Claims
- 1. A nebulizable coating compositions for making high quality fluorine-doped tin oxide coatings having a low sheet resistance and high visible light transmission comprising:
- (a) a mixture comprising
- (1) less than 95 wt. % of monobutyltin trichloride, and
- (2) less than 50 wt. % of an inorganic fluorine dopant, which is selected from ammonium fluoride, ammonium bifluoride and dibutyltin difluoride, and,
- (b) the rest being a solvent mixture of water or a trialkylamine, and an organic solvent.
- 2. A nebulizable coating composition according to claim 1 in which said organic solvent is methanol.
- 3. A nebulizable coating oomposition according to claim 1 in which said inorganic fluorine dopant is ammonium fluoride or ammonium bifluoride and said solvent mixture is water and methanol.
- 4. A nebulizable coating composition according to claim 1 in which said inorganic dopant is dibutyltin difluoride and said mixture of solvents is a trialkylamine and methanol.
- 5. A method of depositing a high quality fluorine-doped tin oxide coating having a low sheet resistance and high visible light transmission comprising:
- (a) forming a nebulizable coating composition of claim 1, and
- (b) contacting said composition in an oxygencontaining gas stream with a substrate maintained at a temperature of about 400.degree. to 700.degree. C.
- 6. A method according to claim 5 in which said oxygen-containing gas stream is air.
- 7. A method according to claim 5 where said temperature of 500.degree.-650.degree. C.
- 8. A method according to claim 5 where said substrate is glass.
- 9. A method according to claim 5 where said deposition is carried out at between 6% to 100% relative humidity at 18.degree. C.
CROSS-REFERENCE TO RELATED APPLICATIONS
This application is a continuation-in-part of co-pending U.S. Ser. No. 941,493, filed 12-15-86, now abandoned which was a continuation-in-part of Ser. No. 828,936, filed Feb. 12, 1986, now abandoned which was a continuation-in-part of U.S. Ser. No. 784,279, filed Oct. 4, 1985, now U.S. Pat. No. 4,601,917 which was a continuation-in-part of U.S. Ser. No. 705,595 filed Feb. 26, 1985, and now abandoned; which was a continuation-in-part of U.S. Ser. No. 687,065, filed Dec. 28, 1984 and now abandoned; which was a continuation-in-part of U.S. Ser. No. 598,623, filed Apr. 10, 1984 and now abandoned.
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Continuation in Parts (6)
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Number |
Date |
Country |
Parent |
941493 |
Dec 1986 |
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Parent |
828936 |
Feb 1986 |
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Parent |
784279 |
Oct 1985 |
|
Parent |
705595 |
Feb 1985 |
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Parent |
687065 |
Dec 1984 |
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Parent |
598623 |
Apr 1984 |
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