Patent Application
20220185930
The present invention relates to low temperature (<80° C.) moisture curable, “one package” pigmented coatings composition composed of
Said polymeric composition is particularly suitable for ambient cure coatings and adhesives applications.
The use of silane in coating formulations are well known and especially acrylic-silane coating compositions have an accepted cure rate and upon curing product films having good physical and chemical properties. However, one important disadvantage of these compositions is their short potlife. Since decades options to solve this main drawback has been addressed by the industry.
The U.S. Pat. No. 4,043,953 is about ambient temperature, moisture-curable coating compositions in which improved potlife is achieved by this invention comprise a blend of an acrylic-silane interpolymer derived from monomers which are devoid of active hydrogen atoms, a cure accelerating catalyst and a monomeric hydrolytically reactive organo-silicon compound represented by the structural formula: Xn Si(OR)4-n.
The EP0007765 stated the following comment on the above: while the method disclosed in U.S. Pat. No. 4,043,953 undoubtedly improves the stability of polymeric organosilanes, we have found that this method has certain limitations, especially when one desires to employ the polymeric organosilanes as adhesion promoter additives, rather than as coatings per se. For a number of reasons the viscosity stability requirements are somewhat more stringent when the polymeric organosilane is used as an adhesion promoter additive, rather than as a coating material. Therefore the EP 0007765 and EP 0050249 have found the presence of a low molecular weight alcohol and a monomeric hydrolytically reactive compound has a synergic effect on the stability of the acrylic-silane interpolymer.
The WO 0198419 two decades later is still looking to propose so called one-pack system by the physical separation of the catalyst, the catalyst is normally packaged separately from the (pigmented) polymer. The components are mixed together shortly before application of the coating. Fast drying storage stable one- pack systems are possible using “duplex” tins where the catalyst is stored separately from the paint in one can.
The WO 04067576 demonstrates that a stable coating formulation can be obtained when the acrylic polymer is substantially free of functional groups that can react with the polysiloxane or with the catalyst. The document is silent about the coating properties.
Accordingly, there is a need for compositions which have a reduced cure cycle and temperature while minimizing the effects of undesirable chemicals and in methods for applying such compositions. Most preferably, the industry is looking for systems able to cure at room temperature after application and yet being stable in the can before application.
Embodiments of the invention are directed to polymeric compositions and processes for applying polymeric composition.
In one aspect of the invention, a polymer composition is provided, the composition including an organosilane copolymer derived from at least Al and A2 monomers, wherein, the Al monomer comprises a vinyl ester monomer and the A2monomer comprises a vinyl silane monomer and a water scavenger(E) selected from the group consisting of a vinyl silane, an orthoester, a titanate, a zirconate, an oxazolidine, a sulfate, and combinations thereof. The composition may further include one or more materials selected from the group consisting of a solvent, a catalyst, a pigment, a filler, a paint additive, a C1 to C6 alcohol, a polysiloxane polymer, an adhesion promotor, and combinations thereof.
In another aspect of the invention, a method is provided for applying a composition including an organosilane copolymer derived from at least A1 and A2 monomers, wherein, the Al monomer comprises a vinyl ester monomer and the A2 monomer comprises a vinyl silane monomer and a water scavenger selected from the group consisting of a vinyl silane, an orthoester, a titanate, a zirconate, an oxazolidine, a sulfate, and combinations thereof. The composition may further be cured in the presence of moisture.
The present invention provides polymeric compositions that are useful in coating and other applications. The polymeric composition may include an organosilane copolymer and a water scavenger. The water scavenger may be selected from the group consisting of a vinyl silane, an orthoester, a titanate, a zirconate, an oxazolidine, a sulfate, and combinations thereof. The composition may further include one or more materials selected from the group consisting of a solvent, a catalyst, a pigment, a filler, a paint additive, a C1 to C6 alcohol, a polysiloxane polymer, an adhesion promotor, and combinations thereof.
The polymeric composition may be formulated to the desired viscosity that allows the application by standard coating technics, and the curing rate is optimized in the presence of an appropriated catalyst.
The polymeric composition may include an organosilane copolymer and a water scavenger. The organosilane copolymer may comprise from 5 wt. % to 80 wt. %, such as from 10 wt. % to 60 wt. %, for example, from 20 wt. % to 50 wt. % of the polymeric composition. The water scavenger may comprise from 0,05 wt. % to 10 wt. %, such as from 0.1 wt. % to 5 wt. %, for example, from 1 wt. % to 3 wt. % of the polymeric composition. The total weight percent of the components of the polymeric composition comprise 100 weight percent.
The polymeric composition comprises an organosilane copolymer. In one embodiment, the organosilane copolymer may be derived from at least A1 and A2 monomers, wherein, the A1 monomer comprises a vinyl ester monomer and the A2 monomer comprises a vinyl silane monomer. The co-polymer may also be derived from one or more optional monomers selected from the group consisting of a monomer comprising vinyl acetate (A3 monomer), a monomer comprising an acrylate ester, a metacrylate ester(A4 monomer), or a combination thereof, a monomer comprising an acrylosilane monomer, a methacrylo silane monomer or a combination thereof, (A5 monomer), a monomer comprising any other vinyl monomer than a vinyl ester or vinyl silane (A6 monomer), and combinations thereof.
The A1 monomer comprising a vinyl ester monomer may have the formula:
The vinyl ester monomer, Al monomer, may comprise from 15 wt. % to 95% wt. %, such as from 30 wt. % to 95 wt. %, from 50 wt. % to 90 wt. %, of the total weight percent (100 wt. %) of the monomers.
The vinyl silane monomer, A2 monomer, may comprises the formula:
wherein R4, R5, and R6 are alkyl groups having 1 to 4 carbon atoms. Suitable vinyl silanes and R4-R6 are methoxy or ethoxy. Suitable examples of these vinyl silane monomers include vinyl trimethoxy silane, vinyl triethoxy silane, methyl vinyl diethoxy silane, and combinations thereof. Commercial examples of the vinyl silane monomers include Silquest A171 and Silquest A151, and combinations thereof, are commercially available from Momentive Performance Materials Inc, from New York, USA (Country, or City and state if US).
The vinyl silane monomer, A2 monomer, may comprise from 1 wt. % to 35% wt. %, such as from 2 wt. % to 25 wt. %, for example, from 2 wt. % to 20 wt. %, of the total weight percent (100 wt. %) of the monomers.
The monomer comprising vinyl acetate, A3 monomer, may comprise from 0 wt. % to 75% wt. %, such as from 0 wt. % to 60 wt. %, from 20 wt. % to 50 wt. %, of the total weight percent (100 wt. %) of the monomers.
The monomer comprising an acrylate ester, a metacrylate ester, or a combination thereof, A4 monomer, may also be used for the copolymer. Suitable examples of the A4 monomer include methyl methacrylate, ethyl methacrylate, n-butyl methacrylate,iso-butyl methacrylate, ter-butyl methacrylate, isopropyl methacrylate, and isobornyl methacrylate, ethyl acrylate, butyl acrylate, and 2-ethyl hexyl acrylate and combinations thereof. The monomer comprising an acrylate ester, a metacrylate ester, or a combination thereof, A4 monomer, may comprise from 0 wt. % to 80% wt. %, such as from 0 wt. % to 40 wt. %, from 5 wt. % to 25 wt. %, of the total weight percent (100 wt. %) of the monomers.
The monomer comprising an acrylosilane or methacrylo silane, A5 monomer, may also be used for the copolymer. Suitable examples of the acrylosilane monomer include Methacryloxypropyl methyldimethoxysilane, methacryloxy trimethoxysilane and methacryloxy triethoxysilane and combinations thereof. Commercial examples of the acrylosilane monomer include Silquest A 174, Silquest* Y-11878 and combinations thereof, are commercially available from Momentive Performance Materials Inc, (Company name) from New York, USA (Country, or City and state if US)
The monomer comprising an acrylosilane, As monomer, may comprise from 0 wt. % to 25% wt. %, such as from 0 wt. % to 15 wt. %, from 5 wt. % to 10 wt. %, of the total weight percent (100 wt. %) of the monomers.
The monomer comprising any other vinyl monomer than a vinyl ester or vinyl silane, A6 monomer, may also be used for the copolymer. Suitable examples of the A6 monomer include N-vinyl pyrolidone, vinyl ethers, acrylic acid, methacrylic acid and combinations thereof.
The monomer comprising any other vinyl monomer than a vinyl ester or vinyl silane, A6 monomer, may comprise from 0 wt. % to 30% wt. %, such as from 0 wt. % to 10 wt. %, from 0 wt. % to 5 wt. %, of the total weight percent (100 wt. %) of the monomers.
In one embodiment of the invention, the copolymer derived from at least the A1 and A2 monomers comprises:
The copolymer may have a Number average molecular weight from 1,000 daltons to 40,000 daltons, such as from 2,000 daltons to 25,000 daltons, from 3,500 daltons to 12,000 daltons.
Suitable water scavenger may be selected from the group consisting of vinyl silanes, orthoesters, titanates, zirconates, oxazolidines, calcium sulfate, cacium oxide, isocyanates zeolite based molecular sieves and combinations thereof. Examples of water scavengers include vinyl trimethoxy silane, vinyl triethoxy silane, trimethyl orthoformate, triethyl orthoformate, triethyl orthoacetate, tetra n-Butyl titanate, di-isobutoxyl titanium chelate with Ethyl acetoacetate, and combinations thereof.
In one embodiment, polymeric composition includes a coating formulation comprising the copolymer based on the monomers described herein, a water scavenger described herein, a catalyst, an organic solvent, and optionally, one or more additives.
In one embodiment, the copolymer may comprise from 10 wt. % to 90 wt. %, such as from 5 wt. % to 80 wt. %, from 10 wt. % to 60 wt. %, of the total weight percent (100 wt. %) of the coating formulation.
In one embodiment, the water scavenger may comprise from 0.05 wt. % to 15 wt. %, such as from 0.1 wt. % to 10 wt. %, from 0.2 wt. % to 5 wt. %, of the total weight percent (100 wt. %) of the coating formulation.
The catalyst may be selected from the group of a strong acid, a lewis acid, a carboxylic acid, a base, like an amine, caustic or an alcolate and combinations thereof. An alternative catalyst is a nitrate of a polyvalent metal ion such as calcium nitrate, magnesium nitrate, aluminium nitrate, zinc nitrate, or strontium nitrate, Nitrates might also be conveniently combined with amines. Other catalysts include carbonates such as sodium or calcium carbonate. Commercial examples of catalysts include SiliXan Cat 240 (SiliXan GmbH), Nacure 4054, Nacure 5076, TYZOR TNBT, TYZOR 9000, K-Kat 670(King Industries), DBTDL (dibutyl tin dilaurate) (Sigma Aldrich),3-Aminopropyltrimethoxysilane (Sigma), 2-ethyl hexanoic acid, Versatic acid (Hexion) and combinations thereof. A preferred commercial catalyst for an one package system for coating formulation is DBTDL.
In one embodiment, the catalyst may comprise from 0.1 wt. % to 3 wt. %, such as from 0.2 wt. % to 2 wt. %, from 0.3 wt. % to 1 wt. %, of the total weight percent (100 wt. %) of the polymeric composition.
The organic solvent may be selected from the group of esters, ethers, ketones, aromatics and aliphatics and combinations thereof. Examples of organic solvents include butyl acetate, xylene, methyl amyl ketone, ethoxyethyl propionate, and combinations thereof
In one embodiment, the organic solvent may comprise from 5 wt. % to 60 wt. %, such as from 10 wt. % to 55 wt. %, from 25 wt. % to 50 wt. %, of the total weight percent (100 wt. %) of the polymeric composition.
The optional one or more additives may include one or more materials including a pigment, a filler, a paint additive, a C1 to C6 alcohol, a polysiloxane polymer [[formula x-O-Si (R, R′) n -y]], an adhesion promotor, and combinations thereof.
The C1 to C6 alcohol may be selected from the group consisting of ethanol, methanol, propanol, isopropanol, butanol, isobutanol, and combinations thereof. The formulation may have 0 wt. % of the optional C1 to C6 alcohol. When present the C1 to C6 alcohol may be from 0.1 wt. % to 15 wt. %, such as from 1 wt. % to 10 wt. %, from 2 wt. % to 6 wt. %, of the total weight percent (100 wt. %) of the polymeric composition.
Suitable polysiloxane polymers may be selected from the group consisting of linear and branched polyalkyl siloxane and combinations thereof. The formulation may have 0 wt. % of the polysiloxane polymer. When present the polysiloxane polymer may be from 1 wt. % to 60 wt. %, such as from 5 wt. % to 30 wt. %, from 10 wt. % to 25 wt. %, of the total weight percent (100 wt. %) of the polymeric composition.
The adhesion promotor may include epoxy silanes, alkoxysilanes and aminosilanes, titanates and zirconates and combinations thereof. Examples of suitable adhesion promoters may be selected from the group consisting of epoxypropyl trimethoxy silane and, epoxy silane oligomers, and combinations thereof. Commercial examples of adhesion promotors include Silquest A-187, Silquest A-1871 and CoatOsil MP 200 commercially available from Momentive Performance Materials from New York USA.
The formulation may have 0 wt. % of the adhesion promotor. When present the adhesion promotor may be from 0.05 wt. % to 4 wt. %, such as from 0.1 wt. % to 3 wt. %, from 0.5 wt. % to 2 wt. %, of the total weight percent (100 wt. %) of the polymeric composition.
Pigments may include anatase and rutile type of titanium dioxide, lead oxide, zinc oxide, iron oxides, carbon black and organic pigments and combinations thereof Examples of suitable pigments may be selected from the group consisting of titanium oxide, iron oxide and combinations thereof The formulation may have 0 wt. % of the pigments. When present the pigments may be from 3 wt. % to 60 wt. %, such as from 5 wt. % to 50 wt. %, for example, from 5 wt. % to 40 wt. %, of the total weight percent (100 wt. %) of the polymeric composition.
Fillers may include barium and calcium sulfate, silica oxides, silicates and combinations thereof. The formulation may have 0 wt. % of the fillers. When present the fillers may be from 5 wt. % to 50 wt. %, such as from 10 wt. % to 40wt. %, from 10 wt .% to 30 wt. %, of the total weight percent (100 wt. %) of the polymeric composition.
Paint additives may include UV stabilizers, corrosion inhibitors, heat stabilizers, slip and mar additives, biocides, thickeners and combinations thereof The formulation may have 0 wt. % of the paint additives. When present the paint additives may be from 0,01 wt. % to 8 wt. %, such as from 0.02 wt. % to 6 wt. %, from 0.02 wt. % to 5 wt. %, of the total weight percent (100 wt. %) of the polymeric composition.
In one embodiment, the formulation comprises:
The total weight percent of the components of the polymeric composition comprise 100 weight percent.
This invention also concerns an one package system that has an extended self-life of at least one month comprising the copolymer based on the monomers described herein, a water scavenger described herein, a catalyst, an organic solvent, and optionally, one or more additives. The one package system has the wt. % of the components as described for the formulation described herein.
In order to provide a better understanding of the present invention including representative advantages thereof, the following examples are offered.
In order that those skilled in the art may more fully understand the invention presented herein, the following procedures and examples are set forth. Unless otherwise indicated, the following units of measurement and definitions apply in this application: all parts and percentages are by weight; temperatures are in degrees centigrade (° C.).
For the following examples, the data was derived in accordance with the following procedures.
Solids: The solids is the weight percentage of non volatile material present in the coating formulations. Viscosity: The viscosity is the resistance of the polymer preparation to flow. Viscosity is determined by Brookfield viscosimeter.
Molecular weight: The molecular weight is a number average/number average? Molecular weight determined by Gel permeation chromatograph using polystyrene as reference and tetrahydrofurane as elution solvent. DIN Standard 55672
Potlife: The potlife is an estimation of the time during which the polymer composition can be used for a specific application. In the present case potlife is determined by the time taken for the polymer composition to double of viscosity in a closed can.
The following examples were performed and are provided to illustrate the invention, and should not be interpreted as limiting the scope of the invention.
in a 3L glass reactor equipped with a stirrer and a nitrogen inflow. The solvent (part 1) is poured in the reactor and a nitrogen blanket is applied (101 n/h). The stirrer is set at 80 RPM. The temperature is set to 115° C. The monomer mix I is prepared by mixing the monomers, of part 3 and the initiator. Once the temperature inside the reactor is reached, a shot of (part 2) is added and the nitrogen flow is stopped. Afterwards the monomer mix I is added into the reactor over a period of 4 hours. At the end of the addition, the booster composed of the initiator and the solvent (part 5) is added for 1 hour at 115° C. Then, the reactor is kept at 115° C. for an hour. The reactor is eventually cooled down below 80° C.
The resin is first diluted with the solvent (of the synthesis) to a viscosity between 300 and 400 cPs. Then the catalyst is added to the diluted resin at a level of 0.05 to 3% active. Afterwards, the formulated resin is applied on a panel at 100 um wet with a Mayer rod and left to dry at 23±2° C. and 50±5%
in a 3 L glass reactor equipped with a stirrer and a nitrogen inflow. The solvent (part 1) is poured in the reactor and a nitrogen blanket is applied (10 ln/h). The stirrer is set at 80 RPM. The temperature is set to 115° C. The monomer mix is prepared by mixing the monomers, of part 3 and the initiator. Once the temperature inside the reactor is reached, the initiator (part 2) is added and the nitrogen flow is stopped. Afterwards the monomer mix is added into the reactor over a period of 4 hours. At the end of the addition, the booster composed of the initiator and the solvent (part 5) is added for 1 hour at 115° C. Then, the reactor is kept at 115° C. for an hour. The reactor is eventually cooled down below 80° C.
The water content of example 3 was adjusted to 0,2% by the addition of demineralized water catalyst (a strong acid catalyst based on Dodecylbenzenesulfonic acid from King Industries) was added. The resin was then fractioned in small portions and 3% of water scavenger, optionally 3% of an alcohol and 1% Nacure 5076. All percentages were calculated on solid resins content. The samples were stored at 23° C. and their viscosity was measured after 2 and 4 hours. After 10 weeks of storage, the samples with trimethyl orthofoimate and trimethyl orthoacetate only had a very moderate increase in viscosity.
The water content of example 3 was adjusted to 0,2% by the addition of demineralized water. The resin was then fractioned in small portions and 3% of water scavenger, optionally 3% of an alcohol and 1% dibutyltin dilaurate, (DBTDL). All percentages were calculated on solid resins content. The samples were stored at 23° C. and their viscosity was measured after 2 and 4 hours.
A resin was prepared in the same way as example 3 except that the solvent, butyl acetate was replaced by a more hydrophobic solvent with a lower water content and lower tendency to capture moisture from the ambient air, Shellsol D40.
0,5% of catalyst was added to the resins and their viscosity increasing rate was assessed qualitatively. Results are reported on 1-5 scale, a score of 5 indicating the fastest viscosity increasing rate.
Various levels of catalyst were added to the resin of example 4. The resins were then applied with a barcoater on Q panels and the Koenig hardness was monitored over time
| Number | Date | Country | Kind |
|---|---|---|---|
| 19075011.7 | Jul 2019 | EP | regional |
| Filing Document | Filing Date | Country | Kind |
|---|---|---|---|
| PCT/EP2020/000133 | 7/8/2020 | WO | 00 |
