Claims
- 1. An oligomerization process comprising contacting in a reaction zone under slurry polymerization reactor conditions:
- a) ethylene;
- b) a catalyst system comprising 2-pyridine carboxaldimine nickel dihalide complex represented by the formula ##STR2## wherein R can be the same or different and is selected from the group consisting of branched and/or linear alkyl or aromatic groups having from about 1 to about 70 carbon atoms per alkyl group and can be in any position on the aromatic ring:
- R' and R" on the aromatic and pyridine rings of the 2-pyridine carboxaldimine nickel dihalide complex can be the same or different, and are selected from the group consisting of hydrogen and branched or linear, aliphatic or aromatic groups having from about 1 to about 15 carbon atoms per alkyl group; and
- Z is a halogen selected from the group consisting of fluorine, chlorine, bromine, iodine, and mixtures thereof; and
- c) an organoalumium cocatalyst system;
- wherein an oligomer is recovered.
- 2. A process according to claim 1 further comprising a comonomer selected from the group of alpha-olefins having from 3 to 10 carbon atoms per molecule is present.
- 3. A process according to claim 2 wherein said comonomer is selected from the group consisting of propylene, 1-butene, 1-pentene, 1 -hexene, 1 -octene, 4-methyl-1-pentene, and mixtures thereof.
- 4. A process according to claim 1 wherein said R substituent group is selected from the group consisting of hydrogen and branched, linear, cyclic, aromatic or aliphatic radicals having from about 1 to about 20 carbon atoms per radical.
- 5. A process according to claim 4 wherein said R substituent is terminal or is linked to the pyridine group and is selected from the group consisting of hydrogen and branched, linear, cyclic, aromatic or aliphatic radicals having from about 1 to about 12 carbon atoms per radical.
- 6. A process according to claim 1 wherein said R' or R" substituent is selected from the group consisting of methyl, ethyl, propyl, isopropyl, butyl, isobutyl, tert-butyl, phenyl groups, fused phenyl groups (such that the pyridine group and the substituent taken together form a quinoline group), and mixtures of two or more thereof.
- 7. A process according to claim 6 wherein said R' or R" substituent is an electron-donating species, selected from the group consisting of linear or branched aliphatic or fused aromatic groups having from about 1 to about 15 carbon atoms per group.
- 8. A process according to claim 1 wherein said Z is selected from the group consisting of chlorine, bromine and mixtures thereof.
- 9. A process according to claim 1 wherein said 2-pyridine carboxaldimine nickel dihalide complexes and said organoaluminum cocatalyst system are present in the reactor in amounts to have an aluminum to nickel molar ratio of less than about 5000:1.
- 10. A process according to claim 9 where in said aluminum to nickel molar ratio is within a range of about 10:1 to about 4000:1.
- 11. A process according to claim 1 wherein said slurry polymerization reactor conditions comprise a temperature within a range of about 10.degree. to about 90.degree. C. and a pressure within a range of about 100 to about 1000 psia.
- 12. A process according to claim 1 wherein said slurry polymerization reactor conditions comprise a diluent of isobutane.
- 13. A process according to claim 1 wherein said organoaluminum cocatalyst is selected from the group consisting of methylaluminoxanes; supported, partially hydrated alkyl aluminum compounds and mixtures thereof.
- 14. A process according to claim 1 wherein said organoaluminum cocatalyst is a methylaluminoxane.
- 15. A process according to claim 1 wherein said organoaluminum cocatalyst is a supported, partially hydrated alkyl aluminum compound.
Parent Case Info
This application is a Division of application Ser. No. 09/050,725, filed Mar. 30, 1998, now U.S. Pat. No. 5,932,670.
US Referenced Citations (8)
Foreign Referenced Citations (1)
Number |
Date |
Country |
WO 9623010 |
Aug 1996 |
WOX |
Non-Patent Literature Citations (1)
Entry |
Crociani et al., Organometallics, vol. 16, pp. 384-391, 1997. |
Divisions (1)
|
Number |
Date |
Country |
Parent |
050725 |
Mar 1998 |
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