The present application claims priority pursuant to 35 U.S.C. §119 from Japanese patent application number 2013-013853, filed on Jan. 29, 2013, the entire disclosure of which is incorporated by reference herein.
Technical Field
The present invention relates to an optical element for use in an optical system of such equipment as various camera devices, projectors, and the like, a mold for preparing the optical element, and an optical device employing the optical element.
Related Art
The optical element for use in an optical system of the optical device is in general subjected to reflection prevention or antireflection treatment to minimize ghosting and flare. Typically, an antireflection film is formed on the surface of the optical element.
However, the antireflection film must be formed as multiple layers for higher performance. Multiple layer formation of antireflection film requires a number of processes, preparing time, and processing cost. That is, it is difficult to design and manufacture a high-quality antireflection film.
Recently, various approaches have been tried to provide resinous optical devices at reduced cost. However, forming an antireflection film on the resinous material adversely affects heat and humidity resistance due to poor adhesion compared to formation of the antireflection film on glass.
Accordingly, a subwavelength structure (SWS) as a reflection prevention structure has been explored as an alternative to the antireflection film. The subwavelength structure has a microstructure with a pitch or width smaller than the wavelength of the light whose reflection is to be prevented. The optical effect of the subwavelength structure depends on the shape and material of the specific microstructure employed. The microstructure is formed by a dry process alone and is appropriate for a cost-effective production.
In order to produce an optical element having a minute concavo-convex structure, use of a nanoparticle etching method is conceivable. Considering the antireflection effect with regard to light with a wide wavelength area or light of infrared wavelength (i.e., longer wavelength than visible light), an interval of a lattice having a minute concavo-convex shape should be defined so that the diffraction light does not occur due to the microstructure up to a specific incident angle in the permeation reflection. Specifically, the interval of the microstructure should be preferably shorter than 200 nm. On the other hand, the height of the lattice of the microstructure should be defined so that the refractive index changes more smoothly for the higher performance. As a result, the height of the microstructure should preferably be more than 200 nm. Accordingly, an effective antireflection effect relative to light with a wide wavelength or the long wavelength longer than the visible light requires an aspect ratio greater than 1 and a height greater than 200 nm. Such a microstructure is difficult to produce with.
To solve the aforementioned problem, the present invention provides an improved optical element having a better antireflection effect. The optical element includes an incident plane and an emission plane and a conical microstructure formed on at least one plane of the incident plane and the emission plane. The conical microstructure includes: a first structure formed of a plurality of conical microprojections with an average height H1; and a second structure formed of a plurality of conical microrecesses with an average height H2, the average height H1 satisfies an inequality: H1≦1/3*λ/n; and the average height H2 satisfies an inequality: H2≦1/3*λ/n. Further, an average pitch P between the first structure and the second structure satisfies following conditions: H1/2≦P≦1/3*λ/n, and H2/2≦P≦1/3*λ/n, in which the use wavelength is defined as λ; and the refractive index relative to the use wavelength is n.
These and other objects, features, and advantages of the present invention will become apparent upon consideration of the following description of the preferred embodiments of the present invention when taken in conjunction with the accompanying drawings.
Hereinafter, an embodiment of an optical element according to the present invention will be described with reference to drawings. Without otherwise specified in the present embodiment, use wavelength for an optical element is 900 nm.
The microstructure is formed of a plurality of minute concavo-convex structures with the height of a base b1 set as a reference. Specifically, the microstructure is formed of a first structure s21 and a second structure s22. The first structure s21 is formed of a plurality of conical microprojections and the second structure is formed of a plurality of conical microrecesses. As illustrated in
The arrangement of the first structure s21 and the second structure s22 is not limited to the example illustrated in
The shape of the bottom plane of the first structure s21 and the second structure s22 is not limited to the one illustrated in
Referring to
The first structure s21 satisfies a condition that the average height H21 is in a range H21≦1/3*λ/n and the second structure s22 satisfies a condition that the average height H22 is in a range H22≦1/3*λ/n, in which the use wavelength is defined as λ and the refractive index of the use wavelength is n.
In this case, the average pitch P21 between the first structure s21 and the second structure s22 satisfies the following conditions: H21/2≦P21≦1/3*λ/n, and H22/2≦P21≦1/3*λ/n.
Then, the height H21 of the first structure s21 and the height H22 of the second structure s22 of the optical element 1 capable of obtaining an optimal antireflection effect are both below 200 nm, so that both structures can be produced with no difficulty.
Next, a comparative example of the optical element 1 will be described, in which the microstructure is formed with either a concave shape or a convex shape alone.
The optical element 10 includes a plurality of convex portions s1 on the transparent base b1. Herein, the optical element 10 includes the microstructure formed of the convex portions s1 having a height H1 and an average pitch P1.
Referring to
By contrast, the optical element 1 according to the first embodiment includes the microstructure formed of the first structure s21 as a convex portion and the second structure s22 as a concave portion. The thus-configured optical element can realize a height of the microstructure capable of obtaining an optimal antireflection effect with a comparatively low height.
How a relation between the height, the average pitch, and the transmittance of the microstructure of the optical element changes due to the difference of the use wavelength will be described using
Referring to
On the other hand, referring to
Next, another embodiment of the optical element according to the present invention will be described.
As described above, the optical element 1 has a high antireflection effect with respect to a predetermined use wavelength. By contrast, the optical element according to a second embodiment has a high antireflection effect even though the use wavelength includes a predetermined range. A case in which the optical element has a high antireflection effect relative to the incident light of the use wavelength ranging from 450 nm to 700 nm will now be described.
The microstructure is formed of a plurality of minute concavo-convex structures with the height of the base b1 set as a reference plane. Specifically, the microstructure is formed of a first structure s21 and a second structure s22. The first structure s21 is formed of a plurality of conical microprojections and the second structure is formed of a plurality of conical microrecesses.
The first structure s21 includes a height H21. In addition, the second structure s22 includes a height H22. The first and second structures are disposed with an average pitch P21 between the first and second structures.
The arrangement and shape of the first structure s21 and the second structure s22 of the optical element 1a are similar to those of the optical element 1, and therefore, redundant explanations thereof will be omitted.
Referring to
The first structure s21 satisfies a condition that the average height H21 is in a range H21≦1/3*λL/nL. In addition, the second structure s22 satisfies a condition that the average height H22 is in a range H22≦1/3*λL/nL. In the above formulae, a lower limit of the use wavelength is λS, an upper limit of the use wavelength is λL, a lower limit of the refractive index corresponding to the use wavelength is nS, and an upper limit of the refractive index corresponding to the use wavelength is nL.
In this case, the average pitch P21 between the first structure s21 and the second structure s22 satisfies the following conditions: H21/2≦P21≦1/3*λS/nS, and H22/2≦P21≦1/3*λS/nS.
Next, a comparative example of the optical element 1a will be described, in which the microstructure is formed with a concave portion or a convex portion alone, using
Referring to
In addition, as illustrated in
Referring to
However, such a microstructure with a high aspect ratio of more than 2 may lack sufficient rigidity and durability. Further, if such a microstructure is formed with a metal mold, it may cause a problem of the durability and releaseability of the metal mold.
By contrast, the optical element 1a according to the second embodiment includes the microstructure formed of the first structure s21 as a convex portion and the second structure s22 as a concave portion. The thus-configured optical element 1a can realize a height of the microstructure capable of obtaining an optimal antireflection effect with a comparatively low height which can be produced with comparative ease, even though the use wavelength includes a predetermined width.
Next, how a relation between the height, the average pitch, and the transmittance of the microstructure of the optical element (1, 1a) changes due to the difference of the use wavelength when the use wavelength includes a predetermined width, will be described.
Referring to
Referring to
As illustrated in
Referring to
Next, a relation between an occupancy rate of the microstructure, transmittance, and reflectance will be described as to the optical element (1, 1a) according to the present invention.
Specifically, the microstructure of the optical element according to the present invention is formed of a first structure s21 including a plurality of conical microprojections and a second structure s22 including a plurality of conical microrecesses with a base b1 set as a reference plane.
In addition, the first structure s21 includes a height H21 and the second structure s22 includes a height H22. The first and second structures are disposed with an average pitch P21 between the first and second structures.
Herein, when the occupancy rate of the first structure s21 relative to the base b1 is set to P1 and the occupancy rate of the second structure s22 relative to the base b1 is set to P2, the optical element 1 satisfies the following inequalities: 0.3≦P1/P2≦1.0 or 0.3≦P2/P1≦1.0.
In the following description, an example in which the wavelength of the incident light is 900 nm, H21 is equal to H22 and is 150 nm, P21 is equal to P22 and is 200 nm, and the refractive index nd of the base is 1.53, will be described.
Referring to
On the other hand, if the occupancy rate P1/P2 of the first structure s21 and the second structure s22 is P1/P2<0.3 or P2/P1<0.3, the transmittance becomes 99% and the reflectance becomes 1.0%, and a satisfactory antireflection effect cannot be obtained.
The foregoing relations between the occupancy rate, the transmittance, and the reflectance are generated because changes in the refractive index near the surface of the medium occur due to a difference in the height of the microprojections of the first structure s21 and the microrecesses of the second structure s22. When there is a large bias in the occupancy rate of the first structure s21 or the second structure s22, the difference in the height of the first structure s21 and the second structure s22 becomes small and the refractive index varies drastically.
Accordingly, the optical element according to the present invention is configured such that the occupancy rate of the first structure s21 and the second structure s22 is preferably within a range 0.3≦P1/P2≦1, or 0.3≦P2/P1≦1. As a result, even though the optical element according to the present invention includes a structure with a comparative low height which can be produced with ease, an optimal antireflection effect with a high performance can still be obtained.
Next, a production method of the optical element according to the present invention will be described. Production of the microstructure in the optical element may employ various methods.
First, the simplest and most practical method includes forming the optical element using a plastic material and forming the microstructure with a resin treatment. In this production method, thermoplastic resins and thermocurable resins are used as a plastic material, and the microstructure is produced by projection-molding.
When producing the optical element 1 including the microstructure by projection-molding, melting resins are filled with injection into a cavity of a metal mold including: structure to develop desired optical properties such as an optical surface, deflation structure, and diffusion structure of the lens; and an optical mold forming the antireflection structure by the microstructure. By injection molding, the optical element with an antireflection structure can be produced at low cost.
Alternatively, there is a method for producing the antireflection structure by nanoimprinting, using nanoimprint resins as plastic materials. Examples of nanoimprint resins include thermoplastic resins, UV curable resins, and Hydrogen silsesquioxane (HSQ).
Nanoimprinting provides excellent transferrability and nanoimprinting to the resinous materials can be performed with a short cycle compared to nanoimprinting to glass materials. Accordingly, producing the optical element using a nanoimprinting method can provide an optical element having optimal antireflection performance at low cost.
Further alternatively, there is a method in which the base of the optical element is produced by using one type of resin and the antireflection structure using a resin different from that of the base is added onto the base.
Further alternatively, resins may be used for the base of the optical element, the antireflection structure may be added on the base, and another antireflection structure formed of resins different from those used for the base and the antireflection structure may be further added.
Furthermore, an optical glass may be used for the base of the optical element and the antireflection structure is added thereon. Specifically, the optical element 1 having a microstructure is formed into a sheet and laminated on the base formed of the optical glass.
It is to be noted that the methods of production of the optical element according to the present invention are not limited to the above-described methods, and various other methods may be applicable.
Next, examples of materials for the optical element will be described.
When injection molding is used, thermoplastic resins and thermocurable resins may be used as materials for the optical element according to the present invention. Examples of thermoplastic resins include polymeta-acrylic resins, polycarbonate resins, alicyclic acrylic resins, circular olefin copolymer, cycloolefin polymer, and the like. Examples of thermocurable resins include epoxy resins, silicon resins, and the like.
Further, the materials for producing the optical element according to the present invention are not limited to the above-described resinous materials, and alternatively the microstructure may be formed on glass or metallic materials.
Next, a metal mold for producing the optical element according to the present invention will be described. Exemplary methods for producing the microstructure on the metal mold for molding include:
(1) Forming minute registration patterns on the surface of the metal mold, and performing anisotropic etching such as reactive ion etching to remove the registration patterns;
(2) Performing etching repeatedly with anodized porous aluminum to form the metal mold, and form the microstructure;
(3) Blowing nanoparticles onto the metal mold, to form the microstructure; and
(4) Performing ion-beam treatment, using gas including oxygen, on the base formed of glass-like carbon to form the metal mold, and form the microstructure.
Next, an embodiment of an optical device such as a sensing camera including the optical element according to the present invention will be described. The sensing camera employs the optical element in its optical system.
The light emitter 101 includes a light source 110 such as a laser diode; and an optical system formed of a lens L11 to convert the laser beams into parallel light, and a lens L12. Herein, the lens L12 is an optical element according to the embodiments of the present invention and includes a first lens surface Sur11 and a second lens surface Sur12, on which the microstructures having an antireflection effect are disposed. It is to be noted that the microstructures of the lens L12 are disposed on either of the lens surfaces Sur11 and Sur12.
The light receiver 102 includes a lens L13 to receive the laser beams AR emitted from the light emitter 101 and a sensor 111. The sensor 111, which in the present embodiment is a photodiode, receives the laser beams AR, converts the received laser beams into electrical signals, and transmits the converted data to the optical device.
Herein, the wavelength (use wavelength) of the laser beams which transit the group of lenses of the optical system is 900 nm. The wavelength is not limited only to the above length, and the infrared light having a wavelength of more than 700 nm may be used.
As described above, if the lens L12 employs the optical element according to the present embodiment, the sensing camera can provide an optimal antireflection effect even for the use of wavelength of the infrared light. Accordingly, the sensing camera uses light efficiently.
As described above, if the lens L12 employs the optical element according to the present embodiment, the sensing camera can reduce adverse effect of ghosting, which is a main factor of noise. By effectively suppressing ghosting, the optimal sensing capability is enhanced.
In the embodiments as described above, an example in which the optical element according to the present embodiment is applied to the lens L12 is shown; however, the optical element according to the present embodiment can be applied to the lens L11 or the lens L13. The disposition of the optical system to which the optical element according to the present embodiment is applied is not limited to the above-described example.
Next, another embodiment in which the optical device according to the present invention is applied to a camera device will be described.
The optical system of the camera device is used for an imaging optical system of a single focal length, a projection optical system, or a zoom lens. Specifically, examples of imaging optical system include various camera devices such as a car-mounted camera, video camera, camera monitor, industrial camera, and the like. The projection optical system includes, for example, a projector.
As illustrated in
Herein, the use wavelength range of the camera's optical element is the visible light range (i.e., wavelength of from 450 nm to 700 nm). The wavelength is not limited only to the above. Among the lenses constituting the optical system, the lens L12 is an optical element according to the embodiments of the present invention and includes a lens surface Sur21 and another lens surface Sur22, both having the microstructures having an antireflection effect. The microstructure may be disposed on either the lens surface Sur21 or the lens surface Sur22. The optical element may be applied to a lens other than the lens L12.
According to the camera as described above, use of the optical element according to the present embodiments enables a high antireflection effect corresponding to a wide wavelength.
In the imaging optical system, unnecessary reflected light on the lens surface that is incident to the image plane causes flare and ghosting to occur. In particular, if the face angle of the imaging optical system becomes large, the flare and ghosting tends to occur easily.
Use of the optical element according to the present embodiments that exerts an optimal antireflection effect prevents occurrence of flare and ghosting, thereby providing an optical device having a high optical performance.
Additional modifications and variations of the present invention are possible in light of the above teachings. It is therefore to be understood that, within the scope of the appended claims, the invention may be practiced other than as specifically described herein.
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