This disclosure relates to an optoelectronic component comprising wavelength conversion materials.
Radiation-emitting optoelectronic components comprising wavelength conversion materials are described, for example, in the document WO 97/50132. Such an optoelectronic component includes a semiconductor body that emits electromagnetic radiation when operating, and wavelength conversion materials that are incorporated into an encapsulant of the semiconductor body or are disposed in a layer on the semiconductor body. The wavelength conversion materials convert a portion of the electromagnetic radiation emitted by the semiconductor body to radiation of another, usually higher, wavelength, such that the component emits mixed radiation.
As described for example in the document DE 102 61 428, it is also possible to dispose multiple layers comprising different wavelength conversion materials downstream of the radiation-emitting semiconductor body, such that different fractions of the radiation emitted by the radiation-emitting body are converted by different wavelength conversion materials to radiation in different regions of the spectrum.
In the past, attempts have been made to improve the efficiency of optoelectronic components comprising wavelength conversion materials by increasing the efficiency of the semiconductor body and the wavelength conversion material, on the one hand, and on the other hand by improving the geometry of the component housing to this effect.
One object of the present invention is to specify an optoelectronic component comprising wavelength conversion materials and exhibiting high efficiency. Another object of the present invention is to specify an optoelectronic component comprising a wavelength conversion material and exhibiting high efficiency in conjunction with good color rendering. These objects are achieved by means of an optoelectronic component having the features of claim 1. Advantageous improvements and embodiments of the optoelectronic component are set forth in Dependent claims 2 to 25.
An optoelectronic component having high efficiency includes, in particular:
“Spacedly,” in the present context, means in particular that the optical element is arranged such that it is spatially separated from the semiconductor body in a prescribed manner, a defined gap that is free of wavelength conversion material being formed between the semiconductor body and the optical element.
Since the first wavelength conversion material is comprised by the optical element, which is disposed spacedly from the radiation-emitting semiconductor body, the first wavelength conversion material is also disposed spacedly from the radiation-generating semiconductor body. The efficiency of the component is advantageously increased over that of an optoelectronic component in which the first wavelength conversion material is disposed directly adjacent the radiation-emitting semiconductor body and in particular directly adjacent its radiation-emitting front side, for example within an encapsulant of the semiconductor body or of a layer. In addition, it is particularly advantageous to incorporate the wavelength conversion material into the optical element, which serves to effect beam shaping and essentially determines the radiation characteristic of the component, since, as a rule, the radiation characteristic obtained in this way is not only enhanced, but is also particularly uniform.
In a particularly preferred embodiment, the wavelength conversion material includes particles and the optical element comprises a matrix material in which the particles are embedded. Since the radiation emitted by the semiconductor body and the radiation converted by the wavelength conversion material are normally scattered by the particles, and since the wavelength conversion material emits radiation in random directions, a wavelength conversion material comprising particles will, as a rule, advantageously increase the uniformity of the radiation characteristic of the component. Furthermore, disposing the particles of the first wavelength conversion material spacedly from the semiconductor body, in a separate optical element of defined geometry, yields the advantage that less radiation, particularly converted radiation, is deflected back into the semiconductor body by scattering from the particles, and is absorbed there, than is the case if the wavelength conversion material is contained in a wavelength conversion element that is directly adjacent the semiconductor body, such as a layer or an encapsulant, for example.
In a preferred embodiment, the first wavelength is in the ultraviolet, blue and/or green region of the spectrum. Since wavelength conversion materials normally convert radiation to radiation of higher wavelengths, wavelengths from the short-wave end of the visible spectrum and the ultraviolet region of the spectrum are particularly suitable for use in combination with wavelength conversion materials.
A semiconductor body that emits ultraviolet, blue and/or green radiation preferably comprises an active layer sequence that is suitable for emitting electromagnetic radiation in the particular spectral region and is made of a nitride- or phosphide-based compound semiconductor material.
“Nitride-based compound semiconductor material” means in the present context that the active layer sequence or at least a portion thereof comprises a nitride III compound semiconductor material, preferably AlnGamIn1-n-mN, where 0≦n≦1, 0≦m≦1 and n+m≦1. The composition of this material need not necessarily be mathematically exactly that of the above formula. Rather, it can contain one or more dopants and additional constituents that do not substantially alter the characteristic physical properties of the AlnGamIn1-n-mN material. For the sake of simplicity, however, the above formula includes only the essential components of the crystal lattice (Al, Ga, In, N), even though these may be partially replaced by very small quantities of other substances. By the same token, “phosphide-based compound semiconductor material” means in the present context that the active layer sequence or at least a portion thereof comprises a phosphide III compound semiconductor material, preferably AlnGamIn1-n-mP, where 0≦n≦1, 0≦m≦1 and n+m≦1. The composition of this material need not necessarily be mathematically exactly that of the above formula. Rather, it can contain one or more dopants and additional constituents that do not substantially alter the characteristic physical properties of the AlnGamIn1-n-mP material. For the sake of simplicity, however, the above formula includes only the essential components of the crystal lattice (Al, Ga, In, P), even though these may be partially replaced by very small quantities of other substances.
The active layer sequence of the semiconductor body is, for example, epitaxially grown and preferably has a pn junction, a double heterostructure, a single quantum well or, particularly preferably, a multiple quantum well (MQW) structure. The term “quantum well structure” carries no implication here as to the dimensionality of the quantization. It therefore includes, among other things, quantum troughs, quantum wires and quantum dots and any combination of these structures.
The semiconductor body can be, for example, a light-emitting diode chip (“LED chip” for short) or a thin-film light-emitting diode chip (“thin-film LED chip” for short). However, other radiation-generating semiconductor bodies, such as laser diodes, are also suitable for use in the component.
A thin-film LED chip is distinguished in particular by at least one of the following characteristic features:
Furthermore, the epitaxial layer sequence preferably includes at least one semiconductor layer that has at least one surface with an intermixed structure that in the ideal case brings about a nearly ergodic distribution of the light in the epitaxial layer sequence, i.e., said layer has a stochastic scattering behavior that is as ergodic as possible.
A basic principle of a thin-layer LED chip is described, for example, in I. Schnitzer et al., Appl. Phys. Lett. 63 (16), Oct. 18, 1993, 2174-2176, whose disclosure content in that regard is hereby incorporated by reference.
A thin-film LED chip is, as a good approximation, a Lambertian surface radiator, and is therefore particularly suitable for use in an optical system, such as a floodlight, for example.
If the first wavelength is in the visible region of the spectrum, then the component preferably emits polychromatic mixed radiation that includes radiation of the first wavelength and radiation of the second wavelength. The term “polychromatic mixed radiation” here denotes in particular mixed radiation that includes radiation of different colors. Particularly preferably, the color space of the mixed radiation is in the white region of the CIE standard chromaticity diagram. It is therefore possible, via the choice and concentration of the wavelength conversion material, to fabricate components whose color space can be adjusted over wide ranges.
Particularly preferably, a semiconductor body that emits radiation in the blue region of the spectrum is used in combination with a wavelength conversion material that converts this blue radiation to yellow radiation. An optoelectronic component is thereby obtained that emits mixed radiation having a color space in the white region of the CIE standard chromaticity diagram.
If the semiconductor body emits only non-visible radiation, however, for example in the UV region, then efforts are made to convert this radiation as fully as possible, since it does not contribute to the brightness of the component. In the case of short-wave radiation, such as UV radiation, it may even damage the human eye. For this reason, with components of this kind, measures are preferably taken to prevent the component from emitting short-wave radiation.
Such measures can be, for example, absorber particles or reflective elements, which are disposed downstream of the first wavelength conversion material in the radiation direction of the semiconductor body and absorb the unwanted short-wave radiation or reflect it back to the wavelength conversion material.
It should be pointed out at this juncture that, as explained in still further detail below, a component can also emit polychromatic mixed radiation in cases where the semiconductor body emits only non-visible radiation. This is brought about by using at least two different wavelength conversion materials that convert the incident radiation to different wavelengths. If the semiconductor body emits only non-visible radiation, then this embodiment is particularly advantageous in comparison to converting the non-visible radiation to only one second wavelength. If the component comprises more than one wavelength conversion material, then measures to prevent the component from emitting short-wave radiation are preferably disposed downstream of all the wavelength conversion materials in the radiation direction of the semiconductor body.
In a preferred embodiment of the optoelectronic component, the semiconductor body is provided with an encapsulant that is transparent to the radiation emitted by the component. The semiconductor body can in this case be disposed in a recess in a component housing, such as a reflector trough, for example. Alternatively, the semiconductor body can also be mounted on a circuit board or on a cooling element of a circuit board. One function performed by the encapsulant is to protect the semiconductor body. In addition, the encapsulant is preferably so arranged that it fills the gap between the optical element and the semiconductor body and thereby decreases the refractive index mismatch on the path of the radiation from the semiconductor body to the optical element, thus advantageously reducing radiation losses due to reflection at interfaces.
The encapsulant preferably contains a matrix material comprising a silicone material, an epoxy material, a hybrid material or a refractive-index-matched material. The term “refractive-index-matched material” is understood to be a material whose refractive index falls between the refractive indices of the adjacent materials, hence, in the present context, between the refractive index of the semiconductor body and the refractive index of the matrix material of the optical element.
In a further preferred embodiment of the optoelectronic component, the encapsulant comprises at least one second wavelength conversion material different from the first. The second wavelength conversion material preferably converts the radiation from the first wavelength conversion material to radiation of a third wavelength different from the first and second wavelengths, such that the component emits mixed radiation of the second wavelength, the third wavelength and, where appropriate, the first wavelength.
The mutually spatially separated arrangement of the first wavelength conversion material and the second wavelength conversion material achieves the effect, in particular, of reducing the absorption by one of the wavelength conversion materials of radiation that has already been converted by the respective other wavelength conversion material. This is a risk, in particular, when the one wavelength conversion material converts the radiation to a wavelength that is close to the excitation wavelength of the other wavelength conversion material. The described arrangement and spatial separation of the two wavelength conversion materials increases the efficiency of the component, as well as the uniformity of the color impression and the reproducibility of these parameters during mass production.
A semiconductor body that emits only non-visible radiation in the ultraviolet region is also particularly suitable for this embodiment of the optoelectronic component. In this case, a portion of the radiation emitted by the semiconductor body is preferably converted to radiation of the third wavelength by the second wavelength conversion material in the encapsulant. Another portion, and any remaining portion of the radiation emitted by the semiconductor body that similarly passes unconverted through the encapsulant, are converted to radiation of the second wavelength by the first wavelength conversion material in the optical element, such that the component emits polychromatic mixed radiation composed of radiation of the second and the third wavelength.
In this exemplary embodiment, as well, the second wavelength conversion material preferably includes particles that are embedded in the matrix material of the encapsulant.
Furthermore, in this exemplary embodiment the semiconductor body and the two wavelength conversion materials are preferably adapted to each other in such a way that the radiation of the first wavelength comes from the blue region of the spectrum, and the second wavelength conversion material converts a portion of this blue radiation to red radiation and the first wavelength conversion material converts another portion of the remaining blue radiation to green radiation, such that the component emits white mixed radiation having red, green and blue components. The color space of the white mixed radiation can be matched to a desired value especially well in this case by adjusting the quantities of wavelength conversion materials.
In another preferred embodiment, disposed between the encapsulant and the optical element is a coupling layer comprising a refractive-index-matched material whose refractive index falls between the refractive index of the encapsulant and the refractive index of the matrix material of the optical element, thereby reducing radiation losses caused by reflections at the interfaces. Furthermore, the coupling layer can also serve to mechanically connect the encapsulant and the optical element.
Additionally or alternatively to the second wavelength conversion material in the encapsulant, a wavelength conversion layer comprising at least one wavelength conversion material that is different from the first and, where applicable, from the second wavelength conversion material can also be applied to the semiconductor body. This third wavelength conversion material preferably converts the radiation of the first wavelength to radiation of a fourth wavelength, such that the component emits mixed radiation of the third, of the fourth, where applicable of the second, and where applicable of the first wavelength.
If the wavelength conversion material disposed on the semiconductor body is used alternatively to the second wavelength conversion material disposed in the encapsulant, here again, the semiconductor body and the two wavelength conversion materials are adapted to one another in such a way that the radiation from the first wavelength conversion material is in the blue region of the spectrum, the third wavelength conversion material converts a portion of this radiation to red radiation, and the first wavelength conversion material converts a further portion of the residual radiation to green radiation, such that the component emits white mixed radiation having red, green and blue components.
As described above, the wavelength conversion layer need not necessarily be disposed on the semiconductor body. On the contrary, a wavelength conversion layer can also be disposed between the encapsulant and the optical element. Furthermore, it is possible for the component to have not just one, but a plurality of wavelength conversion layers, each preferably comprising different wavelength conversion materials.
If the wavelength conversion layer is used in addition to the second wavelength conversion material in the encapsulant, such that a total of at least three different wavelength conversion materials are used in the component, then a semiconductor body emitting non-visible radiation in the ultraviolet region of the spectrum is preferably used. A portion of the non-visible radiation from the semiconductor body is then converted to radiation in the red region of the spectrum, preferably by the third wavelength conversion material of the wavelength conversion layer, whereas another portion of the non-visible radiation emitted by the semiconductor body passes unconverted through the wavelength conversion layer, and another portion of this unconverted radiation is converted to radiation in the green region of the spectrum by the second wavelength conversion material in the encapsulant. A further portion of the non-visible radiation passes in turn unconverted through the encapsulant. The last portion of the non-visible radiation having passed unconverted through the encapsulant is then converted, preferably completely, to blue radiation, so that the component emits mixed radiation in the red, green and blue regions of the spectrum having a color space in the white region of the CIE standard chromaticity diagram. Depending on the desired color space of the mixed radiation, it is also conceivable for radiation from the semiconductor body to be converted to other respective regions of the spectrum.
The use of at least three wavelength conversion materials in combination with a semiconductor body emitting radiation in the visible region of the spectrum can be effective, for example, when the mixed radiation emitted by the component is intended to conform to a given color space.
In one preferred embodiment, the thickness of the wavelength conversion layer is constant, since the path length of the radiation within the wavelength conversion layer then becomes uniform. This advantageously imparts uniformity to the color impression given by the optoelectronic component.
If the component includes a wavelength conversion layer comprising a third wavelength conversion material, then the wavelength conversion layer preferably in turn comprises a matrix material and the third wavelength conversion material includes particles that are embedded in the matrix material.
As a rule, the matrix material of the wavelength conversion layer comprises or consists of a polymer that hardens to transparency, such as, for example, an epoxy, an acrylate, a polyester, a polyimide or a polyurethane, or a chlorine-containing polymer, such as, for example, a polyvinyl chloride. Mixtures of the above-cited materials are also suitable for use as the matrix material, as are silicones and hybrid materials, which are usually mixed forms composed of silicones, epoxies and acrylates. Polymers that contain polysiloxane chains are generally suitable as the matrix material.
When more than one spatially separated wavelength conversion material is used, said materials are preferably so arranged that the wavelength to which the radiation of the first wavelength is converted by the particular wavelength conversion material is in each case shorter, as viewed from the semiconductor body in its radiation direction, than the wavelength to which the preceding wavelength conversion material, with respect to the radiation direction of the semiconductor chip, converts the radiation of the first wavelength. This operates particularly effectively to prevent already converted radiation from being absorbed by a wavelength conversion material that is downstream in the radiation direction of the semiconductor chip.
The first, second and third wavelength conversion materials are selected, for example, from the group formed by the following materials: garnets doped with rare earth metals, alkaline earth sulfides doped with rare earth metals, thiogallates doped with rare earth metals, aluminates doped with rare earth metals, orthosilicates doped with rare earth metals, chlorosilicates doped with rare earth metals, alkaline earth silicon nitrides doped with rare earth metals, oxynitrides doped with rare earth metals, and aluminum oxynitrides doped with rare earth metals.
A Ce-doped YAG wavelength conversion material (YAG:Ce) is particularly preferably used as the first, second or third wavelength conversion material.
The optical element is preferably a lens, particularly preferably a convex lens. The optical element serves to shape the radiation characteristic of the optoelectronic component in a desired manner. Spherical lenses or aspherical lenses, for example elliptical lenses, can be used for this purpose. It is further conceivable to use other optical elements for beam shaping, such as, for example, a solid body configured in a pyramidal or truncated cone shape or in the manner of a compound parabolic concentrator, a compound elliptical concentrator or a compound hyperbolic concentrator.
The optical element comprises, as matrix material for the particles of the wavelength conversion material, for example a material selected from the group formed by the following materials: glass, polymethyl methacrylate (PMMA), polycarbonate (PC), cyclic olefins (COC), silicones and polymethyl methylacrylimide (PMMI).
Particularly preferably, the particular wavelength conversion material is distributed substantially uniformly in the matrix material of the optical element and/or in the matrix material of the encapsulant and/or in the matrix material of the wavelength conversion layer. A substantially uniform distribution of the wavelength conversion material advantageously leads, as a rule, to a very uniform radiation characteristic and a very uniform color impression from the optoelectronic component. The phrase “substantially uniform” means in the present context that the particles of the wavelength conversion material are distributed in the particular matrix material as evenly as is possible and useful within the limits of technical feasibility. It particularly means that the particles are not agglomerated.
However, the possibility is not to be ruled out that the arrangement of the particles in the matrix material may deviate slightly from an ideal uniform distribution, for example as a result of sedimentation of the particles during the hardening of the particular matrix material.
In a preferred embodiment, the matrix material of the optical element and/or the matrix material of the encapsulant and/or the matrix material of the wavelength conversion layer comprises light-scattering particles. These can advantageously impart uniformity to the radiation characteristic or influence the optical properties of the component in a desirable manner.
It should be noted at this point that, as a rule, the semiconductor body does not emit radiation of a single first wavelength, but rather, radiation of a plurality of different first wavelengths that preferably fall within a common first wavelength range. The first, second or third wavelength conversion material converts radiation at least from a single first wavelength to radiation of at least one other, second, third or fourth wavelength. As a rule, the first, second or third wavelength conversion material converts radiation of a plurality of first wavelengths that preferably fall within a first wavelength range to radiation of a plurality of other, second, third or fourth, wavelengths, which in turn fall within another common second, third or fourth wavelength range.
The invention is explained in more detail below with reference to five exemplary embodiments, considered in conjunction with
Therein:
In the exemplary embodiments and figures, like or like-acting elements are provided with the same respective reference numerals. The illustrated elements are basically not to be considered true to scale, but rather, individual elements, such as for example layer thicknesses, may be depicted as exaggeratedly large for the sake of better understanding.
The optoelectronic component according to the exemplary embodiment of
As illustrated in
A suitable component housing 1 is described in the document WO 02/084749 A2, whose disclosure content in that regard is hereby incorporated by reference.
The semiconductor chip in the case under consideration is a gallium nitride based LED chip 3 that emits electromagnetic radiation of a first wavelength, for instance in the blue region of the spectrum. The recess 2 in the component housing 1 in which the LED chip 3 is mounted is filled with an encapsulant 8, for example comprising a silicone compound as matrix material 81. Disposed downstream of the encapsulant 8 in the radiation direction of the LED chip 3 is a separately fabricated lens 9, which is mounted on the base body 5 of the component housing 1. In the present case, the lens 9 comprises polycarbonate as matrix material 91. However, silicones, PAAI or polyurethane (PU) are also suitable as the matrix material 91 of the lens 9. Furthermore, the lens 9 inwardly comprises particles of a first wavelength conversion material 10 that partially converts the radiation of the first wavelength from the LED chip 3, i.e., for example, in the blue region of the spectrum, to radiation of a second wavelength, for instance in the yellow region of the spectrum, such that the component as a whole emits white radiation from its front side. The particles of the first wavelength conversion material 10 in the case at hand are distributed substantially uniformly and without agglomeration in the matrix material of the lens 9. YAG:Ce, for example, can be used as the first wavelength conversion material 10.
In the case under consideration, the spaced-apart arrangement of the first wavelength conversion material 10 in the optical element 9 particularly also advantageously increases the backscattering of converted radiation from the particles of the first wavelength conversion material 10 to recess 2 configured as a reflector trough, thereby increasing the efficiency of the component.
In the optoelectronic component according to the second exemplary embodiment, that of
As distinguished from the first wavelength conversion material 10 in
Two wavelength conversion materials 10, 14 are also used in the optoelectronic component according to the exemplary embodiment of
The thickness of the wavelength conversion layer 13 comprising the third wavelength conversion material 14 is substantially constant in the present case, so the path length of the blue radiation in the wavelength conversion layer 13 is substantially constant and the fraction of the radiation converted by the third wavelength conversion material 14 does not depend on the position of the converting particles in the wavelength conversion layer 13. This contributes to a uniform color impression from the component. Like the component according to
In the optoelectronic component according to the exemplary embodiment of
The first wavelength conversion material 10, which is suitable for converting a portion of the ultraviolet radiation to radiation in the blue region of the spectrum, can be, for example, a barium magnesium aluminate, while the second wavelength conversion material 12, which is suitable for converting a portion of the ultraviolet radiation to radiation in the green region of the spectrum, can be a green-emitting Eu-doped nitride. The third wavelength conversion material 14, which is suitable for converting radiation in the ultraviolet region of the spectrum to radiation in the red region of the spectrum, can be, for example, a red-emitting Eu-doped nitride.
In the exemplary embodiment of
The component according to the exemplary embodiment of
The use of the aluminum frame 15 in the present component is optional. It is suitable for being filled with an encapsulant 8 (not shown) that serves to protect the LED chip 3 and reduces the refractive index mismatch between the LED chip 3 and its environment. In addition, a second wavelength conversion material 12 can be contained in the encapsulant 8, as described with reference to
Furthermore, the inner flanks of the aluminum frame can be configured as reflectors that serve to effect beam shaping.
For electrically contacting the LED chips 3 on their back sides, electrically conductive contact areas 18 are provided on the heat sink 16 and are electrically conductively connected by bonding wires each to a respective electrical connection area 19 on the circuit board 17 laterally of the heat sink 16. On the front side, the LED chips 3 are also each electrically conductively connected by a bonding wire to a corresponding electrical connection area 19.
The electrical connection areas 19 are connected by conductive traces 20 to additional electrical connection areas 21 that establish an electrical connection to pins 22 of an external connector 23. Electrical connector 23 is suitable for being contacted to the outside via a plug-type connector.
For mounting the optoelectronic component, holes 24 for dowel pins are also provided on the circuit board 17. In addition, the circuit board 17 includes varistors 25 to protect the component against electrostatic discharges (ESD protection).
The separate lens 9 further comprises, in the present case, integrated pins 92, which, when the lens 9 is placed on the aluminum frame 15, engage in corresponding holes 26 in the circuit board 17 and snap into them so that the lens 9 is fixed.
The invention is not limited by the description provided with reference to the exemplary embodiments. Rather, the invention encompasses any novel feature and any combination of features, including in particular any combination of features recited in the claims, even if that feature or combination itself is not explicitly mentioned in the claims or exemplary embodiments.
In particular, the invention is not limited to specific wavelength conversion materials, wavelengths, radiation-generating semiconductor bodies or optical elements.
Number | Date | Country | Kind |
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10 2005 041 063.4 | Aug 2005 | DE | national |
10 2006 020 529.4 | May 2006 | DE | national |
This application is the National Stage of International Application No PCT/DE2006/001493, filed Aug. 24, 2006, which claims priority to German Patent Application No. 10 2005 041 063.4., filed Aug. 30, 2005, and German Patent Application No. 10 2006 020 529.4, filed May 3, 2006, the contents of which are incorporated herein by reference.
Filing Document | Filing Date | Country | Kind | 371c Date |
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PCT/DE2006/001493 | 8/24/2006 | WO | 00 | 7/9/2008 |