1. Field of the Invention
The present invention generally relates to a non-reciprocal circuit element and, in particular, to a non-reciprocal circuit element used in a microwave band, such as an isolator and a circulator.
2. Description of the Related Art
In general, non-reciprocal circuit elements, such as isolators and circulators, have a characteristic in which a signal is transmitted in only a predetermined particular direction and is not transmitted in the opposite direction. By using such a characteristic, for example, isolators are used in a transmission circuit unit of mobile communication devices, such as car telephones and cell phones.
In such non-reciprocal circuit elements, in order to protect an assembly body of a ferrite having a center electrode formed therein and a permanent magnet for applying a direct current magnetic field to the ferrite from an external magnetic field, the assembly body is enclosed by a ring-shaped yoke (refer to International Application Publication No. 2006/011383) or a box-shaped yoke (refer to Japanese Unexamined Patent Application Publication No. 2002-198707).
However, since existing non-reciprocal circuit elements employ a ring-shaped yoke obtained by processing a soft iron or a box-shaped yoke for a magnetic shield component, the processing and assembly requires a large number of steps, and therefore, the manufacturing cost is increased. In addition, since a yoke is present around a ferrite and a permanent magnet, the outer shape of the non-reciprocal circuit element is increased in size. In contrast, if the size of the outer shape of the non-reciprocal circuit element is maintained unchanged, the sizes of the ferrite and the permanent magnet are reduced, and therefore, the electrical characteristics disadvantageously deteriorate. This is because, if the size of the ferrite is reduced, the size of the center electrode is also reduced, and therefore, the inductance value and the Q value are decreased.
In addition, since the yoke is in contact with or in close proximity to a circuit board, a floating capacitance is generated between the yoke and an internal electrode of the circuit board. Thus, a variation in the electrical characteristic of the non-reciprocal circuit element occurs. Furthermore, in the case in which a yoke made of a soft iron is soldered onto a ceramic circuit board, a heat stress acts on a soldered portion due to heat generated when the non-reciprocal circuit element operates, since the linear expansion coefficient of a soft iron is two to ten times that of a ceramic. Thus, the circuit board may curl, cracks may form in the circuit board, or the soldered portion may break. As a result, the reliability of the non-reciprocal circuit element is decreased.
In view of the above problems, preferred embodiments of the present invention provide a non-reciprocal circuit element having a simplified structure, a stable electrical characteristic, and a high reliability.
According to a preferred embodiment of the present invention, a non-reciprocal circuit element preferably includes permanent magnets, a ferrite, where a direct current magnetic field is applied to the ferrite by the permanent magnet, a first center electrode disposed on the ferrite, where one end of the first center electrode is electrically connected to an input port and the other end of the first center electrode is electrically connected to an output port, a second center electrode disposed on the ferrite, where the second center electrode intersects with the first center electrode while being electrically insulated from the first center electrode, one end of the second center electrode is electrically connected to an output port, and the other end of the first center electrode is electrically connected to a ground port, a first matching capacitor electrically connected between the input port and the output port, a second matching capacitor electrically connected between the output port and the ground port, a resistor electrically connected between the input port and the output port, and a circuit board having a terminal electrode arranged on a surface thereof. The ferrite and the permanent magnets define a ferrite magnet assembly in which the permanent magnets sandwich the ferrite to be parallel or substantially parallel to a surface of the ferrite having the first and second center electrodes disposed thereon. The ferrite magnet assembly is disposed on the circuit board so that the surface of the ferrite having the first and second center electrodes is perpendicular or substantially perpendicular to the surface of the circuit board, and a planar yoke is disposed on the upper surface of the ferrite magnet assembly with a dielectric layer therebetween.
According to the non-reciprocal circuit element of a preferred embodiment of the present invention, a 2-port lumped constant isolator having low insertion loss can be obtained. In addition, since the planar yoke is disposed immediately above the ferrite magnet assembly with the dielectric layer therebetween, the yoke can be significantly simplified. Accordingly, the ferrite magnet assembly can be very easily manufactured and manipulated, as compared with an existing soft-iron yoke surrounding a ferrite magnet assembly. In addition, since the need for a yoke disposed in the vicinity of the ferrite magnet assembly is eliminated, the outer shape of the non-reciprocal circuit element can be reduced in size, and/or the ferrite magnet assembly can be increased in size. Consequently, the electrical characteristics can be improved. In particular, since the center electrode is increased in size, the inductance value and the Q value can be increased.
In addition, the planar yoke is not physically joined to the circuit board. Accordingly, damage of the circuit board due to thermal expansion of the yoke can be prevented, and therefore, the reliability can be increased. Furthermore, a gap defined by an appropriate air layer is provided between the yoke and a surface of the circuit board. Accordingly, negligible floating capacitance is defined between the yoke and an internal electrode incorporated in the circuit board. As a result, stable electrical properties of the non-reciprocal circuit element can be obtained.
According to a preferred embodiment of the present invention, it is desirable that the first and second central electrodes are arranged on the ferrite and intersect with each other at a predetermined angle while being electrically insulated from each other. The first and second central electrodes can be stably formed more accurately using a thin-film forming technology, such as a photolithographic method, for example.
In addition, it is desirable that the thickness of the dielectric layer ranges from about 0.02 mm to about 0.10 mm, for example. The thickness of the dielectric layer in this range can reduce a leakage magnetic flux and provide a direct current bias magnetic flux density having an excellent intensity distribution. The effect of a thickness in this range is described in more detail below with reference to
Furthermore, an adhesive agent layer can be suitably included in the dielectric layer disposed between the ferrite magnet assembly and the planar yoke. In order to increase heat resistance, it is desirable that an epoxy-based resin is used for the adhesive agent layer, for example.
An end portion of the planar yoke may be bent in either direction perpendicular, substantially perpendicular, parallel, or substantially parallel to the magnetic bias direction from the permanent magnet to the ferrite. By providing such a bent portion, increased magnetic utilization of the permanent magnet can be obtained.
According to a preferred embodiment of the present invention, since the planar yoke is disposed immediately above the ferrite magnet assembly with the dielectric layer therebetween, the structure of the yoke can be simplified. Accordingly, an increase in the size of the element and deterioration of the electrical characteristics can be prevented. In addition, a floating capacitance between the yoke and a surface of the circuit board rarely occurs. Thus, the electrical characteristics can be stabilized. Furthermore, the risk of damage of the circuit board due to heat stress can be eliminated, and therefore, the reliability can be increased.
Other features, elements, steps, characteristics and advantages of the present invention will become more apparent from the following detailed description of preferred embodiments of the present invention with reference to the attached drawings.
Non-reciprocal circuit elements according to various preferred embodiments of the present invention are described below with reference to the accompanying drawings.
As shown in
In addition, the permanent magnets 41 are bonded to either of the principal surfaces 32a and 32b of the ferrite 32 using, for example, an epoxy-based adhesive agent 42 so that the magnetic field is applied to the principal surfaces 32a and 32b in a direction perpendicular or substantially perpendicular to the principal surfaces 32a and 32b (refer to
As shown in
The second center electrode 36 is arranged to extend from the lower right to the upper left on the first principal surface 32a of the ferrite 32. First, a half turn 36a of the second center electrode 36 is preferably inclined at a relatively large angle with respect to the upper long side of the first principal surface 32a. The second center electrode 36 further extends onto the second principal surface 32b around a relay electrode 36b defined on the upper surface 32c to define a first turn 36c. The 1st turn 36c substantially perpendicularly intersects with the first center electrode 35 on the second principal surface 32b. The lower end portion of the 1st turn 36c extends onto the first principal surface 32a around a relay electrode 36d defined on the lower surface 32d so as to define a 1.5th turn 36e. The 1.5th turn 36e extends parallel or substantially parallel to the 0.5th turn 36a and intersects with the first center electrode 35 on the first principal surface 32a. The 1.5th turn 36e further extends onto the second principal surface 32b through a relay electrode 36f defined on the upper surface 32c so as to define a 2nd turn 36g. In a similar way, the 2nd turn 36g, a relay electrode 36h, a 2.5th turn 36i, a relay electrode 36j, a 3rd turn 36k, a relay electrode 36l, a 3.5th turn 36m, a relay electrode 36n, a 4th turn 36o are defined on the surface of the ferrite 32. In addition, one end of the second center electrode 36 is connected to the connection electrode 35c and the other end of the second center electrode 36 is connected to a connection electrode 36p defined on the lower surface 32d. Note that the connection electrode 35c functions as a connection electrode of the first center electrode 35 and a connection electrode of the second center electrode 36.
That is, the second center electrode 36 is wound around the ferrite 32 for four turns in a spiral manner. As used herein, the term “0.5 turn” refers to a portion of the second center electrode 36 extending across the first principal surface 32a or the second principal surface 32b one time. An angle defined by the center electrodes 35 and 36 is appropriately determined in order to adjust the input impedance and the insertion loss.
In addition, the connection electrodes 35b, 35c, and 36p, and the relay electrodes 35a, 36b, 36d, 36f, 36h, 36j, 36l, and 36n are preferably formed by applying an electrode conductive material, such as silver, silver alloy, copper, or copper alloy, for example, to recess portions 37 (refer to
For example, a YIG ferrite is preferably used for the ferrite 32. The first center electrode 35, the second center electrode 36, and the variety of electrodes can be thick films or thin films of silver or a silver alloy formed using a printing technique, a transfer technique, or a photolithographic technique, for example. A dielectric thick film, such as glass and alumina, or a resin film, such as polyimide, for example, can be used as the insulating film disposed between the center electrodes 35 and 36. Similarly, these films can be formed using a printing technique, a transfer technique, or a photolithographic technique.
In general, the permanent magnets 41 is formed from a strontium-based, barium-based, or lanthanum cobalt-based ferrite magnet, for example. A one-component heat-curable epoxy adhesive agent can be suitably used as the adhesive agent 42 used for bonding the permanent magnets 41 to the ferrite 32. An adhesive agent of such a type has excellent working properties at room temperature. The adhesive agent excellently flows into an overall bonded portion so as to form a film having a small thickness of about 5 μm to about 25 μm, for example, and be in tight contact with the bonded portion. In addition, the adhesive agent has heat resistance. Thus, the adhesive agent does not melt or is not peeled off due to heat of a reflow. Furthermore, the adhesive agent has a good resistance to the environment. Thus, the adhesive agent has excellent reliability against heat and moisture.
The circuit board 20 is preferably a laminated board defined by forming predetermined electrodes on a plurality of dielectric sheets, stacking the sheets, and sintering the sheets. As shown by equivalent circuit diagrams in
The connection relationship among these matching circuit elements, the first center electrode 35, and the second center electrode 36 is shown in
The external connection terminal electrode 26 arranged on the lower surface of the circuit board 20 functions as an input port P1. The external connection terminal electrode 26 is connected to the matching capacitor C1 and the termination resistor R through the matching capacitor Cs1. In addition, the external connection terminal electrode 26 is connected to one end of the first center electrode 35 through the terminal electrode 25a arranged on the upper surface of the circuit board 20 and the connection electrode 35b arranged on the lower surface 32d of the ferrite 32.
The other end of the first center electrode 35 and one end of the second center electrode 36 are connected to the matching capacitors C1 and C2 through the connection electrode 35c arranged on the lower surface 32d of the ferrite 32 and the terminal electrode 25b arranged on the upper surface of the circuit board 20, and are connected to the external connection terminal electrode 27 arranged on the lower surface of the circuit board 20 through the matching capacitor Cs2. The electrode 27 functions as an output port P2.
The other end of the second center electrode 36 is connected to the matching capacitor C2 and the external connection terminal electrode 28 arranged on the lower surface of the circuit board 20 through the connection electrode 36p arranged on the lower surface 32d of the ferrite 32 and the terminal electrode 25c arranged on the upper surface of the circuit board 20. The electrode 28 functions as a ground port P3.
In addition, the impedance matching capacitor Cp1 that is connected to ground is connected to a connection point of the input port P1 and the capacitor Cs1. Similarly, the impedance matching capacitor Cp2 that is connected to ground is connected to a connection point of the output port P2 and the capacitor Cs2.
The ferrite magnet assembly 30 is mounted on the circuit board 20. The variety of electrodes disposed on the lower surface 32d of the ferrite 32 are preferably reflow-soldered to the terminal electrodes 25a, 25b, and 25c disposed on the circuit board 20 in an integrated fashion. In addition, the lower surfaces of the permanent magnets 41 are bonded to the circuit board 20 using an adhesive agent in an integrated fashion.
For the reflow solder, a tin-silver-copper alloy-based solder, a tin-silver-zinc alloy-based solder, a tin-zinc-bismuth alloy-based solder, a tin-zinc-aluminum alloy-based solder, or a tin-copper-bismuth alloy-based solder can be used, for example. In addition to connection using a reflow solder, connection using a solder bump, a gold bump, a conductive paste, or a conductive adhesive agent may be employed.
For an adhesive agent used for bonding the permanent magnets 41 to the circuit board 20, one-component or two-component heat curable epoxy-based adhesive agent is suitably used. That is, by using both soldering and bonding when the ferrite magnet assembly 30 is connected to the circuit board 20, reliable connection can be obtained.
For the circuit board 20, a board formed by sintering the mixture of glass, alumina, and other dielectric materials or a composite board formed from a combination of a resin and other dielectric materials or a combination of a glass and other dielectric materials is employed. For the internal and external electrodes, a thick film formed from silver or a silver alloy, a copper thick film, or a copper foil is employed. In particular, for the external connection electrodes, it is desirable that nickel having a thickness of about 0.1 μm to about 5 μm, for example, is plated on the external connection electrodes and, subsequently, gold having a thickness of about 0.01 μm to about 1 μm, for example, is plated on the external connection electrodes. This plating increases corrosion resistance, decreases solder leaching, and prevents a reduction in the strength of solder connection caused by a variety of reasons.
The tabular yoke 10 has an electromagnetic shield function. The tabular yoke 10 is preferably secured to the upper surface of the ferrite magnet assembly 30 through a dielectric layer (for example, an adhesive agent layer) 15. The tabular yoke 10 is used to reduce magnetic leakage from the ferrite magnet assembly 30, leakage of a high-frequency electromagnetic field, and a magnetic effect from the outside and to provide an area used by a vacuum nozzle when the isolator is mounted on a substrate (not shown) using a chip mounter, and the vacuum nozzle picks up the isolator. The tabular yoke 10 is not necessarily connected to ground. However, the tabular yoke 10 may be connected to ground using a solder or a conductive adhesive agent, for example. When the tabular yoke 10 is connected to ground, the effect of high-frequency shielding can be improved.
The tabular yoke 10 is formed by plating a soft iron steel sheet, a silicon steel sheet, a pure iron sheet, a nickel sheet, or a nickel-iron alloy sheet. A soft iron steel sheet, a silicon steel sheet, and a pure iron sheet have a high saturation magnetic flux density and a low remanent magnetic flux density and therefore have a large electromagnetic shield effect. In addition, adjustment of the remanent magnetic flux density of the permanent magnets 41 is facilitated, and the remanent magnetic flux density is advantageously stabilized. It is desirable to plate such a sheet with a nickel undercoat having a thickness of about 1 μm to about 5 μm, for example, and a silver overcoat having a thickness of about 1 μm to about 5 μm, for example. However, the undercoat may be copper. The silver overcoat reduces eddy current loss, and therefore, the insertion loss of the isolator can be minimized.
It is desirable that an epoxy-based resin, such as a one-component heat-curable epoxy-based adhesive agent, for example, is used for the dielectric layer 15 that secures the tabular yoke 10 to the upper surface of the ferrite magnet assembly 30. This is because the adhesive agent has an excellent heat resistance, working properties, and mechanical strength. Alternatively, an adhesive agent arranged into a sheet in advance, for example, a semi-cured heat-curable epoxy-based adhesive sheet, may be used. The adhesive agent sheet allows the thickness of the adhesive layer to be uniform, and therefore, an isolator having stable electrical properties can be produced.
The tabular yoke 10 is assembled onto the ferrite magnet assembly 30 mounted on the circuit board 20. At that time, a plurality of the tabular yokes 10 cut into a predetermined size may be individually assembled. A plurality of yokes 10 integrated into one piece and defining a collective yoke may be separated one by one and assembled onto the ferrite magnet assembly 30. Alternatively, the collective yoke 10 may be assembled onto the ferrite magnet assembly 30 mounted on a collective circuit board 20. Thereafter, the collective yoke 10 may be separated into individual yokes 10 by using, for example, a dicer. In such a method for producing a plurality of components at a time, the circuit board 20 and the tabular yoke 10 have the same outer shape.
In a 2-port isolator having the above-described structure, one end of the first center electrode 35 is connected to the input port P1, while the other end is connected to the output port P2. One end of the second center electrode 36 is connected to the output port P2, while the other end is connected to the ground port P3. Accordingly, a 2-port lumped constant isolator having a small insertion loss can be generated. In addition, during operation, a large high-frequency current flows in the second center electrode 36, while negligible high-frequency current flows in the first center electrode 35. Therefore, the direction of the high-frequency magnetic field generated by the first center electrode 35 and the second center electrode 36 is determined by the layout of the second center electrode 36. Since the direction of the high-frequency magnetic field can be determined, a method for decreasing the insertion loss can be easily implemented.
In addition, since the tabular yoke 10 is disposed immediately above the ferrite magnet assembly 30 with the dielectric layer 15 therebetween, the need for a soft iron yoke having a ring shape or a box shape that is required for existing isolators can be eliminated. Thus, the tabular yoke 10 can be easily produced and manipulated. Thus, the total cost can be reduced. Furthermore, since the tabular yoke 10 is not mechanically joined to the circuit board 20, damage of the circuit board 20 due to heat stress can be prevented. Thus, the reliability can be increased. Still furthermore, since the air gap G is defined between the tabular yoke 10 and a surface of the circuit board 20, a floating capacitance is rarely generated, as described above.
Furthermore, the need for a yoke that surrounds the ferrite magnet assembly 30 and that is required for existing isolators can be eliminated. Accordingly, the size of the outer shape can be reduced. Alternatively, the size of the outer shape of the ferrite magnet assembly 30 can be increased. Therefore, the electrical properties can be improved. In particular, when the sizes of the first center electrode 35 and the second center electrode 36 are increased, the inductance value and the Q value are increased.
Still furthermore, in the ferrite magnet assembly 30, since the ferrite 32 and a pair of the permanent magnets 41 are integrated into one piece using an adhesive agent 42, the ferrite magnet assembly 30 is mechanically stabilized. Thus, a rigid isolator that does not deform and is not damaged by vibration or a shock can be achieved.
In this isolator, the circuit board 20 is preferably a multi-layer dielectric board. Accordingly, the circuit board 20 can include a circuit network having capacitors and resistors therein. As a result, the size and thickness of the isolator can be reduced. In addition, since connection between the circuit components can be made inside the board, the reliability can be increased. It should be noted that the circuit board 20 does not necessarily have a multi-layer structure. For example, the circuit board 20 may have a single-layer structure, or matching capacitor chips may be externally mounted on the board.
A magnetic flux flow occurring when the tabular yoke 10 is employed is described next. As shown in
In addition, in order to make the isolator to be low-profile, it is desirable that the thickness of the tabular yoke 10 is small. However, if the thickness of the tabular yoke 10 is too small, the magnetic flux density inside the tabular yoke 10 increases. If the magnetic flux density exceeds the saturation magnetic flux density, the occurrence of magnetic flux leakage increases, and therefore, a magnetic resistance increases. To solve this problem, more powerful and larger permanent magnets 41 are required. Accordingly, it is desirable that the thickness of the tabular yoke 10 preferably ranges from about 0.02 mm to about 0.2 mm, for example. However, the thickness is not limited to this range.
The thickness of the dielectric layer 15 is described next. That is, by setting the thickness of the dielectric layer 15 disposed between the ferrite magnet assembly 30 and the tabular yoke 10 to a value within a predetermined range described below, a leakage magnetic flux can be reduced. In addition, a direct-current bias magnetic flux density having an excellent intensity distribution can be realized.
More specifically, it is desirable that the thickness of the dielectric layer 15 is preferably greater than or equal to about 0.02 mm, for example. As shown in
In addition, it is desirable that the thickness of the dielectric layer 15 is preferably less than or equal to about 0.1 mm, for example. As shown in
It is desirable that the magnetic flux densities shown in
Note that the graphs shown in
Ferrite: a YIG ferrite, a thickness of about 0.12 mm, a height of about 0.50 mm, a length of about 1.5 mm (the length in a depth direction in
Magnet: a ferrite magnet, a thickness of about 0.45 mm, a height of about 0.50 mm, a length of about 1.5 mm (the length in a depth direction in
Dielectric layer: a semi-cured epoxy-based adhesive sheet, a horizontal width of about 1.95 mm, a thickness of 0.00 to about 0.20 mm, a length of about 1.95 mm (the length in a depth direction in
Yoke: a nickel-iron alloy plated with a copper undercoat and a silver overcoat, a horizontal width of about 1.95 mm, a thickness of about 0.10 mm, a length of about 1.95 mm (the length in a depth direction in
Modification of Center Electrode (
More specifically, the ferrite 32 is separated into a middle segment 32x and side segments 32y and 32z. The electrodes 36b, 36f, 36j, and 35a are arranged on the upper surface of the middle segment 32x. The electrodes 35b, 35c, 36d, 36h, and 36l are arranged on the lower surface of the middle segment 32x. The first center electrode 35 and separated portions of the second center electrode 36 are arranged from conductor films on a principal surface of each of the side segments 32y and 32z. By bonding the principle surface of the side segment 32y to one of the principle surfaces of the middle segment 32x and bonding the principle surface of the side segment 32z to the other principle surface of the middle segment 32x, the ferrite 32 including the center electrodes 35 and 36 therein can be formed. The permanent magnets 41 are bonded, using the adhesive agent 42, to the two principle surfaces of the ferrite 32 formed by using the above-described bonding procedure. In this way, the ferrite magnet assembly 30 is formed.
According to a second preferred embodiment, as shown in
More specifically, each of the bent portions 10a is bent towards a direction perpendicular or substantially perpendicular to the direction of a magnetic bias emanating from the permanent magnets 41 and acting on the ferrite 32 (the direction indicated by arrow A). The bent portions 10a receive the direct current magnetic flux emanating from the side surface perpendicular or substantially perpendicular to the magnetic bias direction of the permanent magnets 41 and cause the direct current magnetic flux to circulate inside the yoke 10. As a result, leakage of the direct current magnetic flux can be reduced, and therefore, the risk of the leakage magnetic field having a negative effect on the outside can be reduced. In addition, the magnetic resistance of the direct current magnetic circuit is reduced, and therefore, the size of the permanent magnets 41 can be reduced. As a result, the size of the isolator can be reduced.
According to a third preferred embodiment, as shown in
More specifically, each of the bent portions 10b is bent towards a direction parallel or substantially parallel to the direction of a magnetic bias emanating from the permanent magnets 41 and acting on the ferrite 32 (the direction indicated by arrow A). The bent portions 10b can increase the cross-section of a magnetic path portion where the direct current magnetic flux circulating inside the yoke 10 is maximized. As a result, magnetic saturation of the yoke 10 can be prevented, and therefore, leakage of the direct current magnetic flux can be reduced. Thus, the risk of the leakage magnetic field having a negative effect on the outside can be reduced. In addition, since magnetic saturation rarely occurs, a thinner magnetic material plate can be used, and therefore, the isolator can be made low-profile and can be reduced in size. Furthermore, leakage of the magnetic flux from a surface parallel or substantially parallel to the magnetic bias direction can be reduced.
While the non-reciprocal circuit elements according to the present invention has been described with reference to the foregoing preferred embodiments, various modifications can be made without departing from the spirit of the present invention.
For example, by reversing the N pole and S pole of the permanent magnets 41, the input port P1 and the output port P2 can be reversed. In addition, while the foregoing preferred embodiments have been described with reference to a circuit board including all of the matching circuit elements, a chip inductor and a chip capacitor may be externally mounted on the circuit board, for example.
Furthermore, the shapes of the first center electrode 35 and the second center electrode 36 may be changed in a variety of ways. For example, while the foregoing preferred embodiments have been described with reference to the first center electrode 35 that branches into two on the principal surfaces 32a and 32b of the ferrite 32, the first center electrode 35 need not be branched. Still furthermore, the second center electrode 36 may be wound for at least one turn, for example.
As described above, the present invention can be effectively applied to a non-reciprocal circuit element. In particular, the non-reciprocal circuit element according to various preferred embodiments of the present invention is advantageous in that the non-reciprocal circuit element has a simplified structure, a stable electrical characteristic, and a high reliability.
While preferred embodiments of the present invention have been described above, it is to be understood that variations and modifications will be apparent to those skilled in the art without departing the scope and spirit of the present invention. The scope of the present invention, therefore, is to be determined solely by the following claims.
Number | Date | Country | Kind |
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2007-028390 | Feb 2007 | JP | national |
Number | Name | Date | Kind |
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7532084 | Wada et al. | May 2009 | B2 |
20020014927 | Makino et al. | Feb 2002 | A1 |
20020033742 | Makino et al. | Mar 2002 | A1 |
20070046390 | Soda et al. | Mar 2007 | A1 |
Number | Date | Country |
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2002-026615 | Jan 2002 | JP |
2002-198707 | Jul 2002 | JP |
2006-013970 | Jan 2006 | JP |
2006-211373 | Aug 2006 | JP |
2006011382 | Feb 2006 | WO |
2006011383 | Feb 2006 | WO |
Number | Date | Country | |
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20090261920 A1 | Oct 2009 | US |
Number | Date | Country | |
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Parent | PCT/JP2007/072477 | Nov 2007 | US |
Child | 12495850 | US |