Claims
- 1. A nitro-substituted heterocyclic compound of the formula (I): ##STR324## wherein R represents hydrogen or C.sub.1-4 -alkyl;
- Z represents C.sub.6-10 -aryl, or a 5- to 6-membered heterocyclic group containing 1 to 2 hetero atoms selected from the group consisting of O, S and N, at least one of which is a nitrogen atom, and said aryl and heterocyclic group is unsubstituted or substituted by a member selected from the group consisting of halogen, C.sub.1-4 -alkyl, C.sub.1-4 -alkoxy, C.sub.1-4 -haloalkyl, C.sub.1-4 -alkylthio, C.sub.1-4 -haloalkoxy, C.sub.1-4 -haloalkylthio, nitro, and cyano;
- A represents unsubstituted ethylene or ethylene substituted by methyl; and
- B represents 3 members of a heterocyclic ring which is formed, together with the adjacent C-atom and N-atom, wherein 2 members are carbon atoms and 1 member is an oxygen or sulfur atom, or wherein 1 member is a carbon atom, 1 member is a nitrogen atom and 1 member is a sulfur atom, and the members of B are unsubstituted or substituted by at least one substituent selected from the group consisting of halogen, C.sub.1-6 -alkyl, C.sub.1-4 -alkoxy, alkoxycarbonyl having 1 to 4 carbon atoms in the alkoxy part, unsubstituted or substituted C.sub.6-10 -aryl, keto, imino, phenoxy, C.sub.1-4 -alkoxythio, alkoxycarbonylimino having 1 to 4 carbon atoms in the alkoxy part, phenoxycarbonylimino, benzoylimino, benzyl, cyano, thioketo, hydroxy and C.sub.1-2 -alkylidene and the sulfur atoms of B are unbound or bound to one or two extracyclic oxygen atoms.
- 2. A nitro-substituted heterocyclic compound according to claim 1, wherein
- R represents hydrogen or methyl;
- Z represents phenyl, or a 5- to 6-membered heterocyclic group containing 1 to 2 hetero atoms selected from the group consisting of O, S and N, at least one of which is a nitrogen atom, and said phenyl and heterocyclic group is unsubstituted or substituted respectively by one or two substituents selected from the group consisting of fluorine, chlorine, bromine, methyl, ethyl, methoxy, trifluoromethyl, methylthio, trifluoromethoxy, nitro and cyano;
- A represents unsubstituted ethylene or ethylene substituted by methyl; and
- B represents 3 members of a heterocyclic ring which is formed, together with the adjacent C-atom and N-atom, wherein 2 members are carbon atoms and 1 member is an oxygen or sulfur atom, or wherein 1 member is a carbon atom, 1 member is a nitrogen atom and 1 member is a sulfur atom, and the members of B are unsubstituted or substituted by at least one substituent selected from the group consisting of fluorine, chlorine, bromine, methyl, methoxy, alkoxycarbonyl having 1 to 2 carbon atoms in the alkoxy part, phenyl, keto, imino, phenoxy, alkoxycarbonylimino having 1 to 2 carbon atoms in the alkoxy part, phenoxycarbonylimino, benzoylimino, benzyl, cyano, thioketo, hydroxy and C.sub.1-2 -alkylidene.
- 3. An arthropod pesticidal composition comprising an arthropod pesticidally effective amount of at least one nitro-substituted heterocyclic compound according to claim 1 in admixture with a diluent.
- 4. A method for combating harmful arthropod pests comprising applying to said arthropod pests and/or their habitat an arthropod pesticidally effective amount of at least one nitro-substituted heterocyclic compound according to claim 1.
Priority Claims (1)
Number |
Date |
Country |
Kind |
62-15728 |
Jun 1987 |
JPX |
|
Parent Case Info
This is a division of application Ser. No. 08/126,950, filed Sep. 27, 1993 now U.S. Pat. No. 5,366,976, which is a division of application Ser. No. 07/998,337, filed Dec. 30, 1992, now U.S. Pat. No. 5,290,779, which is a division of application Ser. No. 07/823,240, filed Jan. 21, 1992, now U.S. Pat. No. 5,231,098, which is a division of Ser. No. 699,068, filed May 13, 1991, now U.S. Pat. No. 5,122,527, which is a division of application Ser. No. 510,509, filed Apr. 18, 1990, now U.S. Pat. No. 5,036,082, which is a division of application Ser. No. 353,370, filed May 17, 1989, now U.S. Pat. No. 4,960,780, which is a division of application Ser. No. 208,421, filed Jun. 17, 1988, now U.S. Pat. No. 4,876,263.
US Referenced Citations (5)
Foreign Referenced Citations (2)
Number |
Date |
Country |
0247477 |
Dec 1987 |
EPX |
3638121 |
Dec 1987 |
DEX |
Non-Patent Literature Citations (10)
Entry |
Soloway et al, Advances in Pesticide Science, Part 2, Pergamon Press. pp. 206-217 (1978). |
Paterson et al., J. C. S. Perkin I, pp. 1051-1056 (1972). |
Schroeder et al., Pesticide Biochem. and Physiology, 22, pp. 148-160 (1984). |
Chemische Berichte, 1986, vol. 119, pp. 2208-2219, Huang et al. |
J. Chem. So.c, 1979, pp. 2361-2363, Viswanathan et al. |
Heterocycles, 1980, vol. 15, pp. 437-453, Uhlmann et al. |
Heterocycles an International Journal for Reviews and Communications in Heterocyclic Chemistry, vol. 15, No. 1, 1981 Eugen Uhlmann and Wolfgang Pfleiderer pp. 437-453. |
Journal of the Chemical Society, 4-Nitro-1, 2, 3-Triazoles from Nitor-a-B-Unsaturated Gem-Diamines; Narayana Lyer Viswanathan and Venkstachalsm Balakrishnan pp. 2361-2362 (1979). |
Journal of Heterocyclic Chemistry, vol. 17 No. 5, Jul. 1980 Kurt Pilgram "Synthesis of 2, 3-Dihydro-1-H-Imidazo [1,2-b]-Pyrazoles. " pp. 1413-1416. |
Chemische Berichte; Synthesis of Ketene Aminals with an Imidazolidine Ring of Concensation of 4, 5-Dihydro-2-(Methylthio)-1H-Imidazoles with Active Methylene Compounds and Some Additon and Cyclocondensation Reactions; Zhi-Tang Hunang and Lu-hang Tzai Chem; Ber. 119, pp. 2208-2219 (1986). |
Divisions (7)
|
Number |
Date |
Country |
Parent |
126950 |
Sep 1993 |
|
Parent |
998337 |
Dec 1992 |
|
Parent |
823240 |
Jan 1992 |
|
Parent |
699068 |
May 1991 |
|
Parent |
510509 |
Apr 1990 |
|
Parent |
353370 |
May 1989 |
|
Parent |
208421 |
Jun 1988 |
|