The present invention generally relates to an optical-effect-producing medium of the type comprising a carrier medium containing or comprising pigment particles having at least one optically responsive pigment or dye that responds to incident electromagnetic radiation of at least a selected excitation wavelength or wavelength band by producing an optical response in the visible or near-visible spectrum.
In the context of the present invention, the expression “optical-effect-producing medium” designates any medium that can be printed, transferred, applied, embedded or otherwise provided onto or into a substrate. This in particular includes:
In the case of printing inks, varnishes and like printable materials, the carrier medium would basically be a binder or vehicle for the pigment particles, which, at the time of printing or varnishing, is in a substantially liquid or pasty state and, following the printing/varnishing operation, is then dried or cured to exhibit a substantially solid state.
In the case of transferable or embeddable elements, the carrier medium would basically be a substantially solid carrier layer (for example of a suitable polymer material). In the case of transfer elements, the application process would typically involve activation of an adhesive layer provided on the side of the carrier layer (or of any additional layer linked therewith) which is intended to be applied onto the surface of the desired object (for instance on the surface of a security document). In the case of embeddable elements, the elements are directly embedded in the substrate during the manufacture thereof (for instance bonded with the fibers of typical cotton-paper as used for the production of banknotes).
Suitable printing processes (such as intaglio printing, offset printing, silk-screen printing, etc., which are typically used in the security printing industry), application/transfer processes (such hot- or cold-stamping techniques), and embedding processes (such as used in the context of the manufacture of cotton-paper substrates) are known to those skilled in the art and could be used to apply or form the optical-effect producing medium of the instant invention.
Optical-effect-producing mediums are generally known in the art.
As already mentioned in the preamble hereof, the present invention is directed to a more particular subset of optical-effect-producing mediums, namely optical-effect-producing mediums of the type comprising a carrier medium containing or comprising pigment particles having at least one optically responsive pigment or dye that responds to incident electromagnetic radiation of at least a selected excitation wavelength or wavelength band by producing an optical response in the visible or near-visible spectrum.
In the context of the present invention, it is to be understood that the optically responsive pigment or dye is not directly incorporated into the carrier medium, but rather in distinct pigment particles that are distributed in the carrier medium. The optical-effect producing medium which forms the subject-matter of the instant application is therefore of the type comprising at least two constituents, namely the carrier medium and the pigment particles, each pigment particle constituting a platform or system carrying the optically responsive pigment or dye. The main advantage of such a configuration is that the pigment particles can be suitably designed to protect the optically responsive pigment or dye from external factors and influences. Such a configuration further guarantees that the optically responsive pigment or dye stays and remains in a locally-stable environment contained within each pigment particle.
Pigment particles as mentioned hereinabove are for instance disclosed and discussed in International Publication No. WO 2007/005354 A2, which is incorporated herein by reference in its entirety. In that context, the pigment particles can in particular be single-layer or multi-layered particles.
A general aim of the invention is to provide an optical-effect-producing medium of the above-mentioned type where the performance of the optically responsive pigment or dye is optimized.
More specifically, an aim of the invention is to provide such an optical-effect-producing medium where the performance of the optically responsive pigment or dye is not degraded by factors such as the surrounding materials used for the carrier medium and the pigment particles, especially the optical characteristics thereof.
These aims are achieved thanks to the optical-effect-producing medium as defined in the appended claims.
There is accordingly provided an optical-effect-producing medium comprising a carrier medium containing or comprising pigment particles having at least one optically responsive pigment or dye that responds to incident electromagnetic radiation of at least a selected excitation wavelength or wavelength band by producing an optical response in the visible or near-visible spectrum, wherein a refractive index of the carrier medium and a refractive index of the pigment particles are selected to maximise the amount of incident electromagnetic radiation reaching the said at least one optically responsive pigment or dye.
Advantageous embodiments of the above optical-effect-producing medium form the subject-matter of the dependent claims.
Also claimed is the use of the above optical-effect-producing medium to produce an optically responsive feature, especially for security, authentication and/or identification purposes.
In that respect, there is further provided an object comprising a substrate and at least one optically responsive feature printed, transferred, applied, embedded or otherwise provided onto or into the substrate, which optically responsive feature is produced using the above-mentioned optical-effect-producing medium.
There is also provided an object comprising a substrate, an under-layer provided onto a surface of the substrate, and at least one optically responsive feature printed, transferred, applied or otherwise provided onto the under-layer, which optically responsive feature is produced using the above-mentioned optical-effect-producing medium.
Advantageous embodiments of the above objects form the subject-matter of the dependent claims.
Other features and advantages of the present invention will appear more clearly from reading the following detailed description of embodiments of the invention which are presented solely by way of non-restrictive examples and illustrated by the attached drawings in which:
Reference is made to
The pigment particles 10 are substantially spherical pigment particles having a mean particle diameter of the order of a few microns or tenths of microns, preferably of the order of 0.1 to 10 microns. Such multilayered pigment particles can in particular be micro-encapsulated particles produced using suitable micro-encapsulation techniques. In this context, the inner core material 3 could advantageously be liquid at ambient temperature.
While
As schematically illustrated in
A particularly advantageous practical implementation of the optical-effect-producing medium can be in the form a printing ink, varnish or like printable material. In such case, as already mentioned in the preamble part hereof, the carrier medium 1 would basically be a binder or vehicle for the pigment particles, which, at the time of printing, is in a substantially liquid or pasty state and, following printing, is then dried or cured to exhibit a substantially solid state. Suitable examples could be intaglio printing inks, offset printing inks, silk-screen printing inks or varnishes as used in flexographic or offset printing processes. The specific nature of the binder or vehicle depends on the relevant practical application and the ink/varnish properties. In the case of water-based or solvent-based inks/varnishes, the binder or vehicle would contain at least one solvent (for instance water) that would be evaporated during a drying process following the printing operation. In the case of UV-cured inks/varnishes, the binder or vehicle would contain at least one UV-activated curing substance that would be activated by UV radiation following the printing operation to typically initiate polymerisation of the binder or vehicle. So-called oxidative (or oxidatively curing) inks/varnishes are also contemplated. In this latter case, the binder or vehicle contains an oxidative polymerisation agent which reacts to exposure to air oxygen to initiate the polymerisation process.
Alternately, the optical-effect-producing medium could take the form of a transfer element or an embeddable element comprising a carrier layer acting as the carrier medium 1. Transfer elements may in particular be foils, patches, and like transfer elements that can be transferred onto a substrate by foil stamping techniques, such as hot-stamping and cold-stamping techniques. Embeddable elements may in particular be threads, fibers, planchettes, and like embeddable elements that can be incorporated into a substrate during the manufacture thereof.
In the context of the invention, the main property of the carrier medium 1 that one is particularly concerned with is the particular refractive index of the carrier medium 1 that will be designated hereinafter as refractive index n1.
Similarly, a property that plays a role in the context of the invention is a refractive index of the pigment particles. In the case of
The optically responsive pigment or dye 100, which in this case is contained within the inner core material 3, can be any suitable pigment or dye that responds to incident electromagnetic radiation of a selected excitation wavelength(s) or wavelength band(s) λEX by producing an optical response in the visible or near-visible spectrum. The following pigments or dyes are in particular contemplated (the following list being however non-exhaustive):
According to the invention, the refractive index n1 of the carrier medium 1 and the refractive index (or indexes) n2, n3 of the pigment particles 10 are selected to maximise the amount of incident electromagnetic radiation reaching the optically responsive pigment or dye 100.
In the context of a printing ink, varnish or like printable material comprising a binder or vehicle acting as the carrier medium 1, the binder or vehicle undergoes a change of state (namely from a liquid or pasty state to a substantially solid state) as a result of the curing or drying process that typically takes place following the printing operation. What matters is therefore the refractive index n1 of the binder or vehicle in a cured or dried state.
Maximization of the amount of incident electromagnetic radiation reaching the optically responsive pigment or dye 100 can be achieved by substantially matching the relevant refractive indexes for the selected excitation wavelength or wavelength band λEX of the incident electromagnetic radiation. It should be appreciated that the refractive index of materials is dependent on the relevant wavelength being considered. In particular, the refractive index of various materials is typically greater at wavelengths in the UV range as compared to the refractive index in the visible spectrum. One should therefore suitably take into account the relevant excitation wavelength (or wavelength band) λEX when matching the relevant refractive indexes of the various constituents of the optical-effect-producing medium.
Tests have shown that slight differences between the relevant refractive indexes may be tolerated in practice. Preferably, an absolute difference between the refractive indexes should be below 0.5, even more preferably below 0.1.
Tests carried out with an optical-effect-producing medium of the type illustrated schematically in
Maximization of the amount of incident electromagnetic radiation reaching the optically responsive pigment or dye 100 is further achieved by ensuring that the carrier medium 1 is substantially transparent at the selected excitation wavelength or wavelength band λEX to prevent absorption of the incident electromagnetic radiation in the carrier medium 1 itself.
A way to adjust the refractive index of any relevant constituent of the optical-effect-producing medium may consist in incorporating a suitable additive in the said constituent to change its nominal refractive index and adjust it to the desired refractive index. A possible additive may in particular be titanium dioxide (TiO2) sub-particles, on the order of 1 micron or less in mean particle diameter (more preferably less that 100 nm), or like high refractive index additives. Titanium dioxide has a relatively high refractive index (of approx. 2.4 to 2.8) which is higher than that of most materials. Any other suitable additive could however be used.
In the same way, it may be appropriate to use a visible light absorbing additive, such as carbon black sub-particles, to reduce scattering of visible light within the optical-effect-producing medium.
The above-mentioned additives could be incorporated in either one of the various constituents of the optical-effect-producing medium, and in various sub-particle sizes (small, large or a combination thereof), for instance in the inner core material 3 (see
Turning now to
Depending on the nature of the under-layer 4, various effects and results could be obtained.
For instance, the under-layer 4 may be a broad-band absorbing layer designed to absorb most of the visible spectrum, such as a dark-colored, preferably black, layer. In this way, and assuming that the incident electromagnetic radiation used to activate the optically responsive pigment or dye is white light (or like broad-band visible radiation), the under-layer 4 would absorb most of this light and prevent scattering of light and reflection thereof which could otherwise be produced at the surface of the underlying substrate 5.
The under-layer 4 may alternately be a narrow-band absorbing layer absorbing only part of the visible spectrum, such as colored layer. In this way, the under-layer 4 could help to prevent scattering and/or reflection of light within the said narrow band that could impact on the desired performance or optical effect of the optically responsive feature.
Still in the same way, the under-layer 4 could be a broad-band reflective layer reflecting most of the visible spectrum, such as a bright-colored, preferably white, layer.
A further measure to prevent scattering of light may consist in ensuring that the exposed surface of the optically responsive feature at the interface between air and the carrier medium 1 exhibits a substantially flat and smooth surface.
Various modifications and/or improvements may be made to the above-described embodiments without departing from the scope of the invention as defined by the appended claims. For instance, the pigment particles may be single-layer (or monolithic) particles or may comprise two or more membranes or shells, rather than one as illustrated in
Number | Date | Country | |
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61353511 | Jun 2010 | US |