a) is a schematic diagram showing a disc ID of an optical information recording medium according to the present invention; and
An optical information recording medium according to the present invention includes a light transmitting layer on a substrate. Information is recorded by utilizing a change in transmittance of the light transmitting layer caused by irradiation of recording light. Information can be recorded and reproduced without an information recording layer which has been conventionally provided. Thus, media can be produced easily with a low cost. The light transmitting layer is formed of a cover layer (sheet) and an adhesive layer formed of an adhesive resin. The transmittance is changed in the adhesive layer part.
The method for recording information by reducing the transmittance of the light transmitting layer is particularly suitable for an area for recording data other than user data (for example, identification information of the medium). However, the method can also be applied to an area for recording user data.
The optical information recording medium of the present invention may include a light absorption layer between the substrate and the light transmitting layer. The light absorption layer may also serve the role as a conventional reflective film, and absorbs heat generated by use of recording light which has a power higher than that of conventional one to reduce an influence of extra heat.
Hereinafter, embodiments of the present invention will be described with reference to the drawings.
The optical information recording medium 20 includes a light absorption layer 22 provided across a surface of a substrate 21. On the substrate 21, grooves or pits, or both grooves and pits are formed. The optical information recording medium 20 further includes a light transmitting layer 23 provided across a surface of the light absorption layer 22.
For producing the substrate 21, injection molding of a polycarbonate resin is performed to obtain a polycarbonate substrate having a diameter of 120 mm and a center hole diameter of 15 mm and having a groove of a spiral pattern. The light absorption layer 22 is produced on the substrate 21 with a sputtering device so as to have a thickness of 20 nm. Then, the light transmitting layer 23 having a thickness of 100 μm is formed to be ready for high density recording using a lens with high NA. The light transmitting layer 23 is formed by adhering a sheet formed of a polycarbonate resin material having a thickness of 75 μm on the formed light absorption layer 22 using a resin adhesive of polyacrylate group as an adhesive layer of 25 μm thick.
The adhesive used in above process is an adhesive formed of a cross-linked material of acrylate copolymers and a photocurable component. Herein, the acrylate copolymer refers to a copolymer including acrylate derivatives as a main component, and other monomers may be copolymerized. For example, acrylate may be methyl acrylate, or a methyl group of the methyl acrylate may be changed to an ethyl group, butyl group, isobutyl group or the like, or they may be combined to produce the acrylate. The other monomers to be copolymerized with the acrylate may be, for example, an acrylic acid, a crotonic acid, a maleic acid, an acrylonitrile, vinyl acetate, or the like. A curable component of the adhesive may be oligomers or monomers which includes an unsaturated group within a molecular and in which an average molecular weight is 20,000 or lower when ultraviolet curing occurs. For example, acrylate-based materials, particularly, trimethylol propane triacrylate, polyurethane acrylate, polyester acrylate, polyether acrylate, epoxy acrylate, and the like may be used. In the optical information recording medium 20, an adhesive employing methyl acrylate and trimethylol propane triacrylate is used.
An experiment for confirming that information can be recorded by changing the transmittance of the light transmitting layer with irradiation of recording light was conducted using the optical information recording medium 20.
For confirming a recording operation easily, a region where the light of a recording laser does not impinge was intentionally produced in the optical information recording medium 20 by using a metal mask for shielding light. Then, the optical information recording medium 20 was irradiated entirely with recording UV light having a wavelength of 250 nm. Then, reproduction was performed using a laser of a wavelength of 405 nm.
The change in the transmittance was caused by a thermal damage applied to the light transmitting layer 23 in the region which is not shielded. Particularly, the thermal damage was high because heat from the recording light was absorbed by the light absorption layer 22. It can be assumed that the cross-linked molecules are cleaved in the region which is not shielded. Specifically, cross-linkage between functional groups such as carboxyl groups, hydroxyl groups or the like in the acrylate copolymer which is a component of the resin adhesive of the light transmitting layer 23 and unsaturated groups (for example, acrylyl groups) are cleaved by the laser light, and the transmittance changes.
In this way, information can be recorded on an optical information recording medium without employing a special layer for storing recorded information as in the conventional optical information recording medium 10.
An experiment was conducted for confirming whether the change in the transmittance in the optical information recording medium 20 of the present invention with the information being recorded as described with reference to
Table 1 shows changes in the reflectance of the media 20 before and after the weatherability test. The reflectance Hi represents the reflectance of the area where the reflectance is not changed as shown in
In this embodiment, the recording UV light is used for recording. However, it is difficult to record fine information with the UV light using a mask. Therefore, the above embodiment is suitable for recording information in the size of about few μm.
a) and 3(b) show a result of recording fine marks on the optical information recording medium 20 without any mask.
The recorded data formed of marks can be recorded and reproduced similarly on the user data area 41.
In the present embodiment, the material of the light transmitting layer 23 is a combination of the polycarbonate sheet and a resin adhesive of polyacrylate group. However, the material is not limited to such a combination. Combinations including an acryl-based resin sheet or a polyolefin-based resin sheet instead of the polycarbonate sheet can achieve the similar results.
Also, the adhesive is not limited to the one of polyacrylate group. A UV curable resin or an adhesive including a UV curable resin can achieve the similar results.
When the light transmitting layer 23 is produced by a spin coat method using a UV resin so as to have a film thickness of 100 μm, similar effects can be achieved except that the modification rate obtained as shown in
The same result can be obtained when a hard coat layer formed of a UV resin is formed on the UV resin.
According to the present invention, recording and reproduction can be established by the light transmitting layer 23. Thus, by just providing the light transmitting layer 23 on a conventional optical information recording medium 10, write once recording and rewritable recording become possible. Herein, the conventional optical information recording medium has a structure including an information recording layer formed of a phase change recording layer and the like in the user data area. Media ID and other types of information specific to manufacturer are to be write-once recorded by changing the transmittance of the light transmitting layer 23 in the area other than the user data area. In this embodiment, the light absorption layer is provided to prepare for recording light with a high power in the present invention, but it also serves a role of a conventional reflective film.
The recording information is assumed to be individual information. The individual information is a set of information unique to or substantially unique to each of the discs, and basic information common among the optical discs. Herein, the disc ID is described as typical individual information. The disc ID is used with other key information in order to protect copyrights of video, audio, data and the like recorded on optical discs. For example, it is used for encryption recording a work which is allowed to be copied for only once differently for each of the optical discs based on disc IDs and the like.
According to the present invention, the optical information recording medium 20 can be recorded by using normal recording laser light with only the recording conditions being changed. Unlike the conventional write once recording, this allows the optical information recording medium 20 to have a higher density. Thus, if the data amount is the same, an area to be occupied can be small. Therefore, more user data area 51 can be reserved. This allows a use of a recording medium with a smaller diameter and small user data area 51. For recording important information such as disc ID, a recording area may be formed in an outer peripheral region to secure reliability in consideration of data corruption and the like. According to the optical information recording medium 20 of the present invention, an area reserved as the recording area can be small. Thus, recording areas may be provided both in an inner peripheral region and the outer peripheral region.
According to the recording and reproduction apparatus of the present invention, when there are a plurality of recording areas for which different recording methods are used as shown in
In
Embodiments of the present invention have been described by way of examples. However, the present invention is not limited to the above-described embodiments, and can be applied to other embodiments based on technical idea of the present invention. For example, write once recording can be performed on any of recording and reproduction media, write once media, ROM media, and the like.
The optical information recording medium, and the recording and reproduction method and the recording and reproduction apparatus for the optical information recording media according to the present invention enable recording and reproduction of information without using an information recording layer. Thus, they are useful for optical information recording media, recording and reproduction methods for optical information recording media, and the like with a low cost and a high density.
Number | Date | Country | Kind |
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2003-378262 | Nov 2003 | JP | national |
Filing Document | Filing Date | Country | Kind | 371c Date |
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PCT/JP04/16210 | 11/1/2004 | WO | 00 | 1/24/2007 |