OPTICAL GLASS, OPTICAL ELEMENT, OPTICAL SYSTEM, CEMENTED LENS, INTERCHANGEABLE LENS FOR CAMERA, OBJECTIVE LENS FOR MICROSCOPE, AND OPTICAL DEVICE

Abstract

An optical glass comprising: by mass%, 20% or more and 55% or less of a content rate of P2O5; 10% or more and 40% or less of a content rate of TiO2; 0% or more and 30% or less of a content rate of Nb2O5; 0% or more and 2% or less of a content rate of Al2O3; 0% or more and 10% or less of a content rate of B2O3; 3% or more and 30% or less of a content rate of BaO; 0% or more and 30% or less of a content rate of Bi2O3; 0% or more and 20% or less of a content rate of Ta2O5; and 0% or more and 25% or less of a content rate of WO3, wherein a ratio of a total content rate of Li2O, Na2O and K2O (ΣA2O; where, A = Li, Na and K) to a content rate of TiO2 (ΣA2O/TiO2) is 0.10 or more and 0.65 or less, and a ratio of a content rate of TiO2 to a total content rate of P2O5, B2O3, and Al2O3 (TiO2/(P2O5 + B2O3 + Al2O3) ) is 0.25 or more and 0.85 or less.

Description

TECHNICAL FIELD

The present invention relates to an optical glass, an optical element, an optical system, a cemented lens, an interchangeable camera lens, an objective lens for a microscope, and an optical device.

BACKGROUND ART

In recent years, imaging equipment and the like including an image sensor with a large number of pixels have been developed, and an optical glass that has low dispersion and a high partial dispersion ratio has been demanded as an optical glass to be used for such equipment.

CITATION LIST

Patent Literature

PTL 1: JP2006-219365 A

SUMMARY OF INVENTION

A first aspect according to the present invention is an optical glass including: by mass%, 20% to 55% of a content rate of P₂O₅; 10% to 40% of a content rate of TiO₂; 0% to 30% of a content rate of Nb₂O₅; 0% to 2% of a content rate of Al₂O₃; 0% to 10% of a content rate of B₂O₃; 0% to 30% of a content rate of BaO; 0% to 30% of a content rate of Bi₂O₃; 0% to 20% of a content rate of Ta₂O₅; and 0% to 25% of a content rate of WO₃, wherein a ratio of a content rate of TiO₂ to a total content rate of P₂O₅, B₂O₃, and Al₂O₃ (TiO₂/(P₂O₅ + B₂O₃ + Al₂O₃) ) is from 0.25 to 0.85, and a ratio of a content rate of TiO₂ to a total content rate of TiO₂, Nb₂O₅, WO₃, B1₂O₃, and Ta₂O₅ (TiO₂/ (TiO₂ + Nb₂O₅ + WO₃ + Bi₂O₃ + Ta₂O₅) ) is from 0.25 to 1.00. An optical glass includes: by mass%, 20% to 55% of a content rate of P₂O₅; 10% to 40% of a content rate of TiO₂; 0% to 30% of a content rate of Nb₂O₃; 0% to 2% of a content rate of Al₂O_3; 0% to 10% of a content rate of B₂O₃; 0% to 30% of a content rate of BaO; 0% to 30% of a content rate of Bi₂O₃; 0% to 20% of a content rate of Ta₂O₃; and 0% to 25% of a content rate of WO₃, wherein a ratio of a total content rate of BaO and TiO₂ to a content rate of P₂O₅ ((BaO + TiO₂) /P₂O₅) is from 0.40 to 1.50.

A second aspect according to the present invention is an optical element using the optical glass described above.

A third aspect according to the present invention is an optical system including the optical element described above.

A fourth aspect according to the present invention is an interchangeable camera lens including the optical system including the optical element described above.

A fifth aspect according to the present invention is an objective lens for a microscope including the optical system including the optical element described above.

A sixth aspect according to the present invention is an optical device including the optical system including the optical element described above.

A seventh aspect according to the present invention is a cemented lens including a first lens element and a second lens element, and at least one of the first lens element and the second lens element is the optical glass described above.

An eighth aspect according to the present invention is an optical system including the cemented lens described above.

A ninth aspect according to the present invention is an objective lens for a microscope including the optical system including the cemented lens described above.

A tenth aspect according to the present invention is an interchangeable camera lens including the optical system including the cemented lens described above.

An eleventh aspect according to the present invention is an optical device including the optical system including the cemented lens described above.

BRIEF DESCRIPTION OF DRAWINGS

FIG. 1 is a perspective view illustrating one example of an optical device according to the present embodiment as an imaging device.

FIG. 2 is a schematic diagram illustrating another example of the optical device according to the present embodiment as an imaging device, and is a front view of the imaging device.

FIG. 3 is a schematic diagram illustrating another example of the optical device according to the present embodiment as an imaging device, and is a back view of the imaging device.

FIG. 4 is a block diagram illustrating one example of a configuration of a multi-photon microscope according to the present embodiment.

FIG. 5 is a schematic diagram illustrating one example of a cemented lens according to the present embodiment.

FIG. 6 is a graph in which P_g,F and V_d of Examples and Comparative Examples are plotted.

DESCRIPTION OF EMBODIMENTS

Hereinafter, description is made on an embodiment of the present invention (hereinafter, referred to as the “present embodiment”). The present embodiment described below is an example for describing the present invention, and is not intended to limit the present invention to the contents described below. The present invention may be modified as appropriate and carried out without departing from the gist thereof.

In the present specification, a content rate of each of all the components is expressed with mass% (mass percentage) with respect to the total weight of glass in terms of an oxide-converted composition unless otherwise stated. Note that, assuming that oxides, complex salt, and the like, which are used as raw materials as glass constituent components in the present embodiment, are all decomposed and turned into oxides at the time of melting, the oxide-converted composition described herein is a composition in which each component contained in the glass is expressed with a total mass of the oxides as 100 mass%.

An expression that a Q content rate is “0% to N%” is an expression including a case where a Q component is not included and a case where a Q component is more than 0% and equal to or less than N%.

An expression that a “Q component is not included” means that the Q component is not substantially included, and that a content rate of the constituent component is an impurity level or less. The impurity level or less means, for example, being less than 0.01%.

An expression of “devitrification resistance stability” means resistance to devitrification of glass. Here, “devitrification” means a phenomenon in which transparency of glass is lost due to crystallization, phase splitting, or the like that occurs when the glass is heated to a glass transition temperature or higher or when the glass is lowered from a molten state to a liquid phase temperature or lower.

An optical glass according to the present embodiment is an optical glass including: by mass%, 20% to 55% of a content rate of P₂O₅; 10% to 40% of a content rate of TiO₂; 0% to 30% of a content rate of Nb₂O₅; 0% to 2% of a content rate of Al₂O₃; 0% to 10% of a content rate of B₂O₃; 0% to 30% of a content rate of BaO; 0% to 30% of a content rate of Bi₂O₃; 0% to 20% of a content rate of Ta₂O₅; and 0% to 25% of a content rate of WO₃, wherein a ratio of a content rate of TiO₂ to a total content rate of P₂O₅, B₂O₃, and Al₂O₃ (TiO₂/(P₂O₅ + B₂O₃ + Al₂O₃) ) is from 0.25 to 0.85, and a ratio of a content rate of TiO₂ to a total content rate of TiO₂, Nb₂O₅, WO₃, B1₂O₃, and Ta₂O₅ (TiO₂/ (TiO₂ + Nb₂O₅ + WO₃ + Bi₂O₃ + Ta₂O₅) ) is from 0.25 to 1.00. An optical glass includes: by mass%, 20% to 55% of a content rate of P₂O₅; 10% to 40% of a content rate of TiO₂; 0% to 30% of a content rate of Nb₂O₅; 0% to 2% of a content rate of Al₂O_3; 0% to 10% of a content rate of B₂O₃; 0% to 30% of a content rate of BaO; 0% to 30% of a content rate of Bi₂O₃; 0% to 20% of a content rate of Ta₂O₅; and 0% to 25% of a content rate of WO₃, wherein a ratio of a total content rate of BaO and TiO₂ to a content rate of P₂O₅ ((BaO + TiO₂) /P₂O₅) is from 0.40 to 1.50.

The optical glass according to the present embodiment can have low dispersion (great abbe number) and can have a high partial dispersion ratio. Thus, a light-weighted lens that is advantageous in aberration correction can be achieved.

P₂O₅ is a component that forms a glass frame, improves devitrification resistance stability, reduces a refractive index, and degrades chemical durability. When the content rate of P₂O₅ is excessively reduced, devitrification is liable to be caused. When the content rate of P₂O₅ is excessively increased, a refractive index is liable to be reduced, and chemical durability is liable to be degraded. From such a viewpoint, the content rate of P₂O₅ is from 20% to 55%. A lower limit of this content rate is preferably 25%, more preferably 30%, further preferably 38%. An upper limit of this content rate is preferably 50%, more preferably 45%, further preferably 40%. When the content rate of P₂O₅ falls within such a range, devitrification resistance stability can be improved, chemical durability can be satisfactory, and a refractive index can be increased.

TiO₂ is a component that increases a refractive index and a partial dispersion ratio and reduces a transmittance. When the content rate of TiO₂ is excessively reduced, a refractive index and a partial dispersion ratio are liable to be reduced. When the content rate of TiO₂ is excessively increased, a transmittance is liable to be degraded. From such a viewpoint, the content rate of TiO₂ is from 10% to 40%. A lower limit of this content rate is preferably 15%, more preferably 17%. An upper limit of this content rate is preferably 30%, more preferably 28%, further preferably 25%. When the content rate of TiO₂ falls within such range, a high transmittance can be achieved without reducing a refractive index and a partial dispersion ratio.

Nb₂O₅ is a component that increases a refractive index, improves dispersion, and reduces a transmittance. When the content rate of Nb₂O₅ is reduced, a refractive index is liable to be reduced. When the content rate of Nb₂O₅ is increased, a transmittance is liable to be degraded. From such a viewpoint, the content rate of Nb₂O₅ is from 0% to 30%. A lower limit of this content rate is preferably more than 0%, more preferably 5% or more. An upper limit of this content rate is preferably 25%, more preferably 18%, further preferably 10%.

Al₂O₃ is a component that improves chemical durability and reduces a partial dispersion ratio and meltability. When the content rate of Al₂O₃ is excessively reduced, chemical durability is liable to be degraded. When the content rate of Al₂O₃ is excessively increased, a partial dispersion ratio is liable to be reduced, and meltability is liable to be degraded. From such a viewpoint, the content amount of Al₂O₃ is from 0% to 2%. A lower limit of this content rate is preferably 1%. An upper limit of this content rate is preferably 1.6%. When the content rate of Al₂O₃ falls within such range, chemical durability can be increased, and reduction of a partial dispersion ratio can be prevented.

From a viewpoint of achieving high dispersion, the content rate of B₂O₃ is from 0% to 10%. A lower limit of this content rate may be more than 0%. An upper limit of this content rate is preferably 6%, more preferably 4%.

BaO is a component that improves a partial dispersion ratio and degrade devitrification resistance stability. When the content rate of BaO is excessively reduced, a partial dispersion ratio is liable to be reduced. When the content rate of BaO is excessively increased, devitrification resistance stability is liable to be degraded. From such a viewpoint, the content rate of BaO is from 0% to 30%. A lower limit of this content rate is preferably 3%, more preferably 5%, further preferably 7%. An upper limit of this content rate is preferably 25%, more preferably 20%, further preferably 15%. When the content rate of BaO falls within such range, a partial dispersion ratio can be increased, and degradation of devitrification resistance stability can be prevented.

Bi₂O₃ is a component that increases a refractive index and a partial dispersion ratio. When the content rate of Bi₂O₃ is excessively increased, a transmittance is liable to be degraded, and dispersion is liable to be increased. When the content rate of Bi₂O₃ is excessively reduced, meltability is liable to be degraded. From such a viewpoint, the content rate of Bi₂O₃ is from 0% to 30%. A lower limit of this content rate is preferably 2%, more preferably 5%, further preferably 10%. An upper limit of this content rate is preferably 25%, more preferably 20%. When the content rate of Bi₂O₃ falls within such range, meltability can be increased, and a dispersion increase can be prevented.

Ta₂O₅ is a component that increases a refractive index, improves dispersion, and degrade devitrification resistance stability. When the content rate of Ta₂O₅ is increased, devitrification resistance stability is liable to be degraded. From such a viewpoint, the content rate of Ta₂O₅ is from 0% to 20%. A lower limit of this content rate may be more than 0%. An upper limit of this content rate is preferably 16%, more preferably 10%. Further preferably, Ta is substantially excluded. Here, “substantially excluded” means that the component is not contained as a constituent component that affects a property of a glass composition beyond a concentration in which the component is inevitably contained as an impurity. For example, when the content amount is approximately 100 ppm, the component is considered to be substantially excluded. The optical glass according to the present embodiment enables a content rate of Ta₂O₅ being an expensive raw material to be reduced, and further enables such material to be excluded. Thus, the optical glass according to the present embodiment is also excellent in reduction of raw material cost.

From a viewpoint of a transmittance, the content rate of WO₃ is from 0% to 25%. A lower limit of this content rate may be more than 0%. An upper limit of this content rate is preferably 20%, more preferably 15%, further preferably 10%.

A ratio of the content rate of TiO₂ to the total content rate of P₂O₅, B₂O₃, and Al₂O₃ (TiO₂/ (P₂O₅ + B₂O₃ + Al₂O₃) ) is preferably from 0.25 to 0.85. A lower limit of this ratio is more preferably 0.30, further preferably 0.40. An upper limit of this ratio is more preferably 0.70, further preferably 0.60. When TiO₂/(P₂O₅ + B₂O₃ + Al₂O₃) falls within such range, a partial dispersion ratio can be increased.

A ratio of the content rate of TiO₂ to the total content rate of TiO₂, Nb₂O₅, WO₃, B1₂O₃, and Ta₂Ό₅ (TiO₂/ (TiO₂ + Nb₂O₅ + WO₃ + Bi₂O₃ + Ta₂O₅)) is preferably from 0.25 to 1.00. A lower limit of this ratio is more preferably 0.30, further preferably 0.40. An upper limit of this ratio is more preferably 0.90, further preferably 0.80. When TiO₂/ (TiO₂ + Nb₂O₅ + WO₃ + Bi₂O₃ + Ta₂O₅) falls within such range, a partial dispersion ratio can be increased.

A ratio of the total content rate of BaO and TiO₂ to the content rate of P₂O₅ ((BaO + TiO₂) /P₂O₅) is preferably from 0.40 to 1.50. A lower limit of this ratio is more preferably 0.70. An upper limit of this ratio is more preferably 1.10, further preferably 0.90. When (BaO + TiO₂)/P₂O₅falls within such range, a refractive index can be increased.

The optical glass according to the present embodiment may further contain, as any component, one or more compounds selected from the group consisting of Na₂O, K₂O, Li₂O, ZnO, MgO, CaO, SrO, SiO₂, ZrO₂, Sb₂O₃, Y₂O₃, La₂O₃, and Gd₂O₃.

Na₂O is a component that improves meltability and reduces a refractive index. When the content rate of Na₂O is excessively reduced, meltability is liable to be degraded. When the content rate of Na₂O is excessively increased, a refractive index is liable to be reduced, and chemical durability is liable to be degraded. From such a viewpoint, the content rate of Na₂O is from 0% to 30%. A lower limit of this content rate is preferably more than 0%, more preferably 5%. An upper limit of this content rate is preferably 20%, more preferably 15%. When the content rate of Na₂O falls within such range, meltability can be increased, and reduction of a refractive index and degradation of chemical durability can be prevented.

K₂O is a component that improves meltability and reduces a refractive index. When the content rate of K₂O is excessively reduced, meltability is liable to be degraded. When the content rate of K₂O is excessively increased, a refractive index is liable to be reduced, and chemical durability is liable to be degraded. From such a viewpoint, the content rate of K₂O is from 0% to 25%. A lower limit of this content rate is preferably more than 0%, more preferably 3%. An upper limit of this content rate is preferably 20%, more preferably 15%, further preferably 5%. When the content rate of K₂O falls within such range, meltability can be increased, and reduction of a refractive index and degradation of chemical durability can be prevented.

From a viewpoint of meltability, the content rate of Li₂O is from 0% to 5%. A lower limit of this content rate may be more than 0%. An upper limit of this content rate is preferably 4%, more preferably 2%.

ZnO is a component that improves devitrification resistance stability and reduces a partial dispersion ratio. When the content rate of ZnO is excessively reduced, devitrification resistance stability is liable to be degraded. When the content rate of ZnO is excessively increased, a partial dispersion ratio is liable to be reduced. From such a viewpoint, the content rate of ZnO is from 0% to 15%. A lower limit of this content rate is preferably more than 0%, more preferably 1%. An upper limit of this content rate is preferably 10%, more preferably 8%. When the content rate of ZnO falls within such range, devitrification resistance stability can be increased, and reduction of a partial dispersion ratio can be prevented.

From a viewpoint of achieving high dispersion, the content rate of MgO is from 0% to 10%. A lower limit of this content rate may be more than 0%. An upper limit of this content rate is preferably 5%, more preferably 4%.

From a viewpoint of achieving high dispersion, the content rate of CaO is from 0% to 10%. A lower limit of this content rate may be more than 0%. An upper limit of this content rate is preferably 8%, more preferably 6%.

From a viewpoint of achieving high dispersion, the content rate of SrO is from 0% to 15%. A lower limit of this content rate may be more than 0%. An upper limit of this content rate is preferably 12%, more preferably 10%.

From a viewpoint of meltability, the content rate of SiO₂ is from 0% to 5%. A lower limit of this content rate may be more than 0%. An upper limit of this content rate is preferably 3%, more preferably 1%.

From a viewpoint of meltability, the content rate of ZrO₂ is from 0% to 5%. A lower limit of this content rate may be more than 0%. An upper limit of this content rate is preferably 3% or less, more preferably 1.5%.

The content rate of Sb₂O₃ is, from a viewpoint of a defoaming property at the time of melting of glass, from 0% to 1%. A lower limit of this content rate may be more than 0%. An upper limit of this content rate is preferably 0.5%, more preferably 0.2%.

From a viewpoint of meltability, the content rate of Y₂O₃ is from 0% to 8%. A lower limit of this content rate may be more than 0%. An upper limit of this content rate is preferably 6%, more preferably 5%, further preferably 4.5%.

From a viewpoint of meltability, the content rate of La₂O₃ is from 0% to 5%. A lower limit of this content rate may be more than 0%. An upper limit of this content rate is preferably 4%, more preferably 3.5%. From a viewpoint of cost, La₂O₃ is more preferably substantially excluded. Here, “substantially excluded” means that the component is not contained as a constituent component that affects a property of a glass composition beyond a concentration in which the component is inevitably contained as an impurity. For example, when the content amount is approximately 100 ppm, the component is considered to be substantially excluded.

Gd₂O₃ is an expensive raw material, and hence the content rate thereof is preferably from 0% to 10%. A lower limit of this content rate may be more than 0%. An upper limit of this content rate is preferably 8%, more preferably 7.5%.

Furthermore, the optical glass according to the present embodiment preferably satisfies the following relationships.

A ratio of the content rate of TiO₂ to the content rate of P₂O₅ (TiO₂/P₂O₅) is preferably from 0.25 to 0.85. A lower limit of this ratio is more preferably 0.30, further preferably 0.40. An upper limit of this ratio is more preferably 0.75, further preferably 0.60. When TiO₂/P₂O₅ falls within such range, a partial dispersion ratio can be increased.

A ratio of the content rate of Al₂O₃ to the content rate of TiO₂ (Al₂O₃/TiO₂) is from 0 to 0.15. A lower limit of this ratio may be more than 0. An upper limit of this ratio is preferably 0.12, more preferably 0.09. When Al₂O₃/TiO₂ falls within such range, a partial dispersion ratio can be increased.

A ratio of the content rate of B₂O₃ to the content rate of P₂O₅ (B₂O₃/P₂O₅) is preferably 0 to 0.30. A lower limit of this ratio may be more than 0. An upper limit of this ratio is more preferably 0.25, further preferably 0.20. When B₂O₃/P₂O₅ falls within such range, a partial dispersion ratio can be increased.

A ratio of the total content rate of BaO, TiO₂, Nb₂O₅, WO₃, Bi₂O₃, and Ta₂O₅ to the total content rate of P₂O₅, B₂O₃, SiO₂, and Al₂O₃ ((BaO + TiO₂ + Nb₂O₅ + WO₃ + Bi₂O₃ + Ta₂O₅) / (P₂O₅ + B₂O₃ + SiO₂ + Al₂O₃)) is preferably from 0.40 to 2.00. A lower limit of this ratio is more preferably 0.50, further preferably 0.60. An upper limit of this ratio is more preferably 1.60, further preferably 1.00. When (BaO + TiO₂ + Nb₂O₅ + WO₃ + Bi₂O₃ + Ta₂O₅) / (P₂O₅ + B₂O₃ + SiO₂ + Al₂O₃) falls within such a range, a partial dispersion ratio can be increased, and reduction of a refractive index can be prevented.

From a viewpoint of meltability, a refractive index, and chemical durability, the total content rate of Li₂O, Na₂O, and K₂O (∑A₂O; where, A = Li, Na, K) is 5% to 35%. A lower limit of this total content rate is preferably 7%, more preferably 9%, further preferably 11%. An upper limit of this total content rate is preferably 25%, more preferably 20%, further preferably 18%.

A suitable combination of the content rates is the content rate of Li₂O: 0% or more and 5% or less, the content rate of Na₂O: 0% or more and 30% or less, and the content rate of K₂O: 0% or more and 25% or less. With the combination, meltability can be increased, and degradation of chemical durability can be prevented.

From a viewpoint of meltability, a refractive index, and chemical durability, the total content rate of MgO, CaO, SrO, BaO, and ZnO (EEO; where, E = Mg, Ca, Sr, Ba, Zn) is 0% to 30%. A lower limit of this total content rate is preferably 5%, more preferably 8%, further preferably 10%. An upper limit of this total content rate is preferably 25%, more preferably 15%.

Another suitable combination is the content rate of BaO: 0% or more and 30% or less, the content rate of ZnO: 0% or more and 15% or less, the content rate of MgO: 0% or more and 10% or less, the content rate of CaO: 0% or more and 10% or less, and the content rate of SrO: 0% or more and 15% or less. With the combination, a partial dispersion ratio can be increased, and low dispersion can be prevented.

The total content rate of SiO₂ and B₂O₃ (SiO₂ + B₂O₃) is from 0% to 10%. A lower limit of this total content rate is preferably more than 0%, more preferably 1%, further preferably 2%. An upper limit of this total content rate is preferably 7%, more preferably 6%, further preferably 4%.

Still another suitable combination is the content rate of SiO₂: 0% or more and 5% or less and the content rate of B₂O₃: 0% or more and 10% or less. With the combination, meltability can be increased, and low dispersion can be prevented.

A ratio of the total content rate of Li₂O, Na₂O, and K₂O (∑A₂O; where, A = Li, Na, K) to TiO₂ (∑A₂O/TiO₂) is preferably from 0.10 to 2.00. A lower limit of this ratio is more preferably 0.20, further preferably 0.30. An upper limit of this ratio is more preferably 1.60, further preferably 1.30. When ∑A₂O/TiO₂ falls within such range, a partial dispersion ratio can be increased, and reduction of meltability can be prevented.

A ratio of the total content rate of Li₂O, Na₂O, and K₂O (∑A₂O; where, A = Li, Na, K) to the total content rate of MgO, CaO, SrO, BaO, and ZnO (∑EO; where, E = Mg, Ca, Sr, Ba, Zn) (∑EO/∑A₂O) is preferably from 0 to 3.00. A lower limit of this ratio is preferably more than 0, more preferably 0.20, further preferably 0.80. An upper limit of this ratio is more preferably 2.00, further preferably 1.50. When ∑EO/∑A₂O falls within such range, meltability can be increased, and reduction of a refractive index can be prevented.

For the purpose of, for example, performing fine adjustments of fining, coloration, decoloration, and optical constant values, a known component such as a fining agent, a coloring agent, a defoaming agent, and a fluorine compound may be added by an appropriate amount to the glass composition as needed. In addition to the above-mentioned components, other components may be added as long as the effect of the optical glass according to the present embodiment can be exerted.

A method of manufacturing the optical glass according to the present embodiment is not particularly limited, and a publicly known method may be adopted. Further, suitable conditions can be selected for the manufacturing conditions as appropriate. For example, there may be adopted a manufacturing method in which raw materials such as oxides, carbonates, nitrates, and sulfates are blended to obtain a target composition, melted at a temperature of preferably from 1,100 to 1,400° C., uniformed by stirring, subjected to defoaming, then poured in a mold, and molded. A lower limit of the melting temperature described above is more preferably 1200° C. An upper limit of the melting temperature is more preferably 1350° C., further preferably 1300° C. The optical glass thus obtained is processed to have a desired shape by performing reheat pressing or the like as needed, and is subjected to polishing. With this, a desired optical element is obtained.

A high-purity material with a small content rate of impurities is preferably used as the raw material. The high-purity material indicates a material including 99.85 mass% or more of a concerned component. By using the high-purity material, an amount of impurities is reduced, and hence an inner transmittance of the optical glass is likely to be increased.

Next, description is made on physical properties of the optical glass according to the present embodiment.

From a viewpoint of reduction in thickness of the lens, the optical glass according to the present embodiment preferably has a high refractive index (a refractive index (n_d) is large). However, in general, as the refractive index (n_d) is higher, the transmittance is liable to be reduced. In view of such a circumstance, the refractive index (n_d) of the optical glass according to the present embodiment with respect to a d-line preferably falls within a range from 1.60 to 1.85. A lower limit of the refractive index (n_d) is more preferably 1.65. An upper limit of the refractive index (n_d) is more preferably 1.80.

An abbe number (_Vd) of the optical glass according to the present embodiment preferably falls within a range from 20 to 35. A lower limit of the abbe number (_Vd) is more preferably 22. An upper limit of the abbe number (_Vd) is more preferably 30.

From a viewpoint of aberration correction of the lens, the optical glass according to the present embodiment preferably has a large partial dispersion ratio (P_g, _F). In view of such circumstance, the partial dispersion ratio (P_g, _F) of the optical glass according to the present embodiment is preferably 0.61 or more. A lower limit of the partial dispersion ratio (P_g, _F) is more preferably 0.62, further preferably 0.64. An upper limit of the partial dispersion ratio (P_g, _F) is not particularly limited, but may be, for example, 0.66.

From a viewpoint of aberration correction of the lens, the optical glass according to the present embodiment preferably has great abnormal dispersibility (ΔP_g, _F). In view of such circumstance, the value (ΔP_g, _F) indicating the abnormal dispersibility of the optical glass according to the present embodiment is preferably 0.015 or more. A lower limit of the value (ΔP_g, _F) indicating the abnormal dispersibility is more preferably 0.020, further preferably 0.030. An upper limit of the value (ΔP_g, _F) indicating the abnormal dispersibility is not particularly limited, but may be, for example, 0.055.

From the above-mentioned viewpoint, the optical glass according to the present embodiment can be suitably used as, for example, an optical element included in optical equipment. Such an optical element includes a mirror, a lens, a prism, a filter, and the like. Examples of an optical system in which the optical element described above is used include, for example, an objective lens, a condensing lens, an image forming lens, and an interchangeable camera lens. The optical system can be suitably used for an imaging device, such as a camera with an interchangeable lens and a camera with a non-interchangeable lens, and various optical devices such as a microscope device such as a fluorescence microscope and a multi-photon microscope. The optical device is not limited to the imaging device and the microscope described above, and also includes a telescope, a binocular, a laser range finder, a projector, and the like, which are not limited thereto. An example thereof will be described below.

Imaging Device

FIG. 1 is a perspective view illustrating one example of an optical device according to the present embodiment as an imaging device. An imaging device 1 is a so-called digital single-lens reflex camera (a lens-interchangeable camera), and a photographing lens 103 (an optical system) includes, as a base material, an optical element including the optical glass according to the present embodiment. A lens barrel 102 is mounted to a lens mount (not illustrated) of a camera body 101 in a removable manner. An image is formed with light, which passes through the lens 103 of the lens barrel 102, on a sensor chip (solid-state imaging elements) 104 of a multi-chip module 106 arranged on a back surface side of the camera body 101. The sensor chip 104 is a so-called bare chip such as a CMOS image sensor, and the multi-chip module 106 is, for example, a Chip On Glass (COG) type module including the sensor chip 104 being a bare chip mounted on a glass substrate 105.

FIGS. 2 and 3 are schematic diagrams illustrating another example of the optical device according to the present embodiment as an imaging device. FIG. 2 illustrates a front view of an imaging device CAM, and FIG. 3 illustrates a back view of the imaging device CAM. The imaging device CAM is a so-called digital still camera (a fixed lens camera), and a photographing lens WL (an optical system) includes an optical element including the optical glass according to the present embodiment, as a base material.

When a power button (not illustrated) of the imaging device CAM is pressed, a shutter (not illustrated) of the photographing lens WL is opened, light from an object to be imaged (a body) is converged by the photographing lens WL and forms an image on imaging elements arranged on an image surface. An object image formed on the imaging elements is displayed on a liquid crystal monitor M arranged on the back of the imaging device CAM. A photographer decides composition of the object image while viewing the liquid crystal monitor M, then presses down a release button B1 to capture the object image with the imaging elements. The object image is recorded and stored in a memory (not illustrated).

An auxiliary light emitting unit EF that emits auxiliary light in a case that the object is dark and a function button B2 to be used for setting various conditions of the imaging device CAM and the like are arranged on the imaging device CAM.

A higher resolution, low chromatic aberration, and a smaller size are demanded for the optical system to be used in such digital camera or the like. In order to achieve such demands, it is effective to use glass with dispersion characteristics different from each other as the optical system. Particularly, glass that achieves both low dispersion and a higher partial dispersion ratio (P_{g, F}) is highly demanded. From such a viewpoint, the optical glass according to the present embodiment is suitable as a member of such optical equipment. Note that, in addition to the imaging device described above, examples of the optical equipment to which the present embodiment is applicable include a projector and the like. In addition to the lens, examples of the optical element include a prism and the like.

Microscope

FIG. 4 is a block diagram illustrating an example of a configuration of a multi-photon microscope 2 according to the present embodiment. The multi-photon microscope 2 includes an objective lens 206, a condensing lens 208, and an image forming lens 210. At least one of the objective lens 206, the condensing lens 208, and the image forming lens 210 includes an optical element including, as a base material, the optical glass according to the present embodiment. Hereinafter, description is mainly made on the optical system of the multi-photon microscope 2.

A pulse laser device 201 emits ultrashort pulse light having, for example, a near infrared wavelength (approximately 1,000 nm) and a pulse width of a femtosecond unit (for example, 100 femtoseconds). In general, ultrashort pulse light immediately after being emitted from the pulse laser device 201 is linearly polarized light that is polarized in a predetermined direction.

A pulse division device 202 divides the ultrashort pulse light, increases a repetition frequency of the ultrashort pulse light, and emits the ultrashort pulse light.

A beam adjustment unit 203 has a function of adjusting a beam diameter of the ultrashort pulse light, which enters from the pulse division device 202, to a pupil diameter of the objective lens 206, a function of adjusting convergence and divergence angles of the ultrashort pulse light in order to correct chromatic aberration (a focus difference) on an axis of a wavelength of light emitted from a sample S and the wavelength of the ultrashort pulse light, a pre-chirp function (group velocity dispersion compensation function) providing inverse group velocity dispersion to the ultrashort pulse light in order to correct the pulse width of the ultrashort pulse light, which is increased due to group velocity dispersion at the time of passing through the optical system, and the like.

The ultrashort pulse light emitted from the pulse laser device 201 have a repetition frequency increased by the pulse division device 202, and is subjected to the above-mentioned adjustments by the beam adjustment unit 203. The ultrashort pulse light emitted from the beam adjustment unit 203 is reflected on a dichroic mirror 204 in a direction toward a dichroic mirror, passes through the dichroic mirror 205, is converged by the objective lens 206, and is radiated to the sample S. At this time, an observation surface of the sample S may be scanned with the ultrashort pulse light through use of scanning means (not illustrated).

For example, when the sample S is subjected to fluorescence imaging, a fluorescent pigment by which the sample S is dyed is subjected to multi-photon excitation in an irradiated region with the ultrashort pulse light and the vicinity thereof on the sample S, and fluorescence having a wavelength shorter than a near infrared wavelength of the ultrashort pulse light (hereinafter, also referred to “observation light”) is emitted.

The observation light emitted from the sample S in a direction toward the objective lens 206 is collimated by the objective lens 206, and is reflected on the dichroic mirror 205 or passes through the dichroic mirror 205 depending on the wavelength.

The observation light reflected on the dichroic mirror 205 enters a fluorescence detection unit 207. For example, the fluorescence detection unit 207 is formed of a barrier filter, a photo multiplier tube (PMT), or the like, receives the observation light reflected on the dichroic mirror 205, and outputs an electronic signal depending on an amount of the light. The fluorescence detection unit 207 detects the observation light over the observation surface of the sample S, in conformity with the ultrashort pulse light scanning on the observation surface of the sample S.

Note that, all the observation light emitted from the sample S in a direction toward the objective lens 206 may be detected by the fluorescence detection unit 211 by excluding the dichroic mirror 205 from the optical path. In that case, the observation light is de-scanned by a scanning means (not illustrated), passes through the dichroic mirror 204, is converged by the condensing lens 208, passes through a pinhole 209 provided at a position substantially conjugate to a focal position of the objective lens 206, passes through the image forming lens 210, and enters a fluorescence detection unit 211.

For example, the fluorescence detection unit 211 is formed of a barrier filter, a PMT, or the like, receives the observation light forming an image on a light formed by the image forming lens 210 reception surface of the fluorescence detection unit 211, and outputs an electronic signal depending on an amount of the light. The fluorescence detection unit 211 detects the observation light over the observation surface of the sample S, in conformity with the ultrashort pulse light scanning on the observation surface of the sample S.

The observation light emitted from the sample S in a direction opposite to the objective lens 206 is reflected on a dichroic mirror 212, and enters a fluorescence detection unit 213. The fluorescence detection unit 113 is formed of, for example, a barrier filter, a PMT, or the like, receives the observation light reflected on the dichroic mirror 212, and outputs an electronic signal depending on an amount of the light. The fluorescence detection unit 213 detects the observation light over the observation surface of the sample S, in conformity with the ultrashort pulse light scanning on the observation surface of the sample S.

The electronic signals output from the fluorescence detection units 207, 211, and 213 are input to, for example, a computer (not illustrated). The computer is capable of generating an observation image, displaying the generated observation image, storing data on the observation image, based on the input electronic signals.

Cemented Lens

FIG. 5 is a schematic diagram illustrating one example of a cemented lens according to the present embodiment. A cemented lens 3 is a compound lens including a first lens element 301 and a second lens element 302. The optical glass according to the present embodiment is used as at least one of the first lens element and the second lens element. The first lens element and the second lens element are joined through intermediation with a joining member 303. As the joining member 303, a publicly known adhesive agent or the like may be used. Note that, the “lens element” refers to each lens constituting a single lens or a cemented lens.

The cemented lens according to the present embodiment is effective in view of correction of chromatic aberration, and can be used suitably for the optical element, the optical system, and the optical device that are described above and the like. Furthermore, the optical system including the cemented lens can be used suitably for, especially, an interchangeable camera lens and an optical device. Note that, in the aspect described above, description is made on the cemented lens using the two lens elements. The present invention is however not limited thereto, and a cemented lens using three or more lens elements may be used. When the cemented lens uses three or more lens elements, it is only required that at least one of the three or more lens elements be formed by using the optical glass according to the present embodiment.

EXAMPLES

Next, description is made on Examples in the present invention and Comparative Examples. Note that, the present invention is not limited thereto.

Production of Optical Glasses

The optical glasses in each example and each comparative example were produced by the following procedures. First, glass raw materials selected from oxides, hydroxides, phosphate compounds (phosphates, orthophosphoric acids, and the like), carbonates, nitrates, and the like were weighed so as to obtain the compositions (mass%) illustrated in each table. Next, the weighed raw materials were mixed and put in a platinum crucible, melted at a temperature of from 1,100 to 1,350° C., and uniformed by stirring. After defoaming, the resultant was lowered to an appropriate temperature, poured in a mold, annealed, and molded. In this manner, each sample was obtained.

Evaluation of Physical Properties

FIG. 6 is a graph in which P_g,F and V_d of Examples and Comparative Examples are plotted.

Refractive Index (n_d) and Abbe Number (_Vd)

The refractive index (n_d) and the abbe number (V_d) in each of the samples were measured and calculated through use of a refractive index measuring instrument (KPR-2000 manufactured by Shimadzu Device Corporation). n_d indicates a refractive index of the glass with respect to light of 587.562 nm. V_d was obtained based on Expression (1) given below. n_c and n_F indicates refractive indexes of the glass with respect to light having a wavelength of 656.273 nm and light having a wavelength of 486.133 nm, respectively.

$\begin{array}{cc}{v}_{\text{d}}=\left({\text{n}}_{\text{d}}-1\right)/\left({\text{n}}_{\text{F}}-{\text{n}}_{\text{c}}\right)& \text{­­­(1)}\end{array}$

Partial Dispersion Ratio (P_g,_F)

The partial dispersion ratio (P_g,_F) in each of the samples indicates a ratio of partial dispersion (n_g - n_F) to main dispersion (n_F - n_c), and was obtained based on Expression (2) given below. n_g indicates a refractive index of the glass with respect to light having a wavelength of 435.835 nm. A value of the partial dispersion ratio (P_g,_F) was truncated to the third decimal place.

$\begin{array}{cc}{\text{P}}_{\text{g,F}}=\left({\text{n}}_{\text{g}}-{\text{n}}_{\text{f}}\right)/\left({\text{n}}_{\text{F}}-{\text{n}}_{\text{c}}\right)& \text{­­­(2)}\end{array}$

Abnormal Dispersibility (ΔP_g,F)

The abnormal dispersibility (ΔP_g,F) of each sample indicates a deviation from a partial dispersion ratio standard line with reference to two types of glass of F2 and K7 as glass having normal dispersion. In other words, on coordinates with a partial dispersion ratio (P_g,F) as a vertical axis and an abbe number v_g as a horizontal axis, a difference in ordinate between a straight line connecting two types of glass and a value of glass to be compared is a deviation of the partial dispersion ratio, i.e., abnormal dispersibility (ΔP_g,F). In the coordinate system described above, when a value of the partial dispersion ratio is located above the straight line connecting the types of glass as a reference, glass indicates positive abnormal dispersibility (+ΔP_g,F), and when the value is located below the straight line, glass indicates negative abnormal dispersibility (-ΔP_g,F). Note that, the abbe number V_d and the partial dispersion ratio (P_g,F) of F2 and K7 are as follows.

• F2: abbe number ν_d = 36.33, partial dispersion ratio (P_g,F) = 0.5834
• K7: abbe number ν_d = 60.47, partial dispersion ratio (P_g,F) = 0.5429
• A value of abnormal dispersibility (ΔP_g,F) is truncated to the third decimal place.

$\begin{array}{cc}\Delta {\text{P}}_{\text{g}}{,}_{\text{F}}={\text{P}}_{\text{g}}{,}_{\text{F}}-\left(-0.0016777\times v_{\text{d}}+0.6443513\right)& \text{­­­(3)}\end{array}$

Tables 1 to 36 illustrate a composition of components by mass% in terms of an oxide and evaluation results of physical properties for optical glass of Examples and Comparative Examples. “∑A₂O” in Expressions indicates a total content rate of Li₂O, Na₂O, and K₂O (A = Li, Na, K). “∑EO” in Expressions indicates a total content rate of MgO, CaO, SrO, BaO, and ZnO (E = Mg, Ca, Sr, Ba, Zn). In the first to third comparative examples, the optical glass could not be obtained, and thus physical properties were “unmeasurable”.

MASS %	EXAMPLE 1	EXAMPLE 2	EXAMPLE 3	EXAMPLE 4
P3O5	43.11	44.31	45.40	42.92
SiO3
B2O3
Li2O
Na2O	17.82	17.06	18.13	17.14
K2O	7.21	7.42	8.56	8.09
MgO
CaO
SrO
BaO	8.35	7.03	5.60	5.29
ZnO	2.24	2.31	1.54	1.46
Al2O8	1.52	1.56
TiO2	19.64	20.19	20.68	20.09
ZrO2
Nb2O5				4.94
Sb2O3	0.11	0.12	0.09	0.09
Ta 2O5
Y2O3
La2O3
Gd2O3
WO3
Bi2O3
TOTAL	100.00	100.00	100.00	100.00
nd	1.6633	1.67116	1.66813	1.68412
vd	27.03	26.37	25.72	25.58
Pg, F	0.634	0.635	0.639	0.635
Pg, F	0.035	0.035	0.038	0.034
Σ A2O	25.03	24.48	26.69	25.23
∑ EO	10.59	9.34	7.13	6.74
TiO2/P2O5	0.46	0.46	0.46	0.47
Al2O3/TiO2	0.08	0.06
B2O3/P2O5
TiO2/ (P2O5+B2O2+Al2O3)	0.44	0.44	0.46	0.47
TiO2/ (TiO2+Nb2O5+WO3+ Bi2O3+Ta2O5)	1.00	1.00	1.00	0.80
(BaO+TiO2) / P2O5	0.65	0.61	0.58	0.59
(BaO+TiO2+Nb2O5 +Ta2O5+WO3+Bi2O3) / (P2O5+B2O3+SiO2+Al2O3)	0.63	0.59	0.58	0.71
∑ A2O/TiO2	1.27	1.21	1.29	1.26
Σ EO/ΣA2O	0.42	0.38	0.27	0.27
SiO2+B2O3

MASS%	EXAMPLE 5	EXAMPLE 6	EXAMPLE 7	EXAMPLE 8
P2O8	45.09	43.78	48.14	44.83
SiO2
B2O3		2.78
Li2O			3.77
Na2O	19.26	13.77	12.08	23.47
K2O	6.59	7.33	8.05
MgO
CaO
SrO
BaO	8.43	8.48	6.02	5.60
ZnO		2.28	1.58	1.47
Al2O3		1.54
TiO2	20.54	19.94	20.23	24.50
ZrO2
Nb2O5
Sb2O3	0.09	0.12	0.13	0.12
Ta2O5
Y2O3
La2O3
Gd2O3
WO3
Bi2O3
TOTAL	100.00	100.00	100.00	100.00
nd	1.66718	1.67664	1.68424	1.68975
vd	26.14	27.26	25.52	25.11
Pg,f	0.637	0.630	0.638	0.636
Pg,f	0.036	0.032	0.036	0.033
Σ A2O	25.85	21.09	23.90	23.47
Σ EO	8.43	10.75	7.60	7.06
TiO2/P2O5	0.46	0.46	0.42	0.55
Al2O3/TiO2		0.08
B2O3/P2O5		0.06
TiO2/(P2O5+B2O3+Al2O3)	0.46	0.41	0.42	0.55
TiO2/ (TiO2+Nb2O5+WO3+ Bi2O3+Ta2O5)	1.00	1.00	1.00	1.00
(BaO+TiO2) /P2O5	0.64	0.65	0.55	0.67
(BaO+TiO2+Nb2O5 +Ta2O5 +WO3+Bi2O3)/ (P2O5+B2O3+SiO2+Al2O3)	0.64	0.59	0.55	0.67
Σ A2O/TiO2	1.26	1.06	1.18	0.96
Σ EO/Σ A2O	0.33	0.51	0.32	0.30
SiO2+B2O3		2.78

MASS %	EXAMPLE 9	EXAMPLE 10	EXAMPLE 11	EXAMPLE 12
P2O5	39.64	37.13	42.22	42.63
SiO2
B2O3	3.68	3.45
Li2O			1.77	1.20
Na2O	18.83	13.34	10.70	13.92
K2O	8.88	8.32	7.06	7.13
MgO
CaO
SrO
BaO	5.81	16.07	7.62	5.13
ZnO	1.59	1.49
Al2O3
TiO2	21.47	20.11	25.75	29.86
ZrO2
Nb2O5			4.76
Sb2O5	0.09	0.09	0.11	0.11
Ta2O5
Y2O3
La2O3
Gd2O3
WO3
Bi2O3
TOTAL	100.00	100.00	100.00	100.00
nd	1.66080	1.68280	1.75149	1.74476
vd	28.20	28.16	22.52	22.16
Pg,F	0.625	0.627	0.644	0.649
Pg,F	0.028	0.030	0.038	0.041
Σ A2O	27.71	21.66	19.53	22.26
Σ EO	7.40	17.56	7.62	5.13
TiO2/P2O5	0.54	0.54	0.61	0.70
Al2O3/TiO2
B2O5/P2O5	0.09	0.09
TiO2/ (P2O5+B2O5+Al2O3)	0.50	0.50	0.61	0.70
TiO2/ (TiO2+Nb2O5+WO5+ Bi2O2+Ta2O3)	1.00	1.00	0.84	1.00
(BaO+TiO2) /P2O3	0.69	0.97	0.79	0.82
(BaO+TiO2+Nb2O5 +Ta8O8+WO8+Bi2O2) /(P2O3+B2O2+SiO2+Al2O3)	0.63	0.89	0.90	0.82
Σ A2O/TiO2	1.29	1.08	0.76	0.75
Σ EO/ Σ A20	0.27	0.81	0.39	0.23
SiO2+B3O3	3.68	3.45

MASS%	EXAMPLE 13	EXAMPLE 14	EXAMPLE 15	EXAMPLE 16
P2O5	38.46	42.50	41.27	44.38
SiO3
B2O3	2.02
Li3O		1.78	1.02	1.86
Na2O	11.59	11.71	14.03	12.35
K2O	13.08	7.11	6.06	7.43
MgO
CaO
SrO
BaO	5.27	5.37	5.04	5.29
ZnO	6.16
Al2O3
TiO2	18.78	26.52	32.48	28.58
ZrO2
Nb2O3
Sb2O3	0.11	0.11	0.10	0.12
Ta2O3
Y2O3
La2O3
Gd3O3
WO3
Bi2O3	4.52	4.90
TOTAL	100.00	100.00	100.00	100.00
nd	1.67862	1.75015	1.75766	1.81066
vd	27.26	22.30	21.99	23.02
	0.630	0.645	0.647	0.634
	0.031	0.039	0.039	0.028
Σ A3O	24.67	20.59	21.11	21.64
Σ EO	11.43	5.37	5.04	5.29
TiO8/P2O5	0.49	0.62	0.79	0.64
Al3O3/TiO3
B2O3/P2O8	0.05
TiO2/ (P2O5+B2O3+Al2O2)	0.46	0.62	0.79	0.64
TiO2/ (TiO2+Nb3O3+WO2+ Bi3O3+Ta2O8)	0.81	0.84	1.00	1.00
(BaO+TiO2) /P2O6	0.63	0.75	0.91	0.76
(BaO+TiO3+Nb2O5 +Ta2O6+WO3+Bi2O2) / (P2O5+B2O3+SiO2+Al2O2)	0.71	0.87	0.91	0.76
Σ A2O/TiO2	1.31	0.78	0.65	0.76
Σ EO/ Σ A2O	0.46	0.26	0.24	0.24
SiO2+B3O3	2.02
indicates text missing or illegible when filed

MASS %	EXAMPLE 17	EXAMPLE 18	EXAMPLE 19	EXAMPLE 20
P2O5	45.00	44.32	43.47	42.87
SiO2
B2O3
Li2	2.60
Na2O		19.27	17.97	17.72
K2O	19.87	7.42	7.27	7.17
MgO
CaO
SrO
BaO	11.86	5.49	6.17	6.09
ZnO	2.34	1.49	2.26	2.23
Al2O	1.80
TiO3	16.41	18.57	18.22	17.97
ZrO2
Nb2O5		2.68
Sb2O2	0.12	0.06	0.06	0.06
Ta2O3
Y2O3
La2O3
Gd2O3
WO3		0.70	4.59	4.52
Bi2O8				1.36
TOTAL	100.00	100.00	100.00	100.00
ad	1.65697	1.66138	1.66615	1.66908
vd	28.39	26.85	26.50	26.50
	0.627	0.631	0.63	0.635
	0.030	0.032	0.033	0.035
ΣA2O	22.48	26.68	25.24	24.89
ΣEO	14.20	6.96	8.43	8.32
TiO2/P3O5	0.36	0.42	0.42	0.42
Al3O2/TiO3	0.11
B2O2/P3O8
TiO2/ (P2O3 +B2O2+Al3O3)	0.35	0.42	0.42	0.42
TiO2/ (TiO2+Nb2O5+WO3+ Bi2O3Ta3O8)	1.00	0.85	0.80	0.75
(BaO+TiO2) /P2O8	0.63	0.54	0.56	0.56
(BaO+TiO2+Nb2O8 +Ta2O8+WO3+Bi 2O3) /(P2O8+B2O3+SiO3+Al2O2)	0.60	0.62	0.67	0.70
Σ A2O/TiO2	1.37	1.44	1.39	1.39
Σ EO/ Σ A2O	0.63	0.26	0.33	0.33
SiO2+B2O2
indicates text missing or illegible when filed

MASS %	Example 21	EXAMPLE 22	EXAMPLE 23	EXAMPLE 24
P2O5	44.34	41.09	46.69	45.90
SiO2 SiO2		1.11
B2O3
Li2O		0.61	0.69	0.68
Na2O	18.32	12.42	14.11	13.87
K2O	7.42	7.74	8.80	8.65
MgO			4.40
CaO				6.02
SrO
BaO	6.30	21.81	8.02	7.89
ZnO	2.31
Al2O3
TiO2	18.58	15.11	17.17	16.88
ZrO2
Nb2O5	2.68
Sb2O3	0.06	0.11	0.12	0.12
Ta2O5
Y2O3
La2O3
Gd2O2
WO3
Bi2O3
TOTAL	100.00	100.00	100.00	100.00
nd	1.66545	1.66162	1.65551	1.65787
vd	26.72	28.9	28.23	28.57
Pg, F	0.633	0.630	0.633	0.631
◁Pg, F	0.034	0.034	0.036	0.034
ΣA3O	25.74	20.76	23.59	23.19
ΣEO	8.60	21.81	12.43	13.91
TiO2/P3O8	0.42	0.37	0.37	0.37
Al8O3/TiO2
B8O3/P2O6
TiO8/ (P2O8+B2O3+Al2O8)	0.42	0.37	0.37	0.37
TiO3/ (TiO2+Nb8O8+WO2Bi2+Bi2O3+Ta2O5)	0.87	1.00	1.00	1.00
(BaO+TiO2) /P8O5	0.56	0.90	0.54	0.54
(BaO+TiO2+Nb2O5+Ta5O8+WO2+Bi3O3) /(P3O5+B2O3+SiO2+Al2O3)	0.62	0.87	0.54	0.54
Σ A2O/TiO2	1.39	1.37	1.37	1.37
Σ E0/ Σ A2O	0.33	1.05	0.53	0.60
SiO2+B5O3		1.11

MASS%	EXAMPLE 25	EXAMPLE 26	EXAMPLE 27	EXAMPLE 28
P2O8	43.67	40.86	40.93	40.86
SiO2
B2O8
Li2O	0.64	0.60	0.60	0.60
NaaO	13.19	12.35	12.37	12.35
K2O	8.23	7.70	7.71	7.70
MgO
CaO
SrO	10.59
BaO	7.51	21.69	21.72	21.69
ZnO
Al2O3
TiO2	16.06	15.03	15.05	16.03
ZrO3
Nb2O3
Sb2O3	0.12	0.11	0.11	0.11
Ta2O3
Y2O3		1.66
La2O2			1.50
Gd2O8				1.67
WO 3
Bi2O3
TOTAL	100.00	100.00	100.00	100.00
nd	1.65953	1.66630	1.66633	1.66635
vd	28.67	29.13	29.05	28.96
	0.631	0.630	0.630	0.631
	0.035	0.035	0.034	0.035
Σ A2O	22.06	20.65	20.68	20.65
Σ EO	18.09	21.69	21.72	21.69
TiO2/P2O5	0.37	0.37	0.37	0.37
Al2O3/TiO3
B3O2/P3O5
TiO2/ (P2O5+B2O2+Al2O3)	0.37	0.37	0.37	0.37
TiO2/ (TiO2+Nb2O5+WO3+ Bi2O3+Ta2O5)	1.00	1.00	1.00	1.00
(BaO+TiO2) /P2O5	0.54	0.90	0.90	0.90
(BaO+TiO2+Nb2O5+Ta2O8+WO3+Bi2O8) /(P2O3+B2O3+SiO2+Al2O3)	0.54	0.90	0.90	0.90
Σ A2O/TiO2	1.37	1.37	1.37	1.37
Σ E0/ Σ A2O	0.82	1.05	1.05	1.05
SiO2+B3O3
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MASS %	EXAMPLE 29	EXAMPLE 30	EXAMPLE 31	EXAMPLE 32
P2O8	40.96	41.13	41.60	44.31
SiO2
B8O3
Li2O	0.60	0.61	0.61
Na3 O	12.38	12.43	12.57	17.06
K2 O	7.72	7.75	7.84	7.42
MgO
CaO
SrO
BaO	21.74	21.83	22.08	7.03
ZnO				2.31
Al2O2				1.56
TiO2	15.06	15.13	15.30	20.19
ZrO8		1.03
Nb3O8
Sb2O8	0.11	0.11		0.12
Ta2O8	1.42
Y2O3
La2O3
Gd2O3
WO3
Bi2O3
TOTAL	100.00	100.00	100.00	100.00
n4	1.66723	1.66720	1.66413	1.67115
v8	28.70	28.96	28.76	26.37
	0.630	0.632	0.633	0.635
	0.034	0.036	0.036	0.035
Σ A2 O	20.70	20.78	21.02	24.48
Σ EO	21.74	21.83	22.08	9.84
TiO2/P2O5	0.37	0.37	0.37	0.46
Al2O8/TiO2				0.08
B2O5/P2O5
TiO2/ (P2O5+B3O3+Al2O2)	0.37	0.37	0.37	0.44
TiO2/ (TiO2+Nb2O8+WO2+ Bi2O3+Ta2O8)	0.91	1.00	1.00	1.00
(BaO+TiO2) /P2O8	0.90	0.90	0.90	0.61
(BaO+TiO2+Nb2O6 +Ta2O8+WO3+Bi2O2) /(P2O5+B2O2+SiO2+Al2O2)	0.93	0.90	0.90	0.59
Σ A3O/TiO2	1.37	1.37	1.37	1.21
Σ E0/ Σ A2O	1.05	1.05	1.05	0.38
SiO2+B3O3
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MASS %	EXAMPLE 33	EXAMPLE 34	EXAMPLE 35	EXAMPLE 36
P2O6	45.40	42.92	45.09	43.78
SiO8
B8O3				2.78
Li2O
na2O	18.13	17.14	19.26	13.77
K2O	8.56	8.09	6.59	7.33
MgO
CaO
SrO
BaO	5.60	5.29	8.43	8.48
ZnO	1.54	1.45		2.28
Al2O3				1.54
TiO2	20.68	20.09	20.54	19.94
ZrO8
Nb2O8		4.94
Sb2O2	0.09	0.09	0.09	0.12
Ta2O8
Y2O8
La2O3
Gd2 O 3
WO3
B i2O8
TOTAL	100.00	100.00	100.00	100.00
n4	1.66813	1.68412	1.66718	1.67654
v4	25.72	25.58	26.14	27.26
	0.639	0.635	0.637	0.630
	0.038	0.034	0.036	0.032
Σ A2 O	26.69	25.23	25.86	21.09
Σ E O	7.13	6.74	8.43	10.75
TiO2/P2O8	0.46	0.47	0.46	0.46
Al2O3/TiO2				0.08
B2O3/P2O3				0.06
TiO2/ (P2O8+B2O3+Al2O2)	0.46	0.47	0.46	0.41
TiO3/(Ti2+Nb3O8+WO3+Bi2O3+Ta2O5)	1.00	0.80	1.00	1.00
(BaO+TiO2)/P2O6	0.58	0.59	0.64	0.65
(BaO+TiO3+Nb8O6 +Ta2O5+WO3+Bi2O3) /(P2O5+B2O3+Si2+Al2O8)	0.58	0.71	0.64	0.59
Σ A3O/TiO2	1.29	1.26	1.26	1.06
Σ EO/Σ A2O	0.27	0.27	0.33	0.51
SiO2+B2O3				2.78
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MASS %	EXAMPLE 37	EXAMPLE 38	EXAMPLE 39	EXAMPLE 40
P2O8	48.14	44.83	39.64	37.13
SiO2
B2O3			8.68	3.45
Li2O	8.77
Na2O	12.08	23.47	18.83	13.34
K2O	8.05		8.88	8.32
MgO
CaO
SrO
BaO	6.02	5.60	5.81	16.07
ZnO	1.58	1.47	1.59	1.49
Al2O3
TiO2	20.23	24.50	21.47	20.11
ZrO2
Nb2O5
Sb2O3	0.13	0.12	0.09	0.09
Ta2U5
Y2O5
La2O3
Gd2O3
WO3
Bi2O3
TOTAL	100.00	100.00	100.00	100.00
ni	1.68424	1.68975	1.66080	1.68280
vd	25.52	25.11	28.20	28.16
	0.638	0.636	0.625	0.627
	0.036	0.033	0.028	0.030
ΣA2O	23.90	23.47	27.71	21.66
ΣEO	7.60	7.08	7.40	17.56
TiO2/P2O5	0.42	0.55	0.54	0.54
Al2O3/TiO2
B2O3/P2O5			0.09	0.09
TiO3/ (P2O3+B2O3+Al2O3	0.42	0.55	0.50	0.50
TiO2/ (TiO2+Nb2O5+WO3+ Bi2O3+Ta2O5)	1.00	1.00	1.00	1.00
(BaO+TiO2) /P8O5	0.55	0.67	0.69	0.97
(BaO+TiO2+Nb2O5 +Ta2O8+WO3+Bi2O3) /(P8O8+B2O8+Si3+Al2O3)	0.55	0.67	0.63	0.89
Σ A3O/TiO2	1.18	0.96	1.29	1.08
Σ E0/ Σ A2O	0.32	0.30	0.27	0.81
SiO2+B2O3			3.68	3.45
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MASS %	EXAMPLE 41	EXAMPLE 42	EXAMPLE 43	EXAMPLE 44
P2O5	35.25	34.54	32.62	35.11
SiO2
B2O3
Li2O	0.99	0.97	0.92
Na2O	11.51	11.28	10.65	11.92
K2O	5.90	5.78	5.46	5.18
MgO
CaO
SrO
BaO
ZnO
Al2O3	1.81	1.77	1.67	1.59
TiO2	20.57	20.16	17.09	16.23
ZrO2
Nb2n3
Sb2O3	0.09	0.09	0.09	0.08
Ta2O3
Y2O2
La2O3
Gd2O3
WO5	7.80	5.66	9.09	8.63
Bi2O3	16.08	19.75	22.41	21.27
TOTAL	100.00	100.00	100.00	100.00
ni	1.76276	1.76663	1.77271	1.75803
v4	23.06	23.25	23.37	23.44
P	0.639	0.637	0.636	0.638
	0.034	0.032	0.030	0.033
Σ A2 O	18.40	18.03	17.03	17.10
Σ E O
TiO2/P8O5	0.58	0.58	0.52	0.46
Al2O2/TiO2	0.09	0.09	0.10	0.10
B2O3/P2O5
TiO2/ (P3O8+B2O3+Al3O8)	0.56	0.56	0.50	0.44
TiO3/ (TiO8+Nb2O3+WO3+ Bi2O8+Ta2O8	0.46	0.44	0.35	0.35
(BaO+TiO2) /P2O8	0.58	0.58	0.52	0.46
(BaO+TiO3+Nb2O5 +Ta2O8+WO3+Bi2O3) /(P2O3+B2O2+SiO2+Al2O3	1.20	1.25	1.42	1.26
Σ A8O/TiO2	0.89	0.89	1.00	1.05
Σ EO/ Σ A5O
SiO22+B3O3
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MASS %	EXAMPLE 45	EXAMPLE 46	EXAMPLE 47	EXAMPLE 48
P2O5	30.71	36.47	37.93	30.35
SiO2
B2O2
Li2O
Na2O	10.03	12.38	12.88	9.91
K2O	5.14	5.38	5.60	5.08
MgO
CaO
SrO
BaO
ZnO
Al2O3	1.57	1.65	1.71	1.55
TiO2	16.09	16.85	17.53	15.31
ZrO2
Nb2On
Sb2O3	0.08	0.09	0.09	0.08
Ta2O5
Y2O
La2O3
Gd2O3
WO3	15.28	12.80	17.31	16.85
Bi2O3	21.10	14.39	6.95	20.86
TOTAL	100.00	100.00	100.00	100.00
nd	1.78911	1.74422	1.72734	1.78605
vd	22.50	23.56	23.89	22.69
	0.639	0.638	0.637	0.637
	0.033	0.033	0.033	0.031
ΣA2O	15.17	17.76	18.48	14.99
ΣEO
TiO3/P2O5	0.52	0.46	0.46	0.50
Al2O8/TiO2	0.10	0.10	0.10	0.10
B2O3/P8O5
TiO2/ (P3O8+B2O55+Al2O3)	0.50	0.44	0.44	0.48
TiO2/ (TiO2+Nb2O5+WO3+ Bi2O3+Ta2O3)	0.31	0.38	0.42	0.29
(BaO+TiO2) /P2O8	0.52	0.46	0.46	0.50
(BaO+TiO2+Nb2O8 +Ta3O8+WO3+Bi2O3) /(P2O8+B8O8+SiO2+Al2O3)	1.63	1.16	1.05	1.66
Σ A2O/TiO2	0.94	1.05	1.05	0.98
Σ EO/ ΣA2O
SiO8+B2O3
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MASS %	EXAMPLE 49	EXAMPLE 50	EXAMPLE 51	EXAMPLE 52
P2O3	33.24	29.67	38.86	36.59
SiO2
B2O3
Li3O	0.94		1.62	2.90
Na2 O	14.51	7.41	12.69	15.98
K2O		4.97	6.50
MgO
CaO
SrO
BaO		5.64
ZnO
Al2O3	1.70	1.52
TiO2	17.42	15.55	21.88	19.18
ZrO2
Nb2O3
Sb2O3	0.09	0.08	0.10	0.10
Ta2O3
Y2O2
La2O3
Gd3O3
WO2	9.27	14.77
Bi2O3	22.84	20.39	18.34	25.27
TOTAL	100.00	100.00	100.00	100.00
nd	1.77604	1.80301	1.75238	1.75526
Vd	23.54	22.62	23.10	24.47
	0.634	0.638	0.639	0.629
	0.029	0.031	0.033	0.026
∑ A3O	15.45	12.38	20.82	18.87
∑ EO		5.64
TiO8/P2O5	0.52	0.52	0.56	0.52
Al3O3/Ti8	0.10	0.10
B2O8/P8B8
TiO/2 (P2O6+B2O3+ Al8O3)	0.50	0.50	0.56	0.52
TiO2/ (Ti8+Nb3O8+WO2+ Bi2O3+Ta8O3)	0.35	0.31	0.54	0.43
(BaO+TiO2) / P8O8	0.52	0.71	0.56	0.52
(BaO+TiO2+Nb2O3 +Ta8O5+WO3+Bi2O2) / (P2O5+B2O8+SiO2+Al2O3)	1.42	1.81	1.03	1.21
∑ A8O/Ti2	0.89	0.80	0.95	0.98
∑ EO/ ∑ A3O		0.46
SiO2+B8O3
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MASS %	EXAMPLE 53	EXAMPLE 54	EXAMPLE 55	EXAMPLE 56
P2 O3	28.71	42.65	36.90	42.21
SiO2			1.09
B3O3
Li2O		2.47	1.54
Na3O	4.97		9.35	14.33
K2O	4.80	18.83	6.17	6.23
MgO
CaO
SrO
BaO	10.91	11.23	6.66
ZnO		2.22		2.14
Al2O3	1.47	1.50
TiO2	15.05	15.55	20.77	22.19
ZrO2
Nb2O5
Sb3O3	0.08	0.11	0.10	0.10
Ta3O3
Y2O3
La2O2
Gd3O3
WO3	14.29
Bi2O3	19.73	5.43	17.41	12.80
TOTAL	100.00	100.00	100.00	100.00
nd	1.81066	1.67374	1.76761	1.73607
vd	23.02	27.62	22.94	22.88
	0.634	0.627	0.640	0.639
	0.028	0.029	0.035	0.033
∑ A3O	9.77	21.30	17.07	20.56
∑ EO	10.91	13.46	6.66	2.14
TiO8/P2O5	0.52	0.36	0.56	0.53
Al2O3/TiO2	0.10	0.10
B2O3/P2O5
TiO8/ (P3O5+B8O3+Al2O8)	0.50	0.35	0.56	0.53
TiO8/ (TiO2+Nb3O5+WO3+ Bi2O5+Ta2O3)	0.31	0.74	0.54	0.63
(BaO+TiO2) /P2O8	0.90	0.63	0.74	0.53
(BaO+TiO2+Nb8O8 +Ta2O5+WO2+Bi2O8)/ (P3O8+B8O3+SiO8+Al3O3)	1.99	0.73	1.18	0.83
∑ A8O/Ti8	0.65	1.37	0.82	0.93
∑ EO/ ∑ A 2O	1.12	0.63	0.39	0.10
SiO8+B8O3			1.09
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MASS %	EXAMPLE 57	EXAMPLE 58	EXAMPLE 59	EXAMPLE 60
P2O2	29.37	29.41	29.31	29.01
SiO2
B2O3	1.01
Li3O
Na2O	7.34	7.35	7.32	7.25
K2O	4.92	4.92	4.90	4.85
MgO		0.88
Ca O			1.22
SrO				2.23
BaO	5.58	5.59	5.57	5.51
ZnO
Al2O3	1.50	1.51	1.50	1.49
TiO2	15.40	15.42	15.36	15.21
ZrO2
Nb2O5
Sb2O3	0.08	0.08	0.08	0.08
Ta8O5
Y3O3
La2O3
Gd2O3
WO3	14.62	14.64	14.59	14.44
Bi3O3	20.18	20.21	20.14	19.93
TOTAL	100.00	100.00	100.00	100.00
nd	1.79468	1.79736	1.79719	1.79614
vd	23.17	23.06	23.21	23.29
	0.634	0.637	0.636	0.635
	0.029	0.031	0.031	0.030
∑ A 2 O	12.25	12.27	12.23	12.10
∑ E O	5.58	6.47	6.79	7.75
TiO2/P3O8	0.52	0.52	0.52	0.52
Al2O3/Ti2	0.10	0.10	0.10	0.10
B2O3/P2O5	0.03
TiO3/ (P8O5+B2O3+Al3O3)	0.48	0.50	0.50	0.50
TiO2/ (TiO2+Nb2O3+WO3+ Bi3O3+Ta2O5)	0.31	0.31	0.31	0.31
(BaO+TiO3) /P2O5	0.71	0.71	0.71	0.71
(BaO+TiO2+Nb3O5 +Ta2O8+WO3+Bi2O3) / (P8O5+B8O5+SiO3+Al8O8	1.75	1.81	1.81	1.81
∑ A2O/TiO8	0.80	0.80	0.80	0.80
∑ E0/ ∑ A2O	0.46	0.53	0.56	0.64
Si8O2+B2O3	1.01
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MASS	EXAMPLE 61	EXAMPLE 62	EXAMPLE 63	EXAMPLE 64
P2O2	29.11	29.11	28.74	29.19
SiO2
B2O3
Li3O
Na2O	7.34	7.37	7.18	7.29
K2O	4.92	4.87	4.81	4.88
MgO
CaO
SrO
BaO	6.59	5.53	5.46	5.55
Zn0
Al2O3	1.51	1.49	1.47	1.50
TiO2	15.41	16.25	15.06	15.30
ZrO2	0.90
Nb2O2		1.92
Sb2O2	0.08	0.08	0.08	0.08
Ta2O6			3.15
Y2O6				1.63
La2Os
Gd3O2
WO3	14.64	14.48	14.30	14.53
Bi3Os	20.21	20.00	19.75	20.06
TOTAL	100.00	100.00	100.00	100.00
nd	1.79949	1.80754	1.80652	1.79792
vd	23.01	22.57	22.70	23.21
	0.635	0. 637	0.634	0.636
	0.029	0.031	0.027	0.030
Σ A 2 O	12.27	12.14	11.99	12.17
Σ E O	5.59	5.59	5.46	5.55
TiO2/P2O2	0.52	0.52	0.52	0.52
Al2O3/TiO2	0.10	0.10	0.10	0.10
B8O2/P2O5
TiO2/ (P2O5+B2O3+Al2O3)	0.50	0.50	0.50	0.50
TiO2/ (TiO2+Nb2O8+WO3+ Bi2O3+Ta3O8	0.31	0.30	0.29	0.31
(BaO+TiO2) /P2O8	0.71	0.71	0.71	0.71
(BaO+Ti2+Nb2O8 +Ta3O8+WO3+Bi2O3) / (P2O8+B8O3+SiO2+Al2O3	1.81	1.87	1.91	1.61
Σ A3O/TiO3	0, 80	0.80	0.80	0.80
Σ EO/ Σ A2O	0.46	0.46	0.46	0.46
SiO8+B2O3
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MASS	EXAMPLE 63	EXAMPLE 66	EXAMPLE 67	EXAMPLE 68
P2O3	28.90	29.36	28.73	28.66
SiO4
B2O3
Li2O
Na2O	7.22	7.33	7.17	7.16
K2O	4.84	4.91	4.81	4.80
MgO
CaO
SrO
BaO	5.49	5.58	5.46	5.45
ZnO
Al2O3	1.48	1.50	1.47	1.47
TiO2	15.15	15.39	15.06	15.02
ZrO2
Nb2O4			4.92	15.01
Sb2O3	0.08	0.08
Ta2Os
Y2O3
La2O3		1.07
Gd2Os	2.60
WO2	14.38	14.61	12.65	2.74
Bi3O3	19.86	20.17	19.74	19.70
TOTAL	100.00	100.00	100.00	100.00
nd	1.80073	1.80153	1.81691	1.83290
vd	23.13	22.91	22.36	21.96
	0.634	0.632	0.639	0.638
	0.028	0.026	0.032	0.031
Σ A 2 O	12.06	12.24	11.98	11.96
Σ E O	5.49	5.58	5.46	5.45
TiO3/P2O8	0.52	0.52	0.52	0.52
Al8O2/Ti2	0.10	0.10	0.10	0.10
B8O3/P2O8
TiO8/ (P2O5+B8O3+Al8O3	0.50	0.50	0.50	0.50
TiO8/ (TiO3+Nb8O5+WO3+Bi8+Ta8O5)	0.31	0.31	0.29	0.29
(BaO+TiO2) /P2O5	0.71	0.71	0.71	0.71
(BaO+TiO3+Nb2O5 +Ta3O5+WO3+Bi3O2) / (P2O5+B2O2+SiO3Al2O2)	1.81	1.81	1.91	1.92
Σ A2O/TiO3	0.80	0.80	0.80	0.80
Σ EO/ Σ A2O	0.46	0.46	0.46	0.46
SiO3+B5O8
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MASS %	EXAMPLE 69	EXAMPLE 70	EXAMPLE 71	EXAMPLE 72
P2O3	45.89	46.96	45.20	44.85
SiO2
B2O3
Li2O
Na2O	18.96	19.41	18.68	17.27
K2O	7.68	7.86	7.56	9.43
MgO
CaO
SrO
BaO	4.08	4.17	4.02	3.99
ZnO	2.39	2.44	2.35	2.33
Al3O3	1.62	1.66	1.59	1.58
TiO2	19.39	17.51	20.59	20.43
ZrO2
Nb2O3
Sb2O3				0.12
Ta2O3
Y2O3
La3O3
Gd2O3
WO2
B i2O3
TOTAL	100.00	100.00	100.00	100.00
nd	1.61155	1.63762	1.65940	1.66443
vd	31.26	28.58	26.87	26.27
	0.618	0.627	0.633	0.636
	0.027	0.031	0.033	0.036
Σ A8 O	26.64	27.26	26.24	26.70
Σ E O	6.47	6.62	6.37	6.32
TiO2/P2O5	0.42	0.37	0.46	0.46
Al2O2/TiO2	0.08	0.09	0.08	0.08
B2O2/P2O2
TiO2/(P2O5+B2O3+Al3O3)	0.41	0.36	0.44	0.44
TiO2/ (TiO2+Kb2O2+WO3+ Bi2O3+Ta2O3)	1.00	1.00	1.00	1.00
(BaO+TiO2) /P2O3	0.51	0.46	0.54	0.54
(BaO+TiO2+Nb2O3 +Ta2O5+WO3+Bi2O3) /- (P2O2+B8O3+SiO2+ Al2O2)	0.49	0.45	0.53	0.53
Σ A3O/TiO2	1.37	1.56	1.27	1.31
Σ EO/ Σ A3O	0.24	0.24	0.24	0.24
SiO3+B3O3
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MASS %	EXAMPLE 73	EXAMPLE 74	EXAMPLE 75	EXAMPLE 76
P2O3	45.11	47.45	44.73	44.20
SiO3			0.92
B2O2	0.71			2.10
Li2O
Na2O	18.01	17.88	18.49	18.21
K2O	7.55	7.24	7.49	7.40
MgO
CaO
SrO
BaO	4.01	3.84	3.98	3.93
ZnO	2.35	2.25	2.33	2.30
Al2O3	1.59	1.52	1.58	1.56
TiO2	20.55	19.70	20.38	20.13
ZrO2
Nb2O5
Sb2O3	0.12	0.11	0.12	0.12
Ta2O5
Y2O3
La2O3
Gd3O3
WO2
Bi3O3
TOTAL	100.00	100.00	100.00	100.00
nd	1.66496	1.66163	1.66204	1.65893
vd	26.67	26.47	26.63	27.67
	0.633	0.634	0.633	0.629
	0.033	0.034	0.034	0.031
Σ A2O	25.56	25.11	25.97	25.66
Σ EO	6.36	6.10	6.30	6.23
TiO2/P2O5	0.46	0.42	0.46	0.46
Al2O3/TiO2	0.08	0.08	0.08	0.08
B2O5/P2O8	0.02			0.05
TiO2/ (P3O5+B2O2+Al3O3)	0.43	0.40	0.44	0.42
TiO2/ (TiO2+NB2O5+WO5+ Bi2O2+Ta2O5)	1.00	1.00	1.00	1.00
(BaO+TiO2) /P2O5	0.54	0.50	0.54	0.54
(BaO+TiO2+Nb2O5 +Ta2O5+WO3+Bi2O2) /(P2O2+b2O3+SiO2+Al2O3)	0.52	0.48	0.52	0.50
Σ A8O/TiO2	1.24	1.27	1.27	1.27
Σ E0/ Σ A20	0.25	0.24	0.24	0.24
SiO2+B8O3	0.71		0.92	2.10
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MASS %	EXAMPLE 77	EXAMPLE 78	EXAMPLE 79	EXAMPLE 80
P2 O3	44.73	44.30	43.87	44.59
SiO2
B8O3
Li2O	0.91
Na3O	18.49	20.18	18.13	18.43
K3O	7.49	7.41	10.16	7.46
MgO				1.23
CaO
SrO
BaO	3.98	3.94	3.90	3.96
ZnO	2.33	2.31	2.28	2.32
Al2O3	1.58	1.56	1.55	1.57
TiO3	20.38	20.18	19.99	20.31
ZrO2
Nb2O3
Sb2O3	0.12	0.12	0.12	0.12
Ta2O3
Y8O3
La2O3
Gd3O3
WO3
Bi2O3
TOTAL	100.00	100.00	100.00	100.00
nd	1.66592	1.65721	1.65541	1.66062
Vd	26.59	27.16	27.01	27.17
	0.635	0.632	0.634	0.630
	0.035	0.033	0.035	0.031
Σ A2O	213.89	27.60	28.30	26.89
Σ EO	6.30	6.24	6.18	7.51
TiO2/P3O5	0.46	0.46	0.46	0.46
Al2O3/TiO2	0.08	0.08	0.08	0.08
B2O2/P2O3
TiO2/ (P2O3+B2O2+Al2O3)	0.44	0.44	0.44	0.44
TiO2/ (TiO3+Nb2O5+WO2 + Bi2O3+Ta2O5	1.00	1.00	1.00	1.00
(BaO+TiO2) /P2O5	0.54	0.54	0.54	0.54
(BaO+TiO2+Nb2O5 +Ta3O3+WO3+Bi 2O2) /- (P2O3+B2O3+SiO2+Al2O3)	0.53	0.53	0.53	0.53
Σ A2O/TiO2	1.32	1.37	1.42	1.27
Σ EO/ Σ A2O	0.23	0.23	0.22	0.29
SiO2+B2O3
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MASS %	EXAMPLE 81	EXAMPLE 82	EXAMPLE 83	EXAMPLE 84
P2O5	44.38	43.11	44.04	44.06
SiO2
B2O3
L12O
Na3O	18.34	17.82	18.20	18.21
К3O	7.43	7.21	7.37	7.37
MgO
CaO	1.70
SrO
BaO	3.94	8.35	3.91	3.92
ZnO	2.31	2.24	4.74	2.29
Al2O3	1.56	1.52	1.55	1.55
TiO2	20.22	19.64	20.06	22.48
ZrO2
Nb2O5
Sb2O3	0.12	0.11	0.12	0.12
Ta2O5
Y2O3
La2O2
Gd2O3
WO3
Bi2O3
TOTAL	100.00	100.00	100.00	100.00
nd	1.66410	1.66633	1.66526	1.67912
vd	27.00	27.03	26.78	25.50
	0.633	0.634	0.633	0.637
	0.034	0.035	0.034	0.035
∑A2O	25.77	25.03	25.57	25.58
∑EO	7.95	10.59	8.65	6.21
TiO2/P2O8	0.46	0.46	0.46	0.51
Al2O3/TiO2	0.08	0.08	0.08	0.07
B2O2/P2O5
TiO2/ (P2O3+B2O3+Al2O3)	0.44	0.44	0.44	0.49
TiO3/ (TiO2+Nb2O3+WO3+ Bi2O2+Ta2O5)	1.00	1.00	1.00	1.00
(BaO+TiO2) /P2O5	0.54	0.65	0.54	0.60
(BaO+TiO2+Nb2O3 +Ta2O5+WO2+Bi2O3)/ (P3O5+B2O3+SiO2+Al2O3)	0.53	0.63	0.53	0.58
∑A2O/TiO2	1.27	1.27	1.27	1.14
∑BO/ ∑A2O	0.31	0.42	0.34	0.24
SiO2+B2O2
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MASS %	EXAMPLE 85	EXAMPLE 86	EXAMPLE 87	EXAMPLE 88
P2O5	44.58	42.13	39.48	43.68
SiO2
B2O3
Li2O
Na2O	18.43	17.41	16.31	18.05
K2O	7.46	7.05	6.61	7.31
MgO
CaO
SrO
BaO	3.96	3.75	3.51	3.98
ZnO	2.32	2.19	2.05	2.27
Al2O3	1.57	1.49	1.39	1.54
TiO3	20.31	19.19	17.98	19.90
ZrO2	1.25
Nb2O5
Sb3O3	0.12	0.11	0.10	0.12
Ta2O3
Y2O3
La2Os				3.24
Gd2O3
WO3		6.67
Bi2O2			12.56
TOTAL	100.00	100.00	100.00	100.00
nd	1.66738	1.67562	1.69631	1.66770
vd	26.56	26.17	25.90	27.01
	0.634	0.632	0.632	0.634
	0.035	0.032	0.031	0.035
∑A2O	25.89	24.46	22.92	25.36
∑EO	6.28	5.94	5.56	6.16
TiO2/P2O6	0.46	0.46	0.46	0.46
Al3O2/TiO3	0.08	0.08	0.08	0.08
B2O3/P2O6
TiO2/ (P2O5+B2O3+Al2O3)	0.44	0.44	0.44	0.44
TiO2/ TiO2+Nb2O5+WO2+ Bi2O3+Ta2O5	1.00	0.74	0.59	1.00
(BaO+TiO2) /P2O5	0.54	0.54	0.54	0.54
(BaO+TiO2+Nb2O5 +Ta2O3+WO3+Bi2O5) / (P3O8+B2O2+SiO2+Al3O3)	0.53	0.68	0.83	0.53
∑A2O/TiO2	1.27	1.27	1.27	1.27
∑EO/ ∑A2O	0.24	0.24	0.24	0.24
SiO2+B2O2
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MASS %	EXAMPLE 89	EXAMPLE 90	EXAMPLE 91	EXAMPLE 92
P2O5	44.12	43.53	46.08	46.20
SiO3
B2O2			1.43
Li2O
Na2O	18.24	17.99	17.36	17.41
K2O	7.38	7.28	7.54	7.56
MgO
CaO				1.15
SrO
Ba0	3.92	3.87	4.01	4.02
ZnO	2.30	2.27	2.35	2.35
Al2O3	1.56	1.53	1.59	1.59
TiO2	20.10	19.83	20.53	20.59
ZrO
Nb2O5
Sb2O s	0.12	0.12	0.12	0.12
Ta2O5
Y2O3	2.27
La2O
Gd2O3		3.59
WO3
Bi2O3
TOTAL	100.00	100.00	100.00	100.00
nd	1.66421	1.66575	1.66526	1.66963
vd	27.13	27.13	26.62	26.35
	0.632	0.633	0.634	0.635
	0.033	0.034	0.035	0.035
∑A2O	25.62	25.27	24.90	24.97
∑EO	6.22	6.13	6.35	7.52
TiO2/P2O5	0.46	0.46	0.46	0.46
Al3O3/TiO2	0.08	0.08	0.08	0.08
B3O3/P2O5			0.03
TiO2/(P2O5+ B3O3+Al2O3)	0.44	0.44	0.43	0.44
TiO2/(TiO2+Nb2O5+WO3+ Bi2O3+Ta2O8)	1.00	1.00	1.00	1.00
(BaO+TiO2)/P2O5	0.54	0.54	0.64	0.54
(BaO+TiO2+Nb2O8 +Ta2O8+WO2+Bi2O2)/ (P3O5+B3O3+SiO2+Al2O3)	0.53	0.53	0.51	0.53
∑A2O/TiO2	1.27	1.27	1.21	1.21
∑EO/ ∑A2O	0.24	0.24	0.26	0.30
SiO2+B2O2			1.43
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MASS %	EXAMPLE 93	EXAMPLE 94	EXAMPLE 95	EXAMPLE 96
P2O5	44.97	43.68	42.52	45.01
SiO2
B2O8				2.85
Li2O
Na2O	17.32	16.82	16.37	16.06
K2O	7.52	7.31	7.11	7.53
MgO
CaO
SrO
BaO	4.00	3.88	3.78	4.00
ZnO	4.01	2.27	2.21	2.34
Al2Os	1.59	1.54	1.50	1.59
TiO2	20.48	19.90	19.37	20.50
ZrO2
Nb2O3
Sb2O8	0.12	0.12	0.11	0.12
Ta2O5
Y2O3		4.49
La3O8
Gd2O8			7.02
WO8
Bi2O4
TOTAL	100.00	100.00	100.00	100.00
nd	1.67205	1.67080	1.67218	1.66750
vd	26.06	27.22	27.43	27.23
	0.635	0.631	0.631	0.631
	0.035	0.033	0.033	0.032
Σ A3O	24.84	24.13	23.49	23.59
Σ EO	8.00	6.16	6.99	6.34
TiO3/P2O9	0.46	0.46	0.46	0.46
Al3O3/TiO8	0.08	0.08	0.08	0.08
B2O3/P8O8				0.06
TiO2/(P2Or+B2O2+Al2O2)	0.44	0.44	0.44	0.41
TiO2/(TiO3+Nb2O3+FO2+ Bi3O3+Ta2O6)	1.00	1.00	1.00	1.00
(BaO+TiO3)/P2O5	0.54	0.54	0.54	0.54
(BaO+TiO2+NhaO3 +Ta2O3+WO+Bi2O3) /- (P2O5+B2O3+SiO2+Al2O2)	0.53	0.53	0.53	0.50
ΣA2O/TiO3	1.21	1.21	1.21	1.15
ΣEO/ΣA2O	0.32	0.26	0.26	0.27
SiO3+B2O3				2.85
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MASS %	EXAMPLE 97	EXAMPLE 98	EXAMPLE 99	EXAMPLE 100
P2O9	44.83	44.04	44.22	44.94
SiO2
B2O3	2.84			4.27
Li2O
Na2O	14.73	18.20	17.65	14.77
K2O	7.60	7.37	7.40	7.52
MgO
CaO
SrO
BaO	3.98	3.91	3.93	3.99
ZnO	3.99	2.29	2.30	2.34
Al2O3	1.58		1.56	1.58
TiO2	20.42	24.07	20.14	20.47
ZrO2
Nb2O3			2.68
Sb2O3	0.12	0.12	0.12	0.12
Ta2O5
Y2O5
La2O3
Gd8O8
WO8
Bi2O4
TOTAL	100.00	100.00	100.00	100.00
nd	1.67309	1.69090	1.67300	1.66650
vd	27.07	24.49	26.29	27.78
	0.631	0.640	0.634	0.628
	0.032	0.037	0.034	0.031
Σ A2O	22.23	25.57	25.05	22.29
Σ EO	7.98	6.21	6.23	6.33
TiO2/P2O,	0.46	0.55	0.46	0.46
Al2O3/TiO3	0.08		0.08	0.08
B2O3/P3O8	0.06			0.10
TiO2/(P2O5+B2O3+Al8O3)	0.41	0.55	0.44	0.40
TiO2/(TiO7+Sb2O8+RO3+ Bi2O2+Ta2O3)	1.00	1.00	0.88	1.00
(BaO+TiO2)/P2O3	0.54	0.64	0.54	0.54
(BaO+TiO2+Nb2O8 +Ta2O5+WO2+Bi2O3) /- P2O2+B8O3+SiO2+Al2O2)	0.50	0.64	0.58	0.48
ΣA3O/TiO2	1.09	1.06	1.24	1.09
ΣΕO/ΣA5O	0.36	0.24	0.25	0.28
SiO2+B2O3	2.84			4.27
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MASS %	EXAMPLE: 101	EXAMPLE 102	EXAMPLE 103	EXAMPLE 104
P2O5	44.94	45.09	44.90	44.61
SiO2
B2O3	4.27		1.42
Li2O
Na2O	14.77	19.26	16.02	14.66
K2O	7.52	6.59	7.51	7.47
MgO
CaO
SrO
BaO	3.99	8.43	3.99	3.97
ZnO	2.34		4.00	7.28
Al3O3	1.58		1.58	1.57
TiO2	20.47	20.54	20.45	20.32
ZrO8
Nb2Os
Sb2O3	0.12	0.09	0.12	0.12
Ta2O8
Y2O8
La2O3
Gd8O3
WO3
Bi2O3
TOTAL	100.00	100.00	100.00	100.00
nd	1.66844	1.66718	1.67030	1.68131
vd	27.63	26.14	26.84	25.94
	0.630	0.637	0.632	0.634
	0.032	0.036	0.033	0.034
Σ A3O	22.29	25.85	23.53	22.13
Σ EO	6.33	8.43	7.99	11.25
TiO3/P3O3	0.46	0.46	0.46	0.46
Al2O3/TiO2	0.08		0.08	0.08
B2O3/P2O5	0.10		0.03
TiO2/(P2O8+82O3+Al3O3)	0.40	0.46	0.43	0.44
TiO2/(TiO3+Nb2O2+FO3+	1.00	1.00	1.00	1.00
(BiO+TiO2)/P2O5	0.54	0.64	0.54	0.54
(BaO+TiO2+Nb4O5 +Ta2O5+WO3+Bi2O3 /- (P2O5+SiO4+Al2O2)	0.46	0.64	0.51	0.53
Σ A8O/TiO2	1.09	1.26	1.15	1.09
Σ EO/ΣA2O	0.28	0.33	0.34	0.51
SiO2+B2O3	4.27		1.42
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MASS %	EXAMPLE 105	EXAMPLE 106	EXAMPLE 107	EXAMPLE 108
P2O3	43.78	45.88	44.42	45.61
SiO2
B8O3	2.78	2.91	2.82	2.89
Li2O				1.24
Na3O	13.77	14.43	13.34	13.70
K2O	7.33	7.68	11.24	7.63
MgO
CaO
SrO
BaO	8.48	4.08	3.95	4.05
Z8O	2.28	2.39	2.31	2.37
Al2O3	1.54	1.62	1.57	1.61
TiO2	19.94	20.90	20.23	20.77
ZrO2
Nb2O8
Sb8O3	0.12	0.12	0.12	0.12
Ta2O8
Y2O8
La2O8
Gd2O8
WO3
Bi2O8
TOTAL	100.00	100.00	100.00	100.00
as	1.67654	1.67496	1.66703	1.67910
νd	27.26	26.70	26.96	26.65
Pe,F	0.630	0.631	0.633	0.632
ΔPs,F	0.032	0.032	0.034	0.032
ΣA2O	21.09	22.11	24.59	22.57
ΣEO	10.75	6.47	6.26	6.43
TiO2/P2O8	0.46	0.46	0.46	0.46
Al2O3/TiO2	0.08	0.08	0.08	0.08
B2O3/P3O8	0.06	0.06	0.06	0.06
TiO2/(P2O2+B2O2+Al2O8)	0.41	0.41	0.41	0.41
TiO2/(TiO3(TiO3+Nb2O8+WO3+ Bi3O3+Ta2O5)	1.00	1.00	1.00	1.00
(BaO+TiO2) /P3O5	0.65	0.54	0.54	0.54
(BaO+TiO2+Nb2O8 +Ta2O8+WO3+Bi2O2) /(P4O5+B2+SiO2+Al2O2)	0.59	0.50	0.50	0.50
ΣA2O/TiO8	1.06	1.06	1.22	1.09
ΣEO/ΣA2O	0.51	0.29	0.25	0.28
SiO2+B2O3	2.78	2.91	2.82	2.89

MASS %	EXAMPLE 109	EXAMPLE 110	EXAMPLE 111	EXAMPLE 112
P2O8	47.29	44.86	31.88	32.05
SiO2
B2O3
Li2O
Na2O	17.10	18.54	7.96	8.00
K2O	7.43	7.51	5.34	5.36
MgO
CaO
SrO
BaO	3.95		6.06	6.09
ZnO	2.31	4.45
Al2O2	1.57		1.63	1.64
TiO2	20.23	24.52	16.71	16.80
ZrO8
Nb2O8				5.91
Sb2O3	0.12	0.12
Ta2O8
Y2O8
La2O3
Gd8O3
WO3			15.87	3.98
Bi8O3			14.55	20.17
TOTAL	100.00	100.00	100.00	100.00
n4	1.66771	1.69134	1.76560	1.79432
n4	26.09	24.29	22.76	23.06
Peε	0.636	0.640	0.643	0.636
Peε	0.036	0.037	0.037	0.030
ΣA8O	24.54	26.05	13.30	13.37
ΣEO	6.26	4.45	6.06	6.09
TiO2/P2O5	0.43	0.55	0.52	0.52
Al3O3/TiO3	0.08		0.10	0.10
B3O3/P3O8
TiO2/(P8O5+B3O8+Al2O3)	0.41	0.55	0.50	0.50
TiO2/(TiO2+Nb8O5+WO8+ Bi2O3+Ta2O8)	1.00	1.00	0.35	0.36
(BaO+TiO2)/P2O8	0.51	0.55	0.71	0.71
(BaO+TiO2+Nb2O8 +Ta2O5+WO3+Bi2O3) /(P8O8+B8O8+SiO8+Al8O3)	0.49	0.55	1.59	1.57
ΣA2O/TiO2	1.21	1.06	0.80	0.80
ΣEO/ΣA2O	0.26	0.17	0.46	0.46
SiO2+B2O3

MASS %	EXAMPLE 113	EXAMPLE 114	EXAMPLE 115	EXAMPLE 116
P2O8	39.58	43.53	40.33	41.34
SiO2
B2O3
Li2O		1.82	1.69	2.67
Na3O	15.24	14.21	13.17	15.92
K8O	6.62	7.28	6.75	3.24
MgO
CaO
SrO
BaO	3.52
ZnO	2.06
Al2O3	1.84			1.92
TiO2	20.55	28.03	24.45	20.06
ZrO3
Nb3O3
Sb2O8	0.11	0.12	0.11	0.11
Ta3O8
Y3O8
La3O8
Gd2O8
WO3
Bi2O8	10.50	5.02	13.50	14.75
TOTAL	100.00	100.00	100. 00	100.00
n4	1.70813	1.74456	1.75529	1.71684
ν3	25.27	21.97	22.27	25.21
Peε	0.635	0. 649	0.645	0.632
Peε	0.033	0.041	0.038	0.030
ΣA2O	21.86	23.32	21.61	21.83
ΣEO	5.58
TiO2/P8O8	0.52	0.64	0.61	0.49
Al2O2/TiO2	0.09			0.10
B2O3/P2O2
TiO2/(P2O8+Al2O3)	0.50	0.64	0.61	0.46
TiO3/(TiO2+Nb2O8+WO3+ Bi2O8+Ta2O8)	0.66	0.85	0.64	0.58
(BaO+TiO8)/P2O8	0.61	0.64	0.61	0.49
(BaO+TiO2+Nb2O5 +Ta8O8+WO2+Bi3O3) /(P3O8+B2O3+SiO3+Al3O3)	0.83	0.76	0.94	0.80
ΣA2O/TiO8	1.06	0.83	0.88	1.09
ΣEO/ΣA2O	0.26
SiO3+B2O3

MASS %	EXAMPLE 92	EXAMPLE 118	EXAMPLE 119	EXAMPLE 120
P2O5	36.67	42.54	40.52	36.93
SiO2
B2O6
Li2O	2.37			1.54
Na2O	14.12	17.58	16.75	12.06
K2O	2.87	7.12	6.78	6.18
MgO
CaO
SrO
BaO
ZnO		4.22	4.02
Al2O3	1.70
TiO2	20.04	23.25	20.03	21.21
ZrO2
Nb2O6			4.95
Sb2Os	0.10	0.11	0.11	0.10
TasOs				9.61
Y2O3
La2O3
Gd2O3
WO3			1.82
Bi2O2	22.14	5.19	5.03	12.36
TOTAL	100.00	100.00	100.00	100.00
	1.74388	1.70204	1.70692	1.76027
	25.00	24.32	24.75	22.93
P3	0.628	0.640	0.634	0.639
ΔP	0.026	0.037	0.031	0.033
∑A2O	19.36	24.70	23.53	19.78
∑EO		4.22	4.02
TiO3/P2O5	0.55	0.55	0.49	0.57
Al2O3/TiO2	0.08
B2O3/P3O5
TiO2/ (P2O8+B2O3+Al2O2)	0.52	0.55	0.49	0.57
TiO3/(TiO2+Nb2O5+WO2+ Bi2O3+Ta2O8)	0.48	0.82	0.63	0.49
(BaO+TiO2) /P2O6	0.55	0.55	0.49	0.57
(Ba0+TiO2+Nb2O5 +Ta2O8+WO3+Bi2O3 / (P2O8+Bi2O3+SiO2+Al2O3)	1.10	0.67	0.79	1.17
∑A2O/TiO2	0.97	1.06	1.17	0.93
∑ EO/ ∑ A2O		0.17	0.17
SiO2+B2O3
indicates text missing or illegible when filed

MASS %	EXAMPLE 121	EXAMPLE 122	EXAMPLE 123	EXAMPLE 124
P2O5	37.05	42.38	35.68	43.46
SiO2
B2O3			3.51
Li2O	1.55	1.56	2.77
Na2O	12.10	14.39	16.50	17.96
K3O	6.20	6.26	3.36	1.21
MgO				2.14
CaO
SrO
BaO
ZnO
Al2O3			1.99
TiO2	21.28	30.26	20.79	23.76
ZrO2
Nb2O5
Sb2O3	0.10	0.10	0.11	0.12
TaxO5	15.43
Y3O3
LazO3
Gd2Oa
WO3
Bi2Oa	6.30	5.05	15.28	5.30
TOTAL	100.00	100.00	100.00	100.00
	1.75265	1.75884	1.70707	1.69980
	23.27	21.62	26.91	24.27
Pa r	0.634	0.647	0.622	0.637
ΔPas	0.029	0.039	0.023	0.033
∑A2O	19.85	22.21	22.63	25.23
∑EO				2.14
TiO2/P2O5	0.57	0.71	0.58	0.55
Al3O3/TiO2			0.10
B2O3/P2O5			0.10
TiO2/(P2O8+B2O5+Bi2O3)	0.57	0.71	0.50	0.55
TiO2/ (TiO2+Nb2O5+WO2+ Bi2O2+Ta2O5)	0.49	0.86	0.58	0.82
(BaO+TiO2) /P2O5	0.57	0.71	0.58	0.55
(BaO+TiO2+Nb2O5 +Ta2O5+WO3+Bi2O2) / (P2O5+B2O3+SiO2+Al2O3)	1.16	0.83	0.88	0.67
∑ A2O/TiO2	0.93	0.73	1.09	1.06
∑ EO/ ∑A3O				0.08
SiO2+B2O3			3.51
indicates text missing or illegible when filed

MASS%	EXAMPLE 125	EXAMPLE 126	EXAMPLE 127	EXAMPLE 128
P2O5	43.10	42.05	41.38	40.17
SiO3
B2O3
Li2O
Na2O	17.81	17.38	17.10	16.60
K2O	7.21	7.04	6.92	6.72
MgO
CaO	2.95
SrO		5.31
BaO
ZnO			2.57	2.50
Al2O3
TiO8	23.55	22.98	22.61	21.95
ZrO2
Nb2O0
Sb2O8	0.11	0.11	0.11	0.11
Ta2O5
Y2O3			4.25
La2O3
Gd2O3				6.63
WO3
Bi2O3	5.26	6.13	5.05	5.33
TOTAL	100.00	100.00	100.00	100.00
	1.69772	1.69810	1.69989	1.70469
	24.80	24.82	25.46	25.30
P	0.622	0.636	0.627	0.633
ΔP	0.019	0.033	0.025	0.031
∑A2O	25.03	24.42	24.02	23.32
∑EO	2.95	5.31	2.57	2.50
TiO2/P2O5	0.55	0.55	0.55	0.55
Al2O3/TiO2
B2O3/P2O5
TiO2/ (P2O5+B8O3+Al3O3)	0.55	0.55	0.55	0.55
TiO2/(TiO2+Nb2O5+WO5+ Bi2O3+Ta2O5)	0.82	0.82	0.82	0.80
(BaO+TiO2) /P2O5	0.55	0.55	0.55	0.55
(BaO+TiO2+Nb2O5 +Ta2O5+WO5+Bi2O3)/ (P2O5 +B2O3+SiO5+Al3O3)	0.67	0.67	0.67	0.68
∑ A2O/TiO2	1.06	1.06	1.06	1.06
∑ EO/ ∑A2O	0.12	0.22	0.11	0.11
SiO2+B2O3
indicates text missing or illegible when filed

MASS %	EXAMPLE 129	EXAMPLE 130	EXAMPLE 131	EXAMPLE 132
P2O2	42.05	41.97	44.47	43.06
SiO2	1.15
B2O3		1.33
Li2O			1.86
Na2O	17.38	17.35	19.42	17.80
K2O	7.04	7.02		7.21
MgO
CaO
SrO
BaO
ZaO	4.17	4.16	4.41	2.68
Al2O3
TiO2	22.98	22.94	24.30	20.24
ZrO2
Nb2O2
Sb2O2	0.11	0.11	0.12	0.11
Ta2O3
Y2O3
La2O3				3.19
Gd2O2
WO3
Bi2O3	5.13	5.12	5.42	5.71
TOTAL	100.00	100.00	100.00	100.00
	1.70042	1.69808	1.71941	1.68460
	24.40	25.01	24.03	25.71
PsF	0.635	0.629	0.637	0.626
ΔPs.F	0.032	0.027	0.033	0.025
∑ A2 O	24.41	24.37	21.28	25.00
∑ E O	4.17	4.16	4.41	2.68
TiO2/P2O2	0.55	0.55	0.55	0.47
Al2O2/TiO2
B2O2/P2O2		0.03
TiO2/ (P2O5+B2O2+Al2O3)	0.55	0.53	0.55	0.47
TiO2/ (TiO2+Nb2O5+WO2+ Bi2O3+Ta2O5	0.82	0.82	0.82	0.78
(BaO+TiO2)/P2O5	0.56	0.55	0.55	0.47
(BaO+TiO2+Nb2O5+ Ta5O5+WO5+Bi2O2) / (P2O5+B2O5+SiO2+Al2O3)	0.65	0.65	0.67	0.60
∑ A2O/TiO2	1.06	1.06	0.88	1.24
∑ BO/ ∑A2O	0.17	0.17	0.21	0.11
SiO2+B2O3	1.15	1.33
indicates text missing or illegible when filed

MASS %	EXAMPLE 133	EXAMPLE 134	EXAMPLE 135	EXAMPLE 136
P2 O 5	42.08	43.51	41.88	24.37
S i O2				0.76
B3 O 3				5.85
L i 2 O
N a 2 O	17.39		17.31	5.13
K 2 O	7.04	19.21	7.01	10.20
M g O		3.40
C a O
S r O
B a O				14.32
Z n O	4.18	8.35	4.15
A l 2 O 3
T i O2	23.00	20.07	22.88	15.45
Z r O2	1.06
N b 2 O 2				23.86
S b2 O 3	0.11	0.12	0.11	0.06
T a2 O 5
Y2 O 3
L a 2 O 3			1.55
G d2 O 3
W O3
B i 2 O 3	5.13	5.35	5.11
TOTAL	100.00	100.00	100.00	100.00
ns	1.70538	1.68675	1.70164	1.78593
v3	24.29	25.66	24.68	23.93
Pa.F	0.637	0.625	0.634	0.633
ΔPs.F	0.034	0.023	0.031	0.029
∑ A2 O	24.43	19.21	24.31	15.33
∑ E O	4.18	11.74	4.15	14.32
TiO2/P2O5	0.55	0.46	0.55	0.63
Al2O3/TiO2
B2O5/P2O5				0.24
TiO2/ (P2O5+B2O5+Al2O5)	0.55	0.46	0.55	0.51
TiO2/(TiO2+Nb2O5+WO2+ Bi2O3+Ta2O3)	0.82	0.79	0.82	0.39
(BaO+TiO3) /P2O5	0.55	0.46	0.55	1.22
(BaO+TiO2+Nb2O6 +Ta3O6+WO3+Bi2O3 / (P3O5+B2O3+SiO2+Al2O2)	0.67	0.58	0.67	1.73
∑ A2O/TiO2	1.06	0.96	1.06	0.99
∑ EO/ ∑ A2O	0.17	0.61	0.17	0.93
SiO2+B2O3				6.61

MASS %	EXAMPLE 92	EXAMPLE 138	EXAMPLE 139
P2 O 5	24.37	24.38	35.44
S i O2	0.76	1.06
B2 O 3	5.85	5.65	1.42
L i2 O
N a2 O	4.51	5.13	6.96
K 3 O	10.82	10.20	1.01
M g O
C a O	1.01		6.29
S r O
B a O	13.31	13.82	14.83
Z n O
A l2 O 3
T i O2	15.45	15.44	25.94
Z r O2
N b2 O s	23.86	24.36	8.12
S b2 O 3	0.06	0.06
T a 2 O 5
Y2 O 3
L a2 O 3
G d2 O 3
W O3
B i 3 O 3
TOTAL	100.00	100.00	100.00
na	1.78524	1.78802	1.80663
v 6	24.04	23.76	23.16
Ps.F	0.633	0.632	0.640
ΔPa.F	0.029	0.027	0.035
∑ A2 O	15.33	15.33	7.97
∑ E O	14.32	13.82	21.12
TiO2/P2O5	0.63	0.63	0.73
Al2O3/TiO3
B2O2/P3O3	0.24	0.23	0.04
TiO2/(P2O3+B2O3+Al2O3)	0.51	0.52	0.70
TiO2/ (TiO2+Nb2O5+WO3+ Bi2O3+Ta2O5)	0.39	0.39	0.76
(BaO+TiO2) /P2O5	1.18	1.20	1.15
(BaO+TiO2+Nb2O2 +Ta2O5+WO3+Bi2O3) / (P3O5+B2O3+SiO2+Al2O3)	1.70	1.73	1.33
∑ A2O/TiO2	0.99	0.99	0.31
∑ EO/ ∑ A2O	0.93	0.90	2.65
SiO2+B3O3	6.61	6.61	1.42

MASS %	COMPARATIVE EXAMPLE 1	COMPARATIVE EXAMPLE 2	COMPARATIVE EXAMPLE 3
P2O5	29.59	28.75	28.75
SiO2
B2O3
Li3O		0.39	0.39
Na2O	8.94	8.69	8.69
K2O	5.68	5.42	5.42
MgO
CaO
SrO
BaO	15.70	15.26	15.26
ZnO
Al2O3		0.33	0.33
TiO2	40.12	40.53	40.53
ZrO2		0.64	0.64
Nb2O5
Sb2O3	0.08	0.08
Ta2O5
Y2O3
La2O3
Gd2O3
WO3
Bi2O3
Total	100.00	100.08	100.00
	UNMEASURABLE	UNMEASURABLE	UNMEASURABLE
	UNMEASURABLE	UNMEASURABLE	UNMEASURABLE
P	UNMEASURABLE	UNMEASURABLE	UNMEASURABLE
P	UNMEASURABLE	UNMEASURABLE	UNMEASURABLE
ΣA2O	14.51	14.49	14.49
ΣEO	15.70	15.26	15.26
TiO3/P2O5	1.36	1.41	1.41
Al2O5/TiO2		0.01	0.01
B2O3/P2O5
TiO2/ (P2O5+Al2O3)	1.36	1.39	1.39
TiO2/(TiO2+Nb2O2+WO3+ Bi2O3+Ta2O5)	1.00	1.00	1.00
(BaO+TiO2)/P2O5	1.89	1.94	1.94
(BaO+TiO2+Nb2O5 +Ta2O5+WO5+Bi5O3)/ (P2O3+B2O3+SiO3+Al2O3)	1.89	1.92	1.92
ΣA2O/TiO2	0.36	0.36	0.36
ΣEO/ΣA2O	1.08	1.05	1.05
SiO2+B2O3
indicates text missing or illegible when filed

From above, it was confirmed that the optical glasses in Examples were highly dispersive and had a high partial dispersion ratio. Further, it was confirmed that the optical glasses in Examples were excellent in transparency with suppressed coloration.

REFERENCE SIGNS LIST

• 1 Imaging device
• 101 Camera body
• 102 Lens barrel
• 103 Lens
• 104 Sensor chip
• 105 Glass substrate
• 106 Multi-chip module
• CAM Imaging device (fixed lens camera)
• WL Photographing lens
• M Liquid crystal monitor
• EF Auxiliary light emitting unit
• B1 Release button
• B2 Function button
• 2 Multi-photon microscope
• 201 Pulse laser device
• 202 Pulse division device
• 203 Beam adjustment unit
• 204, 205, 212 Dichroic mirror
• 206 Objective lens
• 207, 211, 213 Fluorescence detection unit
• 208 Condensing lens
• 209 Pinhole
• 210 Image forming lens
• S Sample
• 3 Cemented lens
• 301 First lens element
• 302 Second lens element
• 303 Joining member

Claims

1. An optical glass comprising: by mass%,20% or more and 55% or less of a content rate of P2O5;10% or more and 40% or less of a content rate of TiO2;0% or more and 30% or less of a content rate of Nb2O5;0% or more and 2% or less of a content rate of Al2O3;0% or more and 10% or less of a content rate of B2O3;3% or more and 30% or less of a content rate of BaO;0% or more and 30% or less of a content rate of Bi2O3;0% or more and 20% or less of a content rate of Ta2O5; and0% or more and 25% or less of a content rate of WO3, whereina ratio of a total content rate of Li2O, Na2O and K2O (ΣA2O; where, A = Li, Na and K) to a content rate of TiO2 (ΣA2O/TiO2) is 0.10 or more and 0.65 or less, and a ratio of a content rate of TiO2 to a total content rate of P2O5, B2O3, and Al2O3 (TiO2/ (P2O5 + B2O3 + Al2O3)) is 0.25 or more and 0.85 or less.

2. The optical glass according to claim 1, wherein by mass%,a ratio of a total content rate of BaO and TiO2 to a content rate of P2O5 ((BaO + TiO2) / P2O5) is 0.40 or more and 1.50 or less.

3. The optical glass according to claim 1, wherein by mass%,a ratio of a content rate of TiO2 to a total content rate of TiO2, Nb2O5, WO3, Bi2O3, and Ta2O5 (TiO2/ (TiO2 + Nb2O5 + WO3 + Bi2O3 + Ta2O5)) is 0.25 or more and 1.00 or less.

4. The optical glass according to claim 1, further comprising: by mass%,0% or more and 30% or less of a content rate of Na2O;0% or more and 25% or less of a content rate of K2O; and0% or more and 5% or less of a content rate of Li2O.

5. The optical glass according to claim 1, further comprising: by mass%,0% or more and 15% or less of a content rate of ZnO;0% or more and 10% or less of a content rate of MgO;0% or more and 10% or less of a content rate of CaO; and0% or more and 15% or less of a content rate of SrO.

6. The optical glass according to claim 1, further comprising: by mass%,0% or more and 5% or less of a content rate of SiO2;0% or more and 5% or less of a content rate of ZrO2; and0% or more and 1% or less of a content rate of Sb2O3.

7. The optical glass according to claim 1, further comprising: by mass%,0% or more and 10% or less of a total content rate of SiO2 and B2O3.

8. The optical glass according to claim 1, further comprising: by mass%,0% or more and 8% or less of a content rate of Y2O3;0% or more and 5% or less of a content rate of La2O3; and0% or more and 10% or less of a content rate of Gd2O3.

9. The optical glass according to claim 1, further comprising: by mass%,5% or more and 35% or less of a total content rate of Li2O, Na2O, and K2O (ΣA2O; where, A = Li, Na, K).

10. The optical glass according to claim 1, further comprising: by mass%,0% or more and 30% or less of a total content rate of MgO, CaO, SrO, BaO, and ZnO (ΣEO; where, E = Mg, Ca, Sr, Ba, Zn).

11. The optical glass according to claim 1, wherein a ratio of a content rate of TiO2 to a content rate of P2O5 (TiO2/P2O5) is 0.25 or more and 0.85 or less.

12. The optical glass according to claim 1, wherein a ratio of a content rate of Al2O3 to a content rate of TiO2 (Al2O3/TiO2) is 0 or more and 0.15 or less.

13. The optical glass according to claim 1, wherein a ratio of a content rate of B2O3 to a content rate of P2O5 (B2O3/P2O5) is 0 or more and 0.30 or less.

14. The optical glass according to claim 1, wherein a ratio of a total content rate of BaO, TiO2, Nb2O5, WO3, Bi2O3, and Ta2O5 to a total content rate of P2O5, B2O3, SiO2, and Al2O3 ((BaO + TiO2 + Nb2O5 + WO3 + Bi2O3 + Ta2O5) / (P2O5 + B2O3 + SiO2 + Al2O3)) is 0.40 or more and 2.00 or less.

15. The optical glass according to claim 3, wherein a ratio of a total content rate of Li2O, Na2O, and K2O (ΣA2O; where, A = Li, Na, K) to a content rate of TiO2 (ΣA2O/TiO2) is 0.10 or more and 2.00 or less.

16. The optical glass according to claim 1, wherein a ratio of a total content rate of MgO, CaO, SrO, BaO, and ZnO (ΣEO; where, E = Mg, Ca, Sr, Ba, Zn) to a total content rate of Li2O, Na2O, and K2O (ΣA2O; where, A = Li, Na, K) (ΣEO/ΣA2O) is 0 or more and 3.00 or less.

17. The optical glass according to claim 1, wherein a refractive index (nd) with respect to a d-line falls within a range of 1.60 or more and 1.85 or less.

18. The optical glass according to claim 1, wherein an abbe number (νd) falls within a range of 20 or more and 35 or less.

19. The optical glass according to claim 1, wherein a partial dispersion ratio (Pg,F) is 0.61 or more and 0.66 or less.

20. The optical glass according to claim 1, wherein abnormal dispersibility (ΔPg,F) is 0.015 or more and 0.055 or less.

21. An optical element using the optical glass according to claim 1.

22. An optical system comprising the optical element according to claim 21.

23. An interchangeable camera lens comprising the optical system according to claim 22.

24. An objective lens for a microscope comprising the optical system according to claim 22.

25. An optical device comprising the optical system according to claim 22.

26. A cemented lens comprising: a first lens element; anda second lens element, wherein at least one of the first lens element and the second lens element comprises the optical glass according to claim 1.

27. An optical system comprising the cemented lens according to claim 26.

28. An objective lens for a microscope comprising the optical system according to claim 27.

29. An interchangeable camera lens comprising the optical system according to claim 27.

30. An optical device comprising the optical system according to claim 27.