Claims
- 1. A method of microbial or chemical decontamination comprising:
exposing an item to be microbially or chemically decontaminated to a multi-component vapor which includes a gaseous oxidant and a second vapor component; and detecting the gaseous oxidant in the multi-component vapor including:
directing light through the multi-component vapor, the directed light including light of at least a first wavelength range where the gaseous oxidant absorbs but at which second vapor component does not significantly absorb, the first wavelength range including one or more wavelengths between about 7500 and 8400 nanometers, detecting the absorbance of light which has passed through the vapor in the first wavelength range, and determining the concentration of the gaseous oxidant in the multi-component vapor from the detected absorbance.
- 2. The method of claim 1, wherein the gaseous oxidant includes hydrogen peroxide.
- 3. The method of claim 1, wherein the second vapor component includes water and the directed light further includes light of a second wavelength range, the second wavelength range being spaced from the first wavelength range, where water absorbs and the gaseous oxidant does not significantly absorb, the step of detecting the absorbance of light further including:
detecting the absorbance of light in the second wavelength range; and determining the concentration of water in the multi-component vapor from the detected absorbance in the second wavelength range.
- 4. The method of claim 3, wherein the second wavelength range is in the range of from about 5200 nanometers to about 7200 nanometers.
- 5. The method of claim 1, wherein the directed light further includes light of a third wavelength range, the third wavelength range being spaced from the first and second wavelengths, where both the second vapor component and the gaseous oxidant do not significantly absorb, the method further including:
detecting the absorbance of light in the third wavelength range; and determining a background absorption value from the detected absorbance detecting the absorbance of light in the third wavelength range.
- 6. The method of claim 1, further including:
in response to the determined concentration of the gaseous oxidant being outside a preselected concentration range, controlling at least one of:
a length of time to which the item is exposed to the vapor; a pressure of the vapor; a temperature of the vapor; and a rate at which the gaseous oxidant is added to the vapor; to maintain selected decontamination conditions whereby the item is effectively decontaminated.
- 7. The method of claim 6, further including monitoring at least one of:
the pressure of the vapor; the temperature of the vapor; and the relative humidity of the vapor.
- 8. The method of claim 6, wherein the gaseous oxidant is hydrogen peroxide and the step of controlling the rate at which hydrogen peroxide is added to the vapor includes controlling the rate at which liquid hydrogen peroxide is admitted to a vaporizer which generates the multi-component vapor.
- 9. The method of claim 8, wherein the step of controlling includes maintaining the concentration of hydrogen peroxide in the vapor below its saturation point, whereby condensation of vapor on the item is minimized.
- 10. The method of claim 1, further including:
passing a first portion of the light which has passed through the vapor through a first filter which is selective for light in the first wavelength range; and detecting the absorption of light which has been filtered by the first filter with a first detector.
- 11. The method of claim 10, further including:
passing a second portion of the light which has passed through the vapor through a second filter which is selective for light in a second wavelength range at which water absorbs, but at which hydrogen peroxide does not significantly absorb; and detecting the absorption of light which has been filtered by the second filter with a detector.
- 12. The method of claim 11, where the detector which detects the absorption of light which has been filtered by the second filter is the first detector and the method further includes:
moving the first and second filters such that the first detector sequentially receives light which has passed through the first filter and light which has passed through the second filter.
- 13. The method of claim 1, wherein the step of detecting includes:
detecting the absorbance of light which has passed through the vapor over a first portion of the first wavelength range when the gaseous oxidant concentration is above a threshold value, and detecting the absorbance of light which has passed through the vapor over a second portion of the first wavelength range when the gaseous oxidant concentration is below the threshold value, the absorbance of gaseous oxidant in the second portion of the first wavelength range being higher than the absorbance of gaseous oxidant in the first portion of the first wavelength range.
- 14. The method of claim 13, wherein the gaseous oxidant is hydrogen peroxide and at least one of the following conditions applies:
the first portion of the first wavelength range includes wavelengths of no less than about 8200 nm; and the first and second portions of the first wavelength range are overlapping.
- 15. The method of claim 1, wherein the method further includes:
providing a modulated beam of the directed light; and wherein the step of directing light includes: directing the modulated beam of light through the multi-component vapor.
- 16. The method of claim 15, wherein the step of directing the light through the multi-component vapor further includes:
reflecting the light such that it passes back and forth through the multi-component vapor a plurality of times.
- 17. The method of claim 1 further including at least one of:
collimating the light to block stray radiation from being detected; and providing louvers which permit the vapor to pass through the directed light but which inhibit stray radiation from being detected.
- 18. A method for determining the concentration of hydrogen peroxide and water in a multi-component vapor, the method including:
directing light through the multi-component vapor, the light including wavelengths in a first wavelength range of the mid infrared spectrum at which hydrogen peroxide absorbs but at which water does not significantly absorb and wavelengths in a second wavelength range of the mid infrared spectrum at which water absorbs but at which hydrogen peroxide does not significantly absorb; detecting light which has passed through the multi-component vapor in the first wavelength range; separately detecting light which has passed through the multi-component vapor in the second wavelength range; and determining concentrations of water and hydrogen peroxide in the multi-component vapor from detected light in the first and second wavelength ranges.
- 19. The method of claim 18, wherein the mid infrared range of the spectrum is from 2,000-10,000 nanometers.
- 20. A decontamination system comprising:
a chamber which receives items to be microbially decontaminated; a source of a gaseous sterilant which supplies the gaseous sterilant to the chamber; a sensor system including:
a transmitting portion which directs light through the gaseous sterilant; and a receiving portion which receives light which has passed through the gaseous sterilant, the receiving portion including:
a first detector positioned to receive light which has passed through the gaseous sterilant, the first detector detecting light in a wavelength range of the mid-infrared spectrum at which a first component of the gaseous sterilant absorbs; and a control system which controls conditions within the chamber in response to a signal indicative of the light detected by the first detector.
- 21. The system of claim 20, wherein the receiving portion further includes:
a filter positioned to filter light to be received by the first detector.
- 22. The system of claim 20, further including:
a second detector which detects light in a second wavelength range spaced from the first wavelength range at which a second component of the sterilant absorbs but at which the first component does not substantially absorb.
- 23. The system of claim 20, wherein the sterilant includes a mixture of water vapor and vapor hydrogen peroxide, the first detector detecting light in a wavelength range of from about 7500 to 8400 nm.
- 24. The system of claim 20, wherein the, sensor system further includes:
an elongated polygonally cross sectional, apertured tube connected with the transmitting and receiving portions to maintain the transmitting and receiving portions in a fixed relationship.
- 25. The system of claim 24, wherein the apertured tube includes louvers adjacent the apertures which inhibit stray radiation from entering the receiving portion.
- 26. The system of claim 24, wherein the detector is displaced from the apertured tube to shield the detector from stray light.
Parent Case Info
[0001] This application claims the priority of U.S. Provisional Application Serial No. 60/290,599, filed May 11, 2001.
Provisional Applications (1)
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Number |
Date |
Country |
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60290599 |
May 2001 |
US |