Claims
- 1. In a method for the trimerization of an aromatic polyisocyanate to a polyisocyanurate polymer in the presence of a trimerization catalyst the improvement which comprises employing as said catalyst a composition comprising a solution of the product obtained by reacting, in an inert solvent, substantially equimolar proportions of ketene-aminal and an olefin having the respective formulae (I) and (II) ##STR4## wherein R.sub.1, R.sub.2, R.sub.3, and R.sub.4 when taken separately are independently selected from the group consisting of lower-alkyl, aralkyl, cycloalkyl, and, when taken together as R.sub.1 with R.sub.2 and R.sub.3 with R.sub.4 with the respective nitrogen atoms to which they are attached represent independently heterocyclic groups having 6 or 7 ring atoms, R.sub.5 and R.sub.6 are independently selected from the group consisting of hydrogen, lower-alkyl, aryl, aralkyl, and cycloalkyl, R.sub.7 and R.sub.8 when taken separately are independently selected from the group consisting of hydrogen, lower-alkyl, aryl, aralkyl, and cycloalkyl, provided that R.sub.7 and R.sub.8 are not both hydrogen at the same time, and, R.sub.7 and R.sub.8, when taken together with the carbon atom to which they are attached represent a cyclic hydrocarbon group having 5 or 6 carbon atoms in the ring, and R.sub.9 and R.sub.10 represent the same or different electron withdrawing groups.
- 2. A method according to claim 1 wherein said ketene-aminal (I) R.sub.5 and R.sub.6 are hydrogen and lower-alkyl respectively.
- 3. A method according to claim 1 wherein in said olefin (II) R.sub.7 and R.sub.8 are hydrogen and aryl respectively and R.sub.9 and R.sub.10 are both the same electron withdrawing group.
- 4. A method according to claim 1 wherein said aromatic polyisocyanate is a liquefied methylenebis(phenyl isocyanate).
- 5. A method according to claim 4 wherein said catalyst composition comprises a solution of the product obtained by reacting 1,1-bis(N-morpholinyl)-2-methylethylene with benzylidene malononitrile in an organic polyol.
- 6. A method according to claim 4 wherein said catalyst composition comprises a solution of the product obtained by reacting 1,1-bis(N-piperidinyl)-2-methylethylene with benzylidene malononitrile in an organic polyol.
- 7. A method according to claim 4 wherein said catalyst composition comprises a solution of the product obtained by reacting 1,1-bis(dibutylamino)-2-methylethylene with benzylidene malononitrile in acetonitrile.
- 8. A method according to claim 4 wherein said catalyst composition comprises a solution of the product obtained by reacting 1,1-bis(N-piperidinyl)-2-methylethylene with diethyl benzylidene malonate in an organic polyol.
- 9. A method according to claim 4 wherein said catalyst composition comprises a solution of the product obtained by reacting 1,1-bis(N-piperidinyl)-2-methylethylene with 1,1-bisacetyl-2-phenylethylene in an organic polyol.
- 10. A method according to claim 4 wherein additional organic polyol and a urethane catalyst are present so that the product is a molded polyisocyanurate polyurethane polymer.
Parent Case Info
This is a divisional, of Ser. No. 737,837 filed May 28, 1985, 4632989 which is a divisional application of Ser. No. 587,429 filed Mar. 8, 1984 now U.S. Pat. No. 4,536,490.
US Referenced Citations (4)
Non-Patent Literature Citations (1)
Entry |
Gompper et al., Angewandte Chemie, Int. Ed., 6, 453 (1967). |
Divisions (2)
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Number |
Date |
Country |
Parent |
737837 |
May 1985 |
|
Parent |
587429 |
Mar 1984 |
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