Organic coated development electrodes and methods thereof

CROSS REFERENCE TO RELATED APPLICATIONS
Attention is directed to the following copending applications assigned to the assignee of the present application: U.S. application Ser. No. 08/841,033 filed Apr. 29, 1997, entitled, "Coated Development Electrodes and Methods Thereof," U.S. application Ser. No. 08/841,129 filed Apr. 29, 1997, entitled, "Inorganic Coated Development Electrodes and Methods Thereof;" U.S. application Ser. No. 08/841,034, filed Apr. 29, 1997, entitled "Composite Coated Development Electrodes and Methods Thereof;" and U.S. application Ser. No. 08/841,235, filed Apr. 29, 1997, entitled "Coating Compositions for Development Electrodes and Methods Thereof;" The disclosures of each of these applications are hereby incorporated by reference in their entirety.
BACKGROUND OF THE INVENTION
The present invention relates to methods, processes and apparatii for development of images, and more specifically, to electrode members for use in a developer unit in electrophotographic printing machines. Specifically, the present invention relates to methods and apparatii in which at least a portion of a development unit electrode member is coated with a coating material, and in embodiments, a low surface energy coating material. In embodiments, electrode member history, damping and/or toner accumulation is controlled or reduced.
Generally, the process of electrophotographic printing includes charging a photoconductive member to a substantially uniform potential so as to sensitize the photoconductive member thereof. The charged portion of the photoconductive member is exposed to a light image of an original document being reproduced. This records an electrostatic latent image on the photoconductive member. After the electrostatic latent image is recorded on the photoconductive member, the latent image is developed by bringing a developer material into contact therewith. Two component and single component developer materials are commonly used. A typical two component developer material comprises magnetic carrier granules having toner particles adhering triboelectrically thereto. A single component developer material typically comprises toner particles. Toner particles are attracted to the latent image forming a toner powder image on the photoconductive member. The toner powder image is subsequently transferred to a copy sheet. Finally, the toner powder image is heated to permanently fuse it to the copy sheet in image configuration.
One type of single component development system is a scavengeless development system that uses a donor roll for transporting charged toner to the development zone. At least one, and preferably a plurality of electrode members are closely spaced to the donor roll in the development zone. An AC voltage is applied to the electrode members forming a toner cloud in the development zone. The electrostatic fields generated by the latent image attract toner from the toner cloud to develop the latent image.
Another type of a two component development system is a hybrid scavengeless development system which employs a magnetic brush developer roller for transporting carrier having toner adhering triboelectrically thereto. A donor roll is used in this configuration also to transport charged toner to the development zone. The donor roll and magnetic roller are electrically biased relative to one another. Toner is attracted to the donor roll from the magnetic roll. The electrically biased electrode members detach the toner from the donor roll forming a toner powder cloud in the development zone, and the latent image attracts the toner particles thereto. In this way, the latent image recorded on the photoconductive member is developed with toner particles.
Various types of development systems have hereinbefore been used as illustrated by the following disclosures, which may be relevant to certain aspects of the present invention.
U.S. Pat. No. 4,868,600 to Hays et al., the subject matter of which is hereby incorporated by reference in its entirety, describes an apparatus wherein a donor roll transports toner to a region opposed from a surface on which a latent image is recorded. A pair of electrode members are positioned in the space between the latent image surface and the donor roll and are electrically biased to detach toner from the donor roll to form a toner cloud. Detached toner from the cloud develops the latent image.
U.S. Pat. No. 4,984,019, to Folkins, the subject matter of which is hereby incorporated by reference in its entirety, discloses a developer unit having a donor roll with electrode members disposed adjacent thereto in a development zone. A magnetic roller transports developer material to the donor roll. Toner particles are attracted from the magnetic roller to the donor roller. When the developer unit is inactivated, the electrode members are vibrated to remove contaminants therefrom.
U.S. Pat. No. 5,124,749 to Bares, the subject matter of which is hereby incorporated by reference in its entirety, discloses an apparatus in which a donor roll advances toner to an electrostatic latent image recorded on a photoconductive member wherein a plurality of electrode wires are positioned in the space between the donor roll and the photoconductive member. The wires are electrically biased to detach the toner from the donor roll so as to form a toner cloud in the space between the electrode wires and the photoconductive member. The powder cloud develops the latent image. A damping material is coated on a portion of the electrode wires at the position of attachment to the electrode supporting members for the purpose of damping vibration of the electrode wires.
U.S. Pat. Nos. 5,300,339 and 5,448,342 both to Hays et al., the subject matter each of which is hereby incorporated by reference in their entirety, disclose a coated toner transport roll containing a core with a coating thereover.
U.S. Pat. No. 5,172,170 to Hays et al., the subject matter of which is hereby incorporated by reference in its entirety, discloses an apparatus in which a donor roll advances toner to an electrostatic latent image recorded on a photoconductive member. The donor roll includes a dielectric layer disposed about the circumferential surface of the roll between adjacent grooves.
Primarily because the adhesion force of the toner particles is greater than the stripping force generated by the electric field of the electrode members in the development zone, a problem results in that toner tends to build up on the electrode members. Accumulation of toner particles on the wire member causes non-uniform development of the latent image, resulting in print defects. The problem is aggravated by toner fines and any toner components, such as high molecular weight, crosslinked and/or branched components, and the voltage breakdown between the wire member and the donor roll.
One specific example of toner contamination results upon development of a document having solid areas which require a large concentration of toner to be deposited at a particular position on the latent image. The areas of the electrode member corresponding to the high throughput or high toner concentration areas tend to include higher or lower accumulation of toner because of this differing exposure to toner throughput. When the printer subsequently attempts to develop another, different image, the toner accumulation on the electrode member will lead to differential development of the newly developed image corresponding to the areas of greater or lesser toner accumulation on the electrode members. The result is a darkened or lightened band in the position corresponding to the solid area of the previous image. This is particularly evident in areas of intermediate density, since these are the areas most sensitive to differences in development. These particular image defects caused by toner accumulation on the electrode wires at the development zone are referred to as wire history. FIG. 5 contains an illustration of wire contamination and wire history. Wire contamination results when fused toner forms between the electrode member and donor member due to toner fines and any toner components, such as high molecular weight, crosslinked and/or branched components, and the voltage breakdown between the wire member and the donor roll. Wire history is a change in developability due to toner or toner components sticking to the top of the electrode member.
Accordingly, there is a specific need for electrode members in the development zone of a development unit of an electrophotographic printing machine which provide for a decreased tendency for toner accumulation in order to decrease wire history and wire contamination, especially at high throughput areas, and decreasing the production of unwanted surface static charges from which contaminants may not release. One possible solution is to change the electrical properties of the wire. However, attempts at decreasing toner build-up on the development wire by changing the electrical properties thereof, may result in an interference with the function of the wire and its ability to produce the formation of the toner powder cloud. Therefore, there is a specific need for electrode members which have a decreased tendency to accumulate toner and which also retain their electrical properties in order to prevent interference with the functioning thereof. There is an additional need for electrode members which have superior mechanical properties including durability against severe wear the electrode member receives when it is repeatedly brought into contact with tough rotating donor roll surfaces.
SUMMARY OF THE INVENTION
Examples of objects of the present invention include:
It is an object of the present invention to provide an apparatus for reducing toner accumulation of electrode members in the development zone of a developing unit in an electrophotographic printing apparatus with many of the advantages indicated herein.
Another object of the present invention is to provide an apparatus for reducing toner adhesion to electrode members.
It is another object of the present invention to provide an apparatus comprising electrode members having a lower surface energy.
It is yet another object of the present invention to provide an apparatus comprising electrode members having increased mechanical strength.
Still yet another object of the present invention is to provide an apparatus comprising electrode members which have superior electrical properties.
A further object of the present invention is to provide an apparatus comprising electrode members which have smooth surfaces.
Many of the above objects have been met by the present invention, in embodiments, which includes: an apparatus for developing a latent image recorded on a surface, comprising: wire supports; a donor member spaced from the surface and being adapted to transport toner to a region opposed from the surface; an electrode member positioned in the space between the surface and the donor member, the electrode member being closely spaced from the donor member and being electrically biased to detach toner from the donor member thereby enabling the formation of a toner cloud in the space between the electrode member and the surface with detached toner from the toner cloud developing the latent image, wherein opposed end regions of the electrode member are attached to wire supports adapted to support the opposed end regions of the electrode member; and an organic coating, for example a low surface energy organic coating, on at least a portion of nonattached regions of the electrode member.
Embodiments further include: an electrophotographic process comprising: a) forming an electrostatic latent image on a charge-retentive surface; b) applying toner in the form of a toner cloud to the latent image to form a developed image on the charge retentive surface, wherein the toner is applied using a development apparatus comprising wire supports; a donor member spaced from the surface and being adapted to transport toner to a region opposed from the surface; an electrode member positioned in the space between the surface and the donor member, the electrode member being closely spaced from the donor member and being electrically biased to detach toner from the donor member thereby enabling the formation of a toner cloud in the space between the electrode member and the surface with detached toner from the toner cloud developing the latent image, wherein opposed end regions of the electrode member are attached to the wire supports adapted to support the opposed end regions of the electrode member; and a low surface energy organic coating on at least a portion of nonattached regions of the electrode member; and c) transferring the toner image from the charge-retentive surface to a substrate; d) fixing the toner image to the substrate.
The present invention provides electrode members which, in embodiments, have a decreased tendency to accumulate toner and which also, in embodiments, retain their electrical properties in order to prevent interference with the functioning thereof. The present invention further provides electrode members which, in embodiments, have superior mechanical properties including durability against severe wear the electrode member receives when it is repeatedly brought into contact with tough rotating donor roll surfaces.

BRIEF DESCRIPTION OF THE DRAWINGS
The above aspects of the present invention will become apparent as the following description proceeds upon reference to the drawings in which:
FIG. 1 is a schematic illustration of an embodiment of a development apparatus useful in an electrophotographic printing machine.
FIG. 2 is an enlarged, schematic illustration of a donor roll and electrode member representing an embodiment of the present invention.
FIG. 3 is a fragmentary schematic illustration of a development housing comprising a donor roll and an electrode member from a different angle than as shown in FIG. 2.
FIG. 4 is an enlarged, schematic illustration of an electrode member supported by mounting means in an embodiment of the present invention.
FIG. 5 is an illustration of wire contamination and wire history.

DETAILED DESCRIPTION
For a general understanding of the features of the present invention, a description thereof will be made with reference to the drawings.
FIG. 1 shows a development apparatus used in an electrophotographic printing machine such as that illustrated and described in U.S. Pat. No. 5,124,749, the disclosure of which is hereby incorporated by reference in its entirety. This patent describes the details of the main components of an electrophotographic printing machine and how these components interact. The present application will concentrate on the development unit of the electrophotographic printing machine. Specifically, after an electrostatic latent image has been recorded on a photoconductive surface, a photoreceptor belt advances the latent image to the development station. At the development station, a developer unit develops the latent image recorded on the photoconductive surface.
Referring now to FIG. 1, in a preferred embodiment of the invention, developer unit 38 develops the latent image recorded on the photoconductive surface 10. Preferably, developer unit 38 includes donor roller 40 and electrode member or members 42. Electrode members 42 are electrically biased relative to donor roll 40 to detach toner therefrom so as to form a toner powder cloud in the gap between the donor roll 40 and photoconductive surface 10. The latent image attracts toner particles from the toner powder cloud forming a toner powder image thereon. Donor roller 40 is mounted, at least partially, in the chamber of developer housing 44. The chamber in developer housing 44 stores a supply of developer material. The developer material is a two component developer material of at least carrier granules having toner particles adhering triboelectrically thereto. A magnetic roller 46 disposed interior of the chamber of housing 44 conveys the developer material to the donor roller 40. The magnetic roller 46 is electrically biased relative to the donor roller so that the toner particles are attracted from the magnetic roller to the donor roller.
More specifically, developer unit 38 includes a housing 44 defining a chamber 76 for storing a supply of two component (toner and carrier) developer material therein. Donor roller 40, electrode members 42 and magnetic roller 46 are mounted in chamber 76 of housing 44. The donor roller can be rotated in either the `with` or `against` direction relative to the direction of motion of belt 10. In FIG. 1, donor roller 40 is shown rotating in the direction of arrow 68. Similarly, the magnetic roller can be rotated in either the `with` or `against` direction relative to the direction of motion of belt 10. In FIG. 1, magnetic roller 46 is shown rotating in the direction of arrow 92. Donor roller 40 is preferably made from anodized aluminum or ceramic.
Developer unit 38 also has electrode members 42 which are disposed in the space between the belt 10 and donor roller 40. A pair of electrode members are shown extending in a direction substantially parallel to the longitudinal axis of the donor roller. The electrode members are made from of one or more thin (i.e., 50 to 100 .mu.m in diameter) stainless steel or tungsten electrode members which are closely spaced from donor roller 40. The distance between the electrode members and the donor roller is from about 5 to about 35 .mu.m, preferably about 10 to about 25 .mu.m or the thickness of the toner layer on the donor roll. The electrode members are self-spaced from the donor roller by the thickness of the toner on the donor roller. To this end, the extremities of the electrode members supported by the tops of end bearing blocks also support the donor roller for rotation. The electrode member extremities are attached so that they are slightly above a tangent to the surface, including toner layer, of the donor structure. Mounting the electrode members in such a manner makes them insensitive to roll run-out due to their self-spacing.
As illustrated in FIG. 1, an alternating electrical bias is applied to the electrode members by an AC voltage source 78. The applied AC establishes an alternating electrostatic field between the electrode members and the donor roller is effective in detaching toner from the photoconductive member of the donor roller and forming a toner cloud about the electrode members, the height of the cloud being such as not to be substantially in contact with the belt 10. The magnitude of the AC voltage is relatively low and is in the order of 200 to 500 volts peak at a frequency ranging from about 9 kHz to about 15 kHz. A DC bias supply 80 which applies approximately 300 volts to donor roller 40 establishes an electrostatic field between photoconductive member of belt 10 and donor roller 40 for attracting the detached toner particles from the cloud surrounding the electrode members to the latent image recorded on the photoconductive member. At a spacing ranging from about 0.001 .mu.m to about 45 .mu.m between the electrode members and donor roller, an applied voltage of 200 to 500 volts produces a relatively large electrostatic field without risk of air breakdown. A cleaning blade 82 strips all of the toner from donor roller 40 after development so that magnetic roller 46 meters fresh toner to a clean donor roller. Magnetic roller 46 meters a constant quantity of toner having a substantially constant charge onto donor roller 40. This insures that the donor roller provides a constant amount of toner having a substantially constant charge in the development gap. In lieu of using a cleaning blade, the combination of donor roller spacing, i.e., spacing between the donor roller and the magnetic roller, the compressed pile height of the developer material on the magnetic roller, and the magnetic properties of the magnetic roller in conjunction with the use of a conductive, magnetic developer material achieves the deposition of a constant quantity of toner having a substantially charge on the donor roller. A DC bias supply 84 which applies approximately 100 volts to magnetic roller 46 establishes an electrostatic field between magnetic roller 46 and donor roller 40 so that an electrostatic field is established between the donor roller and the magnetic roller which causes toner particles to be attracted from the magnetic roller to the donor roller. Metering blade 86 is positioned closely adjacent to magnetic roller 46 to maintain the compressed pile height of the developer material on magnetic roller 46 at the desired level. Magnetic roller 46 includes a non-magnetic tubular member 88 made preferably from aluminum and having the exterior circumferential surface thereof roughened. An elongated magnet 90 is positioned interiorly of and spaced from the tubular member. The magnet is mounted stationarily. The tubular member rotates in the direction of arrow 92 to advance the developer material adhering thereto into the nip defined by donor roller 40 and magnetic roller 46. Toner particles are attracted from the carrier granules on the magnetic roller to the donor roller.
With continued reference to FIG. 1, an auger, indicated generally by the reference numeral 94, is located in chamber 76 of housing 44. Auger 94 is mounted rotatably in chamber 76 to mix and transport developer material. The auger has blades extending spirally outwardly from a shaft. The blades are designed to advance the developer material in the axial direction substantially parallel to the longitudinal axis of the shaft.
As successive electrostatic latent images are developed, the toner particles within the developer material are depleted. A toner dispenser (not shown) stores a supply of toner particles which may include toner and carrier particles. The toner dispenser is in communication with chamber 76 of housing 44. As the concentration of toner particles in the developer material is decreased, fresh toner particles are furnished to the developer material in the chamber from the toner dispenser. In an embodiment of the invention, the auger in the chamber of the housing mix the fresh toner particles with the remaining developer material so that the resultant developer material therein is substantially uniform with the concentration of toner particles being optimized. In this way, a substantially constant amount of toner particles are in the chamber of the developer housing with the toner particles having a constant charge. The developer material in the chamber of the developer housing is magnetic and may be electrically conductive. By way of example, in an embodiment of the invention wherein the toner includes carrier particles, the carrier granules include a ferromagnetic core having a thin layer of magnetite overcoated with a non-continuous layer of resinous material. The toner particles may be made from a resinous material, such as a vinyl polymer, mixed with a coloring material, such as chromogen black. The developer material may comprise from about 90% to about 99% by weight of carrier and from 10% to about 1% by weight of toner. However, one skilled in the art will recognize that any other suitable developer material may be used.
In an alternative embodiment of the present invention, one component developer material consisting of toner without carrier may be used. In this configuration, the magnetic roller 46 is not present in the developer housing. This embodiment is described in more detail in U.S. Pat. No. 4,868,600, the disclosure of which is hereby incorporated by reference in its entirety.
An embodiment of the developer unit is further depicted in FIG. 2. The developer apparatus 34 comprises an electrode member 42 which is disposed in the space between the photoreceptor (not shown in FIG. 2) and the donor roll 40. The electrode 42 can be comprised of one or more thin (i.e., 50 to about 100 .mu.m in diameter) tungsten or stainless steel electrode members which are lightly positioned at or near the donor structure 40. The electrode member is closely spaced from the donor member. The distance between the wire(s) and the donor is approximately 0.001 to about 45 .mu.m, and preferably from about 10 to about 25 .mu.m or the thickness of the toner layer 43 on the donor roll. The wires as shown in FIG. 2 are self spaced from the donor structure by the thickness of the toner on the donor structure. The extremities or opposed end regions of the electrode member are supported by support members 54 which may also support the donor structure for rotation. In a preferred embodiment, the electrode member extremities or opposed end regions are attached so that they are slightly below a tangent to the surface, including toner layer, of the donor structure. Mounting the electrode members in such a manner makes them insensitive to roll runout due to their self-spacing.
In an alternative embodiment to that depicted in FIG. 1, the metering blade 86 is replaced by a combined metering and charging blade 86 as shown in FIG. 3. The combination metering and charging device may comprise any suitable device for depositing a monolayer of well charged toner onto the donor structure 40. For example, it may comprise an apparatus such as that described in U.S. Pat. No. 4,459,009, wherein the contact between weakly charged toner particles and a triboelectrically active coating contained on a charging roller results in well charged toner. Other combination metering and charging devices may be employed, for example, a conventional magnetic brush used with two component developer could also be used for depositing the toner layer onto the donor structure, or a donor roller alone used with one component developer.
FIG. 4 depicts an enlarged view of a preferred embodiment of the electrode member of the present invention. Electrode wires 45 are positioned inside electrode member 42. The anchoring portions 55 of the electrode members are the portions of the electrode member which anchor the electrode member to the support member. The mounting sections 56 of the electrode member are the sections of the electrode members between the electrode member and the mounting means 54.
Toner particles are attracted to the electrode members primarily through electrostatic attraction. Toner particles adhere to the electrode members because the adhesion force of the toner is larger than the stripping force generated by the electric field of the electrode member. Generally, the adhesion force between a toner particle and an electrode member is represented by the general expression F.sub.ad =q.sup.2 /kr.sup.2 +W, wherein F.sub.ad is the force of adhesion, q is the charge on the toner particle, k is the effective dielectric constant of the toner and any dielectric coating, and r is the separation of the particle from its image charge within the wire which depends on the thickness, dielectric constant, and conductivity of the coating. Element W is the force of adhesion due to short range adhesion forces such as van der Waals and capillary forces. The force necessary to strip or remove particles from the electrode member is supplied by the electric field of the wire during half of its AC period, qE, plus effective forces resulting from mechanical motion of the electrode member and from bombardment of the wire by toner in the cloud. Since the adhesion force is quadratic in q, adhesion forces will be larger than stripping forces for sufficiently high values of q.
FIG. 5 contains an illustration of wire contamination and wire history. A photoreceptor 1 is positioned near wire 4 and contains an undeveloped image 6 which is subsequently developed by toner originating from donor member 3. Wire contamination occurs when fused toner 5 forms between the wire 4 and donor member 3 due to toner fines and any toner components, such as high molecular weight, crosslinked and/or branched components, and the voltage breakdown between the wire member and the donor roll. Wire history is a change in developability due to toner 2 or toner components sticking to the top of the wire 4, the top of the wire being the part of the wire facing the photoreceptor.
In order to prevent the toner defects associated with wire contamination and wire history, the electrical properties of the electrode member can be changed, thereby changing the adhesion forces in relation to the stripping forces. However, such changes in the electrical properties of the electrode member may adversely affect the ability of the electrode member to adequately provide a toner cloud, which is essential for developing a latent image. The present inventors have developed a way to reduce the unacceptable accumulation of toner on the electrode member while maintaining the desired electrical and mechanical properties of the electrode member. The electrode member of the present invention is coated with a material coating that reduces the significant attraction of toner particles to the electrode member which may result in toner accumulation. However, the material coating does not adversely interfere with the mechanical or electrical properties of the electrode member. Materials having these qualities include materials with a low surface energy.
The low surface energy material decreases the accumulation of toner by assuring electrical continuity for charging the wires and eliminates the possibility of charge build-up. In addition, such low surface energy materials as described herein do not interfere with the electrical properties of the electrode member and do not adversely affect the electrode's ability to produce a toner powder cloud. Moreover, the electrode member maintains its tough mechanical properties, allowing the electrode member to remain durable against the severe wear the electrode member receives when it is repeatedly brought into contact with tough, rotating donor roll surfaces. Also, the electrode member maintains a "smooth" surface after the coating is applied. A smooth surface includes surfaces having a surface roughness of less than about 5 microns, preferably from about 0.01 to about 1 micron.
Examples of suitable low surface energy electrode coating materials include both organic materials and inorganic materials. Examples of suitable organic materials include fluoropolymers, including TEFLON.RTM. and TEFLON.RTM.-like materials and fluoroelastomers; silicone materials such silicone rubbers, siloxanes, polydimethylsiloxanes and fluorosilicones; polyamides; polyimides; aliphatic or aromatic hydrocarbons; copolymers or terpolymers of the above, and the like. The coating is present in an amount of about 65 to about 95 percent, and preferably 80 to about 85 percent by weight of total solids.
Particularly useful fluoropolymer coatings for the present invention include TEFLON.RTM.-like materials such as polytetrafluoroethylene (PTFE), fluorinated ethylenepropylene copolymer (FEP), perfluorovinylalkylethertetrafluoroethylene copolymer (PFA TEFLON.RTM.), polyethersulfone, copolymers thereof, and the like.
Examples of fluoropolymer coatings also include fluoroelastomers particularly from the class of copolymers and terpolymers of vinylidenefluoride, hexafluoropropylene and tetrafluoroethylene, are known commercially under various designations as VITON.RTM. A, VITON.RTM. E, VITON.RTM. E60C, VITON.RTM. E430, VITON.RTM. 910, VITON.RTM. GH and VITON.RTM. GF. The VITON.RTM. designation is a Trademark of E.l. DuPont de Nemours, Inc. Other commercially available materials include FLUOREL.RTM. 2170, FLUOREL.RTM. 2174, FLUOREL.RTM. 2176, FLUOREL.RTM. 2177 and FLUOREL.RTM. LVS 76. FLUOREL.RTM. is a Trademark of 3M Company. Additional commercially available materials include AFLAS.TM. a poly(propylenetetrafluoroethylene) and FLUOREL II.RTM. (LII900) a poly(propylenetetrafluoroethylenevinylidenefluoride) both also available from 3M Company, as well as the Tecnoflons identified as FOR-60KIR.RTM., FOR-LHF.RTM., NM.RTM. FOR-THF.RTM., FOR-TFS.RTM., TH.RTM., TN505.RTM. available from Montedison Specialty Chemical Company. In another preferred embodiment, the fluoroelastomer is one having a relatively low quantity of vinylidenefluoride, such as in VITON.RTM. GF, available from E.l. DuPont de Nemours, Inc. The VITON.RTM. GF has 35 weight percent of vinylidenefluoride, 34 weight percent of hexafluoropropylene and 29 weight percent of tetrafluoroethylene with 2 percent cure site monomer. The cure site monomer can be 4-bromoperfluorobutene-1, 1,1-dihydro-4-bromoperfluorobutene-1, 3-bromoperfluoropropene-1, 1,1-dihydro-3-bromoperfluoropropene-1, available from DuPont, or any other suitable, known cure site monomer.
Examples of other organic low surface energy materials suitable for use as the electrode coating material herein include silicone materials such as silicone rubbers including Dow Corning Sylgard 182 and Dow Corning coatings such as Silastic 590 and 591. Other preferred silicone materials include fluorosilicones such as nonylfluorohexyl and fluorosiloxanes such as DC94003 and Q5-8601, both available from Dow Corning. Silicone conformable coatings such as X3-6765 available from Dow Corning and silicone hard coats such as Dow Corning encapsulent X5-8022, Dow Corning 997 varnish, and Rain X available from Unelko Corp. in Scotsdale, Ariz. are also preferred.
Further examples of silicone materials include Dow Corning Sylgard 182, Dow Corning 806A Resin, Dow Corning 997 varnish silicone Resin and Dow Corning SYL-OFF Q2 series.
Other suitable organic coating materials include the polyamides and polyimides such as nylon 6, nylon 66, nylon 11, nylon 12, nylon 610, nylon 612, PEI (polyetherimide), and polyphthalamide sold under the tradename Amodel.RTM. available from Amoco.
Other preferred organic materials include polyamic acid.
Also preferred are mixtures and copolymers of polyimides and polyamides, such as PAI (polyamide imide) sold under the tradename Torlon.RTM. 7130 or AI10, both available from Amoco.
Other suitable coating materials include aliphatic or aromatic hydrocarbons, preferred being hydrocarbons having from about 1 to about 25 carbons. Particularly preferred hydrocarbons include polyvinylchloride and polyethylene.
In a preferred embodiment of the invention, a primer is used in addition to the organic coating. The thickness of the primer is from about 0.5 to about 25 microns, preferably from about 2 to about 20 microns, and particularly preferred from about 5 to about 10 microns. This is preferred in the case where high temperature cure schedules are used. A preferred primer is DOW CORNING 1200 which is an orthosilicate orthotitanate primer.
A filler such as an electrically conductive filler, may be added to the material coating in the amount of from about 5 to about 35 percent by weight of total solids, preferably from about 15 to about 20 percent by weight of total solids. Total solids herein include the amount of filler and organic solid material, catalyst, and any additives. Examples of electrically conductive fillers include carbon black; metal oxides such as tin oxide, titanium oxide, zirconium oxide, and other oxides that may be doped; and metal hydroxides such as calcium hydroxide, magnesium hydroxide and the like.
In a particularly preferred embodiment of the invention, the coating material is polytetrafluoroethylene having electrically conductive particles of carbon black dispersed therein. Specific examples include those commercially available polytetrafluoroethylene filled compounds are commercially available from DuPont, for example Teflon MP 1100 filler.
The low surface energy organic coating material is preferably present in an amount of from about 65 to about 95 percent by weight of total solids, and preferably from about 80 to about 85 percent by weight of total solids. Total solids as used herein, refers to the total amount by weight of organic coating material, fillers, additives, solvents and other like ingredients contained in the coating solution.
The volume resistivity of the coated electrode is for example from about 10.sup.-10 to about 1.sup.-1 ohm-cm, and preferably from 10.sup.-5 to 10.sup.-1 ohm-cm. The surface roughness is less than about 5 microns and preferably from about 0.01 to about 1 micron. The low surface energy is from about 5 to about 35 dynes/cm and preferably from about 10 to about 25 dynes/cm.
In a preferred embodiment of the invention, the material coating is coated over at least a portion of the nonattached regions of the electrode member. The nonattached region of the electrode member is the entire outer surface region of the electrode minus the region where the electrode is attached to the mounting means 54 and minus the anchoring area (55 in FIG. 4). It is preferred that the coating cover the portion of the electrode member which is adjacent to the donor roll. In another preferred embodiment of the invention, the material coating is coated in an entire area of the electrode member located in a central portion of the electrode member and extending to an area adjacent to the nonattached portion of the electrode member. This area includes the entire surface of the electrode member minus the anchoring area (55 in FIG. 4). In an alternative embodiment, the entire length of the electrode member is coated with the material coating, including the anchoring area 55 and mounting area 56. In embodiments, at lease a portion refers to the non-attached region being coated, or from about 10 to about 90 percent of the electrode member.
Toner can accumulate anywhere along the electrode member, but it will not affect development unless it accumulates in the length of the electrode member near to the donor roll or on the length closest to the photoreceptor. Therefore, it is preferred that the material coating cover the electrode member along the entire length corresponding to the donor roll, and on the entire length corresponding to the photoreceptor.
The material coating may be deposited on at least a portion of the electrode member by any suitable, known method. These deposition methods include liquid and powder coating, dip and spray coating. In a preferred deposition method, the material coating is coated on the electrode member by dip coating. The curing time can be controlled by the concentration of catalyst, temperature, or both.
The average thickness of the coating is from about 1 to about 10 .mu.m thick, and preferably from about 2 to about 4 .mu.m thick. If the coating is applied to only a portion of the electrode member, the thickness of the coating may or may not taper off at points farthest from the midpoint of the electrode member. Therefore, the thickness of the coating may decrease at points farther away from the midpoint of the electrode.
The electrode members of the present invention, the embodiments of which have been described herein exhibit superior performance in terms of low surface energy and decreased accumulation of toner on the surface of the electrode member, while also maintaining electrical properties which stimulate production of powder cloud development without charge build-up. In addition, the electrode members herein exhibit superior mechanical properties such as durability against donor roll surfaces which are normally made of tough materials such as ceramics.
All the patents and applications referred to herein are hereby specifically, and totally incorporated herein by reference in their entirety in the instant specification.
The following Examples further define and describe embodiments of the present invention. Unless otherwise indicated, all parts and percentages are by weight.
EXAMPLES
Example 1
Dip coating of a wire
A dip coating apparatus consisting of a 1 inch (diameter) by 15 inches (length) glass cylinder sealed at one end to hold the liquid coating material was used for dip coating a wire. A cable attached to a Bodine Electric Company type NSH-12R motor was used to raise and lower a wire support holder that keeps the wire taut during the coating process. The dip and withdraw rate of the wire holder into and out of the coating solution was regulated by a motor control device from B&B Motors & Control Corporation, (NOVA PD DC motor speed control). After coating, a motor driven device was used to twirl the wire around its axis while it received external heating to allow for controlled solvent evaporation. When the coating was dry and/or non-flowable, the coated wire was heated in a flow through oven using a time and temperature schedule to complete either drying or cure/post cure of the coating.
The general procedure may include: (A) cleaning and degreasing the wire with an appropriate solvent, for example, acetone, alcohol or water, and roughened if necessary by, for example, sand paper; (B) optionally applying a primer, for example Dow Corning 1200; (C) the coating material may be adjusted to the proper viscosity and solids content by adding solids or solvent to the solution; (D) the wire is dipped into and withdrawn from the coating solution, dried and cured/post cured, if necessary, and dipped again, if required. The coating thickness and uniformity are a function of withdrawal rate and solution viscosity, (solids content in most solvent based systems) and a drying schedule consistent with the uniform solidification of the coating.
Coated and untested wires were evaluated microscopically for morphology, defects, coating thickness and a qualitative softness/hardness estimate. Wires that passed these evaluations were vibrated on a rack and then examined microscopically for coating integrity. Racks or modules containing wires that showed no coating defects were then fitted on a fixture where the wire was pressed against a rotating ceramic roll for a standard time, after which the wire was then examined for coating wear and cleanliness.
Example 2
Preparation of coating solutions
Solution 1
Dow Corning 806A Resin in a solution (17 weight percent Toluene and 32 weight percent Xylene) was further diluted with 3 parts Toluene to 7 parts 806A. The coating was dip coated onto a wire using the procedures outlined in Example 1. The dip rate was 3 inches per minute with a 10 minute air dry time, and a cure time of 20 minutes at 400.degree. F. A smooth, tough coating approximately 2 micron thick was produced. The results are shown in Table I below.
Solution 2
Dow Corning Fluorosilicone 94003 was diluted with methylethyl ketone (25 parts MEK/75 parts 94003), and dip coated onto a wire using the procedures outlined in Example 1, at three inches per minute. The coating was then air dried for 30 minutes, heated for 15 minutes at 120.degree. F., and then ambient post cured for 16 hours before testing. The coating was found to be tough, even and approximately 5 microns in thickness.
Solution 3
Dow Corning 1200 primer was used along with 10 parts of DuPont MP1100 uniformly dispersed in 90 parts of Dow Corning 182 (PART A). Next, 100 parts of this concentrate (Part A) was diluted with 100 parts Toluene. An amount of 40 parts of Dow Corning Q2-7560 was slowly added with stirring to form a single phase solution of Sylgard 182, Teflon and the Q2-7560. The dip coating procedure outlined in Example 1 was used for these formulas and the withdraw rate of the wire from the cylinder was 3 inches a minute. The wire was twirled for approximately ten minutes at 100.degree. F., oven cured for 10 minutes at 250.degree. F., and post cured for 1 hour at 400.degree. F. The cured material in this example was found to be a smooth, even, tough coating, approximately 8 microns in thickness.
Solution 4
Amoco Al 10 polyamide/imide was used along with 21 percent solids in NMP/Ethylacetate. The dip coating procedure outlined in Example 1 was used for these formulas and the withdraw rate of the wire from the cylinder was 4 inches a minute. The wire was twirled for approximately 10 minutes at 100.degree. F., heated for 1 hour at 285.degree. F., 15 minutes at 500.degree. F., and 5 minutes at 600.degree. F. The cured material in this example was found to be a smooth and approximately 2-5 microns in thickness.
Solution 5
LaRC-SI Polyamic acid Roll Coat can be used along with 10-30% solids in NMP/Ethylacetate. The dip coating procedure outlined in Example 1 can be used for these formulas and the withdraw rate of the wire from the cylinder would be about 1-3 inches a minute. The wire can be twirled for approximately 10 minutes at 100.degree. F., heated for 1 hour at 285.degree. F., 15 minutes at 500.degree. F., and 5 minutes at 600.degree. F. The cured material in this example is estimated to be smooth and approximately 2-20 microns in thickness.
TABLE 1______________________________________ Dip CoatingMaterial ID % Solids Coating ThicknessWire/Roll Withdraw Rate Morphology Microns______________________________________Dow Corning (17% by weight Toluene and smooth and 2806A Resin 32 weight percent Xylene) toughDow Corning (25 parts MEK/75 parts tough and 5Fluorosilicone 94003) even94003Dow Corning (10 parts of DuPont MP1100/ smooth, 81200 primer 90 parts of Dow Corning 182) even, and (100 parts Toluene added) tough (40 parts Dow Corning Q2- 7560 added)Amoco Al 10 (21% solids in NMP/ smooth 2-5polyamide/ Ethylacetate)imideRolls & WiresLaRC-SI (10-30% solids in NMP/ smooth 2-20Polyamic acid Ethylacetate)Roll Coat______________________________________
While the invention has been described in detail with reference to specific and preferred embodiments, it will be appreciated that various modifications and variations will be apparent to the artisan. All such modifications and embodiments as may readily occur to one skilled in the art are intended to be within the scope of the appended claims.

Number	Name	Date
4868600	Hays et al.	Sep 1989
4984019	Folkins	Jan 1991
5010368	O'Brien	Apr 1991
5124749	Bares	Jun 1992
5172170	Hays et al.	Dec 1992
5270782	Floyd, Jr.	Dec 1993
5300339	Hays et al.	Apr 1994
5311258	Brewington et al.	May 1994
5448342	Hays et al.	Sep 1995

Organic coated development electrodes and methods thereof

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