NON-EDIBLE COATING COMPRISING WASTE FOOD MATERIAL

Abstract
Non-edible coatings including a filmogen agent and at least one waste food material selected from liquid, solid, fluid or gel waste food materials such as for example water, citrus fruit, red berries, raspberry, strawberry, blackberry, kiwifruit, tomato, vanilla, pomegranate, beet, carrot, leek, potato, pimento, saffron, curry, cinnamon, vanilla, fish eggs, lavender, rice, sugar, herbes de provence, tomato concentrate, tomato extract, ketchup, honey, blackberry marmalade, strawberry marmalade, cocoa, chocolate, carrot puree, grenadine, soy sauce, veggies sauce, wine, liquors, curacao, vinegar, tomato juice, carrot juice, raspberry juice, water, milk, rose water or mixture thereof. Also, a method of manufacturing the same.
Description
FIELD OF INVENTION

This invention relates to the field of coatings, especially to a non-edible coating comprising at least one non-edible waste food material and at least one filmogen agent. Especially, this invention relates to a method for converting food waste, such as for example out-of-date food or not-suitable for consumption food products or parts of food products, into industrial products.


BACKGROUND OF INVENTION

Most of the coatings manufactured worldwide comprise pigments in order to provide a color to the film formed after application. Painters often mix their compositions in order to increase the number of available colors. Therefore, there is always a need to expand the palette of the previously known colors in coatings. This invention provides a coating which includes pigments which are waste food materials, the result of which being a coating providing additional sensorially perceptible enhancement in terms of color, texture or even scent.


One other object of the invention is to provide a coating with a shelf-life of at least 6 months, preferably at least one year, more preferably at least three years, comprising a waste food material. As waste food materials have a limited shelf-life, their uses in coatings have been neglected in favor of synthetic pigments. Surprisingly, the Applicant observed that the filmogen agent of the present invention, in combination with the waste food material, provides to the coating a shelf-life of more than 6 months preferably at least one year, more preferably at least three years.


The use of filmogen agents such as acrylic binders often leads to residual smell. Moreover, during application and until the disappearance of the odors, the users may complain with symptoms such as headache. An advantage of the present invention lies in the fact that aromatic waste food materials may cover the smell of filmogen agents.


As this invention focuses on coatings containing user-friendly components like food materials, the coating of the present invention may be used for craft activities. The coatings of this invention may actually involve three of the five traditional senses, i.e. sight, smell and touch, and may be helpful for developing children's skills.


As using harmful products in craft activities for children is never wished, this invention focuses on coatings containing user-friendly components. Often, the volatile organic components used as solvents in coatings are recognized harmful to the environment or to specialized workers. Moreover, coatings compositions comprise various additives and binders in order to give an attractive rendering regardless of the environmental issues. Another issue intended to be solved by this invention is therefore to manufacture products using user-friendly components limiting the environmental impact. In one embodiment, a solution provided by this invention is to use waste food material in combination with filmogen agents and additive that are exclusively natural additives, natural solvents or natural excipients, such as for instance water.


Some coatings including natural components are described in the prior art: for example, EP 1 352 937 discloses a natural paint where volatilization and release of organic solvents is controlled; and comprises a vegetable drying oil such as for example linseed oil, china wood oil, sesame oil, sunflower oil, etc. and waxes.


WO2007/141557 discloses an edible ink composition for marking foodstuffs comprising a pigment which is a waste food material and a food-permitted solvent.


However, none of the prior art documents describe a coating comprising or consisting of only waste food materials and a filmogen agent. The coating of the present invention does not provide an edible coating for applications on foodstuffs; but a coating with new natural components providing new features to the coatings such as new scents, new textures and new colors.







DESCRIPTION

In a first aspect, the present invention relates to a method for recycling waste food into a coating comprising a filmogen agent and at least one waste food material.


In a second aspect, the present invention relates to a coating comprising a waste food material. In one embodiment, the coating of the present invention comprises at least one filmogen agent. In one embodiment, the present invention relates to a coating, comprising a filmogen agent and at least one waste food material, said coating being non-edible and said waste food material being non edible.


In one embodiment, in both aspects of the invention, the waste food material is used as a pigment. In other words, in one embodiment, the coating contains a pigment which is a waste food material.


In one embodiment, in both aspects of the invention, the filmogen agent comprises single or blended acrylic resin(s), vinyl acetate aqueous dispersion, acrylate polymers, cellulose-based polymers, acrylic polymers, vinyl polymers, polyvinyl butyrals, alkyd resins, or resins derived from aldehyde condensation products, or mixture thereof. In one embodiment, the filmogen agent comprises acrylic binder such as single or blended acrylic resin or mixture thereof.


In one embodiment, the filmogen agent comprises acetate—e.g. methyl acetate, ethyl acetate, butyl acetate . . . —or an acrylate polymer. In one embodiment, the filmogen agent comprises any base coat for nail varnish known by one skilled in the art, such as for example a transparent base coat commercialized by PEGGY SAGE®. In one embodiment, the filmogen agent comprises polymers chosen from nitrocellulose and modified cellulose esters. In one embodiment, the filmogen agent comprises any base coat for nail varnish known by one skilled in the art, such as for example a transparent base coat commercialized by PEGGY SAGE.


In one embodiment, the filmogen agent comprises polymers chosen from nitrocellulose and modified cellulose esters.


In one embodiment, the filmogen agent comprises, by way of non-limiting example, cellulose-based polymers such as nitrocellulose, cellulose acetate, cellulose acetobutyrate, cellulose acetopropionate, and ethylcellulose; polyurethanes; acrylic polymers; vinyl polymers; polyvinyl butyrals; alkyd resins; and resins derived from aldehyde condensation products such as arylsulfonamide-formaldehyde resins, for instance, toluenesulfonamide-formaldehyde resin, arylsulfonamide-epoxy resins; and ethyltosylamide resins.


In one embodiment, the acrylic resin used as a filmogen agent in the coating of the present invention may be any acrylic resin known by a person skilled in the art such as for example Amsterdam acrylic medium glossy 012 commercialized by ROYAL TALENS, or liquid mediums commercialized by LEFRANC & BOURGEOIS, or acrylic binder commercialized by TOURDE, or fluid mediums commercialized by LIQUITEX. In another embodiment, the filmogen agent comprises a vinyl acetate aqueous dispersion, such as for example CAPAROL BINDER®, hereafter CAPAROL®, commercialized by CAPAROL. In an embodiment, the filmogen agent comprises mixture of various filmogen agents such as, for example, those described hereabove.


In one embodiment, the filmogen agent is compatible with the waste food material. In the present invention, compatible refers to the ability for the filmogen agent to provide, to the coating comprising waste food materials, a shelf-life of at least 6 months, preferably at least one year, more preferably at least three years, even more preferably of at least ten years.


In one embodiment, the waste food material is insoluble or immiscible with respect to the filmogen agent. In another embodiment, the waste food material is soluble or miscible with respect to the filmogen agent.


In one embodiment, the coating of the present invention comprises at least one solvent. In one embodiment, the solvent of the coating is an aqueous solvent. In one embodiment, the solvent of the coating is water or a liquid waste food material or mixture thereof. In a preferred embodiment, the solvent of the coating is water, milk or oil. In one embodiment in which liquid waste food material is implemented, there is no solvent added.


In one embodiment in which liquid waste food material is implemented, a solvent is added.


In an embodiment, the waste food material is a liquid, a solid, a fluid or a gel waste food material or a mixture thereof.


In an embodiment, the waste food material is selected from raw waste food material, cooked waste food material or processed waste food material, or a mixture thereof.


In an embodiment, the solid waste food material is selected from herbs, spices, cereals, seeds, flours, flowers, fruits, dried fruits, vegetables, or a mixture thereof.


In an embodiment, the liquid waste food material comprises or consists of naturally liquid waste food material, or from liquid waste food material obtained from solid waste food material;


The liquid material may be liquid waste food material is selected from naturally liquid waste food material, or from liquid waste food material obtained from solid waste food material such as wine, sauce, oil, juice, alcoholic beverage, or mixture thereof. The liquid waste food material may be water; fragrances under liquid form such as for example rose water; milk; wine including red wine, white wine, rosé; liquors; beer; vinegar; sauce including soy sauce and veggies sauce; oil including olive oil; juice including tomato juice, carrot juice, raspberry juice; curacao; alcoholic or non-alcoholic beverage, or a mixture thereof.


In an embodiment, the fluid or gel waste food material comprises or consists of syrup, marmalade, jelly, extract, concentrate, puree, or a mixture thereof.


In one embodiment, the waste food material is a solid waste food material; said solid waste food material may be selected from herbs, spices, cereals, seeds, flours, flowers, fruits, vegetables, starchy foods, or mixture thereof.


In an embodiment, the waste food material comprises or consists of a flour such as for example wholemeal flour, oat flour, corn flour, chestnut flour, wheat flour, buckwheat flour.


In an embodiment, the waste food material comprises or consists of flowers such as for example American elderberry, anise hyssop, arugula, bergamot, chamomile, chervil, Chinese hibiscus, chives, chicory, chrysanthemum, cornflower, dianthus, English marigold, English daisy, fennel, geranium, hollyhock, Japanese honeysuckle, lavender, lilac, lovage, mint, nasturtium, okra, passionflower, pineapple sage, poppy, zucchini flower, red clover, rose, rosemary flower, sage, snapdragon, squash flower, sunflower, tulip, violet.


In an embodiment, the waste food material comprises or consists of starchy foods.


In an embodiment, the waste food material comprises or consists of fish products, including fish eggs, shellfish, crustacean, scallop, oyster, crab, lobster or a mixture thereof. In an embodiment, the solid waste food material may be selected from fishbone.


In an embodiment, the waste food material comprises or consists of meat products.


In an embodiment, the waste food material comprises or consists of egg, or egg-including food products.


In an embodiment, said waste food material is selected from edible roots.


In an embodiment, the waste food material comprises or consists of sugar or sugar-containing product including honey, jelly, marmalade, fruit marmalade or jellies or compotes such as blackberry jelly, strawberry jelly, liquid or solid chocolate, grenadine, any sweet or candy, such as for examples, candy bars, chocolates, liquorice, sour candies, salty candies, tart candies, hard candies, taffies, gumdrops, marshmallows, etc., or mixture thereof. In one embodiment, the chocolate is selected from chocolate powder commercialized under the name LE CHOCOLAT by NESTLÉ. In one embodiment, the cocoa is selected from cocoa commercialized under the brand name VAN HOUTEN commercialized by VAN HOUTEN. In one embodiment, the chocolate is selected from chocolate commercialized under the brand name CHOCOLATE 1848 commercialized by CHOCOLAT POULAIN.


In an embodiment, the waste food material is selected from a fruit selected from citrus fruits, red berries, raspberry, strawberry, blackberry, kiwifruit, blackcurrant, redcurrant, gooseberry, cranberry, blueberry, lucuma, oranges, grapefruit, red berries, raspberry, strawberry, blackberry, kiwifruit, grapes, rhubarb, clementine, melon, orange, lemon, lime, grapefruit, boysenberry, pineapple, fig, mulberry, hedge apple, apple, pear, cherry, peach, apricot, rose hip, tomato, pomegranate, rhubarb.


In an embodiment, said waste food material comprises or consists of vegetables selected from artichokes, Japanese artichoke asparagus, avocado, bamboo shoots, burdock, beans, red bean, white bean, green been, beet, broccoli, cauliflower, cabbage, capers, carrot, cardoon, cucumber, cress, celery, Chinese celery, courgette, eggplant, endive, garlic, ginger, leek, gourd, lettuce, maize, mustard, olive, onion, parsnip, peppers, potato, pumpkin, radish, rutabaga, spinach, shallot, turnip, zucchini or a mixture thereof. In an embodiment, the waste food material is a puree of one or more of the above-mentioned vegetables, especially carrot puree.


In an embodiment, said waste food material comprises or consists of a spice selected from pimento, saffron, curry, cinnamon, chili powder, harissa, paprika, black pepper, liquorice, cardamom, piri piri (also called African bird's eye chili)


In one embodiment, the waste food material comprises or consists of from aromatic herbs, such as for example coriander, parsley, mint, dandelion, parsley, rosemary, thyme, basil, chervil, chive, tarragon, herbes de provence, dill.


In an embodiment, said waste food material comprises or consists of aromatic or fragrant plants such as for example lavender.


In an embodiment, the waste food material comprises or consists of cereals, such as for example rice, basmati, wheat.


In an embodiment, the waste food material comprises or consists of processed products such as for example tomato concentrate, tomato extract, ketchup,


In an embodiment, the waste food material comprises or consists of coffee, including liquid coffee, powder coffee and soluble coffee.


In one embodiment, the waste food material comprises or consists of cocoa, especially powder cocoa. In one embodiment, the cocoa is selected from organic cocoa for drink, commercialized by CARREFOUR, with the following composition: low fat cocoa (32%), sugar cane (67.8%), natural flavor of vanilla.


In one embodiment, the waste food material comprises or consists of exotic fruits or vegetables or plants, such as for example combava, guava, vanilla, pepper, pineapple, mango, banana, soursop (corossol), lime, lemon, papaw, carom (carembole), date, argan, figs, prickly pears, passion fruit, jujube, khaki, kumkat, mangosteen, medlar, coconut, palm, papaya, pepino, pitahaya, rambutan, tamarind, hibiscus, sweet potatoes, ginger, lychees.


In one embodiment, the waste food material comprises or consists of dried fruits, such as for example nuts, chestnuts, hazelnuts, peanut, pistachios, walnut, and almonds or a mixture thereof.


In an embodiment, the waste food material comprises or consists of flours such as wholemeal flour, oat flour, corn flour, chestnut flour, wheat flour, buckwheat flour, etc., or mixture thereof. In an embodiment, the waste food material may be selected from bread.


In an embodiment, the waste food material comprises or consists of dairy product such as for examples yoghurt, milk, cheese, etc. or mixture thereof.


In one embodiment, the waste food material of the present invention is selected from vegetal source. In one embodiment, the waste food material of the present invention is selected from animal source.


In an embodiment, the waste food material used as a component of the coating of the present invention is a raw waste food material. In an embodiment, the waste food material used as a component of the coating of the present invention is a cooked or processed waste food material. In an embodiment, the waste food material used as a component of the coating of the present invention is a processed waste food material, such as for examples Bolognese sauce, candy, macarons, macaroons or cakes.


In an embodiment, the waste food material may be either raw or cooked. Any fruits or vegetables may be used cooked or raw; for example, the waste food material may comprise raw carrots or cooked carrots, cooked rice or raw rice.


In an embodiment, the waste food material is edible. In an embodiment, the waste food material is non-edible.


In an embodiment, the waste food material may be selected from commercialized products. In one embodiment, said waste food material is a food residue. In one embodiment, said waste food material is a food product not suitable for sale. In one embodiment, said waste food material is a food product unfit for human or animal consumption. In an embodiment, the waste food material may be out-of-shelf-life recycling wasted waste food material. In an embodiment, the waste food material may be unsold waste food material. In an embodiment, the waste food material may have passed the sell-by date.


In an embodiment, the coating comprises solvents and/or aqueous solvents.


In an embodiment, the coating comprises additives.


In an embodiment, the coating is scented or fragrant.


The present invention also relates to the use of said coating as paints, varnishes, lacquers, polishes, finishes, stains, primers, inks, dyes, coil coatings, surface coatings, adhesives, clearcoats, and resin.


In an embodiment, the coating is used for providing texture to a substrate, or protecting a substrate, or coloring a substrate, said substrate being an article or a surface.


In an embodiment, the coating is used for craft activities wherein the use of the coating develops various skills and involves many senses including sight and/or smell and/or touch.


In an embodiment, said substrate is partially or totally coated with the coating of the present invention.


In an embodiment, the waste food material, as described herein, is used as pigment for coatings.


In the embodiment, the waste food material may be solid, fluid or gel, or liquid.


In one embodiment, the solid waste food material has a viscosity at 20° C. above 1 Pa·s, or 2 Pa·s, or 5 Pa·s, or 10 Pa·s, or 20 Pa·s. Solid pigments may also have the function of fillers in the coating of the invention and may provide specific texture to the coated film obtained after application of the coating of the present invention.


In one embodiment, the fluid or gel waste food material has a viscosity at 20° C. between 0.001 and 250 Pa·s, or between 0.1 and 100 Pa·s, or between 1 and 20 Pa·s. Fluid or gel pigments may also have the function of fillers in the coating of the invention and may provide specific texture to the coated film obtained after application of the coating of the present invention. In an embodiment, the fluid or gel waste food material may be selected from fruit concentrate, fruit extract, puree, honey, ketchup, syrup, marmalade, jelly, etc. or mixture thereof.


In one embodiment, the liquid waste food material has a viscosity at 20° C. below 1 Pa·s, or 2 Pa·s, or 5 Pa·s, or 10 Pa·s, or 20 Pa·s. Advantageously, the liquid waste food material may be selected from naturally liquid waste food material, or from liquid waste food material obtained from solid waste food material such as alcoholic beverage, sauce, fruit juice, vegetable juice etc.; or mixture thereof. In an embodiment, the liquid waste food material may be selected from sauces, such as soy sauce, veggies sauce, etc., or mixture thereof. In an embodiment, the liquid waste food material may be selected from alcoholic beverages, such as wine (e.g. Bordeaux wine, red wine, white wine, rosé), liquors, distilled beverage, curacao, etc. or mixture thereof. In an embodiment, the liquid waste food material may be selected from juices, such as tomato juice, carrot juice, raspberry juice, etc. or mixture thereof. In an embodiment, the liquid waste food material may be selected from water, milk, vinegar, rose water, oil such as olive oil, etc., or mixture thereof. In an embodiment, the liquid waste food material may be selected from milk, coffee, mate, kuding, herbal teas, etc., or mixture thereof. Liquid pigments may also have the function of fillers in the coating of the invention and may provide specific texture to the coated film obtained after application of the coating of the present invention.


In one embodiment, the coating comprises additives.


In one embodiment, the additives may be one or more plasticizers, preferably natural plasticizers. In one embodiment, the additives may be one or more waxes and/or surfactants, preferably natural waxes or surfactants. In one embodiment, the additives may be one or more preservatives, preferably natural preservatives. In one embodiment, the additives may be one or more excipients, preferably natural excipients. In an embodiment, the coating may comprise various excipients know by a person skilled in the art, such as for example water.


In an embodiment, the proportion of waste food material in the coating ranges from 0.1 to 95% w/w, preferably from 0.5 to 90% w/w more preferably from 1 to 85% w/w.


In an embodiment, the proportion of filmogen agent in the coating ranges from 0 to 98% w/w, preferably from 1 to 95% w/w.


In an embodiment, the proportion of acrylic resin in the coating ranges from 0 to 98% w/w, preferably from 1 to 95% w/w.


In an embodiment, the proportion of vinyl acetate aqueous dispersion in the coating ranges from 0 to 98% w/w, preferably from 1 to 95% w/w.


In an embodiment, the proportion of solvent in the coating ranges from 0 to 60% w/w, preferably from 0 to 55% w/w, more preferably from 1 to 50% w/w.


In an embodiment in which solvent is implemented, the ratio between the proportion of filmogen agent to the proportion of solvent ranges from 0 to 10, preferably from 0.5 to 5; more preferably the ratio is approximately equal to 0, 0.5, 1, 2 or 3.


In an embodiment in which solvent is implemented, the ratio between the proportion of vinyl acetate aqueous dispersion to the proportion of solvent ranges from 0 to 10, preferably from 0.5 to 5; more preferably the ratio is approximately equal to 0, 0.5, 1, 2 or 3.


In an embodiment in which acrylic resin is implemented, the ratio between the proportion of vinyl acetate aqueous dispersion to the proportion of acrylic resin ranges from 0 to 10, preferably from 0.2 to 5; more preferably the ration is approximately equal to 0, 0.2, 0.25, 0.33, 0.5, 1 or 2.


In one embodiment, the coating does not comprise solvent. In one embodiment, the coating does not comprise vinyl acetate aqueous dispersion. In one embodiment, the coating does not comprise binder, such as acrylic binder. In one embodiment, the coating does not comprise resin, such as acrylic resin. In one embodiment, the coating includes user-friendly materials. In one embodiment, the coating does not include synthetic pigment. In one embodiment, the coating does not include vegetable oil.


In one embodiment, the coating does not include linseed oil, china wood oil, sesame oil, sunflower oil, cannabis oil, perilla oil, peanut oil, haze wax, candelilla wax, carnauba wax, rice bran.


In an embodiment, the substrate is non-edible. In an embodiment, the substrate is not a foodstuff. In an embodiment, the coating does not include synthetic pigment. In an embodiment, the coating does not include synthetic aroma.


In an embodiment, the waste food material may be colored or having a natural high color strength.


In one embodiment, the waste food material is selected from a foodstuff which presents a scent and/or a texture and/or a pigmentation. The use and/or the addition of natural pigments to the coating potentiate the brilliance of the coating.


In an embodiment, the waste food materials have various consistencies, such as for example a puree, a mousse, a marmalade, a gel, etc.


In one embodiment, new textures for coated film from available degradable waste food material are achieved. Three textures may be achieved:

    • coarse texture with coarsely ground material,
    • medium texture with pulverization of the material,
    • fine texture with fine pulverisation, dilution and filtration obtaining a limpid solution.


In one embodiment, the use of the coating involves many senses: sight, smell, touch. The coating offers indeed pleasant texture, scent and color. In one embodiment, the coating may comprise natural aroma. In one embodiment, the coating consists of natural components. In one embodiment, the coating may comprise natural pigment.


In one embodiment, the coating and/or the coated film from the coating is non-edible.


In one embodiment, the coating provides pleasant odor upon drying and at least one, two, three, four, five, six, seven days after drying. In an embodiment, the coating remains scented at least one month.


In one embodiment, the coated film obtained from the coating of the present invention involves many senses: sight, smell, touch. The coated film offers indeed pleasant texture, scent and color.


In one embodiment, the coated film obtained from the coating is washable, resistant, insulating and provides good mechanical strength. In one embodiment, the coated film ensures high durability to the coating. In one embodiment, the coated film possesses very good adhesives properties. In one embodiment, the coated film is water-resistant.


In one embodiment, the hiding power of the coated film may be modified according to the waste food material and/or to the amount of solvent and/or binder and/or additive implemented.


This invention also relates to a process for manufacturing the coating of the invention.


In an embodiment, the process for manufacturing a coating comprising the step of:

    • a) providing a waste food material,
    • b) optionally, pulverizing the waste food material,
    • c) optionally, diluting and/or filtrating the waste food material,
    • d) optionally, mixing the composition of step a) or step b) or step c) with additives,
    • e) mixing the previous composition of step a) or step b) or step c) or step d) with the filmogen agent; and homogenizing the composition by appropriate mixing such as for example from gentle to shear mixing.


In this embodiment, the process may comprise step a) and e), or step a) and b) and e), or step a) and c) and e), or step a) and d) and e), or step a) and b) and c) and e) or step a) and c) and d) and e), or step a) and b) and d) and e), or step a) and b) and c) and d) and e).


In an embodiment, the process for manufacturing a coating comprising the step of:

    • a) providing a waste food material,
    • b) optionally, pulverizing the waste food material,
    • c) optionally, diluting and/or filtrating the waste food material,
    • d) mixing the additives with the filmogen agent,
    • e) adding gradually to the solution achieved after step d) the solution achieved after step a) or step b) or step c); and homogenizing the composition by appropriate mixing such as for example from gentle to shear mixing.


In this embodiment, the process may comprise step a), d) and e), or step a), b), d) and e), or step a), c), d) and e), or step a), b), c), d) and e).


In one embodiment, the pulverisation step b) comprises the steps of crushing and/or grinding and/or pounding the solid waste food material in order to obtain a fine powder. This step will provide a coarse or medium texture to the coated film.


In one embodiment, the filtration step c) removes particles larger than 2 mm, preferably 1.5 mm, more preferably 1 mm, even more preferably 0.8 mm. This embodiment will provide a fine texture to the coated film.


In one embodiment, only a portion of the solution obtained after filtration is used in the coating composition.


In one embodiment, step c) allows obtaining various shades according to the way dilution and/or filtration is performed.


In one embodiment, the steps a) and/or step b) and/or step c) may be repeated, and the different waste food materials are mixed together before step d) and/or step e): so various colors and/or textures may be achieved by combining waste food materials and/or solvents.


In one embodiment, the steps a) and/or step b) and/or step c) are repeated before step d) and/or step e) with only solid waste food material.


In one embodiment, the steps a) and/or step b) and/or step c) are repeated before step d) and/or step e) with only liquid waste food material.


In one embodiment, the steps a) and/or step b) and/or step c) are repeated before step d) and/or step e) with liquid and solid waste food material.


In one embodiment, the coating must rest after manufacture for at least 10 minutes, preferably 1 hour, more preferably 2 hours, even more preferably 5 hours before application.


This invention also relates to the applications of the coating.


In one embodiment, the coating may be partially or totally applied onto a substrate, which may be a surface or an article.


In one embodiment, the substrate is clean, dry and not fat.


In one embodiment, the substrate is biodegradable or not biodegradable.


In one embodiment, the substrate may be a human or an animal.


In one embodiment, the coating may be deposited on all supports: buildings, furniture, textiles, fabrics or articles, such as for instance a pillar, a wall, canvas, a floor, a plate, a metal, a glass, a fusuma, a door, a sofa, a bed, a table, floor covering such as a tatami and a carpet; preferably a wall, canvas, a plate, fabrics, textiles, metal, wood, glass, paint, cement, cork, Plexiglas . . .


In one embodiment, the coating may be deposited on wood, metal, plaster, cork, textiles, glass, plastic, paperboard, stone, cement, plastic, iron, aluminium, stainless steel, vinyl paper, porcelain, biscuit, and/or canvas.


In an embodiment, the coating may be implemented into indoor and/or outdoor applications.


In one embodiment, the coating may be used for body painting or as nail polish, nail varnish or nail lacquer.


In one embodiment, the coating may be applied on the surface of various articles for protecting, garnishing, ornamenting, coloring or providing texture to an article or a surface.


In one embodiment, the waste food material is a powder having a particle size of less than 5 millimeters. In a preferred embodiment, the powder has a particle size of 0.1-5000 micrometers, preferably of 1-1000 micrometers. In one embodiment, the waste food material includes or consists of cocoa powder having a particle size of 0.1-3000 micrometers, preferably 1-500 micrometers, more preferably 1-300 micrometers, even more preferably 5-100 micrometers.


In one embodiment, the coating may be applied onto a substrate directly after manufacture. In one embodiment, the coating may have monolayer or multilayer applications. In one embodiment, a thick layer of coated film, allowing the creation of specific texture, may be achieved.


In one embodiment, the coating composition has a viscosity at 20° C. that allows the composition to be applied into a substrate in a controlled manner.


In an embodiment, the coating may be applied by brush, spatula, sponge, knife, roller or any other means that a person skilled in the art would find suitable.


The present invention also relates to a cosmetic composition comprising the coating of the present invention and, optionally, a cosmetically acceptable excipient. In an embodiment, said cosmetic composition is a hair cleaning composition, a shampoo, a coloring shampoo, a hair conditioning composition, a mask, a serum, a hair styling composition, a hair fixing composition, a hair coloring composition, an oxidative hair composition.


The present invention also relates to a nail varnish, nail lacquer or nail polish comprising the coating of the present invention.


The present invention also relates to a cosmetic process for making-up and/or for the non-therapeutic care of nails, comprising applying to the nails at least one coat of said nail varnish, nail lacquer or nail polish.


The present invention also relates to a cosmetic article comprising a container comprising said nail varnish, nail lacquer or nail polish and an applicator for withdrawing said nail varnish, nail lacquer or nail polish from the container and applying it to a nail, the applicator being in the form of a spatula, a brush, a foam tip or a flexible strip defining an applicator face.


This cosmetic composition may be a hair, eyebrows, eyelashes, mascara, lipstick, skin care cosmetic composition. The cosmetic composition may be a hair cleaning composition, a shampoo, a coloring shampoo, a hair conditioning composition, a mask, a serum, a hair styling composition, a hair fixing composition, a hair coloring composition, an oxidative hair composition.


In one embodiment, the coating is implemented into varnish like nail varnish.


In one embodiment, the coating of the present invention is implemented into nail varnish.


The nail varnish according to the present invention comprises cosmetically acceptable medium, i.e. a nontoxic medium that may be applied to human keratin materials, such as the nails.


In one embodiment, the nail varnish may be used as varnish base, as a make-up product for the nails, or as a finishing composition, also called top coat.


In one embodiment, the nail varnish may be applied to the nails of human beings or to false nails. According to one embodiment, the nail varnish of the present invention may be applied to a nail, for example a fingernail, toenail or the like. The nail varnish allows simple varnishing of a nail and provides varnish layers which are particularly durable.


In one embodiment, the filmogen agent for the nail varnish may be any composition comprising a polymer capable of forming, by itself alone or in the presence of an additional agent which is capable to form a film, a continuous film on a support, such as keratin materials, at a temperature ranging from 10° C. to 150° C.


In one embodiment, the nail varnish comprises at least one film-forming aid for improving the film-forming properties of the varnish.


In one embodiment, the nail varnish may comprise a plasticizing agent. In another embodiment, the nail varnish may comprise thickening agent for conferring on the composition a consistency allowing good application of the composition to the nails.


In one embodiment, the nail varnish may further comprise at least one cosmetic additive chosen from those known by one skilled in the art such as fillers, spreading agents, wetting agents, dispersing agents, antifoam agents, active agents, surfactants, moisturizing agents, perfumes, neutralizers, UV-screening agents, preserving agents, stabilizers and/or antioxidants.


In one embodiment, the nail varnish further comprises a resin for increasing the gloss of the nail varnish.


The present invention also relates to a cosmetic method for making-up and/or non-therapeutic care of the nails, comprising applying to the nails at least one layer of the nail varnish.


The nail varnish of the present invention may be applied by any means that one skilled in the art would find suitable such as a standard nail varnish applicator comprising a brush. According to one embodiment, the nail varnish of the present invention may be used in single layer applications or multi-layer applications.


The present invention also relates to a cosmetic article comprising a container, and, therein a nail varnish according to the present invention, and optionally an applicator for withdrawing the nail varnish present in the container and applying it to a nail, the applicator being in the form of a brush, a spatula, a foam tip or a flexible strip defining an applicator face.


According to one embodiment, the container may be in any suitable form, for examples, bottles, and may be at least partly made of a material such as glass. However, materials such as polypropylene, polyethylene, or metals may be used.


In one embodiment, the coating should be keep away from frost and used above 10° C.


While various embodiments have been chosen to illustrate the invention, it will be understood by those skilled in the art that some changes and modifications can be made therein without departing from the scope of the invention as defined in the appended claims.


Definitions

In the present invention, the following terms have the following meanings:

    • “Additive”: refers to miscellaneous compounds which may modify the properties of the coating.
    • “Coating”: refers to a composition in liquid form with various viscosities. Therefore, in the present invention a coating is a film-forming composition which, after or upon application onto a substrate, is converted into a film by mere evaporation of the solvents contained therein. Coatings may include components such as for example binders, solvents, pigments and/or additive. Coatings of the invention may be paints, varnishes, lacquers, polish, finishes, stains, primers, inks, dyes, hair shampoo or conditioners, hair coloring products, oxidative hair products, coil coatings, surface coatings, laminants, adhesives, clearcoats, and resins. In the present invention, coating refers to a filmogen composition, whereas coated film refers to the result of the application of the coating according to the present invention.
    • “Diluent or Solvent”: refers to a volatile compound that dilutes the composition leading to liquid and practicable coating. During and after the application, the solvent evaporates and the coating solidifies.
    • “Filmogen agent”: refers to the film-forming component capable of forming a continuous film on a support at a temperature ranging from 10° C. to 150° C.
    • “Waste food material” refers to uneaten food and food preparation wastes from individual, commercial and industrial sources, and includes food leftovers, discarded food, out-of-shelf life food products, and/or also coproducts of food products which are not suitable for consumption such as for example green bean tails, cherry stems, fruit peelings, vegetable peelings or scraps, nut shells, bones, wastes from seafood such as skins, shells, bones, oils; wastes from dairy processing industry such as whey, curd, and milk sludge from the separation process; vegetable-derived processing food wastes includes peelings, stems, seeds, shells, bran, trimmings residues after extraction of oil, starch, juice and sugar.
    • In the sense of the present invention, “nail varnish or nail polish or nail lacquer” refers to the coating of the present invention forming a film on the nail.
    • “Pigment”: refers to the component which contributes to the color and the structure of the coating. Pigment relates to the part imparting the color whereas the filler refers to the part imparting toughness, and texture. In the present invention the terms pigment or filler are commutable as waste food material may provide on the same time color and texture to the coating. In this invention, pigment or dye are also used interchangeably
    • “User-friendly”: refers in the present invention to compounds which contain at most 30 g/l, preferably 20 g/l, more preferably at most 15 g/l of volatile organic compounds.
    • “w/w”: means in weight to the total weight of the coating.


EXAMPLES

The present invention is further illustrated by the following examples.


Example 1

A coating based on kiwifruit consisting of:

    • kiwifruit: 20 g
    • acrylic resin: 10 g


Methods

First a kiwifruit is pulverized i.e. crushed and/or grinded and/or pounded. 20 grams of the obtained composition (juice, pulp and seeds) are selected. Then said composition is mixed with 10 grams of acrylic resin. The composition is homogenized with first a gentle mixing and then with a shear mixing. The coating thus prepared is then stored until application.


Example 2

A coating based on chocolate (such as for example the cocoa commercialized under the brand name CHOCOLATE 1848) consisting of:

    • chocolate: 3 g
    • milk: 10 g
    • acrylic resin: 30 g


Methods

First chocolate is pulverized i.e. crushed and/or grinded and/or pounded. 3 grams of the obtained powder are selected. The cocoa powder is then mixed with 10 grams of milk used as solvent. Said composition is mixed with 30 grams of acrylic resin. The composition is homogenized with first a gentle mixing and then with a shear mixing. The coating thus prepared is then stored until application.


Example 3

A coating based on curry consisting of:

    • curry: 3 g
    • water: 10 g
    • CAPAROL®: 10 g
    • acrylic resin: 20 g


Methods

First 3 grams of curry powder is provided. The powder is then mixed with 10 grams of water. Said composition is filtrate to remove particles larger than 1 mm.


10 grams of Caparol® and 20 grams of acrylic resin are mixed together in order to provide one filmogen agent. Said filmogen agent is mixed with the previous mixture of water and curry. The composition is homogenized with first a gentle mixing and then with a shear mixing. The coating thus prepared is then stored until application.


Example 4

Coatings according to embodiments of the present invention have been achieved with the following compositions:
























Waste food












material


type
rice
rice
rice
rice
rice
rice
rice
rice
rice
rice


amount
5
5
5
5
5
5
10
10
10
10


(mL or g)


Solvent


water (g)
0
10
0
0
0
0
0
0
0
0


milk (g)
0
0
0
0
0
0
0
0
0
0


Filmogen


agent


acrylic resin
30
30
0
10
20
0
0
0
0
20


(g)


CAPAROL ®
0
0
10
0
0
20
15
20
10
10


(g)


























Waste food







material







type
tomato
tomato
tomato
tomato
tomato



concentrate
concentrate
concentrate
concentrate
concen-







trate


amount (mL
10
30
10
10
10


or g)







Solvent







water (g)
0
0
0
0
0


milk (g)
0
0
0
0
0


Filmogen







agent







acrylic resin
30
0
20
0
10


(g)







CAPAROL ®
0
10
10
20
0


(g)



























Waste food








material








type
tomato
tomato
tomato
tomato
tomato
tomato



concen-
extract
extract
extract
extract
extract



trate







amount
10
10
10
10
10
10


(mL or g)








Solvent








water (g)
0
0
0
0
0
0


milk (g)
0
0
0
0
0
0


Filmogen








agent








acrylic resin
20
30
10
10
20
30


(g)








CAPAROL ®
0
0
0
0
0
0


(g)



























Waste food








material








type
tomato
tomato
tomato
tomato
tomato
tomato



extract
extract
extract
juice
juice
juice


amount
100
20
20
30
30
10


(mL or g)








Solvent








water (g)
0
0
0
0
0
0


milk (g)
0
0
0
0
0
0


Filmogen








agent








acrylic resin
20
30
10
0
20
0


(g)








CAPAROL ®
0
0
0
10
10
10


(g)



























Waste food








material








type
cura-
cura-
cura-
cura-
cura-
cura-



cao
cao
cao
cao
cao
cao


amount
10
10
10
10
30
30


(mL or g)








Solvent








water (g)
0
0
0
0
0
0


milk (g)
0
0
0
0
0
0


Filmogen








agent








acrylic resin
0
20
0
10
20
0


(g)








CAPAROL ®
20
0
10
0
0
20


(g)































Waste food












material












type
wine
wine
wine
wine
wine
wine
wine
wine
wine
wine


amount
20
20
20
20
20
20
30
30
30
30


(mL or g)












Solvent












water (g)
0
0
0
0
0
0
0
0
0
0


milk (g)
0
0
0
0
0
0
0
0
0
0


Filmogen












agent












acrylic resin
30
20
0
0
0
40
100
80
60
40


(g)












CAPAROL ®
10
0
20
40
20
0
20
20
20
20


(g)



























Waste food








material








type
kiwi-
kiwi-
kiwi-
kiwi-
chocolate
chocolate



fruit
fruit
fruit
fruit
1848
1848


amount
10
10
20
20
6
6


(mL or g)








Solvent








water (g)
0
0
0
0
0
0


milk (g)
0
0
0
0
10
30


Filmogen








agent








acrylic resin
10
0
0
10
0
30


(g)








CAPAROL ®
0
10
10
0
30
0


(g)


























Waste food







material







type
chocolate
chocolate
chocolate
chocolate
chocolate



1848
1848
1848
1848
1848


amount (mL or
6
3
3
3
3


g)







Solvent







water (g)
0
0
0
4
0


milk (g)
10
10
0
0
0


Filmogen agent







acrylic resin (g)
30
0
20
20
20


CAPAROL ®
0
30
0
0
0


(g)



























Waste food








material








type
chocolate
chocolate
red
red
red
red



1848
1848
berry
berry
berry
berry


amount
3
3
10
10
10
10


(mL or g)








Solvent








water (g)
10
0
0
0
0
0


milk (g)
0
10
0
0
0
0


Filmogen








agent








acrylic resin
10
30
10
0
20
0


(g)








CAPAROL ®
0
0
0
10
0
20


(g)






























Waste food











material











type
co-
co-
co-
co-
co-
co-
co-
co-
co-



coa
coa
coa
coa
coa
coa
coa
coa
coa


amount
1.5
3
5
6
7
8
9
10
10


(mL or g)











Solvent











water (g)
10
10
10
10
10
10
10
10
10


milk (g)
0
0
0
0
0
0
0
0
0


Filmogen agent

20









acrylic resin
20
10
20
20
20
20
20
15
20


(g)











CAPAROL ®
10
20
10
10
10
10
10
5
10


(g)





























Waste food










material










type
cocoa
curry
curry
curry
curry
curry
curry
curry


amount
15
20
3
3
3
10
15
5


(mL or g)










Solvent










water (g)
10
10
10
10
10
10
10
10


milk (g)
0
0
0
0
0
0
0
0


Filmogen










agent










acrylic resin
20
20
20
20
20
20
20
20


(g)










CAPAROL ®
10
10
10
10
10
10
10
10


(g)



























Waste food








material








type
cinna-
cinna-
cinna-
cinna-
pimen-
pimen-



mon
mon
mon
mon
to
to


amount
3
6
6
10
5
3


(mL or g)








Solvent








water (g)
10
20
10
10
10
10


milk (g)
0
0
0
0
0
0


Filmogen








agent








acrylic resin
20
20
20
20
20
20


(g)








CAPAROL ®
10
10
10
10
10
10


(g)


























Waste food







material







type
herbes de
herbes de
herbes de
herbes de
herbes de



provence
provence
provence
provence
provence


amount (mL or
2
2
2
2
2


g)







Solvent







water (g)
0
10
0
0
0


milk (g)
0
0
0
0
0


Filmogen agent







acrylic resin (g)
10
30
30
0
0


CAPAROL ®
0
0
0
10
20


(g)


























Waste food







material







type
herbes de
herbes de
herbes de
herbes de
herbes de



provence
provence
provence
provence
provence


amount (mL or
5
5
5
5
5


g)







Solvent







water (g)
0
10
0
0
0


milk (g)
0
0
0
0
0


Filmogen agent







acrylic resin (g)
0
20
20
20
10


CAPAROL ®
10
0
0
0
0


(2)




























Waste food









material









type
carrot
carrot
carrot
carrot
carrot
carrot
carrot



puree
puree
puree
puree
puree
puree
puree


amount
50
50
50
40
40
30
30


(mL or g)









Solvent









water (g)
0
0
0
0
0
0
0


milk (g)
0
0
0
0
0
0
0


Filmogen









agent









acrylic resin
30
10
20
10
0
0
10


(g)









CAPAROL ®
0
0
0
0
20
20
0


(g)




























Waste food









material









type
carrot
carrot
carrot
carrot
carrot
carrot
milk



puree
puree
puree
puree
juice
juice



amount
20
10
10
10
20
20
/


(mL or g)









Solvent









water (g)
0
0
0
0
0
0
0


milk (g)
0
0
0
0
0
0
20


Filmogen









agent









acrylic resin
10
0
0
10
10
0
20


(g)









CAPAROL ®
0
20
10
0
10
10
0


(g)





























Waste food










material










type
sug-
sug-
sug-
sug-
hon-
hon-
hon-
hon-



ar
ar
ar
ar
ey
ey
ey
ey


amount
6
6
20
30
5
5
5
10


(mL or g)










Solvent










water (g)
0
0
0
0
0
0
0
0


milk (g)
0
0
0
0
0
0
0
0


Filmogen










agent










acrylic resin
0
0
0
0
10
20
0
20


(g)










CAPAROL ®
20
20
20
20
0
0
20
0


(g)





























Waste food










material










type
vanil-
vanil-
vanil-
vanil-
gren-
gren-
gren-
gren-



la
la
la
la
adine
adine
adine
adine


amount
2
2
2
2
40
40
40
20


(mL or g)










Solvent










water (g)
0
0
0
0
0
10
0
0


milk (g)
0
0
0
0
0
0
0
0


Filmogen










agent










acrylic resin
20
0
10
0
30
30
20
30


(g)










CAPAROL ®
0
20
0
10
0
0
10
0


(g)



























Waste food








material








type
rasp-
rasp-
rasp-
rasp-
rasp-
rasp-



berry
berry
berry
berry
berry
berry



juice
juice
juice
juice




amount
10
10
10
10
10
10


(mL or g)








Solvent








water (g)
0
0
0
0
0
0


milk (g)
0
0
0
0
0
0


Filmogen








agent








acrylic resin
20
10
0
0
0
0


(g)








CAPAROL ®
0
0
10
20
20
10


(g)


























Waste food







material







type
vegetable
blackberry
strawberry
strawberry
straw-



soup
jam
jam
jam
berry







jam


amount (mL
20
10
5
10
5


or g)







Solvent







water (g)
0
10
0
0
0


milk (g)
0
0
0
0
0


Filmogen







agent







acrylic resin
10
20
0
0
10


(g)







CAPAROL ®
0
10
20
10
0


(g)









Example 5

Nail varnishes according to embodiments of the present invention have been achieved with the following compositions:



















Waste food material





type
cocoa Van Houten
cocoa Van Houten



amount (mL or g)
1
1



Solvent





water (g)
0
0



olive oil (g)
0
0



Filmoaen element





Transparent base
1
2



coat PEGGY





SAGE ® (g)


























Waste food material






type
chocolate
chocolate
chocolate
chocolate



Nestlé
Nestlé
Nestlé
Nestlé


amount (mL or g)
1
1
1
1


Solvent






water (g)
0
0
0
0


olive oil (g)
0
0
0
1


Filmogen element






Transparent base
1
2
3
1


coat PEGGY






SAGE ® (g)

























Waste food material






type
chocolate
chocolate
chocolate
cocoa



Nestlé
Nestlé
Nestle
Carrefour


amount (mL or g)
1
1
1
1


Solvent






water (g)
0
0
0
0


olive oil (g)
1
1
1
1


Filmoaen element






Transparent base
2
3
4
3


coat PEGGY






SAGE ® (g)



























Waste food








material








type
cocoa
cocoa
cocoa
cocoa
cocoa
cocoa



Car-
Car-
Car-
Car-
Car-
Car-



re-
re-
re-
re-
re-
re-



four
four
four
four
four
four


amount
1
1
1
1
1
1


(mL or g)








Solvent








water (g)
0
0
1
2
0
0


olive oil (g)
0
0
0
0
1
1


Filmogen








element








Transparent
1
2
2
2
1
2


base coat








PEGGY SAGE ®(g)


























Waste food material







type
Bordeaux
Bordeaux
Bordeaux
piri piri
piri piri



Wine
Wine
Wine




amount (mL or g)
1
1
1
1
1


Solvent







water (g)
0
0
0
0
0


olive oil (g)
0
0
0
0
0


Filmogen element







Transparent base
1
2
3
1
2


coat PEGGY







SAGE ® (g)








Claims
  • 1. A method for recycling waste food, comprising mixing at least one waste food material with a filmogen agent to form a coating selected from the group consisting of paints, varnishes, lacquers, polishes, finishes, stains, primers, inks, dyes, coil coatings, surface coatings, adhesives, clearcoats, and resins.
  • 2. The method according to claim 1, wherein said filmogen agent comprises a component selected from the group consisting of single or blended acrylic resin(s), vinyl acetate aqueous dispersion, acrylate polymers, cellulose-based polymers, acrylic polymers, vinyl polymers, polyvinyl butyrals, alkyd resins, or resins derived from aldehyde condensation products, and mixtures thereof.
  • 3. The method according to claim 1, wherein said waste food material is in a form selected from the group consisting of liquid, solid, fluid, gel and mixtures thereof.
  • 4. The method according to claim 1, wherein said waste food material is selected from the group consisting of raw waste food materials, cooked waste food materials, and processed waste food materials.
  • 5. The method according to claim 1, wherein said waste food material is selected from the group consisting of herbs, spices, cereals, seeds, flours, flowers, fruits, vegetables, starchy foods, and mixtures thereof.
  • 6. The method according to claim 1, wherein said waste food material is selected from the group consisting of naturally liquid waste food materials, liquid waste food material obtained from solid waste food material selected from the group consisting of wine, sauce, oil, juice, and alcoholic beverage, and mixtures thereof.
  • 7. The method according to claim 1, wherein said fluid or gel waste food material is selected from the group consisting of syrup, marmalade, jelly, extract, concentrate, puree, and mixtures thereof.
  • 8. The method according to claim 1, wherein said waste food material is selected from the group consisting of herbs, spices, cereals, seeds, flours, flowers, fruits, vegetables, starchy foods, and mixtures thereof.
  • 9. The method according to claim 1, wherein the coating comprises solvents.
  • 10. The method according to claim 1, wherein the coating comprises additives.
  • 11. A process for manufacturing a coating comprising the step of: a) providing a waste food material,b) optionally, pulverizing the waste food material,c) optionally, diluting and/or filtrating the waste food material,d) optionally, mixing the material of step a) or step b) or step c) with additives,e) mixing the material of step a) or step b) or step c) or step d) with a filmogen agent to obtain a composition; and homogenizing the composition by mixing.
  • 12. A process for manufacturing a coating comprising the step of: a) providing a waste food material,b) optionally, pulverizing the waste food material,c) optionally, diluting and/or filtrating the waste food material,d) mixing additives and a filmogen agent to form a solution,e) adding gradually to the solution achieved after step d) the material achieved after step a) or step b) or step c) to form a composition; and homogenizing the composition by mixing.
Priority Claims (2)
Number Date Country Kind
13160661.8 Mar 2013 EP regional
13193143.8 Nov 2013 EP regional
Continuation in Parts (1)
Number Date Country
Parent 14779225 Sep 2015 US
Child 15816540 US