NOVEL COMPOSITIONS FOR SOUR TASTE BALANCING

Information

  • Patent Application
  • 20240292874
  • Publication Number
    20240292874
  • Date Filed
    January 08, 2021
    4 years ago
  • Date Published
    September 05, 2024
    a year ago
  • CPC
    • A23L27/88
    • A23L27/204
    • A23L27/84
  • International Classifications
    • A23L27/00
    • A23L27/20
Abstract
The invention relates to an aroma composition comprising at least one taste modifier having the general formula I or a salt thereof, a semi-finished product comprising such an aroma composition, a finished product comprising such an aroma composition and/or such a semi-finished product, the use of at least one specific taste modifier and a method for improving the sweet/sour balance and/or reducing the sweet/sour imbalance and/or improving the mouthfeel in a preparation.
Description

The invention relates to an aroma composition comprising at least one taste modifier having the general formula I or a salt thereof, a semi-finished product comprising such an aroma composition, a finished product comprising such an aroma composition and/or such a semi-finished product, the use of at least one specific taste modifier and a method for improving the sweet/sour balance and/or reducing the sweet/sour imbalance and/or improving the mouthfeel in a preparation.


Food or beverages often contain various unpleasant-tasting substances, such as strong acidic substances. These substances provide a (strong) sour taste of the food or beverage, which may be desirable in some cases (e.g. fruit or edible acids in sweet juices or refreshing drinks). However, in many cases, this strong sour taste is not desired or accepted by consumers and is typically attenuated or masked by a sweet taste conveyed by diverse sweetening substances.


Sour taste is caused by proton acids. In this case, the so-called titratable proton concentration is more important for the acid impression than the pH: for example, a hydrochloric acid solution having the same pH value as a malic acid solution tastes significantly less acidic in comparison. Classically, the unpleasant acid taste is greatly mitigated by combination with sweet flavours, especially sugar. In this case, however, regularly sweet-tasting substances (for example, sweeteners) have to be used in comparatively high concentrations, i.e. usually in an amount, which would correspond to at least 2 wt.-% aqueous sucrose solution (sucrose solution).


Likewise, foods (nourishment, including beverages) or semi-luxury foods which have a high sugar content (primarily sucrose, lactose, glucose or fructose or mixtures thereof) are usually strongly preferred by consumers owing to their sweetness.


Simultaneously, it is generally known that a high content of easily metabolisable carbohydrates allows the blood sugar level to strongly increase, leads to the formation of fatty deposits and can ultimately lead to health problems, such as excess weight, obesity, insulin resistance, late-onset diabetes and their secondary diseases. In particular there is also the aggravation that many of the above-mentioned carbohydrates can also affect dental health as they are broken down by specific types of bacteria in the oral cavity, e.g. into lactic acid, and can attack the tooth enamel of adolescent or adult teeth (e.g. causing cavities). It has therefore long been the aim and policy to reduce the sugar content of foods and/or semi-luxury foods to the absolutely necessary amount.


The negative impact of this approach is that the acid-masking effect as described above is negatively influenced by reducing the sugar contents in the targeted products. Consequently, the balance of sweet and sour perception in these products is disturbed, which appears as unpleasant and imbalanced to consumers. This also applies to products, in which a sour taste impression is desired, as described above, as also in these products, the sour taste is perceived as unpleasant if it becomes too strong.


A reduction of the components evoking the acidic taste would presumably restore the balance. However, in a large number of cases, such as foods derived from sweet and sour fruits or vegetables (e.g. fruit juices, fruit preparations and foodstuffs made therefrom) and products made by fermentation using acid-producing microorganisms (e.g. yoghurt, ghee, kefir, soy yoghurt, Sauerkraut, sourdough bread, sausages, sour milk, cheese, mixed pickles, lactobionic acid or glucuronic acid-containing soft drinks), the amount of acids is necessary to produce the microbial stability of the product. Thus, it is usually not possible to simply reduce the amount of the components evoking the acidic taste.


The same also applies to compositions and semi-finished products, which are processed into such foods and semi-luxury foods.


Typically, in the state of the art, the acidic taste, which is intensified by reducing sweet tasting sugar components as described above, is masked or reduced by artificially increasing the sweet taste impression with one or more sweeteners. These are chemically uniform substances, which do not themselves have a calorific value, or have only a very low calorific value, and simultaneously give a strong sweet taste impression. The substances are usually non-cariogenic (overview: Valerie B. Duffy, Madeleine Sigman-Grant, Margaret A. Powers, Denise Elmore, Esther F. Myers, Diane Quagliani, Marie Spano, Kimberly F. Stitzel, Sue Taylor, Robert Earl and Sonja Connor, Journal of the American Dietetic Association 2004, 104 (2), 255-275). Some of these are known as bulk sweeteners, such as sorbitol, mannitol or other sugar alcohols, which are outstanding sweeteners and can also partially replace the remaining food technology-related properties of sugars, but too frequent intake leads to osmotically-induced digestion problems among some people. While, owing to their low concentration in use, the non-nutritive, highly intensive sweeteners are very suitable for bringing sweetness into foods, however they often exhibit taste-related problems as a result of time-intensity profiles which are not similar to sugar (e.g. sucralose, stevioside, cyclamate), a bitter and/or astringent aftertaste (e.g. acesulfame K, saccharin), or pronounced additional flavour impressions (e.g. glycyrrhetinic acid ammonium salt). Some of the sweeteners are not particularly stable as regards heat (e.g. thaumatin, brazzein, monellin), are not stable in all applications (e.g. aspartame) and are sometimes very long-lasting in terms of their sweet effect (strong sweet aftertaste, e.g. saccharin).


An improvement in the taste properties, in particular the aftertaste problem of non-nutritive, highly intensive sweeteners, can be achieved by the use of tannic acid, e.g. as described in WO 98/20753, or phenolic acids as in U.S. Pat. No. 3,924,017. However, substances of this type are not particularly stable in applications owing to their catechol units.


A further possibility—without using non-nutritive sweeteners—consists in reducing the sugar content of food and/or semi-luxury foods and adding sensorially weak or imperceptible substances which indirectly or directly enhance the sweetness, as described for example in WO 2005/041684. The substances described in WO 2005/041684 are, however, explicitly of non-natural origin and are therefore more difficult to assess from a toxicological perspective than substances of natural origin and need to be declared as such on the product's ingredient list, in particular if the latter occur in foods or semi-luxury foods or originate from raw materials for obtaining foods or semi-luxury foods.


EP 1 291 342 A1 describes non-nutritive sweeteners of natural origin (pyridinium betaines). However, they do not selectively affect the sweet taste, as rather other tastes, such as savouriness or saltiness, are affected. In addition, the disclosed substances can only be purified with high expenditure.


Thus, by using the sweeteners, the sweet taste impression is such strong, that the consumers no longer perceive the sour taste impression, at least in an unpleasant manner. However, it is often difficult to find the correct amount of sweeteners to perfectly balance the sweet and sour taste impressions. Typically, the sweeteners need to be added in huge amounts to mask or reduce the sour taste impression. However, in these amounts, the sweeteners themselves cause a negative, usually bitter, taste impression, as described above. Furthermore, such a high amount of sweeteners is often not applicable, for example in products, in which such a strong sweet taste impression is not desired.


It was therefore the primary object of the present invention to provide aroma compositions, which can mask and/or reduce the acidic taste impression of compounds, also in preparations, in particular in foodstuffs and pharmaceuticals, preferably without influencing the desired taste impression of these preparations.


The primary object of the present invention is achieved by an aroma composition, wherein the aroma composition comprises at least one taste modifier having the general formula I or a salt thereof,




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    • wherein

    • X and Y denote independently of each other —CH2—or O, wherein either
      • X=—CH2—and Y═O, or
      • X═O and Y=—CH2—,
      • under the provision that
        • if X=—CH2—and Y=O, R1 and R2 together represent a single bond or R1=H and R2=H, and
        • if X=—O—and Y=—CH2—, R1 and R2 together represent a single bond,

    • R3 denotes —H or —OH,

    • R4 denotes —H or —CH3,

    • preferably wherein
      • R3 and R4 denote —H, or
      • R3 denotes —OH and R4 denotes —CH3,

    • and

    • R5 denotes —H, —OH or —O-glucopyranoside, preferably —H, —OH or —O-beta-D-glucopyranoside,

    • wherein the total amount of the at least one taste modifier in the aroma composition
      • is such that the at least one taste modifier provides no sweetness impression or a sweetness impression of less than 1.5% sucrose equivalents in the aroma composition, and
      • such that the total amount of the at least one taste modifier is not sufficient to enhance the sweetness of a/another sweet tasting substance in the aroma composition, if present.





The term “R1 and R2 together represent a single bond” is meant to be understood such that the Y in formula (I), which is connected to R1, and the carbon atom in formula (I), which is connected to R2, together are connected with a single bond and thus form part of a closed 6-membered ring structure, further including X and the 3 further carbon atoms.


It was surprisingly found that balancing the acidic taste impressions by adding the taste modifiers according to formula (I) in a concentration, in which the taste modifiers themselves do not provide a sweet taste or only a sweet taste, which is below 1.5% sucrose equivalents, has been particularly advantageous in masking and/or reducing. This is in contrast to the procedures in the prior art, in which the acidic taste impressions are masked by (strongly) increasing or adding a sweet taste impression.


The terms “acidic taste”, “acidic taste impression”, “sour taste” and “sour taste impression” as used herein can preferably be used interchangeably.


The term “such that the at least one taste modifier provides no sweetness impression or a sweetness impression of less than 1.5% sucrose equivalents” is meant to be understood such that the respective taste modifier(s) itself/themselves does not have a sweet taste or a sweet taste of less than 1.5% sucrose equivalents. In case, several taste modifiers are present, preferably the combination of all taste modifiers does not have a sweet taste or a sweet taste of less than 1.5% sucrose equivalents.


In contrast, the term “such that the total amount of the at least one taste modifier is not sufficient to enhance the sweetness of a/another sweet tasting substance” refers to (an) other substance(s) present in the aroma composition. The sweetness of which is not enhanced by the total amount of all taste modifiers according to formula (I) together in the aroma composition according to the invention.


For a taste modifier providing (or not providing) a sweet taste, the sweetness must be measured. Measuring sweetness is typically based on the “percent sucrose equivalent”: Sweetness is commonly measured by comparison to reference solutions of sucrose, which is the standard to which all other sweeteners are compared. The human threshold for recognizing sweetness in a sucrose solution is at approximately 1.5% sucrose, which is thus defined as 1.5% sucrose equivalents. As a comparison, coffee is typically sweetened to an extent, which corresponds to a 5% sucrose solution (5% sucrose equivalents), whereas soft drinks are typically as sweet as a 10% sucrose solution (10% sucrose equivalents). For assessing the sweetness, taste panellists are requested to quantitate sweetness, using 2 to 15% sucrose solutions as references. Other sweeteners are then tasted at a series of dilutions to determine the concentration that is as sweet as a given percent sucrose reference.


It was surprisingly further found that the aroma composition according to the invention does not only reduce and/or mask the acidic taste impression but may also have a positive effect on other, desired taste impressions. Thus, it is preferred that the total amount of the at least one taste modifier according to formula (I) is sufficient to improve or enhance a desired taste impression, preferably one or more selected from spicy, mouthfeel, complex, balanced, juicy, floral, richness and combinations thereof, such as spicy, juicy and/or floral.


All of the taste impressions, as described above, are common taste impressions used by panellists to describe taste impressions and are thus known to the skilled person. To determine whether such a desired taste impression (or preferably any taste impression) is improved or enhanced, simple testing (usually in duplicates, preferably in triplicates) performed by panellists may be applied, in which the panellists evaluate e.g. samples with and samples without the at least one taste modifier(s) according to formula (I) and/or different samples with varying amounts of the at least one taste modifier according to formula (I).


It is preferred that the at least one taste modifier is/are selected from the group consisting of naringenin, phloretin, hesperetin, hesperetin dihydrochalcone, phyllodulcin, trilobatin, hydrangenol, hesperetin dihydrochalcone 4-O-glucoside, and salts thereof. Furthermore, it is preferred that the at least one taste modifier is/are

    • phloretin,
    • hesperetin,
    • hesperetin dihydrochalcone,
    • naringenin,
    • phyllodulcin,
    • phloretin and at least one further taste modifier selected from the group consisting of naringenin, hesperetin, hesperetin dihydrochalcone, phyllodulcin, trilobatin, hydrangenol, hesperetin dihydrochalcone 4-O-glucoside, or (a) salt(s) thereof.


The terms “and salts thereof” and “or (a) salt(s) thereof”, as used herein, are to be used interchangeably and are both to be understood such that, in case several taste modifiers according to formula (I) are used, at least one is present as a salt of the above mentioned taste modifiers, whereas the other(s) may be present as the taste modifier as described above and/or a salt thereof. Thus, in case more than one taste modifier is used, the aroma composition according to the invention comprises a mixture of these taste modifiers, wherein

    • all of the taste modifiers are present as described above, i.e. not as a salt thereof,
    • all of the taste modifiers are present as a salt of the taste modifiers as described above, wherein a salt may be any physiologically acceptable salt thereof, or
    • one or more of the taste modifiers are present as a salt of the taste modifiers as described above, wherein a salt may be any physiologically acceptable salt thereof, which includes the possibility, in which the aroma composition may comprise at least one taste modifier(s) as described above, i.e. not as a salt, as well as a salt of this/these taste modifier(s).


It was surprisingly found that phloretin was particularly advantageous in masking and/or reducing the acidic taste impression.


The taste modifiers listed above are described by the following chemical structures. In case of discrepancies, the chemical structures as shown below are the compounds, it is referred to herein.




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Furthermore, it is preferred that the aroma composition according to the invention comprises two taste modifiers having the general formula I, wherein the taste modifiers are

    • phloretin and hesperetin
    • phloretin and hesperetin dihydrochalcone
    • hesperetin and hesperetin dihydrochalcone
    • phloretin and naringenin
    • naringenin and hesperetin
    • phloretin and phyllodulcin
    • hesperetin and phyllodulcin
    • hesperetin dihydrochalcone and naringenin


      or
    • hesperetin dihydrochalcone and phyllodulcin


      or salts thereof.


It is also preferred that the aroma composition according to the invention comprises three taste modifiers having the general formula I, wherein the taste modifiers are

    • phloretin, hesperetin and naringenin
    • phloretin, hesperetin and hesperetin dihydrochalcone
    • phloretin, naringenin and hesperetin dihydrochalcone
    • phloretin, phyllodulcin and hesperetin dihydrochalcone
    • hesperetin, phyllodulcin and hesperetin dihydrochalcone
    • phloretin, hesperetin and phyllodulcin
    • phloretin, naringenin and phyllodulcin
    • hesperetin, naringenin and phyllodulcin
    • phloretin, hesperetin and trilobatin
    • phloretin, naringenin and trilobatin
    • hesperetin, naringenin and trilobatin


      or salts thereof.


It was surprisingly found that these compounds or these combinations of compounds, as described above, are particularly advantageous when used as taste modifiers in a composition according to the invention.


Furthermore it is preferred in the aroma composition according to the invention, that the at least one taste modifier is present in a total amount of 0.5 to 100 ppm, preferably in a total amount of 1 to 80 ppm and most preferably in a total amount of 1.5 to 60 ppm.


The term “the at least one taste modifier is present in a total amount of” is meant to be understood such that the total amount of all taste modifiers according to formula (I) is in the described range.


It was surprisingly found that in this range the masking and/or reduction of the acidic taste was particularly advantageous.


It is to be noted that the conditions of the total amount of taste modifiers according to formula (I), as described above, i.e. such that the at least one taste modifier provides no sweetness impression or a sweetness impression of less than 1.5% sucrose equivalents in the aroma composition, and such that the total amount of the at least one taste modifier is not sufficient to enhance the sweetness of a/another sweet tasting substance in the aroma composition, if present, still apply.


Typically, all conditions are complied with, when the total amount of taste modifiers according to formula (I) in the aroma composition according to the invention is in the ranges as described above. To confirm that all conditions are complied with, it is a simple procedure, as described above, and which is commonly and routinely performed in the state of the art, to determine whether these conditions are fulfilled. Thus, a skilled person can easily determine, whether the at least one taste modifiers according to formula (I) is present in a total amount as described as preferred above in the aroma composition, and provide(s) a sweetness impression itself/themselves or not (and if yes, in which extent) or enhance(s) the sweetness of a/another substance in the composition or not.


Consequently, it is preferred that the total amount of taste modifiers according to formula (I) in the composition

    • is such that the at least one taste modifier provides no sweetness impression or a sweetness impression of less than 1.5% sucrose equivalents in the aroma composition, and such that the total amount of the at least one taste modifier is not sufficient to enhance the sweetness of a/another sweet tasting substance in the aroma composition, if present,


      and simultaneously
    • is in a range of from 0.5 to 100 ppm, preferably in a range of from 1 to 80 ppm and most preferably in a range of from 1.5 to 60 ppm.


It was surprisingly found that the taste modifiers according to formula (I) are particularly advantageous for reducing and/or masking an acidic taste impression. In many applications, such as several foodstuffs or semi-luxury foods, a sour taste is generally desired, however not in an unpleasant extent. Thus, in this case, at least one compound conveying a sour taste needs to be present. Additionally, it is beneficial if such a compound is an acid, as it may then be used to adjust the pH value in the composition such that it is microbially stable. Furthermore, as the aroma composition according to the invention may be consumed, e.g. when present in foodstuff or semi-luxury foods, it is (in this case) necessary that the compound conveying a sour taste and providing the necessary pH value needed for microbial stability, as described above, is physiologically acceptable.


Thus, the aroma composition additionally preferably comprises at least one compound conveying a sour taste, preferably one or more food acids, preferably selected from the group consisting of acetic acid, adipic acid, aspartic acid, benzoic acid, sorbic acid, caffeotannic acid, citric acid, iso-citric acid, fumaric acid, galacturonic acid, gluconic acid, glucuronic acid, glyceric acid, glycolic acid, ketoglutaric acid, [alpha]-ketoglutaric acid, lactic acid, lactoisocitric acid, malic acid, maleic acid, oxalacetic acid, oxalic acid, phosphoric acid, pyruvic acid, quinic acid, shikimic acid, succinic acid, tannic acid, and tartaric acid, in particular preferred one or more food acids selected from adipic acid, citric acid, fumaric acid, gluconic acid, glucuronic acid, lactic acid, malic acid, phosphoric acid, succinic acid, and tartaric acid.


Further, it is advantageous in many applications, that the aroma composition itself provides a sweet taste impression, e.g. when present in foodstuff or semi-luxury foods. Thus, in this case, at least one compound conveying a sweet taste at least needs to be present. Also in this case, it is necessary that the compound conveying a sweet taste is physiologically acceptable.


Therefore, additionally or alternatively to what was described for the at least one compound conveying a sour taste, it is preferred that the aroma composition according to the invention additionally comprises at least one compound conveying a sweet taste, preferably selected from the group consisting of natural sweeteners, preferably naturally occurring sweet tasting substances, including plant extracts, such as proteins (such as miraculin, pentaidin, monellin, thaumatin, curculin, brazzein, mabinlin), D-amino acids (such as D-phenylalanine, D-tryptophan) or extracts or fractions obtained from natural sources containing these amino acids and/or proteins and the physiologically acceptable salts of these amino acids and/or proteins, particularly the sodium, potassium, calcium or ammonium salts thereof; neohesperidindihydrochalkone, naringindihydrochalkone, steviolgylcoside, stevioside, steviolbioside, rebaudioside, rebaudioside A, rebaudioside B, rebaudioside C, rebaudioside D, rebaudioside E, rebaudioside F, rebaudioside G, rebaudioside H, rebaudioside M, rebaudioside N, rebaudioside X, dulcoside, Rubusoside, suavioside A, suavioside B, suavioside G, suavioside H, suavioside I, suavioside J, baiyunoside 1, baiyunoside 2, phlomisoside 1, phlomisoside 2, phlomisoside 3, phlomisoside 4, abrusoside A, abrusoside B, abrusoside C, abrusoside D, cyclocaryoside A, cyclocaryoside I, oslandin, polypodoside A, strogin 1, strogin, 2, strogin 4, selligueanin A, dihydroquercetin-3-acetate, perillartin, telosmosid A15, periandrin I-V, pterocaryoside, cyclocaryoside, mukurozioside, trans-Anethol, trans-cinnamaldehyd, bryoside, bryonoside, bryonodulcoside, carnosifloside, scandenoside, gypenoside, hematoxylin, cyanin, chlorogenic acid, albiziasaponin, telosmoside, gaudichaudiosid, mogrosides, such as mogroside V, hernandulcine, monatin, glycyrrhetinic acid and its derivatives, particularly glycyrrhizin, preferably glycyrrhizin ammonium salt; extracts or enriched fractions of such extracts such as extracts of Thaumatococcus or Stevia ssp., particularly Stevia rebaudiana, swingle extracts, particularly Momordica or Siratio grosvenorii or Luo-Han-Guo, extracts of Glycerrhyzia ssp., particularly Glycerrhyzia glabra, extracts of Rubus ssp., particularly Rubus suavissimus, extracts of Lippia dulcis, extracts of Mycetia balansae, preferably comprising balansin A and/or balansin B, or further extracts as described in EP 11168468;

    • synthetic sweeteners, preferably synthetic sweet tasting substances, preferably selected from the group consisting of magap, sodium cyclamate or other physiologically acceptable salts of cyclamic acid, acesulfam K; neohesperidindihydrochalcone, naringindihydrochalcone, saccharin, saccharin sodium salt, aspartam, superaspartam, neotam, alitam, advantam, perillartin, sucralose, lugduname, carrelame, sucrononate or sucrooctate;
    • sweet tasting carbohydrates, preferably selected from the group consisting of sucrose, trehalose, lactose, maltose, melizitose, melibiose, raffinose, palatinose, lactulose, D-fructose, D-glucose, D-galactose, I-rhamnose, D-sorbose, D-mannose, D-tagatose, D-allulose, D-arabinose, I-arabinose, D-ribose, D-glyceraldehyde, maltodextrin, and vegetable preparations comprising one or more of these carbohydrates, preferably in an amount of at least 5 wt.-%, preferably at least 15 wt.-%, wherein in these preparations the carbohydrates can be present as naturally occurring or synthetic carbohydrates or a mixture thereof, such as preferably honey, invert sugar syrup or highly enriched fructose syrup from maize starch, and/or the physiologically acceptable salts of these carbohydrates, particularly sodium, potassium, calcium or ammonium salts thereof;
    • sugar alcohols, preferably naturally occurring sugar alcohols, preferably selected from the group consisting of glycerin, erythritol, threitol, arabitol, ribitol, xylitol, sorbitol, mannitol, maltitol, isomaltit, dulcitol, lactitol and the physiologically acceptable salts thereof, particularly the sodium, potassium, calcium or ammonium salts thereof.


Furthermore, it is preferred that the aroma composition according to the invention comprises at least one compound conveying a sour taste, preferably as described above, and at least one compound conveying a sweet taste, preferably as described above, and wherein the total amount of the at least one taste modifier in the aroma composition is sufficient to improve the sweet/sour balance and/or reduce the sweet/sour imbalance and/or improve the mouthfeel in a composition. As described above, these characteristics can be easily determined by e.g. evaluations of panellists.


The term “improve the sweet/sour balance” is meant to be understood such that the balance of the sour and sweet taste impressions is in a range, in which a consumer generally perceives it as pleasant or at least not unpleasant, i.e. it is balanced. However, such a perception of the consumer includes a broad range of the sweet/sour balance. Improving the sweet/sour balance is thus achieved by enhancing the sweet taste impression, however within the limits as described above, and/or reducing and/or masking the sour taste impression.


The term “reduce the sweet/sour imbalance” is meant to be understood such that the balance of the sour and sweet taste impressions is in a range, in which a consumer generally perceives it as unpleasant or at least not pleasant, i.e. it is imbalanced. However, such a perception of the consumer includes a broad range of the sweet/sour balance. Reducing the sweet/sour imbalance is thus achieved by enhancing the sweet taste impression, however within the limits as described above, and/or reducing and/or masking the sour taste impression.


The invention is further related to a semi-finished product intended for nutrition, enjoyment or cosmetic or pharmaceutical purposes comprising the aroma composition according to the invention.


What was said above with regard to the aroma composition according to the invention applies accordingly to the aroma composition comprised in the semi-finished product and/or the semi-finished product itself.


It is preferred that the total amount of the at least one taste modifier in the semi-finished product is such that the at least one taste modifier provides no sweetness impression or a sweetness impression of less than 1.5% sucrose equivalents in the semi-finished product, and such that the total amount of the at least one taste modifier is not sufficient to enhance the sweetness of a/another sweet tasting substance in the semi-finished product, if present.


Thus, and for the reasons outlined above, it is preferred that the semi-finished product additionally comprises

    • at least one compound conveying a sour taste, preferably one or more food acids, preferably selected from the group consisting of acetic acid, adipic acid, aspartic acid, benzoic acid, sorbic acid, caffeotannic acid, citric acid, iso-citric acid, fumaric acid, galacturonic acid, gluconic acid, glucuronic acid, glyceric acid, glycolic acid, ketoglutaric acid, [alpha]-ketoglutaric acid, lactic acid, lactoisocitric acid, malic acid, maleic acid, oxalacetic acid, oxalic acid, phosphoric acid, pyruvic acid, quinic acid, shikimic acid, succinic acid, tannic acid, and tartaric acid, in particular preferred one or more food acids selected from adipic acid, citric acid, fumaric acid, gluconic acid, glucuronic acid, lactic acid, malic acid, phosphoric acid, succinic acid, and tartaric acid,


      and/or


      at least one compound conveying a sweet taste, preferably selected from the group consisting of
    • natural sweeteners, preferably naturally occurring sweet tasting substances, including plant extracts, such as proteins (such as miraculin, pentaidin, monellin, thaumatin, curculin, brazzein, mabinlin), D-amino acids (such as D-phenylalanine, D-tryptophan) or extracts or fractions obtained from natural sources containing these amino acids and/or proteins and the physiologically acceptable salts of these amino acids and/or proteins, particularly the sodium, potassium, calcium or ammonium salts thereof; neohesperidindihydrochalkone, naringindihydrochalkone, steviolgylcoside, stevioside, steviolbioside, rebaudioside, rebaudioside A, rebaudioside B, rebaudioside C, rebaudioside D, rebaudioside E, rebaudioside F, rebaudioside G, rebaudioside H, rebaudioside M, rebaudioside N, rebaudioside X, dulcoside, Rubusoside, suavioside A, suavioside B, suavioside G, suavioside H, suavioside I, suavioside J, baiyunoside 1, baiyunoside 2, phlomisoside 1, phlomisoside 2, phlomisoside 3, phlomisoside 4, abrusoside A, abrusoside B, abrusoside C, abrusoside D, cyclocaryoside A, cyclocaryoside I, oslandin, polypodoside A, strogin 1, strogin, 2, strogin 4, selligueanin A, dihydroquercetin-3-acetate, perillartin, telosmosid A15, periandrin I-V, pterocaryoside, cyclocaryoside, mukurozioside, trans-Anethol, trans-cinnamaldehyd, bryoside, bryonoside, bryonodulcoside, carnosifloside, scandenoside, gypenoside, hematoxylin, cyanin, chlorogenic acid, albiziasaponin, telosmoside, gaudichaudiosid, mogrosides, such as mogroside V, hernandulcine, monatin, glycyrrhetinic acid and its derivatives, particularly glycyrrhizin, preferably glycyrrhizin ammonium salt; extracts or enriched fractions of such extracts such as extracts of Thaumatococcus or Stevia ssp., particularly Stevia rebaudiana, swingle extracts, particularly momordica or Siratio grosvenorii or Luo-Han-Guo, extracts of Glycerrhyzia ssp., particularly Glycerrhyzia glabra, extracts of Rubus ssp., particularly Rubus suavissimus, extracts of Lippia dulcis, extracts of Mycetia balansae, preferably comprising balansin A and/or balansin B, or further extracts as described in EP 11168468;
    • synthetic sweeteners, preferably synthetic sweet tasting substances, preferably selected from the group consisting of magap, sodium cyclamate or other physiologically acceptable salts of cyclamic acid, acesulfam K; neohesperidindihydrochalcone, naringindihydrochalcone, saccharin, saccharin sodium salt, aspartam, superaspartam, neotam, alitam, advantam, perillartin, sucralose, lugduname, carrelame, sucrononate or sucrooctate;
    • sweet tasting carbohydrates, preferably selected from the group consisting of sucrose, trehalose, lactose, maltose, melizitose, melibiose, raffinose, palatinose, lactulose, D-fructose, D-glucose, D-galactose, I-rhamnose, D-sorbose, D-mannose, D-tagatose, D-allulose, D-arabinose, I-arabinose, D-ribose, D-glyceraldehyde, maltodextrin, and vegetable preparations comprising one or more of these carbohydrates, preferably in an amount of at least 5 wt.-%, preferably at least 15 wt.-%, wherein in these preparations the carbohydrates can be present as naturally occurring or synthetic carbohydrates or a mixture thereof, such as preferably honey, invert sugar syrup or highly enriched fructose syrup from maize starch, and/or the physiologically acceptable salts of these carbohydrates, particularly sodium, potassium, calcium or ammonium salts thereof;
    • sugar alcohols, preferably naturally occurring sugar alcohols, preferably selected from the group consisting of glycerin, erythritol, threitol, arabitol, ribitol, xylitol, sorbitol, mannitol, maltitol, isomaltit, dulcitol, lactitol and the physiologically acceptable salts thereof, particularly the sodium, potassium, calcium or ammonium salts thereof, preferably wherein the semi-finished product comprises at least one compound conveying a sour taste and at least one compound conveying a sweet taste, wherein the total amount of the at least one taste modifier in the aroma composition, preferably in the semi-finished product, is sufficient to improve the sweet/sour balance and/or reduce the sweet/sour imbalance and/or improve the mouthfeel in the semi-finished product.


The at least one compound conveying a sour taste and/or the at least one compound conveying a sweet taste may be present in the aroma composition according to the invention before being added to produce the semi-finished product. Additionally or alternatively, the at least one compound conveying a sour taste and/or the at least one compound conveying a sweet taste may be present in a separate component than the aroma composition according to the invention (and/or a mixture of separate components) when producing the semi-finished product.


It is also preferred that, before being added to produce the semi-finished product, the aroma composition comprises the at least one compound conveying a sour taste or the at least one compound conveying a sweet taste, but not both, and a separate component (and/or a mixture of separate components) for producing the semi-finished product comprises the at least one compound conveying a sweet taste or the at least one compound conveying a sour taste. Thus, only the semi-finished product but not the aroma composition for producing the semi-finished product comprises both, the at least one compound conveying a sour taste and the at least one compound conveying a sweet taste. In this case, the desired effect caused by the aroma composition according to the invention is obtained during/after the production of the semi-finished product.


Preferably, a semi-finished product is to be understood as an orally consumable product, which, because of a very high content of flavourings and taste-imparting substances, is unsuitable for use as a ready-to-eat orally consumable product (in particular oral stuff or feed). Only by mixing with at least one further constituent (e.g. by reducing the concentration of the flavourings and taste-imparting substances in question) and optionally further process steps (e.g. heating, freezing) is the semi-finished product converted into a ready-to-eat orally consumable product (in particular oral stuff or feed).


The invention is further related to a finished product intended for nutrition, enjoyment or cosmetic or pharmaceutical purposes comprising the aroma composition according to the invention or a semi-finished product according to the invention.


What was said above with regard to the aroma composition according to the invention applies accordingly to the aroma composition comprised in the finished product.


It is further preferred that the total amount of the at least one taste modifier in the finished product is such that the at least one taste modifier provides no sweetness impression or a sweetness impression of less than 1.5% sucrose equivalents in the finished product, and such that the total amount of the at least one taste modifier is not sufficient to enhance the sweetness of a/another sweet tasting substance in the finished product, if present.


Thus, and for the reasons outlined above, it is preferred that the finished product additionally comprises

    • at least one compound conveying a sour taste, preferably one or more food acids, preferably selected from the group consisting of acetic acid, adipic acid, aspartic acid, benzoic acid, sorbic acid, caffeotannic acid, citric acid, iso-citric acid, fumaric acid, galacturonic acid, gluconic acid, glucuronic acid, glyceric acid, glycolic acid, ketoglutaric acid, [alpha]-ketoglutaric acid, lactic acid, lactoisocitric acid, malic acid, maleic acid, oxalacetic acid, oxalic acid, phosphoric acid, pyruvic acid, quinic acid, shikimic acid, succinic acid, tannic acid, and tartaric acid, in particular preferred one or more food acids selected from adipic acid, citric acid, fumaric acid, gluconic acid, glucuronic acid, lactic acid, malic acid, phosphoric acid, succinic acid, and tartaric acid,


      and/or


      at least one compound conveying a sweet taste, preferably selected from the group consisting of
    • natural sweeteners, preferably naturally occurring sweet tasting substances, including plant extracts, such as proteins (such as miraculin, pentaidin, monellin, thaumatin, curculin, brazzein, mabinlin), D-amino acids (such as D-phenylalanine, D-tryptophan) or extracts or fractions obtained from natural sources containing these amino acids and/or proteins and the physiologically acceptable salts of these amino acids and/or proteins, particularly the sodium, potassium, calcium or ammonium salts thereof; neohesperidindihydrochalkone, naringindihydrochalkone, steviolgylcoside, stevioside, steviolbioside, rebaudioside, rebaudioside A, rebaudioside B, rebaudioside C, rebaudioside D, rebaudioside E, rebaudioside F, rebaudioside G, rebaudioside H, rebaudioside M, rebaudioside N, rebaudioside X, dulcoside, Rubusoside, suavioside A, suavioside B, suavioside G, suavioside H, suavioside I, suavioside J, baiyunoside 1, baiyunoside 2, phlomisoside 1, phlomisoside 2, phlomisoside 3, phlomisoside 4, abrusoside A, abrusoside B, abrusoside C, abrusoside D, cyclocaryoside A, cyclocaryoside I, oslandin, polypodoside A, strogin 1, strogin, 2, strogin 4, selligueanin A, dihydroquercetin-3-acetate, perillartin, telosmosid A15, periandrin I-V, pterocaryoside, cyclocaryoside, mukurozioside, trans-Anethol, trans-cinnamaldehyd, bryoside, bryonoside, bryonodulcoside, carnosifloside, scandenoside, gypenoside, hematoxylin, cyanin, chlorogenic acid, albiziasaponin, telosmoside, gaudichaudiosid, mogrosides, such as mogroside V, hernandulcine, monatin, glycyrrhetinic acid and its derivatives, particularly glycyrrhizin, preferably glycyrrhizin ammonium salt; extracts or enriched fractions of such extracts such as extracts of Thaumatococcus or Stevia ssp., particularly Stevia rebaudiana, swingle extracts, particularly momordica or Siratio grosvenorii or Luo-Han-Guo, extracts of Glycerrhyzia ssp., particularly Glycerrhyzia glabra, extracts of Rubus ssp., particularly Rubus suavissimus, extracts of Lippia dulcis, extracts of Mycetia balansae, preferably comprising balansin A and/or balansin B, or further extracts as described in EP 11168468;
    • synthetic sweeteners, preferably synthetic sweet tasting substances, preferably selected from the group consisting of magap, sodium cyclamate or other physiologically acceptable salts of cyclamic acid, acesulfam K; neohesperidindihydrochalcone, naringindihydrochalcone, saccharin, saccharin sodium salt, aspartam, superaspartam, neotam, alitam, advantam, perillartin, sucralose, lugduname, carrelame, sucrononate or sucrooctate;
    • sweet tasting carbohydrates, preferably selected from the group consisting of sucrose, trehalose, lactose, maltose, melizitose, melibiose, raffinose, palatinose, lactulose, D-fructose, D-glucose, D-galactose, I-rhamnose, D-sorbose, D-mannose, D-tagatose, D-allulose, D-arabinose, I-arabinose, D-ribose, D-glyceraldehyde, maltodextrin, and vegetable preparations comprising one or more of these carbohydrates, preferably in an amount of at least 5 wt.-%, preferably at least 15 wt.-%, wherein in these preparations the carbohydrates can be present as naturally occurring or synthetic carbohydrates or a mixture thereof, such as preferably honey, invert sugar syrup or highly enriched fructose syrup from maize starch, and/or the physiologically acceptable salts of these carbohydrates, particularly sodium, potassium, calcium or ammonium salts thereof;
    • sugar alcohols, preferably naturally occurring sugar alcohols, preferably selected from the group consisting of glycerin, erythritol, threitol, arabitol, ribitol, xylitol, sorbitol, mannitol, maltitol, isomaltit, dulcitol, lactitol and the physiologically acceptable salts thereof, particularly the sodium, potassium, calcium or ammonium salts thereof,


      preferably wherein the finished product comprises at least one compound conveying a sour taste and at least one compound conveying a sweet taste, wherein the total amount of the at least one taste modifier in the aroma composition, preferably in the semi-finished product, particularly preferably in the finished product, is sufficient to improve the sweet/sour balance and/or reduce the sweet/sour imbalance and/or improve the mouthfeel in the finished product.


The at least one compound conveying a sour taste and/or the at least one compound conveying a sweet taste may be present in the aroma composition according to the invention before being added to produce the finished product. Additionally or alternatively, the at least one compound conveying a sour taste and/or the at least one compound conveying a sweet taste may be present in a separate component than the aroma composition according to the invention (and/or a mixture of separate components) when producing the finished product.


It is also preferred that, before being added to produce the finished product, the aroma composition comprises the at least one compound conveying a sour taste or the at least one compound conveying a sweet taste, but not both, and a separate component (and/or a mixture of separate components) for producing the finished product comprises the at least one compound conveying a sweet taste or the at least one compound conveying a sour taste. Thus, only the finished product but not the aroma composition for producing the finished product comprises both, the at least one compound conveying a sour taste and the at least one compound conveying a sweet taste. In this case, the desired effect caused by the aroma composition according to the invention is obtained during/after the production of the finished product.


What was said with regard to the semi-finished product above, applies accordingly, in case, a semi-finished product is used to produce the finished product.


Preferably, a finished product may be selected from the group consisting of (reduced-calorie) baked goods (e.g. bread, dry biscuits, cakes, other baked articles), confectionery (e.g. muesli bar products, chocolates, chocolate bars, other products in bar form, fruit gums, dragees, hard and soft caramels, chewing gum), non-alcoholic drinks (e.g. cocoa, coffee, green tea, black tea, (green, black) tea drinks enriched with (green, black) tea extracts, rooibos tea, other herbal teas, fruit-containing soft drinks, isotonic drinks, refreshing drinks, nectars, fruit and vegetable juices, fruit or vegetable juice preparations), instant drinks (e.g. instant cocoa drinks, instant tea drinks, instant coffee drinks), meat products (e.g. ham, fresh sausage or raw sausage preparations, spiced or marinated fresh or salt meat products), eggs or egg products (dried egg, egg white, egg yolk), cereal products (e.g. breakfast cereals, muesli bars, precooked ready-to-eat rice products), dairy products (e.g. full-fat or reduced-fat or fat-free milk drinks, rice pudding, yoghurt, kefir, cream cheese, soft cheese, hard cheese, dried milk powder, whey, butter, buttermilk, ice-cream, partially or completely hydrolysed milk-protein-containing products), products made from soy protein or other soybean fractions (e.g. soy milk and products produced therefrom, drinks containing isolated or enzymatically treated soy protein, drinks containing soy flour, preparations containing soy lecithin, fermented products such as tofu or tempeh or products produced therefrom and mixtures with fruit preparations and optionally flavours), dairy-like preparations (milk-type, yoghurt-type, dessert-type, ice cream) from protein rich plant materials (e.g. from seed materials of oat, almond, pea, lupine, lentils, faba beans, chickpea, rice, canola), plant protein-enriched non-dairy drinks, fruit preparations (e.g. jams, sorbets, fruit sauces, fruit fillings), vegetable preparations (e.g. ketchup, sauces, dried vegetables, frozen vegetables, precooked vegetables, boiled-down vegetables), snacks (e.g. baked or fried potato crisps or potato dough products, maize- or groundnut-based extrudates), fat- and oil-based products or emulsions thereof (e.g. mayonnaise, remoulade, dressings, in each case full-fat or reduced-fat), other ready-made dishes and soups (e.g. dried soups, instant soups, precooked soups), spices, spice mixtures and in particular seasonings which are used, for example, in the snacks field, sweetener preparations, tablets or sachets, other preparations for sweetening or whitening drinks.


Furthermore, the invention also relates to the use of at least one taste modifier selected from the group consisting of naringenin, phloretin, hesperetin, hesperetin dihydrochalcone, phyllodulcin, trilobatin, hydrangenol, hesperetin dihydrochalcone 4-O-glucoside, and salts thereof for improving the sweet/sour balance and/or reducing the sweet/sour imbalance and/or improving the mouthfeel in a preparation, preferably, wherein the preparation comprises at least one compound conveying a sour taste and at least one compound conveying a sweet taste.


What was said with regard to the aroma composition according to the invention, a semi-finished product according to the invention and the finished product according to the invention applies accordingly, particularly in case the preparation is a semi-finished or a finished product.


Preferably in the use according to the invention, the preparation is selected from the group consisting of preparations intended for nutrition, enjoyment or cosmetic or pharmaceutical purposes, preferably aroma compositions, semi-finished products and finished products as respectively defined above.


Further, the present invention is related to a method for improving the sweet/sour balance and/or reducing the sweet/sour imbalance and/or improving the mouthfeel in a preparation, comprising or consisting of the steps:

    • i) providing a preparation, the sweet/sour balance and/or the mouthfeel of which should be improved and/or the sweet/sour imbalance of which should be reduced, preferably wherein the preparation is selected from the group consisting of preparations intended for nutrition, enjoyment or cosmetic or pharmaceutical purposes,
    • ii) providing an aroma composition according to the invention,
    • iii) mixing the preparation provided in step i) with the aroma composition provided in step ii),
    • iv) optionally, further processing of the mixture obtained in step iii),
    • v) obtaining a composition with an improved sweet/sour balance and/or a reduced sweet/sour imbalance and/or an improved mouthfeel.


What was said with regard to the aroma composition according to the invention, a semi-finished product according to the invention and the finished product according to the invention applies accordingly, particularly in case the preparation is a semi-finished or a finished product. Furthermore, what was said with regard to the preparation above, applies accordingly.


Thus, and for the reasons outlined above, it is preferred in the method according to the invention that the preparation comprises at least one compound conveying a sour taste, preferably one or more food acids, preferably selected from the group consisting of acetic acid, adipic acid, aspartic acid, benzoic acid, sorbic acid, caffeotannic acid, citric acid, iso-citric acid, fumaric acid, galacturonic acid, gluconic acid, glucuronic acid, glyceric acid, glycolic acid, ketoglutaric acid, [alpha]-ketoglutaric acid, lactic acid, lactoisocitric acid, malic acid, maleic acid, oxalacetic acid, oxalic acid, phosphoric acid, pyruvic acid, quinic acid, shikimic acid, succinic acid, tannic acid, and tartaric acid, in particular preferred one or more food acids selected from adipic acid, citric acid, fumaric acid, gluconic acid, glucuronic acid, lactic acid, malic acid, phosphoric acid, succinic acid, and tartaric acid.


Also for the reasons outlined above, it is preferred in the method according to the invention that the preparation comprises at least one compound conveying a sweet taste, preferably selected from the group consisting of

    • natural sweeteners, preferably naturally occurring sweet tasting substances, including plant extracts, such as proteins (such as miraculin, pentaidin, monellin, thaumatin, curculin, brazzein, mabinlin), D-amino acids (such as D-phenylalanine, D-tryptophan) or extracts or fractions obtained from natural sources containing these amino acids and/or proteins and the physiologically acceptable salts of these amino acids and/or proteins, particularly the sodium, potassium, calcium or ammonium salts thereof; neohesperidindihydrochalkone, naringindihydrochalkone, steviolgylcoside, stevioside, steviolbioside, rebaudioside, rebaudioside A, rebaudioside B, rebaudioside C, rebaudioside D, rebaudioside E, rebaudioside F, rebaudioside G, rebaudioside H, rebaudioside M, rebaudioside N, rebaudioside X, dulcoside, Rubusoside, suavioside A, suavioside B, suavioside G, suavioside H, suavioside I, suavioside J, baiyunoside 1, baiyunoside 2, phlomisoside 1, phlomisoside 2, phlomisoside 3, phlomisoside 4, abrusoside A, abrusoside B, abrusoside C, abrusoside D, cyclocaryoside A, cyclocaryoside I, oslandin, polypodoside A, strogin 1, strogin, 2, strogin 4, selligueanin A, dihydroquercetin-3-acetate, perillartin, telosmosid A15, periandrin I-V, pterocaryoside, cyclocaryoside, mukurozioside, trans-Anethol, trans-cinnamaldehyd, bryoside, bryonoside, bryonodulcoside, carnosifloside, scandenoside, gypenoside, hematoxylin, cyanin, chlorogenic acid, albiziasaponin, telosmoside, gaudichaudiosid, mogrosides, such as mogroside V, hernandulcine, monatin, glycyrrhetinic acid and its derivatives, particularly glycyrrhizin, preferably glycyrrhizin ammonium salt; extracts or enriched fractions of such extracts such as extracts of Thaumatococcus or Stevia ssp., particularly Stevia rebaudiana, swingle extracts, particularly momordica or Siratio grosvenorii or Luo-Han-Guo, extracts of Glycerrhyzia ssp., particularly Glycerrhyzia glabra, extracts of Rubus ssp., particularly Rubus suavissimus, extracts of Lippia dulcis, extracts of Mycetia balansae, preferably comprising balansin A and/or balansin B, or further extracts as described in EP 11168468;
    • synthetic sweeteners, preferably synthetic sweet tasting substances, preferably selected from the group consisting of magap, sodium cyclamate or other physiologically acceptable salts of cyclamic acid, acesulfam K; neohesperidindihydrochalcone, naringindihydrochalcone, saccharin, saccharin sodium salt, aspartam, superaspartam, neotam, alitam, advantam, perillartin, sucralose, lugduname, carrelame, sucrononate or sucrooctate;
    • sweet tasting carbohydrates, preferably selected from the group consisting of sucrose, trehalose, lactose, maltose, melizitose, melibiose, raffinose, palatinose, lactulose, D-fructose, D-glucose, D-galactose, I-rhamnose, D-sorbose, D-mannose, D-tagatose, D-allulose, D-arabinose, I-arabinose, D-ribose, D-glyceraldehyde, maltodextrin, and vegetable preparations comprising one or more of these carbohydrates, preferably in an amount of at least 5 wt.-%, preferably at least 15 wt.-%, wherein in these preparations the carbohydrates can be present as naturally occurring or synthetic carbohydrates or a mixture thereof, such as preferably honey, invert sugar syrup or highly enriched fructose syrup from maize starch, and/or the physiologically acceptable salts of these carbohydrates, particularly sodium, potassium, calcium or ammonium salts thereof;
    • sugar alcohols, preferably naturally occurring sugar alcohols, preferably selected from the group consisting of glycerin, erythritol, threitol, arabitol, ribitol, xylitol, sorbitol, mannitol, maltitol, isomaltit, dulcitol, lactitol and the physiologically acceptable salts thereof, particularly the sodium, potassium, calcium or ammonium salts thereof.





DESCRIPTION OF THE FIGURES


FIG. 1 shows the results of the sensory evaluation according to Example 1, revealing that that the acidic taste impression was reduced by adding an aroma composition according to the invention (dashed or dotted lines, samples 2 to 7) compared to the control (sample 1), but provides less sweetness impression than the sample with full sugar content (continuous line, sample 8).



FIG. 2 shows the results of the sensory evaluation according to Example 2 (ice tea), revealing that the aroma compositions according to the invention (samples 2 to 5) provide a lower acidic taste impression and simultaneously an improved or at least similar evaluation of the further taste impressions than the control (sample 1).



FIG. 3 shows the results of the sensory evaluation according to Example 2 (lemon/lime base), revealing that the aroma compositions according to the invention (samples 2 to 5) provide a lower acidic taste impression and simultaneously an improved or at least similar evaluation of the further taste impressions than the control (sample 1).



FIG. 4 shows the results of the sensory evaluation according to Example 3 (ice tea), revealing that the aroma compositions according to the invention (samples 2 to 5) provide a lower acidic taste impression and simultaneously an improved or at least similar evaluation of the further taste impressions than the control (sample 1).



FIG. 5 shows the results of the sensory evaluation according to Example 3 (lemon/lime base), revealing that the aroma compositions according to the invention (samples 2 to 5) provide a lower acidic taste impression and simultaneously an improved or at least similar evaluation of the further taste impressions than the control (sample 1).



FIG. 6 shows the results of the sensory evaluation according to Example 3 (orange flavoured base), revealing that the aroma compositions according to the invention (samples 2 to 5) provide a lower acidic taste impression and simultaneously an improved or at least similar evaluation of the further taste impressions than the control (sample 1).



FIGS. 7 to 10 show the results of the sensory evaluation according to Example 4, revealing that the aroma composition according to the invention (dashed line, sample 2) provided a significantly lower acidity independent of the amount of acid and simultaneously an improved or at least similar evaluation in the further taste impressions compared to the control (continuous line, sample 1).





Further features and advantages of the invention result from the subsequent description of preferred application examples.


EXAMPLES
Example 1: Reduction of Acidity and Limited Effect on Sweetness

The acidic taste impression as well as the sweet taste impression were evaluated in an ice tea preparation. Provided was the ice tea preparation (sugar-reduced) (A1) as well as such ice tea preparations (sugar-reduced) including aroma compositions according to the invention. Further, as a comparison, the ice tea preparation with the regular sugar content (A2) was provided. The sugar-reduced preparation (A1) had 5° Bx, the preparation with the regular sugar content (A2) had 6.5° Bx. Thus, the increased sugar content in A2 corresponds to 1.5% sucrose equivalents, i.e. the threshold for human perception as described above.


Samples of 300 ml of each preparation were evaluated by panellists with regard to the acidic and the sweet taste impressions. Furthermore, the impressions mouthfeel and aftertaste, as generally important impressions of a consumer, were evaluated.


The number of panellists was N=7.


The results are listed in the following table and are plotted in FIG. 1.


















Sweetness
Sweetness





Sample
impact
intensity
Mouthfeel
Acidity
Aftertaste





















1
Reduced Base (A1) Ice Tea Peach
3
4
3.5
4
2.5


2
A1 + 20 ppm hesperetin
4
4.5
4
3.75
3


3
A1 + 30 ppm phloretin
4
4.5
4.5
3.5
3


4
A1 + 30 ppm phloretin + 7 ppm hesperetin
5
5
5
3
2.5


5
A1 + 30 ppm phloretin + 20 ppm hesperetin dihydrochalcone
4.5
4.5
4.5
3.5
3


6
A1 + 20 ppm phloretin + 3 ppm phyllodulcin + 40 ppm naringenin
4.5
4.5
4.5
3.5
3.25


7
A1 + 5 ppm hesperetin + 40 ppm naringenin + 40 ppm trilobatin
4.5
4.5
4.75
3
3


8
Full Sugar (A2) Ice Tea Peach
6
6
5.5
2.75
2









The results show that the acidic taste impression was reduced by adding an aroma composition according to the invention. Also, A2 reduced the acidic taste impression. However, in A2 the impact and intensity of sweetness is perceived as very high compared to A1. Thus, the reduction and/or masking effect on the acidic taste impression is achieved by a high sweetness impression in A2.


The impact and intensity of sweetness in the aroma compositions according to the invention is clearly below the evaluations of A2. Consequently, the aroma compositions according to the invention provide a sweetness impression of less than 1.5% sucrose equivalents (as in A2).


Furthermore, the aroma compositions according to the invention provide a better aftertaste and mouthfeel as the sugar-reduced preparation (A1).


Example 2: Reduction of Acidity and Positive Effect on Further Taste Impressions

The acidic taste impression as well as further taste impressions were evaluated in beverage preparations. Provided were the respective beverage preparation (ice tea peach (A3); lemon/lime flavoured beverage (A4)) as well as such preparations including aroma compositions according to the invention with one taste modifier according to formula (I).


Samples of 300 ml of each preparation were evaluated by panellists with regard to the acidic and further taste impressions, which are important to consumers.


The number of panellists was N=8.


The results are listed in the following tables and are plotted in FIGS. 2 and 3.





















Sample
Fruity
Juicy
Peach
Authenticity
Liking
Complexity
Balanced
Richness
Acidity

























1
Ice Tea Peach (A3)
5
4
6
5
4
3.5
3.5
3.5
6


2
A3 + 40 ppm trilobatin
5.25
4.5
6
5
4.5
4
4.5
4
5.5


3
A3 + 7 ppm hesperetin
5.5
4.5
6.5
5.5
4.75
4.25
4.5
4.5
5.5


4
A3 + 30 ppm phloretin
5.75
5.25
6.25
5.25
5.25
5
5
5
5


5
A3 + 40 ppm naringenin
5.5
5.25
6.25
5.5
5.25
5.25
5.5
5.5
5




























Sample
Lemon/lime
Floral
Peely
Authenticity
Liking
Complexity
Balanced
Richness
Acidity

























1
Lemon/lime base (A4)
5.5
4
4.25
4.5
3
4
3
3.5
5


2
A4 + 30 ppm phloretin
6
4
4.25
5
3.5
4.5
4
4.25
4


3
A4 + 40 ppm naringenin
6
4
4.5
4.5
3.5
4.5
3.75
4
4.5


4
A4 + 7 ppm hesperetin
5.25
3.75
4.5
4.5
3.5
4.5
4
4
4.5


5
A4 + 40 ppm trilobatin
5.5
4
4.25
4.5
2.75
4
3.5
3.5
4.5









The results show that all aroma compositions according to the invention provided a lower acidity and simultaneously an improved or at least similar evaluation in the further taste impressions.


Example 3: Reduction of Acidity and Positive Effect on Further Taste Impressions

The acidic taste impression as well as further taste impressions were evaluated in beverage preparations. Provided were the respective beverage preparation (ice tea peach (A5); lemon/lime flavoured beverage (A6); orange flavoured beverage (A7)) as well as such preparations including aroma compositions according to the invention with a combination of taste modifiers according to formula (I).


Samples of 300 ml of each preparation were evaluated by panellists with regard to the acidic and further taste impressions, which are important to consumers.


The number of panellists was N=7 (with regard to A5 and A7) and N=5 (with regard to A6). The results are listed in the following tables and are plotted in FIGS. 4, 5 and 6.





















Sample
Fruity
Juicy
Peach
Authenticity
Liking
Complexity
Balanced
Richness
Acidity

























1
Ice Tea Peach (A5)
5
4
6
5
4
3.5
3.5
3.5
6


2
A5 + 30 ppm phloretin
6
5.5
6.5
6
5
5.5
5
6
4



+ 7 ppm hesperetin


3
A5 + 30 ppm phloretin +
5
5
6
5
4.75
5
4.5
5
4.25



20 ppm hesperetin



dihydrochalcone


4
A5 + 20 ppm phloretin +
6
5.25
6
5.5
5
5.5
5
5.5
4



3 ppm phyllodulcin +



40 ppm naringenin


5
A5 + 5 ppm hesperetin +
5
5
6
5.5
4.5
5
4.5
5
4.5



40 ppm naringenin +



40 ppm trilobatin




























Sample
Lemon/lime
Floral
Peely
Authenticity
Liking
Complexity
Balanced
Richness
Acidity

























1
Lemon/lime base (A6)
5.5
4
4.25
4.5
3
4
3
3.5
5


2
A6 + 30 ppm phloretin +
5.5
5
4.75
5
4
5
5.5
5.5
3.5



7 ppm hesperetin


3
A6 + 30 ppm phloretin +
6
5
5
4.75
4
5
5
5.5
3.25



20 ppm hesperetin



dihydrochalcone


4
A6 + 20 ppm phloretin +
6
4.5
5
5
4
4.75
4.25
4.5
4



3 ppm phyllodulcin +



40 ppm naringenin


5
A6 + 5 ppm hesperetin +
6.25
4.75
5
5
4
5
4.5
5
3.75



40 ppm naringenin +



40 ppm trilobatin




























Sample
Orange
Juicy
Peely
Authenticity
Liking
Complexity
Balanced
Richness
Acidity

























1
Orange flavoured base (A7)
6
4.25
4.5
4
3.5
4
3.5
3.5
5.5


2
A7 + 30 ppm phloretin +
6.5
5.75
5
5.25
4.75
5.25
5
5.5
4.5



7 ppm hesperetin


3
A7 + 30 ppm phloretin +
6.5
4.5
5
5
4.5
5.25
4.5
4.5
5



20 ppm hesperetin



dihydrochalcone


4
A7 + 20 ppm phloretin +
6.5
5
5
5.5
5
5.5
5
5
4.5



3 ppm phyllodulcin +



40 ppm naringenin


5
A7 + 5 ppm hesperetin +
6
5
4.25
4.5
4
5
5
5.25
4.5



40 ppm naringenin +



40 ppm trilobatin









The results show that all aroma compositions according to the invention provided a significantly lower acidity and simultaneously an improved or at least similar evaluation in the further taste impressions.


Example 4: Reduction of Acidity Independent of the Amount of Acid

The acidic taste impression and further taste impressions were evaluated in beverage preparations. Provided were the respective beverage preparation (lemon-lime base (A8)) with increasing amounts of citric acid as well as such preparations including an aroma composition according to the invention.


Samples of 300 ml of each preparation were evaluated by panellists with regard to the acidic and the further taste impressions, which are important to consumers.


The number of panellists was N=6.


The results are listed in the following tables and are plotted in FIGS. 7 to 10.

















Sample
Acidity
Richness
Balanced
Complexity
Liking





















1
Lemon-lime base (A8.1) + 0.1% Citric acid
3
2.5
3
3.5
2


2
A8.1 + 30 ppm phloretin + 7 ppm hesperetin
2
4
4
4.5
3.5


3
Lemon-lime base (A8.2) + 0.2% Citric acid
5
3.5
3
3.5
2.5


4
A8.2 + 30 ppm phloretin + 7 ppm hesperetin
3.75
4.25
4
4.5
3.5


5
Lemon-lime base (A8.3) + 0.3% Citric acid
7.5
3.25
2
2.5
1.75


6
A8.3 + 30 ppm phloretin + 7 ppm hesperetin
6.25
4.5
3.5
4
3


7
Lemon-lime base (A8.4) + 0.4% Citric acid
9
3.5
1.5
3
1


8
A8.4 + 30 ppm phloretin + 7 ppm hesperetin
7.5
4
3.5
3.25
2









The results show that the aroma composition according to the invention provided a significantly lower acidity independent of the amount of acid and simultaneously an improved or at least similar evaluation in the further taste impressions.

Claims
  • 1-15. (canceled)
  • 16. An aroma composition comprising one or more taste modifiers of Formula (I), or salts thereof:
  • 17. The aroma composition of claim 16, wherein R3 and R4 are H or R3 is —OH R4 is —CH3, andR5 is H, —OH, or —O-glucopyranoside.
  • 18. The aroma composition of claim 16, wherein the one or more taste modifiers of Formula (I) are selected from naringenin, phloretin, hesperetin, hesperetin dihydrochalcone, phyllodulcin, trilobatin, hydrangenol, hesperetin dihydrochalcone 4-O-glucoside, or a salt thereof.
  • 19. The aroma composition of claim 18, wherein the aroma composition comprises phloretin and one or more additional taste modifiers of Formula (I) selected from naringenin, hesperetin, hesperetin dihydrochalcone, phyllodulcin, trilobatin, hydrangenol, hesperetin dihydrochalcone 4-O-glucoside, or salts thereof.
  • 20. The aroma composition of claim 18, wherein the aroma composition comprises at least two taste modifiers of Formula (I), or salts thereof, wherein the at least two taste modifiers are selected from: phloretin and hesperetin,phloretin and hesperetin dihydrochalcone,hesperetin and hesperetin dihydrochalcone,phloretin and naringenin,naringenin and hesperetin,phloretin and phyllodulcin,hesperetin and phyllodulcin,hesperetin dihydrochalcone and naringenin, orhesperetin dihydrochalcone and phyllodulcin.
  • 21. The aroma composition of claim 18, wherein the aroma composition comprises at least three taste modifiers of Formula (I), or salts thereof, wherein the at least three taste modifiers are selected from: phloretin, hesperetin, and naringenin,phloretin, hesperetin, and hesperetin dihydrochalcone,phloretin, naringenin, and hesperetin dihydrochalcone,phloretin, phyllodulcin, and hesperetin dihydrochalcone,hesperetin, phyllodulcin, and hesperetin dihydrochalcone,phloretin, hesperetin, and phyllodulcin,phloretin, naringenin, and phyllodulcin,hesperetin, naringenin, and phyllodulcin,phloretin, hesperetin, and trilobatin,phloretin, naringenin, and trilobatin, andhesperetin, naringenin, and trilobatin.
  • 22. The aroma composition of claim 16, wherein the one or more taste modifiers are present in a total amount of 0.5 to 100 ppm.
  • 23. The aroma composition of claim 16, wherein the one or more taste modifiers are present in a total amount of 1 to 80 ppm.
  • 24. The aroma composition of claim 16, wherein the one or more taste modifiers are present in a total amount of 1.5 to 60 ppm.
  • 25. The aroma composition of claim 16, further comprising one or more compounds conveying a sour taste, one or more compounds conveying a sweet taste, or a combination thereof, wherein the one or more taste modifiers of Formula (I) are in an amount sufficient to improve the sweet and sour balance, reduce the sweet and sour imbalance, improve mouthfeel, or a combination thereof.
  • 26. The aroma composition of claim 25, wherein the one or more compounds conveying a sour taste are selected from acetic acid, adipic acid, aspartic acid, benzoic acid, sorbic acid, caffeotannic acid, citric acid, iso-citric acid, fumaric acid, galacturonic acid, gluconic acid, glucuronic acid, glyceric acid, glycolic acid, ketoglutaric acid, [alpha]-ketoglutaric acid, lactic acid, lactoisocitric acid, malic acid, maleic acid, oxalacetic acid, oxalic acid, phosphoric acid, pyruvic acid, quinic acid, shikimic acid, succinic acid, tannic acid, and tartaric acid; andthe one or more compounds conveying a sweet taste are selected from natural sweeteners, synthetic sweeteners, sweet tasting carbohydrates, sugar alcohols.
  • 27. A semi-finished product for nutrition, enjoyment, cosmetic, or pharmaceutical purposes comprising the aroma composition of claim 16.
  • 28. A semi-finished product of claim 27, further comprising one or more compounds conveying a sour taste, one or more compounds conveying a sweet taste, or a combination thereof, wherein the one or more taste modifiers of Formula (I) are in an amount sufficient to improve the sweet and sour balance of the semi-finished product, reduce the sweet and sour imbalance of the semi-finished product, improve mouthfeel of the semi-finished product, or a combination thereof.
  • 29. The semi-finished product of claim 28, wherein the one or more compounds conveying a sour taste are selected from acetic acid, adipic acid, aspartic acid, benzoic acid, sorbic acid, caffeotannic acid, citric acid, iso-citric acid, fumaric acid, galacturonic acid, gluconic acid, glucuronic acid, glyceric acid, glycolic acid, ketoglutaric acid, [alpha]-ketoglutaric acid, lactic acid, lactoisocitric acid, malic acid, maleic acid, oxalacetic acid, oxalic acid, phosphoric acid, pyruvic acid, quinic acid, shikimic acid, succinic acid, tannic acid, and tartaric acid; andthe one or more compounds conveying a sweet taste are selected from natural sweeteners, synthetic sweeteners, sweet tasting carbohydrates, sugar alcohols.
  • 30. A finished product for nutrition, enjoyment, cosmetic, or pharmaceutical purposes comprising the aroma composition of claim 16.
  • 31. The finished product of claim 30, wherein the one or more taste modifiers of Formula (I) are in an amount sufficient to improve the sweet and sour balance of the finished product, reduce the sweet and sour imbalance of the finished product, improve mouthfeel of the finished product, or a combination thereof, wherein the one or more compounds conveying a sour taste are selected from acetic acid, adipic acid, aspartic acid, benzoic acid, sorbic acid, caffeotannic acid, citric acid, iso-citric acid, fumaric acid, galacturonic acid, gluconic acid, glucuronic acid, glyceric acid, glycolic acid, ketoglutaric acid, [alpha]-ketoglutaric acid, lactic acid, lactoisocitric acid, malic acid, maleic acid, oxalacetic acid, oxalic acid, phosphoric acid, pyruvic acid, quinic acid, shikimic acid, succinic acid, tannic acid, and tartaric acid; andthe one or more compounds conveying a sweet taste are selected from natural sweeteners, synthetic sweeteners, sweet tasting carbohydrates, sugar alcohols.
  • 32. A method for improving sweet and sour balance of a preparation, reducing sweet and sour imbalance of a preparation, improving mouthfeel of a preparation, or a combination thereof, comprising: (i) providing a preparation in need of improved sweet and sour balance, reduced sweet and sour imbalance, improved mouthfeel, or a combination thereof;(ii) providing an aroma composition of claim 16;(iii) mixing the preparation of (i) with the aroma composition of (ii):(iv) optionally, further processing of the mixture obtained in (iii); and(v) obtaining a composition with an improved sweet and sour balance, reduced sweet and sour imbalance, improved mouthfeel, or a combination thereof.
  • 33. The method of claim 32, wherein the preparation comprises one or more compounds conveying a sour taste selected from acetic acid, adipic acid, aspartic acid, benzoic acid, sorbic acid, caffeotannic acid, citric acid, iso-citric acid, fumaric acid, galacturonic acid, gluconic acid, glucuronic acid, glyceric acid, glycolic acid, ketoglutaric acid, [alpha]-ketoglutaric acid, lactic acid, lactoisocitric acid, malic acid, maleic acid, oxalacetic acid, oxalic acid, phosphoric acid, pyruvic acid, quinic acid, shikimic acid, succinic acid, tannic acid, or tartaric acid.
  • 34. The method of claim 32, wherein the preparation comprises one or more compounds conveying a sweet taste selected from natural sweeteners, synthetic sweeteners, sweet tasting carbohydrates, or sugar alcohols.
PCT Information
Filing Document Filing Date Country Kind
PCT/EP2021/050223 1/8/2021 WO