Non-chromate primer for painting

Information

  • Patent Grant
  • 7572324
  • Patent Number
    7,572,324
  • Date Filed
    Wednesday, May 14, 2008
    16 years ago
  • Date Issued
    Tuesday, August 11, 2009
    15 years ago
Abstract
The present invention uses titanate compounds to replace chromates in metal primer paints used for corrosion protection on metal substrates.
Description
BACKGROUND OF THE INVENTION

(1) Field of the Invention


The present invention is directed to corrosion protection of stainless steel and aluminum alloys. In particular, the present invention is directed to a unique use of titanate compounds to replace chromates in metal primer paints used for corrosion protection on metal substrates.


(2) Description of the Prior Art


Currently, technology is being sought that for a non-chromate conversion coating of certain types of aluminum. Included in this work are potential candidates including: acidic aqueous solutions containing potassium permanganate and cerous chloride, silane based materials, sol-gel technologies, vapor deposition processes, thermal spray technologies including high velocity oxygen and flame spray technologies, and anodizing using sulfuric acid/boric acid processes. Other chromate free conversions being considered are those that form a thin layer of aluminum oxyhydroxide, which is then sealed using solutions of metallic salts and organic compounds. Work has also been conducted that focused on organo-functional silanes as a possible replacement candidate for protecting aluminum and stainless steel alloys. Methods have been studied on titanium substrates to replace conventional acid etch and zinc chromate preparations. Silanes were investigated due to their good coupling agent capabilities to form covalent bonds with the titanium oxides sites on one side and the structural adhesive coatings on the other side. This covalent bonding and the hydrophobic nature of the silanes restrict bond degradation.


SUMMARY OF THE INVENTION

It is a general purpose and object of the present invention to produce a primer for painting aluminum and steel alloys that does not have any chromates.


The above objects are accomplished with the present invention by using solvents in combination with titanates to replace zinc chromate







DETAILED DESCRIPTION OF THE INVENTION

The present invention will seek to replace chromates with titanates in primer for painting. The formulation for a non-chromate primer for painting is as follows: xylene 4% by wt, 2-propanol, 27% by wt, 2-butoxyethanol 10% by wt, methyl isobutyl ketone 9% by wt, ethanol 2% by wt, isopropyl acetate 3% by wt, dibutyl phthalate 1% by wt, talc 27.8% by wt, titanium dioxide 5% by wt, carbon black 0.2% by wt, titanium zinc oxide 6% by wt and toluene 5% by wt.

Claims
  • 1. A primer for painting comprising: xylene 4% by wt;2-propanol 27% by wt;2-butoxyethanol 10% by wt;methyl isobutyl ketone 9% by wt;ethanol 2% by wt;isopropyl acetate 3% by wt;dibutyl phthalate 1% by wt;talc 27.8% by wt;titanium dioxide 5% by wt;carbon black 0.2% by wt;titanium zinc oxide 6% by wt; andtoluene 5% by wt.
STATEMENT OF GOVERNMENT INTEREST

The invention described herein may be manufactured and used by or for the Government of the United States of America for governmental purposes without the payment of any royalties thereon or therefore.

US Referenced Citations (19)
Number Name Date Kind
4014703 Hayati et al. Mar 1977 A
5266611 Teschendorf Nov 1993 A
5708039 Daly et al. Jan 1998 A
5888655 Harris et al. Mar 1999 A
5951747 Lewis et al. Sep 1999 A
6059867 Lewis et al. May 2000 A
6451443 Daech Sep 2002 B1
6475300 Shimakura et al. Nov 2002 B2
6482274 Shimakura et al. Nov 2002 B2
6482536 Tanaka et al. Nov 2002 B1
6583187 Daly et al. Jun 2003 B1
6638369 Tucker et al. Oct 2003 B1
6696106 Schultz et al. Feb 2004 B1
6706207 Tucker et al. Mar 2004 B2
6726916 Ramin Apr 2004 B1
7001533 Tucker et al. Feb 2006 B2
7022254 Tucker et al. Apr 2006 B2
7101808 Tucker et al. Sep 2006 B2
20060233958 Matsumura et al. Oct 2006 A1