Patent Application
20100062340
This invention relates to a negative electrode for nonaqueous electrolyte secondary batteries such as lithium secondary batteries and a process of producing the same.
The present inventors have proposed a nonaqueous secondary battery negative electrode comprising a pair of surface layers for current collection, each surface of which is in contact with an electrolyte and an active material layer containing a particulate active material having high capability of forming a lithium compound interposed between the surface layers (see US 2005/208379A1, US 2006/051675A1, and US 2006/115735A1). The surface layers of the negative electrode disclosed each have a thickness of 0.3 to 10 μm. The surface layer provided on the surface of the active material layer protects the active material particles from being exposed on the electrode surface. Therefore, even if the particles are pulverized as a result of expansion and contraction accompanying charge/discharge cycles, they are prevented from falling off. This type of a negative electrode provides a battery with prolonged cycle life.
The surface layer aforementioned has a large number of micropores extending in its thickness direction, through which a nonaqueous electrolyte is allowed to pass. A nonaqueous electrolyte is able to infiltrate the micropores of small size and reach the active material layer because it has a smaller surface tension than an aqueous one. If the surface layer has too large a thickness, however, it would be difficult for a nonaqueous electrolyte to reach the active material layer, so that the overpotential in initial charge tends to increase. It follows that lithium ions may be reduced on the surface of the surface layer to form a lithium dendrite during charge of the secondary battery, that the nonaqueous electrolyte can decompose to increase the irreversible capacity, and that the positive electrode can be damaged.
An object of the present invention is to provide a nonaqueous secondary battery negative electrode with further improved performance properties over the aforementioned conventional negative electrodes.
The present invention provides a nonaqueous secondary battery negative electrode having an active material layer containing a particulate active material. The active material layer has a metallic material which has low capability of forming a lithium compound and is deposited between the active material particles by electroplating. The active material layer has its surface coated continuously or discontinuously with a surface layer. The surface layer has an average thickness of 0.25 μm or smaller and comprises a metallic material which may be the same as or different from the metallic material.
The invention also provides a preferred process of producing the negative electrode. The process comprises the steps of forming a coating layer using a slurry containing a particulate active material, subjecting the coating layer to electroplating in a plating bath containing a metallic material having low capability of forming a lithium compound to deposit the metallic material in a direction from one side to the other side of the coating layer, stopping the electroplating before the metallic material is deposited across the whole thickness of the coating layer, and removing the part of the coating layer where the metallic material is not deposited.
The invention also provides a nonaqueous secondary battery negative electrode having an active material layer containing particles of an active material. The active material layer has a metallic material which has low capability of forming a lithium compound and is deposited between the particles by electroplating using a plating bath having a pH of 7.1 or higher. The surface of the particles inside the active material layer are coated with the metallic material. Voids are formed between the metallic material-coated particles. The proportion of the voids in the active material layer is from 15% to 40% by volume.
The present invention will be described based on its preferred embodiments by way of the accompanying drawing.
The active material layer 12 contains particles 12a of an active material. The active material layer 12 is formed by, for example, applying a slurry containing the active material particles 12a. The active material is exemplified by silicon based materials, tin based materials, aluminum based materials, and germanium based materials. Silicon based materials are particularly preferred to provide an improved capacity density per weight of a negative electrode. Examples of the silicon based material include those capable of intercalating lithium, such as elemental silicon, compounds of silicon and metal element(s), and silicon oxides.
As shown in
The surface of the active material particles 12a inside the active material layer 12 is coated with the deposited metallic material 13. It should be noted that the metallic material 13 does not cover the surface of the particles 12a in a manner that interferes with a nonaqueous electrolyte reaching the particles 12a. In other words, the metallic material 13 coats the surface of the particles 12a while securing gaps through which a nonaqueous electrolyte may reach the particles 12a.
The average thickness of the metallic material 13 covering the surface of the active material particles 12 is preferably as thin as 0.05 to 2 μm, more preferably 0.1 to 0.25 μm. With this minimum thickness, the active material particles 12a can be coated substantially continuously with the metallic material 13, thereby to prevent falling-off of the particles 12a having pulverized as a result of expansion and contraction accompanying charge/discharge cycles while improving the energy density. As used herein the term “average thickness” denotes an average calculated from the thicknesses in the part of the surface of the particle 12a that is actually coated with the metallic material 13. The non-coated part of the surface of the particle 12a is excluded from the basis of calculation. There are cases where the thickness of the metallic material 13 covering the surface of the active material particles 12a exceeds the thickness of the surface layer 14 hereinafter described. This phenomenon is attributed to the following cause. When the negative electrode 10 is produced by the process described later, the degree of electroplating differs between the particles 12a located deep in the active material layer 12 (i.e., near the current collector 11) and those located on the surface of the negative electrode 10. As a result, the particles 12a that are located deeper in the active material layer 12 are liable to be coated thicker with the metallic material 13.
Voids are formed between the particles 12a coated with the metallic material 13. The voids provide vacant spaces to serve to relax the stress resulting from volumetric changes of the active material particles 12a accompanying charge and discharge cycles. The volume gain of the active material particles 12a resulting from charging is absorbed by the voids. Therefore, the particles 12a are less liable to pulverize, and noticeable deformation of the negative electrode 10 is avoided effectively. The voids formed between the particles 12 also provide channels for a nonaqueous electrolyte. For all these considerations, the proportion of the voids in the active material layer 12 is preferably 15% to 40% by volume, still preferably 20% to 35% by volume. When the proportion of the voids is less than that proportion, it may be necessary to positively make holes by laser machining, punching or etching to secure necessary vacancy for the negative electrode, which can invite increase of production cost or impair production stability. The proportion of the voids is obtained through mapping by an electron microscope. The proportion of the voids can be controlled within the recited range by, for example, properly selecting the conditions for depositing the metallic material 13 between the particles 12a by electroplating. Such conditions include the composition and pH of the plating bath and the electrolytic current density.
The void volume is also controllable by proper selection of the particle size of the active material particles 12a. In this regard, the particles 12a preferably have a maximum particle size of 30 μm or smaller, still preferably 10 μm or smaller. The particle size of the particles 12a represented in terms of D50 is preferably 0.1 to 8 μm, still preferably 0.3 to 4 μm. The particle size of the particles can be measured by the laser diffraction-scattering method for particle size distribution or electron microscopic (SEM) observation.
If the amount of the active material based on the whole negative electrode is too small, the battery energy density is difficult to be improved sufficiently. If it is too large, the binding strength tends to be insufficient so that the active material is liable to fall off. A suitable amount of the active material for these considerations is 5% to 80%, more suitably 10% to 70%, even more suitably 20% to 50%, by weight based on the whole negative electrode.
The metallic material 13 having low capability of forming a lithium compound and precipitating in the active material layer 12 is an electroconductive material exemplified by copper, nickel, iron, cobalt, and their alloys. A highly ductile metallic material is preferred, which forms on the surface of the particle 12a a coat break-proof against expansion and shrinking of the particle 12a in the active material. A preferred example of such a material is copper. The expression “low capability of forming a lithium compound” as used herein means no capability of forming an intermetallic compound or a solid solution with lithium or, if any, the capability is such that the resulting lithium compound contains only a trace amount of lithium or is very unstable.
Some conventional negative electrodes for nonaqueous secondary batteries contain particles of an electroconductive material such as acetylene black or graphite in the active material layer to enhance the electron conductivity of the active material layer. It is preferred, however, for the negative electrode of the present embodiment to contain no or a minimized amount, if any, of electroconductive material particles in the active material layer, e.g., not more than 3% by weight based on the active material layer 12. The reason therefor will be explained later with respect to the process of producing the negative electrode 10, for which reason the most preferred material as an active material is elemental silicon.
As previously stated, it is preferred in the negative electrode of the present embodiment that the metallic material 13 is present across the whole thickness of the active material layer 12. This preferred manner of existence of the metallic material 13 in the whole thickness direction of active material layer 12 being defined to have an existence ratio of 100%, the present invention does not demand the existence ratio of the metallic material 13 is 100%. To put it another way, the metallic material 13 is not required to exist over the whole thickness of the active material layer 12. The inventors have revealed that the effects as desired are obtained as far as the existence ratio of the metallic material 13 in the active material layer 12 is 90% or more. At an existence ratio of less than 90%, the metallic material 13 can fail to prevent the particles 12a from falling off the active material layer 12. The existence ratio of the metallic material 13 in the active material layer 12 is obtained by observing a cross-section of the negative electrode 10 under a microscope. When the existence ratio of the metallic material 13 is 90%, for example, it means that the metallic material 13 exists in 90% of the thickness of the active material layer 12.
The negative electrode 10 of the present embodiment may or may not have a thin surface layer 14 on the surface of the active material layer 12. The surface layer 14 coats the active material layer 12 continuously or discontinuously. The average thickness of the surface layer 14 is as small as 0.25 μm or less, preferably 0.1 μm or less, still preferably 0.08 μm or less. There is no lower limit of the thickness of the surface layer 14, which means that the thickness may be zero. To have a zero thickness means that the negative electrode 10 has no surface layer, i.e., the active material layer 12 is not coated with the surface layer. In using a poorly electron-conductive active material such as silicon as an active material, the surface layer preferably has a thickness of more than zero, still preferably has an average thickness of 0.01 μm or more, to secure electron conductivity. The term “average thickness” as used here is a value calculated from the thicknesses including those measured in the part where the active material layer 12 is not coated with the surface layer 14. When the existence ratio of the metallic material 13 in the active material layer 12 is less than 100%, the active material layer 12 is generally not coated with the surface layer.
The negative electrode 10's having such a thin surface layer 14 or not having a surface layer enables decrease of overpotential of a secondary battery having the negative electrode 10 in the battery's assembling and initial charging. This means that lithium reduction on the surface of the negative electrode 10 can be prevented during charge. Reduction of lithium would lead to generation of a lithium dendrite, which causes a short circuit between the opposing electrodes. Decrease of overpotential is also advantageous to prevent decomposition of a nonaqueous electrolyte. Decomposition of a nonaqueous electrolyte will result in increase of irreversible capacity. Decrease of overpotential is also beneficial to protect a positive electrode from being damaged. The negative electrode 10's having such a thin surface layer 14 or not having a surface layer provides the advantage of improving capacity density of a secondary battery having the negative electrode.
In cases where the negative electrode 10 has the surface layer 14, the surface layer 14 coats the surface of the active material layer 12 either continuously or discontinuously. As the surface layer 14 becomes thinner, the coat of the surface layer changes from continuous to discontinuous. As the thickness becomes further smaller, the surface layer 14 is fine particles 13a of the metallic material 13 adhered to the particles 12a on and near the surface of the active material layer 12 as shown in
In cases where the surface layer 14 continuously coats the surface of the active material layer 12, it is preferred for the surface layer 14 to have a number of micropores (not shown) open on its surface and connecting to the active material layer 12. The micropores preferably extend in the thickness direction of the surface layer 14. The micropores enable passage of a nonaqueous electrolyte. The role of the micropores is to supply a nonaqueous electrolyte into the active material layer 12. The amount of the micropores is preferably such that when the negative electrode 10 is observed from above by an electron microscope, the ratio of the area covered with the metallic material 13, namely a coating ratio, is not more than 95%, more preferably 80% or less, even more preferably 60% or less.
According to conventional techniques, coating the surface of the active material layer 12 with a surface layer has been considered effective to prevent falling-off of the active material having pulverized through charge/discharge cycles. Although this idea itself is true, the inventors have found that falling-off of the active material resulting from pulverization with charge/discharge cycles may be prevented without forming a surface layer if the state of existence of the metallic material 13 in the active material layer 12 is properly controlled. Specifically, it has been revealed that falling-off of the active material pulverized with charge/discharge cycles can be prevented without forming a surface layer by coating the surface of the particles 12a in the active material layer 12 with the metallic material 13 and providing adequate voids between the coated particles 12a. In view of this, the surface layer functions sufficiently with a minimized small thickness, and, in some cases, the surface layer may be dispensed with. To provide no surface layer is advantageous to prevent lithium dendrite formation and to increase the battery energy density.
The surface layer 14 is made up of a metallic material having low capability of forming a lithium compound. The metallic material of the surface layer 14 may be the same as or different from the metallic material present in the active material layer 12. Taking into consideration ease of production of the negative electrode 10, the metallic material present in the active material layer 12 and the metallic material fanning the surface layer 14 are preferably the same.
Any current collector conventionally used in negative electrodes for nonaqueous secondary batteries can be used as the current collector 11 of the negative electrode 10. The current collector 11 is preferably made out of the above-described metallic material having low capability of forming a lithium compound, examples of which are given supra. Current collectors made of copper, nickel or stainless steel are particularly preferred. Copper alloy foil typified by Corson alloy foil is also usable. While not critical in the present embodiment, the thickness of the current collector 11 is preferably 9 to 35 μm in view of the balance between retention of strength of the negative electrode 10 and improvement of energy density.
A preferred process of producing the negative electrode 10 of the present embodiment will then be described with reference to
As illustrated in
The coating layer 15 thus formed has a number of fine interstices between the particles 12a. The current collector 11 with the coating layer 15 is then immersed in a plating bath containing a metallic material having low capability of forming a lithium compound. Whereupon, the plating bath infiltrates into the interstices of the coating layer 15 and reaches the interface between the coating layer 15 and the current collector 11. In this state, electroplating is carried out (this plating will hereinafter be sometimes called penetration plating). Penetration plating is carried out by immersing the current collector 11 as a cathode and a counter electrode (anode) in the plating bath and connecting the two electrodes to a power source.
In the process, it is important to control the deposition of the metallic material during penetration plating. In detail, it is important to have the metallic material deposited in a direction from one side to the opposite side of the coating layer 15. Specifically, electroplating is carried out in a manner such that deposition of the metallic material 13 proceeds from the interface between the coating layer 15 and the current collector 11 toward the surface of the coating layer 15 as illustrated in
The conditions of penetration plating for depositing the metallic material 13 as described include the composition and pH of the plating bath and the electrolytic current density. In using elemental silicon as an active material, for instance, the pH of the plating bath is preferably 7.1 or higher, more preferably 7.1 to 11. With a plating bath at pH 7.1 or higher, the surface of the active material particles 12a is cleaned to have a uniform surface condition, which enables uniform deposition of the metallic material 13 thereon, while leaving moderate voids between the particles 12a. With a plating bath at pH 11 or lower, appreciable dissolution of the particles 12a may be prevented. The pH values recited here are those measured at the penetration plating temperature. In penetration plating with copper as a metallic material, a copper pyrophosphate plating bath is preferably used. In using nickel as a metallic material, an alkaline nickel bath, for example, is preferably used. To use a copper pyrophosphate plating bath is advantageous in that the aforementioned voids can easily be formed throughout the thickness of the active material layer even when the active material layer has an increased thickness. Using a copper pyrophosphate bath provides an additional advantage that the metallic material 13, while being deposited on the surface of the active material particles 12a, is hardly deposited between the particles 12a so as to leave vacant spaces therebetween. The copper pyrophosphate bath to be used preferably has the following composition and pH.
When in using an alkaline nickel bath, the nickel salt to be used is exemplified by nickel sulfate hexahydrate. An ammonium salt, e.g., ammonium chloride, can be used as an alkali source to make the bath alkaline. The bath may further contain boric acid, etc. in addition. A preferred composition and a preferred pH of the bath are as follows.
Penetration plating using the plating baths described above results in selective deposition of the metallic material on the active material particle surface to coat the particle surface with the metallic material. Plating using the copper pyrophosphate bath is preferred to plating using the alkaline nickel plating bath because the former tends to form adequate vacant spaces in the active material layer 12 thereby providing a negative electrode with a prolonged life as compared with the latter plating.
When the coating layer contains particles of an electroconductive material, the electroconductive material particles serve as precipitation sites so that the metallic material 13 is apt to be deposited on the electroconductive material particles in preference to deposition from the interface between the coating layer 15 and the current collector 11. It may follow that the metallic material 13 cannot be successfully deposited while forming voids as desired between the active material particles 12a. To avoid this, it is desirable that the coating layer contains no or a small amount, if any, of particles of an electroconductive material.
As shown in
The electroplating is stopped before the metallic material 13 is deposited throughout the whole thickness of the coating layer 15. At this point, the metallic material 13 has not deposited on the surface and the region near the surface of the coating layer 15 as shown in
The region R can be removed by, for example, applying water jets or rubbing with a soft material such as sponge. Water jetting is preferred in terms of production efficiency because washing with water after electroplating and removal of the region R can be accomplished simultaneously. When water jetting is applied, it is advisable to use a water-soluble binder in the slurry to be used to form the coating layer 15 so as to facilitate removal of the region R. Such a binder is exemplified by styrene-butadiene rubber (SBR). Since the inside of the active material layer has undergone penetration plating, the active material layer itself is not destroyed even if the water soluble binder is dissolved and removed by the water jetting operation.
The surface condition of the resulting negative electrode 10 varies depending on the degree of removal of the region R. When, for example, a strong water jet is applied, the region R is removed to a considerable degree, and the fine particles 13a of the metallic material 13 that are distributed like islands on the surface of the active material particles 12a are completely removed, on the surface of the negative electrode 10, only leaving a thin surface layer 14 formed of a continuous film of the metallic material 13. When, on the other hand, a weak water jet is used, removal of the region R is not so remarkable, leaving a thin surface layer 14 formed of discontinuous film of the metallic material 13, or a discontinuous surface layer 14 composed of the fine particles 13a of the metallic material 13 distributed like islands on the surface of the active material particles 12a, or no surface layer on the surface of the negative electrode 10.
The thus obtained negative electrode 10 is well suited for use in nonaqueous secondary batteries, e.g., lithium secondary batteries. The positive electrode to be used is obtained as follows. A positive electrode active material and, if necessary, an electroconductive material and a binder are mixed in an appropriate solvent to prepare a positive electrode active material slurry. The active material slurry is applied to a current collector, dried, rolled, and pressed, followed by cutting and punching. Conventional positive electrode active materials can be used, including lithium-nickel composite oxide, lithium-manganese composite oxide, and lithium-cobalt composite oxide. Preferred separators to be used in the battery include nonwoven fabric of synthetic resins and a porous film of polyethylene or polypropylene. The nonaqueous electrolyte is a solution of a lithium salt, a supporting electrolyte, in an organic solvent. Examples of the lithium salt include LiClO4, LiAlCl4, LiPF6, LiAsF6, LiSbF6, LiSCN, LiCl, LiBr, LiI, LiCF3SO3, and LiC4F9SO3.
The present invention will now be illustrated in greater detail with reference to Examples, but it should be understood that the invention is not construed as being limited thereto.
A 18 μm thick electrolytic copper foil as a current collector was cleaned with an acid at room temperature for 30 seconds and washed with pure water for 15 seconds. A slurry containing Si particles was applied to the current collector to a thickness of 15 μm to form a coating layer. The particles had a median particle size D50 of 2 μm. The slurry contained the particles and styrene-butadiene rubber (binder) at a weight ratio of 100:1.7 with no electroconductive particles.
The current collector having the coating layer was immersed in a copper pyrophosphate bath having the following composition, and the coating layer was penetration-plated with copper by electrolysis under the following conditions to form an active material layer. A DSE was used as a positive electrode, and a direct current power source was used.
The penetration plating was stopped before copper was deposited throughout the thickness of the coating layer. The current collector having the penetration-plated coating layer was taken out of the plating bath. Water jets were applied to the coating layer under a water pressure of 1 Mpa to remove the region where copper had not been deposited. The current collector with the coating layer was then dried in the atmosphere to provide a negative electrode having the structure shown in
A negative electrode was made in the same manner as in Example 1, except for changing the water jet pressure to 2 MPa. The surface of the resulting negative electrode was observed with an electron microscope to obtain the micrograph of
A negative electrode was made in the same manner as in Example 1, except that the water jets were not applied and that the copper penetration plating time was adjusted so that the existence ratio of copper (metallic material 13) in the active material layer is 90%. The results of electron microscopic observation on the surface of the active material layer revealed absence of a copper surface layer. The active material particles inside the active material layer were found coated with an average thickness of 0.18 μm of copper layer as measured within the region of the active material layer where copper had penetrated. As a result of electron microscopic mapping of copper presence in the region of the active material where copper had penetrated, the proportion of the voids in the region was found to be 28% by volume.
A negative electrode was made in the same manner as in Example 1, except that the water jets were not applied and that the copper penetration plating time was adjusted so as to form a surface layer with an average thickness of 0.23 μm. The results of electron microscopic observation on the surface of the resulting negative electrode revealed that the surface layer had micropores extending in its thickness direction. The active material particles inside the active material layer were found coated with an average thickness of 0.18 μm of copper layer. As a result of electron microscopic mapping of copper presence, the proportion of the voids in the active material layer was found to be 28% by volume.
A negative electrode was obtained in the same manner as in Example 1 with the following exceptions. The copper pyrophosphate plating bath used in Example 1 was replaced with a copper sulfate bath containing 250 g/l of CuSO4 and 70 g/l of H2SO4. The penetration plating was conducted at a current density of 5 A/dm2. The penetration plating was carried out to deposit copper throughout the whole thickness of the coating layer and further continued until a 3 μm thick surface layer of copper was formed on the coating layer. As a result of electron microscopic mapping of copper presence, the proportion of the voids in the active material layer was found to be 10% by volume.
Each of the negative electrodes obtained in Examples 1 to 4 and Comparative Example 1 was assembled into a lithium secondary battery together with LiCo1/3Ni1/3Mn1/3O2 as a positive electrode and an electrolyte prepared by dissolving LiPF6 in a 1:1 by volume mixed solvent of ethylene carbonate and diethyl carbonate in a concentration of 1 mol/l and externally adding 2% by volume of vinylene carbonate to the solution. The resulting secondary battery was subjected to a first charge operation. The charging curve obtained in the first charge is shown in
Twenty lithium secondary batteries were made in the same manner as in Evaluation 1 per each of the negative electrodes of Examples 1 to 4 and Comparative Example 1. The batteries were charged and discharged up to 50 cycles under the following conditions, and the rate of occurrence of a short-circuit was measured. The results are shown in Table 1. The charge/discharge rate was 1C. The charging was conducted at a constant current to 4.2 V. On reaching 4.2 V, the voltage was maintained constant. When the current reached ⅕, the charging was stopped. The discharging was carried out at a constant voltage to 2.7 V, at which the discharge was stopped.
The results in Table 1 apparently prove that the secondary batteries using the negative electrodes of Examples have a markedly lower rate of occurrence of short-circuits than the batteries using the negative electrode of Comparative Example 1. This is considered to be because lithium reduction on the surface of the negative electrode and the resulting dendrite growth are prevented in the secondary batteries of Examples during charge.
According to the invention, even if the particles of an active material pulverize through repeated expansion and contraction accompanying charge/discharge cycles, the particles are prevented from falling off. A nonaqueous electrolyte is allowed to reach the active material layer easily, so that the overpotential in the initial charge is reduced, whereby lithium dendrite growth on the negative electrode surface is prevented. The nonaqueous electrolyte hardly decomposes, and an increase of irreversible capacity is prevented. The positive electrode is protected from damage.
| Number | Date | Country | Kind |
|---|---|---|---|
| 200--323892 | Nov 2005 | JP | national |
| Filing Document | Filing Date | Country | Kind | 371c Date |
|---|---|---|---|---|
| PCT/JP2006/322167 | 11/7/2006 | WO | 00 | 4/21/2008 |
