The disclosure relates to an optoelectronic semiconductor device, an array of optoelectronic semiconductor devices and a method for manufacturing an optoelectronic semiconductor device.
An optoelectronic semiconductor device usually comprises differently doped semiconductor layers as well as an active zone. For example, when the optoelectronic semiconductor device is implemented as a light emitting diode (LED), electrons and holes may recombine with each other within the active zone, for example, when a corresponding voltage is applied to the optoelectronic semiconductor device. When electrons and holes recombine with each other, electromagnetic radiation is generated. Mesa etching is usually performed during the manufacture of micro LEDs in order to optically and electrically isolate the individual devices, or to isolate the pixels in an array. Mesa etching is also performed when manufacturing photodetectors or other radiation receiving devices in order to reduce the capacitance and therefore increase the speed.
Embodiments provide an improved optoelectronic semiconductor device and an improved method for manufacturing an optoelectronic semiconductor device.
An optoelectronic semiconductor device comprises a semiconductor layer stack comprising an active zone for generating or receiving electromagnetic radiation, the semiconductor layer stack being patterned to form a mesa having a width w measured in a first lateral direction. The optoelectronic semiconductor device further comprises a hard mask arranged over the semiconductor layer stack and having a width d measured in the first lateral direction, with d>w, the hard mask protruding from the mesa at a first lateral end and at a second lateral end of the mesa, the first lateral end and the second lateral end being arranged at opposing sides of the mesa along the first lateral direction, wherein the hard mask comprises a conductive layer directly adjacent to a semiconductor layer of the semiconductor layer stack. The optoelectronic semiconductor device additionally comprises a cover layer arranged over sidewalls of the mesa, the cover layer comprising a semiconductor material.
Generally, within the present disclosure, the mesa may have the shape of a square, a circle, a square having rounded corners, a hexagon or a hexagon having rounded corners. For example, the mesa may have the width d measured in a second lateral direction that may intersect or may be perpendicular to the first lateral direction.
For example, according to all embodiments, the hard mask may protrude from the mesa at opposing lateral ends of the mesa, e.g. along the second lateral direction. According to embodiments, the hard mask may protrude at any side of the mesa.
According to all embodiments, the conductive layer may at least extend from one side of the mesa to the other side of the mesa. For example, the conductive layer may protrude at opposing lateral ends of the mesa, e.g. along the second lateral direction. According to embodiments, the conductive layer may protrude at any side of the mesa.
The hard mask may further comprise a dielectric layer.
For example, a width of the cover layer may be equal to at least a difference between d and w, the width being measured in the first lateral direction.
A band gap of a material of the cover layer may be larger than the band gap of the active zone, e.g. of any layer or quantum well structure constituting the active zone. For example, the band gap of all materials of the cover layer may be larger than the band gap of any layer or quantum well structure constituting the active zone.
According to embodiments, the semiconductor layer stack comprises a first semiconductor layer of a first conductivity type and a second semiconductor layer of a second conductivity type and the active zone is arranged between the first semiconductor layer and the second semiconductor layer. The second semiconductor layer is directly adjacent to the conductive layer.
For example, the cover layer comprises a first sublayer of a first conductivity type and a second sublayer of a second conductivity type, the first sublayer being directly adjacent to the sidewalls of the mesa. For example, the band gap of the first sublayer and/or the second sublayer may be larger than the band gap of the active zone, e.g. of any layer or quantum well structure constituting the active zone.
In an array of optoelectronic semiconductor devices as defined above, adjacent optoelectronic semiconductor devices may be separated from each other by a separating groove in the cover layer, the separating groove extending between the hard masks of the adjacent optoelectronic semiconductor devices.
An array of optoelectronic semiconductor devices comprises a semiconductor layer stack comprising an active zone for generating or receiving electromagnetic radiation, the semiconductor layer stack being patterned to form a plurality of mesas having a width w measured in a first lateral direction. The array further comprises portions of a hard mask arranged over the semiconductor layer stack and having a width d measured in the first lateral direction, with d>w, the hard mask protruding from each of the mesas at a first lateral end and at a second lateral end of each of the mesas, the first lateral end and the second lateral end being arranged at opposing sides of the mesas along the first lateral direction. The array additionally comprises a cover layer arranged over sidewalls of each of the mesas, the cover layer comprising a semiconductor material and a plurality of separating grooves between adjacent optoelectronic semiconductor devices, the separating groove extending between the portions of the hard mask of adjacent optoelectronic semiconductor devices and being directly adjacent to the portions of the hard mask of the adjacent optoelectronic semiconductor devices.
A method of manufacturing an optoelectronic semiconductor device comprises forming a semiconductor layer stack comprising an active zone for generating or receiving electromagnetic radiation, forming a hard mask layer over the semiconductor layer stack, patterning the hard mask layer to form a hard mask having a width d measured in the first lateral direction, and patterning the semiconductor layer stack to form a mesa having a width w measured in a first lateral direction with d>w. The hard mask protrudes from the mesa at a first lateral end and at a second lateral end of the mesa, the first lateral end and the second lateral end being arranged at opposing sides of the mesa along the first lateral direction. The method further comprises forming a cover layer over sidewalls of the mesa, the cover layer comprising a semiconductor material and etching the semiconductor material of the cover layer using the hard mask as an etching mask to form a separating groove.
According to embodiments, patterning the semiconductor layer stack may comprise an anisotropic etching step followed by an isotropic etching step.
For example, the semiconductor layer stack may comprise a first semiconductor layer of a first conductivity type and a second semiconductor layer of a second conductivity type and the active zone is arranged between the first semiconductor layer and the second semiconductor layer, the second semiconductor layer being formed to be directly adjacent to the hard mask layer.
According to embodiments, forming the hard mask layer comprises forming a conductive layer directly adjacent to the second semiconductor layer of the semiconductor layer stack.
According to further embodiments, forming the hard mask layer comprises forming a dielectric layer directly adjacent to the second semiconductor layer of the semiconductor layer stack.
The method may further comprise removing the dielectric layer after forming the separating groove.
According to embodiments, the method further comprises forming a passivation layer after forming the separating groove, removing horizontal portions of the passivation layer to expose a surface of the mesas, and forming a conductive material to cover the surface of the mesas.
For example, due to forming the separating grooves a plurality of semiconductor devices are obtained.
According to further embodiments, a portion of the semiconductor layer stack is maintained when forming the separating grooves. In this case, adjacent optoelectronic semiconductor devices may be electrically connected by a portion of the semiconductor layer stack.
An optoelectronic apparatus according to embodiments comprises the optoelectronic semiconductor device or the array of optoelectronic semiconductor devices as explained above.
The accompanying drawings are included to provide a further understanding of embodiments of the invention and are incorporated in and constitute a part of this specification. The drawings illustrate the embodiments of the present invention and together with the description serve to explain the principles. Other embodiments of the invention and many of the intended advantages will be readily appreciated, as they become better understood by reference to the following detailed description. The elements of the drawings are not necessarily to scale relative to each other. Like reference numbers designate corresponding similar parts.
In the following detailed description reference is made to the accompanying drawings, which form a part hereof and in which are illustrated by way of illustration specific embodiments in which the invention may be practiced. In this regard, directional terminology such as “top”, “bottom”, “front”, “back”, “over”, “on”, “above”, “leading”, “trailing” etc. is used with reference to the orientation of the Figures being described. Since components of embodiments of the invention can be positioned in a number of different orientations, the directional terminology is used for purposes of illustration and is in no way limiting. It is to be understood that other embodiments may be utilized and structural or logical changes may be made without departing from the scope defined by the claims.
The terms “wafer” or “semiconductor substrate” used in the following description may include any semiconductor-based structure that has a semiconductor surface. Wafer and structure are to be understood to include doped and undoped semiconductors, epitaxial semiconductor layers, e.g. supported by a base semiconductor foundation, and other semiconductor structures. For example, a layer of a first semiconductor material may be grown on a growth substrate of a second semiconductor material. According to further embodiments, the growth substrate may be an insulating substrate such as a sapphire substrate. Depending on the purpose of use, the semiconductor may be based on a direct or an indirect semiconductor material. Examples of semiconductor materials particularly suitable for generation of electromagnetic radiation comprise nitride-compound semiconductors, by which e.g. ultraviolet or blue light or longer wavelength light may be generated, such as GaN, InGaN, AlN, AlGaN, AlGaInN, phosphide-compound semiconductors, by which e.g. green or longer wavelength light may be generated such as GaAsP, AlGaInP, GaP, AlGaP, as well as further semiconductor materials including AlGaAs, SiC, ZnSe, GaAs, ZnO, Ga2O3, diamond, hexagonal BN und combinations of these materials. Further examples of semiconductor materials may as well be silicon, silicon-germanium and germanium. The stoichiometric ratio of the compound semiconductor materials may vary. In the context of the present specification, the term “semiconductor” further encompasses organic semiconductor materials.
The term “vertical” as used in this specification intends to describe an orientation which is arranged perpendicular to the first surface of a substrate or semiconductor body.
The terms “lateral” and “horizontal” as used in this specification intends to describe an orientation parallel to a first surface of a substrate or semiconductor body. This can be for instance the surface of a wafer or a die.
As employed in this specification, the terms “coupled” and/or “electrically coupled” are not meant to mean that the elements must be directly coupled together—intervening elements may be provided between the “coupled” or “electrically coupled” elements. The term “electrically connected” intends to describe a low-ohmic electric connection between the elements electrically connected together.
The term “electrically connected” further comprises tunnelling contacts between connected elements.
As used herein, the terms “having”, “containing”, “including”, “comprising” and the like are open ended terms that indicate the presence of stated elements or features, but do not preclude additional elements or features. The articles “a”, “an” and “the” are intended to include the plural as well as the singular, unless the context clearly indicates otherwise.
Embodiments of the present application are explained while referring to an LED. As is to be clearly understood, the optoelectronic semiconductor device according to all embodiments may as well be implemented as a light receiving device, e.g. a photodetector.
For performing the method according to embodiments, a semiconductor layer stack 105 is epitaxially grown over an appropriate substrate 100. In particular, the substrate 100 may be a growth substrate for the specific semiconductor layers of the semiconductor layer stack 105. For example, the semiconductor layer stack 105 may comprise a first semiconductor layer 110 of a first conductivity type, e.g. n-type, an active zone 115 and a second semiconductor layer 120 of a second conductivity type, e.g. p-type. For example, the semiconductor layers of the semiconductor layer stack 105 may comprise a phosphide compound semiconductor. For example, materials may comprise AlnGamIn1-n-mP or InuGa1-uAsvP1-v or mixtures thereof, with 0≤n≤1, 0≤m≤1 and n+m≤1, 0≤u≤1, 0≤v≤1. As is to be clearly understood, any other semiconductor material may be employed.
In the context of the present specification, the term “active zone” refers to those layers of the optoelectronic device which are configured to generate the electromagnetic radiation emitted by the optoelectronic device. Specific examples comprise inter alia a pn junction, a double heterostructure, a single quantum well structure (SQW), a multiple quantum well (MQW) structure and/or a quantum cascade structure and any combination of these structures. According to further embodiments, the term “active zone” also refers to those layers of the optoelectronic device which absorb electromagnetic radiation.
Then, as is shown in
In the next step as illustrated in
In a next step, an etching process for etching the semiconductor layer stack 105 is performed. In particular, this etching comprises an anisotropic etching step in which an etching rate in a vertical direction is larger than in a horizontal direction. For example, this etching process may comprise a dry or plasma etching process. This etching is performed so as to completely etch the second semiconductor layer 120, the active zone 115 and portion of the first semiconductor layer 110. Further, an isotropic etching process is performed. For example, this etching process may comprise a wet etching step. Due to this etching step, a portion of the hard mask 123 facing the substrate 100 is exposed. For example, when the semiconductor layers of the semiconductor layer stack comprise layers of the (In)Ga(Al)P material system, the etchant may contain HCl For example, this etching may determine the width w of the mesa 130.
The mesa 130 has two opposing sidewalls 132. The sidewalls 132 extend in a direction intersecting a horizontal direction. For example, the sidewalls 132 may extend in a vertical direction. According to further embodiments, the extension direction of the sidewalls 132 may be oblique with respect to a vertical direction. For example, the mesas 130 may have a tapered shape, so that a diameter of the mesa 130 on a side facing the growth substrate 100 is larger than on a side remote from the growth substrate 100.
A difference between the width d of the hard mask 123 and the width w of the mesa 130 may be determined by the isotropic etching process. For example, the difference may be larger than 0.2 μm. The difference to be set depends on the diffusion length of the charge carriers and thus the specific semiconductor material employed. The difference may be designed depending on material parameters and the width of the resulting optoelectronic semiconductor device (pixel).
Thereafter, a cover layer 135 is formed over sidewalls 132 of the mesa 130. The cover layer comprises a semiconductor material.
A cover layer 135 may be epitaxially formed, e.g. using an MOCVD (“metal organic chemical vapour deposition”) method. For example, a material of the cover layer 135 may comprise a III-V or a II-VI semiconductor material. For example, a band gap of the cover layer 135 may be larger than the band gap of the active zone 115. For example, the band gap of the material of the cover layer 135 may be larger than the band gap of any layer or quantum well structure constituting the active zone 115.
For example, the cover layer 135 may comprise GaN, AlGaP, InAlP or ZnSSe. The cover layer 135 may be doped or may be semi-insulating. For example, the cover layer may comprise several sublayers of opposite polarity, e.g. n-type, p-type or semi-insulating. The cover layer 135 may fill the space between adjacent mesas.
For example, as is shown in
In a next step, for example, this further material of the cover layer 135 may be removed from the hard mask 123, e.g. by polishing. According to further embodiments, this part of the cover material 135 may as well be removed during subsequent processing steps.
In a next step, separating grooves 140 are formed so as to separate adjacent optoelectronic semiconductor devices (pixels) 10 from each other. The separating grooves 140 are formed using the hard mask 123 as an etching mask. In particular, an etching step is performed so as to etch the cover layer 135. For example, this may be accomplished using an anisotropic etching method, e.g. dry etching. For example, the separating grooves 140 may be formed to extend to the substrate 100. According to further examples, the separating grooves 140 may be formed so as not to extend to the substrate 100. For example, by forming separating grooves 140 that do not completely separate the single pixels, a pixel array may be formed. In this case, adjacent pixels may be connected by a portion of the first semiconductor layer 110.
Thereafter, the dielectric layer 124 may be removed from the single optoelectronic semiconductor devices 10, e.g. using an etching process. According to embodiments, a further cleaning step may be performed so as to clean the resulting surface.
The semiconductor device 10 further comprises a hard mask 123 arranged over the semiconductor layer stack 105 and having a width d, measured in the first lateral direction, with d>w. For example, due to the isotropic etching described with reference to
For example, the hard mask may protrude from the mesa 130 at opposing lateral ends of the mesa, e.g. along the second lateral direction. According to embodiments, the hard mask 123 may protrude at any side of the mesa 130.
As is further shown in
As is further illustrated in
The cover layer 135 may be epitaxially grown. For example, atoms or molecules of the cover layer may be bonded to dangling bonds or unpaired bonds at the sidewalls of the mesa 130 in a region of the active zone 115. For example, after etching the mesa, the mesa edges are defective and include dangling bonds which may be recombination centres. As a result, non-radiative combination of carriers may be caused at the mesa edges. Due to the presence of the cover layer, these dangling bonds may be removed or bonded to atoms or molecules of the cover layer 135. Hence, non-radiative recombination may be reduced.
Since, as has been described above, the hard mask 123 that has been used for etching the mesa is also used for defining the separating grooves 140, the alignment accuracy of the separating grooves 140 may be greatly improved. More specifically, a self-aligned formation of the optoelectronic semiconductor devices 10 is enabled.
In particular, when the pixels or optoelectronic semiconductor devices have a small width, e.g. in the order of 1 μm in a lateral direction, a more precise alignment of the separating grooves 140 increases the performance between the manufactured optoelectronic semiconductor devices over a wafer and on a wafer-to-wafer scale. To be more specific, when the optoelectronic semiconductor devices have a small size, the distance between a central portion of the active zone to an edge of the optoelectronic semiconductor devices may determine the degree of non-radiative recombination. Hence, when this distance is set to a uniform value over a wafer or on a wafer-to-wafer scale, a more uniform performance may be achieved. Moreover, additional processing steps for photolithographic defining the position of the separating grooves 140 may be dispensed with.
For example, the conductive layer 125 may comprise a transparent conductive oxide such as ITO. ITO is not attacked during a wet etching process. Further, it is stable at high temperature, e.g. temperatures during growth of the cover layer 135.
According to further embodiments, the conductive layer 125 may be dispensed with.
Starting from any of
Thereafter, a polishing step may be performed so as to polish horizontal portions of the passivation layer 143 arranged over the mesas 130. As a result, a surface of the dielectric layer 124 or the conductive layer 125 is exposed.
As is illustrated in
Thereafter, as is illustrated in
Thereafter, for example, the substrate 100 may be removed from the workpiece, allowing the placement of a second contact to the device. This second contact can also be obtained through the grooves so that both contacts are formed on the same side. The light emission may be through the side that is remote from the bonded carrier. Other processing steps such as to make the array transfer-printable onto an electronic driver (for example, CMOS) wafer or directly bonded onto the driver wafer are also possible.
For example, starting from a workpiece similar to a workpiece explained with reference to
Then, as is illustrated in
Thereafter, second contact pads 122 may be formed so as to be connected to the second contact elements 121, as is shown in
Thereafter, for example, a wiring pattern may be provided over the target carrier 155 so as to electrically connect the second contact elements 121 with the second contact pads 122 and to address the first contact elements 111. Further wiring schemes may be applied so as to electrically contact the first and the second semiconductor layers of each of the optoelectronic semiconductor devices. For example, the first and the second contact elements 111, 121 may be formed from opposite sides of the workpiece 20.
Thereafter, as is illustrated in
Thereafter, for example, the substrate 100 may be removed from the workpiece, allowing the placement of second contact elements to the device. This second contact element may also be obtained through the grooves so that both contacts are formed on the same side. For example, forming the first and second contact elements may accomplish in the manner as has been explained with reference to
The described contacting of the semiconductor layer 120 or the conductive layer 125 may also be achieved using lithographic methods and etching processes. For example, instead of polishing the passivation layer 143, the passivation layer 143 on top of the pixel may be etched to expose the semiconductor layer 120 or the conductive layer 125.
While embodiments of the invention have been described above, it is obvious that further embodiments may be implemented. For example, further embodiments may comprise any subcombination of features recited in the claims or any subcombination of elements described in the examples given above. Accordingly, this spirit and scope of the appended claims should not be limited to the description of the embodiments contained herein.
Number | Date | Country | Kind |
---|---|---|---|
10 2021 117 123.7 | Jul 2021 | DE | national |
This patent application is a national phase filing under section 371 of PCT/EP2022/067933, filed Jun. 29, 2022, which claims the priority of German patent application 10 2021 117 123.7, filed Jul. 2, 2021, each of which is incorporated herein by reference in its entirety.
Filing Document | Filing Date | Country | Kind |
---|---|---|---|
PCT/EP2022/067933 | 6/29/2022 | WO |