Novel castor oil-based polyol emulsions

Abstract

A polyol emulsion of castor oil and monoepoxides is combined with methylenediphenyl diisocyanate (MDI) and cement to produce a polymer cement.

Description

Claims

1. An emulsion comprising: a) from 25 to 45 parts by weight of water,b) from 45 to 69.5 parts by weight of castor oil,c) from 5 to 30 parts by weight of monoepoxide andd) from 0.5 to 5 parts by weight of auxiliaries and additives.

2. The emulsion of claim 1 in which c) is a compound represented by the formula (I)

3. The emulsion of claim 2 in which d) comprises a nonionic emulsifier based on a sorbitan ester, mineral oil or hydroxyethylcellulose.

4. The emulsion of claim 1 in which d) comprises a nonionic emulsifier based on a sorbitan ester, mineral oil or hydroxyethylcellulose.

5. The emulsion of claim 1 having a viscosity of from 90 to 300 mPa·s at 23° C.

6. The emulsion of claim 2 having a viscosity of from 90 to 300 mPa·s at 23° C.

7. The emulsion of claim 3 having a viscosity of from 90 to 300 mPa·s at 23° C.

8. A polymer cement comprising: (1) from 10 to 25 parts by weight of the emulsion of claim 1,(2) from 10 to 40 parts by weight of MDI (methylenediphenyl diisocyanate) and(3) from 35 to 80 parts by weight of cement.

9. The polymer cement of claim 8 in which (2) is a mixture of from 30 to 85% by weight of MDI isomers having two aromatic 6-membered rings per molecule and from 15 to 70% by weight of higher molecular weight MDI homologs containing three or more aromatic 6-membered rings per molecule.

10. The polymer cement of claim 9 in which the cement contains at least 23% by weight of CaO and from 1 to 10% by weight of calcium hydroxide.

11. The polymer cement of claim 8 in which the cement contains at least 23% by weight of CaO and from 1 to 10% by weight of calcium hydroxide.

12. A molded article produced from the polymer cement of claim 8.