The invention relates to optical measuring devices and in particular to a measuring device, components thereof and methods for measurement for applications where the sensing zone in which the measurement is to be made contains hydrogen that can potentially contaminate optical components of the optical measuring device.
The effects of hydrogen diffusion into optical fibers have been studied for more than a decade. Four principal aspects have been the objects of these studies: enhancing the photosensitivity of optical fibers, Bragg wavelength shift due to an increase of the effective index of optical fiber, absorption losses increase and hydrogen sensing.
More specifically, the presence of hydrogen molecules in the optical fiber changes its effective refractive index (nef). When a Bragg grating is present in the optical fiber, the resulting reflected Bragg wavelength (λB) as described by the Bragg condition equation is affected by the refractive index change:
λB=2neffΛ (1)
where Λ is the period between the fringes of different refractive indexes.
Another effect of the presence of molecular hydrogen into an optical fiber is the increased attenuation of the light energy traveling through it, via molecular absorption. This phenomenon has an impact on fiber optics based monitoring systems for oil and gas extraction where pressure, temperature and environmental hydrogen concentration are usually quite high.
It is known to use either Bragg wavelength shift or absorption losses increase due to the presence of molecular hydrogen in the core of an optical fiber to monitor the concentration of hydrogen in the environment, or in other substances that would chemically react to create hydrogen. This type of sensors can have a very slow dynamic reactive time because it is limited by the diffusion rate of hydrogen through the glass of the optical fiber until it reaches the core of the fiber. Typically it takes a month to reach 97.3% of the equilibrium concentration of hydrogen for a standard 125 microns diameter fiber at 20° C. For that reason, most hydrogen sensors based on fiber Bragg gratings use a hydrogen-reactive coating, such as a palladium-based coating, that swells by absorbing hydrogen, and so, strain the fiber segment containing the Bragg grating increasing the refractive indexes fringes (Λ).
There is a need in the industry to provide optical measuring devices that can operate in sensing zones containing hydrogen, that are of simple construction, are reliable and provide accurate measurements results.
As embodied and broadly described herein the invention provides a signal processing apparatus which has an input for receiving a signal conveying a response from first and second optical components to an optical excitation. The first and second optical components are in an optical sensor which is intended to be placed in a sensing zone. The sensing zone contains hydrogen susceptible to migrate into the optical sensor. The signal processing apparatus has a processing entity for processing the response from the first and second optical components to derive information on hydrogen concentration in the optical sensor.
As embodied and described herein the invention also provides a measurement apparatus having an optical sensor for use in a sensing zone containing hydrogen susceptible to migrate into the optical sensor. The optical sensor has first and second optical components for generating a response to optical excitation impressed in the optical sensor. The measurement apparatus has an input for receiving the response generated by the first and second optical components and a processing entity for processing the response to derive information on hydrogen concentration in the optical sensor.
As embodied and described herein the invention also provides an apparatus for measuring a physical parameter. The apparatus has an optical sensor for exposure to the physical parameter, the optical sensor capable of producing a response dependent on the intensity of the physical parameter acting on the optical sensor. The optical sensor is susceptible to contamination by hydrogen potentially present in the vicinity of the optical sensor. The apparatus also has a processing entity in communication with the optical sensor for processing the response to derive a measure of the physical parameter intensity corrected for hydrogen contamination. The processing operation including determining from information contained in the response a degree of attenuation an optical signal manifests in the optical sensor, in at least at two different ranges of wavelengths of light.
As embodied and broadly described herein the invention also provides a method for measuring a physical parameter in a sensing zone, the method comprising placing an optical sensor in the sensing zone, the optical sensor including a plurality of optical components responsive to the intensity of the physical parameter acting on the optical sensor. The optical sensor is susceptible to contamination by hydrogen potentially present in the sensing zone which alters the response manifested by the optical components to the physical parameter. The method also includes introducing an optical excitation in the optical sensor and observing the response of the optical components to the optical excitation, the optical components responding to different ranges of wavelengths of light in the optical excitation. The method also includes processing the response of the optical components to derive a measure of the physical parameter intensity corrected for hydrogen contamination.
As embodied and broadly described herein, the invention also provides a method to derive information on hydrogen concentration in an optical sensor located in a sensing zone containing hydrogen susceptible to migrate into the optical sensor. The method includes receiving a signal conveying a response from first and second optical components of the optical sensor to an optical excitation and processing the response from the first and second optical components to derive information on hydrogen concentration in the optical sensor.
As embodied and broadly described herein, the invention also provides a method for measuring hydrogen concentration in an optical sensor. The method includes receiving a signal conveying a response from the optical sensor to an optical excitation and processing the response to derive a measure of the hydrogen concentration in the optical sensor. The processing operation includes determining from information contained in the response a degree of attenuation an optical signal manifests in the optical sensor, in at least at two different ranges of wavelengths of light.
As embodied and broadly described herein the invention also provides an apparatus for measuring temperature in a well of an oil extraction installation. The apparatus has an optical sensor for placement in the well which contains hydrogen susceptible to migrate into the optical sensor. The apparatus also has a signal processing device for processing an optical response of the optical sensor and derive from the optical response a temperature measurement in the well corrected for effects of hydrogen migration into the optical sensor.
As embodied and broadly described herein the invention also provides a method for measuring temperature in a well of an oil extraction installation, the method comprising the step of receiving an optical response from an optical sensor placed in the well which contains hydrogen susceptible to migrate into the optical sensor. The method also includes performing signal processing on information conveyed in the optical response and deriving from the information a temperature measurement in the well corrected for effects of hydrogen migration into the optical sensor.
As embodied and broadly described herein the invention further includes an optical sensor for measuring temperature in a well of an oil extraction installation, the well contains hydrogen susceptible to migrate into the optical sensor. The optical sensor has a first optical component and a second optical component and a common optical path containing the first optical component and the second optical component. The first and second optical components are capable of generating an optical response to an optical excitation conveying information from which can be derived a temperature measurement corrected for effects of hydrogen migration into the optical sensor.
A detailed description of examples of implementation of the present invention is provided hereinbelow with reference to the following drawings, in which:
In the drawings, embodiments of the invention are illustrated by way of example. It is to be expressly understood that the description and drawings are only for purposes of illustration and as an aid to understanding, and are not intended to be a definition of the limits of the invention.
The sensing zone 12 is the area where the measurement is to be made. In this specific example of implementation, the sensing zone 12 is susceptible to contain gaseous hydrogen. The hydrogen can migrate into the optical sensor and affect the way the sensor responds to the physical parameter. This will, in turn, produce an erroneous reading of the intensity of the physical parameter at the signal processing device 16 unless the measurement is corrected to take into account the hydrogen concentration. Specific applications where the measurement apparatus 10 can be used include oil and gas exploration/exploitation where the need exists for optical sensors that can reliably function in areas that often contain hydrogen gas.
In use, the optical excitation generator 18 generates light which is injected into the optical fiber length that leads to the optical sensor 14. The optical excitation reaches the fiber gratings 22, 24 which filter out from the optical excitation two distinct wavelength ranges. Specifically, the wavelengths in the ranges of wavelengths of light to which the fiber gratings 22, 24 respond are reflected back toward the optical excitation generator such that the optical excitation that reaches the signal processing device 16 is lacking the wavelengths in those ranges. The signal processing device 16 uses the information it receives from the optical sensor 14 to derive the intensity of the physical parameter acting on the optical sensor 14 in the sensing zone 12, corrected for hydrogen concentration in the optical sensor. As indicated previously, the physical parameter can be the temperature, pressure or mechanical strain acting on the optical sensor 14. In the case of mechanical strain or pressure, there may be a necessity to mount the optical sensor 14 on a transducer structure (not shown in the drawings) that is directly exposed to pressure or mechanical strain and communicates this pressure or mechanical strain directly to the optical sensor 14. Such transducer structures are known in the art and do not need to be discussed here in greater details.
Note that while the specification discusses the fiber gratings 22, 24 as being responsive to respective ranges of wavelength, in practice those ranges are quite narrow, since in most practical applications the fiber gratings 22, 24 are designed to be as selective as possible. For the purposes of performing signal analysis on the fiber gratings 22, 24 responses, where a mathematical representation of a range of wavelengths may be overly complex, it is acceptable to represent the response of a fiber grating by a single wavelength, such as the peak wavelength in the range.
The signal processing device extracts from the response from the optical sensor 14 the wavelength ranges that have been filtered out by the gratings 22, 24 and also the degree at which the optical excitation has been attenuated in the optical sensor. The degree of optical excitation attenuation is due largely to the hydrogen concentration in the core of the optical sensor 14. These two elements of information can then be used to determine the hydrogen concentration in the core of the optical sensor 14, the temperature of the optical sensor 14, as well as the intensity of the physical parameter acting on the optical sensor 14 (other than temperature).
Techniques to determine the degree of attenuation of an optical signal in an optical fiber are generally known and will not be described in detail. Suffice it to say that a determination of the degree of attenuation can be made by comparing the amount of power received by the signal processing device 16 to the amount of power injected by the optical excitation generator 18. In instances where a direct measure of the amount of power injected by the optical excitation generator 18 is not readily available, a computation based on the nominal amount of power produced by the optical excitation generator can be used as a basis for calculating the degree of attenuation.
The signal processing device 16 also has an output interface 32 that allows communicating the result of the mathematical processing to an external entity. The external entity can be a human operator or a piece of equipment that uses the information generated by the signal processing device 16 for specific purposes.
Molecular hydrogen absorbs photons according to their wavelength;
H2 loss (λ,T)=A f(λ/λref)g(T) [H2]L (2
where λ is the specific wavelength at which the absorption is calculated, g (T) is the increasing molecular absorption function with temperature of Arrhenius type, A is the absorption at the reference wavelength of one unitary concentration of hydrogen for one unity of length at the Arrhenius reference temperature and f (λ/λref) is the function describing the ratio of absorption with wavelength normalized against a specific wavelength. Such a function, f (λ/λref) is illustrated in
The presence of hydrogen in the optical sensor 14 also raises its effective index, shifting linearly the reflected Bragg wavelength:
ΔλB=B[H2] (3)
The temperature also raises effective index of the optical fiber, shifting independently and also linearly the reflected Bragg wavelength:
ΔλB=B[H2]+C(T−Tref) (4)
By using two optical components 22, 24 in the form of fiber gratings at very close proximity to one another, one can assume that they are for all practical purposes at the same location, so the temperature, light path length and hydrogen concentration in the core of the optical sensor 14 are the same for both optical components 22, 24. The difference in absorption losses is then given by:
H2 loss (λ1,T)−H2 loss (λ2, T)={A g(T) [H2]L}{f(λ1/λref)−f(λ2/λref)} (5)
The signal processing device 16 can determine using known signal processing techniques the wavelength ranges to which the fiber gratings 22, 24 respond and the degree of attenuation the optical excitation has been subjected to by the optical sensor 14. This can therefore yield {H2 loss (λ1, T)−H2 loss (λ2, T)}, λ1 and λ2. The model characterization supplies all the other parameters except for the temperature and hydrogen concentration. Using equations (4) and (5), it is possible to solve the mathematical system using standard methods and obtain the values of hydrogen concentration and temperature in the core of the optical sensor 14 where the fiber gratings 22, 24 are located.
Several mathematical methods can be used to resolve these equations.
Note that since the mathematical system has two unknowns, the hydrogen concentration and the temperature, and three equations are available, equation (5) and one equation (4) for each fiber grating wavelength shift, the fiber gratings wavelength shifts can be used to measure another parameter or measurand (M) such as the intensity of the physical parameter acting on the optical sensor 14, other than temperature for which a result is already available. As indicated earlier, strain on the optical sensor causes an increase of the period of the fringes of refractive index (Λ), and so shifts the Bragg wavelength linearly according to equation (1) and independently of hydrogen or thermal effects. Using transducer structures as discussed above, several measurands, such as force, pressure, can be converted into strain of the fiber. Then:
ΔλB=B[H2]+C(T−Tref)+D(M−Mref) (6)
The above examples of implementation of the invention have all been discussed in the context of systems using optical responses based on signal transmission through optical components. In other words, the information conveyed in the response is carried in the part of the optical excitation passing through the optical components. It is also possible to use systems based on signal reflection where the response resides in the portion of the optical excitation that is reflected instead of being transmitted.
The various embodiments discussed earlier can be used for different practical applications. One example is the field of oil/gas exploration where it is often required to obtain temperature measurements in deep wells that contain a sufficient concentration of hydrogen gas, which as discussed earlier can migrate into the optical sensor and affect its index of refraction.
Specifically, the extraction of oil from oil sands requires the injection of steam into a well that softens the bitumen sufficiently allowing it to flow to the surface via a collection conduit. For operational reasons, it is necessary to monitor the temperature inside the steam well with reasonable accuracy. Temperature measuring devices constructed according to the principles of the present invention have been found satisfactory. Specifically, since those devices are optical they do not require electrical energy to operate and, therefore, do not create a risk of explosion due to the high concentration of gases capable of igniting and burning. In addition, they measuring devices can correct the raw measurements for the effects of hydrogen diffusion and thus produce accurate results.
Although various embodiments have been illustrated, this was for the purpose of describing, but not limiting, the invention. Various modifications will become apparent to those skilled in the art and are within the scope of this invention, which is defined more particularly by the attached claims.
The present application claims the benefit under 35 USC § 119(e) of prior U.S. provisional patent application Ser. No. 60/825,019 filed on Sep. 8, 2006, hereby incorporated by reference herein.
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