Patent Application
20120128527
1. Field of Endeavor
The invention deals with the field of materials science. It relates to a nickel-base superalloy, in particular for the production of single-crystal components (SX alloy) or components with a directionally solidified microstructure (DS alloy), such as for example blades or vanes for gas turbines, but also for conventionally cast components.
2. Brief Description of the Related Art
Nickel-base superalloys of the aforementioned type are known. Single-crystal components made from these alloys have a very good material strength at high temperatures. This allows, for example, the intake temperature of gas turbines to be increased, with the result that the efficiency of the gas turbine rises.
Nickel-base superalloys for single-crystal components, as are known from U.S. Pat. No. 4,643,782, EP 0 208 645 and U.S. Pat. No. 5,270,123, for this purpose contain alloying elements which strengthen the solid solution, for example Re, W, Mo, Co, Cr, and elements which form γ′ phases, for example Al, Ta and Ti. The level of high-melting alloying elements (W, Mo, Re) in the basic matrix (austenitic γ phase) increases continuously as the temperature of load on the alloy increases. For example, standard nickel-base superalloys for single crystals contain 6-8% W, about 3-6% Re and up to 2% Mo (in % by weight). The alloys disclosed in the abovementioned documents have a high creep strength, good LCF (low cycle fatigue) and HCF (high cycle fatigue) properties and a high resistance to oxidation.
These known alloys were developed for aircraft turbines and were therefore optimized for short-term and medium-term use, i.e., the load time was designed for up to 20 000 hours. By contrast, industrial gas turbine components have to be designed for a load time of up to 75 000 hours, i.e., for long-term loading.
By way of example, after a load time of 300 hours, the alloy CMSX-4, which is known from U.S. Pat. No. 4,643,782, when it was tested for use in a gas turbine at a temperature of over 1000° C., underwent considerable coarsening of the γ′ phase, which disadvantageously leads to an increase in the creep rate of the alloy.
On account of the long-term loading of gas turbines, it is therefore necessary to improve the resistance of the known alloys to oxidation at very high temperatures.
It is known from GB 2 234 521 A that enriching nickel-base superalloys with boron or carbon during a directional solidification produces microstructures which have an equiaxed or prismatic grain structure. Carbon and boron strengthen the grain boundaries, since C and B cause the precipitation of carbides and borides at the grain boundaries, and these compounds are stable at high temperatures. Moreover, the presence of these elements in and along the grain boundaries delays the diffusion process, which is a primary cause of the grain boundary weakness. It is therefore possible to increase the misorientations (usually 6°) to 10° to 12° yet still achieve good properties of the material at high temperatures.
EP 1 359 231 B1 discloses a nickel-base superalloy which has improved casting properties and a higher resistance to oxidation than known nickel-base superalloys and is additionally suitable, for example, particularly for large gas turbine single-crystal components having a length of >80 mm. The nickel-base superalloy disclosed therein is characterized by the following chemical composition (details in % by weight): 7.7-8.3 Cr, 5.0-5.25 Co, 2.0-2.1 Mo, 7.8-8.3 W, 5.8-6.1 Ta, 4.9-5.1 Al, 1.3-1.4 Ti, 0.11-0.15 Si, 0.11-0.15 Hf, 200-750 ppm C, 50-400 ppm B, remainder nickel and production-related impurities. A preferred alloy having the composition (in % by weight): 7.7-8.3 Cr, 5.0-5.25 Co, 2.0-2.1 Mo, 7.8-8.3 W, 5.8-6.1 Ta, 4.9-5.1 Al, 1.3-1.4 Ti, 0.11-0.15 Si, 0.11-0.15 Hf, 200-300 ppm C, 50-100 ppm B, remainder nickel and production-related impurities, is outstandingly suitable for producing large single-crystal components, for example blades or vanes for gas turbines.
One of numerous aspects of the invention includes an alloy which, compared to the alloys known from the prior art, can be distinguished by a further optimization in properties with respect to the use as a gas turbine component. Another of these aspects includes a nickel-base superalloy which has a high resistance to oxidation and, at the same time, a high resistance to corrosion (given a differing fuel quality) and is additionally, advantageously less expensive compared to known nickel-base superalloys of this type.
In another aspect, a nickel-base superalloy is characterized by the following chemical composition (in % by weight):
Advantages of the alloys embodying principles of the present invention include that the alloy has a very high resistance to oxidation and, at the same time, a high resistance to corrosion at high temperatures. This is surprisingly achieved primarily by the relatively small addition of Re.
It is particularly advantageous if the alloy comprises 1.0-1.5% by weight, preferably 1.5% by weight, Re. If the C content is only about 200-300 ppm and the boron content is 50-100 ppm, preferably 90 ppm, alloys embodying principles of the present invention are particularly suitable for producing single-crystal components. The alloy can optionally comprise up to 0.5% by weight, preferably 0.1-0.2% by weight, Nb.
A particularly preferred nickel-base superalloy has the following composition (in % by weight):
A further advantageous alloy composition is specified hereinbelow (in % by weight):
The drawings show an exemplary embodiment of the invention.
The invention is explained in more detail below with reference to an exemplary embodiment and
Nickel-base superalloys having the chemical composition given in table 1 were investigated (in % by weight):
The alloy IN738LC is a comparative alloy known from the prior art, KNX0 is likewise a comparative alloy (according to EP 1 359 231 B1), whereas the alloys KNX1 to KNX4 are alloys according to the invention. Here, the addition CC is an abbreviation for “conventionally cast”, i.e., conventionally cast alloys having a conventional multi-crystal microstructure, and the addition DS is an abbreviation for “directionally solidified”, i.e., for a directionally solidified microstructure.
The alloys according to the invention and the comparative alloy differ, for example, in that the comparative alloy, in contrast to the alloys according to the invention, does not contain C, Si, Hf and Re as alloying elements.
Carbon, primarily also with the boron present, strengthens the grain boundaries, in particular also the small-angle grain boundaries which occur in the <001> direction in SX or DS gas turbine blades or vanes made from nickel-base superalloys, since these elements cause the precipitation of carbides/borides at the grain boundaries, and these compounds are stable at high temperatures. Moreover, the presence of C in and along the grain boundaries reduces the diffusion process, which is a primary cause of the grain boundary weakness. This considerably improves the casting properties of long single-crystal components, for example gas turbine blades or vanes with a length of about 200 to 230 mm.
If nickel-base superalloys with small contents of C and B (max. 200-300 ppm C and 50-100 ppm B) are selected, these can be used as single-crystal alloys; at higher contents of these elements (max 0.17 C, max 400 ppm B)), the components produced from corresponding alloys can also be conventionally cast.
The addition of 0.11 to 0.15% by weight Si, in particular in combination with Hf in the given order of magnitude, significantly improves the resistance to oxidation at high temperatures compared to the nickel-base superalloy known from the prior art (see, for example,
Al and Cr, in the given quantities, also bring about a good resistance to oxidation for the nickel-base superalloys described herein. Moreover, Cr, in conjunction with the Si, also has a positive effect on improving the resistance to corrosion.
Re, W, Mo, Co and Cr are alloying elements which strengthen the solid solution, and Al, Ta and Ti are elements which form γ′ phases, which all improve the material strength at high temperatures. Since, in this respect, particularly the content of high-melting alloying elements (W, Mo, Re) in the basic matrix is considered decisive for an increase in the maximum possible temperature of load on the alloy, these alloying elements, primarily the Re, have been added in relatively large quantities to date.
The moderate rhenium content of the nickel-base superalloy according to principles of the present invention, preferably 1.5% by weight, advantageously firstly increases the creep strength of the alloy, and secondly this alloying element does not entail such extremely high costs, as arise for example in the case of the second and third generation nickel-base single-crystal superalloys known from the prior art, which have relatively high rhenium contents (about 3 to 6% by weight Re).
Before the tensile strength samples were produced, the material was subjected to the following heat treatment:
It can readily be seen in
It is also clear from
It goes without saying that the invention is not restricted to the exemplary embodiments described.
While the invention has been described in detail with reference to exemplary embodiments thereof, it will be apparent to one skilled in the art that various changes can be made, and equivalents employed, without departing from the scope of the invention. The foregoing description of the preferred embodiments of the invention has been presented for purposes of illustration and description. It is not intended to be exhaustive or to limit the invention to the precise form disclosed, and modifications and variations are possible in light of the above teachings or may be acquired from practice of the invention. The embodiments were chosen and described in order to explain the principles of the invention and its practical application to enable one skilled in the art to utilize the invention in various embodiments as are suited to the particular use contemplated. It is intended that the scope of the invention be defined by the claims appended hereto, and their equivalents. The entirety of each of the aforementioned documents is incorporated by reference herein.
| Number | Date | Country | Kind |
|---|---|---|---|
| 01069/09 | Jul 2009 | CH | national |
This application is a Continuation of, and claims priority under 35 U.S.C. §120 to, International Application No. PCT/EP2010/059368, filed 1 Jul. 2010, and claims priority therethrough under 35 U.S.C. §§119, 365 to Swiss Application No. 01069/09, filed 9 Jul. 2009, the entireties of which are incorporated by reference herein.
