Claims
- 1. A composition comprising a compound of formula I:
- 2. The composition of claim 1 further comprising at least one additional component selected from the group consisting of:
a) a surfactant wherein either:
(i) the ratio of the weight of the surfactant divided by the weight of the substituted salicylanilide compound of formula I is greater than or equal to 1.0 and further provided that the surfactant is 1 wt % or greater of the composition; or (ii) the composition comprises at least 1 wt % of a cationic surfactant, wherein the ratio of the weight of the surfactant divided by the weight of said compound I is greater than or equal to 1.0; and wherein a 10 wt % aqueous solution of this composition has a pH less than or equal to 7.0; b) from 0.5% to 90% by weight of a solvent said solvent having Hildebrand solubility parameter dS (cal/cm3)1/2 meeting the following criterion: 5<dS<20, wherein a 10 wt % aqueous solution of this composition has a pH≧(pKa−1) where pKa is the calculated pKa of the O-G phenol of formula I, or when G is not H, the pKa of the O-G phenol of formula I that results from replacing G with H; c) a perfume having a C log P greater than or equal to 2.0; d) 0.001 to 1.0% by weight of an enzyme; and e) mixtures thereof.
- 3. The composition of claim 2 wherein the enzyme is selected from the group consisting of: proteases, amylases, cellulases, mannanases, xyloglucanases, pectinases, lipases, laccases, peroxidases and mixtures thereof.
- 4. The composition of claim 2 wherein the composition comprises at least two of said additional components.
- 5. A method of reducing bacteria or inhibiting bacterial growth comprising contacting a substrate comprising a textile with the composition of claim 1.
- 6. A substrate treated according to the method of claim 5.
- 7. A liquid detergent comprising the composition of claim 1.
- 8. The composition of claim 2 wherein m is 0 or 1; t is 0 or 1; a, b and g are all 0; G is H and R1, when present, is not H.
- 9. The composition of claim 8 wherein said compound is selected from the group consisting of:
- 10. The composition of claim 9 wherein R2 is selected from the group consisting of:
a.) C1-C16 linear or branched, substituted or unsubstituted alkyl; and b.) C6-C16 substituted or unsubstituted aryl.
- 11. The composition of claim 2, wherein m is 0 or 1; t is 0 or 1; and G is H
- 12. The composition of claim 11, wherein t is 0.
- 13. The composition of claim 12, wherein all a, b and g are 0.
- 14. The composition of claim 13, wherein m is 0.
- 15. A compound selected from:
A) 8C) mixtures thereof; wherein R2 is selected from the group consisting of: i) H; ii) C1-C16 linear or branched, substituted or unsubstituted alkyl; iii) C2-C16 linear or branched, substituted or unsubstituted alkenyl; iv) C2-C16 linear or branched, substituted or unsubstituted alkynyl; v) C3-C16 linear or branched, substituted or unsubstituted cycloalkyl; vi) C3-C16 linear or branched, substituted or unsubstituted cycloalkenyl; vii) C7-C16 linear or branched, substituted or unsubstituted alkaryl; viii) C7-C16 linear or branched, substituted or unsubstituted aralkyl; ix) C6-C16 substituted or unsubstituted aryl; and x) C5-C20 heteroaryl units comprising one or more heteroatoms selected from the group consisting of nitrogen, oxygen, sulfur, and mixtures thereof; and G is H, a suitable charge balancing counterion (Mn+)1/n, or a cleaveable group selected from the group consisting of Si((O)pR3)3, where p is independently 0 or 1; C(O)q((O)pR3)r, wherein p is independently 0 or 1 and when q is 1, r is 1, and when q is 0, r is 3; R3 is independently selected from the group consisting of C1-C16 linear or branched, substituted or unsubstituted alkyl, alkenyl, alkynyl, cycloalkyl, cycloalkenyl, alkaryl, aralkyl, and aryl, and mixtures thereof.
- 16. The compound of claim 15, wherein R2 is selected from the group consisting of:
a.) C1-C16 linear or branched, substituted or unsubstituted alkyl; and b.) C6-C16 substituted or unsubstituted aryl.
- 17. The compound of claim 16, wherein R2 is selected from the group consisting of:
a.) C5-C11 linear or branched, substituted or unsubstituted alkyl; and b.) C6-C14 substituted or unsubstituted aryl.
- 18. A method of synthesizing a 5-acyl substituted salicylamide comprising the step of moving the attachment point of an acyl group, said acyl group being attached to the phenolic oxygen atom at position 2 of a salicylamide, from said phenolic oxygen atom to the carbon atom at the 5 position of said salicylamide.
- 19. The method of claim 18 wherein moving said acyl group comprises the step of contacting the salicylamide having the acyl group attached to the phenolic oxygen atom at position 2 of said salicylamide with a Lewis acid.
- 20. The method of claim 19 wherein said moving step is performed in the presence of a solvent.
CROSS-REFERENCES TO RELATED APPLICATIONS
[0001] This application is a continuation-in-part of U.S. application Ser. No. 09/903,309, filed Jul. 11, 2001, and claims priority under 35 U.S.C. § 119(e) to U.S. Provisional Application Serial No. 60/411,812 filed Sep. 18, 2002. U.S. application Ser. No. 09/903,309 and U.S. Provisional Application Serial No. 60/411,812 are herein incorporated by reference.
Provisional Applications (1)
|
Number |
Date |
Country |
|
60218207 |
Jul 2000 |
US |
Continuation in Parts (1)
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Number |
Date |
Country |
Parent |
09903309 |
Jul 2001 |
US |
Child |
10662644 |
Sep 2003 |
US |