot stream to the cold stream. The amount of heat can be calculated from the conditions and thermal properties of both the hot and cold streams. From the hot stream point of view, the thermal duty of the heat exchanger is the product of the hot stream flow rate, the hot stream specific heat, and a difference in temperature between the hot stream inlet temperature to the heat exchanger and the hot stream outlet temperature from the heat exchanger. From the cold stream point of view, the thermal duty of the heat exchanger is the product of the cold stream flow rate, the cold stream specific heat and a difference in temperature between the cold stream outlet from the heat exchanger and the cold stream inlet temperature from the heat exchanger. In several applications, the two quantities can be considered equal assuming no heat loss to the environment for these units, particularly, where the units are well insulated. The thermal duty of a heat exchanger can be measured in watts (W), megawatts (MW), millions of British Thermal Units per hour (Btu/hr), or millions of kilocalories per hour (Kcal/h). In the configurations described here, the thermal duties of the heat exchangers are provided as being “about X MW,” where “X” represents a numerical thermal duty value. The numerical thermal duty value is not absolute. That is, the actual thermal duty of a heat exchanger can be approximately equal to X, greater than X or less than X.
Flow Control System
In each of the configurations described later, process streams (also called “streams”) are flowed within each plant in a NGL fractionation plant and between plants in the NGL fractionation plant. The process streams can be flowed using one or more flow control systems implemented throughout the NGL fractionation plant. A flow control system can include one or more flow pumps to pump the process streams, one or more flow pipes through which the process streams are flowed and one or more valves to regulate the flow of streams through the pipes.
In some implementations, a flow control system can be operated manually. For example, an operator can set a flow rate for each pump and set valve open or close positions to regulate the flow of the process streams through the pipes in the flow control system. Once the operator has set the flow rates and the valve open or close positions for all flow control systems distributed across the NGL fractionation plant, the flow control system can flow the streams within a plant or between plants under constant flow conditions, for example, constant volumetric rate or such flow conditions. To change the flow conditions, the operator can manually operate the flow control system, for example, by changing the pump flow rate or the valve open or close position.
In some implementations, a flow control system can be operated automatically. For example, the flow control system can be connected to a computer system to operate the flow control system. The computer system can include a computer-readable medium storing instructions (such as flow control instructions and other instructions) executable by one or more processors to perform operations (such as flow control operations). An operator can set the flow rates and the valve open or close positions for all flow control systems distributed across the NGL fractionation plant using the computer system. In such implementations, the operator can manually change the flow conditions by providing inputs through the computer system. Also, in such implementations, the computer system can automatically (that is, without manual intervention) control one or more of the flow control systems, for example, using feedback systems implemented in one or more plants and connected to the computer system. For example, a sensor (such as a pressure sensor, temperature sensor or other sensor) can be connected to a pipe through which a process stream flows. The sensor can monitor and provide a flow condition (such as a pressure, temperature, or other flow condition) of the process stream to the computer system. In response to the flow condition exceeding a threshold (such as a threshold pressure value, a threshold temperature value, or other threshold value), the computer system can automatically perform operations. For example, if the pressure or temperature in the pipe exceeds the threshold pressure value or the threshold temperature value, respectively, the computer system can provide a signal to the pump to decrease a flow rate, a signal to open a valve to relieve the pressure, a signal to shut down process stream flow, or other signals.
In some implementations, the techniques described here can be implemented using a waste heat recovery network that includes 17 heat exchanger units distributed in specific areas in the NGL fractionation plant and a utility plant to heat high pressure buffer streams. A 1st buffer stream is hot oil. The heated oil is used for generating power using a modified Goswami Cycle. A 2nd buffer stream is high pressure water. The heated water is used to generate potable water from salt water using a MED system. The modified Goswami Cycle is coupled to 15 of the 17 heat exchanger units in the network and uses the 1st buffer stream. The MED system is coupled to the two remaining heat exchanger unit and uses the 2nd buffer stream. In some implementations, the heat recovered from the streams of the NGL fractionation plant can be used to operate the modified Goswami Cycle alone or the MED system alone. In some implementations, the heat can be used to operate both the modified Goswami Cycle and the MED system. In some implementations, the 1st and 2nd buffer streams can be the same buffer stream having the same composition and stored in the same storage tank/storage unit.
The techniques can be implemented to increase the temperature of the first buffer fluid stream from a temperature of between 115° F. and 125° F. (for example, about 120° F.) to a temperature between 180° F. and 190° F. (for example, about 187° F.). The first buffer fluid stream is then used to drive a modified Goswami cycle system to produce between 20 MW and 30 MW (for example, 26 MW) of power and between 60 MM Btu/h and 70 MM Btu/h (for example, about 63 MM Btu/h) of sub-ambient cooling. The first buffer fluid stream temperature is reduced in the modified Goswami cycle system to between 115° F. and 125° F. (for example, 120° F.), and the stream is flowed back to the first buffer fluid stream storage tank. The techniques can be implemented to increase the temperature of the second buffer fluid stream from a temperature of between 115° F. and 125° F. (for example, about 120° F.) to a temperature between 130° F. and 140° F. (for example, about 136° F.). The second buffer fluid stream is then used to drive a modified MED system to produce about 32,000 m3/day of potable water. The second buffer fluid stream temperature is reduced in the MED system to between 115° F. and 125° F. (for example, 120° F.), and the stream is flowed back to the second buffer fluid stream storage tank.
In some implementations, the buffer fluid of the 1st type and the buffer fluid of the 2nd type are the same buffer fluid having the same composition. In such implementations, the buffer fluid can be flowed from a single storage tank. A stream of the buffer fluid can be used to generate power and sub-ambient cooling capacity in the modified Goswami cycle system 1313, and another stream of the buffer fluid can be used to generate potable water in the modified MED system 1311. The buffer fluids can then be returned to the common storage tank.
A 5th heat exchanger 13e is located in the de-butanizer section of the NGL fractionation plant. In some implementations, the first buffer fluid in the storage tank 1305 (namely, oil) at a temperature of between 115° F. and 125° F. (for example, 120° F.) flows from the storage tank 1305 to the 5th heat exchanger 13e to cool down the de-butanizer overhead outlet stream. In turn, the temperature of the first buffer fluid stream increases to between 150° F. and 160° F. (for example, 152° F.). The first buffer fluid stream is flowed to the collection header to join other first buffer fluid streams to flow to the modified Goswami cycle 1313. The total thermal duty of the 5th heat exchanger 13e is between 515 MM Btu/h and 525 MM Btu/h (for example, about 518 MM Btu/h).
A 6th heat exchanger 13f is located in the de-butanizer section of the NGL fractionation plant. In some implementations, the first buffer fluid stream flows from the storage tank 1305 to the 6th heat exchanger 13f to cool down the de-butanizer bottoms outlet stream. In turn, the temperature of the first buffer fluid stream increases to between 255° F. and 265° F. (for example, 261° F.). The first buffer fluid stream flows to the collection header to join other first buffer fluid streams to flow to the modified cycle system 1313. The total thermal duty of the 6th heat exchanger 13f is between 50 MM Btu/h and 60 MM Btu/h (for example, about 56 MM Btu/h).
A 9th heat exchanger 13i is located in the ADIP regeneration section of the NGL fractionation plant. The first buffer fluid stream flows from the storage tank 1305 to the 9th heat exchanger 13i to cool down the ADIP regeneration section bottoms outlet stream. In turn, the temperature of the first buffer fluid stream increases to between 165° F. and 175° F. (for example, 171° F.). The first buffer fluid stream flows to the collection header to join other first buffer fluid streams to flow to the modified Goswami cycle system 1313. The total thermal duty of the 9th heat exchanger 13i is between 215 MM Btu/h and 225 MM Btu/h (for example, about 219 MM Btu/h).
An 11th heat exchanger 13k is located in the natural gas de-colorizing section of the NGL fractionation plant. In some implementations, the first buffer fluid stream flows from the storage tank 1305 to the 11th heat exchanger 13k to cool down the natural gas de-colorizer overhead outlet stream. In turn, the temperature of the first buffer fluid stream increases to between 225° F. and 235° F. (for example, 229° F.). The first buffer fluid stream flows to the collection header to join other first buffer fluid streams to flow to the modified Goswami cycle system 1313. The total thermal duty of the 11th heat exchanger 13k is between 50 MM Btu/h and 60 MM Btu/h (for example, about 53 MM Btu/h).
The modified Goswami cycle system 1313 can use specific mixtures of ammonia and water streams (for example, mixtures in the ratio of 50% to 50% ammonia to water stream) at defined pressures in a heat exchanger network including four heat exchangers (for example, heat exchangers 1312a, 1312b, 1312c and 1312d) and three coolers simultaneously satisfy specific cooling capacity in the NGL fractionation plant de-ethanizer overhead stream condensation and to generate power. The ammonia-water mixture is divided into two branches at about 11.5 bar. These two branches are heated and partially vaporized using thermal energy of between about 1400 MM Btu/h and 1600 MM Btu/h (for example, 1500 MM Btu/h) of waste heat from the buffer fluid flowed to the modified Goswami cycle 1313 from the heat exchanger network 1307, and between about 390 MM Btu/h and 400 MM Btu/h (for example, about 392 MM Btu/h) from the modified Goswami cycle separator bottom stream. The Goswami cycle heat exchangers network configuration is in a parallel configuration with two heat exchangers in series in each branch for the ammonia-water stream path.
The thermal duty of the first Goswami heat exchanger 1312a ranges between about 510 MM Btu/h and 520 MM Btu/h (for example, 517 MM Btu/h). The thermal duty of the second Goswami heat exchanger 1312b ranges between about 710 MM Btu/h and 720 MM Btu/h (for example, 714 MM Btu/h). The thermal duty of the third Goswami heat exchanger 1312c ranges between about 265 MM Btu/h and 275 MM Btu/h (for example, 271 MM Btu/h). The thermal duty of the fourth Goswami heat exchanger 1312d ranges between about 385 MINI Btu/h and 395 MM Btu/h (for example, 392 MM Btu/h). The ammonia-water liquid stream is partially vaporized in the four Goswami heat exchangers and separated to high ammonia concentrated vapor stream. A portion of the high ammonia concentrated vapor stream (for example, about 27%) is flowed to the turbine at high pressure where it is expanded to lower pressure of between about 2 bar and 5 bar (for example, about 4.3 bar) to generate power between about 1 MW and 5 MW (for example, 4 MW). The remainder of the high ammonia concentrated vapor stream (for example, about 73%) is flowed to the first water cooler for condensation at high pressure and then throttled in a throttling valve to lower pressure to about 4.3 bar to generate cooling capacity. The condensed stream at a temperature of about 37° F. is used for the in-plant cooling of the NGL fractionation plant in the de-ethanizer section to save mechanical compression, thereby saving thermal energy of about 388 MM Btu/h (for example, about 47 MW of power).
The high water concentration liquid stream out from the separator is used in a hydraulic pump to generate about 1.0 MW of power. The three ammonia-water vapor streams are then merged together in one stream that is then condensed in a second water cooler using water stream at a temperature of about 77° F. to continue the cycle. The first buffer fluid stream at a temperature ranging between about 180° F. and 190° F. (for example, about 187° F.) is used to pre-heat and partially vaporize the ammonia-water liquid feed (at a temperature ranging between about 10 bar and 20 bar (for example, about 11.5 bar) and a temperature ranging between about 80° F. and 90° F. (for example, about 87° F.)). The hot oil temperature is then flowed back to the storage tank 1305 to continue the waste heat recovery cycle in the NGL fractionation plant as described earlier.
The MED system feed water is distributed onto the heat exchanger of the first effect in all of the trains. The second buffer fluid stream, heated in the 2nd heat exchanger 13b and the 4th heat exchanger 13d, transfers some of its energy to the distributed feed water to evaporate a portion of the feed water. The produced vapor then condenses into potable water in the heat exchanger of the second effect, and the heat of the condensation is used to evaporate more water in that effect. The brine from the first effect is then purged. At the second effect, the evaporated feed water goes on to power the third effect with the resulting brine being drained from the bottom of the effect. This process continues to the last effect within each train of each phase with the corresponding produced vapor entering the condenser section to be condensed by the incoming saline water acting as a coolant. Part of the pre-heated saline water is then sent to the various effects as feed water. The saline water temperature can be between 25° C. and 35° C. (for example, about 28° C.), and the feed water temperature can be between 30° C. and 40° C. (for example, about 35° C.). The temperature drop from one effect to the next can be between 3° C. and 7° C. (for example, 5° C.).
In some implementations, a steam booster unit is included in the MED system to better exploit the waste heat stream to increase the fresh water yield. The steam booster unit includes an evaporator powered by the outgoing waste heat source of the MED system. The vapor generated from the steam booster unit is introduced into a suitable effect of the MED system. The inclusion of the steam booster unit in the MED system can increase the production rate to the extent allowed by the temperature drop across the steam booster unit.
In some implementations, one or more flashing chambers can be included in the MED system to improve the efficiency of the MED system, to extract more energy from the waste heat, and to utilize the extracted energy to generate stream, thereby increasing fresh water production. In such implementations, the outlet source from the MED system goes on to heat the feed water via a liquid-liquid heat exchanger, which is slightly heated by the outlet brine stream from the last flashing chamber. The heated feed water goes through a series of flashing chambers. The vapor generated from each stage of the flashing is then injected into an effect of the MED system for further boosting.
By identifying a best match between the waste heat load temperature profile and the number of effects used in each train, the quantity of water that can be generated using the MED system is optimized.
Thus, particular implementations of the subject matter have been described. Other implementations are within the scope of the following claims.
This application is a continuation of and claims the benefit of priority under 35 USC § 120 to U.S. patent application Ser. No. 15/842,292 entitled “Natural Gas Liquid Fractionation Plant Waste Heat Conversion to Simultaneous Power, Cooling and Potable Water Using Modified Goswami Cycle and New Modified Multi-Effect-Distillation System,” filed Dec. 14, 2017, which claims the benefit of priority under 35 USC § 119(e) to U.S. Provisional Application Ser. No. 62/542,687, filed on Aug. 8, 2017, the contents of each and all of which are hereby incorporated by reference in its respective entirety.
| Number | Date | Country | |
|---|---|---|---|
| 62542687 | Aug 2017 | US |
| Number | Date | Country | |
|---|---|---|---|
| Parent | 15842292 | Dec 2017 | US |
| Child | 16597479 | US |
