In a number of embodiments, devices, systems and methods hereof relate to organic light-emitting diode display devices and systems.
The following information is provided to assist the reader in understanding technologies disclosed below and the environment in which such technologies may typically be used. The terms used herein are not intended to be limited to any particular narrow interpretation unless clearly stated otherwise in this document. References set forth herein may facilitate understanding the technologies or the background thereof The disclosure of all references cited herein are incorporated by reference.
Opto-electronic devices that make use of organic materials are becoming increasingly desirable for a number of reasons. Many of the materials used to make such devices are relatively inexpensive, so organic opto-electronic devices have the potential for cost advantages over inorganic devices. In addition, the inherent properties of organic materials, such as their flexibility, may make them well suited for particular applications such as fabrication on a flexible substrate. Examples of organic opto-electronic devices include organic light emitting devices (OLEDs), organic phototransistors, organic photovoltaic cells, and organic photodetectors. For OLEDs, the organic materials may have performance advantages over conventional materials. For example, the wavelength at which an organic emissive layer emits light may generally be readily tuned with appropriate dopants.
OLEDs make use of thin organic films that emit light when voltage is applied across the device. OLEDs are becoming an increasingly interesting technology for use in applications such as flat panel displays, illumination, and backlighting. Several OLED materials and configurations are described in U.S. Pat. Nos. 5,844,363, 6,303,238, and 5,707,745, which are incorporated herein by reference in their entirety.
One application for phosphorescent emissive molecules is a full color display. Industry standards for such a display call for pixels adapted to emit particular colors, referred to as “saturated” colors. In particular, these standards call for saturated red, green, and blue pixels. Color may be measured using International Commission on Illumination (CIE) coordinates, which are well known to the art.
One example of a green emissive molecule is tris(2-phenylpyridine) iridium, denoted Ir(ppy)3, which has the following structure:
In this structure, we depict the dative bond from nitrogen to metal (here, Ir) as a straight line.
As used herein, the term “organic” includes polymeric materials as well as small molecule organic materials that may be used to fabricate organic opto-electronic devices. “Small molecule” refers to any organic material that is not a polymer, and “small molecules” may actually be quite large. Small molecules may include repeat units in some circumstances. For example, using a long chain alkyl group as a substituent does not remove a molecule from the “small molecule” class. Small molecules may also be incorporated into polymers, for example as a pendent group on a polymer backbone or as a part of the backbone. Small molecules may also serve as the core moiety of a dendrimer, which consists of a series of chemical shells built on the core moiety. The core moiety of a dendrimer may be a fluorescent or phosphorescent small molecule emitter. A dendrimer may be a “small molecule,” and it is believed that all dendrimers currently used in the field of OLEDs are small molecules.
As used herein, “top” means furthest away from the substrate, while “bottom” means closest to the substrate. Where a first layer is described as “disposed over” a second layer, the first layer is disposed further away from substrate. There may be other layers between the first and second layer, unless it is specified that the first layer is “in contact with” the second layer. For example, a cathode may be described as “disposed over” an anode, even though there are various organic layers in between.
As used herein, “solution processible” means capable of being dissolved, dispersed, or transported in and/or deposited from a liquid medium, either in solution or suspension form.
More details on OLEDs, and the definitions described above, can be found in U.S. Pat. No. 7,279,704, which is incorporated herein by reference in its entirety.
In active-matrix organic light-emitting diode (AMOLED) displays, an active matrix of OLED pixels is deposited or integrated onto a thin film transistor (TFT) array. Each of the driving TFTs of the array functions as a switch to control current flowing to the individual pixel associated the TFT. A shortcoming of AMOLED displays driven by, for example, polycrystalline silicon or poly-Si TFTs is that it is difficult to control low gray scales with high accuracy as a result of 1) the sub-threshold current having an exponential function, and 2) non-uniformity of the threshold voltage of the driving transistors. Higher resolution display devices require lower driving current for each subpixel. Since the sub-threshold current is an exponential function of the gate voltage controlled by display data, minor changes in threshold voltages of the transistors and/or non-uniformity of the transistor performance make significant changes in brightness in the low gray scales. In certain cases, the transistor's leakage current can supply a driving current to OLEDs, resulting in wrongly-addressed OLEDs (for example, wrong-gray-scale and partially-lit pixels).
In summary, in one aspect, a circuit for a pixel in a display device includes drive circuitry, an organic light emitting diode in electrical connection with the drive circuitry, and at least one resistive current path which is selected to be non-emissive in electrical connection with the drive circuitry and in parallel with the organic light emitting diode. The resistive current path may, for example, include a resistor, a transistor, or a resistive layer of the display device. In a number of embodiments, a ratio of luminous efficacy at higher brightness to luminous efficacy at lower brightness is greater than 1. The ratio of luminous efficacy at 1000 cd/m2 to luminous efficacy at 1 cd/m2 may, for example, be greater than 1, greater than 5 or greater than 8.
The resistive current path may, for example, include a two-terminal transistor. In a number of embodiments, the resistive current path includes a section of an intrinsic or doped polycrystalline silicon layer, a section of an amorphous silicon layer, a section of a oxide semiconductor layer or a section of an organic semiconductor layer. The resistive current path may also include a conductive layer defining a boundary of the pixel.
In another aspect, a display includes a plurality of pixel circuits. At least one of the pixel circuits includes drive circuitry, an organic light-emitting diode in electrical connection with the drive circuitry, and at least one resistive current path which is selected to be non-emissive in electrical connection with the drive circuitry and in parallel with the organic light emitting diode.
In a further aspect, a method of fabricating a pixel circuit for an organic light-emitting diode display includes providing an organic light emitting diode in electrical connection with drive circuitry, and providing at least one resistive current path which is selected to be non-emissive in electrical connection with the drive circuitry and in parallel with the organic light emitting diode.
In still a further aspect, a method of controlling activation of a pixel circuit for an organic light-emitting diode of an organic light-emitting diode display includes providing at least one resistive current path which is selected to be non-emissive in parallel with the organic light emitting diode.
The pixel circuits hereof may, for example, be used in an AMOLED display, and are particularly useful in higher resolution display devices. Fabrication costs may, for example, be lowered by a higher fabrication yield. Introduction of additional non-emissive current paths to a pixel circuit of an OLED, which causes a greater fraction of the pixel current to become non-emissive at low luminance levels as compared to higher luminance levels, may, for example, prevent the pixel from being lit when an off-state is required or provide more accurate control in the lower brightness region, while maintaining approximately the same efficacy as the conventional pixel structure in the higher brightness region. The methods and structures hereof may, for example, provide reliable OLED display devices and significantly improve manufacturing yield.
The foregoing is a summary and thus may contain simplifications, generalizations, and omissions of detail; consequently, those skilled in the art will appreciate that the summary is illustrative only and is not intended to be in any way limiting.
For a better understanding of the embodiments, together with other and further features and advantages thereof, reference is made to the following description, taken in conjunction with the accompanying drawings. The scope of the claimed invention will be pointed out in the appended claims.
Generally, an OLED comprises at least one organic layer disposed between and electrically connected to an anode and a cathode. When a current is applied, the anode injects holes and the cathode injects electrons into the organic layer(s). The injected holes and electrons each migrate toward the oppositely charged electrode. When an electron and hole localize on the same molecule, an “exciton,” which is a localized electron-hole pair having an excited energy state, is formed. Light is emitted when the exciton relaxes via a photoemissive mechanism. In some cases, the exciton may be localized on an excimer or an exciplex. Non-radiative mechanisms, such as thermal relaxation, may also occur, but are generally considered undesirable.
Early OLEDs used emissive molecules that emitted light from their singlet states (“fluorescence”) as disclosed, for example, in U.S. Pat. No. 4,769,292, which is incorporated by reference in its entirety. Fluorescent emission generally occurs in a time frame of less than 10 nanoseconds.
More recently, OLEDs having emissive materials that emit light from triplet states (“phosphorescence”) have been demonstrated. Baldo et al., “Highly Efficient Phosphorescent Emission from Organic Electroluminescent Devices,” Nature, vol. 395, 151-154, 1998; (“Baldo-I”) and Baldo et al., “Very high-efficiency green organic light-emitting devices based on electrophosphorescence,” Appl. Phys. Lett., vol. 75, No. 3, 4-6 (1999) (“Baldo-II”), which are incorporated by reference in their entireties. Phosphorescence is described in more detail in U.S. Pat. No. 7,279,704 at cols. 5-6, which are incorporated by reference.
More examples for each of these layers are available. For example, a flexible and transparent substrate-anode combination is disclosed in U.S. Pat. No. 5,844,363, which is incorporated by reference in its entirety. An example of a p-doped hole transport layer is m-MTDATA doped with F4-TCNQ at a molar ratio of 50:1, as disclosed in U.S. Patent Application Publication No. 2003/0230980, which is incorporated by reference in its entirety. Examples of emissive and host materials are disclosed in U.S. Pat. No. 6,303,238 to Thompson et al., which is incorporated by reference in its entirety. An example of an n-doped electron transport layer is BPhen doped with Li at a molar ratio of 1:1, as disclosed in U.S. Patent Application Publication No. 2003/0230980, which is incorporated by reference in its entirety. U.S. Pat. Nos. 5,703,436 and 5,707,745, which are incorporated by reference in their entireties, disclose examples of cathodes including compound cathodes having a thin layer of metal such as Mg:Ag with an overlying transparent, electrically-conductive, sputter-deposited ITO layer. The theory and use of blocking layers is described in more detail in U.S. Pat. No. 6,097,147 and U.S. Patent Application Publication No. 2003/0230980, which are incorporated by reference in their entireties. Examples of injection layers are provided in U.S. Patent Application Publication No. 2004/0174116, which is incorporated by reference in its entirety. A description of protective layers may be found in U.S. Patent Application Publication No. 2004/0174116, which is incorporated by reference in its entirety.
The simple layered structure illustrated in
Structures and materials not specifically described may also be used, such as OLEDs comprised of polymeric materials (PLEDs) such as disclosed in U.S. Pat. No. 5,247,190 to Friend et al., which is incorporated by reference in its entirety. By way of further example, OLEDs having a single organic layer may be used. OLEDs may be stacked, for example as described in U.S. Pat. No. 5,707,745 to Forrest et al, which is incorporated by reference in its entirety. The OLED structure may deviate from the simple layered structure illustrated in
Unless otherwise specified, any of the layers of the various embodiments may be deposited by any suitable method. For the organic layers, preferred methods include thermal evaporation, ink-jet, such as described in U.S. Pat. Nos. 6,013,982 and 6,087,196, which are incorporated by reference in their entireties, organic vapor phase deposition (OVPD), such as described in U.S. Pat. No. 6,337,102 to Forrest et al., which is incorporated by reference in its entirety, and deposition by organic vapor jet printing (OVJP), such as described in U.S. Pat. No. 7,431,968, which is incorporated by reference in its entirety. Other suitable deposition methods include spin coating and other solution based processes. Solution based processes are preferably carried out in nitrogen or an inert atmosphere. For the other layers, preferred methods include thermal evaporation. Preferred patterning methods include deposition through a mask, cold welding such as described in U.S. Pat. Nos. 6,294,398 and 6,468,819, which are incorporated by reference in their entireties, and patterning associated with some of the deposition methods such as ink-jet and OVJD. Other methods may also be used. The materials to be deposited may be modified to make them compatible with a particular deposition method. For example, substituents such as alkyl and aryl groups, branched or unbranched, and preferably containing at least 3 carbons, may be used in small molecules to enhance their ability to undergo solution processing. Substituents having 20 carbons or more may be used, and 3-20 carbons is a preferred range. Materials with asymmetric structures may have better solution processibility than those having symmetric structures, because asymmetric materials may have a lower tendency to recrystallize. Dendrimer substituents may be used to enhance the ability of small molecules to undergo solution processing.
OLED Devices may further optionally comprise a barrier layer. One purpose of the barrier layer is to protect the electrodes and organic layers from damaging exposure to harmful species in the environment including moisture, vapor and/or gases, etc. The barrier layer may be deposited over, under or next to a substrate, an electrode, or over any other parts of a device including an edge. The barrier layer may comprise a single layer, or multiple layers. The barrier layer may be formed by various known chemical vapor deposition techniques and may include compositions having a single phase as well as compositions having multiple phases. Any suitable material or combination of materials may be used for the barrier layer. The barrier layer may incorporate an inorganic or an organic compound or both. A barrier layer may, for example, comprise a mixture of a polymeric material and a non-polymeric material as described in U.S. Pat. No. 7,968,146, PCT Pat. Application Nos. PCT/US2007/023098 and PCT/US2009/042829, which are incorporated herein by reference in their entireties. To be considered a “mixture”, the aforesaid polymeric and non-polymeric materials comprising the barrier layer should be deposited under the same reaction conditions and/or at the same time. The weight ratio of polymeric to non-polymeric material may be in the range of 95:5 to 5:95. The polymeric material and the non-polymeric material may be created from the same precursor material. In one example, the mixture of a polymeric material and a non-polymeric material consists essentially of polymeric silicon and inorganic silicon.
Devices fabricated in accordance with embodiments hereof may be incorporated into a wide variety of consumer products, including flat panel displays, computer monitors, medical monitors, televisions, billboards, lights for interior or exterior illumination and/or signaling, heads up displays, fully transparent displays, flexible displays, laser printers, telephones, cell phones, personal digital assistants (PDAs), laptop computers, digital cameras, camcorders, viewfinders, micro-displays, vehicles, a large area wall, theater or stadium screen, or a sign. Various control mechanisms may be used to control devices fabricated in accordance with the methods hereof, including passive matrix and active matrix. Many of the devices are intended for use in a temperature range comfortable to humans, such as 18 degrees C. to 30 degrees C., and more preferably at room temperature (20-25 degrees C.).
The materials and structures described herein may have applications in devices other than OLEDs. For example, other optoelectronic devices such as organic solar cells and organic photodetectors may employ the materials and structures. More generally, organic devices, such as organic transistors, may employ the materials and structures.
The terms halo, halogen, alkyl, cycloalkyl, alkenyl, alkynyl, arylkyl, heterocyclic group, aryl, aromatic group, and heteroaryl are known to the art, and are defined in U.S. Pat. No. 7,279,704 at cols. 31-32, which are incorporated herein by reference.
It will be readily understood that the components of the embodiments, as generally described and illustrated in the figures herein, may be arranged and designed in a wide variety of different configurations in addition to the described example embodiments. Thus, the following more detailed description of the example embodiments, as represented in the figures, is not intended to limit the scope of the embodiments, as claimed, but is merely representative of example embodiments.
Reference throughout this specification to “one embodiment” or “an embodiment” (or the like) means that a particular feature, structure, or characteristic described in connection with the embodiment is included in at least one embodiment. Thus, the appearance of the phrases “in one embodiment” or “in an embodiment” or the like in various places throughout this specification are not necessarily all referring to the same embodiment.
Furthermore, the described features, structures, or characteristics may be combined in any suitable manner in one or more embodiments. In the following description, numerous specific details are provided to give a thorough understanding of embodiments. One skilled in the relevant art will recognize, however, that the various embodiments can be practiced without one or more of the specific details, or with other methods, components, materials, et cetera. In other instances, well known structures, materials, or operations are not shown or described in detail to avoid obfuscation.
As used herein and in the appended claims, the singular forms “a,” “an”, and “the” include plural references unless the context clearly dictates otherwise. Thus, for example, reference to “a resistor” or “a resistive path” includes a plurality of such resistors or resistive paths and equivalents thereof known to those skilled in the art, and so forth, and reference to “the resistor” or the “resistive path” is a reference to one or more such resistors or resistive paths and equivalents thereof known to those skilled in the art, and so forth.
As performances of OLED devices such as phosphorescent OLED devices or PHOLED devices (including, for example, the current efficacy) are improved, the driving currents required are reduced. In particular, the driving current level at low brightness decreases significantly for high-resolution displays. For example, to drive a PHOLED of 100 cd/A at 1 cd/m2 for a 300 dpi display, approximately 24 pA is needed. That order of current corresponds to a sub-threshold current of the driving transistors or the off-state current, depending on the dimensions or performances of the transistors. This low driving current causes technical difficulties in being accurately controlled in AMOLED displays, because 1) the sub-threshold current is an exponential function of the gate data voltage and 2) the threshold voltage of the driving transistors is not ideally uniform. Because of the former, highly-resolved data voltages are required to produce the correct linear gray scales. In reality, OLEDs may be lit much brighter than required for any specific video image. Similarly, the non-uniformity of the threshold voltage affects illumination of each pixel significantly. As set forth above, in certain circumstances, the highly efficient OLEDs can be lit partially in the off-state as a result of the comparable leakage current of the driving transistors. Therefore, lower luminous efficacy at lower brightness can be preferable to higher efficacy at lower brightness. Here, we define a ratio, which we refer to as the “RATIO” throughout the application, of efficacy at 1000 cd/m2 to that at 1 cd/m2 to quantify the characteristics. Most PHOLED devices have a RATIO close to unity as seen in
Thus, to increase the RATIO, in a number of embodiments hereof, a non-emissive current path was implemented parallel to the OLED at low brightness. OLEDs exhibit highly non-linear resistance, with OLED resistance at lower voltages being significantly greater than OLED resistance at higher voltages.
Estimates of the required resistance to drive subpixels in AMOLED displays can be made as a function of display resolution, Dots Per Inch (DPI). In a representative example, the resistance requirements based on an OLED with a current efficacy of 75 cd/A was calculated. The results are shown in
wherein I is the required resistive current per subpixel in amps (A), L is Lumiance in nits, candela/m2 or cd/m2, LE is Luminous Efficacy in candela/amp or cd/A, and resolution/DPI is provided in dots per inch.
wherein R is resistance of the parallel resistor in Ohm and VOLED is measured from an OLED J-V curve (see, for example,
The high resistive current path described herein may, for example, be achieved in a number of manners without adding significant complications to fabrication. For example, the required resistance may be achieved using a two-terminal transistor in parallel with an OLED as depicted in
In other embodiments, an intrinsic or lightly doped poly-Si layer may be used to provide a resistive pathway in parallel with the OLED. Typically, the poly-Si layer has a resistivity of about 104 Ωcm, depending on its material conditions. A typical thickness of 50 nm for a thin film transistor (TFT) provides a sheet resistance of 2 GΩ/sq (gigaohms per square). A desired resistance range may be attained by controlling the ratio of the width and length of the poly-Si film. An embodiment of pixel circuitry including the poly-Si layer as the resistor is illustrated in
Conductive grid 410 may, for example, be prepared by adding fine conductive powder into a polyimide grid precursor. The precursor may, for example, be coated over substrate 430 and processed by photolithography to form a grid to define pixels 440. The conductive powder may, for example, be composed of fine metal particles (for example, Al, Cu, Ag, and/or Zn) or some other conductive materials (for example, TiN, or semiconductor materials). In a number of embodiments, the size of the particles is chosen to be significantly less than the thickness of conductive grid 410 to avoid increasing the film roughness and, thereby, maintaining a high device yield. The conductivity of the material and concentration of the particles in conductive grid 410 may be varied to “tune” the resistance of conductive grid 410 and to affect the RATIO.
This disclosure has been presented for purposes of illustration and description but is not intended to be exhaustive or limiting. Many modifications and variations will be apparent to those of ordinary skill in the art. The example embodiments were chosen and described in order to explain principles and practical application, and to enable others of ordinary skill in the art to understand the disclosure for various embodiments with various modifications as are suited to the particular use contemplated.
Thus, although illustrative example embodiments have been described herein with reference to the accompanying figures, it is to be understood that this description is not limiting and that various other changes and modifications may be affected therein by one skilled in the art without departing from the scope or spirit of the disclosure.
This application claims priority to U.S. Provisional Patent Application Nos. 61/552,765, filed on Oct. 28, 2011, and 61/555,736, filed on Nov. 4, 2011, the entireties of which are herein incorporated by reference. The claimed invention was made by, on behalf of, and/or in connection with one or more of the following parties to a joint university corporation research agreement: Regents of the University of Michigan, Princeton University, The University of Southern California, and the Universal Display Corporation. The agreement was in effect on and before the date the claimed invention was made, and the claimed invention was made as a result of activities undertaken within the scope of the agreement.
Number | Date | Country | |
---|---|---|---|
61552765 | Oct 2011 | US | |
61555736 | Nov 2011 | US |