Patent Application
20230422567
The present invention relates to an optical film, a display device, and a composition for forming a colored layer.
Self-luminous display devices that include self-luminescent elements such as organic light emitting elements are, unlike liquid crystal display devices and the like, easy to miniaturize and have good characteristics such as low power consumption, high luminance, and high response speed, and thus have potential as next-generation display devices. Electrodes and wires made of metal are provided in a region of the display surface of a self-luminous display device. Thus, light incident on the display screen from the outside (i.e., external light) is reflected by the electrodes or the wires, easily leading to lower display quality such as lower contrast.
In order to solve the above problem, for example, a configuration has been proposed in which a polarizing plate and a phase retardation plate are provided on the surface of a self-luminous display device. However, in the configuration using a polarizing plate and a phase retardation plate, when light emerging from the display device passes through the polarizing plate and the phase retardation plate to the outside, most of the light is lost, easily leading to a shorter life of elements.
Furthermore, display devices are required to have high color purity. Color purity indicates the range of colors that can be displayed by a display device, and is also referred to as a color reproduction range. Thus, high color purity means a large color reproduction range and high color reproducibility. Known methods of achieving higher color reproducibility include a technique in which a light source that emits white light is subjected to color separation using a color filter, and a technique in which a light source that emits monochromatic light in the three primary colors R, G, and B is subjected to correction for a narrow half-value width using a color filter. In order to achieve higher color reproducibility of a display device using a color filter, a color filter having a greater thickness and a higher concentration of colorant material are required, thus leading to lower display quality such as a poor pixel shape or poor viewing angle characteristics. For a display device including a light source that emits monochromatic light in the three primary colors R, G, and B, a process of forming a color filter is required, thus leading to higher cost.
As a display device having a configuration different from the configuration using a polarizing plate and a phase retardation plate or the configuration using a color filter described above, for example, Patent Literature 1 discloses an organic light emitting display device that includes a display substrate including an organic light emitting element, and a sealing substrate provided apart from the display substrate and in which a space between the display substrate and the sealing substrate is filled with a filler that selectively absorbs external light for each wavelength range to adjust the transmittance. In this configuration, reflection of external light is reduced to provide better visibility, and of light emerging from the display device, in particular, light in the wavelength range that leads to lower color purity is selectively absorbed to achieve higher color purity. However, the disclosed technique is insufficient to reduce reflection of external light, and causes coloration of reflected light. Furthermore, colorant materials that absorb light having specific wavelengths have insufficient reliability in terms of light resistance or the like, and are thus difficult to be put into practical use.
The conventional technique as described above has the following problems.
In a device using a polarizing plate and a phase retardation plate, the amount of external light that is reflected can be reduced, but the amount of display light generated by an organic light emitting element is also reduced.
Furthermore, Patent Literature 1 proposes, as the filler having wavelength selective absorption properties disclosed in Patent Literature 1, a configuration containing a colorant having the maximum absorption wavelength in the wavelength region of 480 nm to 510 nm and a colorant having the maximum absorption wavelength in the wavelength region of 580 nm to 610 nm. Thus, it is difficult to remove the influence of external light in the wavelength range of less than 480 nm and the wavelength range of more than 610 nm. Failure in reducing external light in such a wavelength range leads to an insufficient reflectance reduction effect and deterioration in reflection hue.
Furthermore, colorants having wavelength selective absorption properties as described above have insufficient reliability in terms of light resistance or the like, and are thus difficult to be put into practical use unless the reliability of the colorants is improved.
In view of the above circumstances, an object of the present invention is to provide an optical film achieving higher display quality and a longer life of a light emitting element, a display device including the optical film, and a composition for forming a colored layer that is used to produce the film.
In order to solve the above problem, an optical film of a first aspect of the present invention includes a transparent substrate in which an ultraviolet shielding rate in accordance with JIS L 1925 is 85% or more, one or more functional layers arranged to face a first surface of the transparent substrate, and a colored layer including one or more layers and being arranged to face a second surface of the transparent substrate. The colored layer includes one or more layers containing a first colorant material in which a maximum absorption wavelength is in a range of 470 nm or more and 530 nm or less and a half width of an absorption spectrum thereof is 15 nm or more and 45 nm or less, a second colorant material in which a maximum absorption wavelength is in a range of 560 nm or more and 620 nm or less and a half width of an absorption spectrum thereof is 15 nm or more and 55 nm or less, and a third colorant material in which in a wavelength range of 400 nm to 780 nm, a wavelength at which a transmittance is lowest is in a range of 650 nm or more and 780 nm or less, and each of chromaticness indexes a* and b* of a reflection hue of the optical film that are defined by the following formulas (1) to (9) is in a range from −5 to +5 inclusive. The values a* and b* are calculated from a reflectance R (λ), where the reflectance R (λ) is the reflectance of the optical film on the side of the optical film irradiated with illuminant D65 light from the side closest to an outermost surface of the one or more functional layers in the thickness direction, and a reflectance RE (λ) of a lowermost layer portion of the colored layer is 100% at all wavelengths in a wavelength range of 380 nm to 780 nm.
In this case, λ is a variable representing a wavelength, and t is a variable representing a ratio of X, Y, and Z to Xn, Yn, and Zn, respectively.
The values a* and b* calculated from the formulas (1) to (3) are calculated according to a calculation method for a CIE 1976 L*a*b* color space, which is a CIELAB color space. In the formulas (1) and (2), Xn, Yn, and Zn are tristimulus values at a white point of illuminant D65.
In the formula (4), RE (λ) is a function representing a reflectance [%] of a perfect reflecting diffuser, which is 100% at each wavelength, R2 (λ) is a function representing a surface reflectance [%] of an outermost surface of the one or more functional layers, and T (λ) is a function representing a transmittance [%] of the optical film.
In the formula (6) to (9), PD65 (λ) is an illuminant D65 spectrum, and
The definite integrals in formulas (6) to (9) are obtained by appropriate numerical integration. The numerical integration is performed at a wavelength interval of, for example, 1 nm.
In the formula (5), R (λ) represents the reflectance of the optical film for incident light from the side most distant from the colored layer, considering internal reflection in the transparent substrate of the optical film.
X, Y, and Z given by the formulas (6) to (8) are tristimulus values at a white point of illuminant D65.
A display device of a second aspect of the present invention includes a light source, and the optical film.
A composition for forming a colored layer of a third aspect of the present invention includes an active energy ray-curable resin, a photopolymerization initiator, a colorant, an additive, and a solvent, wherein the colorant contains a third colorant material and at least one of a first colorant material and a second colorant material, the colorant does not contain a dye having a main absorption wavelength range in a wavelength range of 390 to 435 nm, and the additive contains at least one of a radical scavenger, a peroxide decomposer, and a singlet oxygen quencher. In the first colorant material, a maximum absorption wavelength is in a range of 470 nm or more and 530 nm or less and a half width of an absorption spectrum thereof is 15 nm or more and 45 nm or less. In the second colorant material, a maximum absorption wavelength is in a range of 560 nm or more and 620 nm or less and a half width of an absorption spectrum thereof is 15 nm or more and 55 nm or less. In the third colorant material, in a wavelength range of 400 nm to 780 nm, a wavelength at which a transmittance is lowest is in a range of 650 nm or more and 780 nm or less.
The present invention provides an optical film, a display device, and a composition for forming a colored layer that achieve higher display quality by reducing external light reflection and a longer life of a light emitting element of the display device.
Embodiments of the present invention will be described with reference to the accompanying drawings. Throughout the drawings, even in different embodiments, the same or corresponding members are denoted by the same reference signs, and common description is omitted.
An optical film and a display device according to a first embodiment of the present invention will be described.
A display device 50A of the present embodiment whose cross section in the thickness direction is shown in
The display unit 20 includes a substrate 21, light emitting elements 22, and a color filter module 23.
The substrate 21 is composed of, for example, a silicon substrate.
The light emitting elements 22 emit white light. The light emitting elements 22 may be, for example, organic EL (electroluminescent) devices. In an organic EL device, a direct-current voltage is applied between an anode and a cathode to cause an electron and a positive hole to be injected into an organic light emitting layer and recombined to form an exciton, and light generated when the exciton is deactivated is used to emit light. Light from the light emitting elements 22 is emitted in a light emission direction from the lower side toward the upper side of
The light emitting elements 22 are produced on the substrate 21, for example, using a semiconductor manufacturing process.
An electrode of each of the light emitting elements 22 is connected to a driving circuit (not shown) through a metal wire provided on the substrate 21. The driving circuit controls the ON and OFF states of the light emitting elements 22 based on an image signal.
Each pixel that performs color display includes, as the light emitting elements 22, for example, a first light emitting element 22R that is turned on according to an image signal of a red component, a second light emitting element 22G that is turned on according to an image signal of a green component, and a third light emitting element 22B that is turned on according to an image signal of a blue component.
The color filter module 23 is provided in the light emission direction of each of the light emitting elements 22.
The color filter module 23 includes red filters that allow red light to pass through, green filters that allow green light to pass through, and blue filters that allow blue light to pass through. The red filters are provided to face the first light emitting elements 22R, the green filters are provided to face the second light emitting elements 22G, and the blue filters are provided to face the third light emitting elements 22B.
The color filter module 23 may include a lens that collects light passing through each of the red filters, the green filters, and the blue filters.
The optical film 10A of the present embodiment is laminated on the color filter module 23 of the display unit 20. The optical film 10A is used to provide higher color purity in a display region of the display unit 20 to prevent lower display quality due to external light reflection.
The optical film 10A includes a colored layer 12, a transparent substrate 11, a hard coat layer 13, and a low refractive index layer 14A in this order in the light emission direction of the display unit 20.
The transparent substrate 11 is a plate or a sheet that has a first surface 11a and a second surface 11b in the thickness direction. The second surface 11b of the transparent substrate 11 is arranged to face the color filter module 23 of the display unit 20 while the colored layer 12 is located between the color filter module 23 and the transparent substrate 11. It is preferable that the transmittance of the material of the transparent substrate 11 to visible light be as close to 100% as possible. Visible light is light in the visible light wavelength range of 380 nm or more and 780 nm or less.
The transparent substrate 11 has an ultraviolet absorption function with an ultraviolet shielding rate of 85% or more, and functions as an ultraviolet absorption layer for protecting a colorant contained in the colored layer 12 from ultraviolet light. The ultraviolet shielding rate is measured and calculated based on JIS L 1925, and is represented by a value [%] obtained by subtracting, from 100%, the average transmittance (unit: [%]) in the wavelength range of 290 nm to 400 nm.
The material of the transparent substrate 11 may be a transparent resin or inorganic glass such as polyolefin such as polyethylene or polypropylene, polyester such as polybutylene terephthalate or polyethylene naphthalate, polyacrylate such as polymethyl methacrylate, polyamide such as nylon 6 or nylon 66, polyimide, polyarylate, polycarbonate, triacetyl cellulose, polyvinyl alcohol, polyvinyl chloride, cycloolefin copolymer, norbornene-containing resin, polyether sulfone, or polysulphone. Of these, a film made of polyethylene terephthalate (PET), a film made of triacetyl cellulose (TAC), a film made of polymethyl methacrylate (PMMA), and a film made of polyester are preferable. The thickness of the transparent substrate 11 is not particularly limited, but is preferably 10 μm to 100 μm.
Ultraviolet absorption properties can be imparted to the transparent substrate 11, for example, by adding an ultraviolet absorber to a resin material for forming the transparent substrate 11. The material used as an ultraviolet absorber is not particularly limited, but may be a benzophenone-based, a benzotriazole-based, a triazine-based, an oxalic acid anilide-based, or a cyanoacrylate-based compound.
The colored layer 12 is a layer portion containing a colorant, and is provided on the second surface 11b of the transparent substrate 11 to overlap with the transparent substrate 11. Thus, the colored layer 12 is located between the color filter module 23 of the display unit 20 and the transparent substrate 11.
The colored layer 12 contains, as a colorant, a first colorant material, a second colorant material, and a third colorant material.
In the first colorant material, the maximum absorption wavelength is in the range of 470 nm or more and 530 nm or less, and the half width (full width at half maximum) of the absorption spectrum thereof is 15 nm or more and 45 nm or less. The maximum absorption wavelength indicates a wavelength at which the highest maximum absorbance is obtained in an absorbance spectrum (absorption spectrum). In a transmittance spectrum, this wavelength indicates a wavelength at which the lowest minimum transmittance is obtained. The same applies to the following description.
In the second colorant material, the maximum absorption wavelength is in the range of 560 nm or more and 620 nm or less, and the half width of the absorption spectrum thereof is 15 nm or more and 55 nm or less.
In the third colorant material, a wavelength in the wavelength range of 400 to 780 nm at which the transmittance is lowest is in the range of 650 nm or more and 780 nm or less. In the third colorant material, the half width of the absorption spectrum is, for example, 10 nm or more and 300 nm or less, but is not particularly limited.
Hereinafter, the first colorant material, the second colorant material, and the third colorant material may be collectively referred to as simply a colorant material.
The first colorant material, the second colorant material, and the third colorant material contained in the colored layer 12 may contain one or more compounds selected from the group consisting of a compound having a porphyrin structure, a compound having a merocyanine structure, a compound having a phthalocyanine structure, a compound having an azo structure, a compound having a cyanine structure, a compound having a squarylium structure, a compound having a coumarin structure, a compound having a polyene structure, a compound having a quinone structure, a compound having a tetraazaporphyrin structure, a compound having a pyrromethene structure, a compound having an indigo structure, and metal complexes thereof. The first colorant material, the second colorant material, and the third colorant material particularly preferably contain, for example, a compound having a porphyrin structure, a pyrromethene structure, a phthalocyanine structure, or a squarylium structure in the molecules.
The colored layer 12 of the present embodiment does not contain a dye having a main absorption wavelength range in the wavelength range of 390 to 435 nm.
The colored layer 12 may contain a dye having a main absorption wavelength range in the wavelength range of 390 to 435 nm. However, a dye having a main absorption wavelength range in the wavelength range of 390 to 435 nm does not have a function of providing higher reliability such as higher light resistance and heat resistance, although such a function is intended by the present invention. Thus, the colored layer 12 may contain a dye having a main absorption wavelength range in the wavelength range of 390 to 435 nm simply in order to adjust the color characteristics of the colored layer 12. Furthermore, the transparent substrate 11 above the colored layer 12 may contain a dye having a main absorption wavelength range in the wavelength range of 390 to 435 nm in order to allow the colored layer 12 to have higher reliability.
In the optical film 10A of the present invention, each of chromaticness indexes (values) a* and b* of a reflection hue of the optical film represented by the formulas (1) to (9) is in the range from −5 to +5 inclusive, where a reflectance R (λ) is the reflectance of the optical film measured from the side closest to a surface 10a which is the outermost surface of functional layers, the hard coat layer 13 and the low refractive index layer 14A, on the side of the optical film closest to the first surface 11a of the transparent substrate 11 when the optical film 10A is irradiated with illuminant D65 light from the side closest to the surface 10a, and the light is perfectly diffusely reflected on the side closest to a lowermost surface 10b of the optical film. The hue is represented by a three-dimensional orthogonal coordinate system with axes representing three values: the value represented by the formula (1), the value represented by the formula (2), and a lightness index L* represented by the following formula (10). The three-dimensional orthogonal coordinate system is a uniform color space defined by the International Commission on Illumination (CIE) (also referred to as CIE 1976 L*a*b* color space or CIELAB color space).
In this case, Y is a tristimulus value for reflected light with the reflectance R (λ) for illuminant D65, and is calculated from the formulas (4), (5), (7) and (9), and Yn is a tristimulus value at the white point of illuminant D65.
The method of calculating the chromaticness indexes a* and b* as indicators of an external light reflection hue of the optical film of the present invention will be described in detail with reference to
When the optical film 10A is irradiated with illuminant D65 light from the surface 10a which is the outermost surface of the functional layers of the optical film 10A in the thickness direction, light emerging from the optical film 10A can be divided into a surface reflection component and an internal reflection component. The surface reflection component is defined by R2 (λ) [%], which is the surface reflectance of the surface 10a. The internal reflection component is defined by R1 (λ) [%] calculated from the formula (4) using a reflectance RE (λ) [%] of a perfect reflecting diffuser, which is 100% irrespective of the wavelength, a transmittance T (λ) of the optical film 10A, and the surface reflectance R2 (λ) [%] of the surface 10a.
R (λ) [%] is calculated from the formula (5), where R (λ) is the reflectance of the optical film 10A on the side closest to the surface 10a irradiated with illuminant D65 light.
R (λ) is a function of wavelength λ as with R1 (λ) and R2 (λ), and thus tristimulus values X, Y, and Z are determined by calculating definite integrals fork in the formulas (6) to (9). The definite integrals may be obtained by appropriate numerical integration. For example, the numerical integration may be performed at a wavelength interval such as an equal interval of, for example, 1 nm.
As described above, X, Y, and Z in the formulas (1) and (2) are the tristimulus values for reflected light with the reflectance R (λ) for illuminant D65 of the optical film 10A on the side closest to the surface 10a, and Xn, Yn, and Zn represent the tristimulus values at the white point of illuminant D65. These values can be used to calculate the chromaticness indexes a* and b* as the indicators of the external light reflection hue of the optical film 10A. Each of the chromaticness indexes (values) a* and b* of the external light reflection hue of the optical film 10A is preferably in the range from −5 to +5 inclusive from the viewpoint of achieving higher display quality by reducing external light reflection. The internal reflectance for light reflected by an internal surface such as a display unit or an electrode wiring portion of a self-luminous display device such as an organic light emitting display device typically has different values at wavelengths in the wavelength range of 380 nm to 780 nm. However, as a result of intensive study, the inventors of the present invention have found that when each of the chromaticness indexes (values) a* and b* of the external light reflection hue of the optical film 10A is in the range from −5 to +5 inclusive, and RE (λ) as the reflectance of a perfect reflecting diffuser, which is 100% at all wavelengths, is substituted with the internal reflectance of the display unit 20 of an actual self-luminous display device, the chromaticness indexes a* and b* as the indicators of the external light reflection hue are in the range from −5 to +5 inclusive, achieving high display quality.
The colored layer 12 having such a configuration has, as a whole, the maximum absorption wavelength, that is, the minimum transmittance, in the range of 470 nm or more and 530 nm or less and in the range of 560 nm or more and 620 nm or less, and further contains the third colorant material in which the maximum absorption in the range of 400 nm to 780 nm is in the range of 650 nm or more and 780 nm or less, thus achieving a spectral absorption spectrum having the minimum absorption wavelength, that is, the maximum transmittance, in the range of 620 nm to 780 nm. This allows most of red light, green light, and blue light emerging from the display unit 20 to pass through the colored layer 12.
On the other hand, the colored layer 12 reduces the amount of transmitted light for part of each of a wavelength component between the maximum wavelength of red light and the maximum wavelength of green light, a wavelength component between the maximum wavelength of green light and the maximum wavelength of blue light, ultraviolet light, and infrared light. Thus, for example, of reflected light of external light reflected by the wire or the like of the display unit 20, a wavelength component that reduces the color purity for display light is absorbed by the colored layer 12.
The colored layer 12 may contain, as an additive, at least one of a radical scavenger, a peroxide decomposer, and a singlet oxygen quencher. When the colored layer 12 contains such an additive, as described below, it is possible to prevent the colorant materials contained in the colored layer 12 from fading due to light, heat, or the like, thus achieving higher durability.
For example, a radical scavenger serves to prevent autooxidation by capturing radicals when oxidative degradation of a colorant occurs, and prevents deterioration (fading) of the colorant. When the colored layer 12 contains, as a radical scavenger, a hindered amine light stabilizer having a molecular weight of 2,000 or more, the colored layer 12 has a high fading prevention effect. If the colored layer 12 contains a radical scavenger having a small molecular weight, which easily evaporates, only a small number of molecules remain in the colored layer, making it difficult for the colored layer 12 to have a sufficient fading prevention effect. A material suitable as a radical scavenger is, for example, Chimassorb (registered trademark) 2020 FDL, Chimassorb (registered trademark) 944 FDL, or Tinuvin (registered trademark) 622 manufactured by BASF, or LA-63P manufactured by Adeka Corporation.
A peroxide decomposer serves to decompose a peroxide generated when oxidative degradation of a colorant occurs, and stop the autooxidation cycle to prevent deterioration (fading) of the colorant. A peroxide decomposer may be a phosphorus-based antioxidant or a sulfur-based antioxidant.
Examples of a phosphorus-based antioxidant include 2,2′-methylenebis(4,6-di-t-butyl-1-phenyloxy)(2-ethylhexyloxy)phosphorus, 3,9-bis(2,6-di-tert-butyl-4-methylphenoxy)-2,4,8,10-tetraoxa-3,9-diphosphaspiro[5.5]undecane, and 6-[3-(3-t-butyl-4-hydroxy-5-methylphenyl)propoxy]-2,4,8,10-tetra-t-butyldibenz[d,f][1,3,2]dioxaphosphepine.
Examples of a sulfur-based antioxidant include 2,2-bis({[3-(dodecylthio)propionyl]oxy}methyl)-1,3-propanediyl-bis[3-(dodecylthio)propionate], 2-mercaptobenzimidazole, dilauryl-3,3′-thiodipropionate, dimyristyl-3,3′-thiodipropionate, distearyl-3,3′-thiodipropionate, pentaerythrityl-tetrakis(3-laurylthiopropionate), and 2-mercaptobenzothiazole.
A singlet oxygen quencher serves to inactivate highly reactive singlet oxygen that easily causes oxidative degradation (fading) of a colorant, to prevent oxidative degradation (fading) of the colorant. Examples of a singlet oxygen quencher include transition metal complexes, colorants, amines, phenols, and sulfides. A material particularly suitable as a singlet oxygen quencher is a transition metal complex of dialkyl phosphate, dialkyl dithiocarbamate, or benzenedithiol, and a material suitable as a central metal is nickel, copper, or cobalt. The singlet oxygen quencher may be, for example, NKX1199, NKX113, or NKX114 manufactured by Hayashibara Biochemical Laboratories, Inc., Research Institute for Photosensitizing Dyes, or D1781, B1350, B4360, or T3204 manufactured by Tokyo Chemical Industry Co., Ltd.
The colorant materials contained in the colored layer 12 have a good color correction function, but have insufficient resistance to light, particularly ultraviolet light. Thus, when the colorant materials are irradiated with ultraviolet light, the colorant materials deteriorate with time and can no longer absorb light having a wavelength near the maximum absorption wavelength.
In the present embodiment, the optical film 10A includes the transparent substrate 11 having an ultraviolet shielding rate of 85% or more provided so that external light arrives at the transparent substrate 11 before the colored layer 12, thus reducing the amount of ultraviolet light contained in external light that enters the colored layer 12. This allows the colored layer 12 to have higher resistance to ultraviolet light.
In the example shown in
The optical film 10A may include the hard coat layer 13 as a functional layer of the present embodiment. The hard coat layer 13 is a layer portion that protects the transparent substrate 11 from external force and that allows light to pass through. The hard coat layer 13 preferably has a visible light transmittance close to 100%.
The optical film 10A including the hard coat layer 13 has, as a surface hardness, a pencil hardness of H or more at a load of 500 gf (4.9 N) (hereinafter, a load of 500 g). The pencil hardness is measured based on JIS-K5600-5-4: 1999.
The hard coat layer 13 is formed by applying and drying a composition containing an active energy ray-curable resin, a photopolymerization initiator, and a solvent, followed by irradiation with an energy ray such as ultraviolet light to cure the composition.
An active energy ray-curable resin is a resin that is polymerized and cured by irradiation with an active energy ray such as ultraviolet light or an electron beam, and the material used as an active energy ray-curable resin may be, for example, monofunctional, bifunctional, or tri- or higher functional (meth)acrylate monomer. Herein, “(meth)acrylate” collectively refers to both acrylate and methacrylate, and “(meth)acryloyl” collectively refers to both acryloyl and methacryloyl.
Examples of a monofunctional (meth)acrylate compound include 2-hydroxyethyl (meth)acrylate, 2-hydroxypropyl (meth)acrylate, 2-hydroxybutyl (meth)acrylate, n-butyl (meth)acrylate, isobutyl (meth)acrylate, t-butyl (meth)acrylate, glycidyl (meth)acrylate, acryloylmorpholine, N-vinylpyrrolidone, tetrahydrofurfuryl acrylate, cyclohexyl (meth)acrylate, 2-ethyl hexyl (meth)acrylate, isobornyl (meth)acrylate, isodecyl (meth)acrylate, lauryl (meth)acrylate, tridecyl (meth)acrylate, cetyl (meth)acrylate, stearyl (meth)acrylate, benzyl (meth)acrylate, 2-ethoxyethyl (meth)acrylate, 3-methoxybutyl (meth)acrylate, ethyl carbitol (meth)acrylate, phosphoric acid (meth)acrylate, ethylene oxide-modified phosphoric acid (meth)acrylate, phenoxy (meth)acrylate, ethylene oxide-modified phenoxy (meth)acrylate, propylene oxide-modified phenoxy (meth)acrylate, nonylphenol (meth)acrylate, ethylene oxide-modified nonylphenol (meth)acrylate, propylene oxide-modified nonylphenol (meth)acrylate, methoxy diethylene glycol (meth)acrylate, methoxy polyethylene glycol (meth)acrylate, methoxy propylene glycol (meth)acrylate, 2-(meth)acryloyl oxyethyl-2-hydroxypropyl phthalate, 2-hydroxy-3-phenoxy propyl (meth)acrylate, 2-(meth)acryloyl oxyethyl hydrogen phthalate, 2-(meth)acryloyl oxypropyl hydrogen phthalate, 2-(meth)acryloyl oxypropyl hexahydro hydrogen phthalate, 2-(meth)acryloyl oxypropyl tetrahydro hydrogen phthalate, dimethylaminoethyl (meth)acrylate, trifluoroethyl (meth)acrylate, tetrafluoropropyl (meth)acrylate, hexafluoropropyl (meth)acrylate, octafluoropropyl (meth)acrylate, and adamantane derivative mono(meth)acrylates such as adamantyl acrylate having a monovalent mono(meth)acrylate derived from 2-adamantane or adamantane diol.
Examples of a bifunctional (meth)acrylate compound include di(meth)acrylates such as ethylene glycol di(meth)acrylate, diethylene glycol di(meth)acrylate, butanediol di(meth)acrylate, hexanediol di(meth)acrylate, nonanediol di(meth)acrylate, ethoxylated hexanediol di(meth)acrylate, propoxylated hexanediol di(meth)acrylate, diethylene glycol di(meth)acrylate, polyethylene glycol di(meth)acrylate, tripropylene glycol di(meth)acrylate, polypropylene glycol di(meth)acrylate, neopentyl glycol di(meth)acrylate, ethoxylated neopentyl glycol di(meth)acrylate, tripropylene glycol di(meth)acrylate, and hydroxypivalic acid neopentyl glycol di(meth)acrylate.
Examples of a tri- or higher functional (meth)acrylate compound include tri(meth)acrylates such as trimethylolpropane tri(meth)acrylate, ethoxylated trimethylolpropane tri(meth)acrylate, propoxylated trimethylolpropane tri(meth)acrylate, tris 2-hydroxyethyl isocyanurate tri(meth)acrylate, and glycerin tri(meth)acrylate, trifunctional (meth)acrylate compounds such as pentaerythritol tri(meth)acrylate, dipentaerythritol tri(meth)acrylate, and ditrimethylolpropane tri(meth)acrylate, tri- or higher functional polyfunctional (meth)acrylate compounds such as pentaerythritol tetra(meth)acrylate, ditrimethylolpropane tetra(meth)acrylate, dipentaerythritol tetra(meth)acrylate, dipentaerythritol penta(meth)acrylate, ditrimethylolpropane penta(meth)acrylate, dipentaerythritol hexa(meth)acrylate, and ditrimethylolpropane hexa(meth)acrylate, and polyfunctional (meth)acrylate compounds obtained by substituting part of any of these (meth)acrylates with an alkyl group or ε-caprolactone.
As an active energy ray-curable resin, a urethane (meth)acrylate may be used. The urethane (meth)acrylate may be obtained, for example, by reacting a (meth)acrylate monomer having a hydroxyl group with a product obtained by reacting an isocyanate monomer or a prepolymer with a polyester polyol.
Examples of the urethane (meth)acrylate include pentaerythritol triacrylate hexamethylene diisocyanate urethane prepolymer, dipentaerythritol pentaacrylate hexamethylene diisocyanate urethane prepolymer, pentaerythritol triacrylate toluene diisocyanate urethane prepolymer, dipentaerythritol pentaacrylate toluene diisocyanate urethane prepolymer, pentaerythritol triacrylate isophorone diisocyanate urethane prepolymer, and dipentaerythritol pentaacrylate isophorone diisocyanate urethane prepolymer.
The above active energy ray-curable resins may be used singly or in combination of two or more. The above active energy ray-curable resins may be monomers or partially polymerized oligomers in the composition for forming a hard coat layer.
The composition for forming a hard coat layer may contain any photopolymerization initiator that generates radicals when irradiated with ultraviolet light. Specific examples of such a photopolymerization initiator include an acetophenone compound, a benzoin compound, a benzophenone compound, an oxime ester compound, a thioxanthone compound, a triazine compound, a phosphine compound, a quinone compound, a borate compound, a carbazole compound, an imidazole compound, and a titanocene compound. The composition for forming a hard coat layer may contain, as a photopolymerization initiator, for example, 2,2-ethoxyacetophenone, 1-hydroxycyclohexyl phenyl ketone, dibenzoyl, benzoin, benzoin methyl ether, benzoin ethyl ether, p-chlorobenzophenone, p-methoxybenzophenone, Michler's ketone, acetophenone, 2-chlorothioxanthone, diphenyl(2,4,6-trimethylbenzoyl) phosphine oxide, or phenylbis(2,4,6-trimethylbenzoyl) phosphine oxide. These materials may be used singly or in combination of two or more.
Examples of a solvent contained in the composition for forming a hard coat layer include ethers such as dibutyl ether, dimethoxymethane, dimethoxyethane, diethoxyethane, propylene oxide, 1,4-dioxane, 1,3-dioxolane, 1,3,5-trioxane, tetrahydrofuran, anisole, and phenetole, ketones such as acetone, methyl ethyl ketone, diethyl ketone, dipropyl ketone, diisobutyl ketone, methyl isobutyl ketone, cyclopentanone, cyclohexanone, methylcyclohexanone, and methylcyclohexanone, esters such as ethyl formate, propyl formate, n-pentyl formate, methyl acetate, ethyl acetate, methyl propionate, ethyl propionate, n-pentyl acetate, and γ-butyrolactone, and cellosolves such as methyl cellosolve, cellosolve, butyl cellosolve, and cellosolve acetate. These materials may be used singly or in combination of two or more.
In order to adjust the refractive index of the hard coat layer 13 and to impart hardness to the hard coat layer 13, the composition for forming the hard coat layer 13 may contain metal oxide fine particles. Examples of metal oxide fine particles include fine particles of zirconium oxide, titanium oxide, niobium oxide, antimony trioxide, antimony pentoxide, tin oxide, indium oxide, indium tin oxide, and zinc oxide.
In order to impart at least one of water repellency and oil repellency to the hard coat layer 13 to achieve higher antifouling properties, the composition for forming the hard coat layer 13 may contain any of a silicon oxide, a fluorine-containing silane compound, fluoroalkylsilazane, fluoroalkylsilane, a fluorine-containing silicon compound, and a perfluoropolyether group-containing silane coupling agent.
The composition for forming the hard coat layer 13 may further contain, as other additives, a leveling agent, an antifoaming agent, a photosensitizer, a conductive material such as quaternary ammonium cations or conductive metal fine particles, and the like. The conductive material imparts antistatic properties to the optical film.
The optical film 10A may include the low refractive index layer 14A as a functional layer of the present embodiment. In the optical film 10A applied to the display device 50A, the low refractive index layer 14A is located closest to a user (viewer) who views a display. In the present embodiment, the low refractive index layer 14A is laminated on the surface of the hard coat layer 13 facing away from the transparent substrate 11. The thickness of the low refractive index layer 14A is not particularly limited, but is preferably 40 nm to 1 μm.
The low refractive index layer 14A is made of a material having a lower refractive index than the hard coat layer 13. Thus, interference occurs between reflected light of external light entering from the outside that is reflected by the interface between the hard coat layer 13 and the low refractive index layer 14A and reflected light reflected by the surface of the low refractive index layer 14A, achieving a lower surface reflectance for external light.
The low refractive index layer 14A can reduce surface reflection of external light, achieving better visibility of the display device 50A.
The low refractive index layer 14A is a layer portion made of an inorganic material or an inorganic compound. The inorganic material or inorganic compound may be, for example, fine particles of LiF, MgF, 3NaF·AlF, AlF, or Na3AlF6, silica fine particles, or the like. As silica fine particles, fine particles having voids inside the particles such as porous silica fine particles or hollow silica fine particles are effective to allow the low refractive index layer 14A to have a low refractive index. A composition for forming the low refractive index layer 14A may appropriately contain, in addition to an inorganic material or an inorganic compound, any of the materials described as an active energy ray-curable resin, a photopolymerization initiator, a solvent, and other additives for the hard coat layer 13.
The composition for forming the low refractive index layer 14A may contain any of a silicon oxide, a fluorine-containing silane compound, fluoroalkylsilazane, fluoroalkylsilane, a fluorine-containing silicon compound, and a perfluoropolyether group-containing silane coupling agent. Such a material can impart at least one of water repellency and oil repellency to the low refractive index layer 14A, achieving higher antifouling properties.
The colored layer 12 is a layer portion composed of one or more layers that are provided on the side of the transparent substrate 11 closest to the second surface 11b. A composition for forming the colored layer 12 contains an active energy ray-curable resin, a photopolymerization initiator, a colorant, an additive, and a solvent. The composition for forming the colored layer 12 may contain any of the materials described as an active energy ray-curable resin, a photopolymerization initiator, and a solvent for the hard coat layer 13.
The composition for forming the colored layer 12 contains, as a colorant, the third colorant material and at least one of the first colorant material and the second colorant material described above. The composition for forming the colored layer 12 contains, as an additive, at least one of a radical scavenger, a peroxide decomposer, and a singlet oxygen quencher.
The optical film 10A can be produced by forming the colored layer 12 on the second surface 11b of the transparent substrate 11, and forming, on the first surface 11a of the transparent substrate 11, the hard coat layer 13 and the low refractive index layer 14A in this order. However, the order in which the colored layer 12 and the two layers, the hard coat layer 13 and the low refractive index layer 14A, are formed is not particularly limited. The optical film 10A may be produced, for example, by first forming the colored layer 12 and then forming the hard coat layer 13 and the low refractive index layer 14A, or by first forming the hard coat layer 13 and the low refractive index layer 14A and then forming the colored layer 12. The colored layer 12, the hard coat layer 13, and the low refractive index layer 14A can each be formed, for example, by applying and drying a corresponding one of coating liquids each containing the constituent materials of a respective one of the layers, followed by irradiation with an active energy ray such as ultraviolet light to cure the coating liquid. Other than this method, the low refractive index layer 14A can also be formed, for example, by vapor deposition, sputtering, or the like.
The optical film 10A of the present embodiment may include another appropriate functional layer on the side of the optical film closest to the first surface 11a of the transparent substrate 11 as long as the optical film 10A can achieve the necessary frontal luminance, external light reflection visibility, and color purity for display light.
The display device 50A can be produced by preparing the display unit 20, and bonding and fixing the colored layer 12 of the optical film 10A to a surface of the color filter module 23 via an adhesive layer or the like.
In the display device 50A of the present embodiment, when the light emitting elements 22 are turned on according to an image signal, display light generated by the light emitting elements 22 passes through the color filter module 23. Thus, light from the first light emitting elements 22R, light from the second light emitting elements 22G, and light from the third light emitting elements 22B pass, as red light, green light, and blue light, respectively, through the colored layer 12, the transparent substrate 11, the hard coat layer 13, and the low refractive index layer 14A to the outside of the optical film 10A.
In this case, the colored layer 12 has a good transmittance to light with red, green, and blue wavelengths in the display light, and thus can prevent a reduction in luminance of the display light in each color, achieving higher color purity for the display light in each color. The transparent substrate 11 mainly absorbs light in the ultraviolet region, and thus allows the display light to pass through with almost no reduction in luminance. The low refractive index layer 14A has a good transmittance to visible light, and thus allows the display light to pass through to the outside with almost no reduction in luminance.
On the other hand, external light enters the display device 50A through the optical film 10A.
The low refractive index layer 14A reduces the surface reflectance for external light, and thus prevents poor visibility due to excessive surface reflection of the external light.
When the external light enters the transparent substrate 11, a wavelength component in the ultraviolet region of the external light is absorbed by the transparent substrate 11, and then the external light enters the colored layer 12.
The colored layer 12 further absorbs wavelength components of the external light near the absorption wavelengths of the colorant materials contained in the colored layer 12. Then, the external light passes through the color filter module 23, and reaches the substrate 21. The substrate 21 includes, for example, metal portions having a high reflectance such as a wire and an electrode.
Thus, the external light is reflected by the wire, the electrode, or the like, and sequentially passes through the color filter module 23, the colored layer 12, the transparent substrate 11, the hard coat layer 13, and the low refractive index layer 14A to the outside.
An observer of the display device 50A observes, in addition to display light, reflected light obtained by combining surface reflected light of external light from the display device 50A and internal reflected light of external light transmitted through and reflected by internal portions of the display device 50A.
In the present embodiment, external light passes through the colored layer 12 twice to the outside to reduce a wavelength component different from the wavelength component of display light; thus, it is possible to prevent a reduction in luminance of display light while reducing internal reflection of external light, achieving higher color purity for display light.
Even while the display device 50A performs no display, when the chromaticness indexes a* and b* as the indicators of the external light reflection hue of the optical film 10A are from −5 to +5 inclusive, the influence of the color of the optical film is small, and thus the blackness of the display screen is maintained.
In the present embodiment, the transparent substrate 11 absorbs ultraviolet light components of external light, preventing deterioration of the colorant materials when the colored layer 12 is irradiated with ultraviolet light. Thus, the spectral characteristics of the colorant materials of the colored layer 12 are more likely to be maintained with time.
An optical film and a display device according to a second embodiment of the present invention will be described.
A display device 50C of the present embodiment whose cross section in the thickness direction is shown in
The optical film 10C has the same configuration as the optical film 10A except that the optical film 10C includes an oxygen barrier layer 16 between the transparent substrate 11 and the hard coat layer 13.
The following description will focus on differences from the first embodiment.
The oxygen barrier layer 16 is a transparent layer that allows light to pass through. The oxygen barrier layer 16 has an oxygen permeability of 10 cc/m2·day·atm or less. The main constituent material of the oxygen barrier layer 16 is preferably polyvinyl alcohol (PVA), ethylene-vinyl alcohol copolymer (EVOH), vinylidene chloride, siloxane resin, or the like, and may be, for example, Maxive (registered trademark) manufactured by Mitsubishi Gas Chemical Company, Inc., EVAL (registered trademark) or Poval manufactured by Kuraray Co., Ltd., or Saran latex (registered trademark) or Saran (registered trademark) resin manufactured by Asahi Kasei Corporation. In the oxygen barrier layer 16, inorganic particles such as silica particles, alumina particles, silver particles, copper particles, titanium particles, zirconia particles, or tin particles may be dispersed to reduce the oxygen permeability.
When the optical film 10C is attached to the display device 50C, oxygen contained in the outside air would have to pass through the oxygen barrier layer 16 to reach the colored layer 12. This prevents deterioration of the colorant materials of the colored layer 12 due to light or heat with the involvement of oxygen in the outside air. Thus, the light absorption performance of the colored layer 12 is maintained for a long time.
The oxygen barrier layer 16 of the present embodiment may be placed in an appropriate portion of the optical film 10C in which the entry of oxygen is to be prevented.
For example, in order to prevent the entry of oxygen from the outside of the display device 50C into the colored layer 12, the oxygen barrier layer 16 may be placed between the appropriate members or layers located closer to the outer side of the optical film 10C than the colored layer 12.
For example, in order to prevent the entry of oxygen from the side of the display device 50C closest to the display unit 20 into the colored layer 12, the oxygen barrier layer 16 may also be placed between the color filter module 23 and the colored layer 12.
The optical film 10C and the display device 50C of the present embodiment include the colored layer 12, the hard coat layer 13, and the low refractive index layer 14A as in the first embodiment, and thus have the same effects as in the first embodiment.
In particular, the optical film 10C of the present embodiment further includes the oxygen barrier layer 16, and can thus prevent oxidative degradation of the colorant of the colored layer 12 due to light or heat under the influence of oxygen.
An optical film and a display device according to a third embodiment of the present invention will be described.
A display device 50D of the present embodiment whose cross section in the thickness direction is shown in
The optical film 10D has the same configuration as the optical film 10A except that the optical film 10D includes an antiglare layer 17 instead of the low refractive index layer 14A and the hard coat layer 13.
The following description will focus on differences from the first embodiment.
The antiglare layer 17 is a layer portion having an antiglare function.
The antiglare function is a function of scattering external light using a fine uneven structure on the surface to reduce glare due to external light. The surface of the optical film 10D including the antiglare layer 17 has a pencil hardness of H or more as in the first embodiment.
The antiglare layer 17 can be formed by curing a coating liquid containing the same composition as the composition for forming the hard coat layer 13 and at least organic fine particles or inorganic fine particles that impart an antiglare function. The organic fine particles are to form a fine uneven structure on the surface of the antiglare layer 17 to impart a function of diffusing external light, and may be, for example, resin particles of an optically transmissive resin material such as an acrylic resin, a polystyrene resin, a styrene-(meth)acrylic ester copolymer, a polyethylene resin, an epoxy resin, a silicone resin, a polyvinylidene fluoride, or a polyethylene fluoride resin. The organic fine particles may be a mixture of two or more types of resin particles of different materials (with different refractive indexes) in order to adjust the refractive index and the dispersibility of the resin particles. The inorganic fine particles are to adjust the precipitation and aggregation of the organic fine particles in the antiglare layer 17, and may be silica fine particles, metal oxide fine particles, various mineral fine particles, or the like. The silica fine particles may be, for example, silica fine particles surface-modified with a reactive functional group such as colloidal silica or a (meth)acryloyl group. The metal oxide fine particles may be fine particles of, for example, alumina, zinc oxide, tin oxide, antimony oxide, indium oxide, titania, zirconia, or the like. The mineral fine particles may be fine particles of, for example, mica, synthetic mica, vermiculite, montmorillonite, iron montmorillonite, bentonite, beidellite, saponite, hectorite, stevensite, nontronite, magadiite, ilerite, kanemite, layered titanate, smectite, synthetic smectite, or the like. The mineral fine particles may be a natural product or a synthetic product (including a substitution product and a derivative), or may be a mixture of a natural product and a synthetic product. The mineral fine particles are more preferably made of layered organoclay. A layered organoclay is a material in which organic onium ions are introduced between layers of swelling clay. Layered organoclay may contain any organic onium ions that can organically modify swelling clay using the cation exchange properties of the swelling clay. When layered organoclay mineral particles are used as mineral fine particles, synthetic smectite can be suitably used as described above. Synthetic smectite has a function of increasing the viscosity of a coating liquid for forming an antiglare layer to prevent precipitation of resin particles and inorganic fine particles, adjusting the uneven shape of the surface of an optical functional layer.
The composition for forming the antiglare layer 17 may contain any of a silicon oxide, a fluorine-containing silane compound, fluoroalkylsilazane, fluoroalkylsilane, a fluorine-containing silicon compound, and a perfluoropolyether group-containing silane coupling agent. Such a material can impart at least one of water repellency and oil repellency to the antiglare layer 17, allowing the optical film 10D to have better antifouling properties.
The antiglare layer 17 may be configured such that a layer having a relatively high refractive index and a layer having a relatively low refractive index are sequentially laminated from the side closest to the first surface 11a. The antiglare layer 17 containing unevenly distributed materials can be formed, for example, by applying a composition containing a low refractive index material containing surface-modified silica fine particles or hollow silica fine particles and a high refractive index material, and performing phase separation using the difference in surface free energy between the two materials. When the antiglare layer 17 is composed of two layers obtained by phase separation, the antiglare layer 17 is preferably configured such that the layer having a relatively high refractive index on the side closest to the first surface 11a of the transparent substrate 11 has a refractive index of 1.50 to 2.40 and that the layer having a relatively low refractive index on the side closest to the surface of the optical film 10D has a refractive index of 1.20 to 1.55.
The optical film 10D and the display device 50D of the present embodiment include the colored layer 12 and the transparent substrate 11 as in the first embodiment, and thus have the same effects as in the first embodiment.
In particular, the optical film 10D of the present embodiment includes the antiglare layer 17, causing external light to be scattered in the antiglare layer 17. This reduces surface reflection and glare of external light, achieving better visibility of the display screen and display light, thus preventing lower display quality due to external light reflection.
An optical film and a display device according to a fourth embodiment of the present invention will be described.
A display device 50E of the present embodiment whose cross section in the thickness direction is shown in
The optical film 10E has the same configuration as the optical film 10D except that the optical film 10E includes a low refractive index layer 14E that is laminated on the antiglare layer 17.
The following description will focus on differences from the third embodiment.
The low refractive index layer 14E is the same as the low refractive index layer 14A of the first embodiment except that the low refractive index layer 14E has a lower refractive index than the antiglare layer 17.
Thus, interference occurs between reflected light of external light entering from the outside that is reflected by the interface between the antiglare layer 17 and the low refractive index layer 14E and reflected light reflected by the surface of the low refractive index layer 14E, achieving a lower reflectance for external light.
The low refractive index layer 14E can reduce reflection of external light, achieving better visibility of the display device 50E.
The optical film 10E and the display device 50E of the present embodiment include the colored layer 12 and the antiglare layer 17 as in the third embodiment, and thus have the same effects as in the third embodiment.
In particular, the optical film 10E of the present embodiment includes the low refractive index layer 14E on the outer side, and this reduces surface reflection and glare of external light, achieving better visibility of the display screen and display light, thus preventing lower display quality due to external light reflection.
In the embodiments and modification described above, the light emitting elements are organic EL devices. However, the light emitting elements are not limited to organic EL devices. The light emitting elements may be, for example, white LED devices, inorganic phosphor light emitting elements, or quantum dot light emitting elements. When a light source that emits monochromatic light in the three primary colors R, G, and B is used, the display unit 20 may be configured not to include the color filter module 23.
In the above embodiments and modification, various functional layer configurations of the optical film other than the colored layer, such as the low refractive index layer, the hard coat layer, the oxygen barrier layer, and the antiglare layer, are described; however, the functional layer configuration of the optical film is not limited to these.
For example, the optical film may include an antifouling layer that has water repellency, or an antistatic layer that contains a conductive material. Each functional layer may be a layer portion having two or more functions of the functional layers described above.
In the examples described in the above embodiments and modification, at least the transparent substrate has ultraviolet absorption properties. However, the optical film may further include an ultraviolet absorption layer having the ultraviolet absorption function. In the optical film, the colored layer or a functional layer other than the colored layer may also serve as an ultraviolet absorption layer.
For example, an ultraviolet absorption layer may be placed closer to the outer side of the optical film than a layer portion for which irradiation with ultraviolet light is to be prevented. In such a case, the ultraviolet absorption layer can protect, from ultraviolet light irradiated from the outside of the optical film, the layer portion located closer to the inner side of the optical film than the ultraviolet absorption layer.
The optical film according to the present invention will be further described using Examples 1 to 12 and Comparative Examples 1 to 6. The present invention should not be limited in any way by the specific content of the following examples.
In the examples and the comparative examples, optical films 1 to 18 having a layer configuration shown in Table 1 or 2 were prepared, and the prepared optical films 1 to 15 were evaluated for the characteristics of the optical films. Furthermore, the optical films 7, 12, and 16 to 18 were used to examine by simulation the characteristics of a display device including an organic EL panel.
<Preparation of Optical Films>
The method of forming each layer will be described.
[Formation of Colored Layer]
(Materials Used for Composition for Forming Colored Layer)
The following materials were used as materials for a composition for forming a colored layer to form a colored layer.
The maximum absorption wavelength and half width of colorant materials were calculated as characteristic values of a cured coating film from the spectral transmittance.
First Colorant Material:
Second Colorant Material:
Third Colorant Material:
Solvent:
The composition for forming a colored layer did not contain a dye having a main absorption wavelength range in the wavelength range of 390 to 435 nm, and thus the colored layer used in the examples did not contain a dye having a main absorption wavelength range in the wavelength range of 390 to 435 nm.
(Transparent Substrate)
The following materials were used as a transparent substrate.
(Formation of Colored Layer)
The composition for forming a colored layer shown in Table 3 was applied to a surface of the transparent substrate shown in Tables 1 and 2, and dried in an oven at 80° C. for 60 seconds. Then, the coating film was cured by irradiation with ultraviolet light at an exposure dose of 150 mJ/cm2 using an ultraviolet irradiation device (manufactured by Fusion UV Systems Japan K.K., light source H bulb) to form colored layers 1 to 8 so that the colored layers 1 to 8 after curing had a thickness of 5.0 μm. The added amounts shown in Table 3 are expressed as a mass ratio.
[Formation of Functional Layer]
Composition for Forming Oxygen Barrier Layer 1:
(Formation of Oxygen Barrier Layer)
The composition for forming an oxygen barrier layer 1 was applied onto the configuration of Example 11 shown in Table 1 and dried to form the oxygen barrier layer 1 having an oxygen permeability of 1 cc/m2·day·atm.
(Materials Used for Composition for Forming Hard Coat Layer)
The following materials were used as materials for a composition for forming a hard coat layer to form a hard coat layer.
Ultraviolet Absorber:
Active Energy Ray-Curable Resin:
Initiator:
Solvent:
(Formation of Hard Coat Layer)
The composition for forming a hard coat layer shown in Table 4 was applied onto the transparent substrate, the colored layer, or the oxygen barrier layer shown in Tables 1 and 2, and dried in an oven at 80° C. for 60 seconds. Then, the coating film was cured by irradiation with ultraviolet light at an exposure dose of 150 mJ/cm2 using an ultraviolet irradiation device (manufactured by Fusion UV Systems Japan K.K., light source H bulb) to form hard coat layers 1 and 2 shown in Tables 1 and 2 so that the hard coat layers 1 and 2 after curing had a thickness of 5.0 μm.
(Composition for Forming Antiglare Layer 1)
The following materials were used as a composition for forming an antiglare layer 1.
Active Energy Ray-Curable Resin:
Photopolymerization Initiator:
Resin Particles:
Inorganic Fine Particles 1:
Inorganic Fine Particles 2:
Solvent
(Formation of Antiglare Layer)
The composition for forming the antiglare layer 1 was applied onto the transparent substrate shown in Table 1, and dried in an oven at 80° C. for 60 seconds. Then, the coating film was cured by irradiation with ultraviolet light at an exposure dose of 150 mJ/cm2 using an ultraviolet irradiation device (manufactured by Fusion UV Systems Japan K.K., light source H bulb) to form the antiglare layer 1 shown in Table 1 so that the antiglare layer 1 after curing had a thickness of 5.0
(Composition for Forming Low Refractive Index Layer 1)
The following materials were used as a composition for forming a low refractive index layer 1.
Refractive Index Adjusting Agent:
Antifouling Agent:
Active Energy Ray-Curable Resin:
Leveling Agent:
Solvent:
(Formation of Low Refractive Index Layer 1)
The composition for forming the low refractive index layer 1, having the above composition, was applied onto the hard coat layer or the antiglare layer shown in Tables 1 and 2, and dried in an oven at 80° C. for 60 seconds. Then, the coating film was cured by irradiation with ultraviolet light at an exposure dose of 200 mJ/cm2 using an ultraviolet irradiation device (manufactured by Fusion UV Systems Japan K.K., light source H bulb) to form the low refractive index layer 1 shown in Tables 1 and 2 so that the low refractive index layer 1 after curing had a thickness of 100 nm.
[Evaluation of Characteristics of Films]
The obtained optical films 1 to 15 were evaluated for the following items.
(Ultraviolet Shielding Rate)
In Examples 1 to 12 in which the transparent substrate was provided above the colored layer, the transmittance of the substrate was measured by using an automatic spectrophotometer (U-4100 manufactured by Hitachi, Ltd.). In Comparative Examples 1 to 3 in which the colored layer was provided above the substrate, the layers located above the colored layer were peeled off using a cellophane tape in accordance with JIS-K 5600 adhesion test. The transmittance of the layers located above the colored layer was measured by using an automatic spectrophotometer (U-4100 manufactured by Hitachi, Ltd.) using an adhesive tape as a reference. Then, the transmittances were used to calculate the average transmittance [%] in the ultraviolet region (290 nm to 400 nm), and the ultraviolet shielding rate [%] was calculated as a value obtained by subtracting the average transmittance [%] in the ultraviolet region (290 nm to 400 nm) from 100%.
(Pencil Hardness Test)
The surface of the optical films was subjected to a test using a pencil (Uni manufactured by Mitsubishi Pencil Co., Ltd.; pencil hardness: H) at a load of 500 gf (4.9 N) (hereinafter, a load of 500 g) in accordance with JIS-K5600-5-4: 1999 by using a Clemens-type scratch hardness tester (HA-301 manufactured by Tester Sangyo Co., Ltd.), and the optical films were evaluated by visual observation for a change in appearance due to scratches. The optical films on which no scratches were observed were determined to be good (“Good” in Tables 5 and 6), and the optical film on which scratching was observed was determined to be poor (“Poor” in Table 6).
(Light Resistance Test)
The obtained optical films including the colored layer were subjected to a reliability test using a xenon weather meter (X75 manufactured by Suga Test Instruments Co., Ltd.) at a xenon lamp illuminance of 60 W/cm2 (300 nm to 400 nm) at a temperature of 45° C. and a humidity of 50% RH in the tester for 120 hours, and before and after the test, the transmittance of the optical films was measured using an automatic spectrophotometer (U-4100 manufactured by Hitachi, Ltd.). Then, a transmittance difference ΔTλ1 between before and after the test at a wavelength λ1 at which the minimum transmittance before the test was in the wavelength range of 470 nm to 530 nm, a transmittance difference ΔTλ2 between before and after the test at a wavelength λ2 at which the minimum transmittance before the test was in the wavelength range of 560 nm to 620 nm, and a transmittance difference ΔTλ3 between before and after the test at a wavelength at which the minimum transmittance before the test was in the wavelength range of 650 nm to 780 nm were calculated. An optical film having a transmittance difference closer to zero is better. An optical film in which |ΔTλN|≤20 (N=1 to 3) is preferable, and an optical film in which |ΔTλN|≤10 (N=1 to 3) is more preferable.
The results of the evaluation for the above items are shown in Tables 5 and 6.
As shown in Tables 5 and 6, the optical films in which the transparent substrate having an ultraviolet shielding rate of 85% or more was provided above the colored layer maintained the hardness, and the colored layer containing the first to third colorant materials had significantly higher light resistance. The use of a colored layer having ultraviolet absorptivity was less effective, and it was preferable to provide a layer having ultraviolet absorptivity as a separate layer located above the colored layer. In the optical film in which the oxygen barrier layer was laminated on the colored layer and the optical films in which the colored layer contained a hindered amine light stabilizer having a high molecular weight as a radical scavenger and a dialkyl dithiocarbamate nickel complex as a singlet oxygen quencher, the colored layer had even higher light resistance.
[Evaluation of Characteristics of Display Devices]
The obtained optical films 7, 12, and 16 to 18 were evaluated for the following items.
(White Display Transmission Characteristic)
The transmittance of the obtained optical films was measured using an automatic spectrophotometer (U-4100 manufactured by Hitachi, Ltd.). The transmittance was used to calculate the efficiency of light transmitted through the optical films during white display, and the efficiency was evaluated as a white display transmission characteristic. The efficiency was calculated as a ratio of the light intensity at each wavelength of light transmitted through the optical films to the light intensity at each wavelength during white display in which light was emitted from a white organic EL light source (hereinafter may be referred to as an organic EL light source) and output through the color filter. A higher light intensity ratio indicates a higher luminous efficacy of the light source.
(Display Device Reflection Characteristic 1)
The transmittance T (λ) and the surface reflectance R2 (λ) of the obtained optical films were measured using an automatic spectrophotometer (U-4100 manufactured by Hitachi, Ltd.). In the measurement of the surface reflectance R2 (λ), the optical films were subjected to antireflection treatment by applying a matte black coating material to the surface of the triacetylcellulose film which is the transparent substrate, on which neither the colored layer nor the functional layer was provided, and the spectral reflectance at an incident angle of 5° of the optical films was measured to obtain the surface reflectance R2 (λ). A relative reflection value relative to the intensity of reflected light from illuminant D65 when no optical film was provided was calculated, without considering interfacial reflection between the layers or surface reflection, based on formulas (4), (5), (7), and (9), where the electrode reflectance RE (λ) was 100% at all wavelengths in the wavelength range of 380 nm to 780 nm, and the relative reflection value was evaluated as a display device reflection characteristic 1. A lower relative reflection value indicates a lower intensity of reflected light and higher display quality.
(Display Device Reflection Hue 1)
The transmittance T (λ) and the surface reflectance R2 (λ) of the obtained optical films were measured using an automatic spectrophotometer (model number: U-4100 manufactured by Hitachi, Ltd.). In the measurement of the surface reflectance R2 (λ), the optical films were subjected to antireflection treatment by applying a matte black coating material to the surface of the triacetylcellulose film which is the transparent substrate, on which neither the colored layer nor the functional layer was provided, and the spectral reflectance at an incident angle of 5° of the optical films was measured to obtain the surface reflectance R2 (λ). The chromaticness indexes (values) a* and b* of the reflection hue for illuminant D65 were calculated, without considering interfacial reflection between the layers or surface reflection, based on formulas (1) to (9), where the electrode reflectance RE (λ) was 100% at all wavelengths in the wavelength range of 380 nm to 780 nm, and the values a* and b* were evaluated as a display device reflection hue 1.
Values a* and b* closer to zero indicate better values with less color. The values a* and b* are preferably from −5 to +5 inclusive.
(Display Device Reflection Characteristic 2)
A relative reflection value was obtained in the same manner as the display device reflection characteristic 1 except that the electrode reflectance RE (λ) was an electrode reflectance obtained by reflectance measurement using an organic light emitting display device (organic EL TV OLED55C8PJA manufactured by LG Electronics) shown in
(Display Device Reflection Hue 2)
The chromaticness indexes (values) a* and b* of the reflection hue for illuminant D65 were obtained in the same manner as the display device reflection hue 1 except that the electrode reflectance RE (λ) was an electrode reflectance obtained by reflectance measurement using an organic light emitting display device (organic EL TV OLED55C8PJA manufactured by LG Electronics) shown in
(Color Reproducibility)
The transmittance of the obtained optical films was measured using an automatic spectrophotometer (U-4100 manufactured by Hitachi, Ltd.). A CIE 1931 chromaticity value was calculated using the transmittance and a spectrum of light for each of red display, green display, and blue display as shown in
A higher NTSC ratio indicates higher color reproducibility and is more preferable.
The results of the evaluation for the above items are shown in Table 7.
As shown in Table 7, the display devices including the colored layer had a significantly low reflection characteristic. Although a circular polarizing plate was considered to reduce the transmittance by half, as shown in the evaluation values of the white display transmission characteristic, the display devices including the colored layer had high luminous efficacy and high color reproducibility.
Furthermore, in the colored layer containing the first, second, and third colorant materials in the examples, the absorption intensity of the colorant materials was adjustable so that each of the chromaticness indexes a* and b* of the reflection hue was in the range from −5 to +5 inclusive, where the electrode reflectance RE (λ) was 100% at all wavelengths in the wavelength range of 380 nm to 780 nm. That is, a reflection hue close to neutral was achieved. Furthermore, the results showed that a neutral reflection hue was also maintained in the display device reflection hue 2 obtained using the electrode reflectance of an actual organic light emitting display device, and higher display quality of the display device was confirmed. As described above, it is also an aspect of the present invention to adjust the combination ratio of first, second, and third colorant materials to cause a reflection hue of an optical film including a colored layer to be neutral for the electrode reflectance of an organic light emitting display device having various wavelength dispersion properties.
The preferred embodiments and modification of the present invention have been described by way of examples; however, the present invention is not limited to the embodiments or the examples. Additions, omissions, substitutions, and other changes in the configuration are possible without departing from the spirit of the present invention.
Furthermore, the present invention should not be limited by the foregoing description, but should be limited only by the appended claims.
The present invention provides an optical film, a display device, and a composition for forming a colored layer that achieve higher display quality by reducing external light reflection and a longer life of a light emitting element of the display device.
10A, 10B, 10C, 10D, 10E . . . Optical film; 11 . . . Transparent substrate; 11a . . . First surface; 11b . . . Second surface; 12 . . . Colored layer; 14A, 14B, 14E . . . Low refractive index layer; 16 . . . Oxygen barrier layer; 17 . . . Antiglare layer; 20 . . . Display unit; 21 . . . Substrate; 22 . . . Light emitting element; 22R . . . First light emitting element; 22G . . . Second light emitting element; 22B . . . Third light emitting element; 23 . . . Color filter module; 50A, 50C, 50E . . . Display device.
| Number | Date | Country | Kind |
|---|---|---|---|
| 2021-040750 | Mar 2021 | JP | national |
This application is a continuation application filed under 35 U.S.C. § 111(a) claiming the benefit under 35 U.S.C. §§ 120 and 365(c) of International Patent Application No. PCT/JP2022/010938, filed on Mar. 11, 2022, which is based upon and claims the benefit of priority to Japanese Patent Application No. 2021-040750, both filed on Mar. 12, 2021, the disclosures of which are incorporated herein by reference in their entirety.
| Number | Date | Country | |
|---|---|---|---|
| Parent | PCT/JP22/10938 | Mar 2022 | US |
| Child | 18244895 | US |
