The disclosure relates generally to optical components and more particularly to optical components having optical containers including aversive materials. Cables, such as power transmission cables, telephone cables, optical fiber cables, etc., are used to transmit electricity and/or data over distance. In order to do so, the cables have to be strung across land and/or buried in the ground between electricity/data sources and delivery points. Additionally, such cables are terminated or joined at various enclosures throughout the network. Rodents have been known to chew on cables and enclosures, which damages the cables and enclosures and which can cause network failure. Rodents chew on cables and enclosures for a variety of reasons, such as chewing by juvenile rodents to explore their surroundings, leaving or replacing a scent to mark a rodent's territory, and creating of a nesting site around or within the cables and enclosures. According to some estimates, squirrels alone are attributed with causing approximately 17% of damage to aerial cables.
In one aspect, embodiments of the present disclosure relate to an optical component. The optical component includes an optical container formed from a polymeric composition and an optical element having at least one optical fiber. The optical element is disposed within the optical container. The polymeric composition includes a polymer component and a first aversive additive dispersed in the polymer component. The first aversive additive includes first inorganic particles having an open structure and a chemical aversive material infused into the first inorganic particles.
In another aspect, embodiments of the present disclosure relate to a method of forming an optical component. In the method, a chemical aversive material is infused into first inorganic particles having an open structure to form a first aversive additive. The first aversive additive is compounded with a polymer component to form a polymeric composition. The polymer composition is formed into an optical container of the optical component. The optical container is configured to surround at least one optical element of the optical component.
In still another aspect, embodiments of the present disclosure relate to an optical container configured to at least partially surround an optical element having at least one optical fiber. The optical container is formed from a polymeric composition including polymer component and a first aversive additive dispersed in the polymer component. The first aversive additive includes first inorganic particles having an open structure and a chemical aversive material infused into the first inorganic particles.
Additional features and advantages will be set forth in the detailed description which follows, and in part will be readily apparent to those skilled in the art from the description or recognized by practicing the embodiments as described in the written description and claims hereof, as well as the appended drawings.
It is to be understood that both the foregoing general description and the following detailed description are merely exemplary, and are intended to provide an overview or framework to understand the nature and character of the claims.
The accompanying drawings are included to provide a further understanding and are incorporated in and constitute a part of this specification. The drawings illustrate one or more embodiment(s), and together with the description serve to explain principles and operation of the various embodiments.
Referring generally to the figures, various embodiments of a polymer composition containing a mechanical and chemical aversive for repelling animals from optical containers made from or including the polymer composition are provided. In particular, the polymer composition is suitable for use in optical containers of optical components, such as cable jackets of optical fiber cables or optical fiber splice enclosures. Advantageously, the combination of mechanical and chemical aversive provides a wide range of protection against animal attack for any of the various reasons that animals, especially rodents, chew or gnaw on the optical containers. As will be discussed more fully below, the mechanical and chemical aversive can be combined in a single additive in the form of an open inorganic particle infused with a chemical aversive material. The polymer composition can further include additional inorganic particles to enhance the mechanical aversive effect. The mechanical and chemical aversive can be compounded into the polymeric composition at high temperatures, and the structures formed from the polymeric composition are resistant to environmental degradation. Further, the aversive additive is dispersed evenly throughout the polymer, and the chemical aversive is released upon interaction with an animal. These and other embodiments will be described herein and in relation to the figures. Such exemplary embodiments are provided by way of illustration and not by way of limitation.
As disclosed herein, the polymeric composition containing the aversive additive can be incorporated into a variety of different optical containers of optical components. In the present disclosure, an “optical container” is a structure configured to house one or more optical elements. The optical container is formed at least in part from the polymeric composition containing the aversive additive, including by extruding, molding, overmolding, and injection molding of the structure of the optical container. In one or more embodiments, the optical container may be a cable jacket, an enclosure (e.g., a splice joint enclosure, cabinet, enclosure box, dome enclosure, etc.), an overmold structure (e.g., FlexNAP™ system closure), or single-or multi-port terminals, among other possibilities. Further, as used herein, an “optical component” is the combination of the optical container and at least one optical element, which may be one or more optical fibers or may be a structure that contains one or more optical fibers as will be discussed below.
Further, in the embodiment depicted in
With respect to the optical fiber cable 10 of
The aversive additive can be compounded with a variety of suitable polymers, including thermoplastic polymers, thermoset polymers, elastomers, and thermoplastic elastomers. Exemplary polymers include ethylene-vinyl acetate copolymers, ethylene-acrylate copolymers, polyethylene homopolymers (low, medium, and high density), linear low density polyethylene, very low density polyethylene, polypropylene homopolymer, polyolefin elastomer copolymer, polyethylene-polypropylene copolymer, butene- and octane-branched copolymers, or maleic anhydride-grafted versions of the polymers listed above. In one or more other embodiments, the polymer composition may include halogenated thermoplastics (such as polyvinyl chloride), thermoplastic polyurethane, or a crosslinked polyethylene.
In still one or more other embodiments, the polymeric composition may be compounded with one or more engineering plastics, such as polyethylene terephthalate, polybutylene terephthalate, polyether ether ketone, acrylonitrile butadiene styrene, polyamides (in particular nylon 6,6 or nylon 6,12), polysulfone, polycarbonate, polyphthalamide, poly(methyl methacrylate), styrene-acrylonitrile, polytetrafluoroethylene, polyvinylidene fluoride, acetal (polyoxymethylene), polyethylenimine, polyphenylene sulfide, poly(p-phenylene oxide), amorphous polyetherimide, ultra high molecular weight polyethylene, ionomers (such as Surlyn®), or polyamide-imide. The engineering plastics may provide additional toughness to the cable jacket 12 to dissuade an animal from gnawing or chewing on the cable jacket 12. In one or more embodiments, the engineering plastic is selected to have a hardness of at least 87 on the Rockwell R scale as measured according to ASTM D785, especially when the optical container is a splice enclosure (providing compliance with GR-771-CORE). In one or more embodiments, the engineering plastic is selected to have an Izod impact strength of at least 0.25 J/cm as measured according to ASTM D256 Type A.
The polymeric composition includes as the infused particles any of a variety of open inorganic particles into which a chemical aversive material is infused. By “open,” it is meant that the structure of the inorganic particles is capable of holding the chemical aversive material within its structure. For example, the inorganic particles may be porous or tubular. In one or more embodiments, the inorganic particle is one or more of zeolite, cordierite, halloysite nanotubes, aluminum-titanate composites, magnesium silicate composites, cucryptite, and other silicates, oxides, or hydroxides. In one or more embodiments, the open inorganic particles are within a size range of 20 to 400 mesh, in particular from 50 to 120 mesh. That is, the open inorganic particles will pass through a mesh of size 20 but not pass through a mesh of size 400, or more particularly, the open inorganic particles will pass through a mesh of size 50 but not pass through a mesh of size 120.
As used herein, a “chemical aversive material” is one that will repel an animal in the particular environment in which the chemical aversive material is used. Generally, the chemical aversive material will trigger a flavor, olfactory, or tactile response in the animal, repelling the animal from, e.g., chewing, pecking, or climbing on the structure containing the aversive material. In one or more embodiments, the chemical aversive material is cinnamaldehyde, wintergreen oil, capsaicin, peppermint oil, bergamot oil, geranium oil, natural or synthetic urine (especially predator urine), eucalyptus, bitterants, pinene, lemon citrus oil, cedarwood oil, garlic oil, lithium chloride, natural or synthetic pepper derivatives, tannin, denatonium benzoate (e.g., Bitrex®), bitumen, catnip, nookatone, perilla leaves (all components, any combination of components, or a single component), vanillas (all components, any combination of components, or a single component), and any other aversive materials known in the art to produce an aversive reaction to an animal or animals in any or all environments.
As mentioned above, the polymeric composition may additionally contain inorganic particles that are not infused with a chemical aversive material. Such inorganic particles may be open inorganic particles, such as those mentioned above, including zeolite, cordierite, halloysite nanotubes, aluminum-titanate composites, magnesium silicate composites, and cucryptite. Additionally, the inorganic particles may be aluminum oxide, silicon dioxide, silicon carbide, carborundum, ruby, sapphire, diamond, garnet, amethyst, quartz, feldspar, topaz, granite, emery, marble, optical glass, or glass spheres. In one or more embodiments, the inorganic particles are within a size range of 20 to 400 mesh, in particular from 50 to 120 mesh.
In one or more embodiments, the inorganic particles, including both the infused and non-infused inorganic particles, have a Mohs hardness of 5 or higher. Such a hardness is as hard or harder than rodent teeth, meaning that biting into such inorganic particles will produce an undesirable tactile feedback for the rodent.
In the polymeric composition, the polymeric composition includes 0.2 to 12% by weight, in particular 0.4% to 4% by weight, of the infused particles. When included, the polymeric composition includes 2% to 40% by weight, in particular 5% to 15% by weight, of the inorganic particles. In an embodiment, the infused particles and optional other inorganic particles are mixed with other optional polymer additives prior to or during compounding of the polymer composition. Typical polymer additives include pigments, stabilizers, fungicides, and fillers (in addition to the inorganic particles). In certain embodiments, the infused particles and any optional inorganic particles and other additives together comprise from 2% to 50% by weight of the polymer composition.
Having described the polymer composition, a method of infusing open inorganic particles with chemical aversive material is now described. In one or more embodiments, a solution of the chemical aversive material and a solvent is prepared. In one or more embodiments, the solution may contain 10:90 to 50:50 ratio of solvent to chemical aversive material. In embodiments, the solvent is used to lower the viscosity of the chemical aversive material so that the solution containing the chemical aversive material can infuse into the pores or tubes of the open inorganic material. A variety of solvents may be used to form the aversive solution so long as the chemical aversive material is soluble in the solvent. Thereafter, in embodiments, the porous inorganic material is infused with the aversive solution. In embodiments, the ratio of open inorganic material to aversive solution is from 1:2 to 1:20. In embodiments, the mixture of open inorganic particles and aversive solution is sonicated and placed under vacuum (e.g., 10 inHg to 29.5 inHg) to assist infusion. The mixture may remain under vacuum for a time of 20 minutes to 120 minutes, and the vacuum is slowly released to atmospheric pressure over a time period of, e.g., 30 minutes to 4 hours. In embodiments, the concentration of chemical aversive material in the open inorganic material is from 60 ng/ml to 10 mg/ml.
In an experimental embodiment, samples of zeolite Y were infused with a solution of chemical aversive material at 1 part zeolite to 10 parts aversive solution. In a first example embodiment, the zeolite material was infused with peppermint oil, and in another example embodiment, the zeolite material was infused with menthol. The samples were sonicated in the solution and placed in a vacuum desiccator for a time period of over 20 minutes. Vacuum was pulled at 24 inHg. The vacuum was released slowly over 30 minutes to allow infusion of the aversive solution into the pores of the porous inorganic material. The samples were then centrifuged, the solution was decanted, and the material was rinsed and centrifuged with ethanol, followed by 50:50 ethanol:water, and finally water. In other embodiments, the number of washing steps may be reduced to speed up the infusion process. The samples were then dried by lyophilization.
Advantageously, the open inorganic particles protect the chemical aversive material during compounding and forming despite exposure to temperatures of greater than 150° C., which might otherwise cause degradation of an unprotected chemical aversive material. In this way, the aversive additive as described herein can be extruded or molded with or otherwise dispersed in a polymer usable in a variety of applications. In some embodiments, the aversive additive described herein is added to a thermoplastic polymer material that is then melted and shaped through extrusion, overmolding, injection molding, compression molding, or any other suitable process to form a polymeric article. In other embodiments, the aversive additive described herein is added to a polymer precursor mixture that is then cured or cross-linked, e.g., via UV, heating, etc., to form a polymeric article.
Based on the foregoing, the present disclosure also relates to a method of preparing an optical component, such as the optical cable 10 of
Returning to the embodiment of an optical fiber cable 10, such as the optical fiber cable shown in
The embodiments of the polymer composition incorporated into the optical fiber cable 10 are provided for the purposes of illustration only and not by way of limitation. Indeed, the polymeric composition can be incorporated in many other optical components using the polymer composition as the optical container or as part of the optical container. For example,
While
Unless otherwise expressly stated, it is in no way intended that any method set forth herein be construed as requiring that its steps be performed in a specific order. Accordingly, where a method claim does not actually recite an order to be followed by its steps or it is not otherwise specifically stated in the claims or descriptions that the steps are to be limited to a specific order, it is in no way intended that any particular order be inferred. In addition, as used herein the article “a” is intended include one or more than one component or element, and is not intended to be construed as meaning only one.
It will be apparent to those skilled in the art that various modifications and variations can be made without departing from the spirit or scope of the disclosed embodiments. Since modifications combinations, sub-combinations and variations of the disclosed embodiments incorporating the spirit and substance of the embodiments may occur to persons skilled in the art, the disclosed embodiments should be construed to include everything within the scope of the appended claims and their equivalents.
This application is a continuation of International Application No. PCT/US2023/022692, filed May 18, 2023, which claims the benefit of priority of U.S. Provisional Application Ser. No. 63/347,165 filed on May 31, 2022, the content of which is relied upon and incorporated herein by reference in its entirety.
Number | Date | Country | |
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63347165 | May 2022 | US |
Number | Date | Country | |
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Parent | PCT/US2023/022692 | May 2023 | WO |
Child | 18920125 | US |