Not Applicable
1. Field of Disclosure
This invention relates to extraction of liquefiable hydrocarbons from natural gas.
2. Background
Natural gas produced at the wellhead in most cases contains contaminants and natural gas liquids, and must be processed into pipeline-quality dry natural gas, usually by removing oil; water; elements such as sulfur, helium, and carbon dioxide; and natural gas liquids. Dry natural gas is methane, which has one carbon atom. Natural gas liquids (“NGLs”) are hydrocarbon molecules having two or more, up to about eight, carbon atoms, specifically ethane (C2), propane (C3), butanes (n-C4, i-C4), pentanes (n-C5 and i-C5) and “heaviers” (C5+). Pipelines specify quality standards for acceptance of gas into their transmission systems. Included in these standards are generally a requirement that natural gas be delivered at a specified hydrocarbon dew point (“HDP”). The HDP is a temperature below which any vaporized natural gas liquids in the mix will tend to condense at pipeline pressure.
Gas plants designed to recover NGLs from produced natural gas have used a number of processes, originally refrigeration, then in the 1960's lean oil absorption, and in the 1970's cryogenic plants. Refrigeration plants chill natural gas to about −30° F. with an external propane refrigeration system. Depending upon the gas composition and pressure, propane recoveries range from about 30% to 50%. Lean oil absorption is a process in which the NGLs are removed by contacting the natural gas with a liquid hydrocarbon solvent (oil). Lean oil absorption plants can extract about 90%+ of the C3+ in the gas stream and about 30% of the ethane. Cryogenic plants with modifications made in the 1990's allowed propane recoveries to reach close to a 99% extraction level while recovering about 70% of the contained ethane. Essentially, cryogenic processing consists of lowering the temperature of the gas stream to around −120° F. While there are several ways to perform this function, a turbo expander process is most effective, using external refrigerants to chill the gas stream.
All these processes are performed in permanently installed large plants built to process at least 100 million standard cubic feet per day (MMscfd) of natural gas, often 250 MMscfd and larger.
At the other end of the size and capacity spectrum are small skid mounted transportable plants built to be movable for use in short term operating environments as opposed to permanent installations. These plants process as little as about 2 MMscfd, with mid ranges of about 5 to 15 MMscfd. Some extend up 30, 60 or 90 MMscfd. There are two basic types of these skid mounted transportable NGL recovery plants: those that chill the natural gas using a Joule-Thomson process and those that use a vapor compression cycle process employing a circulating refrigerant.
The Joule-Thomson process involves cooling a gas stream by reducing its pressure (adiabatic expansion) through a control valve (a “J-T” valve). Produced liquids are recovered in a cold separator and the gas stream off the top of the separator is used to cool the inlet stream to the J-T valve. The NGL from the cold separator is routed off skid to a pressurized NGL processing tank, but first may be routed through an inlet NGL/gas exchanger. The J-T process may require considerable compression of the feedstock to the plant to achieve the desired pressure drop across the J-T valve.
Transportable skid mounted refrigeration plants generally make use of the well know vapor compression cycle in which a circulating refrigerant such as Freon enters a compressor as a low pressure, low temperature vapor. The refrigerant is compressed by the compressor to a high pressure and temperature gaseous state. The high pressure and temperature gas then enters a condenser. The condenser cools the vapor until it starts condensing the high pressure and temperature gas to a high temperature liquid by transferring heat to a lower temperature medium, usually ambient air. The high temperature liquid then enters an expansion valve located at the entry into a pressure vessel, where pressure of the high temperature liquid abruptly decreases, causing flash evaporation within the vessel (which for this reason is often referred to as a flash drum). Both the vapor and the residual liquid are cooled to the saturation temperature of the liquid at the reduced pressure. The refrigerant then begins the vapor compression cycle again, passing from the flash drum to the compressor as a low pressure, low temperature vapor.
Both a transportable J-T plant and a refrigeration plant are used mainly to reduce HDP to pipeline specifications. A J-T plant has the least capital cost but also recovers the least amount of NGLs. This simple process primarily recovers the C5+ components. Pentane boils at 96.98° F. at atmospheric pressure. In order to meet HDP pipeline specifications, industry standard has been to insulate J-T units to maintain a 30° F. temperature. For 3 or 4 inch diameter piping or larger, this has resulted in use of 1.5-2 inches of insulation. Two inches of insulation holds the J-T cooling effect down to about 20° F.
A problem with J-T plants and transportable skid mounted refrigeration plants is that after the plant is built, changes may need to be made in the plant in order to use it at another short term operating site, for example, the NGL recovery efficiencies for the new site may need to be improved or lessened, according to the composition of the well stream gas produced at that site or due to the ambient conditions at the site, which may range from subfreezing to very hot ambient temperatures according to the season, especially at more northern latitudes, such as in North Dakota. Sometimes a J-T plant or a transportable skid mounted refrigeration plant constructed to a worse case scenario for the composition of well stream gas at a site, on being put into operation at the site, will be found to need efficiencies reduced for the composition of the well stream gas, for example, more NGLs may need to retained in the processed gas in order to meet pipeline BTU minimums while still meeting HDP specifications. Sometimes the composition of the gas or other conditions, including market conditions, will require NGL recovery efficiencies be improved. In order to make these changes, the J-T plant or transportable skid mounted refrigeration plant either has had to be returned to the manufacturing facility to alter the design or components of the plant, typically involving breaking through insulation, cutting out old parts and welding in other components and reforming the insulation, or attempts to make changes involving these tasks have had to be performed at the natural gas production site.
In recent years a revolutionary method of extracting oil and gas from shale deposits by horizontal drilling and hydraulic fracturing has produced vast new reserves of natural gas, and gas supplies have flooded the market. In consequence, natural gas prices have eroded and NGLs have become a more valuable component of natural gas produced from wells. Accordingly, while it is still necessary to meet gas quality specifications for pipelines, it is now desirable to achieve higher J-T plant and transportable refrigeration plant efficiencies than before in recovering valuable NGLs in the well stream. It is further also desirable for J-T plants and transportable refrigeration plants to have more built-in flexibility in order to make changes in the field to meet changed ambient conditions and changed compositions in the well stream gas.
In the following detailed description of exemplary embodiments, reference is made to the accompanying drawings, which form a part hereof and in which are shown by way of illustration examples of exemplary embodiments with which the invention may be practiced. In the drawings and descriptions, like or corresponding parts are marked throughout the specification and drawings with the same reference numerals. The drawings are not necessarily to scale. Certain features of the invention may be shown exaggerated in scale or in somewhat schematic form and some details of conventional elements may not be shown in the interest of clarity and conciseness.
Specific details described herein, including what is stated in the Abstract, are in every case a non-limiting description and exemplification of embodiments representing concrete ways in which the concepts of the invention may be practiced. This serves to teach one skilled in the art to employ the present invention in virtually any appropriately detailed system, structure or manner consistent with those concepts. Reference throughout this specification to “an exemplary embodiment” means that a particular feature, structure, or characteristic described in connection with the embodiment is included in at least one exemplary embodiment of the present invention. Thus, the appearances of the phrase “in an exemplary embodiment” in various places throughout this specification are not necessarily all referring to the same embodiment. Furthermore, the particular features, structures, or characteristics may be combined in any suitable manner in one or more embodiments. It will be seen that various changes and alternatives to the specific described embodiments and the details of those embodiments may be made within the scope of the invention. It will be appreciated that one or more of the elements depicted in the drawings can also be implemented in a more separated or integrated manner, or even removed or rendered as inoperable in certain cases, as is useful in accordance with a particular application. Because many varying and different embodiments may be made within the scope of the inventive concepts herein described and in the exemplary embodiments herein detailed, it is to be understood that the details herein are to be interpreted as illustrative and not as limiting the invention to that which is illustrated and described herein.
Various directions such as “north,” “south”, “east,” “west,” “upper,” “top”, “lower,” “bottom”, “back,” “front,” “transverse,” “perpendicular”, “vertical”, “normal,” “horizontal,” “length,” “width,” “laterally” and so forth used in the detailed description of exemplary embodiments are made only for easier explanation in conjunction with the drawings. The components may be oriented differently while performing the same function and accomplishing the same result as the exemplary embodiments herein detailed embody the concepts of the invention, and such terminologies are not to be understood as limiting the concepts which the embodiments exemplify.
As used herein, the use of the word “a” or “an” when used in conjunction with the term “comprising” (or the synonymous open ended “having” or “including”) in the claims and/or the specification may mean “one,” but it is also consistent with the meaning of “at least one” and “one or more than one.” In addition, as used herein, the phrase “connected” means joined to or placed into communication with, either directly or through intermediate components.
In accordance with this invention, there are disclosed exemplary embodiments for flexibly recovering natural gas liquids from an inlet natural gas stream having a temperature at atmospheric ambient or higher and a pressure of at least 400 psig. The embodiments comprise a skid; an inlet line for receiving the inlet natural gas stream; first and second one pass tube-in-shell heat exchangers supported on the skid, the second heat exchanger being connected in series with the first heat exchanger by a first transfer line, the first heat exchanger receiving the inlet natural gas stream from the inlet line; a second transfer line for receiving the inlet natural gas stream exiting the second heat exchanger; an NGLs condenser connected to the second transfer line for receiving inlet natural gas stream from the second heat exchanger and operatively sufficient to condense natural gas liquids in the inlet natural gas to two-phase gas-liquid NGLs; a third transfer line for receiving the two-phase gas-liquid NGLs from the NGLs condenser; a gas-liquid separator supported on the skid and connected to the third transfer line, the separator having lower and upper portions for separating two-phase gas-liquid NGLs from natural gas remaining in a single-phase gaseous state as a lean natural gas; a fourth transfer line connected to the separator at the lower portion, for receiving and transporting two-phase gas-liquid NGLs from the separator, the fourth transfer line connecting to the shell of the first heat exchanger proximal a rear end of the shell for shell side flow of NGLs from the rear end toward a front end of the first heat exchanger counter-currently to tube side flow of the inlet natural gas stream entering the first heat exchanger from the inlet line; at least one of the third and fourth transfer lines or both, including a replaceable segment that is removable without cutting the third or fourth transfer line or both, as applicable, for optional replacement of the replaceable segment by a different replaceable segment; a fifth transfer line connected to the shell of the first heat exchanger proximal the front end of the first heat exchanger for receiving a shell side flow stream of NGLs from the front end of the first heat exchanger as product; a sixth transfer line connected to the separator at the upper portion for receiving and transporting a lean natural gas stream from the separator, the sixth transfer line connecting to the shell of the second heat exchanger proximal a rear end of the shell for shell side flow of the lean natural gas stream from the rear end toward a front end of the second heat exchanger counter-currently to tube side flow of inlet natural gas entering the second heat exchanger from the second transfer line; and a seventh transfer line connected to the second heat exchanger proximal the front end of the shell thereof for receiving a shell side flow stream of lean natural gas as a lean gas product.
In exemplary embodiments, valving in at least one of the third or fourth transfer lines or both, upstream of a replaceable segment in the third or fourth transfer lines or both, blocks flow to a replaceable segment in the third or fourth transfer lines or both when the valving is closed. In exemplary embodiments, the replaceable segment either comprises (a) a length of pipe with connectors connecting the pipe with upstream and downstream potions of the third or fourth transfer lines or both that includes or include the replaceable segment, the pipe being downstream of the valving for blocking flow, or (b) a J-T pressure reduction valve with connectors connecting the J-T valve with upstream and downstream potions of the third or fourth transfer line or both that includes or include the replaceable segment, the J-T valve being downstream of the valving for blocking flow. If the replaceable segment comprises the length of pipe, the different replaceable segment comprises a J-T pressure reduction valve with connectors for connecting the J-T valve with upstream and downstream potions of the third or fourth transfer line, or both, that includes the replaceable segment. If the J-T valve comprises the replaceable segment, the different replaceable segment comprises a the length of pipe with connectors for connecting the length of pipe with upstream and downstream potions of the third or fourth transfer line, or both, that includes the replaceable segment.
In exemplary embodiments, the connectors of the length of pipe comprise first and second flanges. The first flange is connected to the pipe for bolting to a flange connected to an upstream portion of the third or fourth transfer lines or both that includes or include the length of pipe. The second flange is connected to the pipe for bolting to a flange connected to a downstream portion of the third or fourth transfer lines or both that includes or include the length of pipe. The connectors of the J-T pressure reduction valve comprise first and second flanges. The first flange is connected to the J-T valve for bolting to a flange connected to the upstream portion of the third or fourth transfer lines or both that includes or include the J-T valve, and the second flange is connected to the J-T valve for bolting to a flange connected to the downstream portion of the third or fourth transfer line or both that includes or include the J-T valve.
In exemplary embodiments, the shells of the first and second heat exchangers, the NGLs condenser, the separator and the first, second, third and fourth transfer lines, including the replaceable segment of the third or fourth transfer line or both the third or fourth transfer lines, as applicable, and the sixth transfer line, are encased in a protectively covered insulation of a kind and thickness sufficient to prevent condensation on the outer surfaces of the shells, the NGLs condenser, the separator, and the first, second, third and fourth transfer lines, including the included replaceable segment or segments, and the sixth transfer line, at a temperature contained within them not below the minimum temperature for which metallurgy of the gas-liquid separator is rated. In exemplary embodiments, the insulation surrounding the replaceable segment or segments is discontinuous with the insulation surrounding the remainder of the third or fourth transfer lines or both, as applicable, for separation from the third or fourth transfer lines without disturbing the remainder of such line or lines if the replaceable segment is removed and replaced with a different replaceable segment.
In an exemplary use, there is provided a process for flexibly recovering NGLs from an inlet natural gas stream having a temperature at atmospheric ambient or higher and a pressure of at least 400 psig. The exemplary process comprises (a) passing the inlet natural gas stream as a tube side flow though a one-pass shell-and-tube first heat exchanger; (b) passing inlet natural gas effluent from the tube side of the first heat exchanger as a tube side flow stream though a shell-and-tube second heat exchanger having a plurality of one-pass tubes; (c) passing the inlet natural gas effluent from the tube side of the second heat exchanger through a NGLs condenser to reduce the temperature and pressure of the inlet natural gas at least sufficiently to condense NGLs in the inlet natural gas to two-phase gas-liquid NGLs; (d) separating the two-phase gas-liquid NGLs in a gas-liquids separator from remaining single phase natural gas as a lean natural gas; (e) passing the separated two-phase gas-liquid NGLs through a replaceable segment of a transfer line to the shell side of the first heat exchanger, the replaceable segment comprising either a length of pipe if no additional cooling of the two-phase gas-liquid NGLs is desired, or a J-T valve if additional cooling of the two-phase gas-liquid NGLs is desired; (f) passing the two-phase gas-liquid NGLs from step (e) for counter-current flow to inlet natural gas in the tube side of the first heat exchanger at a shell side flow rate effective to increase the temperature of the shell side NGLs exiting the first heat exchanger to within a predetermine temperature range less than the temperature of the inlet natural gas entering the tube side of the first heat exchanger; (g) regulating removal of NGLs from the shell side of the first heat exchanger to maintain a flow of NGLs passing to the shell side of the first heat exchanger; (h) passing the separated lean natural gas to the shell side of the second heat exchanger; (i) passing the separated lean natural gas from step (h) for counter-current flow to inlet natural gas in the tube side of the second heat exchanger at a shell side flow rate effective to increase the temperature of the shell side lean natural gas exiting the second heat exchanger to within a predetermine temperature range less than the temperature of the inlet natural gas entering the tube side of the second heat exchanger, and (j) receiving separately NGLs removed from the shell side of the first heat exchanger and lean natural gas removed from the shell side of the second heat exchanger; (k) while insulating the exterior of the shells of the first and second heat exchangers, the exterior of the separator, and passages within which the steps (c), (e), (f), and (h) are performed, to an extent sufficient to prevent condensation on the outer surfaces of the heat exchangers, the separator, and the passages at a temperature, in steps (a) and (b) in a range between the temperature of the fluid entering the shell side of the heat exchangers and the minimum temperature for which metallurgy of the separator is rated, in step (d), in a range between the temperature of the fluids entering the separator and the minimum temperature for which metallurgy of the separator is rated, and in steps (c), (e), (f), and (h), in a range between the temperature of the fluids in the passages and the minimum temperature for which metallurgy of the separator is rated.
As used for exemplary embodiments herein, the term “NGLs condenser” means either a J-T plant or a refrigeration plant for condensing natural gas liquids in an inlet natural gas to two-phase gas-liquid NGLs.
Referring to the drawings,
Referring to
A first transfer line 26 connects to pass-through tube 24 at rear end 22 of first heat exchanger 16 for receiving the inlet natural gas stream exiting first heat exchanger 16.
J-T plant 10 further comprises a one pass shell-and-tube second heat exchanger 28 supported on skid 12. Second heat exchanger 28 includes a hair pin cylindrical shell pressure vessel 30 having a front end 32 and a rear end 34, and is connected on front end 32 to first transfer line 26. A pair of tube sheets (not seen) is transversely affixed to shell 30 inside the front and rear ends 32, 34 of shell 30. A plurality of tubes 33, which in an exemplary embodiment as depicted may be low fin tubes, are longitudinally arranged within shell 30 transversely affixed to and at least partially supported by the said tube sheets, for conducting the inlet natural gas stream introduced into the front end 32 of shell 30 to the rear end 34 of shell 30. In an exemplary embodiment, low fin tubes 33 are arranged to form a tube bundle. The tube bundle is supported by baffles affixed to interior of shell 30 as described further below. The baffles are not depicted
In an exemplary embodiment, referring to
A second transfer line 36 receives the inlet natural gas stream exiting second heat exchanger 28. A J-T adiabatic expansion pressure reduction valve 38 interconnects second transfer line 36 and a third transfer line 40. Pressure reduction valve 38 regulates the upstream pressure of the inlet natural gas stream received from second transfer line 36 to a predetermined set point and adiabatically expands the inlet natural gas to reduce the temperature and pressure of that gas. A third transfer line 40 receives the inlet natural gas stream at the reduced pressure and temperature. Pressure drop across valve 38 is sufficient to reduce the temperature of the inlet natural gas at least enough to condense natural gas liquids in the inlet natural gas and produce two-phase gas-liquid NGLs and a single-phase gas. In an exemplary embodiment, J-T valve 38 is a “fail open” valve and has an associated pressure controller 88 that supplies gas pressure to close the valve to a desired set point regulating the upstream pressure. By “fail open” is meant that if no gas pressure is supplied by pressure controller 88, valve 38 remains completely open. Pressure controller 88 has a sensing line input for sensing upstream pressure, for example, from pressure supply line 89 connected to first transfer line 26 (see
A horizontal gas-liquid separator 42 is supported on skid 12 and is connected to third transfer line 40 that carries the two-phase gas-liquid NGLs and a single-phase gas resulting from the pressure drop across J-T valve 38. Separator 42 has lower and upper portions 43, 45, respectively. Heavier two-phase gas-liquid NGLs gravitationally collect in the lower portion separate from lighter single-phase gas rising as a lean natural gas in the upper portion.
Referring to
In an exemplary embodiment, fourth transfer line 44 for transfer of NGLs includes a replaceable segment 50 between separator 42 and first heat exchanger shell 18. Replaceable segment 50 separates fourth transfer line 44 into an upstream portion 51 proximal to separator 42 and a downstream portion 53 distal from separator 42. Ball valves 49a and 49b and ball valve 52 in fourth transfer line 44 between separator 42 and replaceable segment 50 provide means for blocking NGL flow from separator 42 to replaceable segment 50. In an exemplary embodiment, schematically illustrated in
Alternatively, replaceable segment 50 may be a second J-T pressure reduction valve with its flanges 56 and 58 bolted up at flanges 57 and 59, and if a lesser efficiency is called for by conditions at the gas conditioning site, second J-T pressure reduction valve may be removed and replaced in the field by unbolting it and bolting in instead segment 50 comprising pipe 54 and flanges flange 56 and 58. A second J-T pressure reduction valve is represented in
In an exemplary embodiment, although replaceable segment 50 is shown in
A fifth transfer line 64 connects to shell 18 of first heat exchanger 16 proximal the front end 20 of heat exchanger 16 for receiving a shell side flow stream of NGLs from heat exchanger front end 20 and transferring the NGLs off skid as product for use or sale.
In
Referring to
A sixth transfer line 70 connects to gas-liquid separator 42 at upper portion 45 for receiving and transporting a single phase lean natural gas stream from separator 42. Sixth transfer line 70 connects to shell 30 of second heat exchanger 28 proximal rear end 34 thereof, providing shell side flow of the lean natural gas stream from such rear end 34 toward the front end 32 of the second heat exchanger, counter-currently to tube side flow of inlet natural gas entering second heat exchanger 28 from second transfer line 36.
A seventh transfer line 72 connects to second heat exchanger 28 proximal the front end of the shell 30 thereof, for receiving a shell side flow stream of lean natural gas for transfer of the lean natural gas off skid 12, as at 73.
An eighth transfer line 82 is connected either to first transfer line 26 (as shown in
Lean gas is passed through seventh transfer line 72 off skid 12 to sales or for other use. Gas for pneumatic operation of pressure controller 88, level controller 66 and temperature controller 86 is supplied by a bleed line 91 off seventh transfer line 72. Lean gas in line 91 is dropped in pressure through spring controlled pressure reduction valves 92, 93 and passes into supply gas pot 90. Any condensation of vapor from the lean gas caused by the pressure drops from valves 92, 93 is captured in pot 90. Gas is led from pot 90 by line 94, branched to line 95, and dropped in pressure across pressure reduction valve 96 to a supply gas pressure of from 0 to 30 psi, then fed to pneumatic line 97 and thence to supply branch 98 to J-T valve 38, supply branch 99 to temperature controller 86 and supply branch 11 to pilot 66. Line 94 off pot 90 is controlled by pressure regulator 13 safety valving line 94 to atmosphere in the event of pressure surges in excess of the rated pressure of pot 90. Similarly, gas-liquid separator 42 is safety valved at 15.
Formation of hydrates from any moisture in the inlet natural gas after dehydration off skid is prevented by injection of methanol from a source 35 passed though methanol lines 37, 39 and injected into inlet line 14 and second transfer line 36 at injection fittings 41a, 41b and 55 respectively.
Shells 18 and 30, respectively, of the first and second heat exchangers 16 and 28 are encased in a protectively covered insulation to contain and maintain process temperatures reaching as low as the metallurgical temperature of the gas-liquid separator 42. Referring to
The insulation surrounding segment 50 is discontinuous with the insulation surrounding the remainder of fourth transfer line 44 to allow separation of the insulation around fourth transfer line 44 without disturbing the remainder of the insulation in line 44 if segment 50 is removed for replacement with a second pressure reduction valve 60 (or if alternatively second J-T valve 60 is replaced by segment 50, as described above). In an exemplary embodiment, the insulation surrounding segment 50 is interiorly matingly contoured to the shape of segment 50 (or alternatively to the shape of second J-T valve 60 if it is initially installed instead of segment 50 as described above) and is longitudinally divided and held to segment 50 (or alternatively to second J-T valve 60) by holders, suitably tension latches, to allow nondestructive separation of the insulation from segment 50 for reuse of the insulation if second J-T valve 60 replaces segment 50 or if segment 50 replaces second J-T valve 60, as described above. In an exemplary embodiment, the insulation of segment 50 comprises a precut removable interior portion (not shown) that when removed conforms the interior of the insulation to the external contour of second J-T valve 60, for reuse of the insulation to insulate second pressure reduction valve 60 if it replaces segment 50.
Referring now to
The separated lean natural gas in separator 42 is passed from separator 42 through sixth transfer line 70 to the rear end 34 of the shell side of second heat exchanger 28 for counter-current flow to inlet natural gas entering the front end 32 in the tube side of second heat exchanger 28 and is flowed at a shell side flow rate effective to increase the temperature of the shell side lean natural gas exiting the second heat exchanger 16 at front end 32 into seventh transfer line 72 to within a predetermine temperature range less than the temperature of the inlet natural gas entering the tube side of the second heat exchanger, suitably from 1 to 20° F. less than the temperature of the inlet natural gas entering the tube side of such second heat exchanger. The NGLs passed from level control valve 68 continue in fifth transfer line 64 to a destination off skid as indicated by the terminus 69 of fifth transfer line. The lean natural gas removed from the shell side of the second heat exchanger passes in seventh transfer line 72 to an off skid location, as indicated at the terminus of line 72 at 73.
During this process, the exterior of the shells of the first and second heat exchangers 16 and 28, the exterior of the separator 42, and the exterior of the first, second, third, fourth, and sixth transfer lines, respectively 26, 36, 40, 44, 70, are insulated, as indicated in
The efficiency of a J-T plant exemplary embodiment of the invention is illustrated by the following Examples One through Three. All Examples are produced using HYSIS process simulation software from Aspentech Technology, Inc. 200 Wheeler Road, Burlington, Mass. 01803.
Example One compares the recoveries of a skid of a construction described above with the recoveries of an example of a prior art third party design of a J-T valve skid.
Conditions are inlet gas temperature 95° F., inlet gas pressure=1350 psig, and inlet gas volume=1.6 MMscfd.
The invention embodiment configuration employs a gas/liquid (“G/L”) heat exchanger 16 comprising a 3 inch pass through pipe and a 6 inch shell; a gas/gas (“G/G”) heat exchanger 28 with 1468 square inches of tubing surface; J-T valve 38; gas liquid separator 42; and J-T valve 60 before L/G heat exchanger 16 as described above.
The conventional commercial J-T skid has in serial sequence a gas/gas (“G/G”) heat exchanger with 457 square inches of tubing area, a J-T valve, and a gas liquid separator and a J-T valve in the sales line after the separator. The embodiment configuration is programmed at only 80% efficiency and the conventional skid is programmed at 100% efficiency.
The temperatures (° F.) at the serial components are:
Table 1 below shows volumetric and compositional recoveries for the composition of inlet natural gas and processes set forth in Example One; recoveries of all C5's and C6's are collectively C5+ recoveries in the i-C5 row.
Table 1 shows that the J-T plant of the described embodiment recovers twice as much (208% more) NGLs than a third party conventional prior art design, and the recoveries of the exemplary embodiment reach deeper into the lower molecular weight NGLs than does the prior art design, the recoveries of the described embodiment being less weighted to C5+ heaviers.
The following tables show a comparison of recoveries using the embodiment configuration as described above with a J-T valve 60 between separator 42 and G/L heat exchanger 16 verses a J-T plant design having two serial G/G heat exchangers and a second J-T valve in the NGL product line, as in Example One. Conditions are inlet gas temperature 120° F., inlet gas pressure=1350 psig, and inlet gas volume=5 MMscfd.
Table 2 shows volumetric and compositional recoveries for the composition of inlet natural gas and processes set forth in Example Two; recoveries of all C5's and C6's are collectively C5+ recoveries in the i-C5 row.
Table 2 shows that the J-T plant of the described embodiment recovered 25% more NGLs than a J-T plant having two serial G/G heat exchangers, and the recovery of the exemplary embodiment reached deeper into the lower molecular weight NGLs than did the prior art design, being less weighted to C5+ heaviers.
The following tables show a comparison of recoveries using the embodiment configuration as described above with a J-T valve 60 between separator 42 and G/L heat exchanger 16 verses a J-T plant design having two serial G/G heat exchangers and a second J-T valve in the NGL product line, as in Example One. Conditions are inlet gas temperature 120° F., inlet gas pressure=1350 psig, and inlet gas volume=10 MMscfd.
Table 3 shows volumetric and compositional recoveries for the composition of inlet natural gas set forth; recoveries of all C5's and C6's are collectively C5+ recoveries in the i-C5 row.
Table 3 shows that even at twice the throughput of Example Two, the J-T plant of the described embodiment recovered 29% more NGLs than a J-T plant having two serial G/G heat exchangers, and the recovery of the exemplary embodiment reached deeper into the lower molecular weight NGLs than did the prior art design, being less weighted to C5+ heaviers.
Referring to the drawings,
Referring to
Second transfer line 36 receives the inlet natural gas stream exiting second heat exchanger 28. Pressure regulator valve 65 (
In an exemplary embodiment, two parallel vapor compression refrigerant systems are employed, with compressors and condensers sheltered under housings 101 and 102. In an exemplary embodiment R-404 refrigerant is used. R-404 refrigerant enters the compressors housed in 101, 102 as a low pressure, low temperature vapor. The refrigerant is compressed by the compressors to a high pressure and temperature gaseous state and is passed to condensers housed in 101, 102 that cool the vapor to start it condensing to a high temperature liquid. The high temperature liquid is passed by refrigerant lines 103 and 106 from the condensers in housings 101, 102 respectively, to expansion valves 104, 107 respectively (
The chilled natural gas exits chiller 100 and passes into third transfer line 40 for delivery to horizontal gas-liquid separator 42 (
Alternatively, replaceable segment 50 may be already be a J-T pressure reduction valve with its flanges 56 and 58 bolted up at flanges 57 and 59, and if a lesser efficiency is called for by conditions at the natural gas conditioning site, the J-T pressure reduction valve may be removed and replaced in the field by unbolting it and bolting in instead a segment 50 comprising pipe 54 and flanges flange 56 and 58. The efficiency benefits of a J-T pressure reduction valve between chiller 100 and gas-liquids separator 42 are described below Examples Five and Six.
Third transfer line 40 connects into and delivers the two-phase gas-liquid NGLs and a single-phase gas from chiller 100, and optionally, a JT valve at segment 50, into gas-liquid separator 42.
Horizontal gas-liquid separator 42 is supported on skid 12 and has lower and upper portions 43, 45, respectively. Heavier two-phase gas-liquid NGLs gravitationally collect in the lower portion separate from lighter single-phase gas rising as a lean natural gas in the upper portion.
A fourth transfer line 44 transports two-phase gas-liquid NGLs from the lower portion of gas-liquid separator 42 to shell 18 of first heat exchanger 16 proximal rear end 22 of shell 18 for shell side flow of natural gas liquids from rear end 22 toward front end 20 of first heat exchanger 16 counter-currently to tube side flow of the inlet natural gas stream entering first heat exchanger 16 from inlet line 14.
Referring to
Alternatively, replaceable segment 150 may be a second J-T pressure reduction valve (second, if replaceable segment 50 has a J-T valve already installed there) with its flanges 156 and 158 bolted up at flanges 157 and 159, and if a lesser efficiency is called for by conditions at the gas conditioning site, the second J-T pressure reduction valve may be removed and replaced in the field by unbolting it and bolting in instead segment 150 comprising pipe 154 and flanges flange 156 and 158. The efficiency benefits of a second J-T pressure reduction valve are described below in Examples Five and Six.
Fourth transfer line 44 ells at 161, 163 respectively rising to connect into shell 18 of gas-liquid separator 16.
A fifth transfer line 64 connects to shell 18 of first heat exchanger 16 proximal the front end 20 of heat exchanger 16 for receiving a shell side flow stream of NGLs from heat exchanger front end 20 and transferring the NGLs off skid as product for use or sale.
In
Referring to
A sixth transfer line 70 connects to gas-liquid separator 42 at upper portion 45 for receiving and transporting a single phase lean natural gas stream from separator 42. Sixth transfer line 70 connects to shell 30 of second heat exchanger 28 proximal rear end 34 thereof, providing shell side flow of the lean natural gas stream from such rear end 34 toward the front end 32 of the second heat exchanger, counter-currently to tube side flow of inlet natural gas entering second heat exchanger 28 from second transfer line 36.
A seventh transfer line 72 connects to second heat exchanger 28 proximal the front end of the shell 30 thereof, for receiving a shell side flow stream of lean natural gas for transfer of the lean natural gas off skid 12, as at 73.
Refrigeration compressors in housings 101, 102 are run controlled by a temperature indicator 85 communicating to a temperature controller in housings 101, 102 (
Lean gas is passed through seventh transfer line 72 off skid 12 to sales or for other use. Referring to
Formation of hydrates from any moisture in the inlet natural gas after dehydration off skid is prevented by injection of methanol from a source 35 passed though methanol lines 37, 39 and injected into inlet line 14 and second transfer line 36 at injection fittings 41a, 41b and 55 respectively.
Shells 18 and 30, respectively, of the first and second heat exchangers 16 and 28 are encased in a protectively covered insulation to contain and maintain process temperatures reaching as low as the metallurgical temperature of the gas-liquid separator 42. Referring to
The insulation surrounding segments 50 and 150 is discontinuous with the insulation surrounding the remainder of third and fourth transfer lines 36, 44 respectively to allow separation of the insulation around third and fourth transfer lines 36, 44 respectively without disturbing the remainder of the insulation in lines 36 or 44 if segment 50 or 150, or both, comprising pipe lengths 54, 154 respectively, is or are removed for replacement with a pressure reduction J-T valve (or alternatively if segment 50 or 150 or both each comprising a J-T valve is replaced by pipe lengths 54, 154, respectively, as described above). In an exemplary embodiment, the insulation surrounding segments 50 and 150 is interiorly matingly contoured to the shape of segment 50 or 150 respectively, whether the segment comprise a J-T valve or a length of pipe. The insulation is longitudinally divided and held to segment 50 or 150 by holders, suitably tension latches, to allow nondestructive separation of the insulation from segment 50 or 150 for reuse for a like replaceable segment.
Referring now to
The separated lean natural gas in separator 42 is passed from separator 42 through sixth transfer line 70 to the rear end 34 of the shell side of second heat exchanger 28 for counter-current flow to inlet natural gas entering the front end 32 in the tube side of second heat exchanger 28 and is flowed at a shell side flow rate effective to increase the temperature of the shell side lean natural gas exiting the second heat exchanger 16 at front end 32 into seventh transfer line 72 to within a predetermine temperature range less than the temperature of the inlet natural gas entering the tube side of the second heat exchanger, suitably from 1 to 20° F. less than the temperature of the inlet natural gas entering the tube side of such second heat exchanger. The NGLs passed from level control valve 68 continue in fifth transfer line 64 to a destination off skid as indicated by the terminus 69 of fifth transfer line. The lean natural gas removed from the shell side of the second heat exchanger passes in seventh transfer line 72 to an off skid location, as indicated at the terminus of line 72 at 73.
During this process, the exterior of the shells of the first and second heat exchangers 16 and 28, the exterior of the chiller 100 and the separator 42, and the exterior of the first, second, third, fourth, and sixth transfer lines, respectively 26, 36, 40, 44, 70, are insulated, as variously indicated in the drawings (insulation for third transfer line 40 is not depicted so as to not obscure details of line 40), respectively at 74, 75, 109, 76, 71, 77, 79 (for the fourth transfer line) and 80 (for the sixth transfer line), to an extent sufficient to prevent condensation on the outer surfaces of the heat exchangers 16 and 28, the chiller 100, the separator 42, and second, third, fourth, and sixth transfer lines, respectively 26, 36, 40, 44, 70, at a temperature, for separators 16 and 28 and chiller 100 that is in a range between the temperature of the fluid entering the shell side of the heat exchangers and the chiller and the minimum temperature for which metallurgy of separator 42 is rated, for separator 42, in a range between the temperature of the fluids entering separator 42 and the minimum temperature for which metallurgy of the separator is rated, and in lines steps 26, 36, 40, 44, 70, in a range between the temperature of the fluids in the lines and the minimum temperature for which metallurgy of separator 42 is rated.
Thus there have been described both J-T plant and refrigeration plant embodiments of this invention in which at least one of the third and fourth transfer lines include a replaceable segment that is removable without cutting the third or fourth transfer line, or both, as applicable, for optional replacement of the replaceable segment by a different replaceable segment.
The efficiency of an exemplary refrigeration plant embodiment of the invention is illustrated by the following Examples. All examples are produced using process simulation software on a natural gas of identical composition, at identical natural gas volume (2.0 MMscfd) and identical temperature (100° F.). Example One has an inlet gas pressure of 611 psig. Examples Two and Three have an inlet gas pressure of 1200 psig. The same process simulation software is used as used for Examples One through Three.
Example Four shows the kinds of recoveries achieved with a skidded refrigeration system of a prior art design. The embodiment configuration employs a gas/liquid (“G/L”) heat exchanger 16 comprising a 2 inch pass through pipe and a 3 inch shell; a gas/gas (“G/G”) heat exchanger 28 with 641 square inches of tubing surface; a refrigeration system 100-108; and gas liquid separator 42 with routing of the NGLs to the shell side of the G/L heat exchanger and a routing of the lean gas to the shell side of the G/G heat exchanger.
The temperatures (° F.) at the serial components are:
Table 4 shows volumetric and compositional recoveries for the composition of inlet natural gas set forth; recoveries of all NGL C5's and C6's are collectively C5+ recoveries placed in the i-C5 row.
The following tables show a comparison of recoveries using the embodiment configuration as described above except with a J-T valve 50 between refrigeration heat exchangers 101, 102 and separator 42.
The temperatures (° F.) at the serial components are:
Table 5 below shows volumetric and compositional recoveries for the composition of inlet natural gas set forth; recoveries of all NGL C5's and C6's are collectively C5+ recoveries and placed in the i-C5 row.
Table 5 shows that the described embodiment of Example Five recovers 25% more NGLs than a Refrigeration plant having two serial G/G heat exchangers as in Example Four, and the recoveries of the exemplary embodiment reach deeper into the lower molecular weight NGLs than did the prior art design, being less weighted to C5+ heaviers.
The following tables show a comparison of recoveries using the embodiment configuration as described in Example Five with an additional J-T valve 150 between separator 42 and G/L heat exchanger 16. Inlet gas conditions are the same as in Example Five.
Table 6 shows volumetric and compositional recoveries for the composition of inlet natural gas and process set forth in Example Six; recoveries of all C5's and C6's are collectively C5+ recoveries in the i-C5 row.
From the foregoing, it is seen that the embodiments of Examples Five and Six reach deeper into the natural gas such that methane is about 10% higher in concentration than in the prior art design and C2, C3, C4's, and C5+'s are much lower in concentration. The concentration of ethane is reduced about 40%, propane about 90%, and butanes and pentanes about 230%.
The above-disclosed subject matter is to be considered illustrative, and not restrictive. The appended claims are intended to cover all modifications, enhancements, and other exemplary embodiments that fall within the true scope of the present invention. To the maximum extent allowed by law, the present invention is to be determined by the broadest permissible interpretation of the following claims and their equivalents, unrestricted or limited by the foregoing detailed descriptions of exemplary embodiments of the invention.
This application claims priority to U.S. provisional applications 61/796,047 and 61/796,057, both filed Nov. 1, 2012, the entirety of the contents of which are incorporated herein by reference.
Number | Date | Country | |
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61796047 | Nov 2012 | US | |
61796057 | Nov 2012 | US |