Organic EL device

Abstract

In an organic EL device comprising organic layers between a pair of electrodes participating in at least a light emitting function, at least one organic layer contains an organic compound selected from naphthacene, tetraaryldiamine, anthracene and quinoxaline derivatives as a host material and an organic compound having a specific skeleton, typically diindeno[1,2,3-cd:1′,2′,3′-lm]perylene derivative as a dopant. The device is capable of light emission to a satisfactory luminance, especially in a long wavelength region, and with a chromatic purity sufficient for use in full color displays, and had a sufficient durability to sustain such improved light emission performance over a long time.

Description

BACKGROUND OF THE INVENTION

[0001] 1. Field of the Invention

[0002] This invention relates to an organic electroluminescent (EL) device, and more particularly, to a compound for use in a device of the type wherein an electric field is applied across a thin film of an organic compound to emit light.

[0003] 2. Background Art

[0004] Organic electroluminescent (EL) devices include a thin film containing a luminescent organic compound interleaved between an electron injecting electrode and a hole injecting electrode. Electrons and holes are injected into the thin film where they are recombined to create excitons. Light is emitted by utilizing luminescence (phosphorescence or fluorescence) upon deactivation of excitons.

[0005] The organic EL devices are characterized by plane light emission at a high luminance of about 100 to 10,000 cd/m2 with a voltage of about 10 volts and light emission in a spectrum from blue to red color by a simple choice of the type of fluorescent material.

[0006] Doping is one technique for producing light emission of any desired color from organic EL devices. It was reported in Jpn. J. Appl. Phys., 10, 527 (1971) to change emission color from blue to green by doping anthracene crystals with a minor level of tetracene. With respect to organic thin film EL devices having a multilayer structure, it was reported in JP-A 63-264692 to incorporate in a host material having a light emitting function a minor amount of a fluorescent dye capable of emitting light different from that of the host material in response to light emission from the host material as a dopant to form a light emitting layer, thereby changing the color of light emission from green to orange or red.

[0007] With respect to long wavelength light emission of yellow to red, known light emitting materials or dopant materials include laser dyes capable of red oscillation (EPO 281381), compounds capable of exciplex emission (JP-A 2-255788), perylene compounds (JP-A 3-791), coumarin compounds (JP-A 3-792), dicyanomethylene compounds (JP-A 3-162481), thioxanthene compounds (JP-A 3-177486), mixtures of a conjugated polymer and an electron transporting compound (JP-A 6-73374), squalirium compounds (JP-A 6-93257), oxadiazole compounds (JP-A 6-136359), oxynate derivatives (JP-A 6-145146), and pyrene compounds (JP-A 6-240246).

[0008] It is reported in J. Am. Chem. Soc., 118, 2374-2379, 1996, that benzofluoranthene derivatives have a very high fluorescent quantum yield. JP-A 10-330295 and JP-A 11-233261 disclose organic EL devices having a light emitting layer in which a variety of host materials are doped with dibenzo[f,f′]diindeno[1,2,3-cd:1′,2′,3′-lm]perylene derivatives derived from benzofluoranthene.

[0009] Other light emitting materials disclosed heretofore include condensed polycyclic aromatic compounds (JP-A 5-32966 and 5-214334). Also dopant materials proposed heretofore include various condensed polycyclic aromatic compounds (JP-A 5-258859).

[0010] However, when these materials are used as the dopant, EL devices often fail to allow dopant molecules to exert their own fluorescence due to the interaction between dopants or between the dopant and the host.

[0011] Therefore, with respect to organic EL devices of the type in which a host material is doped with a fluorescent dye, a choice of host material is an important and difficult task in order for the device to produce high efficiency light emission. Currently available organic EL devices fail to reach a practically acceptable level of emission efficiency although fluorescent dyes having a high fluorescent quantum yield are used as the dopant.

[0012] When organic EL devices are fabricated using the doping technique, the energy transfer from host molecules in the excited state to the dopant is not 100%, and often not only the dopant, but also the host material emit light. Especially in the case of red light emitting devices, the chromatic purity is often exacerbated by faint light emission of the host material since the host material emits light in a wavelength region of higher visibility than the dopant. Further improvements in properties pertaining to the luminous lifetime and durability are needed, with the target placed on practical application.

SUMMARY OF THE INVENTION

[0013] An object of the invention is to provide an organic EL device capable of light emission to a satisfactory luminance, especially in a long wavelength region, and with a chromatic purity sufficient for use in full color displays, and having a sufficient durability to sustain such improved light emission performance over a long time.

[0014] The above and other objects are achieved by the invention which is defined below.

[0015] [1] An organic EL device comprising one or more organic layers between a pair of electrodes participating in at least a light emitting function,

[0016] at least one of the organic layers containing at least one of organic compounds having basic skeletons of the following formulas (I) to (IV) and at least one organic compound having a skeleton of the following formula (V) at the same time: 1

[0017]  wherein Q1 to Q8 are independently hydrogen or substituted or unsubstituted alkyl, aryl, amino, heterocyclic or alkenyl radicals, 2

[0018]  wherein R1, R2, R3 and R4 are independently aryl, fluorene, carbazolyl, alkyl, alkoxy, aryloxy, amino or halogen radicals, at least one of R1, R2, R3 and R4 is aryl, r1, r2, r3 and r4 each are 0 or an integer of 1 to 5, with the proviso that r1, r2, r3 and r4 are not 0 at the same time, R5 and R6 are independently alkyl, alkoxy, amino, aryl or halogen radicals and may be the same or different, r5 and r6 each are 0 or an integer of 1 to 4, 3

[0019]  wherein A101 is a monophenylanthryl or diphenylanthryl radical and may be the same or different, L is hydrogen, a single bond or an n-valent linkage, and n is an integer of 1 to 4,

Qn-L101  (IV)

[0020]  wherein Q is a pyrazinyl radical having fused thereto a six-membered aromatic ring containing 0 to 2 nitrogen atoms and may be the same or different, n is 2 or 3, and L101 is a single bond or n-valent radical, 4

[0021]  wherein X1 to X10, L1 and L2 are independently hydrogen, halogen atoms, straight, branched or cyclic alkyl radicals which may have substituents, straight, branched or cyclic alkoxy radicals which may have substituents, straight, branched or cyclic alkylthio radicals which may have substituents, straight, branched or cyclic alkenyl radicals which may have substituents, straight, branched or cyclic alkenyloxy radicals which may have substituents, straight, branched or cyclic alkenylthio radicals which may have substituents, substituted or unsubstituted aralkyl radicals, substituted or unsubstituted aralkyloxy radicals, substituted or unsubstituted aralkylthio radicals, substituted or unsubstituted aryl radicals, substituted or unsubstituted aryloxy radicals, substituted or unsubstituted arylthio radicals, substituted or unsubstituted amino radicals, cyano, hydroxyl, —COOR1 radicals (wherein R1 is hydrogen, a substituted or unsubstituted straight, branched or cyclic alkyl radical, a substituted or unsubstituted straight, branched or cyclic alkenyl radical, a substituted or unsubstituted aralkyl radical or a substituted or unsubstituted aryl radical), —COR2 radicals (wherein R2 is hydrogen, a substituted or unsubstituted straight, branched or cyclic alkyl radical, a substituted or unsubstituted straight, branched or cyclic alkenyl radical, a substituted or unsubstituted aralkyl radical, a substituted or unsubstituted aryl radical or an amino radical), or —OCOR3 radicals (wherein R3 is a substituted or unsubstituted straight, branched or cyclic alkyl radical, a substituted or unsubstituted straight, branched or cyclic alkenyl radical, a substituted or unsubstituted aralkyl radical, or a substituted or unsubstituted aryl radical), or at least two adjoining radicals selected from X1 to X10, L1 and L2 may bond or fuse together to form a substituted or unsubstituted carbocyclic aliphatic ring, aromatic ring or fused aromatic ring with the carbon atoms to which they are attached, or L1 and L2 each may be a single bond. n is 1 or 2.

[0022] [2] The organic EL device of [1] wherein the at least one of the organic layers contains a host material and a dopant,

[0023] said host material comprises at least one compound selected from the organic compounds having basic skeletons of the formulas (I) to (IV) and

[0024] said dopant comprises at least one compound selected from the organic compounds having a skeleton of the formula (V).

[0025] [3] The organic EL device of [1] or [2] wherein in formula (V), at least two adjoining radicals selected from X1 to X10, L1 and L2 bond or fuse together to form a substituted or unsubstituted carbocyclic aliphatic ring, aromatic ring or fused aromatic ring with the carbon atoms to which they are attached.

[0026] [4] The organic EL device of any one of [1] to [3] wherein the compound of formula (V) is a compound of the following formula (VI): 5

[0027] wherein X1 to X6, X9, X10, X11 to X16, X19 and X20 are independently hydrogen, halogen atoms, straight, branched or cyclic alkyl radicals which may have substituents, straight, branched or cyclic alkoxy radicals which may have substituents, straight, branched or cyclic alkylthio radicals which may have substituents, straight, branched or cyclic alkenyl radicals which may have substituents, straight, branched or cyclic alkenyloxy radicals which may have substituents, straight, branched or cyclic alkenylthio radicals which may have substituents, substituted or unsubstituted aralkyl radicals, substituted or unsubstituted aralkyloxy radicals, substituted or unsubstituted aralkylthio radicals, substituted or unsubstituted aryl radicals, substituted or unsubstituted aryloxy radicals, substituted or unsubstituted arylthio radicals, substituted or unsubstituted arylalkenyl radicals, substituted or unsubstituted alkenylaryl radicals, substituted or unsubstituted amino radicals, cyano, hydroxyl, —COOR1 radicals (wherein R1 is hydrogen, a substituted or unsubstituted straight, branched or cyclic alkyl radical, a substituted or unsubstituted straight, branched or cyclic alkenyl radical, a substituted or unsubstituted aralkyl radical or a substituted or unsubstituted aryl radical), —COR2 radicals (wherein R2 is hydrogen, a substituted or unsubstituted straight, branched or cyclic alkyl radical, a substituted or unsubstituted straight, branched or cyclic alkenyl radical, a substituted or unsubstituted aralkyl radical, a substituted or unsubstituted aryl radical or an amino radical), or —OCOR3 radicals (wherein R3 is a substituted or unsubstituted straight, branched or cyclic alkyl radical, a substituted or unsubstituted straight, branched or cyclic alkenyl radical, a substituted or unsubstituted aralkyl radical, or a substituted or unsubstituted aryl radical), or at least two adjoining radicals selected from X1 to X20 may bond together to form a substituted or unsubstituted carbocyclic aliphatic ring, aromatic ring or fused aromatic ring with the carbon atoms to which they are attached.

[0028] [5] The organic EL device of [4] wherein the compound of formula (VI) is a compound of the following formula (VI′): 6

[0029] wherein X1 to X44 are as defined for X1 to X20 in formula (VI).

[0030] [6] The organic EL device of [4] or [5] wherein X1 to X20 in formula (VI) and X1 to X44 in formula (VI′) are independently substituted or unsubstituted aryl, alkyl, alkenyl, alkoxy or aryloxy radicals.

[0031] [7] The organic EL device of any one of [4] to [6] wherein at least one of X1 to X20 in formula (VI) and X1 to X44 in formula (VI′) is an ortho-substituted phenyl radical. [8] The organic EL device of any one of [4] to [7] wherein in formula (VI) or (VI′), either one or both of X1 and X4 and/or either one or both of X11 and X14 are ortho-substituted phenyl radicals.

[0032] [9] The organic EL device of any one of [1] to [8] wherein said at least one of the organic layers contains at least one organic compound having a basic skeleton of the formula (I).

[0033] [10] The organic EL device of any one of [1] to [9] wherein said at least one of the organic layers contains at least one organic compound having a basic skeleton of the formula (I) and at least one organic compound having a basic skeleton of the formula (II) at the same time.

[0034] [11] The organic EL device of any one of [4] to [10] wherein at least one of the organic compounds has a vibration structure in both an excitation spectrum and a fluorescence spectrum.

[0035] [12] The organic EL device of any one of [4] to [11] wherein at least one of the organic compounds has a Stokes shift of up to 0.1 eV.

[0036] [13] The organic EL device of any one of [4] to [12] wherein the host material in a light emitting layer has a greater electron affinity than an electron transporting layer and/or a hole transporting layer.

[0037] [14] The organic EL device of any one of [1] to [13] wherein the organic compound having a basic skeleton of the formula (I) is one wherein at least two of Q1 to Q8 are substituted or unsubstituted aryl radicals.

[0038] [15] The organic EL device of [14] wherein the organic compound having a basic skeleton of the formula (I) is one wherein at least six of Q1 to Q8 are substituted or unsubstituted aryl radicals.

[0039] [16] The organic EL device of [14] or [15] wherein the organic compound having a basic skeleton of the formula (I) is one wherein at least two of Q1, Q2, Q3 and Q4 are substituted or unsubstituted aryl radicals.

[0040] [17] The organic EL device of any one of [14] to [16] wherein the organic compound having a basic skeleton of the formula (I) is one wherein at least four of Q1, Q2, Q3 and Q4 are substituted or unsubstituted aryl radicals.

[0041] [18] The organic EL device of any one of [14] to [17] wherein at least two of the aryl radicals represented by Q1, Q2, Q3 and Q4 have aryl radicals substituted thereon.

[0042] [19] The organic EL device of any one of [2] to [18] wherein the at least one of the organic layers contains 80 to 99.9% by weight of the host material.

[0043] [20] An organic EL device wherein at least one of organic layers contains at least one organic compound having a basic skeleton of the formula (I) as set forth in [16] and at least one organic compound having a basic skeleton of the formula (IV′).

[0044] [21] The organic EL device of any one of [1] to [20], further comprising at least one hole injecting and transporting layer.

[0045] [22] The organic EL device of any one of [1] to [21], further comprising at least one electron injecting and transporting layer.

[0046] [23] An organic EL device comprising one or more organic layers between a pair of electrodes participating in at least a light emitting function, wherein the one or more organic layers contain organic compounds, at least one of which has a vibration structure in both an excitation spectrum and a fluorescence spectrum.

[0047] [24] An organic EL device comprising one or more organic layers between a pair of electrodes participating in at least a light emitting function, wherein the one or more organic layers contain organic compounds, at least one of which has a Stokes shift of up to 0.1 eV.

[0048] [25] The organic EL device of [24] wherein a host material in a light emitting layer has a greater electron affinity than an electron transporting layer and/or a hole transporting layer.

BRIEF DESCRIPTION OF THE DRAWINGS

[0049] FIG. 1 is a schematic cross-sectional view showing the basic construction of an organic EL device according to the invention.

[0050] FIG. 2 is a diagram showing the excitation and fluorescence spectra of the host material and dopant used in Example.

[0051] FIG. 3 is a diagram showing the excitation and fluorescence spectra of the host material and dopant used in Comparative Example.

DESCRIPTION OF THE PREFERRED EMBODIMENT

[0052] According to the invention, an organic EL device having a high luminous efficiency and a long lifetime is obtained by combining an organic compound of formula (V) or (VI) with at least one of organic compounds of formulas (I) to (IV), especially by combining an organic compound of formula (V) or (VI) as a dopant with an organic compound of formula (I) as a host material. First the organic compounds useful as the host material are described in detail.

[0053] Host Materials

[0054] Naphthacene Compounds

[0055] One class of organic compounds useful as the host material according to the invention have a basic skeleton of the following formula (I).

[0056] In the device of the invention, the use of the naphthacene derivative, preferably as the host material, helps induce strong light emission from the dopant.

[0057] Naphthacene derivatives belong to a class of preferable organic compounds, especially effective as the host material, among others. For example, the fluorescence intensity of a film of a naphthacene derivative of host material in example 1 doped with 1 wt % of a dibenzo[f,f′]diindeno[1,2,3-cd:1′,2′,3′-lm]perylene derivative of dopant material in Example 1, as measured on photoexcitation, is about 2 times the fluorescence intensities of films of other organic compounds (e.g., Alq3) as the host.

[0058] The reason why such intense fluorescence is produced is presumably that the combination of a naphthacene derivative with the above dopant is an ideal combination that avoids interaction such as formation of an exciplex, and bipolar interaction between the respective molecules maintains a high intensity of fluorescence.

[0059] In the event of a red dopant, since the energy gap of a naphthacene derivative is relatively approximate to that of the dopant, an energy transfer phenomenon due to emission resorption takes place as well as energy transfer by electron exchange. This accounts for a high fluorescence intensity as well.

[0060] The combination with the above host material minimizes the concentration quenching of the dopant, which also accounts for a high fluorescence intensity.

[0061] In an exemplary organic EL device which was fabricated using the above doped film as a light emitting layer, a luminance of at least 600 cd/m2 at maximum was obtained at a current density of 10 mA/cm2 and a drive voltage as low as about 6 V. When operated at a current density of about 600 mA/cm2, the device consistently produced a luminance of greater than about 20,000 cd/m2. As compared with other organic compounds (e.g., Alq3) serving as the host, this provides a luminous efficiency greater by a factor of about 4 when assessed in terms of current efficiency, and because of possible driving at a lower voltage, a luminous efficiency greater by a factor of about 5 when assessed in terms of power efficiency. In the event of doping with a red dopant as in the above example, entailing the high efficiency of energy transfer from the host to the dopant, the device is characterized by a high chromatic purity in that only the dopant produces light emission, with little light emission from the host being observable.

[0062] It is believed that such a very high luminous efficiency exerted when organic EL devices are fabricated is due to the effects of an improved recombination probability of carriers in the light emitting layer and a singlet excitation state that the dopant forms as a result of energy transfer from the triplet excitation state of naphthacene, as well as the above-mentioned mechanism of providing a high fluorescence intensity.

[0063] As opposed to conventional organic EL devices whose drive voltage is increased by carrier trapping of the dopant, the inventive organic EL device using the above-mentioned light emitting layer has a very low drive voltage, because the order of carrier trapping of the dopant is low and high efficiency light emission is accomplished by the above-mentioned mechanism. Another accomplished by the above-mentioned mechanism. Another probable reason is the ease of injection of carriers into the light emitting layer.

[0064] Since the naphthacene derivative is very stable and highly durable against carrier injection, the device fabricated using the above host-dopant combination has a very long lifetime. For example, an organic EL device having a light emitting layer of a compound of formula (VII′) doped with 1 wt % of a dibenzo[f,f′]diindeno[1,2,3-cd:1′,2′,3′-lm]perylene derivative of dopant material in Example 1 is highly durable as demonstrated by its ability to sustain a luminance of at least 2,400 cd/m2 over a period of 1,000 hours or longer, with an attenuation of less than about 1%, when driven at 50 mA/cm2.

[0065] In organic EL devices as mentioned above, the dopant concentration ensuring a chromatic purity and maximum efficiency is about 1% by weight although dopant concentrations of about 2 or 3% by weight lead to devices which are practically acceptable albeit a drop of less than about 10%. 7

[0066] In formula (I), Q1 to Q4 are independently selected from among hydrogen and substituted or unsubstituted alkyl, aryl, amino, heterocyclic and alkenyl radicals. Preferred are aryl, amino, heterocyclic and alkenyl radicals. It is also desirable that Q2 and Q3 are these preferred radicals and Q1 and Q4 are hydrogen.

[0067] The aryl radicals represented by Q1 to Q4 may be monocyclic or polycyclic, inclusive of fused rings and a collection of rings. Those aryl radicals having 6 to 30 carbon atoms in total are preferred and they may have substituents. Preferred examples of the aryl radical include phenyl, o-, m- and p-tolyl, pyrenyl, perylenyl, coronenyl, 1- and 2-naphthyl, anthryl, o-, m- and p-biphenylyl, terphenyl and phenanthryl.

[0068] The amino radicals represented by Q1 to Q4 may be selected from among alkylamino, arylamino, aralkylamino and analogous radicals. They preferably have aliphatic radicals having 1 to 6 carbon atoms in total and/or aromatic carbocyclic radicals having 1 to 4 rings. Illustrative examples include dimethylamino, diethylamino, dibutylamino, diphenylamino, ditolylamino, bisdiphenylylamino, and bisnaphthylamino radicals.

[0069] The heterocyclic radicals represented by Q1 to Q4 include 5- or 6-membered ring aromatic heterocyclic radicals containing O, N or S as a hetero atom, and fused polycyclic aromatic heterocyclic radicals having 2 to 20 carbon atoms. Examples of the aromatic heterocyclic radicals and fused polycyclic aromatic heterocyclic radicals include thienyl, furyl, pyrolyl, pyridyl, quinolyl, and quinoxalyl radicals.

[0070] The alkenyl radicals represented by Q1 to Q4 are preferably those having a phenyl group as at least one substituent, such as 1- and 2-phenylalkenyl, 1,2- and 2,2-diphenylalkenyl, and 1,2,2-triphenylalkenyl although unsubstituted alkenyl radicals are acceptable.

[0071] When Q1 to Q4 are substituted radicals, at least two of the substituents are preferably aryl, amino, heterocyclic, alkenyl or aryloxy groups. These aryl, amino, heterocyclic and alkenyl groups are as illustrated above for Q1 to Q4. The aryloxy groups to substitute on Q1 to Q4 are preferably those of aryl groups having 6 to 18 carbon atoms in total, for example, o-, m- and p-phenoxy. At least two of these substituents may form a fused ring. Also, these substituents may be further substituted ones, in which preferred substituents are as described above.

[0072] When Q1 to Q4 have substituents, it is preferred that at least two of the substituents have the above-described substituents. The position of substitution is not particularly limited and may be a meta, para or ortho position. Q1 and Q4, and Q2 and Q3 in the respective pairs are preferably identical although they may be different.

[0073] Q5 to Q8 are independently selected from among hydrogen and substituted or unsubstituted alkyl, aryl, amino, heterocyclic and alkenyl radicals.

[0074] The alkyl radicals represented by Q5 to Q8 are preferably those of 1 to 6 carbon atoms, which may be straight or branched. Preferred examples of the alkyl radical include methyl, ethyl, n- and i-propyl, n-, i-, sec- and tert-butyl, n-, i-, neo- and tert-pentyl.

[0075] The aryl, amino and alkenyl radicals represented by Q5 to Q8 are as illustrated above for Q1 to Q4. Q5 and Q6, and Q7 and Q8 in the respective pairs are preferably identical although they may be different.

[0076] It is preferred that rubrene of formula (I) wherein all Q1 to Q4 are phenyl and all Q5 to Q8 are hydrogen be excluded.

[0077] The naphthacene derivative contained in the light emitting layer should preferably have a basic skeleton of the following formula (VII). 8

[0078] In formula (VII), Q11 to Q13, Q21 to Q23, Q31 to Q33 and Q41 to Q43 are hydrogen, aryl, amino, heterocyclic, aryloxy or alkenyl radicals. Preferably the Q's in at least one of these sets are radicals having substituents selected from among aryl, amino, heterocyclic and aryloxy groups. Two or more of these Q's may form a fused ring.

[0079] Preferred examples of the aryl, amino, heterocyclic and aryloxy radicals are as exemplified above for Q1 to Q4. Preferably Q11 to Q13 and Q41 to Q43, and Q21 to Q23 and Q31 to Q33 in the respective paired sets are identical although they may be different.

[0080] The amino groups substituting on Q11 to Q13, Q21 to Q23, Q31 to Q33 and Q41 to Q43 may be selected from among alkylamino, arylamino, aralkylamino and analogous groups. They preferably have aliphatic groups having 1 to 6 carbon atoms in total and/or aromatic carbocyclic groups having 1 to 4 rings. Illustrative examples include dimethylamino, diethylamino, dibutylamino, diphenylamino, ditolylamino, and bisbiphenylylamino groups.

[0081] Examples of the fused ring include indene, naphthalene, anthracene, phenanthrene, quinoline, isoquinoline, quinoxaline, phenazine, acridine, indole, carbazole, phenoxazine, phenothiazine, benzothiazole, benzothiophene, benzofuran, acridone, benzimidazole, coumarin, and flavone.

[0082] Of the naphthacene derivatives used herein, those of the following formula (VII′) are preferred because devices are given a longer lifetime. 9

[0083] In formula (VII′), Q51 to Q55 and Q21 to Q25 are the same as Q11 in formula (VII).

[0084] Illustrative examples of the preferred naphthacene derivatives used herein are given below as IB-1 to IB-189. The substituents Q1 to Q8 are denoted as Q10 to Q80.

TABLE 1
SUBSTITUENT
Compound
No.	Q10	Q20	Q30	Q40	Q50	Q60	Q70	Q80
IB-1	10	11	12	13	H	H	H	H
IB-2	14	15	16	17	H	H	H	H
IB-3	18	19	20	21	H	H	H	H
IB-4	22	23	24	25	H	H	H	H
IB-5	26	27	28	29	H	H	H	H
IB-6	30	31	32	33	H	H	H	H
IB-7	34	35	36	37	H	H	H	H
IB-8	38	39	40	41	H	H	H	H

[0085]

TABLE 2
SUBSTITUENT
Compound
No.	Q10	Q20	Q30	Q40	Q50	Q60	Q70	Q80
IB-9	42	43	44	45	H	H	H	H
IB-10	46	47	48	49	H	H	H	H
IB-11	50	51	52	53	H	H	H	H
IB-12	54	55	56	57	H	H	H	H
IB-13	58	59	60	61	H	H	H	H
IB-14	62	63	64	65	H	H	H	H
IB-15	66	67	68	69	H	H	H	H
IB-16	70	71	72	73	H	H	H	H

[0086]

TABLE 3
SUBSTITUENT
Compound
No.	Q10	Q20	Q30	Q40	Q50	Q60	Q70	Q80
IB-17	74	75	76	77	H	H	H	H
IB-18	78	79	80	81	H	H	H	H
IB-19	82	83	84	85	H	H	H	H
IB-20	86	87	88	89	H	H	H	H
IB-21	90	91	92	93	H	H	H	H
IB-22	94	95	96	97	H	H	H	H
IB-23	98	99	100	101	H	H	H	H
IB-24	102	103	104	105	H	H	H	H

[0087]

TABLE 4
SUBSTITUENT
Compound
No.	Q10	Q20	Q30	Q40	Q50	Q60	Q70	Q80
IB-25	106	107	108	109	H	H	H	H
IB-26	110	111	112	113	H	H	H	H
IB-27	114	115	116	117	H	H	H	H
IB-28	118	119	120	121	H	H	H	H
IB-29	122	123	124	125	H	H	H	H
IB-30	126	127	128	129	H	H	H	H
IB-31	130	131	132	133	H	H	H	H
IB-32	134	135	136	137	H	H	H	H

[0088]

TABLE 5
SUBSTITUENT
Com-
pound
No.	Q10	Q20	Q30	Q40	Q50	Q60	Q70	Q80
IB-33	138	139	140	141	H	H	H	H
IB-34	142	143	144	145	H	H	H	H
IB-35	146	147	148	149	H	H	H	H
IB-36	150	151	152	153	H	H	H	H
IB-37	154	155	156	157	H	H	H	H
IB-38	158	159	160	161	H	H	H	H
IB-39	162	163	164	165	H	H	H	H
IB-40	166	167	168	169	H	H	H	H

[0089]

TABLE 6
SUBSTITUENT
Com-
pound
No.	Q10	Q20	Q30	Q40	Q50	Q60	Q70	Q80
IB-41	170	171	172	173	H	H	H	H
IB-42	174	175	176	177	H	H	H	H
IB-43	178	179	180	181	H	H	H	H
IB-44	182	183	184	185	H	H	H	H
IB-45	186	187	188	189	H	H	H	H
IB-46	190	191	192	193	H	H	H	H
IB-47	194	195	196	197	H	H	H	H

[0090]

TABLE 7
SUBSTITUENT
Compound No.	Q10	Q20	Q30	Q40	Q50	Q60	Q70	Q80
IB-48	198	199	200	201	H	H	H	H
IB-49	202	203	204	205	H	H	H	H
IB-50	206	207	208	209	H	H	H	H
IB-51	210	211	212	213	H	H	H	H
IB-52	214	215	216	217	H	H	H	H
IB-53	218	219	220	221	H	H	H	H
IB-54	222	223	224	225	H	H	H	H
IB-55	226	227	228	229	H	H	H	H

[0091]

TABLE 8
SUBSTITUENT
Compound No.	Q10	Q20	Q30	Q40	Q50	Q60	Q70	Q80
IB-56	230	231	232	233	H	H	H	H
IB-57	234	235	236	237	H	H	H	H
IB-58	238	239	240	241	H	H	H	H
IB-59	242	243	244	245	H	H	H	H
IB-60	246	247	248	249	H	H	H	H
IB-61	250	251	252	253	H	H	H	H
IB-62	254	255	256	257	H	H	H	H

[0092]

TABLE 9
SUBSTITUENT
Compound No.	Q10	Q20	Q30	Q40	Q50	Q60	Q70	Q80
IB-63	258	259	260	261	H	H	H	H
IB-64	262	263	264	265	H	H	H	H
IB-65	266	267	268	269	H	H	H	H
IB-66	270	271	272	273	H	H	H	H
IB-67	274	275	276	277	H	H	H	H
IB-68	278	279	280	281	H	H	H	H
IB-69	282	283	284	285	H	H	H	H

[0093]

TABLE 10
SUBSTITUENT
Com-
pound
No.	Q10	Q20	Q30	Q40	Q50	Q60	Q70	Q80
IB-70	286	287	288	289	H	H	H	H
IB-71	290	291	292	293	H	H	H	H
IB-72	294	295	296	297	H	H	H	H
IB-73	298	299	300	301	H	H	H	H
IB-74	302	303	304	305	H	H	H	H
IB-75	306	307	308	309	H	H	H	H
IB-76	310	311	312	313	H	H	H	H
IB-77	314	315	316	317	H	H	H	H

[0094]

TABLE 11
SUBSTITUENT
Compound
No.	Q10	Q20	Q30	Q40	Q50	Q60	Q70	Q80
IB-78	318	319	320	321	H	H	H	H
IB-79	322	323	324	325	H	H	H	H
IB-80	326	327	328	329	H	H	H	H
IB-81	330	331	332	333	H	H	H	H
IB-82	334	335	336	337	H	H	H	H
IB-83	338	339	340	341	H	H	H	H
IB-84	342	343	344	345	H	H	H	H
IB-85	346	347	348	349	H	H	H	H

[0095]

TABLE 12
SUBSTITUENT
Compound
No.	Q10	Q20	Q30	Q40	Q50	Q60	Q70	Q80
IB-86	350	351	352	353	H	H	H	H
IB-87	354	355	356	357	H	H	H	H
IB-88	358	359	360	361	H	H	H	H
IB-89	362	363	364	365	H	H	H	H
IB-90	366	367	368	369	H	H	H	H
IB-91	370	371	372	373	H	H	H	H
IB-92	374	375	376	377	H	H	H	H
IB-93	378	379	380	381	H	H	H	H

[0096]

TABLE 13
SUBSTITUENT
Compound
No.	Q10	Q20	Q30	Q40	Q50	Q60	Q70	Q80
IB-94	382	383	384	385	H	H	H	H
IB-95	386	387	388	389	H	H	H	H
IB-96	390	391	392	393	H	H	H	H
IB-97	394	395	396	397	H	H	H	H
IB-98	398	399	400	401	H	H	H	H
IB-99	402	403	404	405	H	H	H	H
IB-100	406	407	408	409	H	H	H	H

[0097]

TABLE 14
SUBSTITUENT
Compound
No.	Q10	Q20	Q30	Q40	Q50	Q60	Q70	Q80
IB-101	410	411	412	413	H	H	H	H
IB-102	414	415	416	417	H	H	H	H
IB-103	418	419	420	421	H	H	H	H
IB-104	422	423	424	425	H	H	H	H
IB-105	426	427	428	429	H	H	H	H
IB-106	430	431	432	433	H	H	H	H
IB-107	434	435	436	437	H	H	H	H
IB-108	438	439	440	441	H	H	H	H

[0098]

TABLE 15
SUBSTITUENT
Compound
No.	Q10	Q20	Q30	Q40	Q50	Q60	Q70	Q80
IB-109	442	443	444	445	H	H	H	H
IB-110	446	447	448	449	H	H	H	H
IB-111	450	451	452	453	H	H	H	H
IB-112	454	455	456	457	H	H	H	H
IB-113	458	459	460	461	H	H	H	H
IB-114	462	463	464	465	H	H	H	H
IB-115	466	467	468	469	H	H	H	H
IB-116	470	471	472	473	H	H	H	H

[0099]

TABLE 16
SUBSTITUENT
Compound
No.	Q10	Q20	Q30	Q40	Q50	Q60	Q70	Q80
IB-117	474	475	476	477	H	H	H	H
IB-118	478	479	480	481	H	H	H	H
IB-119	482	483	484	485	H	H	H	H
IB-120	486	487	488	489	H	H	H	H
IB-121	490	491	492	493	H	H	H	H
IB-122	494	495	496	497	H	H	H	H
IB-123	498	499	500	501	H	H	H	H
IB-124	502	503	504	505	H	H	H	H

[0100]

TABLE 17
SUBSTITUENT
Compound
No.	Q10	Q20	Q30	Q40	Q50	Q60	Q70	Q80
IB-125	506	507	508	509	H	H	H	H
IB-126	510	511	512	513	H	H	H	H
IB-127	514	515	516	517	H	H	H	H
IB-128	518	519	520	521	H	H	H	H
IB-129	522	523	524	525	H	H	H	H
IB-130	526	527	528	529	H	H	H	H
IB-131	530	531	532	533	H	H	H	H
IB-132	534	535	536	537	H	H	H	H

[0101]

TABLE 18
SUBSTITUENT
Compound No.	Q10	Q20	Q30	Q40	Q50	Q60	Q70	Q80
IB-133	538	539	540	541	H	H	H	H
IB-134	542	543	544	545	H	H	H	H
IB-135	546	547	548	549	H	H	H	H
IB-136	550	551	552	553	H	H	H	H
IB-137	554	555	556	557	H	H	H	H
IB-138	558	559	560	561	H	H	H	H
IB-139	562	563	564	565	H	H	H	H
IB-140	566	567	568	569	H	H	H	H
IB-141	570	571	572	573	H	H	H	H

[0102]

TABLE 19
574
SUBSTITUENT
Compound No.	Q10	Q20	Q30	Q40	Q50	Q60	Q70	Q80
IB-142	575	576	577	578	579	580	H	H
IB-143	581	582	583	584	CH3	CH3	H	H
IB-144	585	586	587	588	589	590	591	592
IB-145	593	594	595	596	597	598	H	H
IB-146	599	600	601	602	603	604	H	H
IB-147	605	606	607	608	609	610	H	H
IB-148	611	612	613	614	CH3	CH3	CH3	CH3
IB-149	615	616	617	618	619	620	CH3	CH3
IB-150	621	622	623	624	625	626	627	628
IB-151	629	630	631	632	633	634	635	636
IB-152	637	638	639	640	641	642	643	644

[0103]

TABLE 20
645
SUBSTITUENT
Compound No.	Q10	Q20	Q30	Q40	Q50	Q60	Q70	Q80
IB-153	646	647	648	649	H	H	H	H
IB-154	650	651	652	653	654	655	H	H
IB-155	656	657	658	659	CH3	CH3	H	H
IB-156	660	661	662	663	664	665	666	667
IB-157	668	669	670	671	672	673	H	H
IB-158	674	675	676	677	678	679	H	H
IB-159	680	681	682	683	684	685	H	H
IB-160	686	687	688	689	CH3	CH3	CH3	CH3
IB-161	690	691	692	693	694	695	CH3	CH3

[0104]

TABLE 21
696
SUBSTITUENT
Com-
pound
No.	Q10	Q20	Q30	Q40	Q50	Q60	Q70	Q80
IB-162	697	698	699	700	CH3	CH3	H	H
IB-163	701	702	703	704	CH3	CH3	H	H
IB-164	CH3	705	706	CH3	H	H	H	H
IB-165	CH3	707	708	CH3	H	H	H	H
IB-166	CH3	709	710	CH3	H	H	H	H
IB-167	CH3	711	712	CH3	H	H	H	H
IB-168	H	713	714	H	CH3	CH3	H	H
IB 169	H	715	716	H	CH3	CH3	H	H
IB-170	H	717	718	H	CH3	CH3	H	H

[0105]

TABLE 22
719
SUBSTITUENT
Compound No.	Q10	Q20	Q30	Q40	Q50	Q60	Q70	Q80
IB-171	H	720	721	H	CH3	CH3	H	H
IB-172	H	722	723	H	CH3	CH3	CH3	CH3
IB-173	H	724	725	H	CH3	CH3	CH3	CH3
IB-174	H	726	727	H	CH3	CH3	CH3	CH3
IB-175	H	728	729	H	CH3	CH3	CH3	CH3

[0106]

TABLE 23
SUBSTITUENT
Com-
pound
No.	Q10	Q20	Q30	Q40	Q50	Q60	Q70	Q80
IB-176	730	731	732	733	CH3	CH3	H	H
IB-177	734	735	736	737	CH3	CH3	H	H
IB-178	CH3	738	739	CH3	H	H	H	H
IB-179	CH3	740	741	CH3	H	H	H	H
IB-180	CH3	742	743	CH3	H	H	H	H
IB-181	CH3	744	745	CH3	H	H	H	H

[0107]

TABLE 24
SUBSTITUENT
Compound No.	Q10	Q20	Q30	Q40	Q50	Q60	Q70	Q80
IB-182	H	746	747	H	CH3	CH3	H	H
IB-183	H	748	749	H	CH3	CH3	H	H
IB-184	H	750	751	H	CH3	CH3	H	H
IB-185	H	752	753	H	CH3	CH3	H	H
IB-186	H	754	755	H	CH3	CH3	CH3	CH3
IB-187	H	756	757	H	CH3	CH3	CH3	CH3
IB-188	H	758	759	H	CH3	CH3	CH3	CH3
IB-189	H	760	761	H	CH3	CH3	CH3	CH3

[0108] Other illustrative examples of the preferred naphthacene derivatives used herein are given below as IIB-1 to IIB-32 and IIIB-1 to IIIB-36. The substituents Q1 to Q8 are denoted as Q10 to Q80.

TABLE 25
SUBSTITUENT
Com-
pound
No.	Q10	Q20	Q30	Q40	Q50	Q60	Q70	Q80
IIB-1	762	763	764	765	H	H	H	H
IIB-2	766	767	768	769	H	H	H	H
IIB-3	770	771	772	773	H	H	H	H
IIB-4	774	775	776	777	H	H	H	H
IIB-5	778	779	780	781	H	H	H	H
IIB-6	782	783	784	785	H	H	H	H
IIB-7	786	787	788	789	H	H	H	H
IIB-8	790	791	792	793	H	H	H	H

[0109]

TABLE 26
SUBSTITUENT
Compound No.	Q10	Q20	Q30	Q40	Q50	Q60	Q70	Q80
IIB-9	794	795	796	797	H	H	H	H
IIB-10	798	799	800	801	H	H	H	H
IIB-11	802	803	804	805	H	H	H	H
IIB-12	806	807	808	809	H	H	H	H
IIB-13	810	811	812	813	H	H	H	H
IIB-14	814	815	816	817	H	H	H	H
IIB-15	818	819	820	821	H	H	H	H

[0110]

TABLE 27
SUBSTITUENT
Com-
pound
No.	Q10	Q20	Q30	Q40	Q50	Q60	Q70	Q80
IIB-16	822	823	824	825	H	H	H	H
IIB-17	826	827	828	829	H	H	H	H
IIB-18	830	831	832	833	H	H	H	H
IIB-19	834	835	836	837	H	H	H	H
IIB-20	838	839	840	841	H	H	H	H
IIB-21	842	843	844	845	H	H	H	H

[0111]

TABLE 28
SUBSTITUENT
Com-
pound
No.	Q10	Q20	Q30	Q40	Q50	Q60	Q70	Q80
IIB-22	846	847	848	849	H	H	H	H
IIB-23	850	851	852	853	H	H	H	H
IIB-24	854	855	856	857	H	H	H	H
IIB-25	858	859	860	861	H	H	H	H
IIB-26	862	863	864	865	H	H	H	H

[0112]

TABLE 29
SUBSTITUENT
Compound No.	Q10	Q20	Q30	Q40	Q50	Q60	Q70	Q80
IIB-27	866	867	868	869	H	H	H	H
IIB-28	870	871	872	873	H	H	H	H
IIB-29	874	875	876	877	H	H	H	H
IIB-30	878	879	880	881	H	H	H	H
IIB-31	882	883	884	885	H	H	H	H
IIB-32	886	887	888	889	H	H	H	H

[0113]

TABLE 30
SUBSTITUENT
Com-
pound
No.	Q10	Q20	Q30	Q40	Q50	Q60	Q70	Q80
IIIB-1	890	891	892	893	H	H	H	H
IIIB-2	894	895	896	897	H	H	H	H
IIIB-3	898	899	900	901	H	H	H	H
IIIB-4	902	903	904	905	H	H	H	H
IIIB-5	906	907	908	909	H	H	H	H
IIIB-6	910	911	912	913	H	H	H	H

[0114]

TABLE 31
SUBSTITUENT
Compound No.	Q10	Q20	Q30
IIIB-7	914	915	916
IIIB-8	917	918	919
IIIB-9	920	921	922
IIIB-10	923	924	925
IIIB-11	926	927	928
IIIB-12	929	930	931
	SUBSTITUENT
	Compound No.	Q40	Q50	Q60	Q70	Q80
	IIIB-7	932	H	H	H	H
	IIIB-8	933	H	H	H	H
	IIIB-9	934	H	H	H	H
	IIIB-10	935	H	H	H	H
	IIIB-11	936	H	H	H	H
	IIIB-12	937	H	H	H	H

[0115]

TABLE 32
SUBSTITUENT
Compound No.	Q10	Q20	Q30
IIIB-13	938	939	940
IIIB-14	941	942	943
IIIB-15	944	945	946
IIIB-16	947	948	949
IIIB-17	950	951	952
IIIB-18	953	954	955
	SUBSTITUENT
	Compound No.	Q40	Q50	Q60	Q70	Q80
	IIIB-13	956	H	H	H	H
	IIIB-14	957	H	H	H	H
	IIIB-15	958	H	H	H	H
	IIIB-16	959	H	H	H	H
	IIIB-17	960	H	H	H	H
	IIIB-18	961	H	H	H	H

[0116]

TABLE 33
SUBSTITUENT
Compound No.	Q10	Q20	Q30	Q40
IIIB-19	962	963	964	965
IIIB-20	966	967	968	969
IIIB-21	970	971	972	973
IIIB-22	974	975	976	977
IIIB-23	978	979	980	981
IIIB-24	982	983	984	985
	SUBSTITUENT
	Compound No.	Q50	Q60	Q70	Q80
	IIIB-19	H	H	H	H
	IIIB-20	H	H	H	H
	IIIB-21	H	H	H	H
	IIIB-22	H	H	H	H
	IIIB-23	H	H	H	H
	IIIB-24	H	H	H	H

[0117]

TABLE 34
SUBSTITUENT
Compound No.	Q10	Q20	Q30	Q40
IIIB-25	986	987	988	989
IIIB-26	990	991	992	993
IIIB-27	994	995	996	997
IIIB-28	998	999	1000	1001
IIIB-29	1002	1003	1004	1005
IIIB-30	1006	1007	1008	1009
	SUBSTITUENT
	Compound No.	Q50	Q60	Q70	Q80
	IIIB-25	H	H	H	H
	IIIB-26	H	H	H	H
	IIIB-27	H	H	H	H
	IIIB-28	H	H	H	H
	IIIB-29	H	H	H	H
	IIIB-30	H H	H	H

[0118]

TABLE 35
SUBSTITUENT
Compound No.	Q10	Q20	Q30
IIIB-31	1010	1011	1012
IIIB-32	1013	1014	1015
IIIB-33	1016	1017	1018
IIIB-34	1019	1020	1021
IIIB-35	1022	1023	1024
IIIB-36	1025	1026	1027
	SUBSTITUENTS
	Compound No.	Q40	Q50	Q60	Q70	Q80
	IIIB-31	1028	H	H	H	H
	IIIB-32	1029	H	H	H	H
	IIIB-33	1030	H	H	H	H
	IIIB-34	1031	H	H	H	H
	IIIB-35	1032	H	H	H	H
	IIIB-36	1033	H	H	H	H

[0119] Further illustrative examples of the preferred naphthacene derivatives used herein are given below as IVB-1 to IVB-206 and VB-1 to VB-142. The substituents Q1 to Q8 are denoted as Q10 to Q80.

TABLE 36
SUBSTITUENT
Compound No.	Q10	Q20	Q30
IVB-1	1034	1035	1036
IVB-2	1037	1038	1039
IVB-3	1040	1041	1042
IVB-4	1043	1044	1045
IVB-5	1046	1047	1048
IVB-6	1049	1050	1051
IVB-7	1052	1053	1054
IVB-8	1055	1056	1057
IVB-9	1058	1059	1060
IVB-10	1061	1062	1063
IVB-11	1064	1065	1066
	SUBSTITUENT
	Compound No.	Q40	Q50	Q60	Q70	Q80
	IVB-1	1067	CH3	CH3	H	H
	IVB-2	1068	CH3	CH3	H	H
	IVB-3	1069	CH3	CH3	H	H
	IVB-4	1070	CH3	CH3	H	H
	IVB-5	1071	CH3	CH3	H	H
	IVB-6	1072	CH3	CH3	CH3	CH3
	IVB-7	1073	CH3	CH3	CH3	CH3
	IVB-8	1074	CH3	CH3	CH3	CH3
	IVB-9	1075	CH3	CH3	CH3	CH3
	IVB-10	1076	CH3	CH3	CH3	CH3
	IVB-11	1077	CH3	CH3	CH3	CH3

[0120]

TABLE 37
SUBSTITUENT
Compound No.	Q10	Q20	Q30	Q40	Q50	Q60
IVB-12	1078	1079	1080	1081	CH3	CH3
IVB-13	1082	1083	1084	1085	CH3	CH3
IVB-14	1086	1087	1088	1089	CH3	CH3
IVB-15	1090	1091	1092	1093	CH3	CH3
IVB-16	1094	1095	1096	1097	1098	1099
IVB-17	1100	1101	1102	1103	1104	1105
IVB-18	1106	1107	1108	1109	1110	1111
IVB-19	1112	1113	1114	1115	1116	1117
	SUBSTITUENT
	Compound No.	Q70	Q80
	IVB-12	CH3	CH3
	IVB-13	CH3	CH3
	IVB-14	CH3	CH3
	IVB-15	CH3	CH3
	IVB-16	1118	1119
	IVB-17	1120	1121
	IVB-18	1122	1123
	IVB-19	1124	1125

[0121]

TABLE 38
SUBSTITUENT
Compound No.	Q10	Q20	Q30	Q40	Q50
IVB-20	1126	1127	1128	1129	1130
IVB-21	1131	1132	1133	1134	1135
IVB-22	1136	1137	1138	1139	1140
IVB-23	1141	1142	1143	1144	1145
IVB-24	1146	1147	1148	1149	1150
IVB-25	1151	1152	1153	1154	1155
IVB-26	1156	1157	1158	1159	1160
IVB-27	1161	1162	1163	1164	1165
IVB-28	1166	1167	1168	1169	1170
IVB-29	1171	1172	1173	1174	1175
IVB-30	1176	1177	1178	1179	1180
IVB-31	1181	1182	1183	1184	1185
IVB-32	1186	1187	1188	1189	1190
SUBSTITUENT
Compound No.	Q60	Q70	Q80
IVB-20	1191	1192	1193
IVB-21	1194	1195	1196
IVB-22	1197	1198	1199
IVB-23	1200	1201	1202
IVB-24	1203	1204	1205
IVB-25	1206	1207	1208
IVB-26	1209	1210	1211
IVB-27	1212	1213	1214
IVB-28	1215	1216	1217
IVB-29	1218	1219	1220
IVB-30	1221	1222	1223
IVB-31	1224	1225	1226
IVB-32	1227	1228	1229

[0122]

TABLE 39
SUBSTITUENT
Compound No.	Q10	Q20	Q30
IVB-33	1230	1231	1232
IVB-34	1233	1234	1235
IVB-35	1236	1237	1238
IVB-36	1239	1240	1241
IVB-37	1242	1243	1244
IVB-38	1245	1246	1247
IVB-39	1248	1249	1250
IVB-40	1251	1252	1253
IVB-41	1254	1255	1256
IVB-42	1257	1258	1259
IVB-43	1260	1261	1262
IVB-44	1263	1264	1265
IVB-45	1266	1267	1268
SUBSTITUENT
	Compound No.	Q40	Q50	Q60	Q70	Q80
	IVB-33	1269	1270	1271	1272	1273
	IVB-34	1274	1275	1276	1277	1278
	IVB-35	1279	1280	1281	1282	1283
	IVB-36	1284	1285	1286	1287	1288
	IVB-37	1289	1290	1291	1292	1293
	IVB-38	1294	1295	1296	1297	1298
	IVB-39	1299	1300	1301	1302	1303
	IVB-40	1304	1305	1306	H	H
	IVB-41	1307	1308	1309	H	H
	IVB-42	1310	1311	1312	H	H
	IVB-43	1313	1314	1315	H	H
	IVB-44	1316	1317	1318	H	H
	IVB-45	1319	1320	1321	H	H

[0123]

TABLE 40
SUBSTITUENT
Compound No.	Q10	Q20	Q30
IVB-46	1322	1323	1324
IVB-47	1325	1326	1327
IVB-48	1328	1329	1330
IVB-48	1331	1332	1333
IVB-49	1334	1335	1336
IVB-50	1337	1338	1339
IVB-51	1340	1341	1342
IVB-52	1343	1344	1345
IVB-53	1346	1347	1348
IVB-54	1349	1350	1351
IVB-55	1352	1353	1354
IVB-56	1355	1356	1357
IVB-57	1358	1359	1360
IVB-58	1361	1362	1363
SUBSTITUENTS
Compound No.	Q40	Q50	Q60
IVB-46	1364	1365	1366
IVB-47	1367	1368	1369
IVB-48	1370	1371	1372
IVB-49	1373	1374	1375
IVB-50	1376	1377	1378
IVB-51	1379	1380	1381
IVB-52	1382	CH3	CH3
IVB-53	1383	CH3	CH3
IVB-54	1384	CH3	CH3
IVB-55	1385	CH3	CH3
IVB-56	1386	CH3	CH3
IVB-57	1387	CH3	CH3
IVB-58	1388	CH3	CH3
	SUBSTITUENT
	Compound No.	Q70	Q80
	IVB-46	H	H
	IVB-47	H	H
	IVB-48	H	H
	IVB-49	H	H
	IVB-50	H	H
	IVB-51	H	H
	IVB-52	H	H
	IVB-53	H	H
	IVB-54	H	H
	IVB-55	H	H
	IVB-56	H	H
	IVB-57	H	H
	IVB-58	H	H

[0124]

TABLE 41
SUBSTITUENT
Compound No.	Q10	Q20	Q30	Q40	Q50	Q60	Q70	Q80
IVB-59	1389	1390	1391	1392	CH3	CH3	H	H
IVB-60	1393	1394	1395	1396	CH3	CH3	H	H
IVB-61	1397	1398	1399	1400	CH3	CH3	H	H
IVB-62	1401	1402	1403	1404	CH3	CH3	H	H
IVB-63	1405	1406	1407	1408	CH3	CH3	H	H
IVB-64	1409	1410	1411	1412	CH3	CH3	H	H
IVB-65	1413	1414	1415	1416	CH3	CH3	H	H
IVB-66	1417	1418	1419	1420	CH3	CH3	H	H
IVB-67	1421	1422	1423	1424	CH3	CH3	H	H
IVB-68	1425	1426	1427	1428	CH3	CH3	H	H
IVB-69	1429	1430	1431	1432	CH3	CH3	H	H

[0125]

TABLE 42
SUBSTITUENT
Compound No.	Q10	Q20	Q30	Q40	Q50	Q60	Q70	Q80
IVB-70	1433	1434	1435	1436	CH3	CH3	H	H
IVB-71	1437	1438	1439	1440	CH3	CH3	H	H
IVB-72	1441	1442	1443	1444	CH3	CH3	H	H
IVB-73	1445	1446	1447	1448	CH3	CH3	H	H
IVB-74	1449	1450	1451	1452	CH3	CH3	H	H
IVB-75	1453	1454	1455	1456	CH3	CH3	H	H
IVB-76	1457	1458	1459	1460	CH3	CH3	H	H
IVB-77	1461	1462	1463	1464	CH3	CH3	H	H
IVB-78	1465	1466	1467	1468	CH3	CH3	H	H
IVB-79	1469	1470	1471	1472	CH3	CH3	H	H

[0126]

TABLE 42
SUBSTITUENT
Compound
No.	Q10	Q20	Q30	Q40	Q50	Q60	Q70	Q80
IVB-80	1473	1474	1475	1476	CH3	CH3	H	H
IVB-81	1477	1478	1479	1480	CH3	CH3	H	H
IVB-82	1481	1482	1483	1484	CH3	CH3	H	H
IVB-83	1485	1486	1487	1488	CH3	CH3	H	H
IVB-84	1489	1490	1491	1492	CH3	CH3	CH3	CH3
IVB-85	1493	1494	1495	1496	CH3	CH3	CH3	CH3
IVB-86	1497	1498	1499	1500	CH3	CH3	CH3	CH3
IVB-87	1501	1502	1503	1504	CH3	CH3	CH3	CH3

[0127]

TABLE 44
SUBSTITUENT
Compound No.	Q10	Q20	Q30	Q40	Q50	Q60	Q70	Q80
IVB-88	1505	1506	1507	1508	CH3	CH3	CH3	CH3
IVB-89	1509	1510	1511	1512	CH3	CH3	CH3	CH3
IVB-90	1513	1514	1515	1516	CH3	CH3	CH3	CH3
IVB-91	1517	1518	1519	1520	CH3	CH3	CH3	CH3
IVB-92	1521	1522	1523	1524	CH3	CH3	CH3	CH3
IVB-93	1525	1526	1527	1528	CH3	CH3	CH3	CH3
IVB-94	1529	1530	1531	1532	CH3	CH3	CH3	CH3
IVB-95	1533	1534	1535	1536	CH3	CH3	CH3	CH3
IVB-96	1537	1538	1539	1540	CH3	CH3	CH3	CH3
IVB-97	1541	1542	1543	1544	CH3	CH3	CH3	CH3
IVB-98	1545	1546	1547	1548	CH3	CH3	CH3	CH3

[0128]

TABLE 45
SUBSTITUENT
Compound No.	Q10	Q20	Q30	Q40	Q50	Q60	Q70	Q80
IVB-99	1549	1550	1551	1552	CH3	CH3	CH3	CH3
IVB-100	1553	1554	1555	1556	CH3	CH3	CH3	CH3
IVB-101	1557	1558	1559	1560	CH3	CH3	CH3	CH3
IVB-102	1561	1562	1563	1564	CH3	CH3	CH3	CH3
IVB-103	1565	1566	1567	1568	CH3	CH3	CH3	CH3
IVB-104	1569	1570	1571	1572	CH3	CH3	CH3	CH3
IVB-105	1573	1574	1575	1576	CH3	CH3	CH3	CH3
IVB-106	1577	1578	1579	1580	CH3	CH3	CH3	CH3
IVB-107	1581	1582	1583	1584	CH3	CH3	CH3	CH3
IVB-108	1585	1586	1587	1588	CH3	CH3	CH3	CH3

[0129]

TABLE 46
SUBSTITUENT
Compound
No.	Q10	Q20	Q30	Q40	Q50	Q60	Q70	Q80
IVB-109	1589	1590	1591	1592	CH3	CH3	CH3	CH3
IVB-110	1593	1594	1595	1596	CH3	CH3	CH3	CH3
IVB-111	1597	1598	1599	1600	CH3	CH3	CH3	CH3
IVB-112	1601	1602	1603	1604	CH3	CH3	CH3	CH3
IVB-113	1605	1606	1607	1608	CH3	CH3	CH3	CH3
IVB-114	1609	1610	1611	1612	1613	1614	1615	1616
IVB-115	1617	1618	1619	1620	1621	1622	1623	1624
IVB-116	1625	1626	1627	1628	1629	1630	1631	1632

[0130]

TABLE 47
SUBSTITUENT
Compound
No.	Q10	Q20	Q30	Q40	Q50	Q60	Q70	Q80
IVB-117	1633	1634	1635	1636	1637	1638	1639	1640
IVB-118	1641	1642	1643	1644	1645	1646	1647	1648
IVB-119	1649	1650	1651	1652	1653	1654	1655	1656
IVB-120	1657	1658	1659	1660	1661	1662	1663	1664
IVB-121	1665	1666	1667	1668	1669	1670	1671	1672
IVB-122	1673	1674	1675	1676	1677	1678	1679	1680
IVB-123	1681	1682	1683	1684	1685	1686	1687	1688
IVB-124	1689	1690	1691	1692	1693	1694	1695	1696
IVB-125	1697	1698	1699	1700	1701	1702	1703	1704

[0131]

TABLE 48
SUBSTITUENT
Compound
No.	Q10	Q20	Q30	Q40	Q50	Q60	Q70	Q80
IVB-126	1705	1706	1707	1708	1709	1710	1711	1712
IVB-127	1713	1714	1715	1716	1717	1718	1719	1720
IVB-128	1721	1722	1723	1724	1725	1726	1727	1728
IVB-129	1729	1730	1731	1732	1733	1734	1735	1736
IVB-130	1737	1738	1739	1740	1741	1742	1743	1744
IVB-131	1745	1746	1747	1748	1749	1750	1751	1752
IVB-132	1753	1754	1755	1756	1757	1758	1759	1760
IVB-133	1761	1762	1763	1764	1765	1766	1767	1768
IVB-134	1769	1770	1771	1772	1773	1774	1775	1776

[0132]

TABLE 49
SUBSTITUENT
Compound
No.	Q10	Q20	Q30	Q40	Q50	Q60	Q70	Q80
IVB-135	1777	1778	1779	1780	1781	1782	1783	1784
IVB-136	1785	1786	1787	1788	1789	1790	1791	1792
IVB-137	1793	1794	1795	1796	1797	1798	1799	1800
IVB-138	1801	1802	1803	1804	1805	1806	1807	1808
IVB-139	1809	1810	1811	1812	1813	1814	1815	1816
IVB-140	1817	1818	1819	1820	1821	1822	1823	1824
IVB-141	1825	1826	1827	1828	1829	1830	1831	1832

[0133]

TABLE 50
SUBSTITUENT
Compound
No.	Q10	Q20	Q30	Q40	Q50	Q60	Q70	Q80
IVB-142	1833	1834	1835	1836	1837	1838	1839	1840
IVB-143	1841	1842	1843	1844	1845	1846	1847	1848
IVB-144	1849	1850	1851	1852	1853	1854	H	H
IVB-145	1855	1856	1857	1858	1859	1860	H	H
IVB-146	1861	1862	1863	1864	1865	1866	H	H
IVB-147	1867	1868	1869	1870	1871	1872	H	H
IVB-148	1873	1874	1875	1876	1877	1878	H	H
IVB-149	1879	1880	1881	1882	1883	1884	H	H
IVB-150	1885	1886	1887	1888	1889	1890	H	H

[0134]

TABLE 51
SUBSTITUENT
Compound No.	Q10	Q20	Q30	Q40	Q50	Q60	Q70	Q80
IVB-151	1891	1892	1893	1894	1895	1896	H	H
IVB-152	1897	1898	1899	1900	1901	1902	H	H
IVB-153	1903	1904	1905	1906	1907	1908	H	H
IVB-154	1909	1910	1911	1912	1913	1914	H	H
IVB-155	1915	1916	1917	1918	1919	1920	H	H
IVB-156	1921	1922	1923	1924	1925	1926	H	H
IVB-157	1927	1928	1929	1930	1931	1932	H	H
IVB-158	1933	1934	1935	1936	1937	1938	H	H
IVB-159	1939	1940	1941	1942	1943	1944	H	H
IVB-160	1945	1946	1947	1948	1949	1950	H	H
IVB-161	1951	1952	1953	1954	1955	1956	H	H

[0135]

TABLE 52
SUBSTITUENT
Compound No.	Q10	Q20	Q30	Q40	Q50	Q60	Q70	Q80
IVB-162	1957	1958	1959	1960	1961	1962	H	H
IVB-163	1963	1964	1965	1966	1967	1968	H	H
IVB-164	1969	1970	1971	1972	1973	1974	H	H
IVB-165	1975	1976	1977	1978	1979	1980	H	H
IVB-166	1981	1982	1983	1984	1985	1986	H	H
IVB-167	1987	1988	1989	1990	1991	1992	H	H
IVB-168	1993	1994	1995	1996	1997	1998	H	H
IVB-169	1999	2000	2001	2002	2003	2004	H	H

[0136]

TABLE 53
SUBSTITUENT
Compound No.	Q10	Q20	Q30	Q40	Q50	Q60	Q70	Q80
IVB-170	2005	2006	2007	2008	2009	2010	H	H
IVB-171	2011	2012	2013	2014	2015	2016	H	H
IVB-172	2017	2018	2019	2020	2021	2022	H	H
IVB-173	2023	2024	2025	2026	2027	2028	H	H
IVB-174	2029	2030	2031	2032	2033	2034	H	H
IVB-175	2035	2036	2037	2038	2039	2040	H	H

[0137]

TABLE 54
SUBSTITUTENT
Compound No.	Q10	Q20	Q30	Q40	Q50	Q60	Q70	Q80
IVB-176	2041	2042	2043	2044	2045	2046	H	H
IVB-177	2047	2048	2049	2050	2051	2052	H	H
IVB-178	2053	2054	2055	2056	2057	2058	H	H
IVB-179	2059	2060	2061	2062	2063	2064	H	H
IVB-180	2065	2066	2067	2068	2069	2070	H	H
IVB-181	2071	2072	2073	2074	2075	2076	H	H
IVB-182	2077	2078	2079	2080	2081	2082	H	H
IVB-183	2083	2084	2085	2086	2087	2088	H	H
IVB-184	2089	2090	2091	2092	2093	2094	H	H
IVB-185	2095	2096	2097	2098	2099	2100	H	H

[0138]

TABLE 55
SUBSTITUENT
Compound No.	Q10	Q20	Q30	Q40	Q50	Q60	Q70	Q80
IVB-186	2101	2102	2103	2104	2105	2106	H	H
IVB-187	2107	2108	2109	2110	2111	2112	H	H
IVB-188	2113	2114	2115	2116	2117	2118	H	H
IVB-189	2119	2120	2121	2122	2123	2124	H	H
IVB-190	2125	2126	2127	2128	2129	2130	2131	2132
IVB-191	2133	2134	2135	2136	2137	2138	2139	2140
IVB-192	2141	2142	2143	2144	2145	2146	2147	2148
IVB-193	2149	2150	2151	2152	2153	2154	2155	2156
IVB-194	2157	2158	2159	2160	2161	2162	2163	2164

[0139]

TABLE 56
SUBSTITUENT
Compound No.	Q10	Q20	Q30	Q40	Q50	Q60	Q70	Q80
IVB-195	2165	2166	2167	2168	2169	2170	2171	2172
IVB-196	2173	2174	2175	2176	2177	2178	2179	2180
IVB-197	2181	2182	2183	2184	2185	2186	2187	2188
IVB-198	2189	2190	2191	2192	2193	2194	2195	2196
IVB-199	2197	2198	2199	2200	2201	2202	2203	2204
IVB-200	2205	2206	2207	2208	2209	2210	2211	2212
IVB-201	2213	2214	2215	2216	2217	2218	2219	2220
IVB-202	2221	2222	2223	2224	2225	2226	2227	2228
IVB-203	2229	2230	2231	2232	2233	2234	2235	2236

[0140]

TABLE 57
SUBSTITUENT
Compound No.	Q10	Q20	Q30	Q40	Q50	Q70	Q70	Q80
IVB-204	2237	2238	2239	2240	2241	2242	2243	2244
IVB-205	2245	2246	2247	2248	2249	2250	2251	2252
IVB-206	2253	2254	2255	2256	2257	2258	2259	2260

[0141]

TABLE 58
SUBSTITUENT
Compound No.	Q10	Q20	Q30	Q40	Q50	Q60	Q70	Q80
VB-1	H	2261	2262	H	H	H	H	H
VB-2	H	2263	2264	H	H	H	H	H
VB-3	H	2265	2266	H	H	H	H	H
VB-4	H	2267	2268	H	H	H	H	H
VB-5	H	2269	2270	H	H	H	H	H
VB-6	H	2271	2272	H	H	H	H	H
VB-7	H	2273	2274	H	H	H	H	H
VB-8	H	2275	2276	H	H	H	H	H
VB-9	H	2277	2278	H	H	H	H	H
VB-10	H	2279	2280	H	H	H	H	H
VB-11	H	2281	2282	H	H	H	H	H
VB-12	H	2283	2284	H	H	H	H	H
VB-13	H	2285	2286	H	H	H	H	H
VB-14	H	2287	2288	H	H	H	H	H

[0142]

TABLE 59
SUBSTITUENT
Compound
No.	Q10	Q20	Q30	Q40	Q50	Q60	Q70	Q80
VB-15	H	2289	2290	H	H	H	H	H
VB-16	H	2291	2292	H	H	H	H	H
VB-17	H	2293	2294	H	H	H	H	H
VB-18	H	2295	2296	H	H	H	H	H
VB-19	H	2297	2298	H	H	H	H	H
VB-20	H	2299	2300	H	H	H	H	H
VB-21	H	2301	2302	H	H	H	H	H
VB-22	H	2303	2304	H	H	H	H	H
VB-23	H	2305	2306	H	H	H	H	H
VB-24	H	2307	2308	H	H	H	H	H
VB-25	H	2309	2310	H	H	H	H	H
VB-26	H	2311	2312	H	H	H	H	H

[0143]

TABLE 60
SUBSTITUENT
Compound
No.	Q10	Q20	Q30	Q40	Q50	Q60	Q70	Q80
VB-27	H	2313	2314	H	H	H	H	H
VB-28	H	2315	2316	H	H	H	H	H
VB-29	H	2317	2318	H	H	H	H	H
VB-30	H	2319	2320	H	H	H	H	H
VB-31	H	2321	2322	H	H	H	H	H
VB-32	H	2323	2324	H	H	H	H	H
VB-33	H	2325	2326	H	H	H	H	H
VB-34	H	2327	2328	H	H	H	H	H
VB-35	H	2329	2330	H	H	H	H	H
VB-36	H	2331	2332	H	H	H	H	H
VB-37	H	2333	2334	H	H	H	H	H
VB-38	H	2335	2336	H	H	H	H	H
VB-39	H	2337	2338	H	H	H	H	H

[0144]

TABLE 61
SUBSTITUENT
Compound No.	Q10	Q20	Q30	Q40	Q50	Q60	Q70	Q80
VB-40	H	2339	2340	H	H	H	H	H
VB-41	H	2341	2342	H	H	H	H	H
VB-42	H	2343	2344	H	H	H	H	H
VB-43	H	2345	2346	H	H	H	H	H
VB-44	H	2347	2348	H	H	H	H	H
VB-45	H	2349	2350	H	H	H	H	H
VB-46	H	2351	2352	H	H	H	H	H
VB-47	H	2353	2354	H	H	H	H	H
VB-48	H	2355	2356	H	H	H	H	H
VB-49	H	2357	2358	H	H	H	H	H
VB-50	H	2359	2360	H	H	H	H	H
VB-51	H	2361	2362	H	H	H	H	H

[0145]

TABLE 62
SUBSTITUENT
Compound
No.	Q10	Q20	Q30	Q40	Q50	Q60	Q70	Q80
VB-52	H	2363	2364	H	H	H	H	H
VB-53	H	2365	2366	H	H	H	H	H
VB-54	H	2367	2368	H	H	H	H	H
VB-55	H	2369	2370	H	H	H	H	H
VB-56	H	2371	2372	H	H	H	H	H
VB-57	H	2373	2374	H	H	H	H	H
VB-58	H	2375	2376	H	H	H	H	H
VB-59	H	2377	2378	H	H	H	H	H
VB-60	H	2379	2380	H	H	H	H	H

[0146]

TABLE 63
SUBSTITUENT
Compound
No.	Q10	Q20	Q30	Q40	Q50	Q60	Q70	Q80
VB-61	H	2381	2382	H	H	H	H	H
VB-62	H	2383	2384	H	H	H	H	H
VB-63	H	2385	2386	H	H	H	H	H
VB-64	H	2387	2388	H	H	H	H	H
VB-65	H	2389	2390	H	H	H	H	H
VB-66	H	2391	2392	H	H	H	H	H
VB-67	H	2393	2394	H	H	H	H	H
VB-68	H	2395	2396	H	H	H	H	H
VB-69	H	2397	2398	H	H	H	H	H
VB-70	H	2399	2400	H	H	H	H	H

[0147]

TABLE 64
SUBSTITUENT
Compound
No.	Q10	Q20	Q30	Q40	Q50	Q60	Q70	Q80
VB-71	H	2401	2402	H	Ph	Ph	Ph	Ph
VB-72	H	2403	2404	H	Ph	Ph	Ph	Ph
VB-73	H	2405	2406	H	Ph	Ph	Ph	Ph
VB-74	H	2407	2408	H	Ph	Ph	Ph	Ph
VB-75	H	2409	2410	H	Ph	Ph	Ph	Ph
VB-76	H	2411	2412	H	Ph	Ph	Ph	Ph
VB-77	H	2413	2414	H	Ph	Ph	Ph	Ph
VB-78	H	2415	2416	H	Ph	Ph	Ph	Ph
VB-79	H	2417	2418	H	Ph	Ph	Ph	Ph
VB-80	H	2419	2420	H	Ph	Ph	Ph	Ph
VB-81	H	2421	2422	H	Ph	Ph	Ph	Ph
VB-82	H	2423	2424	H	Ph	Ph	Ph	Ph
VB-83	H	2425	2426	H	Ph	Ph	Ph	Ph
VB-84	H	2427	2428	H	Ph	Ph	Ph	Ph

[0148]

TABLE 65
SUBSTITUENT
Compound No.	Q10	Q20	Q30	Q40	Q50	Q60	Q70	Q80
VB-85	H	2429	2430	H	Ph	Ph	Ph	Ph
VB-86	H	2431	2432	H	Ph	Ph	Ph	Ph
VB-87	H	2433	2434	H	Ph	Ph	Ph	Ph
VB-88	H	2435	2436	H	Ph	Ph	Ph	Ph
VB-89	H	2437	2438	H	Ph	Ph	Ph	Ph
VB-90	H	2439	2440	H	Ph	Ph	Ph	Ph
VB-91	H	2441	2442	H	Ph	Ph	Ph	Ph
VB-92		2443	2444	H	Ph	Ph	Ph	Ph
VB-93	H	2445	2446	H	Ph	Ph	Ph	Ph
VB-94	H	2447	2448	H	Ph	Ph	Ph	Ph
VB-95	H	2449	2450	H	Ph	Ph	Ph	Ph
VB-96	H	2451	2452	H	Ph	Ph	Ph	Ph

[0149]

TABLE 66
SUBSTITUENT
Compound
No.	Q10	Q20	Q30	Q40	Q50	Q60	Q70	Q80
VB-97	H	2453	2454	H	Ph	Ph	Ph	Ph
VB-98	H	2455	2456	H	Ph	Ph	Ph	Ph
VB-99	H	2457	2458	H	Ph	Ph	Ph	Ph
VB-100	H	2459	2460	H	Ph	Ph	Ph	Ph
VB-101	H	2461	2462	H	Ph	Ph	Ph	Ph
VB-102	H	2463	2464	H	Ph	Ph	Ph	Ph
VB-103	H	2465	2466	H	Ph	Ph	Ph	Ph
VB-104	H	2467	2468	H	Ph	Ph	Ph	Ph
VB-105	H	2469	2470	H	Ph	Ph	Ph	Ph
VB-106	H	2471	2472	H	Ph	Ph	Ph	Ph

[0150]

TABLE 67
SUBSTITUENT
Compound
No.	Q10	Q20	Q30	Q40	Q50	Q60	Q70	Q80
VB-107	H	2473	2474	H	Ph	Ph	H	H
VB-108	H	2475	2476	H	Ph	Ph	H	H
VB-109	H	2477	2478	H	Ph	Ph	H	H
VB-110	H	2479	2480	H	Ph	Ph	H	H
VB-111	H	2481	2482	H	Ph	Ph	H	H
VB-112	H	2483	2484	H	Ph	Ph	H	H
VB-113	H	2485	2486	H	Ph	Ph	H	H
VB-114	H	2487	2488	H	Ph	Ph	H	H
VB-115	H	2489	2490	H	Ph	Ph	H	H
VB-116	H	2491	2492	H	Ph	Ph	H	H
VB-117	H	2493	2494	H	Ph	Ph	H	H
VB-118	H	2495	2496	H	Ph	Ph	H	H
VB-119	H	2497	2498	H	Ph	Ph	H	H
VB-120	H	2499	2500	H	Ph	Ph	H	H

[0151]

TABLE 68
SUBSTITUENT
Compound
No.	Q10	Q20	Q30	Q40	Q50	Q60	Q70	Q80
VB-121	H	2501	2502	H	Ph	Ph	H	H
VB-122	H	2503	2504	H	Ph	Ph	H	H
VB-123	H	2505	2506	H	Ph	Ph	H	H
VB-124	H	2507	2508	H	Ph	Ph	H	H
VB-125	H	2509	2510	H	Ph	Ph	H	H
VB-126	H	2511	2512	H	Ph	Ph	H	H
VB-127	H	2513	2514	H	Ph	Ph	H	H
VB-128	H	2515	2516	H	Ph	Ph	H	H
VB-129	H	2517	2518	H	Ph	Ph	H	H
VB-130	H	2519	2520	H	Ph	Ph	H	H
VB-131	H	2521	2522	H	Ph	Ph	H	H
VB-132	H	2523	2524	H	Ph	Ph	H	H

[0152]

TABLE 69
SUBSTITUENT
Compound
No.	Q10	Q20	Q30	Q40	Q50	Q60	Q70	Q80
VB-133	H	2525	2526	H	Ph	Ph	H	H
VB-134	H	2527	2528	H	Ph	Ph	H	H
VB-135	H	2529	2530	H	Ph	Ph	H	H
VB-136	H	2531	2532	H	Ph	Ph	H	H
VB-137	H	2533	2534	H	Ph	Ph	H	H
VB-138	H	2535	2536	H	Ph	Ph	H	H
VB-139	H	2537	2538	H	Ph	Ph	H	H
VB-140	H	2539	2540	H	Ph	Ph	H	H
VB-141	H	2541	2542	H	Ph	Ph	H	H
VB-142	H	2543	2544	H	Ph	Ph	H	H

[0153] The naphthacene derivatives used herein can be synthesized, for example, using diphenyltetracene quinone and analogues. A typical synthesis scheme is shown below. 2545

[0154] The naphthacene derivatives are used as the host material in combination with dopants.

[0155] Tetraaryldiamine Compounds

[0156] Another class of organic compounds useful as the host material according to the invention are tetraaryldiamine derivatives of the following formula (II).

[0157] In the device of the invention, the use of the tetraaryldiamine derivative, preferably as the host material, helps induce strong light emission from the dopant while controlling the interaction with the dopant.

[0158] In an exemplary organic EL device which was fabricated using a tetraaryldiamine derivative doped with a dibenzo[f,f′]diindeno[1,2,3-cd:1′,2′,3′-lm]perylene derivative, a luminance of at least 300 cd/m2 at maximum was obtained at a current density of 10 mA/cm2 and a drive voltage as low as about 6.5 V. When operated at a current density of about 500 mA/cm2, the device consistently produced a luminance of greater than about 15,000 cd/m2. When operated at a current density of about 50 mA/cm2, the device marked a very long lifetime as demonstrated by a half-life time of more than 300 hours at an initial luminance of at least 2400 cd/cm2. Since the tetraaryldiamine derivative has hole transporting ability, a mixture thereof with another of the above-mentioned host materials enables to control carrier balance, resulting in a device with a high efficiency and long lifetime.

[0159] In organic EL devices as mentioned above, the dopant concentration ensuring a chromatic purity and maximum efficiency is about 1% by weight although dopant concentrations of about 2 or 3% by weight lead to devices which are practically acceptable albeit a drop of less than about 10%. 2546

[0160] In formula (II), R1 to R4 are independently aryl, fluorene, carbazolyl, alkyl, alkoxy, aryloxy, amino or halogen radicals, at least one of R1 to R4 is aryl, and r1 to r4 each are 0 or an integer of 1 to 5, with the proviso that r1 to r4 are not 0 at the same time, that is, r1+r2+r3+r4 is an integer of at least 1. R5 and R6 are independently alkyl, alkoxy, amino or halogen radicals and may be the same or different, and r5 and r6 each are 0 or an integer of 1 to 4.

[0161] The aryl radicals represented by R1 to R4 may be monocyclic or polycyclic, inclusive of fused rings and a collection of rings. Those aryl radicals having 6 to 20 carbon atoms in total are preferred. They may have substituents, examples of which are alkyl, alkoxy, aryl, aryloxy, amino and halogen groups. Preferred examples of the aryl radical represented by R1 to R4 include phenyl, o-, m- and p-tolyl, pyrenyl, naphthyl, anthryl, biphenylyl, phenylanthryl and tolylanthryl. Of these, phenyl is most preferred. Preferably the aryl radical, especially phenyl is bonded at the 3- or 4-position.

[0162] The alkyl radicals represented by R1 to R4 may be straight or branched alkyl radicals, preferably of 1 to 10 carbon atoms. They may have substituents, examples of which are as illustrated for the aryl radicals. Preferred examples of the alkyl radical represented by R1 to R4 include methyl, ethyl, n- and i-propyl, n-, i-, sec- and tert-butyl.

[0163] The alkoxy radicals represented by R1 to R4 are preferably those having an alkyl moiety of 1 to 6 carbon atoms, for example, methoxy, ethoxy, and t-butoxy. The alkoxy radicals may have substituents.

[0164] Examples of the aryloxy radicals represented by R1 to R4 include phenoxy, 4-methylphenoxy, and 4-(t-butyl)phenoxy.

[0165] The amino radicals represented by R1 to R4 may be substituted or unsubstituted, with the substituted amino radicals being preferred. Illustrative examples include dimethylamino, diethylamino, diphenylamino, phenyltolylamino and bis(biphenyl)amino radicals.

[0166] Examples of the halogen atom represented by R1 to R4 are chlorine and bromine.

[0167] At least one of R1 to R4 is an aryl radical, and preferably at least two, more preferably at least three of R1 to R4 are aryl radicals. It is then preferred that at least two, more preferably at least three of r1 to r4 are integers of at least 1. Especially at least two, even more preferably at least three of r1 to r4 are equal to 1.

[0168] In formula (II), the alkyl, alkoxy, amino and halogen radicals represented by R5 and R6 are the same as illustrated for R1 to R4.

[0169] It is preferred that both r5 and r6 be 0, that is, the biphenylene radical connecting two arylamino radicals be an unsubstituted one.

[0170] When r1 to r4 are integers of at least 2, the R1 groups, R2 groups, R3 groups and R4 groups may be identical or different, respectively. When r5 and r6 are integers of at least 2, the R5 groups and R6 groups may be identical or different, respectively.

[0171] Of the compounds of formula (II), those compounds of the following formulas (II-1) and (II-2) are preferred. 2547

[0172] In formulas (II-1) and (II-2), R7 to R10 are independently alkyl, alkoxy, aryl, aryloxy, amino radicals or halogen atoms, and may be the same or different. Illustrative examples are the same as described for R1 to R4 in formula (II). Letters r7 to r10 are each 0 or an integer of 1 to 4. It is preferred that r7 to r10 be 0 in both formulas (II-1) and (II-2).

[0173] R11 to R14 are independently alkyl, alkoxy, aryl, aryloxy, amino radicals or halogen atoms, and may be the same or different. Illustrative examples are the same as described for R1 to R4 in formula (II). Letters r11 to r14 are each 0 or an integer of 1 to 5.

[0174] R5, R6, r5 and r6 in formulas (II-1) and (II-2) are as defined in formula (II). It is preferred that r5 and r6 be 0.

[0175] In formulas (II-1) and (II-2), when each of r7 to r10 is an integer of at least 2, the R7 groups, R8 groups, R9 groups and R10 groups may be the same or different, respectively; and when each of r11 to r14 is an integer of at least 2, the R11 groups, R12 groups, R13 groups and R14 groups may be the same or different, respectively.

[0176] Of the compounds of formula (II), those compounds of the following formula (II-3) are also preferred. 2548

[0177] R5, R6, r5 and r6 in formula (II-3) are as defined in formula (II). It is preferred that r5 and r6 be 0.

[0178] Ar1 and Ar2 each are an aryl radical and may be the same or different. Illustrative examples of the aryl radical are as described for R1 to R4 in formula (II). Phenyl and biphenyl radicals are preferred among others.

[0179] R15 and R16 are independently alkyl, alkoxy, aryl, aryloxy, amino radicals or halogen atoms, and may be the same or different. Illustrative examples are the same as described for R1 to R4 in formula (II). Letters r15 and r16 are each 0 or an integer of 1 to 4. It is preferred that r15 and r16 be 0.

[0180] R17 and R18 are independently alkyl, alkoxy, aryloxy, amino radicals or halogen atoms, and may be the same or different. Illustrative examples are the same as described for R1 to R4 in formula (II). Letters r17 and r18 are each 0 or an integer of 1 to 5. It is preferred that r17 and r18 be 0.

[0181] In formula (II-3), when each of r15 and r16 is an integer of at least 2, the R15 groups and R16 groups may be the same or different, respectively; and when each of r17 and r18 is an integer of at least 2, the R17 groups and R18 groups may be the same or different, respectively.

[0182] Illustrative, non-limiting, examples of the compound of formula (II) are given below. It is noted that general formulas are followed by lists of R's to show illustrative examples by combinations of R's and optionally Ar's. As to a set of R's, when all R's in that set are hydrogen, H is assigned to that set. When a substituent is present as any of R's in a set, only the substituent is designated in the set, indicating that the remainders are hydrogen. Ar1 and Ar2 are individually shown.

2549
Com-
pound
No.	R1˜R4	R5˜R9	R10˜R13	R14˜R18	R19˜R22	R23˜R27	R28˜R31	R32˜R36	R37˜R44
I-1	H	H	H	H	H	H	H	H	H
I-2	H	R6 = CH3	H	R17═CH3	H	R26 = CH3	H	R35 = CH3	H
I-3	H	R7 = CH3	H	R16 = CH3	H	R25 = CH3	H	R34 = CH3	H
I-4	H	R7 = t-C4H9	H	R16 = t-C4H9	H	R25 = t-C4H9	H	R34 = t-C4H9	H
I-5	H	R7 = OCH3	H	R16 = OCH3	H	R25 = OCH3	H	R34 = OCH3	H
I-6	H	R7 = Ph	H	R16 = Ph	H	R25 = Ph	H	R34 = Ph	H
I-7	H	2550	H	2551	H	2552	H	2553	H
I-8	H	R7 = OPh	H	R16 = OPh	H	R25 = OPh	H	R34 = OPh	H
I-9	H	R7 = N(C2H5)2	H	R16 = N(C2H5)2	H	R25 = N(C2H5)2	H	R34 = N(C2H5)2	H
I-10	H	R7 = N(Ph)2	H	R16 = N(Ph)2	H	R25 = N(Ph)2	H	R34 = N(Ph)2	H
I-11	H	R7 = Cl	H	R16 = Cl	H	R25 = Cl	H	R34 = Cl	H
I-12	R2 = CH3	H	R11 = CH3	H	R20 = CH3	H	R29 = CH3	H	H
I-13	H	R6 = Ph	H	R17 = Ph	H	R26 = Ph	H	R35 = Ph	H
I-14	H	R7 = Ph	H	R16 = Ph	H	H	H	H	H
I-15	H	R6 = Ph	H	R17 = Ph	H	H	H	H	H
I-16	R2 = OCH3	H	R11 = OCH3	H	R20 = OCH3	H	R29 = OCH3	H	H
I-17	R2 = Ph	H	R11 = Ph	H	R20 = Ph	H	R29 = Ph	H	H
I-18	R2 = OPh	H	R11 = OPh	H	R20 = OPh	H	R29 = OPh	H	H
I-19	R2 = N(C2H5)2	H	R11 = N(C2H5)2	H	R20 = N(C2H5)2	H	R29 = N(C2H5)2	H	H
I-20	R2 = Cl	H	R11 = Cl	H	R20 = Cl	H	R29 = Cl	H	H
I-21	H	H	H	H	H	H	H	H	R37 = R42 = CH3
I-22	H	H	H	H	H	H	H	H	R37 = R42 = OCH3
I-23	H	H	H	H	H	H	H	H	R37 = R42 = N(C2H5)2
I-24	H	H	H	H	H	H	H	H	R37 = R42 = Cl
I-25	H	H	H	H	H	H	H	H	R40 = R43 = CH3
I-26	R2 = Ph	R7 = Ph	R11 = Ph	R16 = Ph	R20 = Ph	R25 = Ph	R29 = Ph	R34 = Ph	H
I-27	R2 = N(Ph)2	H	R11 = Ph	H	R20 = Ph	H	R29 = Ph	H	H
I-28	H	R6 = CH3	H	R16 = CH3	H	R26 = CH3	H	R34 = CH3	H
I-29	H	R6 = R8 = CH3	H	H	H	R24 = R26 = CH3	H	H	H

[0183]

2554
Com-
pound
No.	R51˜R54	R55˜R59	R60˜R63	R64˜R68	R69˜R72	R73˜R77	R78˜R81	R82˜R86	R87˜R94
II-1	H	H	H	H	H	H	H	H	H
II-2	H	R56 = CH3	H	R67 = CH3	H	R74 = CH3	H	R85 = CH3	H
II-3	H	R57 = CH3	H	R66 = CH3	H	R75 = CH3	H	R84 = CH3	H
II-4	H	R57 = t-C4H9	H	R66 = t-C4H9	H	R75 = t-C4H9	H	R84 = t-C4H9	H
II-5	H	R57 = OCH3	H	R66 = OCH3	H	R75 = OCH3	H	R84 = OCH3	H
II-6	H	R57 = Ph	H	R66 = Ph	H	R75 = Ph	H	R84 = Ph	H
II-7	H	2555	H	2556	H	2557	H	2558	H
II-8	H	R57 = OPh	H	R66 = OPh	H	R75 = OPh	H	R84 = OPh	H
II-9	H	R57 = N(C2H5)2	H	R66 = N(C2H5)2	H	R75 = N(C2H5)2	H	R84 = N(C2H5)2	H
II-10	H	R57 = N(Ph)2	H	R66 = N(Ph)2	H	R75 = N(Ph)2	H	R84 = N(Ph)2	H
II-11	H	R57 = Cl	H	R66 = Cl	H	R75 = Cl	H	R84 = Cl	H
II-12	R52 = CH3	H	R62 = CH3	H	R72 = CH3	H	R79 = CH3	H	H
II-13	R52 = OCH3	H	R62 = OCH3	H	R72 = OCH3	H	R79 = OCH3	H	H
II-14	R52 = Ph	H	R62 = Ph	H	R72 = Ph	H	R79 = Ph	H	H
II-15	R52 = OPh	H	R62 = OPh	H	R72 = OPh	H	R79 = OPh	H	H
II-16	R52 = N(C2H5)2	H	R62 = N(C2H5)2	H	R72 = N(C2H5)2	H	R79 = N(C2H5)2	H	H
II-17	R52 = Cl	H	R62 = Cl	H	R72 = Cl	H	R79 = Cl	H	H
II-18	H	H	H	H	H	H	H	H	R87 = R92 = CH3
II-19	H	H	H	H	H	H	H	H	R87 = R92 = OCH3
II-20	H	H	H	H	H	H	H	H	R87 = R92 = N(C2H5)2
II-21	H	H	H	H	H	H	H	H	R87 = R92 = Cl
II-22	H	H	H	H	H	H	H	H	R90 = R92 = CH3
II-23	H	R57 = CH3	H	R67 = CH3	H	R75 = CH3	H	R85 = CH3	H
II-24	H	R56 = R58 = CH3	H	H	H	R74 = R76 = CH3	H	H	H

[0184]

2559
Com-
pound
No.	Ar1	Ar2	R101˜R104	R105˜R108	R109˜R113	R114˜R118	R119˜R126
III-1	Ph	Ph	H	H	H	H	H
III-2	Ph	Ph	H	H	R110 = CH3	R115 = CH3	H
III-3	Ph	Ph	H	H	R111 = CH3	R116 = CH3	H
III-4	Ph	Ph	H	H	R111 = t-C4H9	R116 = t-C4H9	H
III-5	Ph	Ph	H	H	R111 = OCH3	R116 = OCH3	H
III-6	Ph	Ph	H	H	R111 = Ph	R116 = Ph	H
III-7	Ph	Ph	H	H	2560	2561	H
III-8	Ph	Ph	H	H	R111 = OPh	R116 = OPh	H
III-9	Ph	Ph	H	H	R111 = N(C2H5)2	R116 = N(C2H5)2	H
III-10	Ph	Ph	H	H	R111 = N(Ph)2	R116 = N(Ph)2	H
III-11	Ph	Ph	H	H	R111 = Cl	R116 = Cl	H
III-12	Ph	Ph	R102 = CH3	R106 = CH3	H	H	H
III-13	Ph	Ph	H	H	R111 = CH3	R115 = CH3	H
III-14	Ph	Ph	H	H	R111 = OCH3	R115 = OCH3	H
III-15	Ph	Ph	R102 = OCH3	R106 = OCH3	H	H	H
III-16	Ph	Ph	R102 = Ph	R106 = Ph	H	H	H
III-17	Ph	Ph	R102 = OPh	R106 = OPh	H	H	H
III-18	Ph	Ph	R102 = N(C2H5)2	R106 = N(C2H5)2	H	H	H
III-19	Ph	Ph	R102 = Cl	R106 = Cl	H	H	H
III-20	Ph	Ph	H	H	H	H	R119 = R124 = CH3
III-21	Ph	Ph	H	H	H	H	R119 = R124 = OCH3
III-22	Ph	Ph	H	H	H	H	R119 = R124 = N(C2H5)2
III-23	Ph	Ph	H	H	H	H	R119 = R124 = Cl
III-24	2562	2563	H	H	H	H	H
III-25	2564	2565	H	H	H	H	H
III-26	2566	2567	H	H	H	H	H
III-27	Ph	2568	H	H	H	H	H
III-28	2569	2570	H	H	H	H	H

[0185]

IV-1	2571
IV-2	2572
IV-3	2573
IV-4	2574
IV-5	2575
V-1	2576
V-2	2577
V-3	2578
V-4	2579
V-5	2580
VI-1	2581
VI-2	2582
VI-3	2583
VI-4	2584
	2585
	2586
	R3 = R23	R4 = R24	R13 = R33	R14 = R44
	Ph	H	H	H
	H	Ph	H	H
	Ph	H	Ph	H
	H	Ph	H	Ph
	CH3	H	H	H
	H	CH3	H	H
	CH3	H	CH3	H
	H	CH3	H	CH3

[0186] The above-described host compounds can be synthesized by the method described in Jean Piccard, Herr. Chim. Acta., 7, 789 (1924), Jean Piccard, J. Am. Chem. Soc., 48, 2878 (1926), etc. or similar methods. More particularly, Ullmann reaction is effected by heating in the presence of copper a combination of a di(biphenyl)amine compound with a diiodobiphenyl compound or a combination of a N,N′-diphenylbenzidine compound with a iodobiphenyl compound, selected in accordance with the end compound.

[0187] The host compounds can be identified by mass analysis, infrared (IR) absorption spectroscopy or nuclear magnetic resonance spectroscopy (1H-NMR).

[0188] These compounds have a molecular weight of about 640 to about 800, a high melting point of about 190 to about 300° C., and a high glass transition temperature of about 80 to about 150° C. On conventional vacuum evaporation, they form satisfactory smooth films which are transparent and remain amorphous even above room temperature. The films maintain the stable amorphous state over a long period of time. Accordingly, thin films can be formed from the compounds alone without a need for binder resins.

[0189] Anthracene Compounds

[0190] A further class of organic compounds useful as the host material according to the invention are phenylanthracene derivatives of the following formula (III).

[0191] In the device of the invention, the use of the anthracene derivative of formula (III), preferably as the host material, helps induce strong light emission from the dopant while controlling the interaction with the dopant. Since the anthracene derivatives are fully heat resistant and durable, organic EL devices with a longer lifetime are obtainable.

[0192] In an exemplary organic EL device which was fabricated using an anthracene derivative doped with a dibenzo[f,f′]diindeno[1,2,3-cd:1′,2′,3′-lm]perylene derivative, a luminance of at least 250 cd/m2 was obtained at a current density of 10 mA/cm2 and a drive voltage as low as about 6.5 V. When operated at a current density of about 600 mA/cm2, the device consistently produced a luminance of greater than about 13,000 cd/m2. When operated at a current density of about 50 mA/cm2, the device marked a very long lifetime as demonstrated by a half-life time of more than 300 hours at an initial luminance of at least 2400 cd/cm2.

[0193] In organic EL devices as mentioned above, the dopant concentration ensuring a chromatic purity and maximum efficiency is about 1% by weight although dopant concentrations of about 2 or 3% by weight lead to devices which are practically acceptable albeit a drop of less than about 10%. 2587

[0194] Herein A101 is a monophenylanthryl or diphenylanthryl radical and may be the same or different, L is hydrogen, a single bond or a divalent linkage, and n is an integer of 1 or 2.

[0195] Of the compounds of formula (III), those compounds of the following formulas (III-1) and (III-2) are preferred. 2588

[0196] Evaporated films of these compounds remain in a stable amorphous state, that is, have sufficient physical properties to produce consistent uniform light emission. The films remain stable over one year in the ambient atmosphere without crystallization.

[0197] Referring to formula (III), A101 is a monophenylanthryl or diphenylanthryl radical and may be the same or different, and n is an integer of 1 or 2. The monophenylanthryl or diphenylanthryl radical represented by A101 may be substituted or unsubstituted. Exemplary substituents are alkyl, aryl, alkoxy, aryloxy and amino groups. These substituents may further have substituents thereon and will be described later. The position of a substituent on the monophenylanthryl or diphenylanthryl radical is not critical although the preferred substitution position is on the phenyl group bonded to the anthracene ring rather than the anthracene ring.

[0198] Preferably the phenyl group is bonded to the anthracene ring at the 9- and 10-positions.

[0199] In formula (III), L is hydrogen, a single bond or a divalent linkage. The divalent linkage represented by L is preferably an arylene radical which may be separated by an alkylene or analogous group. The arylene radical will be described later.

[0200] Of the phenylanthracene derivatives of formula (III), those of formulas (III-1) and (III-2) are preferred. Formula (III-1) is described in detail.

[0201] In formula (III-1), M1 and M2 each are alkyl, cycloalkyl, aryl, alkoxy, aryloxy, amino or heterocyclic radicals.

[0202] The alkyl radicals represented by M1 and M2 may be substituted or unsubstituted, straight or branched alkyl radicals, preferably of 1 to 10 carbon atoms, more preferably 1 to 4 carbon atoms. Unsubstituted alkyl radicals of 1 to 4 carbon atoms are preferred, such as, for example, methyl, ethyl, n- and i-propyl, and n-, i-, sec- and tert-butyl.

[0203] Exemplary of the cycloalkyl radicals represented by M1 and M2 are cyclohexyl and cyclopentyl.

[0204] The aryl radicals represented by M1 and M2 are preferably those aryl radicals having 6 to 20 carbon atoms which may have substituents such as phenyl and tolyl. Preferred examples of the aryl radical include phenyl, o-, m- and p-tolyl, pyrenyl, naphthyl, anthryl, biphenyl, phenylanthryl and tolylanthryl.

[0205] The alkenyl radicals represented by M1 and M2 are preferably those having 6 to 50 carbon atoms in total, which may be substituted or unsubstituted, with the substituted ones being preferred. Such substituents are aryl groups such as phenyl. Exemplary alkenyl radicals are triphenylvinyl, tritolylvinyl and tribiphenylvinyl.

[0206] The alkoxy radicals represented by M1 and M2 are preferably those having an alkyl moiety of 1 to 6 carbon atoms, for example, methoxy and ethoxy. The alkoxy radicals may have substituents.

[0207] Exemplary of the aryloxy radicals represented by M1 and M2 is phenoxy.

[0208] The amino radicals represented by M1 and M2 may be substituted or unsubstituted, with the substituted amino radicals being preferred. Such substituents are alkyl groups such as methyl and ethyl and aryl groups such as phenyl. Illustrative examples of the amino radical include diethylamino, diphenylamino and di(m-tolyl)amino radicals.

[0209] The heterocyclic radicals represented by M1 and M2 include bipyridyl, pyrimidyl, quinolyl, pyridyl, thienyl, furyl and oxadiazoyl radicals and may have substituents such as methyl and phenyl.

[0210] In formula (III-1), q1 and q2 each are 0 or an integer of 1 to 5, especially 0 or 1. When q1 and q2 each are an integer of 1 to 5, especially 1 or 2, M1 and M2 each are preferably alkyl, aryl, alkenyl, alkoxy, aryloxy or amino radicals.

[0211] In formula (III-1), M1 and M2 may be the same or different. Where a plurality of M1 or M2 are included, the M1 groups or M2 groups may be the same or different. Alternatively, the M1 groups or M2 groups bond together to form a ring such as a benzene ring. The ring formation is also a preferred embodiment.

[0212] In formula (III-1), L1 is hydrogen, a single bond or an arylene radical. The arylene radicals represented by L1 are preferably unsubstituted ones, for example, ordinary arylene radicals such as phenylene, biphenylene and anthrylene as well as two or more arylene radicals which are directly bonded. L1 is preferably a single bond, p-phenylene or 4,4′-biphenylene.

[0213] The arylene radical represented by L1 may consist of two or more arylene radicals which are connected by an alkylene radical, —O—, —S— or —NR— wherein R is an alkyl or aryl radical. Exemplary alkyl radicals are methyl and ethyl, and an exemplary aryl radical is phenyl. R is preferably an aryl radical, such as phenyl. Alternatively, R is A101 or a phenyl radical having A101 substituted thereon. The alkylene radicals are preferably methylene and ethylene.

[0214] Illustrative examples of the arylene radical are given below. 2589

[0215] Next referring to formula (III-2), M3 and M4 are the same as M1 and M2 in formula (III-1), q3 and q4 are the same as q1 and q2 in formula (III-1), and L2 is the same as L1 in formula (III-1). Preferred examples of these radicals are also the same.

[0216] In formula (III-2), M3 and M4 may be the same or different. Where a plurality of M3 or M4 are included, the M3 groups or M4 groups may be the same or different. Alternatively, the M3 groups or M4 groups bond together to form a ring such as a benzene ring. The ring formation is also a preferred embodiment.

[0217] Illustrative, non-limiting, examples of the compounds of formulas (III-1) and (III-2) are given below. It is noted that general formulas are followed by lists of M's to show illustrative examples by combinations of M11 to M15 and M21 to M25 or combinations of M31 to M35 and M41 to M45.

2590
Compound No.	M11	M12	M13	M14	M15	M21	M22	M23	M24	M25
I-1	H	H	H	H	H	H	H	H	H	H
I-2	CH3	H	H	H	H	CH3	H	H	H	H
I-3	t-C4H9	H	H	H	H	t-C4H9	H	H	H	H
I-4	OCH3	H	H	H	H	OCH3	H	H	H	H
I-5	OPh	H	H	H	H	OPh	H	H	H	H
I-6	N(C2H5)2	H	H	H	H	N(C2H5)2	H	H	H	H
I-7	N(Ph)2	H	H	H	H	N(Ph)2	H	H	H	H
I-8	Ph	H	H	H	H	Ph	H	H	H	H
I-9	2591	H	H	H	H	2592	H	H	H	H
I-10	H	CH3	H	H	H	H	CH3	H	H	H
I-11	H	CH3	H	CH3	H	H	CH3	H	CH3	H
I-12	H	H	CH3	H	H	H	H	CH3	H	H
I-13	H	CH3	H	H	CH3	H	CH3	H	H	CH3
I-14	t-C4H9	H	H	H	H	H	H	H	H	H
I-15	2593	H	H	H	H	2594	H	H	H	H
I-16	H	Ph	H	H	H	H	Ph	H	H	H
I-17	H	H	Ph	H	H	H	H	Ph	H	H
I-18	2595	H	H	H	H	2596	H	H	H	H
I-19	n-C4H9	H	H	H	H	n-C4H9	H	H	H	H
I-20	2597	H	H	H	H	2598	H	H	H	H
I-21	H	H	2599	H	H	H	H	2600	H	H
I-22	2601	H	H	H	H	2602	H	H	H	H
I-23	H	H	2603	H	H	H	H	2604	H	H
I-24	H	H	Ph	H	Ph	H	H	Ph	H	Ph
I-25	H	H	Ph	Ph	H	H	H	Ph	Ph	H

[0218]

2605
Compound No.	M11	M12	M13	M14	M15	M21	M22	M23	M24	M25
II-1	H	H	H	H	H	H	H	H	H	H
II-2	CH3	H	H	H	H	CH3	H	H	H	H
II-3	t-C4H9	H	H	H	H	t-C4H9	H	H	H	H
II-4	OCH3	H	H	H	H	OCH3	H	H	H	H
II-5	OPh	H	H	H	H	OPh	H	H	H	H
II-6	N(C2H5)2	H	H	H	H	N(C2H5)2	H	H	H	H
II-7	N(Ph)2	H	H	H	H	N(Ph)2	H	H	H	H
II-8	Ph	H	H	H	H	Ph	H	H	H	H
II-9	2606	H	H	H	H	2607	H	H	H	H
II-10	H	CH3	H	H	H	H	CH3	H	H	H
II-11	H	H	CH3	H	H	H	CH3	CH3	H	H
II-12	H	H	CH3	CH3	H	H	H	CH3	CH3	H
II-13	H	H	CH3	H	CH3	H	CH3	CH3	H	CH3
II-14	CH3	CH3	CH3	CH3	CH3	CH3	CH3	CH3	CH3	CH3
II-15	t-C4H9	H	H	H	H	H	H	H	H	H
II-16	2608	H	H	H	H	2609	H	H	H	H
II-17	H	Ph	H	H	H	H	Ph	H	H	H
II-18	H	H	Ph	H	H	H	H	Ph	H	H
II-19	H	H	2610	H	H	H	H	2611	H	H
II-20	2612	H	H	H	H	2613	H	H	H	H
II-21	2614	H	H	H	H	2615	H	H	H	H
II-22	H	H	2616	H	H	H	H	2617	H	H
II-23	H	H	Ph	H	Ph	H	H	Ph	H	Ph
II-24	H	H	Ph	Ph	H	H	H	Ph	Ph	H

[0219]

2618
Compound No.	M11	M12	M13	M14	M15	M21	M22	M23	M24	M25
III-1	H	H	H	H	H	H	H	H	H	H
III-2	CH3	H	H	H	H	CH3	H	H	H	H
III-3	t-C4H9	H	H	H	H	t-C4H9	H	H	H	H
III-4	OCH3	H	H	H	H	OCH3	H	H	H	H
III-5	OPh	H	H	H	H	OPh	H	H	H	H
III-6	N(C2H5)2	H	H	H	H	N(C2H5)2	H	H	H	H
III-7	N(Ph)2	H	H	H	H	N(Ph)2	H	H	H	H
III-8	Ph	H	H	H	H	Ph	H	H	H	H
III-9	2619	H	H	H	H	2620	H	H	H	H
III-10	H	CH3	H	H	H	H	CH3	H	H	H
III-11	H	H	CH3	H	H	H	H	CH3	H	H
III-12	H	H	CH3	CH3	H	H	H	CH3	CH3	H
III-13	H	H	CH3	H	CH3	H	H	CH3	H	CH3
III-14	CH3	CH3	CH3	CH3	CH3	CH3	CH3	CH3	CH3	CH3
III-15	H	Ph	H	H	H	H	Ph	H	H	H
III-16	H	H	Ph	H	H	H	H	Ph	H	H
III-17	2621	H	H	H	H	2622	H	H	H	H
III-18	t-C4H9	H	H	H	H	H	H	H	H	H
III-19	2623	H	H	H	H	2624	H	H	H	H
III-20	2625	H	H	H	H	2626	H	H	H	H
III-21	2627	H	H	H	H	2628	H	H	H	H
III-22	2629	H	H	H	H	2630	H	H	H	H
III-23	2631	H	H	H	H	2632	H	H	H	H
III-24	H	H	2633	H	H	H	H	2634	H	H
III-25	2635	H	H	H	H	2636	H	H	H	H
III-26	H	H	2637	H	H	H	H	2638	H	H
III-27	H	H	Ph	H	Ph	H	H	Ph	H	Ph
III-28	H	H	Ph	Ph	H	H	H	Ph	Ph	H

[0220]

2639
Compound No.	M11	M12	M13	M14	M15	M21	M22	M23	M24	M25
IV-1	H	H	H	H	H	H	H	H	H	H
IV-2	CH3	H	H	H	H	CH3	H	H	H	H
IV-3	t-C4H9	H	H	H	H	t-C4H9	H	H	H	H
IV-4	OCH3	H	H	H	H	OCH3	H	H	H	H
IV-5	OPh	H	H	H	H	OPh	H	H	H	H
IV-6	N(C2H5)2	H	H	H	H	N(C2H5)2	H	H	H	H
IV-7	N(Ph)2	H	H	H	H	N(Ph)2	H	H	H	H
IV-8	Ph	H	H	H	H	Ph	H	H	H	H
IV-9	2640	H	H	H	H	2641	H	H	H	H
IV-10	H	CH3	H	H	H	H	CH3	H	H	H
IV-11	H	H	CH3	H	H	H	H	CH3	H	H
IV-12	H	H	CH3	CH3	H	H	H	CH3	CH3	H
IV-13	H	H	CH3	H	CH3	H	H	CH3	H	CH3
IV-14	CH3	CH3	CH3	CH3	CH3	CH3	CH3	CH3	CH3	CH3
IV-15	H	H	H	H	H	H	H	H	H	H
IV-16	H	H	Ph	H	H	H	H	Ph	H	H
IV-17	2642	H	H	H	H	2643	H	H	H	H
IV-18	t-C4H9	H	H	H	H	H	H	H	H	H
IV-19	2644	H	H	H	H	2645	H	H	H	H
IV-20	2646	H	H	H	H	2647	H	H	H	H
IV-21	2648	H	H	H	H	2649	H	H	H	H
IV-22	H	H	2650	H	H	H	H	2651	H	H
IV-23	2652	H	H	H	H	2653	H	H	H	H
IV-24	H	H	2654	H	H	H	H	2655	H	H
IV-25	H	H	Ph	H	Ph	H	H	Ph	H	Ph
IV-26	H	H	Ph	Ph	H	H	H	Ph	Ph	H

[0221]

2656
Compound No.	M31	M32	M33	M34	M35	M41	M42	M43	M44	M45
V-1	H	H	H	H	H	H	H	H	H	H
V-2	CH3	H	H	H	H	CH3	H	H	H	H
V-3	t-C4H9	H	H	H	H	t-C4H9	H	H	H	H
V-4	OCH3	H	H	H	H	OCH3	H	H	H	H
V-5	OPh	H	H	H	H	OPh	H	H	H	H
V-6	N(C2H5)2	H	H	H	H	N(C2H5)2	H	H	H	H
V-7	N(Ph)2	H	H	H	H	N(Ph)2	H	H	H	H
V-8	Ph	H	H	H	H	Ph	H	H	H	H
V-9	2657	H	H	H	H	2658	H	H	H	H
V-10	H	CH3	H	H	H	H	CH3	H	H	H
V-11	H	H	CH3	H	H	H	H	CH3	H	H
V-12	H	H	CH3	CH3	H	H	H	CH3	CH3	H
V-13	H	H	CH3	H	CH3	H	H	CH3	H	CH3
V-14	CH3	CH3	CH3	CH3	CH3	CH3	CH3	CH3	CH3	CH3
V-15	H	Ph	H	H	H	H	Ph	H	H	H
V-16	H	H	Ph	H	H	H	H	Ph	H	H
V-17	2659	H	H	H	H	2660	H	H	H	H
V-18	t-C4H9	H	H	H	H	t-C4H9	H	H	H	H
V-19	2661	H	H	H	H	2662	H	H	H	H
V-20	2663	H	H	H	H	2664	H	H	H	H
V-21	2665	H	H	H	H	2666	H	H	H	H
V-22	2667	H	H	H	H	2668	H	H	H	H
V-23	2669	H	H	H	H	2670	H	H	H	H
V-24	2671	H	H	H	H	2672	H	H	H	H
V-25	H	H	2673	H	H	H	H	2674	H	H
V-26	2675	H	H	H	H	2676	H	H	H	H
V-27	H	H	2677	H	H	H	H	2678	H	H
V-28	H	H	Ph	H	Ph	H	H	Ph	H	Ph
V-29	H	H	Ph	Ph	H	H	H	Ph	Ph	H

[0222]

2679
Compound No.	M31	M32	M33	M34	M35	M41	M42	M43	M44	M45
VI-1	H	H	H	H	H	H	H	H	H	H
VI-2	CH3	H	H	H	H	CH3	H	H	H	H
VI-3	t-C4H9	H	H	H	H	t-C4H9	H	H	H	H
VI-4	OCH3	H	H	H	H	OCH3	H	H	H	H
VI-5	OPh	H	H	H	H	OPh	H	H	H	H
VI-6	N(C2H5)2	H	H	H	H	N(C2H5)2	H	H	H	H
VI-7	N(Ph)2	H	H	H	H	N(Ph)2	H	H	H	H
VI-8	Ph	H	H	H	H	Ph	H	H	H	H
VI-9	2680	H	H	H	H	2681	H	H	H	H
VI-10	H	CH3	H	H	H	H	CH3	H	H	H
VI-11	H	H	CH3	H	H	H	H	CH3	H	H
VI-12	H	H	CH3	CH3	H	H	H	CH3	CH3	H
VI-13	H	H	CH3	H	CH3	H	H	CH3	H	CH3
VI-14	CH3	CH3	CH3	CH3	CH3	CH3	CH3	CH3	CH3	CH3
VI-15	H	Ph	H	H	H	H	Ph	H	H	H
VI-16	H	H	Ph	H	H	H	H	Ph	H	H
VI-17	2682	H	H	H	H	2683	H	H	H	H
VI-18	t-C4H9	H	H	H	H	H	H	H	H	H
VI-19	2684	H	H	H	H	2685	H	H	H	H
VI-20	2686	H	H	H	H	2687	H	H	H	H
VI-21	2688	H	H	H	H	H	H	H	H	H
VI-22	2689	H	H	H	H	CH3	H	H	H	H
VI-23	2690	H	H	H	H	2691	H	H	H	H
VI-24	2692	H	H	H	H	2693	H	H	H	H
VI-25	H	H	Ph	H	Ph	H	H	Ph	H	Ph
VI-26	H	H	Ph	Ph	H	H	H	Ph	Ph	H
VI-27	H	H	2694	H	H	H	H	2695	H	H
VI-28	H	H	2696	H	H	H	H	2697	H	H

[0223]

2698
Compound No.	M31	M32	M33	M34	M35	M41	M42	M43	M44	M45
VII-1	H	H	H	H	H	H	H	H	H	H
VII-2	CH3	H	H	H	H	CH3	H	H	H	H
VII-3	t-C4H9	H	H	H	H	t-C4H9	H	H	H	H
VII-4	OCH3	H	H	H	H	OCH3	H	H	H	H
VII-5	OPh	H	H	H	H	OPh	H	H	H	H
VII-6	N(C2H5)2	H	H	H	H	N(C2H5)2	H	H	H	H
VII-7	N(Ph)2	H	H	H	H	N(Ph)2	H	H	H	H
VII-8	Ph	H	H	H	H	Ph	H	H	H	H
VII-9	2699	H	H	H	H	2700	H	H	H	H
VII-10	H	H	CH3	CH3	H	H	H	CH3	CH3	H
VII-11	H	H	CH3	H	CH3	H	H	CH3	H	CH3
VII-12	H	CH3	H	H	H	H	CH3	H	H	H
VII-13	H	H	CH3	H	H	H	H	CH3	H	H
VII-14	CH3	CH3	CH3	CH3	CH3	CH3	CH3	CH3	CH3	CH3
VII-15	H	H	Ph	H	Ph	H	H	Ph	H	Ph
VII-16	H	H	Ph	Ph	H	H	H	Ph	Ph	H
VII-17	H	H	2701	H	H	H	H	2702	H	H
VII-18	H	H	2703	H	H	H	H	2704	H	H
VII-19	H	Ph	H	H	H	H	Ph	H	H	H
VII-20	H	H	Ph	H	H	H	H	Ph	H	H
VII-21	2705	H	H	H	H	2706	H	H	H	H
VII-22	t-C4H9	H	H	H	H	H	H	H	H	H
VII-23	2707	H	H	H	H	2708	H	H	H	H
VII-24	2709	H	H	H	H	2710	H	H	H	H
VII-25	2711	H	H	H	H	2712	H	H	H	H
VII-26	2713	H	H	H	H	2714	H	H	H	H
VII-27	2715	H	H	H	H	2716	H	H	H	H
VII-28	n-C4H9	H	H	H	H	n-C4H9	H	H	H	H
VII-29	H	H	OCH3	H	H	H	H	OCH3	H	H
VII-30	H	R32 and R33	H	H	H	R32 and R33	H	H
		form a fused				form a fused
		benzene ring.				benzene ring.
VII-31	2717	H	H	H	H	2718	H	H	H	H
VII-32	2719	H	H	H	H	2720	H	H	H	H
VII-33	H	H	2721	H	H	H	H	2722	H	H
VII-34	2723	H	H	H	H	2724	H	H	H	H
VII-35	H	H	2725	H	H	H	H	2726	H	H
VII-36	H	H	Ph	H	Ph	H	H	Ph	H	Ph
VII-37	H	H	Ph	Ph	H	H	H	Ph	Ph	H

[0224]

2727
Compound
No.	M11═M21	M12═M22	M13═M23	M14═M24	M15═M25
VIII′-1	H	H	H	H	H
VIII′-2	CH3	H	H	H	H
VIII′-3	H	CH3	H	H	H
VIII′-4	H	H	CH3	H	H
VIII′-5	Ph	H	CH3	CH3	H
VIII′-6	H	Ph	H	H	H
VIII′-7	H	H	Ph	H	H
VIII′-8	H	H	Ph	Ph	H
VIII′-9	H	H	Ph	H	Ph
VIII′-10	H	H	2728	H	H
VIII′-11	2729	H	H	H	H
VIII′-12	H	H	2730	H	H
VIII′-13	2731	H	H	H	H
VIII′-14	N(Ph)2	H	H	H	H
VIII′-15	N(C2H5)2	H	H	H	H
VIII′-16	OCH3	H	H	H	H
VIII′-17	Oph	H	H	H	H
VIII′-18	2732	H	H	H	H
VIII′-19	2733	H	H	H	H

[0225] 2734

[0226] The phenylanthracene derivatives used herein can be prepared by coupling a halogenated diphenylanthracene compound with Ni(cod)2 wherein cod represents 1,5-cyclooctadiene, or cross-coupling a Grignard reagent of a dihalogenated aryl with a nickel complex such as NiCl2(dppe) or NiCl2(dppp) wherein dppe represents diphenylphosphinoethane and dppp represents diphenylphosphinopropane. Alternatively, the phenylanthracene derivatives are prepared by a cross-coupling process involving reacting anthraquinone, benzoquinone, phenylanthrone or bianthrone with a Grignard reagent of aryl or a lithiated aryl followed by reduction.

[0227] These compounds can be identified by elemental analysis, mass analysis, IR spectroscopy, 1H and 13C NMR, etc.

[0228] In general, the phenylanthracene derivatives have a molecular weight of about 400 to about 2,000, preferably about 400 to about 1,000, a high melting point of about 200 to about 500° C., and a high glass transition temperature (Tg) of about 80 to about 250° C., preferably about 100 to 250° C., more preferably about 130 to 250° C., especially about 150 to 250° C. By conventional vacuum deposition or the like, they form a transparent, smooth film of quality which maintains a stable amorphous state even above room temperature and over a long period of time.

[0229] Since the phenylanthracene derivatives are relatively neutral compounds, better results are obtained on use of them in a light emitting layer. A freedom of design of the recombination/light emitting region is available by controlling the film thickness in consideration of the carrier mobility and carrier density (which is dependent on ionization potential and electron affinity) of the light emitting layer, hole injecting and transporting layer, and electron injecting and transporting layer to be combined. This enables free design of luminous color, control of the luminance and spectrum of light emission by the interference of the electrodes, and control of the space distribution of light emission.

[0230] Quinoxaline Compounds

[0231] A still further class of organic compounds useful as the host material according to the invention are quinoxaline compounds of the following formula (IV).

Qn-L101  (IV)

[0232] Herein Q is a pyrazinyl radical having fused thereto a six-membered aromatic ring containing 0 to 2 nitrogen atoms and may be the same or different, and n is 2 or 3. Two or three Q radicals may be the same or different. The six-membered aromatic rings forming part of Q are preferably benzene, pyridine, pyrimidine and pyridazine rings. Such a six-membered aromatic ring may be fused to the pyrazine ring at any positions although it is preferred that carbon atoms be present and nitrogen atoms be absent at the fusion positions. It is therefore preferred that fusion be on the side between the 2 and 3-positions or 5 and 6-positions on the pyrazine ring, and on the side between the 2 and 3-positions (or 5 and 6-positions) or the side between the 3 and 4-positions (or 4 and 5-positions) on the pyridine ring, on the side between the 4 and 5-positions (or 5 and 6-positions) on the pyrimidine ring, and on the side between the 3 and 4-positions (or 5 and 6-positions) or the side between the 5 and 4-positions on the pyridazine ring.

[0233] L101 is a single bond or n-valent radical, i.e., di- or trivalent radical. Preferred divalent radicals are arenediyl radicals, such as phenylene, biphenyldiyl, naphthalenediyl, anthracenediyl and pyrenediyl. Preferred trivalent radicals are arenetriyl radicals (e.g., benzenetriyl), nitrogen atoms, and triarylaminetriyl radicals (e.g., triphenylaminetriyl).

[0234] The radicals represented by Q and L101 may further have substituents. Such substituents may be ones containing Q therein. The total number of Q radicals per molecule should preferably be 2 to 10, more preferably 2 to 4. Two or more Q radicals included in one molecule may be the same or different although they are often the same for the sake of easy synthesis.

[0235] Of the quinoxaline compounds of formula (IV), those of formula (VIII) are preferred. 2735

[0236] In formula (VIII), Z is a group of atoms necessary to form a benzene, pyridine, pyrimidine or pyridazine ring with the two carbon atoms of the pyrazine ring.

[0237] The ring completed by Z may further have a substituent(s) or a fused ring. The preferred positions of fusion of the ring completed by Z to the pyrazine ring are the same as described above in conjunction with formula (IV).

[0238] A is a monovalent substituent attached to the pyrazine ring, and k is 0, 1 or 2. Preferred examples of the substituents on the ring completed by Z and the substituents represented by A are the same as A13 etc. in formulas (VIII-a) to (VIII-m) to be described later and will be described later.

[0239] The letter n is 2 or 3. When n is 2, L101 is a single bond, phenylene, biphenyldiyl or naphthalenediyl radical. When n is 3, L101 is a benzenetriyl radical, nitrogen atom or triphenylaminetriyl radical. These radicals will be described later in conjunction with formulas (VIII-a) to (VIII-m).

[0240] The rings completed by Z may be the same or different although they are preferably the same as described in conjunction with formula (IV).

[0241] The fused pyrazine ring having the ring completed by Z may be bonded, at any position, to L101.

[0242] Of the quinoxaline compounds of formula (VIII), those of formulas (VIII-a) to (VIII-m) are preferred. 2736

[0243] First described are those compounds wherein L101 in formula (VIII) is a divalent radical L111 or single bond, as represented by formulas (VIII-a) to (VIII-f) and (VIII-m).

[0244] In formulas (VIII-a) to (VIII-f) and (VIII-m), L111 is a phenylene, biphenyldiyl or naphthalenediyl radical. The phenylene radical represented by L111 may be an o-, m- or p-phenylene radical, with the p-phenylene being especially preferred. The preferred biphenyldiyl radical represented by L111 is 4,4′-biphenyl-1,1′-diyl. The preferred naphthalenediyl radical represented by L111 is 1,5-naphthalenediyl. These divalent radicals are preferably unsubstituted although they may have substituents such as alkyl and aryl groups.

[0245] A13, A15 to A18, A23, A25 to A28 in formula (VIII-a), A13, A16 to A18, A23, A26 to A28 in formula (VIII-b), A13, A15, A17, A18, A23, A25, A27 and A28 in formula (VIII-c), A13, A16, A18, A23, A26 and A28 in formula (VIII-d), A13, A17, A18, A23, A27 and A28 in formula (VIII-e), A13, A15, A18, A23, A25 and A28 in formula (VIII-f), A12, A13, A15, A17, A18, A22, A23, A25, A27 and A28 in formula (VIII-m) each independently stand for hydrogen, halogen atoms, hydroxyl, carboxy, nitro, cyano, alkyl, aryl, alkoxy, aryloxy, amino, alkylthio, arylthio and heterocyclic radicals. In each formula, these radicals may be the same or different.

[0246] Examples of the halogen atoms represented by A13 etc. include fluorine and chlorine atoms.

[0247] The alkyl radicals represented by A13 etc. are preferably those of 1 to 6 carbon atoms in total, which may be straight or branched. The alkyl radicals are preferably unsubstituted ones although they may have substituents such as halogen atoms (e.g., F and Cl). Illustrative examples of the alkyl radicals include methyl, ethyl, n-propyl, isopropyl, n-butyl, isobutyl, sec-butyl, t-butyl, pentyl and hexyl.

[0248] The aryl radicals represented by A13 etc. are preferably those of 6 to 30 carbon atoms in total, which may be monocyclic or polycyclic (fused ring or ring collection) or have substituents. Such substituents are halogen atoms (e.g., F and Cl), alkyl groups (e.g., methyl) and heterocyclic groups. The heterocyclic groups as the substituent are preferably the same as the fused pyrazinyl radical bonded to L111 in formula (VIII-a), such as quinoxalinyl. Illustrative examples of the aryl radicals represented by A13, etc. include phenyl, 1-naphthyl, 2-naphthyl, 2-biphenylyl, 3-biphenylyl, and 4-biphenylyl radicals, which may have substituted thereon a fused pyradinyl group such as quinoxalinyl.

[0249] The alkoxy radicals represented by A13, etc. are preferably those of alkyls of 1 to 6 carbon atoms in total. The alkoxy radicals are preferably unsubstituted ones although they may have substituents. Illustrative examples of the alkoxy radicals include methoxy, ethoxy, propoxy, isopropoxy, butoxy, isobutoxy, sec-butoxy and t-butoxy.

[0250] Exemplary of the aryloxy radicals represented by A13, etc. is phenoxy.

[0251] The amino radicals represented by A13, etc. may have substituents such as alkyl and aryl groups. Exemplary amino radicals are amino, methylamino, dimethylamino, phenylamino and diphenylamino.

[0252] Examples of the alkylthio radical represented by A13, etc. include methylthio and ethylthio.

[0253] Exemplary of the arylthio radical represented by A13, etc. is phenylthio.

[0254] Examples of the heterocyclic radicals represented by A13, etc. include furyl, thienyl, pyrrole, pyridyl, and quinolyl as well as the same as the fused pyradinyl radical bonded to L111 in formula (VIII-a) such as quinoxalinyl.

[0255] Two adjoining ones among A15 to A18 and A25 to A28 in formula (VIII-a), two adjoining ones among A16 to A18 and A26 to A28 in formula (VIII-b), a pair of A17 and A18 or a pair of A27 and A28 in formula (VIII-c), a pair of A17 and A18 or a pair of A27 and A28 in formula (VIII-e), and a pair of A12 and A13, a pair of A17 and A18, a pair of A22 and A23 or a pair of A27 and A28 in formula (VIII-m) may bond together to form a ring. The ring formed herein is preferably a benzene ring. Two or more benzene rings thus formed may be fused together, or the benzene ring thus formed may further have a ring fused thereto.

[0256] In preferred embodiments, A13 and A23 in formulas (VIII-a) to (VIII-f) and A12, A13, A22 and A23 in formula (VIII-m) are aryl radicals; A15 to A18 and A25 to A28 in formula (VIII-a) are hydrogen, alkyl or alkoxy radicals or two adjoining ones thereof bond together to form a benzene ring; and A16 to A18 and A26 to A28 in formula (VIII-b), A15, A17, A18, A25, A27 and A28 in formula (VIII-c), A16, A18, A26 and A28 in formula (VIII-d), A17, A18, A27 and A28 in formula (VIII-e), A15, A18, A25 and A28 in formula (VIII-f), and A15, A17, A18, A25, A27 and A28 in formula (VIII-m) are hydrogen.

[0257] Described next are those compounds wherein L101 in formula (VIII) is a trivalent radical L112, as represented by formulas (VIII-g) to (VIII-l).

[0258] In formulas (VIII-g) to (VIII-l), L112 is a benzenetriyl radical, nitrogen atom or triphenylaminetriyl radical. The preferred benzenetriyl radical represented by L112 is 1,3,5-benzenetriyl. The preferred triphenylaminetriyl radical represented by L112 is 4,4′,4″-triphenyl-1,1′,1″-triyl. These trivalent radicals are preferably unsubstituted although they may have substituents such as alkyl and aryl groups.

[0259] A13, A15 to A18, A23, A25 to A28, A33, A35 to A38 in formula (VIII-g), A13, A16 to A18, A23, A26 to A28, A33, A36 to A38 in formula (VIII-h), A13, A15, A17, A18, A23, A25, A27, A28, A33, A35, A37 and A38 in formula (VIII-i), A13, A16, A18, A23, A26, A28, A33, A36 and A38 in formula (VIII-j), A13, A17, A18, A23, A27, A28, A33, A37 and A38 in formula (VIII-k), A13, A15, A18, A23, A25 A28, A33, A35 and A38 in formula (VIII-l) each independently stand for hydrogen, halogen atoms, hydroxyl, carboxy, nitro, cyano, alkyl, aryl, alkoxy, aryloxy, amino, alkylthio, arylthio and heterocyclic radicals. In each formula, these radicals may be the same or different. Illustrative examples of these radicals are the same as described above in conjunction with formulas (VIII-a) to (VIII-f).

[0260] Two adjoining ones among A15 to A18, A25 to A28 and A35 to A38 in formula (VIII-g), two adjoining ones among A16 to A18, A26 to A28 and A36 to A38 in formula (VIII-h), a pair of A17 and A18 or a pair of A27 and A28, or a pair of A37 and A38 in formula (VIII-i), and a pair of A17 and A18, a pair of A27 and A28 or a pair of A37 and A38 in formula (VIII-k) may bond together to form a ring. Illustrative examples of the ring are the same as described above in conjunction with formulas (VIII-a) to (VIII-f). A13, A23 and A33 in formulas (VIII-a) to (VIII-l) are preferably hydrogen and aryl radicals such as phenyl.

[0261] In preferred embodiments, A15 to A18, A25 to A28 and A35 to A38 in formula (VIII-g) are hydrogen, or two adjoining ones among them bond together to form a ring; A16 to A18, A26 to A28, and A36 to A38 in formula (VIII-h), A15, A17, A18, A25, A27, A28, A35, A37 and A38 in formula (VIII-i), A16, A18, A26, A28, A36 and A38 in formula (VIII-j), A17, A18, A27, A28, A37 and A38 in formula (VIII-k), A15, A18, A25 A28, A35 and A38 in formula (VIII-l) are hydrogen.

[0262] Illustrative, non-limiting, examples of the quinoxaline compounds of formula (IV) are given below. They are shown by combinations of L111, L112, and A's in formulas (VIII-a) to (VIII-m). When A13 and A23 are different, they are individually shown. The expressions of formulas (VIII-a) to (VIII-m) are typical examples and to be construed to encompass corresponding structural isomers because an actual product as synthesized is a mixture of structural isomers due to the synthesis route.

Formula (VIII)
Compound No.	L111	A13═A23	A15═A15	A16═A26	A17═A27	A18═A28
VIII-a-1	2737	—Ph	H	H	H	H
VIII-a-2	2738	—Ph	H	H	CH3	H
VIII-a-3	2739	—Ph	H	CH3	CH3	H
VIII-a-4	2740	—Ph	H	H	C2H5	H
VIII-a-5	2741	—Ph	H	H	n-C3H7	H
VIII-a-6	2742	—Ph	H	H	n-C4H9	H
VIII-a-7	2743	—Ph	H	H	t-C4H9	H
VIII-a-8	2744	—Ph	H	H	—OCH3	H
VIII-a-9	2745	—Ph	H	H	A17 and A18 form a benzene ring. A27 A28 form a benzene ring
VIII-a-10	2746	—Ph	H	A16 and A17 form a benzene ring. A26 and A27 form a benzene ring.	H
VIII-a-11	2747	—Ph	A15 and A16 form a benzene ring. A25 and A26 form a benzene ring	A17 and A18 form a benzene ring. A27 and A28 form a benzene ring.
VIII-a-12	2748	—Ph	H	A16 and A18, and A17 and A18 form benzene rings, respectively, which are fused to form a phenalene ring as a whole. (The same applies to A26 to A28.)
VIII-a-13	2749	—Ph	A15 and A16, A16 and A17, and A17 and A18 form benzene rings, respectively, which form a phenanthrene ring as a whole. (The same applies to A25 to A28.)
VIII-a-14	2750	—Ph	H	H	—Ph	H
VIII-a-15	2751	—Ph	H	—Ph	—Ph	H
VIII-a-16	2752	—Ph	—Ph	H	H	—Ph
VIII-a-17	2753	—Ph	H	H	1-naphthyl	H
VIII-a-18	2754	—Ph	H	H	2-naphthyl	H
VIII-a-19	2755	—Ph	H	H	4-biphenylyl	H
VIII-a-20	2756	—Ph	H	H	3-biphenylyl	H
VIII-a-21	2757	—Ph	H	H	2-biphenylyl	H
VIII-a-22	2758	—Ph	H	4-biphenylyl	4-biphenylyl	H
VIII-a-23	2759	—Ph	H	H	Cl	H
VIII-a-24	2760	—Ph	H	H	—OH	H
VIII-a-25	2761	—Ph	H	H	—NO2	H
VIII-a-26	2762	—Ph	H	H	—CN	H
VIII-a-27	2763	—Ph	H	H	—OPh	H
VIII-a-28	2764	—Ph	H	H	—SCH3	H
VIII-a-29	2765	—Ph	H	H	—SPh	H
VIII-a-30	2766	—Ph	H	H	H	H
VIII-a-31	2767	—Ph	H	H	CH3	H
VIII-a-32	2768	—Ph	H	CH3	CH3	H
VIII-a-33	2769	—Ph	CH3	H	H	CH3
VIII-a-34	2770	—Ph	H	H	C2H5	H
VIII-a-35	2771	—Ph	H	H	n-C3H7	H
VIII-a-36	2772	—Ph	H	H	n-C4H9	H
VIII-a-37	2773	—Ph	H	H	t-C4H9	H
VIII-a-38	2774	—Ph	H	H	—OCH3	H
VIII-a-39	2775	—Ph	H	H	A17 and A18 form a benzene ring. A27 and A28 form a benzene ring.
VIII-a-40	2776	—Ph	H	A16 and A17 form a benzene ring. A26 and A27 form a benzene ring	H
VIII-a-41	2777	—Ph	A15 and A16 form a benzene ring. A25 and A26 form a benzen ring.	A17 and A18 form a benzene ring. A27 and A28 form a benzene ring.
VIII-a-42	2778	—Ph	H	A16 and A18 +L, and A17 and A18 form benzene rings, respectively, which are fused to form a phenalene ring as a whole. (The same applies to A26 to A28 .)
VIII-a-43	2779	—Ph	A15 and A16 +L, A16 and A17 , and A17 and A18 form benzene rings, respectively, which form a phenanthrene ring as a whole. (The same applies to A25 to A28 .)
VIII-a-44	2780	—Ph	H	H	—Ph	H
VIII-a-45	2781	—Ph	H	—Ph	—Ph	H
VIII-a-46	2782	—Ph	—Ph	H	H	—Ph
VIII-a-47	2783	—Ph	H	H	1-naphthyl	H
VIII-a-48	2784	—Ph	H	H	2-naphthyl	H
VIII-a-49	2785	—Ph	H	H	4-biphenylyl	H
VIII-a-50	2786	—Ph	H	H	3-biphenylyl	H
VIII-a-51	2787	—Ph	H	H	2-biphenylyl	H
VIII-a-52	2788	—Ph	H	H	Cl	H
VIII-a-53	2789	—Ph	H	H	—OH	H
VIII-a-54	2790	—Ph	H	H	—NO2	H
VIII-a-55	2791	—Ph	H	H	—CN	H
VIII-a-56	2792	—Ph	H	H	—OPh	H
VIII-a-57	2793	—Ph	H	H	—SCH3	H
VIII-a-58	2794	—Ph	H	H	—SPh	H
VIII-a-59	2795	—Ph	H	H	H	H
VIII-a-60	2796	—Ph	H	H	CH3	H
VIII-a-61	2797	—Ph	H	CH3	CH3	H
VIII-a-62	2798	—Ph	CH3	H	H	CH3
VIII-a-63	2799	—Ph	CH3	CH3	CH3	H
VIII-a-64	2800	—Ph	CH3	CH3	CH3	CH3
VIII-a-65	2801	—Ph	H	H	C2H5	H
VIII-a-66	2802	—Ph	H	H	n-C3H7	H
VIII-a-67	2803	—Ph	H	H	n-C4H9	H
VIII-a-68	2804	—Ph	H	H	t-C4H9	H
VIII-a-69	2805	—Ph	H	H	—OCH3	H
VIII-a-70	2806	—Ph	H	H	A17 and A18 form a benzene ring. A27 and A28 form a benzene ring.
VIII-a-71	2807	—Ph	H	A16 and A17 form a benzene ring. A26 and A27 form a benzene ring.	H
VIII-a-72	2808	—Ph	A15 and A16 form a benzene ring. A25 and A26 form a benzene ring.	A17 and A18 form a benzene ring. A27 and A28 form a benzene ring
VIII-a-73	2809	—Ph	H	A16 and A18 +L, and A17 and A16 form benzene rings, respectively, which are fused to form a phenalene ring as a whole. (The same applies to A26 to A26 .)
VIII-a-74	2810	—Ph	A15 and A16 +L, A16 and A17 , and A17 and A18 form benzene rings, respectively, which form a phenanthrene ring as a whole. (The same applies to A25 to A28 .)
VIII-a-75	2811	—Ph	H	H	—Ph	H
VIII-a-76	2812	—Ph	H	—Ph	—Ph	H
VIII-a-77	2813	—Ph	—Ph	H	H	—Ph
VIII-a-78	2814	—Ph	H	H	1-naphthyl	H
VIII-a-79	2815	—Ph	H	H	2-naphthyl	H
VIII-a-80	2816	—Ph	H	H	4-biphenylyl	H
VIII-a-81	2817	—Ph	H	H	3-biphenylyl	H
VIII-a-82	2818	—Ph	H	H	2-biphenylyl	H
VIII-a-83	2819	—Ph	H	H	Cl	H
VIII-a-84	2820	—Ph	H	H	—OH	H
VIII-a-85	2821	—Ph	H	H	—NO2	H
VIII-a-86	2822	—Ph	H	H	—CN	H
VIII-a-87	2823	—Ph	H	H	—OPh	H
VIII-a-88	2824	—Ph	H	H	—SCH3	H
VIII-a-89	2825	—Ph	H	H	—SPh	H
VIII-a-90	2826	2827	H	H	H	H
VIII-a-91	2828	2829A23 = —Ph	A15 and A16 form a benzene ring. A25 and A26 form a benzen ring.	H	H
VIII-a-92	2830	2831	A15 and A16 form a benzene ring. A25 and A26 form a benzene ring.	A17 and A18 form a benzene ring. A27 and A28 form a benzene ring.
		A23 = —Ph
VIII-a-93	2832	2833	H	H	H	H
		A23 = —Ph
VIII-a-94	2834	2835	A15 and A16 form a benzene ring. A25 and A26 form a benzene ring.	H	H
		A23 = —Ph
VIII-a-95	2836	2837	A15 and A16 form a benzene ring. A25 and A26 form a benzene ring.	A17 and A18 form a benzene ring. A27 and A28 form a benzene ring.
		A23 = —Ph
VIII-a-96	2838	—Ph	H	H	—NPh2	H
VIII-a-97	2839	—Ph	H	H	—COOH	H
VIII-a-98	2840	—Ph	H	H	2-pyridyl	H
VIII-a-99	2841	—Ph	H	H	—NPh2	H
VIII-a-100	2842	—Ph	H	H	—COOH	H
VIII-a-101	2843	—Ph	H	H	2-pyridyl	H
VIII-a-102	2844	—Ph	H	H	—NPh2	H
VIII-a-103	2845	—Ph	H	H	—COOH	H
VIII-a-104	2846	—Ph	H	H	2-pyridyl	H
Formula (VIII)
Compound No.	L111	A13 ═A23	A16═A26	A17═A27	A18═A28
VIII-b-1	2847	—Ph	H	H	H
VIII-b-2	2848	—Ph	H	H	H
VIII-b-3	2849	—Ph	H	H	H
VIII-b-4	2850	2851	H	H	H
		A23 = —Ph
VIII-b-5	2852	2853	H	H	H
		A23 = —Ph
VIII-b-6	2854	—Ph	H	H	CH3
VIII-b-7	2855	—Ph	H	CH3	H
VIII-b-8	2856	—Ph	CH3	H	H
VIII-b-9	2857	—Ph	H	C2H5	H
VIII-b-10	2858	—Ph	H	n-C3H7	H
VIII-b-11	2859	—Ph	H	n-C4H9	H
VIII-b-12	2860	—Ph	H	t-C4H9	H
VIII-b-13	2861	—Ph	H	—OCH3	H
VIII-b-14	2862	—Ph	A16 and A17 form a benzene ring. A26 and A27 form a benzene ring.	H
VIII-b-15	2863	—Ph	H	A17 and A18 form a benzene ring. Ahd 27 and A28 form a benzene ring.
VIII-b-16	2864	—Ph	H	Ph	H
VIII-b-17	2865	—Ph	Ph	Ph	H
VIII-b-18	2866	—Ph	H	1-naphthyl	H
VIII-b-19	2867	—Ph	1-naphthyl	1-naphthyl	H
VIII-b-20	2868	—Ph	H	2-naphthyl	H
VIII-b-21	2869	—Ph	2-naphthyl	2-naphthyl	H
VIII-b-22	2870	—Ph	H	4-biphenylyl	H
VIII-b-23	2871	—Ph	4-biphenylyl	4-biphenylyl	H
VIII-b-24	2872	—Ph	H	3-biphenylyl	H
VIII-b-25	2873	—Ph	3-biphenylyl	3-biphenylyl	H
VIII-b-26	2874	—Ph	H	2-biphenylyl	H
VIII-b-27	2875	—Ph	2-biphenylyl	2-biphenylyl	H
VIII-b-28	2876	—Ph	H	Cl	H
VIII-b-29	2877	—Ph	H	—OH	H
VIII-b-30	2878	—Ph	H	—NO2	H
VIII-b-31	2879	—Ph	H	—CN	H
VIII-b-32	2880	—Ph	H	—OPh	H
VIII-b-33	2881	—Ph	H	—SCH3	H
VIII-b-34	2882	—Ph	H	—SPh	H
VIII-b-35	2883	—Ph	H	—NPh2	H
VIII-b-36	2884	—Ph	H	—COOH	H
VIII-b-37	2885	—Ph	H	2-pyridyl	H
VIII-b-38	2886	—Ph	H	H	CH3
VIII-b-39	2887	—Ph	H	CH3	H
VIII-b-40	2888	—Ph	CH3	H	H
VIII-b-41	2889	—Ph	H	C2H5	H
VIII-b-42	2890	—Ph	H	n-C3H7	H
VIII-b-43	2891	—Ph	H	n-C4H9	H
VIII-b-44	2892	—Ph	H	t-C4H9	H
VIII-b-45	2893	—Ph	H	—OCH3	H
VIII-b-46	2894	—Ph	A16 and A17 form a benzene ring. A26 and A27 form a benzene ring.	H
VIII-b-47	2895	—Ph	H	A17 and A18 form a benzene ring. A27 and A28 form a benzene ring.
VIII-b-48	2896	—Ph	H	Ph	H
VIII-b-49	2897	—Ph	Ph	Ph	H
VIII-b-50	2898	—Ph	H	1-naphthyl	H
VIII-b-51	2899	—Ph	1-naphthyl	1-naphthyl	H
VIII-b-52	2900	—Ph	H	2-naphthyl	H
VIII-b-53	2901	—Ph	2-naphthyl	2-naphthyl	H
VIII-b-54	2902	—Ph	H	4-biphenylyl	H
VIII-b-55	2903	—Ph	4-biphenylyl	4-biphenylyl	H
VIII-b-56	2904	—Ph	H	3-biphenylyl	H
VIII-b-57	2905	—Ph	3-biphenylyl	3-biphenylyl	H
VIII-b-58	2906	—Ph	H	2-biphenylyl	H
VIII-b-59	2907	—Ph	2-biphenylyl	2-biphenylyl	H
VIII-b-60	2908	—Ph	H	Cl	H
VIII-b-61	2909	—Ph	H	—OH	H
VIII-b-62	2910	—Ph	H	—NO2	H
VIII-b-63	2911	—Ph	H	—CN	H
VIII-b-64	2912	—Ph	H	—OPh	H
VIII-b-65	2913	—Ph	H	—SCH3	H
VIII-b-66	2914	—Ph	H	—SPh	H
VIII-b-67	2915	—Ph	H	—NPh2	H
VIII-b-68	2916	—Ph	H	—COOH	H
VIII-b-69	2917	—Ph	H	2-pyridyl	H
VIII-b-70	2918	—Ph	H	H	CH3
VIII-b-71	2919	—Ph	H	CH3	H
VIII-b-72	2920	—Ph	CH3	H	H
VIII-b-73	2921	—Ph	H	C2H5	H
VIII-b-74	2922	—Ph	H	n-C3H7	H
VIII-b-75	2923	—Ph	H	n-C4H9	H
VIII-b-76	2924	—Ph	H	H	t-C4H9
VIII-b-77	2925	—Ph	H	t-C4H9	H
VIII-b-78	2926	—Ph	H	—OCH3	H
VIII-b-79	2927	—Ph	A16 and A17 form a benzene ring. A26 and A27 form a benzene ring.	H
VIII-b-80	2928	—Ph	H	A17 and A18 form a benzene ring. A27 and A28 form a benzene ring.
VIII-b-81	2929	—Ph	H	—Ph	H
VIII-b-82	2930	—Ph	Ph	Ph	H
VIII-b-83	2931	—Ph	H	1-naphthyl	H
VIII-b-84	2932	—Ph	1-naphthyl	1-naphthyl	H
VIII-b-85	2933	—Ph	H	2-naphthyl	H
VIII-b-86	2934	—Ph	2-naphthyl	2-naphthyl	H
VIII-b-87	2935	—Ph	H	4-biphenylyl	H
VIII-b-88	2936	—Ph	4-biphenylyl	4-biphenylyl	H
VIII-b-89	2937	—Ph	H	3-biphenylyl	H
VIII-b-90	2938	—Ph	3-biphenylyl	3-biphenylyl	H
VIII-b-91	2939	—Ph	H	2-biphenylyl	H
VIII-b-92	2940	—Ph	2-biphenylyl	2-biphenylyl	H
VIII-b-93	2941	—Ph	H	Cl	H
VIII-b-94	2942	—Ph	H	—OH	H
VIII-b-95	2943	—Ph	H	—NO2	H
VIII-b-96	2944	—Ph	H	—CN	H
VIII-b-97	2945	—Ph	H	—OPh	H
VIII-b-98	2946	—Ph	H	—SCH3	H
VIII-b-99	2947	—Ph	H	—SPh	H
VIII-b-100	2948	—Ph	H	—NPh2	H
VIII-b-101	2949	—Ph	H	—COOH	H
VIII-b-102	2950	—Ph	H	2-pyridyl	H
Formula (VIII)
Compound No.	L111	A13═A23	A15═A25	A17═A27	A18═A28
VIII-c-1	2951	—Ph	H	H	H
VIII-c-2	2952	—Ph	H	H	H
VIII-c-3	2953	—Ph	H	H	H
VIII-c-4	2954	2955	H	H	H
		A23 = —Ph
VIII-c-5	2956	2957	H	H	H
		A23 = —Ph
VIII-c-6	2958	—Ph	H	H	CH3
VIII-c-7	2959	—Ph	H	CH3	H
VIII-c-8	2960	—Ph	CH3	H	H
VIII-c-9	2961	—Ph	H	C2H5	H
VIII-c-10	2962	—Ph	H	n-C3H7	H
VIII-c-11	2963	—Ph	H	n-C4H9	H
VIII-c-12	2964	—Ph	H	t-C4H9	H
VIII-c-13	2965	—Ph	H	—OCH3	H
VIII-c-14	2966	—Ph	H	A17 and A18 form a benzene ring. A27 and A28 form a beozene ring.
VIII-c-15	2967	—Ph	H	H	—Ph
VIII-c-16	2968	—Ph	H	—Ph	H
VIII-c-17	2969	—Ph	—Ph	H	H
VIII-c-18	2970	—Ph	H	1-naphthyl	H
VIII-c-19	2971	—Ph	H	2-naphthyl	H
VIII-c-20	2972	—Ph	H	4-biphenylyl	H
VIII-c-21	2973	—Ph	H	3-biphenylyl	H
VIII-c-22	2974	—Ph	H	2-biphenylyl	H
VIII-c-23	2975	—Ph	H	Cl	H
VIII-c-24	2976	—Ph	H	—OH	H
VIII-c-25	2977	—Ph	H	—NO2	H
VIII-c-26	2978	—Ph	H	—CN	H
VIII-c-27	2979	—Ph	H	—OPh	H
VIII-c-28	2980	—Ph	H	—SCH3	H
VIII-c-29	2981	—Ph	H	—SPh	H
VIII-c-30	2982	—Ph	H	—NPh2	H
VIII-c-31	2983	—Ph	H	—COOH	H
VIII-c-32	2984	—Ph	H	2-pyridyl	H
VIII-c-33	2985	—Ph	H	H	CH3
VIII-c-34	2986	—Ph	H	CH3	H
VIII-c-35	2987	—Ph	CH3	H	H
VIII-c-36	2988	—Ph	H	C2H5	H
VIII-c-37	2989	—Ph	H	n-C3H7	H
VIII-c-38	2990	—Ph	H	n-C4H9	H
VIII-c-39	2991	—Ph	H	t-C4H9	H
VIII-c-40	2992	—Ph	—OCH3	H	H
VIII-c-41	2993	—Ph	H	A17 and A18 form a benzene ring. A27 and A28 form a benzene ring.
VIII-c-42	2994	—Ph	H	H	—Ph
VIII-c-43	2995	—Ph	H	—Ph	H
VIII-c-44	2996	—Ph	—Ph	H	H
VIII-c-45	2997	—Ph	H	1-naphthyl	H
VIII-c-46	2998	—Ph	H	2-naphthyl	H
VIII-c-47	2999	—Ph	H	4-biphenylyl	H
VIII-c-48	3000	—Ph	H	3-biphenylyl	H
VIII-c-49	3001	—Ph	H	2-biphenylyl	H
VIII-c-50	3002	—Ph	H	Cl	H
VIII-c-51	3003	—Ph	H	—OH	H
VIII-c-52	3004	—Ph	H	—NO2	H
VIII-c-53	3005	—Ph	H	—CN	H
VIII-c-54	3006	—Ph	H	—OPh	H
VIII-c-55	3007	—Ph	H	—SCH3	H
VIII-c-56	3008	—Ph	H	—SPh	H
VIII-c-57	3009	—Ph	H	—NPh2	H
VIII-c-58	3010	—Ph	H	—COOH	H
VIII-c-59	3011	—Ph	H	2-pyridyl	H
VIII-c-60	3012	—Ph	H	H	CH3
VIII-c-61	3013	—Ph	H	CH3	H
VIII-c-62	3014	—Ph	CH3	H	H
VIII-c-63	3015	—Ph	H	C2H5	H
VIII-c-64	3016	—Ph	H	n-C3H7	H
VIII-c-65	3017	—Ph	H	n-C4H9	H
VIII-c-66	3018	—Ph	H	t-C4H9	H
VIII-c-67	3019	—Ph	H	—OCH3	H
VIII-c-68	3020	—Ph	H	A17 and A18 form a benzene ring. A27 and A28 form a benzene ring.
VIII-c-69	3021	—Ph	H	H	—Ph
VIII-c-70	3022	—Ph	H	—Ph	H
VIII-c-71	3023	—Ph	—Ph	H	H
VIII-c-72	3024	—Ph	H	1-naphthyl	H
VIII-c-73	3025	—Ph	H	2-naphthyl	H
VIII-c-74	3026	—Ph	H	4-biphenylyl	H
VIII-c-75	3027	—Ph	H	2-biphenylyl	H
VIII-c-76	3028	—Ph	H	Cl	H
VIII-c-77	3029	—Ph	H	—OH	H
VIII-c-78	3030	—Ph	H	—NO2	H
VIII-c-79	3031	—Ph	H	—CN	H
VIII-c-80	3032	—Ph	H	—OPh	H
VIII-c-81	3033	—Ph	H	—SCH3	H
VIII-c-82	3034	—Ph	H	—SPh	H
VIII-c-83	3035	—Ph	H	—NPh2	H
VIII-c-84	3036	—Ph	H	—COOH	H
VIII-c-85	3037	—Ph	H	2-pyridyl	H
Formula (VIII)
Compound No.	L111	A13 ═A23	A16═A26	A18═A28
VIII-d-1	3038	—Ph	H	H
VIII-d-2	3039	—Ph	H	H
VIII-d-3	3040	—Ph	H	H
VIII-d-4	3041	3042	H	H
		A23 = —Ph
VIII-d-5	3043	3044	H	H
		A23 = —Ph
VIII-d-6	3045	—Ph	H	CH3
VIII-d-7	3046	—Ph	CH3	H
VIII-d-8	3047	—Ph	CH3	CH3
VIII-d-9	3048	—Ph	C2H5	H
VIII-d-10	3049	—Ph	n-C3H7	H
VIII-d-11	3050	—Ph	n-C4H9	H
VIII-d-12	3051	—Ph	t-C4H9	H
VIII-d-13	3052	—Ph	—OCH3	H
VIII-d-14	3053	—Ph	H	—Ph
VIII-d-15	3054	—Ph	—Ph	H
VIII-d-16	3055	—Ph	1-naphthyl	H
VIII-d-17	3056	—Ph	2-naphthyl	H
VIII-d-18	3057	—Ph	4-biphenylyl	H
VIII-d-19	3058	—Ph	3-biphenylyl	H
VIII-d-20	3059	—Ph	2-biphenylyl	H
VIII-d-21	3060	—Ph	Cl	H
VIII-d-22	3061	—Ph	—OH	H
VIII-d-23	3062	—Ph	—NO2	H
VIII-d-24	3063	—Ph	—CN	H
VIII-d-25	3064	—Ph	—OPh	H
VIII-d-26	3065	—Ph	—SCH3	H
VIII-d-27	3066	—Ph	—SPh	H
VIII-d-28	3067	—Ph	—NH2	H
VIII-d-29	3068	—Ph	—NH—Ph	H
VIII-d-30	3069	—Ph	—NPh2	H
VIII-d-31	3070	—Ph	—COOH	H
VIII-d-32	3071	—Ph	2-pyridyl	H
VIII-d-33	3072	—Ph	H	CH3
VIII-d-34	3073	—Ph	CH3	H
VIII-d-35	3074	—Ph	CH3	CH3
VIII-d-36	3075	—Ph	C2H5	H
VIII-d-37	3076	—Ph	n-C3H7	H
VIII-d-38	3077	—Ph	n-C4H9	H
VIII-d-39	3078	—Ph	t-C4H9	H
VIII-d-40	3079	—Ph	—OCH3	H
VIII-d-41	3080	—Ph	H	—Ph
VIII-d-42	3081	—Ph	—Ph	H
VIII-d-43	3082	—Ph	1-naphthyl	H
VIII-d-44	3083	—Ph	4-biphenylyl	H
VIII-d-45	3084	—Ph	3-biphenylyl	H
VIII-d-46	3085	—Ph	2-biphenylyl	H
VIII-d-47	3086	—Ph	Cl	H
VIII-d-48	3087	—Ph	—OH	H
VIII-d-49	3088	—Ph	NO2	H
VIII-d-50	3089	—Ph	—CN	H
VIII-d-51	3090	—Ph	—OPh	H
VIII-d-52	3091	—Ph	—SCH3	H
VIII-d-53	3092	—Ph	—SPh	H
VIII-d-54	3093	—Ph	—NPh2	H
VIII-d-55	3094	—Ph	—COOH	H
VIII-d-56	3095	—Ph	2-pyridyl	H
VIII-d-57	3096	—Ph	H	CH3
VIII-d-58	3097	—Ph	CH3	H
VIII-d-59	3098	—Ph	CH3	CH3
VIII-d-60	3099	—Ph	H	C2H5
VIII-d-61	3100	—Ph	C2H5	H
VIII-d-62	3101	—Ph	n-C3H7	H
VIII-d-63	3102	—Ph	n-C4H9	H
VIII-d-64	3103	—Ph	t-C4H9	H
VIII-d-65	3104	—Ph	H	—OCH3
VIII-d-66	3105	—Ph	—OCH3	H
VIII-d-67	3106	—Ph	—OCH3	—OCH3
VIII-d-68	3107	—Ph	H	—Ph
VIII-d-69	3108	—Ph	—Ph	H
VIII-d-70	3109	—Ph	H	1-naphthyl
VIII-d-71	3110	—Ph	1-naphthyl	H
VIII-d-72	3111	—Ph	2-naphthyl	H
VIII-d-73	3112	—Ph	H	4-biphenylyl
VIII-d-74	3113	—Ph	4-biphenylyl	H
VIII-d-75	3114	—Ph	3-biphenylyl	H
VIII-d-76	3115	—Ph	2-biphenylyl	H
VIII-d-77	3116	—Ph	Cl	H
VIII-d-78	3117	—Ph	—OH	H
VIII-d-79	3118	—Ph	—NO2	H
VIII-d-80	3119	—Ph	—CN	H
VIII-d-81	3120	—Ph	—OPh	H
VIII-d-82	3121	—Ph	—SCH3	H
VIII-d-83	3122	—Ph	—SPh	H
VIII-d-84	3123	—Ph	—NPh2	H
VIII-d-85	3124	—Ph	—COOH	H
VIII-d-86	3125	—Ph	2-pyridyl	H
Formula (VIII)
Compound No.	L111	A13═A23	A17═A27	A18═A28
VIII-e-1	3126	—Ph	H	H
VIII-e-2	3127	—Ph	H	H
VIII-e-3	3128	—Ph	H	H
VIII-e-4	3129	—Ph	H	CH3
VIII-e-5	3130	—Ph	CH3	H
VIII-e-6	3131	—Ph	CH3	CH3
VIII-e-7	3132	—Ph	C2H5	H
VIII-e-8	3133	—Ph	n-C3H7	H
VIII-e-9	3134	—Ph	n-C3H7	n-C3H7
VIII-e-10	3135	—Ph	n-C4H9	H
VIII-e-11	3136	—Ph	t-C4H9	H
VIII-e-12	3137	—Ph	—OCH3	H
VIII-e-13	3138	—Ph	A17 and A18 form a benzene ring. A27 and A28 form a benzene ring.
VIII-e-14	3139	—Ph	H	—Ph
VIII-e-15	3140	—Ph	—Ph	H
VIII-e-16	3141	—Ph	—Ph	—Ph
VIII-e-17	3142	—Ph	1-naphthyl	H
VIII-e-18	3143	—Ph	2-naphthyl	H
VIII-e-19	3144	—Ph	4-biphenylyl	H
VIII-e-20	3145	—Ph	3-biphenylyl	H
VIII-e-21	3146	—Ph	2-biphenylyl	H
VIII-e-22	3147	—Ph	Cl	H
VIII-e-23	3148	—Ph	—OH	H
VIII-e-24	3149	—Ph	—NO2	H
VIII-e-25	3150	—Ph	—CN	H
VIII-e-26	3151	—Ph	—OPh	H
VIII-e-27	3152	—Ph	—SCH3	H
VIII-e-28	3153	—Ph	—SPh	H
VIII-e-29	3154	—Ph	—NPh2	H
VIII-e-30	3155	—Ph	—COOH	H
VIII-e-31	3156	—Ph	2-pyridyl	H
VIII-e-32	3157	—Ph	H	CH3
VIII-e-33	3158	—Ph	CH3	H
VIII-e-34	3159	—Ph	CH3	CH3
VIII-e-35	3160	—Ph	C2H5	H
VIII-e-36	3161	—Ph	n-C3H7	H
VIII-e-37	3162	—Ph	n-C3H7	n-C3H7
VIII-e-38	3163	—Ph	n-C4H9	H
VIII-e-39	3164	—Ph	t-C4H9	H
VIII-e-40	3165	—Ph	H	—OCH3
VIII-e-41	3166	—Ph	—OCH3	H
VIII-e-42	3167	—Ph	A17 and A18 form a benzene ring. A27 and A28 form a benzene ring.
VIII-e-43	3168	—Ph	H	—Ph
VIII-e-44	3169	—Ph	—Ph	H
VIII-e-45	3170	—Ph	—Ph	—Ph
VIII-e-46	3171	—Ph	1-naphthyl	H
VIII-e-47	3172	—Ph	2-naphthyl	H
VIII-e-48	3173	—Ph	H	4-biphenylyl
VIII-e-49	3174	—Ph	4-biphenylyl	4-biphenylyl
VIII-e-50	3175	—Ph	3-biphenylyl	H
VIII-e-51	3176	—Ph	2-biphenylyl	H
VIII-e-52	3177	—Ph	Cl	H
VIII-e-53	3178	—Ph	—OH	H
VIII-e-54	3179	—Ph	—NO2	H
VIII-e-55	3180	—Ph	—CN	H
VIII-e-56	3181	—Ph	—OPh	H
VIII-e-57	3182	—Ph	—SCH3	H
VIII-e-58	3183	—Ph	—SPh	H
VIII-e-59	3184	—Ph	—NPh2	H
VIII-e-60	3185	—Ph	—COOH	H
VIII-e-61	3186	—Ph	2-pyridyl	H
VIII-e-62	3187	—Ph	H	CH3
VIII-e-63	3188	—Ph	CH3	H
VIII-e-64	3189	—Ph	CH3	CH3
VIII-e-65	3190	—Ph	C2H5	H
VIII-e-66	3191	—Ph	n-C3H7	H
VIII-e-67	3192	—Ph	n-C3H7	n-C3H7
VIII-e-68	3193	—Ph	n-C4H9	H
VIII-e-69	3194	—Ph	t-C4H9	H
VIII-e-70	3195	—Ph	t-C4H9	t-C4H9
VIII-e-71	3196	—Ph	—OCH3	H
VIII-e-72	3197	—Ph	A17 and A18 form a benzene ring. A27 and A28 form a benzene ring.
VIII-e-73	3198	—Ph	H	—Ph
VIII-e-74	3199	—Ph	—Ph	H
VIII-e-75	3200	—Ph	—Ph	—Ph
VIII-e-76	3201	—Ph	1-naphthyl	H
VIII-e-77	3202	—Ph	2-naphthyl	H
VIII-e-78	3203	—Ph	3-biphenylyl	H
VIII-e-79	3204	—Ph	2-biphenylyl	H
VIII-e-80	3205	—Ph	Cl	H
VIII-e-81	3206	—Ph	—OH	H
VIII-e-82	3207	—Ph	—NO2	H
VIII-e-83	3208	—Ph	—CN	H
VIII-e-84	3209	—Ph	—OPh	H
VIII-e-85	3210	—Ph	—SCH3	H
VIII-e-86	3211	—Ph	—SPh	H
VIII-e-87	3212	—Ph	—NPh2	H
VIII-e-88	3213	—Ph	—COOH	H
VIII-e-89	3214	—Ph	2-pyridyl	H
Formula (VIII)
Compound No.	L111	A13═A23	A15═A25	A18═A28
VIII-f-1	3215	—Ph	H	H
VIII-f-2	3216	—Ph	H	H
VIII-f-3	3217	—Ph	H	H
VIII-f-4	3218	—Ph	H	CH3
VIII-f-5	3219	—Ph	CH3	H
VIII-f-6	3220	—Ph	CH3	CH3
VIII-f-7	3221	—Ph	C2H5	H
VIII-f-8	3222	—Ph	n-C3H7	H
VIII-f-9	3223	—Ph	n-C4H9	H
VIII-f-10	3224	—Ph	t-C4H9	H
VIII-f-11	3225	—Ph	—OCH3	H
VIII-f-12	3226	—Ph	H	—Ph
VIII-f-13	3227	—Ph	—Ph	H
VIII-f-14	3228	—Ph	—Ph	—Ph
VIII-f-15	3229	—Ph	H	1-naphthyl
VIII-f-16	3230	—Ph	1-naphthyl	H
VIII-f-17	3231	—Ph	2-naphthyl	H
VIII-f-18	3232	—Ph	4-biphenylyl	H
VIII-f-19	3233	—Ph	3-biphenylyl	H
VIII-f-20	3234	—Ph	2-biphenylyl	H
VIII-f-21	3235	—Ph	Cl	H
VIII-f-22	3236	—Ph	—OH	H
VIII-f-23	3237	—Ph	—NO2	H
VIII-f-24	3238	—Ph	—CN	H
VIII-f-25	3239	—Ph	—OPh	H
VIII-f-26	3240	—Ph	—SCH3	H
VIII-f-27	3241	—Ph	—SPh	H
VIII-f-28	3242	—Ph	—NPh2	H
VIII-f-29	3243	—Ph	—COOH	H
VIII-f-30	3244	—Ph	2-pyridyl	H
VIII-f-31	3245	—Ph	H	CH3
VIII-f-32	3246	—Ph	CH3	H
VIII-f-33	3247	—Ph	CH3	CH3
VIII-f-34	3248	—Ph	C2H5	H
VIII-f-35	3249	—Ph	n-C3H7	H
VIII-f-36	3250	—Ph	n-C4H9	H
VIII-f-37	3251	—Ph	t-C4H9	H
VIII-f-38	3252	—Ph	—OCH3	H
VIII-f-39	3253	—Ph	H	—Ph
VIII-f-40	3254	—Ph	—Ph	H
VIII-f-41	3255	—Ph	—Ph	—Ph
VIII-f-42	3256	—Ph	1-naphthyl	H
VIII-f-43	3257	—Ph	2-naphthyl	H
VIII-f-44	3258	—Ph	4-biphenylyl	H
VIII-f-45	3259	—Ph	3-biphenylyl	H
VIII-f-46	3260	—Ph	2-biphenylyl	H
VIII-f-47	3261	—Ph	Cl	H
VIII-f-48	3262	—Ph	OH	H
VIII-f-49	3263	—Ph	—NO2	H
VIII-f-50	3264	—Ph	—CN	H
VIII-f-51	3265	—Ph	—OPh	H
VIII-f-52	3266	—Ph	—SCH3	H
VIII-f-53	3267	—Ph	—SPh	H
VIII-f-54	3268	—Ph	—NPh2	H
VIII-f-55	3269	—Ph	—COOH	H
VIII-f-56	3270	—Ph	2-pyridyl	H
VIII-f-57	3271	—Ph	H	CH3
VIII-f-58	3272	—Ph	CH3	H
VIII-f-59	3273	—Ph	CH3	CH3
VIII-f-60	3274	—Ph	C2H5	H
VIII-f-61	3275	—Ph	n-C3H7	H
VIII-f-62	3276	—Ph	n-C4H9	H
VIII-f-63	3277	—Ph	t-C4H9	H
VIII-f-64	3278	—Ph	—OCH3	H
VIII-f-65	3279	—Ph	H	—Ph
VIII-f-66	3280	—Ph	—Ph	H
VIII-f-67	3281	—Ph	—Ph	—Ph
VIII-f-68	3282	—Ph	1-naphthyl	H
VIII-f-69	3283	—Ph	2-naphthyl	H
VIII-f-70	3284	—Ph	4-biphenylyl	H
VIII-f-71	3285	—Ph	3-biphenylyl	H
VIII-f-72	3286	—Ph	2-biphenylyl	H
VIII-f-73	3287	—Ph	Cl	H
VIII-f-74	3288	—Ph	—OH	H
VIII-f-75	3289	—Ph	—NO2	H
VIII-f-76	3290	—Ph	—CN	H
VIII-f-77	3291	—Ph	—OPh	H
VIII-f-78	3292	—Ph	—SCH3	H
VIII-f-79	3293	—Ph	—SPh	H
VIII-f-80	3294	—Ph	—NPh2	H
VIII-f-81	3295	—Ph	—COOH	H
VIII-f-82	3296	—Ph	2-pyridyl	H
Formula (VIII)		A13═A23	A15═A25	A16═A26	A17═A27	A18═A28
Compound No.	L112	═A33	═A35	═A36	═A37	A38
VIII-g-1	3297	H	H	H	H	H
VIII-g-2	3298	H	A15 and A18 form a benzene ring. A25 and A26 form a benzene ring. A35 and A36 form a benzene ring.	A17 and A18 form a benzene ring. A27 and A28 form a benzene ring. A37 and A38 form a benzene ring.
VIII-g-3	3299	H	A15 and A16 form a benzene ring. A25 and A26 form a benzene ring. A35 and A36 form a benzene ring.	H	H
VIII-g-4	3300	—Ph	H	H	H	H
VIII-g-5	3301	—Ph	A15 and A16 form a benzene ring. A25 and A26 form a benzene ring. A35 and A36 form a benzene ring.	A17 and A18 form a benzene ring. A27 and A28 form a benzene ring. A37 and A38 form a benzene ring.
VIII-g-6	3302	—Ph	A15 and A16 form a benzene ring. A25 and A26 form a benzene ring. A35 and A36 form a benzene ring.	H	H
VIII-g-7	3303	H	H	H	H	H
VIII-g-8	3304	H	A15 and A16 form a benzene ring. A25 and A26 form a benzene ring. A35 and A36 form a benzene ring.	A17 and A18 form a benzene ring. A27 and A28 form a benzene ring. A37 and A38 form a benzene ring.
VIII-g-9	3305	H	A15 and A16 form a benzene ring. A25 and A26 form a benzene ring. A35 and A36 form a benzene ring.	H	H
VIII-g-10	3306	—Ph	H	H	H	H
VIII-g-11	3307	—Ph	A15 and A16 form a benzene ring. A25 and A26 form a benzene ring. A35 and A36 form a benzene ring.	A17 and A18 form a benzene ring. A27 and A28 form a benzene ring. A37 and A38 form a benzene ring.
VIII-g-12	3308	—Ph	A15 and A15 form a benzene ring. A25 and A26 form a benzene ring. A35 and A36 form a benzene ring.	H	H
VIII-g-13	3309	H	H	H	H	H
VIII-g-14	3310	H	A15 and A16 form a benzene ring. A25 and A26 form a benzene ring. A35 and A36 form a benzene ring.	H	H
VIII-g-15	3311	H	A15 and A16 form a benzene ring. A25 and A26 form a benzene ring. A35 and A36 form a benzene ring.	A17 and A18 form a benzene ring. A27 and A28 form a benzene ring. A37 and A38 form a benzene ring.
VIII-g-16	3312	—Ph	H	H	H	H
VIII-g-17	3313	—Ph	A15 and A16 form a benzene ring. A25 and A26 form a benzene ring. A35 and A36 form a benzene ring.	A17 and A18 form a benzene ring. A27 and A28 form a benzene ring. A37 and A38 form a benzene ring.
VIII-g-18	3314	—Ph	A15 and A16 form a benzene ring. A25 and A26 form a benzene ring. A35 and A36 form a benzene ring.	H	H
VIII-g-19	3315	—Ph	H	H	—Ph	H
VIII-g-20	3316	—Ph	—Ph	H	H	H
VIII-g-21	3317	—Ph	H	—Ph	H	H
VIII-g-22	3318	—Ph	H	H	H	—Ph
VIII-g-23	3319	—Ph	H	H	Cl	H
VIII-g-24	3320	—Ph	H	H	—OH	H
VIII-g-25	3321	—Ph	H	H	—NO2	H
VIII-g-26	3322	—Ph	H	H	—CN	H
VIII-g-27	3323	—Ph	H	H	—OPh	H
VIII-g-28	3324	—Ph	H	H	—SCH3	H
VIII-g-29	3325	—Ph	H	H	—SPh	H
VIII-g-30	3326	—Ph	H	H	—NPh	H
VIII-g-31	3327	—Ph	H	H	CH3	H
VIII-g-32	3328	—Ph	H	H	—OCH3	H
VIII-g-33	3329	—Ph	H	H	—COOH	H
VIII-g-34	3330	—Ph	H	H	2-pyridyl	H
VIII-g-35	3331	—Ph	H	H	—Ph	H
VIII-g-36	3332	—Ph	—Ph	H	H	H
VIII-g-37	3333	—Ph	H	—Ph	H	H
VIII-g-38	3334	—Ph	H	H	H	—Ph
VIII-g-39	3335	—Ph	H	H	Cl	H
VIII-g-40	3336	—Ph	H	H	—OH	H
VIII-g-41	3337	—Ph	H	H	—NO2	H
VIII-g-42	3338	—Ph	H	H	—CN	H
VIII-g-43	3339	—Ph	H	H	—OPh	H
VIII-g-44	3340	—Ph	H	H	SCH3	H
VIII-g-45	3341	—Ph	H	H	—SPh	H
VIII-g-46	3342	—Ph	H	H	—NPh	H
VIII-g-47	3343	—Ph	H	H	CH3	H
VIII-g-48	3344	—Ph	H	H	—OCH3	H
VIII-g-49	3345	—Ph	H	H	—COOH	H
VIII-g-50	3346	—Ph	H	H	2-pyridyl	H
VIII-g-51	3347	—Ph	H	H	—Ph	H
VIII-g-52	3348	—Ph	—Ph	H	H	H
VIII-g-53	3349	—Ph	H	—Ph	H	H
VIII-g-54	3350	—Ph	H	H	H	—Ph
VIII-g-55	3351	—Ph	H	H	Cl	H
VIII-g-56	3352	—Ph	H	H	—OH	H
VIII-g-57	3353	—Ph	H	H	—NO2	H
VIII-g-58	3354	—Ph	H	H	—CN	H
VIII-g-59	3355	—Ph	H	H	—OPh	H
VIII-g-60	3356	—Ph	H	H	—SCH3	H
VIII-g-61	3357	—Ph	H	H	—SPh	H
VIII-g-62	3358	—Ph	H	H	—NPh	H
VIII-g-63	3359	—Ph	H	H	CH3	H
VIII-g-64	3360	—Ph	H	H	—OCH3	H
VIII-g-65	3361	—Ph	H	H	—COOH	H
VIII-g-66	3362	—Ph	H	H	2-pyridyl	H
Formula (VIII)		A13═A23	A16═A26	A17═A27	A18═A28
Compound No.	L112	═A33	═A36	═A37	═A38
VIII-h-1	3363	H	H	H	H
VIII-h-2	3364	—Ph	H	H	H
VIII-h-3	3365	H	H	H	H
VIII-h-4	3366	—Ph	H	H	H
VIII-h-5	3367	H	H	H	H
VIII-h-6	3368	—Ph	H	H	H
VIII-h-7	3369	H	A16 and A17 form a benzene ring. A26 and A27 form a benzene ring. A36 and A37 form a benzene ring.	H
VIII-h-8	3370	—Ph	A16 and A17 form a benzene ring. A26 and A27 form a benzene ring. A36 and A37 form a benzene ring.	H
VIII-h-9	3371	H	H	A17 and A18 form a benzene ring. A27 and A28 form a benzene ring. A37 and A38 form a benzene ring.
VIII-h-10	3372	—Ph	H	A17 and A18 form a benzene ring. A37 and A28 form a benzene ring. A37 and A38 form a benzene ring.
VIII-h-11	3373	—Ph	—Ph	H	H
VIII-h-12	3374	—Ph	H	—Ph	H
VIII-h-13	3375	—Ph	H	H	—Ph
VIII-h-14	3376	—Ph	H	Cl	H
VIII-h-15	3377	—Ph	H	—OH	H
VIII-h-16	3378	—Ph	H	—NO2	H
VIII-h-17	3379	—Ph	H	—CN	H
VIII-h-18	3380	—Ph	H	—OPh	H
VIII-h-19	3381	—Ph	H	—SCH3	H
VIII-h-20	3382	—Ph	H	—SPh	H
VIII-h-21	3383	—Ph	H	—NPh2	H
VIII-h-22	3384	—Ph	H	CH3	H
VIII-h-23	3385	—Ph	H	—OCH3	H
VIII-h-24	3386	—Ph	H	—COOH	H
VIII-h-25	3387	—Ph	H	2-pyridyl	H
VIII-h-26	3388	H	A16 and A17 form a benzene ring. A26 and A27 form a benzene ring. A36 and A37 form a benzene ring.	H
VIII-h-27	3389	—Ph	A16 and A17 form a benzene ring. A26 and A27 form a benzene ring. A36 and A37 form a benzene ring.	H
VIII-h-28	3390	H	H	A17 and A16 form a benzene ring. A27 and A28 form a benzene ring. A37 and A38 form a benzene ring.
VIII-h-29	3391	—Ph	H	A17 and A16 form a benzene ring. A27 and A28 form a benzene ring. A37 and A36 form a benzene ring.
VIII-h-30	3392	—Ph	—Ph	H	H
VIII-h-31	3393	—Ph	H	—Ph	H
VIII-h-32	3394	—Ph	H	H	—Ph
VIII-h-33	3395	—Ph	H	Cl	H
VIII-h-34	3396	—Ph	H	—OH	H
VIII-h-35	3397	—Ph	H	—NO2	H
VIII-h-36	3398	—Ph	H	—CN	H
VIII-h-37	3399	—Ph	H	—OPh	H
VIII-h-38	3400	—Ph	H	—SCH3	H
VIII-h-39	3401	—Ph	H	—SPh	H
VIII-h-40	3402	—Ph	H	—NPh2	H
VIII-h-41	3403	—Ph	H	CH3	H
VIII-h-42	3404	—Ph	H	—OCH3	H
VIII-h-43	3405	—Ph	H	—COOH	H
VIII-h-44	3406	—Ph	H	2-pyridyl	H
VIII-h-45	3407	H	A16 and A17 form a benzene ring. A26 and A27 form a benzene ring. A36 and A37 form a benzene ring.	H
VIII-h-46	3408	—Ph	A16 and A17 form a benzene ring. A26 and A27 form a benzene ring. A36 and A37 form a benzene ring.	H
VIII-h-47	3409	H	H	A17 and A18 form a benzene ring. A27 and A28 form a benzene ring. A37 and A38 form a benzene ring.
VIII-h-48	3410	—Ph	H	A17 and A18 form a henzene ring. A27 and A28 form a benzene ring. A37 and A38 form a benzene ring.
VIII-h-49	3411	—Ph	—Ph	H	H
VIII-h-50	3412	—Ph	H	—Ph	H
VIII-h-51	3413	—Ph	H	H	—Ph
VIII-h-52	3414	—Ph	H	Cl	H
VIII-h-53	3415	—Ph	H	—OH	H
VIII-h-54	3416	—Ph	H	—NO2	H
VIII-h-55	3417	—Ph	H	—CN	H
VIII-h-56	3418	—Ph	H	—OPh	H
VIII-h-57	3419	—Ph	H	—SCH3	H
VIII-h-58	3420	—Ph	H	—SPh	H
VIII-h-59	3421	—Ph	H	—NPh2	H
VIII-h-60	3422	—Ph	H	CH3	H
VIII-h-61	3423	—Ph	H	—OCH3	H
VIII-h-62	3424	—Ph	H	—COOH	H
VIII-h-63	3425	—Ph	H	2-pyridyl	H
VIII-i-1	3426	H	H	H	H
VIII-i-2	3427	—Ph	H	H	H
VIII-i-3	3428	H	H	H	H
VIII-i-4	3429	H	H	H	H
VIII-i-5	3430	—Ph	H	H	H
VIII-i-6	3431	H	H	A17 and A18 form a benzene ring. A27 and A28 form a benzene ring. A37 and A38 form a benzene ring.
VIII-i-7	3432	—Ph	H	A17 and A18 form a benzene ring. A27 and A28 form a benzene ring. A37 and A38 form a benzene ring.
VIII-i-8	3433	H	H	A17 and A18 form a benzene ring. A27 and A28 form a benzene ring. A37 and A38 form a benzene ring.
VIII-i-9	3434	H	H	A17 and A18 form a benzene ring. A27 and A28 form a benzene ring. A37 and A38 form a benzene ring.
VIII-i-10	3435	—Ph	H	A17 and A18 form a benzene ring. A27 and A28 form a benzene ring. A37 and A38 form a benzene ring.
VIII-i-11	3436	—Ph	—Ph	H	H
VIII-i-12	3437	—Ph	H	—Ph	H
VIII-i-13	3438	—Ph	H	H	—Ph
VIII-i-14	3439	—Ph	H	Cl	H
VIII-i-15	3440	—Ph	H	—OH	H
VIII-i-16	3441	—Ph	H	—NO2	H
VIII-i-17	3442	—Ph	H	—CN	H
VIII-i-18	3443	—Ph	H	—OPh	H
VIII-i-19	3444	—Ph	H	—SCH3	H
VIII-i-20	3445	—Ph	H	—SPh	H
VIII-i-21	3446	—Ph	H	—N—Ph2	H
VIII-i-22	3447	—Ph	H	CH3	H
VIII-i-23	3448	—Ph	H	—OCH3	H
VIII-i-24	3449	—Ph	H	—COOH	H
VIII-i-25	3450	—Ph	H	2-pyridyl	H
VIII-i-26	3451	—Ph	—Ph	H	H
VIII-i-27	3452	—Ph	H	—Ph	H
VIII-i-28	3453	—Ph	H	H	—Ph
VIII-i-29	3454	—Ph	H	Cl	H
VIII-i-30	3455	—Ph	H	—OH	H
VIII-i-31	3456	—Ph	H	—NO2	H
VIII-i-32	3457	—Ph	H	—CN	H
VIII-i-33	3458	—Ph	H	—OPh	H
VIII-i-34	3459	—Ph	H	—SCH3	H
VIII-i-35	3460	—Ph	H	—SPh	H
VIII-i-36	3461	—Ph	H	—N—Ph2	H
VIII-i-37	3462	—Ph	H	CH3	H
VIII-i-38	3463	—Ph	H	—OCH3	H
VIII-i-39	3464	—Ph	H	—COOH	H
VIII-i-40	3465	—Ph	H	2-pyridyl	H
VIII-i-41	3466	—Ph	—Ph	H	H
VIII-i-42	3467	—Ph	H	—Ph	H
VIII-i-43	3468	—Ph	H	H	—Ph
VIII-i-44	3469	—Ph	H	Cl	H
VIII-i-45	3470	—Ph	H	—OH	H
VIII-i-46	3471	—Ph	H	—NO2	H
VIII-i-47	3472	—Ph	H	—CN	H
VIII-i-48	3473	—Ph	H	—OPh	H
VIII-i-49	3474	—Ph	H	—SCH3	H
VIII-i-50	3475	—Ph	H	—SPh	H
VIII-i-51	3476	—Ph	H	—N—Ph2	H
VIII-i-52	3477	—Ph	H	CH3	H
VIII-i-53	3478	—Ph	H	—OCH3	H
VIII-i-54	3479	—Ph	H	—COOH	H
VIII-i-55	3480	—Ph	H	2-pyridyl	H
Formula (VIII)
Compound No.	L112	A13 ═A23═A33	A16 ═A26═A36	A18 ═A28═A38
VIII-j-1	3481	H	H	H
VIII-j-2	3482	—Ph	H	H
VIII-j-3	3483	H	H	H
VIII-j-4	3484	H	H	H
VIII-j-5	3485	—Ph	H	H
VIII-j-6	3486	—Ph	—Ph	H
VIII-j-7	3487	—Ph	H	—Ph
VIII-j-8	3488	—Ph	Cl	H
VIII-j-9	3489	—Ph	—OH	H
VIII-j-10	3490	—Ph	—NO2	H
VIII-j-11	3491	—Ph	—CN	H
VIII-j-12	3492	—Ph	—OPh	H
VIII-j-13	3493	—Ph	—SCH3	H
VIII-j-14	3494	—Ph	—SPh	H
VIII-j-15	3495	—Ph	—N—Ph2	H
VIII-j-16	3496	—Ph	CH3	H
VIII-j-17	3497	—Ph	—OCH3	H
VIII-j-18	3498	—Ph	—COOH	H
VIII-j-19	3499	—Ph	2-pyridyl	H
VIII-j-20	3500	—Ph	—Ph	H
VIII-j-21	3501	—Ph	H	—Ph
VIII-j-22	3502	—Ph	Cl	H
VIII-j-23	3503	—Ph	—OH	H
VIII-j-24	3504	—Ph	—NO2	H
VIII-j-25	3505	—Ph	—CN	H
VIII-j-26	3506	—Ph	—OPh	H
VIII-j-27	3507	—Ph	—SCH3	H
VIII-j-28	3508	—Ph	—SPh	H
VIII-j-29	3509	—Ph	—N—Ph2	H
VIII-j-30	3510	—Ph	CH3	H
VIII-j-31	3511	—Ph	—OCH3	H
VIII-j-32	3512	—Ph	—COOH	H
VIII-j-33	3513	—Ph	2-pyridyl	H
VIII-j-34	3514	—Ph	—Ph	H
VIII-j-35	3515	—Ph	H	—Ph
VIII-j-36	3516	—Ph	Cl	H
VIII-j-37	3517	—Ph	—OH	H
VIII-j-38	3518	—Ph	—NO2	H
VIII-j-39	3519	—Ph	—CN	H
VIII-j-40	3520	—Ph	—OPh	H
VIII-j-41	3521	—Ph	—SCH3	H
VIII-j-42	3522	—Ph	—SPh	H
VIII-j-43	3523	—Ph	—N—Ph2	H
VIII-j-44	3524	—Ph	CH3	H
VIII-j-45	3525	—Ph	—OCH3	H
VIII-j-46	3526	—Ph	—COOH	H
VIII-j-47	3527	—Ph	2-pyridyl	H
Formula (VIII)
Compound No.	L112	A13 ═A23═A33	A17 ═A27═A37	A18 ═A28═A38
VIII-k-1	3528	H	H	H
VIII-k-2	3529	—Ph	H	H
VIII-k-3	3530	H	H	h
VIII-k-4	3531	—Ph	H	H
VIII-k-5	3532	H	H	H
VIII-k-6	3533	—Ph	H	H
VIII-k-7	3534	H	A17 and A18 form a benzene ring. A27 and A28 form a benzene ring. A37 and A38 form a benzene ring.
VIII-k-8	3535	—Ph	A17 and A18 form a benzene ring. A27 and A28 form a benzene ring. A37 and A38 form a benzene ring.
VIII-k-9	3536	H	A17 and A18 form a benzene ring. A27 and A28 form a benzene ring. A37 and A38 form a benzene ring.
VIII-k-10	3537	—Ph	A17 and A18 form a benzene ring. A27 and A28 form a benzene ring. A37 and A38 form a benzene ring.
VIII-k-11	3538	H	A17 and A18 form a benzene ring. A27 and A28 form a benzene ring. A37 and A38 form a benzene ring.
VIII-k-12	3539	—Ph	A17 and A18 form a benzene ring. A27 and A28 form a benzene ring. A37 and A38 form a benzene ring.
VIII-k-13	3540	—Ph	—Ph	H
VIII-k-14	3541	—Ph	H	—Ph
VIII-k-15	3542	—Ph	Cl	H
VIII-k-16	3543	—Ph	—OH	H
VIII-k-17	3544	—Ph	—NO2	H
VIII-k-18	3545	—Ph	—CN	H
VIII-k-19	3546	—Ph	—OPh	H
VIII-k-20	3547	—Ph	—SCH3	H
VIII-k-21	3548	—Ph	—SPh	H
VIII-k-22	3549	—Ph	—N—Ph2	H
VIII-k-23	3550	—Ph	CH3	H
VIII-k-24	3551	—Ph	—OCH3	H
VIII-k-25	3552	—Ph	—COOH	H
VIII-k-26	3553	—Ph	2-pyridyl	H
VIII-k-27	3554	—Ph	—Ph	H
VIII-k-28	3555	—Ph	H	—Ph
VIII-k-29	3556	—Ph	Cl	H
VIII-k-30	3557	—Ph	—OH	H
VIII-k-31	3558	—Ph	—NO2	H
VIII-k-32	3559	—Ph	—CN	H
VIII-k-33	3560	—Ph	—OPh	H
VIII-k-34	3561	—Ph	—SCH3	H
VIII-k-35	3562	—Ph	—SPh	H
VIII-k-36	3563	—Ph	—N—Ph2	H
VIII-k-37	3564	—Ph	CH3	H
VIII-k-38	3565	—Ph	—OCH3	H
VIII-k-39	3566	—Ph	—COOH	H
VIII-k-40	3567	—Ph	2-pyridyl	H
VIII-k-41	3568	—Ph	—Ph	H
VIII-k-42	3569	—Ph	H	—Ph
VIII-k-43	3570	—Ph	Cl	H
VIII-k-44	3571	—Ph	—OH	H
VIII-k-45	3572	—Ph	—NO2	H
VIII-k-46	3573	—Ph	—CN	H
VIII-k-47	3574	—Ph	—OPh	H
VIII-k-48	3575	—Ph	—SCH3	H
VIII-k-49	3576	—Ph	—SPh	H
VIII-k-50	3577	—Ph	—N—Ph2	H
VIII-k-51	3578	—Ph	CH3	H
VIII-k-52	3579	—Ph	—OCH3	H
VIII-k-53	3580	—Ph	—COOH	H
VIII-k-54	3581	—Ph	2-pyridyl	H
Formula (VIII)
Compound No.	L112	A13 ═A23═A33	A15 ═A25═A35	A18 ═A28═A38
VIII-l-1	3582	H	H	H
VIII-l-2	3583	—Ph	H	H
VIII-l-3	3584	H	H	H
VIII-l-4	3585	—Ph	H	H
VIII-l-5	3586	H	H	H
VIII-l-6	3587	—Ph	—Ph	H
VIII-l-7	3588	—Ph	H	—Ph
VIII-l-8	3589	—Ph	Cl	H
VIII-l-9	3590	—Ph	—OH	H
VIII-l-10	3591	—Ph	—NO2	H
VIII-l-11	3592	—Ph	—CN	H
VIII-l-12	3593	—Ph	—OPh	H
VIIl-l-13	3594	—Ph	—SCH3	H
VIII-l-14	3595	—Ph	—SPh	H
VIII-l-15	3596	—Ph	—N—Ph2	H
VIII-l-16	3597	—Ph	CH3	H
VIII-l-17	3598	—Ph	—OCH3	H
VIII-l-18	3599	—Ph	—COOH	H
VIII-l-19	3600	—Ph	2-pyridyl	H
VIII-l-20	3601	—Ph	—Ph	H
VIII-l-21	3602	—Ph	H	—Ph
VIII-l-22	3603	—Ph	Cl	H
VIII-l-23	3604	—Ph	—OH	H
VIII-l-24	3605	—Ph	—NO2	H
VIII-l-25	3606	—Ph	—CN	H
VIII-l-26	3607	—Ph	—OPh	H
VIII-l-27	3608	—Ph	—SCH3	H
VIII-l-28	3609	—Ph	—SPh	H
VIII-l-29	3610	—Ph	—N—Ph2	H
VIII-l-30	3611	—Ph	CH3	H
VIII-l-31	3612	—Ph	—OCH3	H
VIII-l-32	3613	—Ph	—COOH	H
VIII-l-33	3614	—Ph	2-pyridyl	H
VIII-l-34	3615	—Ph	—Ph	H
VIII-l-35	3616	—Ph	H	—Ph
VIII-l-36	3617	—Ph	Cl	H
VIII-l-37	3618	—Ph	—OH	H
VIII-l-38	3619	—Ph	—NO2	H
VIII-l-39	3620	—Ph	—CN	H
VIII-l-40	3621	—Ph	—OPh	H
VIII-l-41	3622	—Ph	—SCH3	H
VIII-l-42	3623	—Ph	—SPh	H
VIII-l-43	3624	—Ph	—N—Ph2	H
VIII-l-44	3625	—Ph	CH3	H
VIII-l-45	3626	—Ph	—OCH3	H
VIII-l-46	3627	—Ph	—COOH	H
VIII-l-47	3628	—Ph	2-pyridyl	H
Formula (VIII)
Compound No.	L111	A12═A22	A13═A23	A15═A25	A17═A27	A18═A28
VIII-m-1	single bond	H	H	H	H	H
VIII-m-2	single bond	H	H	CH3	H	H
VIII-m-3	single bond	H	H	H	CH3	H
VIII-m-4	single bond	H	H	H	H	CH3
VIII-m-5	single bond	H	H	H	n-C2H5	H
VIII-m-6	single bond	H	H	H	n-C3H7	H
VIII-m-7	single bond	H	H	H	n-C4H9	H
VIII-m-8	single bond	H	H	H	t-C4H9	H
VIII-m-9	single bond	H	H	Ph	H	H
VIII-m-10	single bond	H	H	H	Ph	H
VIII-m-11	single bond	H	H	H	H	Ph
VIII-m-12	single bond	H	H	H	1-naphthyl	H
VIII-m-13	single bond	H	H	H	2-naphthyl	H
VIII-m-14	single bond	H	H	H	4-biphenylyl	H
VIII-m-15	single bond	H	H	H	3-biphenylyl	H
VIII-m-16	single bond	H	H	H	2-biphenylyl	H
VIII-m-17	single bond	H	H	H	2-biphenylyl	H
VIII-m-18	single bond	Ph	Ph	H	H	H
VIII-m-19	single bond	Ph	Ph	CH3	H	H
VIII-m-20	single bond	Ph	Ph	H	CH3	H
VIII-m-21	single bond	Ph	Ph	H	H	CH3
VIII-m-22	single bond	Ph	Ph	H	n- C2H5	H
VIII-m-23	single bond	Ph	Ph	H	n-C3H7	H
VIII-m-24	single bond	Ph	Ph	H	n-C4H9	H
VIII-m-25	single bond	Ph	Ph	H	t-C4H9	H
VIII-m-26	single bond	Ph	Ph	Ph	H	H
VIII-m-27	single bond	Ph	Ph	H	Ph	H
VIII-m-28	single bond	Ph	Ph	H	H	Ph
VIII-m-29	single bond	Ph	Ph	H	1-naphthyl	H
VIII-m-30	single bond	Ph	Ph	H	2-naphthyl	H
VIII-m-31	single bond	Ph	Ph	H	4-biphenylyl	H
VIII-m-32	single bond	Ph	Ph	H	3-biphenylyl	H
VIII-m-33	single bond	Ph	Ph	H	2-biphenylyl	H
VIII-m-34	single bond	3629	3630	H	H	H
VIII-m-35	single bond	3631	3632	CH3	H	H
VIII-m-36	single bond	3633	3634	H	CH3	H
VIII-m-37	single bond	3635	3636	H	H	CH3
VIII-m-38	single bond	3637	3638	H	n-C2H5	H
VIII-m-39	single bond	3639	3640	H	n-C3H7	H
VIII-m-40	single bond	3641	3642	H	n-C4H9	H
VIII-m-41	single bond	3643	3644	H	t-C4H9	H
VIII-m-42	single bond	3645	3646	—Ph	H	H
VIII-m-43	single bond	3647	3648	H	—Ph	H
VIII-m-44	single bond	3649	3650	H	H	Ph
VIII-m-45	single bond	3651	3652	H	1-naphthyl	H
VIII-m-46	single bond	3653	3654	H	2-naphthyl	H
VIII-m-47	single bond	3655	3656	H	4-biphenylyl	H
VIII-m-48	single bond	3657	3658	H	3-biphenylyl	H
VIII-m-49	single bond	3659	3660	H	2-biphenylyl	H
VIII-m-50	3661	H	H	H	H	H
VIII-m-51	3662	H	H	CH3	H	H
VIII-m-52	3663	H	H	H	CH3	H
VIII-m-53	3664	H	H	H	H	CH3
VIII-m-54	3665	H	H	H	n-C2H5	H
VIII-m-55	3666	H	H	H	n-C3H7	H
VIII-m-56	3667	H	H	H	n-C4H9	H
VIII-m-57	3668	H	H	H	t-C4H9	H
VIII-m-58	3669	H	H	Ph	H	H
VIII-m-59	3670	H	H	H	Ph	H
VIII-m-60	3671	H	H	H	H	Ph
VIII-m-61	3672	H	H	H	1-naphthyl	H
VIII-m-62	3673	H	H	H	2-naphthyl	H
VIII-m-63	3674	H	H	H	4-biphenylyl	H
VIII-m-64	3675	H	H	H	3-biphenylyl	H
VIII-m-65	3676	H	H	H	2-biphenylyl	H
VIII-m-66	3677	H	H	H	2-biphenylyl	H
VIII-m-67	3678	Ph	Ph	H	H	H
VIII-m-68	3679	Ph	Ph	CH3	H	H
VIII-m-69	3680	Ph	Ph	H	CH3	H
VIII-m-70	3681	Ph	Ph	H	H	CH3
VIII-m-71	3682	Ph	Ph	H	n-C2H5	H
VIII-m-72	3683	Ph	Ph	H	n-C3H7	H
VIII-m-73	3684	Ph	Ph	H	n-C4H9	H
VIII-m-74	3685	Ph	Ph	H	t-C4H9	H
VIII-m-75	3686	Ph	Ph	Ph	H	H
VIII-m-76	3687	Ph	Ph	H	Ph	H
VIII-m-77	3688	Ph	Ph	H	H	Ph
VIII-m-78	3689	Ph	Ph	H	1-naphthyl	H
VIII-m-79	3690	Ph	Ph	H	2-naphthyl	H
VIII-m-80	3691	Ph	Ph	H	4-biphenylyl	H
VIII-m-81	3692	Ph	Ph	H	3-biphenylyl	H
VIII-m-82	3693	Ph	Ph	H	2-biphenylyl	H
VIII-m-83	3694	3695	3696	H	H	H
VIII-m-84	3697	3698	3699	CH3	H	H
VIII-m-85	3700	3701	3702	H	CH3	H
VIII-m-86	3703	3704	3705	H	H	CH3
VIII-m-87	3706	3707	3708	H	n-C2H5	H
VIII-m-88	3709	3710	3711	H	n-C3H7	H
VIII-m-89	3712	3713	3714	H	n-C4H9	H
VIII-m-90	3715	3716	3717	H	t-C4H9	H
VIII-m-91	3718	3719	3720	Ph	H	H
VIII-m-92	3721	3722	3723	H	Ph	H
VIII-m-93	3724	3725	3726	H	H	Ph
VIII-m-94	3727	3728	3729	H	1-naphthyl	H
VIII-m-95	3730	3731	3732	H	2-naphthyl	H
VIII-m-96	3733	3734	3735	H	4-biphenylyl	H
VIII-m-97	3736	3737	3738	H	3-biphenylyl	H
VIII-m-98	3739	3740	3741	H	2-biphenylyl	H
VIII-m-99	3742	H	H	H	H	H
VIII-m-100	3743	H	H	CH3	H	H
VIII-m-101	3744	H	H	H	CH3	H
VIII-m-102	3745	H	H	H	H	CH3
VIII-m-103	3746	H	H	H	n-C2H5	H
VIII-m-104	3747	H	H	H	n-C3H7	H
VIII-m-105	3748	H	H	H	n-C4H9	H
VIII-m-106	3749	H	H	H	t-C4H9	H
VIII-m-107	3750	H	H	Ph	H	H
VIII-m-108	3751	H	H	H	Ph	H
VIII-m-109	3752	H	H	H	H	Ph
VIII-m-110	3753	H	H	H	1-naphthyl	H
VIII-m-111	3754	H	H	H	2-naplithyl	H
VIII-m-112	3755	H	H	H	4-biphenylyl	H
VIII-m-113	3756	H	H	H	3-biphenylyl	H
VIII-m-114	3757	H	H	H	2-biphenylyl	H
VIII-m-115	3758	H	H	H	2-biphenylyl	H
VIII-m-116	3759	Ph	Ph	H	H	H
VIII-m-117	3760	Ph	Ph	CH3	H	H
VIII-m-118	3761	Ph	Ph	H	CH3	H
VIII-m-119	3762	Ph	Ph	H	H	CH3
VIII-m-120	3763	Ph	Ph	H	n-C2H5	H
VIII-m-121	3764	Ph	Ph	H	n-C3H7	H
VIII-m-122	3765	Ph	Ph	H	n-C4H9	H
VIII-m-123	3766	Ph	Ph	H	t-C4H9	H
VIII-m-124	3767	Ph	Ph	Ph	H	H
VIII-m-125	3768	Ph	Ph	H	Ph	H
VIII-m-126	3769	Ph	Ph	H	H	Ph
VIII-m-127	3770	Ph	Ph	H	1-naphthyl	H
VIII-m-128	3771	Ph	Ph	H	2-naphthyl	H
VIII-m-129	3772	Ph	Ph	H	4-biphenylyl	H
VIII-m-130	3773	Ph	Ph	H	3-biphenylyl	H
VIII-m-131	3774	Ph	Ph	H	2-biphenylyl	H
VIII-m-132	3775	3776	3777	H	H	H
VIII-m-133	3778	3779	3780	CH3	H	H
VIII-m-134	3781	3782	3783	H	CH3	H
VIII-m-135	3784	3785	3786	H	H	CH3
VIII-m-136	3787	3788	3789	H	n-C2H5	H
VIII-m-137	3790	3791	3792	H	n-C3H7	H
VIII-m-138	3793	3794	3795	H	n-C4H9	H
VIII-m-139	3796	3797	3798	H	t-C4H9	H
VIII-m-140	3799	3800	3801	Ph	H	H
VIII-m-141	3802	3803	3804	H	Ph	H
VIII-m-142	3805	3806	3807	H	H	Ph
VIII-m-143	3808	3809	3810	H	1-naphthyl	H
VIII-m-144	3811	3812	3813	H	2-naphthyl	H
VIII-m-145	3814	3815	3816	H	4-biphenylyl	H
VIII-m-146	3817	3818	3819	H	3-biphenylyl	H
VIII-m-147	3820	3821	3822	H	3-biphenylyl	H

[0263] These quinoxaline compounds are obtained by (i) a process involving condensing diaminobenzene or derivatives thereof, diaminopyridine or derivatives thereof, diaminopyrimidine or derivatives thereof, diaminopyridazine or derivatives thereof with a halogenated diketone compound, followed by coupling using a nickel complex of 1,5-cyclooctadiene or the like, (ii) condensing diaminobenzene or derivatives thereof, diaminopyridine or derivatives thereof, diaminopyrimidine or derivatives thereof, diaminopyridazine or derivatives thereof with a bisdiketone compound, (iii) condensing a bisdiamine compound with a diketone compound, or (iv) converting a starting compound into an organometallic reagent of tin or the like, followed by cross-coupling.

[0264] These compounds can be identified by elemental analysis, mass analysis, IR spectroscopy, 1H and 13C NMR, etc.

[0265] In general, the quinoxaline compounds have a molecular weight of about 500 to about 2,000, a melting point of about 250 to about 500° C., and a glass transition temperature (Tg) of about 90 to about 200° C. By conventional vacuum deposition or the like, they form a transparent, smooth film of quality which maintains a stable amorphous state even above room temperature and over a long period of time.

[0266] The term “host material” used herein means a material which participates in light emission, but does not emit light by itself or emits light at a very low luminance. Specifically, an appropriate difference in luminance between the host and the dopant is such that the maximum luminance of the host is equal to or less than 10%, especially equal to or less than 2% of the maximum luminance of the dopant.

[0267] Dopants

[0268] A class of organic compounds useful as the dopant according to the invention are compounds of the following formula (V). 3823

[0269] Herein X1 to X10, L1 and L2 are independently hydrogen, halogen atoms, straight, branched or cyclic alkyl radicals which may have substituents, straight, branched or cyclic alkoxy radicals which may have substituents, straight, branched or cyclic alkylthio radicals which may have substituents, straight, branched or cyclic alkenyl radicals which may have substituents, straight, branched or cyclic alkenyloxy radicals which may have substituents, straight, branched or cyclic alkenylthio radicals which may have substituents, substituted or unsubstituted aralkyl radicals, substituted or unsubstituted aralkyloxy radicals, substituted or unsubstituted aralkylthio radicals, substituted or unsubstituted aryl radicals, substituted or unsubstituted aryloxy radicals, substituted or unsubstituted arylthio radicals, substituted or unsubstituted amino radicals, cyano, hydroxyl, —COOR1 radicals (wherein R1 is hydrogen, a substituted or unsubstituted straight, branched or cyclic alkyl radical, a substituted or unsubstituted straight, branched or cyclic alkenyl radical, a substituted or unsubstituted aralkyl radical or a substituted or unsubstituted aryl radical), —COR2 radicals (wherein R2 is hydrogen, a substituted or unsubstituted straight, branched or cyclic alkyl radical, a substituted or unsubstituted straight, branched or cyclic alkenyl radical, a substituted or unsubstituted aralkyl radical, a substituted or unsubstituted aryl radical or an amino radical), or —OCOR3 radicals (wherein R3 is a substituted or unsubstituted straight, branched or cyclic alkyl radical, a substituted or unsubstituted straight, branched or cyclic alkenyl radical, a substituted or unsubstituted aralkyl radical, or a substituted or unsubstituted aryl radical), or at least two adjoining groups selected from X1 to X10, L1 and L2 may bond or fuse together to form a substituted or unsubstituted carbocyclic aliphatic ring, aromatic ring or fused aromatic ring with the carbon atoms to which they are attached, or L1 and L2 each may be a single bond.

[0270] Preferably, at least two adjoining groups selected from X1 to X10, L1 and L2 bond or fuse together to form a substituted or unsubstituted carbocyclic aliphatic ring, aromatic ring or fused aromatic ring with the carbon atoms to which they are attached. L1 and L2 each may be a single bond. n is 1 or 2.

[0271] Of the compounds of formula (V), preferred are diindeno[1,2,3-cd:1′,2′,3′-lm]perylene derivatives, having a skeleton of the following formula (VI). 3824

[0272] In formula (VI), X1 to X6, X9 to X10, X11 to X16, X19 and X20 are independently hydrogen, halogen atoms, straight, branched or cyclic alkyl radicals which may have substituents, straight, branched or cyclic alkoxy radicals which may have substituents, straight, branched or cyclic alkylthio radicals which may have substituents, straight, branched or cyclic alkenyl radicals which may have substituents, straight, branched or cyclic alkenyloxy radicals which may have substituents, straight, branched or cyclic alkenylthio radicals which may have substituents, substituted or unsubstituted aralkyl radicals, substituted or unsubstituted aralkyloxy radicals, substituted or unsubstituted aralkylthio radicals, substituted or unsubstituted aryl radicals, substituted or unsubstituted aryloxy radicals, substituted or unsubstituted arylthio radicals, substituted or unsubstituted arylalkenyl radicals, substituted or unsubstituted alkenylaryl radicals, substituted or unsubstituted amino radicals, cyano, hydroxyl, —COOR1 radicals (wherein R1 is hydrogen, a substituted or unsubstituted straight, branched or cyclic alkyl radical, a substituted or unsubstituted straight, branched or cyclic alkenyl radical, a substituted or unsubstituted aralkyl radical or a substituted or unsubstituted aryl radical), —COR2 radicals (wherein R2 is hydrogen, a substituted or unsubstituted straight, branched or cyclic alkyl radical, a substituted or unsubstituted straight, branched or cyclic alkenyl radical, a substituted or unsubstituted aralkyl radical, a substituted or unsubstituted aryl radical or an amino radical), or —OCOR3 radicals (wherein R3 is a substituted or unsubstituted straight, branched or cyclic alkyl radical, a substituted or unsubstituted straight, branched or cyclic alkenyl radical, a substituted or unsubstituted aralkyl radical, or a substituted or unsubstituted aryl radical), or at least two adjoining groups selected from X1 to X20 may bond together to form a substituted or unsubstituted carbocyclic aliphatic ring, aromatic ring or fused aromatic ring with the carbon atoms to which they are attached.

[0273] The term “aryl radicals” is used herein to encompass carbocyclic aromatic radicals such as phenyl and naphthyl and heterocyclic aromatic radicals such as furyl, thienyl and pyridyl.

[0274] The straight, branched or cyclic alkyl radicals, straight, branched or cyclic alkoxy radicals, straight, branched or cyclic alkylthio radicals, straight, branched or cyclic alkenyl radicals, straight, branched or cyclic alkenyloxy radicals, and straight, branched or cyclic alkenylthio radicals, represented by X1 to X20 in formulas (V) and (VI), may have a substituent or substituents, for example, halogen atoms, aryl groups of 4 to 20 carbon atoms, alkoxy groups of 1 to 20 carbon atoms, alkoxyalkoxy groups of 2 to 20 carbon atoms, alkenyloxy groups of 2 to 20 carbon atoms, aralkyloxy groups of 4 to 20 carbon atoms, aralkyloxyalkoxy groups of 5 to 20 carbon atoms, aryloxy groups of 3 to 20 carbon atoms, aryloxyalkoxy groups of 4 to 20 carbon atoms, arylalkenyl groups of 5 to 20 carbon atoms, aralkylalkenyl groups of 6 to 20 carbon atoms, alkylthio groups of 1 to 20 carbon atoms, alkoxyalkylthio groups of 2 to 20 carbon atoms, alkylthioalkylthio groups of 2 to 20 carbon atoms, alkenylthio groups of 2 to 20 carbon atoms, aralkylthio groups of 4 to 20 carbon atoms, aralkyloxyalkylthio groups of 5 to 20 carbon atoms, aralkylthioalkylthio groups of 5 to 20 carbon atoms, arylthio groups of 3 to 20 carbon atoms, aryloxyalkylthio groups of 4 to 20 carbon atoms, arylthioalkylthio groups of 4 to 20 carbon atoms, and heteroatom-containing cyclic alkyl groups of 4 to 20 carbon atoms. The aryl groups included in these substituents may be further substituted with halogen atoms, alkyl groups of 1 to 10 carbon atoms, alkoxy groups of 1 to 10 carbon atoms, aryl groups of 3 to 10 carbon atoms, and aralkyl groups of 4 to 10 carbon atoms, among others.

[0275] The aralkyl radicals, aralkyloxy radicals, aralkylthio radicals, aryl radicals, aryloxy radicals and arylthio radicals, represented by X1 to X20 in formulas (V) and (VI), may have a substituent or substituents, for example, alkyl groups of 1 to 20 carbon atoms, alkenyl groups of 2 to 20 carbon atoms, aralkyl groups of 4 to 20 carbon atoms, aryl groups of 3 to 20 carbon atoms, alkoxy groups of 1 to 20 carbon atoms, alkoxyalkyl groups of 2 to 20 carbon atoms, alkoxyalkyloxy groups of 2 to 20 carbon atoms, alkenyloxy groups of 2 to 20 carbon atoms, alkenyloxyalkyl groups of 3 to 20 carbon atoms, alkenyloxyalkyloxy groups of 3 to 20 carbon atoms, aralkyloxy groups of 4 to 20 carbon atoms, aralkyloxyalkyl groups of 5 to 20 carbon atoms, aralkyloxyalkyloxy groups of 5 to 20 carbon atoms, aryloxy groups of 3 to 20 carbon atoms, aryloxyalkyl groups of 4 to 20 carbon atoms, aryloxyalkyloxy groups of 4 to 20 carbon atoms, alkylcarbonyl groups of 2 to 20 carbon atoms, alkenylcarbonyl groups of 3 to 20 carbon atoms, aralkylcarbonyl groups of 5 to 20 carbon atoms, arylcarbonyl groups of 4 to 20 carbon atoms, alkoxycarbonyl groups of 2 to 20 carbon atoms, alkenyloxycarbonyl groups of 3 to 20 carbon atoms, aralkyloxycarbonyl groups of 5 to 20 carbon atoms, aryloxycarbonyl groups of 4 to 20 carbon atoms, alkylcarbonyloxy groups of 2 to 20 carbon atoms, alkenylcarbonyloxy groups of 3 to 20 carbon atoms, aralkylcarbonyloxy groups of 5 to 20 carbon atoms, arylcarbonyloxy groups of 4 to 20 carbon atoms, alkylthio groups of 1 to 20 carbon atoms, aralkylthio groups of 4 to 20 carbon atoms, arylthio groups of 3 to 20 carbon atoms, nitro, cyano, formyl, halogen atoms, halogenated alkyl, hydroxyl, amino, N-mono-substituted amino groups of 1 to 20 carbon atoms, and N,N-di-substituted amino groups of 2 to 40 carbon atoms. The aryl groups included in these substituents may be further substituted with halogen atoms, alkyl groups of 1 to 10 carbon atoms, alkoxy groups of 1 to 10 carbon atoms, aryl groups of 6 to 10 carbon atoms, and aralkyl groups of 7 to 10 carbon atoms, among others.

[0276] The amino radicals represented by X1 to X20 in formulas (V) and (VI) may have a substituent or substituents, for example, be mono- or di-substituted with alkyl groups of 1 to 20 carbon atoms, aralkyl groups of 4 to 20 carbon atoms, and aryl groups of 3 to 20 carbon atoms.

[0277] The alkyl, alkenyl, aralkyl and aryl radicals represented by R1, R2 and R3 in formulas (V) and (VI) may have a substituent or substituents, as exemplified for X1 to X20.

[0278] In a preferred embodiment, X5, X6, X9, X10, X15, X16, X19 and X20 are hydrogen, and X1 to X4 and X11 to X14 are independently hydrogen, halogen atoms, straight, branched or cyclic alkyl radicals of 1 to 24 carbon atoms in total which may have substituents, straight, branched or cyclic alkoxy radicals of 1 to 24 carbon atoms in total which may have substituents, straight, branched or cyclic alkenyl, alkenylaryl and arylalkenyl radicals of 2 to 24 carbon atoms in total which may have substituents, substituted or unsubstituted aralkyl groups of 7 to 24 carbon atoms in total, substituted or unsubstituted aryl radicals of 6 to 24 carbon atoms in total, cyano radicals, heterocyclic radicals, hydroxyl radicals, —COOR1, —COR2 or —OCOR3 radicals wherein R1, R2 and R3 are as defined above.

[0279] Two adjoining groups selected from X1 to X20 may bond or fuse together to form a substituted or unsubstituted carbocyclic aliphatic ring, aromatic ring or fused aromatic ring with the carbon atoms to which they are attached.

[0280] The organic EL device of the invention is characterized by the inclusion of at least one fluoranthene derivative or diindeno[1,2,3-cd:1′,2′,3′-lm]perylene derivative. The use of a diindeno[1,2,3-cd:1′,2′,3′-lm]perylene derivative in a light emitting layer as a luminescent component, for example, enables to produce an organic EL device having improved luminance and durability over similar EL devices of the prior art. The use of the specific derivative in combination with another luminescent component to form a light emitting layer enables to produce an organic EL device capable of emitting white light and having improved luminance and durability.

[0281] Illustrative, non-limiting, examples of the compounds of formulas (V) and (VI) according to the invention are given below. Ph designates phenyl.

				+TC,51/
3825	“A and B form a fused ring” in	3826	means	3827
Com-
pound
No.	X1	X2	X3	X6	X7	X8
A-1	H	H	H	H	H	H
A-2	H	H	H	H	H	H
A-3	H	H	H	H	H	H
A-4	H	H	H	H	H	H
A-5	H	H	H	H	H	H
A-6	H	H	H	H	H	H
A-7	H	H	H	H	H	H
A-8	H	H	H	H	H	H
A-9	H	H	H	H	H	H
A-10	H	H	H	H	H	H
A-11	Ph	H	H	H	H	Ph
A-12	3828	H	H	H	H	3829
A-13	CH3	H	H	H	H	CH3
A-14	H	Ph	H	H	Ph	H
A-15	H	3830	H	H	3831	H
A-16	H	CH3	H	H	CH3	H
A-17	X1 and X2 form a fused ring.	H	H	H	H
A-18	X1 and X2 form a fused ring.	H	H	H	H
A-19	X1 and X2 form a fused ring.	H	H	H	H
A-20	X1 and X2 form a fused ring.	H	H	H	H
A-21	X1 and X2 form a fused ring.	H	H	H	H
A-22	X1 and X2 form a fused ring.	H	H	H	H
A-23	X1 and X2 form a fused ring.	H	H	H	H
A-24	X1 and X2 form a fused ring.	H	H	H	H
A-25	X1 and X2 form a fused ring.	H	H	H	H
A-26	X1 and X2 form a fused ring.	H	H	H	H
A-27	X1 and X2 form a fused ring.	H	H	H	Ph
A-28	X1 and X2 form a fused ring.	H	H	H	3832
A-29	X1 and X2 form a fused ring.	H	H	H	CH3
A-30	X1 and X2 form a fused ring.	H	H	Ph	H
A-31	X1 and X2 form a fused ring.	H	H	3833	H
A-32	X1 and X2 form a fused ring.	H	H	CH3	H
A-33	H	H	H	H	H	H
A-34	H	H	H	H	H	H
A-35	H	H	H	H	H	H
A-36	H	H	H	H	H	H
A-37	H	H	H	H	H	H
A-38	H	H	H	H	H	H
A-39	H	H	H	H	H	H
A-40	H	H	H	H	H	H
A-41	H	H	H	H	H	H
A-42	H	H	H	H	H	H
A-43	Ph	H	H	H	H	Ph
A-44	3834	H	H	H	H	3835
A-45	CH3	H	H	H	H	CH3
A-46	H	Ph	H	H	Ph	H
A-47	H	3836	H	H	3837	H
A-48		CH3	H	H	CH3	H
A-49	H	H	H	H	H	H
A-50	Ph	H	H	H	H	Ph
A-51	3838	H	H	H	H	3839
A-52	CH3	H	H	H	H	CH3
A-53	H	Ph	H	H	Ph	H
A-54	H	3840	H	H	3841	H
A-55	H	CH3	H	H	CH3	H
A-56	X1 and X2 form a fused ring.	H	H	X1 and X2 form a fused ring.
A-57	X1 and X2 form a fused ring.	H	H	X1 and X2 form a fused ring.
A-58	X1 and X2 form a fused ring.	H	H	X1 and X2 form a fused ring.
A-59	X1 and X2 form a fused ring.	H	H	X1 and X2 form a fused ring.
A-60	X1 and X2 form a fused ring.	H	H	X1 and X2 form a fused ring.
A-61	X1 and X2 form a fused ring.	H	H	X1 and X2 form a fused ring.
A-62	X1 and X2 form a fused ring.	H	H	X1 and X2 form a fused ring.
A-63	X1 and X2 form a fused ring.	H	H	X1 and X2 form a fused ring.
A-64	X1 and X2 form a fused ring.	H	H	X1 and X2 form a fused ring.
A-65	X1 and X2 form a fused ring.	H	H	X1 and X2 form a fused ring.
A-66	X1 and X2 form a fused ring.	H	H	X1 and X2 form a fused ring.
	Com-
	pound
	No.	X11	X12	X13	X14
	A-1	H	H	H	H
	A-2	Ph	H	H	Ph
	A-3	3842	H	H	3843
	A-4	3844	H	H	3845
	A-5	3846	H	H	3847
	A-6	CH3	H	H	CH3
	A-7	3848	H	H	3849
	A-8	Ph	Ph	Ph	Ph
	A-9	Ph	3850	3851	Ph
	A-10	Ph	CH3	CH3	Ph
	A-11	Ph	H	H	Ph
	A-12	Ph	H	H	Ph
	A-13	Ph	H	H	Ph
	A-14	Ph	H	H	Ph
	A-15	Ph	H	H	Ph
	A-16	Ph	H	H	Ph
	A-17	H	H	H	H
	A-18	Ph	H	H	Ph
	A-19	3852	H	H	3853
	A-20	3854	H	H	3855
	A-21	3856	H	H	3857
	A-22	CH3	H	H	CH3
	A-23	3858	H	H	3859
	A-24	Ph	Ph	Ph	Ph
	A-25	Ph	3860	3861	Ph
	A-26	Ph	CH3	CH3	Ph
	A-27	Ph	H	H	Ph
	A-28	Ph	H	H	Ph
	A-29	Ph	H	H	Ph
	A-30	Ph	H	H	Ph
	A-31	Ph	H	H	Ph
	A-32	Ph	H	H	Ph
	A-33	H	H	X13 and X14 form a fused ring.
	A-34	Ph	H	X13 and X14 form a fused ring.
	A-35	3862	H	X13 and X14 form a fused ring.
	A-36	3863	H	X13 and X14 form a fused ring.
	A-37	3864	H	X13 and X14 form a fused ring.
	A-38	CH3	H	X13 and X14 form a fused ring.
	A-39	3865	H	X13 and X14 form a fused ring.
	A-40	Ph	Ph	X13 and X14 form a fused ring.
	A-41	Ph	3866	X13 and X14 form a fused ring.
	A-42	Ph	CH3	X13 and X14 form a fused ring.
	A-43	Ph	H	X13 and X14 form a fused ring.
	A-44	Ph	H	X13 and X14 form a fused ring.
	A-45	Ph	H	X13 and X14 form a fused ring.
	A-46	Ph	H	X13 and X14 form a fused ring.
	A-47	Ph	H	X13 and X14 form a fused ring.
	A-48	Ph	H	X13 and X14 form a fused ring.
	A-49	X13 and X14 form a fused ring.	X13 and X14 form a fused ring.
	A-50	X13 and X14 form a fused ring.	X13 and X14 form a fused ring.
	A-51	X13 and X14 form a fused ring.	X13 and X14 form a fused ring.
	A-52	X13 and X14 form a fused ring.	X13 and X14 form a fused ring.
	A-53	X13 and X14 form a fused ring.	X13 and X14 form a fused ring.
	A-54	X13 and X14 form a fused ring.	X13 and X14 form a fused ring.
	A-55	X13 and X14 form a fused ring.	X13 and X14 form a fused ring.
	A-56	H	H	H	H
	A-57	Ph	H	H	Ph
	A-58	3867	H	H	3868
	A-59	3869	H	H	3870
	A-60	3871	H	H	3872
	A-61	CH3	H	H	CH3
	A-62	3873	H	H	3874
	A-63	Ph	Ph	Ph	Ph
	A-64	Ph	3875	3876	Ph
	A-65	Ph	CH3	CH3	Ph
	A-66	Ph	H	H	Ph

[0282]

3877	“A and B form a fused ring in	3878	means	3879
Compound No.	X1	X2	X3	X6	X7	X8	X11
B-1	H	H	H	H	H	H	H
B-2	H	H	H	H	H	H	Ph
B-3	H	H	H	H	H	H	3880
B-4	H	H	H	H	H	H	3881
B-5	H	H	H	H	H	H	3882
B-6	H	H	H	H	H	H	CH3
B-7	H	H	H	H	H	H	3883
B-8	3884	H	H	H	H	3885	Ph
B-9	CH3	H	H	H	H	CH3	Ph
B-10	H	Ph	H	H	Ph	H	Ph
B-11	H	3886	H	H	3887	H	Ph
B-12	H	CH3	H	H	CH3	H	Ph
B-13	H	H	H	H	X7 and X8 form a fused ring.	H
B-14	H	H	H	H	X7 and X8 form a fused ring.	Ph
B-15	H	H	H	H	X7 and X8 form a fused ring.	3888
B-16	H	H	H	H	X7 and X8 form a fused ring.	3889
B-17	H	H	H	H	X7 and X8 form a fused ring.	3890
B-18	H	H	H	H	X7 and X8 form a fused ring.	CH3
B-19	H	H	H	H	X7 and X8 form a fused ring.	3891
B-20	H	H	H	H	X7 and X8 form a fused ring.	Ph
B-21	H	H	H	H	X7 and X8 form a fused ring.	Ph
B-22	H	H	H	H	X7 and X8 form a fused ring.	Ph
B-23	H	H	H	H	X7 and X8 form a fused ring.	Ph
B-24	H	H	H	H	X7 and X8 form a fused ring.	Ph
B-25	H	H	H	H	X7 and X8 form a fused ring.	Ph
B-26	H	H	H	H	X7 and X8 form a fused ring.	Ph
B-27	H	H	H	H	X7 and X8 form a fused ring.	Ph
B-28	H	H	H	H	X7 and X8 form a fused ring.	Ph
B-29	Ph	H	H	H	X7 and X8 form a fused ring.	Ph
B-30	3892	H	H	H	X7 and X8 form a fused ring.	Ph
B-31	CH3	H	H	H	X7 and X8 form a fused ring.	Ph
B-32	H	H	H	H	H	H	H
B-33	H	H	H	H	H	H	Ph
B-34	H	H	H	H	H	H	3893
B-35	H	H	H	H	H	H	3894
B-36	H	H	H	H	H	H	3895
B-37	H	H	H	H	H	H	CH3
B-38	H	H	H	H	H	H	3896
B-39	H	H	H	H	H	H	Ph
B-40	H	H	H	H	H	H	Ph
B-41	H	H	H	H	H	H	Ph
B-42	H	H	H	H	H	H	Ph
B-43	H	H	H	H	H	H	Ph
B-44	H	H	H	H	H	H	Ph
B-45	H	H	H	H	H	H	Ph
B-46	H	H	H	H	H	H	Ph
B-47	H	H	H	H	H	H	Ph
B-48	Ph	H	H	H	H	Ph	Ph
B-49	3897	H	H	H	H	3898	Ph
B-50	CH3	H	H	H	H	CH3	Ph
B-51	H	Ph	H	H	Ph	H	Ph
B-52	H	3899	H	H	3900	H	Ph
B-53	H	CH3	H	H	CH3	H	Ph
B-54	H	H	H	H	H	H	H
B-55	H	H	H	H	H	H	Ph
B-56	H	H	H	H	H	H	3901
B-57	H	H	H	H	H	H	3902
B-58	H	H	H	H	H	H	3903
B-59	H	H	H	H	H	H	CH3
B-60	H	H	H	H	H	H	3904
B-61	H	H	H	H	H	H	Ph
B-62	H	H	H	H	H	H	Ph
B-63	H	H	H	H	H	H	Ph
B-64	H	H	H	H	H	H	Ph
B-65	H	H	H	H	H	H	Ph
B-66	H	H	H	H	H	H	Ph
B-67	H	H	H	H	H	H	Ph
B-68	H	H	H	H	H	H	Ph
B-69	H	H	H	H	H	H	Ph
B-70	Ph	H	H	H	H	Ph	Ph
B-71	3905	H	H	H	H	3906	Ph
B-72	CH3	H	H	H	H	CH3	Ph
B-73	H	Ph	H	H	Ph	H	Ph
B-74	H	3907	H	H	3908	H	Ph
B-75	H	CH3	H	H	CH3	H	Ph
B-76	X1 and X2 form a fused ring.	H	H	X7 and X8 form a fused ring.	H
B-77	X1 and X2 form a fused ring.	H	H	X7 and X8 form a fused ring.	Ph
B-78	X1 and X2 form a fused ring.	H	H	X7 and X8 form a fused ring.	3909
B-79	X1 and X2 form a fused ring.	H	H	X7 and X8 form a fused ring.	3910
B-80	X1 and X2 form a fused ring.	H	H	X7 and X8 form a fused ring.	3911
B-81	X1 and X2 form a fused ring.	H	H	X7 and X8 form a fused ring.	CH3
B-82	X1 and X2 form a fused ring.	H	H	X7 and X8 form a fused ring.	3912
B-83	X1 and X2 form a fused ring.	H	H	X7 and X8 form a fused ring.	Ph
B-84	X1 and X2 form a fused ring.	H	H	X7 and X8 form a fused ring.	Ph
B-85	X1 and X2 form a fused ring.	H	H	X7 and X8 form a fused ring.	Ph
B-86	X1 and X2 form a fused ring.	H	H	X7 and X8 form a fused ring.	Ph
B-87	X1 and X2 form a fused ring.	H	H	X7 and X8 form a fused ring.	Ph
B-88	X1 and X2 form a fused ring.	H	H	X7 and X8 form a fused ring.	Ph
B-89	X1 and X2 form a fused ring.	H	H	X7 and X8 form a fused ring.	Ph
B-90	X1 and X2 form a fused ring.	H	H	X7 and X8 form a fused ring.	Ph
B-91	X1 and X2 form a fused ring.	H	H	X7 and X8 form a fused ring.	Ph
	Compound No.	X14	X15	X16	X17	X18
	B-1	H	X15 and X16 form a fused ring.	X17 and X18 form a fused ring.
	B-2	Ph	X15 and X16 form a fused ring.	X17 and X18 form a fused ring.
	B-3	3913	X15 and X16 form a fused ring.	X17 and X18 form a fused ring.
	B-4	3914	X15 and X16 form a fused ring.	X17 and X18 form a fused ring.
	B-5	3915	X15 and X16 form a fused ring.	X17 and X18 form a fused ring.
	B-6	CH3	X15 and X16 form a fused ring.	X17 and X18 form a fused ring.
	B-7	3916	X15 and X16 form a fused ring.	X17 and X18 form a fused ring.
	B-8	Ph	X15 and X16 form a fused ring.	X17 and X18 form a fused ring.
	B-9	Ph	X15 and X16 form a fused ring.	X17 and X18 form a fused ring.
	B-10	Ph	X15 and X16 form a fused ring.	X17 and X18 form a fused ring.
	B-11	Ph	X15 and X16 form a fused ring.	X17 and X18 form a fused ring.
	B-12	Ph	X15 and X16 form a fused ring.	X17 and X18 form a fused ring.
	B-13	H	H	H	H	H
	B-14	Ph	H	H	H	H
	B-15	3917	H	H	H	H
	B-16	3918	H	H	H	H
	B-17	3919	H	H	H	H
	B-18	CH3	H	H	H	H
	B-19	3920	H	H	H	H
	B-20	Ph	Ph	H	H	Ph
	B-21	Ph	3921	H	H	3922
	B-22	Ph	3923	H	H	3924
	B-23	Ph	3925	H	H	3926
	B-24	Ph	CH3	H	H	CH3
	B-25	Ph	3927	H	H	3928
	B-26	Ph	H	Ph	Ph	H
	B-27	Ph	H	3929	3930	H
	B-28	Ph	H	CH3	CH3	H
	B-29	Ph	H	H	H	H
	B-30	Ph	H	H	H	H
	B-31	Ph	H	H	H	H
	B-32	H	X15 and X16 form a fused ring.	H	H
	B-33	Ph	X15 and X16 form a fused ring.	H	H
	B-34	3931	X15 and X16 form a fused ring.	H	H
	B-35	3932	X15 and X16 form a fused ring.	H	H
	B-36	3933	X15 and X16 form a fused ring.	H	H
	B-37	CH3	X15 and X16 form a fused ring.	H	H
	B-38	3934	X15 and X16 form a fused ring.	H	H
	B-39	Ph	X15 and X16 form a fused ring.	H	Ph
	B-40	Ph	X15 and X16 form a fused ring.	H	3935
	B-41	Ph	X15 and X16 form a fused ring.	H	3936
	B-42	Ph	X15 and X16 form a fused ring.	H	3937
	B-43	Ph	X15 and X16 form a fused ring.	H	CH3
	B-44	Ph	X15 and X16 form a fused ring.	H	3938
	B-45	Ph	X15 and X16 form a fused ring.	Ph	H
	B-46	Ph	X15 and X16 form a fused ring.	3939	H
	B-47	Ph	X15 and X16 form a fused ring.	CH3	H
	B-48	Ph	X15 and X16 form a fused ring.	H	H
	B-49	Ph	X15 and X16 form a fused ring.	H	H
	B-50	Ph	X15 and X16 form a fused ring.	H	H
	B-51	Ph	X15 and X16 form a fused ring.	H	H
	B-52	Ph	X15 and X16 form a fused ring.	H	H
	B-53	Ph	X15 and X16 form a fused ring.	H	H
	B-54	H	H	H	H	H
	B-55	Ph	H	H	H	H
	B-56	3940	H	H	H	H
	B-57	3941	H	H	H	H
	B-58	3942	H	H	H	H
	B-59	CH3	H	H	H	H
	B-60	3943	H	H	H	H
	B-61	Ph	Ph	H	H	Ph
	B-62	Ph	3944	H	H	3945
	B-63	Ph	3946	H	H	3947
	B-64	Ph	3948	H	H	3949
	B-65	Ph	CH3	H	H	CH3
	B-66	Ph	3950	H	H	3951
	B-67	Ph	H	Ph	Ph	H
	B-68	Ph	H	3952	3953	H
	B-69	Ph	H	CH3	CH3	H
	B-70	Ph	H	H	H	H
	B-71	Ph	H	H	H	H
	B-72	Ph	H	H	H	H
	B-73	Ph	H	H	H	H
	B-74	Ph	H	H	H	H
	B-75	Ph	H	H	H	H
	B-76	H	H	H	H	H
	B-77	Ph	H	H	H	H
	B-78	3954	H	H	H	H
	B-79	3955	H	H	H	H
	B-80	3956	H	H	H	H
	B-81	CH3	H	H	H	H
	B-82	3957	H	H	H	H
	B-83	Ph	Ph	H	H	Ph
	B-84	Ph	3958	H	H	3959
	B-85	Ph	3960	H	H	3961
	B-86	Ph	3962	H	H	3963
	B-87	Ph	CH3	H	H	CH3
	B-88	Ph	3964	H	H	3965
	B-89	Ph	H	Ph	Ph	H
	B-90	Ph	H	3966	3967	H
	B-91	Ph	H	CH3	CH3	H
3968	“C, A and B form a fused ring” in	3969	means	3970
Compound No.	X1	X2	X8	X3	X6	X7	X11	X14
B-92	X1, X2 and X8 form a fused ring.	H	H	H	H	H
B-93	X1, X2 and X8 form a fused ring.	H	H	H	Ph	Ph
B-94	X1, X2 and X8 form a fused ring.	H	H	H	3971	3972
B-95	X1, X2 and X8 form a fused ring.	H	H	H	3973	3974
B-96	X1, X2 and X8 form a fused ring.	H	H	H	3975	3976
B-97	X1, X2 and X8 form a fused ring.	H	H	H	CH3	CH3
B-98	X1, X2 and X8 form a fused ring.	H	H	H	3977	3978
B-99	X1, X2 and X8 form a fused ring.	H	H	H	Ph	Ph
B-100	X1, X2 and X8 form a fused ring.	H	H	H	Ph	Ph
B-101	X1, X2 and X8 form a fused ring.	H	H	H	Ph	Ph
B-102	X1, X2 and X8 form a fused ring.	H	H	H	Ph	Ph
B-103	X1, X2 and X8 form a fused ring.	H	H	H	Ph	Ph
B-104	X1, X2 and X8 form a fused ring.	H	H	H	Ph	Ph
B-105	X1, X2 and X8 form a fused ring.	H	H	H	Ph	Ph
B-106	X1, X2 and X8 form a fused ring.	H	H	H	Ph	Ph
B-107	X1, X2 and X8 form a fused ring.	H	H	H	Ph	Ph
B-108	X1, X2 and X8 form a fused ring.	H	H	Ph	Ph	Ph
B-109	X1, X2 and X8 form a fused ring.	H	H	3979	Ph	Ph
B-110	X1, X2 and X8 form a fused ring.	H	H	CH3	Ph	Ph
	Compound No.	X15	X16	X17	X18
	B-92	H	H	H	H
	B-93	H	H	H	H
	B-94	H	H	H	H
	B-95	H	H	H	H
	B-96	H	H	H	H
	B-97	H	H	H	H
	B-98	H	H	H	H
	B-99	Ph	H	H	Ph
	B-100	3980	H	H	3981
	B-101	3982	H	H	3983
	B-102	3984	H	H	3985
	B-103	CH3	H	H	CH3
	B-104	3986	H	H	3987
	B-105	H	Ph	Ph	H
	B-106	H	3988	3989	H
	B-107	H	CH3	CH3	H
	B-108	H	H	H	H
	B-109	H	H	H	H
	B-110	H	H	H	H

[0283]

3990	“A and B form a fused ring in	3991	means	3992
Com-
pound
No.	X1	X2	X3	X6	X7	X8
C-1	H	H	H	H	H	H
C-2	H	H	H	H	H	H
C-3	H	H	H	H	H	H
C-4	H	H	H	H	H	H
C-5	H	H	H	H	H	H
C-6	H	H	H	H	H	H
C-7	H	H	H	H	H	H
C-8	H	H	H	H	H	H
C-9	H	H	H	H	H	H
C-10	H	H	H	H	H	H
C-11	Ph	H	H	H	H	Ph
C-12	3993	H	H	H	H	3994
C-13	CH3	H	H	H	H	CH3
C-14	H	Ph	H	H	Ph	H
C-15	H	3995	H	H	3996	H
C-16	H	CH3	H	H	CH3	H
	Com-
	pound
	No.	X11	X14	P1	P2
	C-1	H	H	H	H
	C-2	Ph	Ph	H	H
	C-3	3997	3998	H	H
	C-4	3999	4000	H	H
	C-5	4001	4002	H	H
	C-6	CH3	CH3	H	H
	C-7	4003	4004	H	H
	C-8	Ph	Ph	Ph	Ph
	C-9	Ph	Ph	4005	4006
	C-10	Ph	Ph	CH3	CH3
	C-11	Ph	Ph	H	H
	C-12	Ph	Ph	H	H
	C-13	Ph	Ph	H	H
	C-14	Ph	Ph	H	H
	C-15	Ph	Ph	H	H
	C-16	Ph	Ph	H	H

[0284]

4007	“A and B form a fused ring” in	4008	means	4009
Compound No.	X1	X2	X3	X4	X5	X6	X7	X8	X11	X14
D-1	H	H	H	H	H	H	H	H	H	H
D-2	H	H	H	H	H	H	H	H	Ph	Ph
D-3	H	H	H	H	H	H	H	H	4010	4011
D-4	H	H	H	H	H	H	H	H	4012	4013
D-5	H	H	H	H	H	H	H	H	CH3	CH3
D-6	H	H	H	H	H	H	H	H	4014	4015
D-7	H	H	H	H	H	H	H	H	4016	4017
D-8	H	H	H	H	H	H	H	H	Ph	Ph
D-9	H	H	H	H	H	H	H	H	Ph	Ph
D-10	H	H	H	H	H	H	H	H	Ph	Ph
D-11	H	H	H	H	H	H	H	H	Ph	Ph
D-12	H	H	H	H	H	H	H	H	Ph	Ph
D-13	H	H	H	H	H	H	H	H	Ph	Ph
D-14	Ph	H	H	H	H	H	H	Ph	Ph	Ph
D-15	4018	H	H	H	H	H	H	4019	Ph	Ph
D-16	CH3	H	H	H	H	H	H	CH3	Ph	Ph
D-17	H	H	H	H	X5 and X6 form a fused ring.	H	H	H	H
D-18	H	H	H	H	X5 and X6 form a fused ring.	H	H	Ph	Ph
D-19	H	H	H	H	X5 and X6 form a fused ring.	H	H	4020	4021
D-20	H	H	H	H	X5 and X6 form a fused ring.	H	H	4022	4023
D-21	H	H	H	H	X5 and X6 form a fused ring.	H	H	CH3	CH3
D-22	H	H	H	H	X5 and X6 form a fused ring.	H	H	4024	4025
D-23	H	H	H	H	X5 and X6 form a fused ring.	H	H	4026	4027
D-24	H	H	H	H	X5 and X6 form a fused ring.	H	H	Ph	Ph
D-25	H	H	H	H	X5 and X6 form a fused ring.	H	H	Ph	Ph
D-26	H	H	H	H	X5 and X6 form a fused ring.	H	H	Ph	Ph
D-27	H	H	H	H	X5 and X6 form a fused ring.	H	H	Ph	Ph
D-28	H	H	H	H	X5 and X6 form a fused ring.	H	H	Ph	Ph
D-29	H	H	H	H	X5 and X6 form a fused ring.	H	H	Ph	Ph
D-30	Ph	H	H	H	X5 and X6 form a fused ring.	H	Ph	Ph	Ph
D-31	4028	H	H	H	X5 and X6 form a fused ring.	H	4029	Ph	Ph
D-32	CH3	H	H	H	X5 and X6 form a fused ring.	H	CH3	Ph	Ph
	Compound No.	X15	X16	X17	X18
	D-1	H	H	H	H
	D-2	H	H	H	H
	D-3	H	H	H	H
	D-4	H	H	H	H
	D-5	H	H	H	H
	D-6	H	H	H	H
	D-7	H	H	H	H
	D-8	Ph	H	H	Ph
	D-9	4030	H	H	4031
	D-10	CH3	H	H	CH3
	D-11	H	Ph	Ph	H
	D-12	H	4032	4033	H
	D-13	H	CH3	CH3	H
	D-14	H	H	H	H
	D-15	H	H	H	H
	D-16	H	H	H	H
	D-17	H	H	H	H
	D-18	H	H	H	H
	D-19	H	H	H	H
	D-20	H	H	H	H
	D-21	H	H	H	H
	D-22	H	H	H	H
	D-23	H	H	H	H
	D-24	Ph	H	H	Ph
	D-25	4034	H	H	4035
	D-26	CH3	H	H	CH3
	D-27	H	Ph	Ph	H
	D-28	H	4036	4037	H
	D-29	H	CH3	CH3	H
	D-30	H	H	H	H
	D-31	H	H	H	H
	D-32	H	H	H	H
4038	“A and B form a fused ring” in	4039	means	4040
Compound No.	X1	X2	X3	X4	X5	X6	X7	X8	X11
D-33	H	H	H	H	H	H	H	H	H
D-34	H	H	H	H	H	H	H	H	Ph
D-35	H	H	H	H	H	H	H	H	4041
D-36	H	H	H	H	H	H	H	H	4042
D-37	H	H	H	H	H	H	H	H	CH3
D-38	H	H	H	H	H	H	H	H	4043
D-39	H	H	H	H	H	H	H	H	4044
D-40	H	H	H	H	H	H	H	H	Ph
D-41	H	H	H	H	H	H	H	H	Ph
D-42	H	H	H	H	H	H	H	H	Ph
D-43	Ph	H	H	H	H	H	H	Ph	Ph
D-44	4045	H	H	H	H	H	H	4046	Ph
D-45	CH3	H	H	H	H	H	H	CH3	Ph
D-46	H	H	H	H	X5 and X6 form a fused ring.	H	H	H
D-47	H	H	H	H	X5 and X6 form a fused ring.	H	H	Ph
D-48	H	H	H	H	X5 and X6 form a fused ring.	H	H	4047
D-49	H	H	H	H	X5 and X6 form a fused ring.	H	H	4048
D-50	H	H	H	H	X5 and X6 form a fused ring.	H	H	CH3
D-51	H	H	H	H	X5 and X6 form a fused ring.	H	H	4049
D-52	H	H	H	H	X5 and X6 form a fused ring.	H	H	4050
D-53	H	H	H	H	X5 and X6 form a fused ring.	H	H	Ph
D-54	H	H	H	H	X5 and X6 form a fused ring.	H	H	Ph
D-55	H	H	H	H	X5 and X6 form a fused ring.	H	H	Ph
D-56	Ph	H	H	H	X5 and X6 form a fused ring.	H	Ph	Ph
D-57	4051	H	H	H	X5 and X6 form a fused ring.	H	4052	Ph
D-58	CH3	H	H	H	X5 and X6 form a fused ring.	H	CH3	Ph
D-59	H	X2 and X3 form a fused ring.	H	H	H	H	H	H
D-60	H	X2 and X3 form a fused ring.	H	H	H	H	H	Ph
D-61	H	X2 and X3 form a fused ring.	H	H	H	H	H	4053
D-62	H	X2 and X3 form a fused ring.	H	H	H	H	H	4054
D-63	H	X2 and X3 form a fused ring.	H	H	H	H	H	CH3
D-64	H	X2 and X3 form a fused ring.	H	H	H	H	H	4055
D-65	H	X2 and X3 form a fused ring.	H	H	H	H	H	4056
D-66	H	X2 and X3 form a fused ring.	H	H	H	H	H	Ph
D-67	H	X2 and X3 form a fused ring.	H	H	H	H	H	Ph
D-68	H	X2 and X3 form a fused ring.	H	H	H	H	H	Ph
D-69	Ph	X2 and X3 form a fused ring.	H	H	H	H	Ph	Ph
D-70	4057	X2 and X3 form a fused ring.	H	H	H	H	4058	Ph
D-71	CH3	X2 and X3 form a fused ring.	H	H	H	H	CH3	Ph
	Compound No.	X14	X15	X16
	D-33	H	H	H
	D-34	Ph	H	H
	D-35	4059	H	H
	D-36	4060	H	H
	D-37	CH3	H	H
	D-38	4061	H	H
	D-39	4062	H	H
	D-40	Ph	Ph	Ph
	D-41	Ph	4063	4064
	D-42	Ph	CH3	CH3
	D-43	Ph	H	H
	D-44	Ph	H	H
	D-45	Ph	H	H
	D-46	H	H	H
	D-47	Ph	H	H
	D-48	4065	H	H
	D-49	4066	H	H
	D-50	CH3	H	H
	D-51	4067	H	H
	D-52	4068	H	H
	D-53	Ph	Ph	Ph
	D-54	Ph	4069	4070
	D-55	Ph	CH3	CH3
	D-56	Ph	H	H
	D-57	Ph	H	H
	D-58	Ph	H	H
	D-59	H	H	H
	D-60	Ph	H	H
	D-61	4071	H	H
	D-62	4072	H	H
	D-63	CH3	H	H
	D-64	4073	H	H
	D-65	4074	H	H
	D-66	Ph	Ph	Ph
	D-67	Ph	4075	4076
	D-68	Ph	CH3	CH3
	D-69	Ph	H	H
	D-70	Ph	H	H
	D-71	Ph	H	H
4077	“A and B form a fused ring” in	4078	means	4079
Compound No.	X1	X2	X3	X4	X5	X6	X7	X8	X11	X14
D-72	H	X2 and X3 form a fused ring.	H	H	H	H	H	H	H
D-73	H	X2 and X3 form a fused ring.	H	H	H	H	H	Ph	Ph
D-74	H	X2 and X3 form a fused ring.	H	H	H	H	H	4080	4081
D-75	H	X2 and X3 form a fused ring.	H	H	H	H	H	4082	4083
D-76	H	X2 and X3 form a fused ring.	H	H	H	H	H	CH3	CH3
D-77	H	X2 and X3 form a fused ring.	H	H	H	H	H	4084	4085
D-78	H	X2 and X3 form a fused ring.	H	H	H	H	H	4086	4087
D-79	H	X2 and X3 form a fused ring.	H	H	H	H	H	Ph	Ph
D-80	H	X2 and X3 form a fused ring.	H	H	H	H	H	Ph	Ph
D-81	H	X2 and X3 form a fused ring.	H	H	H	H	H	Ph	Ph
D-82	H	X2 and X3 form a fused ring.	H	H	H	H	H	Ph	Ph
D-83	H	X2 and X3 form a fused ring.	H	H	H	H	H	Ph	Ph
D-84	H	X2 and X3 form a fused ring.	H	H	H	H	H	Ph	Ph
D-85	Ph	X2 and X3 form a fused ring.	H	H	H	H	Ph	Ph	Ph
D-86	4088	X2 and X3 form a fused ring.	H	H	H	H	4089	Ph	Ph
D-87	CH3	X2 and X3 form a fused ring.	H	H	H	H	CH3	Ph	Ph
D-88	H	X2 and X3 form a fused ring.	H	H	H	H	H	H	H
D-89	H	X2 and X3 form a fused ring.	H	H	H	H	H	Ph	Ph
D-90	H	X2 and X3 form a fused ring.	H	H	H	H	H	4090	4091
D-91	H	X2 and X3 form a fused ring.	H	H	H	H	H	4092	4093
D-92	H	X2 and X3 form a fused ring.	H	H	H	H	H	CH3	CH3
D-93	H	X2 and X3 form a fused ring.	H	H	H	H	H	4094	4095
D-94	H	X2 and X3 form a fused ring.	H	H	H	H	H	4096	4097
D-95	Ph	X2 and X3 form a fused ring.	H	H	H	H	Ph	Ph	Ph
D-96	4098	X2 and X3 form a fused ring.	H	H	H	H	4099	Ph	Ph
D-97	CH3	X2 and X3 form a fused ring.	H	H	H	H	CH3	Ph	Ph
	Compound No.	X15	X16	X17	X18
	D-72	H	H	H	H
	D-73	H	H	H	H
	D-74	H	H	H	H
	D-75	H	H	H	H
	D-76	H	H	H	H
	D-77	H	H	H	H
	D-78	H	H	H	H
	D-79	Ph	H	H	Ph
	D-80	4100	H	H	4101
	D-81	CH3	H	H	CH3
	D-82	H	Ph	Ph	H
	D-83	H	4102	4103	H
	D-84	H	CH3	CH3	H
	D-85	H	H	H	H
	D-86	H	H	H	H
	D-87	H	H	H	H
	D-88	X15 and X16 form a fused ring.	X17 and X18 form a fused ring.
	D-89	X15 and X16 form a fused ring.	X17 and X18 form a fused ring.
	D-90	X15 and X16 form a fused ring.	X17 and X18 form a fused ring.
	D-91	X15 and X16 form a fused ring.	X17 and X18 form a fused ring.
	D-92	X15 and X16 form a fused ring.	X17 and X18 form a fused ring.
	D-93	X15 and X16 form a fused ring.	X17 and X18 form a fused ring.
	D-94	X15 and X16 form a fused ring.	X17 and X18 form a fused ring.
	D-95	X15 and X16 form a fused ring.	X17 and X18 form a fused ring.
	D-96	X15 and X16 form a fused ring.	X17 and X18 form a fused ring.
	D-97	X15 and X16 form a fused ring.	X17 and X18 form a fused ring.

[0285]

4104	“A and B form a fused ring” in	4105	means	4106
Com-
pound
No.	X2	X3	X6	X7	X11 = 21	X12 = X22	X13 = X23	X14 = X24
E-1	H	H	H	H	H	H	H	H
E-2	H	H	H	H	Ph	H	H	Ph
E-3	H	H	H	H	4107	H	H	4108
E-4	H	H	H	H	4109	H	H	4110
E-5	H	H	H	H	4111	H	H	4112
E-6	H	H	H	H	CH3	H	H	CH3
E-7	H	H	H	H	4113	H	H	4114
E-8	H	H	H	H	Ph	Ph	Ph	Ph
E-9	H	H	H	H	Ph	4115	4116	Ph
E-10	H	H	H	H	Ph	CH3	CH3	Ph
E-11	Ph	H	Ph	H	Ph	H	H	Ph
E-12	4117	H	4118	H	Ph	H	H	Ph
E-13	CH3	H	CH3	H	Ph	H	H	Ph
Compound No.	X2	X3	X6	X7	X11 = 21	X12 = X22	X13	X14	X23	X24
E-14	H	H	H	H	H	H	X13 and X14, X23 and X24 form fused rings.
E-15	H	H	H	H	Ph	H	X13 and X14, X23 and X24 form fused rings.
E-16	H	H	H	H	4119	H	X13 and X14, X23 and X24 form fused rings.
E-17	H	H	H	H	4120	H	X13 and X14, X23 and X24 form fused rings.
E-18	H	H	H	H	4121	H	X13 and X14, X23 and X24 form fused rings.
E-19	H	H	H	H	CH3	H	X13 and X14, X23 and X24 form fused rings.
E-20	H	H	H	H	4122	H	X13 and X14, X23 and X24 form fused rings.
E-21	H	H	H	H	Ph	Ph	X13 and X14, X23 and X24 form fused rings.
E-22	H	H	H	H	Ph	4123	X13 and X14, X23 and X24 form fused rings.
E-23	H	H	H	H	Ph	CH3	X13 and X14, X23 and X24 form fused rings.
E-24	Ph	H	H	Ph	Ph	H	X13 and X14, X23 and X24 form fused rings.
E-25	4124	H	H	4125	Ph	H	X13 and X14, X23 and X24 form fused rings.
E-26	CH3	H	H	CH3	Ph	H	X13 and X14, X23 and X24 form fused rings.
Compound No.	X2	X3	X6	X7	X11 = X21	X12 = X22	X13 = X23	X14 = X24
E-27	H	H	H	H	X11 and X12, X21 and X22 form fused rings.	X13 and X14, X23 and X24 form fused rings.
E-28	Ph	H	Ph	H	X11 and X12, X21 and X22 form fused rings.	X13 and X14, X23 and X24 form fused rings.
E-29	4126	H	4127	H	X11 and X12, X21 and X22 form fused rings.	X13 and X14, X23 and X24 form fused rings.
E-30	CH3	H	CH3	H	X11 and X12, X21 and X22 form fused rings.	X13 and X14, X23 and X24 form fused rings.
Compound No.	X2	X3	X6	X7	X11 = 21	X12 = X22
E-31	H	H	H	H	H	H
E-32	H	H	H	H	Ph	H
E-33	H	H	H	H	4128	H
E-34	H	H	H	H	4129	H
E-35	H	H	H	H	4130	H
E-36	H	H	H	H	CH3	H
E-37	H	H	H	H	4131	H
E-38	H	H	H	H	Ph	Ph
E-39	H	H	H	H	Ph	4132
E-40	H	H	H	H	Ph	CH3
E-41	Ph	H	Ph	H	Ph	H
E-42	4133	H	4134	H	Ph	H
E-43	CH3	H	CH3	H	Ph	H
	Compound No.	X13	X14	X23	X24
	E-31	X13 and X14 form a fused ring.	H	H
	E-32	X13 and X14 form a fused ring.	H	Ph
	E-33	X13 and X14 form a fused ring.	H	4135
	E-34	X13 and X14 form a fused ring.	H	4136
	E-35	X13 and X14 form a fused ring.	H	4137
	E-36	X13 and X14 form a fused ring.	H	CH3
	E-37	X13 and X14 form a fused ring.	H	4138
	E-38	X13 and X14 form a fused ring.	Ph	Ph
	E-39	X13 and X14 form a fused ring.	4139	Ph
	E-40	X13 and X14 form a fused ring.	CH3	Ph
	E-41	X13 and X14 form a fused ring.	H	Ph
	E-42	X13 and X14 form a fused ring.	H	Ph
	E-43	X13 and X14 form a fused ring.	H	Ph
Compound No.	X2	X3	X6	X7	X11       X12	X13       X14
E-44	H	H	H	H	X11 and X12 form a fused ring.	X13 and X14 form a fused ring.
E-45	H	H	H	H	X11 and X12 form a fused ring.	X13 and X14 form a fused ring.
E-46	H	H	H	H	X11 and X12 form a fused ring.	X13 and X14 form a fused ring.
E-47	H	H	H	H	X11 and X12 form a fused ring.	X13 and X14 form a fused ring.
E-48	H	H	H	H	X11 and X12 form a fused ring.	X13 and X14 form a fused ring.
E-49	H	H	H	H	X11 and X12 form a fused ring.	X13 and X14 form a fused ring.
E-50	H	H	H	H	X11 and X12 form a fused ring.	X13 and X14 form a fused ring.
E-51	H	H	H	H	X11 and X12 form a fused ring.	X13 and X14 form a fused ring.
E-52	H	H	H	H	X11 and X12 form a fused ring.	X13 and X14 form a fused ring.
E-53	H	H	H	H	X11 and X12 form a fused ring.	X13 and X14 form a fused ring.
E-54	Ph	H	Ph	H	X11 and X12 form a fused ring.	X13 and X14 form a fused ring.
E-55	4140	H	4141	H	X11 and X12 form a fused ring.	X13 and X14 form a fused ring.
E-56	CH3	H	CH3	H	X11 and X12 form a fused ring.	X13 and X14 form a fused ring.
	Compound No.	X21	X22	X23	X24
	E-44	H	H	H	H
	E-45	Ph	H	H	Ph
	E-46	4142	H	H	4143
	E-47	4144	H	H	4145
	E-48	4146	H	H	4147
	E-49	CH3	H	H	CH3
	E-50	4148	H	H	4149
	E-51	Ph	Ph	Ph	Ph
	E-52	Ph	4150	4151	Ph
	E-53	Ph	CH3	CH3	Ph
	E-54	Ph	H	H	Ph
	E-55	Ph	H	H	Ph
	E-56	Ph	H	H	Ph
Compound No.	X2	X3	X6	X7	X11 = 21	X12
E-57	H	H	H	H	H	H
E-58	H	H	H	H	Ph	H
E-59	H	H	H	H	4152	H
E-60	H	H	H	H	4153	H
E-61	H	H	H	H	4154	H
E-62	H	H	H	H	CH3	H
E-63	H	H	H	H	4155	H
E-64	H	H	H	H	Ph	Ph
E-65	H	H	H	H	Ph	4156
E-66	H	H	H	H	Ph	CH3
E-67	Ph	H	Ph	H	Ph	H
E-68	4157	H	4158	H	Ph	H
E-69	CH3	H	CH3	H	Ph	H
	Compound No.	X13	X14	X22	X23	X24
	E-57	X13 and X14 form a fused ring.	X22 and X23 form a fused ring.	H
	E-58	X13 and X14 form a fused ring.	X22 and X23 form a fused ring.	Ph
	E-59	X13 and X14 form a fused ring.	X22 and X23 form a fused ring.	4159
	E-60	X13 and X14 form a fused ring.	X22 and X23 form a fused ring.	4160
	E-61	X13 and X14 form a fused ring.	X22 and X23 form a fused ring.	4161
	E-62	X13 and X14 form a fused ring.	X22 and X23 form a fused ring.	CH3
	E-63	X13 and X14 form a fused ring.	X22 and X23 form a fused ring.	4162
	E-64	X13 and X14 form a fused ring.	X22 and X23 form a fused ring.	Ph
	E-65	X13 and X14 form a fused ring.	X22 and X23 form a fused ring.	Ph
	E-66	X13 and X14 form a fused ring.	X22 and X23 form a fused ring.	Ph
	E-67	X13 and X14 form a fused ring.	X22 and X23 form a fused ring.	Ph
	E-68	X13 and X14 form a fused ring.	X22 and X23 form a fused ring.	Ph
	E-69	X13 and X14 form a fused ring.	X22 and X23 form a fused ring.	Ph
Compound No.	X2	X3	X6	X7	X11 = 24	X12 = X23
E-70	H	H	H	H	H	H
E-71	H	H	H	H	Ph	H
E-72	H	H	H	H	4163	H
E-73	H	H	H	H	4164	H
E-74	H	H	H	H	4165	H
E-75	H	H	H	H	CH3	H
E-76	H	H	H	H	4166	H
E-77	H	H	H	H	Ph	Ph
E-78	H	H	H	H	Ph	4167
E-79	H	H	H	H	Ph	CH3
E-80	Ph	H	Ph	H	Ph	H
E-81	4168	H	4169	H	Ph	H
E-82	CH3	H	CH3	H	Ph	H
	Compound No.	X13	X14	X21	X22
	E-70	X13 and X14 form a fused ring.	X21 and X22 form a fused ring.
	E-71	X13 and X14 form a fused ring.	X21 and X22 form a fused ring.
	E-72	X13 and X14 form a fused ring.	X21 and X22 form a fused ring.
	E-73	X13 and X14 form a fused ring.	X21 and X22 form a fused ring.
	E-74	X13 and X14 form a fused ring.	X21 and X22 form a fused ring.
	E-75	X13 and X14 form a fused ring.	X21 and X22 form a fused ring.
	E-76	X13 and X14 form a fused ring.	X21 and X22 form a fused ring.
	E-77	X13 and X14 form a fused ring.	X21 and X22 form a fused ring.
	E-78	X13 and X14 form a fused ring.	X21 and X22 form a fused ring.
	E-79	X13 and X14 form a fused ring.	X21 and X22 form a fused ring.
	E-80	X13 and X14 form a fused ring.	X21 and X22 form a fused ring.
	E-81	X13 and X14 form a fused ring.	X21 and X22 form a fused ring.
	E-82	X13 and X14 form a fused ring.	X21 and X22 form a fused ring.
Compound No.	X2	X3	X6	X7	X11	X12	X13	X14
E-83	H	H	H	H	X11 and X12 form a fused ring.	X13 and X14 form a fused ring.
E-84	H	H	H	H	X11 and X12 form a fused ring.	X13 and X14 form a fused ring.
E-85	H	H	H	H	X11 and X12 form a fuaed ring.	X13 and X14 form a fused ring.
E-86	H	H	H	H	X11 and X12 form a fuaed ring.	X13 and X14 form a fused ring.
E-87	H	H	H	H	X11 and X12 form a fused ring.	X13 and X14 form a fused ring.
E-88	H	H	H	H	X11 and X12 form a fused ring.	X13 and X14 form a fused ring.
E-89	H	H	H	H	X11 and X12 form a fused ring.	X13 and X14 form a fused ring.
E-90	Ph	H	Ph	H	X11 and X12 form a fused ring.	X13 and X14 form a fused ring.
E-91	4170	H	4171	H	X11 and X12 form a fused ring.	X13 and X14 form a fused ring.
E-92	CH3	H	CH3	H	X11 and X12 form a fused ring.	X13 and X14 form a fused ring.
	Compound No.	X21	X22	X23	X24
	E-83	H	X22 and X23 form a fused ring.	H
	E-84	Ph	X22 and X23 form a fused ring.	Ph
	E-85	4172	X22 and X23 form a fused ring.	4173
	E-86	4174	X22 and X23 form a fused ring.	4175
	E-87	4176	X22 and X23 form a fused ring.	4177
	E-88	CH3	X22 and X23 form a fused ring.	CH3
	E-89	4178	X22 and X23 form a fused ring.	4179
	E-90	Ph	X22 and X23 form a fused ring.	Ph
	E-91	Ph	X22 and X23 form a fused ring.	Ph
	E-92	Ph	X22 and X23 form a fused ring.	Ph
Compound No.	X2	X3	X6	X7	X11	X12	X13	X14
E-93	X2 and X3 form a fused ring.	H	H	H	H	X13 and X14 form a fused ring.
E-94	X2 and X3 form a fused ring.	H	H	Ph	H	X13 and X14 form a fused ring.
E-95	X2 and X3 form a fused ring.	H	H	4180	H	X13 and X14 form a fused ring.
E-96	X2 and X3 form a fused ring.	H	H	4181	H	X13 and X14 form a fused ring.
E-97	X2 and X3 form a fused ring.	H	H	4182	H	X13 and X14 form a fused ring.
E-98	X2 and X3 form a fused ring.	H	H	CH3	H	X13 and X14 form a fused ring.
E-99	X2 and X3 form a fused ring.	H	H	4183	H	X13 and X14 form a fused ring.
E-100	X2 and X3 form a fused ring.	H	H	Ph	Ph	X13 and X14 form a fused ring.
E-101	X2 and X3 form a fused ring.	H	H	Ph	4184	X13 and X14 form a fused ring.
E-102	X2 and X3 form a fused ring.	H	H	Ph	CH3	X13 and X14 form a fused ring.
E-103	X2 and X3 form a fused ring.	Ph	H	Ph	H	X13 and X14 form a fused ring.
E-104	X2 and X3 form a fused ring.	4185	H	Ph	H	X13 and X14 form a fused ring.
E-105	X2 and X3 form a fused ring.	CH3	H	Ph	H	X13 and X14 form a fused ring.
	Compound No.	X21	X22	X23	X24
	E-93	X21 and X22 form a fused ring.	H	H
	E-94	X21 and X22 form a fused ring.	H	Ph
	E-95	X21 and X22 form a fused ring.	H	4186
	E-96	X21 and X22 form a fused ring.	H	4187
	E-97	X21 and X22 form a fused ring.	H	4188
	E-98	X21 and X22 form a fused ring.	H	CH3
	E-99	X21 and X22 form a fused ring.	H	4189
	E-100	X21 and X22 form a fused ring.	Ph	Ph
	E-101	X21 and X22 form a fused ring.	4190	Ph
	E-102	X21 and X22 form a fused ring.	CH3	Ph
	E-103	X21 and X22 form a fused ring.	H	Ph
	E-104	X21 and X22 form a fused ring.	H	Ph
	E-105	X21 and X22 form a fused ring.	H	Ph
Com-
pound
No.	X2	X3	X6	X7	X11 = 21	X12 = X22	X13 = X23	X14 = X24
E-106	X2 and X3 form a fused ring.	H	H	H	H	H	H
E-107	X2 and X3 form a fused ring.	H	H	Ph	H	H	Ph
E-108	X2 and X3 form a fused ring.	H	H	4191	H	H	4192
E-109	X2 and X3 form a fused ring.	H	H	4193	H	H	4194
E-110	X2 and X3 form a fused ring.	H	H	4195	H	H	4196
E-111	X2 and X3 form a fused ring.	H	H	CH3	H	H	CH3
E-112	X2 and X3 form a fused ring.	H	H	4197	H	H	4198
E-113	X2 and X3 form a fused ring.	H	H	Ph	Ph	Ph	Ph
E-114	X2 and X3 form a fused ring.	H	H	Ph	4199	4200	Ph
E-115	X2 and X3 form a fused ring.	H	H	Ph	CH3	CH3	Ph
E-116	X2 and X3 form a fused ring.	Ph	H	Ph	H	H	Ph
E-117	X2 and X3 form a fused ring.	4201	H	Ph	H	H	Ph
E-118	X2 and X3 form a fused ring.	CH3	H	Ph	H	H	Ph
Compound No.	X2      X3	X6	X7	X11 = 21	X12
E-119	X2 and X3 form a fused ring.	H	H	H	H
E-120	X2 and X3 form a fused ring.	H	H	Ph	H
E-121	X2 and X3 form a fused ring.	H	H	4202	H
E-122	X2 and X3 form a fused ring.	H	H	4203	H
E-123	X2 and X3 form a fused ring.	H	H	4204	H
E-124	X2 and X3 form a fused ring.	H	H	CH3	H
E-125	X2 and X3 form a fused ring.	H	H	4205	H
E-126	X2 and X3 form a fused ring.	H	H	Ph	Ph
E-127	X2 and X3 form a fused ring.	H	H	Ph	4206
E-128	X2 and X3 form a fused ring.	H	H	Ph	CH3
E-129	X2 and X3 form a fused ring.	Ph	H	Ph	H
E-130	X2 and X3 form a fused ring.	4207	H	Ph	H
E-131	X2 and X3 form a fused ring.	CH3	H	Ph	H
	Compound No.	X13	X22	X23	X14 = X24
	E-119	H	X22 and X23 form a fused ring.	H
	E-120	H	X22 and X23 form a fused ring.	Ph
	E-121	H	X22 and X23 form a fused ring.	4208
	E-122	H	X22 and X23 form a fused ring.	4209
	E-123	H	X22 and X23 form a fused ring.	4210
	E-124	H	X22 and X23 form a fused ring.	CH3
	E-125	H	X22 and X23 form a fused ring.	4211
	E-126	Ph	X22 and X23 form a fused ring.	Ph
	E-127	4212	X22 and X23 form a fused ring.	Ph
	E-128	CH3	X22 and X23 form a fused ring.	Ph
	E-129	H	X22 and X23 form a fused ring.	Ph
	E-130	H	X22 and X23 form a fused ring.	Ph
	E-131	H	X22 and X23 form a fused ring.	Ph
Compound No.	X2	X3	X6	X7	X11 = 21	X12 = X22	X13 = X23	X14 = X24
E-132	X2 and X3 form a fused ring.	X6 and X7 form a fused ring.	H	H	H	H
E-133	X2 and X3 form a fused ring.	X6 and X7 form a fused ring.	Ph	H	H	Ph
E-134	X2 and X3 form a fused ring.	X6 and X7 form a fused ring.	4213	H	H	4214
E-135	X2 and X3 form a fused ring.	X6 and X7 form a fused ring.	4215	H	H	4216
E-136	X2 and X3 form a fused ring.	X6 and X7 form a fused ring.	4217	H	H	4218
E-137	X2 and X3 form a fused ring.	X6 and X7 form a fused ring.	CH3	H	H	CH3
E-138	X2 and X3 form a fused ring.	X6 and X7 form a fused ring.	4219	H	H	4220
E-139	X2 and X3 form a fused ring.	X6 and X7 form a fused ring.	Ph	Ph	Ph	Ph
E-140	X2 and X3 form a fused ring.	X6 and X7 form a fused ring.	Ph	4221	4222	Ph
E-141	X2 and X3 form a fused ring.	X6 and X7 form a fused ring.	Ph	CH3	CH3	Ph
Compound No.	X2       X3	X6       X7	X11 = 21	X12
E-142	X2 and X3 form a fused ring.	X6 and X7 form a fused ring.	H	H
E-143	X2 and X3 form a fused ring.	X6 and X7 form a fused ring.	Ph	H
E-144	X2 and X3 form a fused ring.	X6 and X7 form a fused ring.	4223	H
E-145	X2 and X3 form a fused ring.	X6 and X7 form a fused ring.	4224	H
E-146	X2 and X3 form a fused ring.	X6 and X7 form a fused ring.	4225	H
E-147	X2 and X3 form a fused ring.	X6 and X7 form a fused ring.	CH3	H
E-148	X2 and X3 form a fused ring.	X6 and X7 form a fused ring.	4226	H
E-149	X2 and X3 form a fused ring.	X6 and X7 form a fused ring.	Ph	Ph
E-150	X2 and X3 form a fused ring.	X6 and X7 form a fused ring.	Ph	4227
E-151	X2 and X3 form a fused ring.	X6 and X7 form a fused ring.	Ph	CH3
	Compound No.	X13	X22	X23	X14 = X24
	E-142	H	X22 and X23 form a fused ring.	H
	E-143	H	X22 and X23 form a fused ring.	Ph
	E-144	H	X22 and X23 form a fused ring.	4228
	E-145	H	X22 and X23 form a fused ring.	4229
	E-146	H	X22 and X23 form a fused ring.	4230
	E-147	H	X22 and X23 form a fused ring.	CH3
	E-148	H	X22 and X23 form a fused ring.	4231
	E-149	Ph	X22 and X23 form a fused ring.	Ph
	E-150	4232	X22 and X23 form a fused ring.	Ph
	E-151	CH3	X22 and X23 form a fused ring.	Ph
Compound No.	X2       X3	X6       X7	X11 = 21	X12 = 22
E-152	X2 and X3 form a fused ring.	X6 and X7 form a fused ring.	H	H
E-153	X2 and X3 form a fused ring.	X6 and X7 form a fused ring.	Ph	H
E-154	X2 and X3 form a fused ring.	X6 and X7 form a fused ring.	4233	H
E-155	X2 and X3 form a fused ring.	X6 and X7 form a fused ring.	4234	H
E-156	X2 and X3 form a fused ring.	X6 and X7 form a fused ring.	4235	H
E-157	X2 and X3 form a fused ring.	X6 and X7 form a fused ring.	CH3	H
E-158	X2 and X3 form a fused ring.	X6 and X7 form a fused ring.	4236	H
E-159	X2 and X3 form a fused ring.	X6 and X7 form a fused ring.	Ph	Ph
E-160	X2 and X3 form a fused ring.	X6 and X7 form a fused ring.	Ph	4237
E-161	X2 and X3 forms fused ring.	X6 and X7 form a fused ring.	Ph	CH3
	Compound No.	X13	X14	X23	X24
	E-152	X13 and X14 form a fused ring.	H	H
	E-153	X13 and X14 form a fused ring.	H	Ph
	E-154	X13 and X14 form a fused ring.	H	4238
	E-155	X13 and X14 form a fused ring.	H	4239
	E-156	X13 and X14 form a fused ring.	H	4240
	E-157	X13 and X14 form a fused ring.	H	CH3
	E-158	X13 and X14 form a fused ring.	H	4241
	E-159	X13 and X14 form a fused ring.	Ph	Ph
	E-160	X13 and X14 form a fused ring.	4242	Ph
	E-161	X13 and X14 form a fused ring.	CH3	Ph
Compound No.	X2	X3	X6	X7	X11 = 21	X12 = X22	X13	X14	X23	X24
E-162	X2 and X3 form a fused ring.	X6 and X7 form a fused ring.	H	H	X13 and X14 form a fused ring.	X23 and X24 form a fused ring.
E-163	X2 and X3 form a fused ring.	X6 and X7 form a fused ring.	Ph	H	X13 and X14 form a fused ring.	X23 and X24 form a fused ring.
E-164	X2 and X3 form a fused ring.	X6 and X7 form a fused ring.	4243	H	X13 and X14 form a fused ring.	X23 and X24 form a fused ring.
E-165	X2 and X3 form a fused ring.	X6 and X7 form a fused ring.	4244	H	X13 and X14 form a fused ring.	X23 and X24 form a fused ring.
E-166	X2 and X3 form a fused ring.	X6 and X7 form a fused ring.	4245	H	X13 and X14 form a fused ring.	X23 and X24 form a fused ring.
E-167	X2 and X3 form a fused ring.	X6 and X7 form a fused ring.	CH3	H	X13 and X14 form a fused ring.	X23 and X24 form a fused ring.
E-168	X2 and X3 form a fused ring.	X6 and X7 form a fused ring.	4246	H	X13 and X14 form a fused ring.	X23 and X24 form a fused ring.
E-169	X2 and X3 form a fused ring.	X6 and X7 form a fused ring.	Ph	Ph	X13 and X14 form a fused ring.	X23 and X24 form a fused ring.
E-170	X2 and X3 form a fused ring.	X6 and X7 form a fused ring.	Ph	4247	X13 and X14 form a fused ring.	X23 and X24 form a fused ring.
E-171	X2 and X3 form a fused ring.	X6 and X7 form a fused ring.	Ph	CH3	X13 and X14 form a fused ring.	X23 and X24 form a fused ring.
Compound No.	X2       X3	X6       X7	X11	X12	X13	X14
E-172	X2 and X3 form a fused ring.	X6 and X7 form a fused ring.	H	H	X13 and X14 form a fused ring.
E-173	X2 and X3 form a fused ring.	X6 and X7 form a fused ring.	Ph	H	X13 and X14 form a fused ring.
E-174	X2 and X3 form a fused ring.	X6 and X7 form a fused ring.	4248	H	X13 and X14 form a fused ring.
E-175	X2 and X3 form a fused ring.	X6 and X7 form a fused ring.	4249	H	X13 and X14 form a fused ring.
E-176	X2 and X3 form a fused ring.	X6 and X7 form a fused ring.	4250	H	X13 and X14 form a fused ring.
E-177	X2 and X3 form a fused ring.	X6 and X7 form a fused ring.	CH3	H	X13 and X14 form a fused ring.
E-178	X2 and X3 form a fused ring.	X6 and X7 form a fused ring.	4251	H	X13 and X14 form a fused ring.
E-179	X2 and X3 form a fused ring.	X6 and X7 form a fused ring.	Ph	Ph	X13 and X14 form a fused ring.
E-180	X2 and X3 form a fused ring.	X6 and X7 form a fused ring.	Ph	4252	X13 and X14 form a fused ring.
E-181	X2 and X3 form a fused ring.	X6 and X7 form a fused ring.	Ph	CH3	X13 and X14 form a fused ring.
	Compound No.	X21	X22	X23	X24
	E-172	X21 and X22 form a fused ring.	H	H
	E-173	X21 and X22 form a fused ring.	H	Ph
	E-174	X21 and X22 form a fused ring.	H	4253
	E-175	X21 and X22 form a fused ring.	H	4254
	E-176	X21 and X22 form a fused ring.	H	4255
	E-177	X21 and X22 form a fused ring.	H	CH3
	E-178	X21 and X22 form a fused ring.	H	4256
	E-179	X21 and X22 form a fused ring.	Ph	Ph
	E-180	X21 and X22 form a fused ring.	4257	Ph
	E-181	X21 and X22 form a fused ring.	CH3	Ph
Compound No.	X2       X3	X6       X7	X11 = 21	X12
E-182	X2 and X3 form a fused ring.	X6 and X7 form a fused ring.	H	H
E-183	X2 and X3 form a fused ring.	X6 and X7 form a fused ring.	Ph	H
E-184	X2 and X3 form a fused ring.	X6 and X7 form a fused ring.	4258	H
E-185	X2 and X3 form a fused ring.	X6 and X7 form a fused ring.	4259	H
E-186	X2 and X3 form a fused ring.	X6 and X7 form a fused ring.	4260	H
E-187	X2 and X3 form a fused ring.	X6 and X7 form a fused ring.	CH3	H
E-188	X2 and X3 form a fused ring.	X6 and X7 form a fused ring.	4261	H
E-189	X2 and X3 form a fused ring.	X6 and X7 form a fused ring.	Ph	Ph
E-190	X2 and X3 form a fused ring.	X6 and X7 form a fused ring.	Ph	4262
E-191	X2 and X3 form a fused ring.	X6 and X7 form a fused ring.	Ph	CH3
	Compound No.	X13	X14	X22	X23	X24
	E-182	X13 and X14 form a fused ring.	X22 and X23 form a fused ring.	H
	E-183	X13 and X14 form a fused ring.	X22 and X23 form a fused ring.	Ph
	E-184	X13 and X14 form a fused ring.	X22 and X23 form a fused ring.	4263
	E-185	X13 and X14 form a fused ring.	X22 and X23 form a fused ring.	4264
	E-186	X13 and X14 form a fused ring.	X22 and X23 form a fused ring.	4265
	E-187	X13 and X14 form a fused ring.	X22 and X23 form a fused ring.	CH3
	E-188	X13 and X14 form a fused ring.	X22 and X23 form a fused ring.	4266
	E-189	X13 and X14 form a fused ring.	X22 and X23 form a fused ring.	Ph
	E-190	X13 and X14 form a fused ring.	X22 and X23 form a fused ring.	Ph
	E-191	X13 and X14 form a fused ring.	X22 and X23 form a fused ring.	Ph

[0286]

4267	“A and B form a fused ring” in	4268	means	4269
Compound No.	X2	X3	X6	X7	X11 = X21	X14 = X24	X15 = X25
F-1	H	H	H	H	H	H	H
F-2	H	H	H	H	Ph	Ph	H
F-3	H	H	H	H	4270	4271	H
F-4	H	H	H	H	4272	4273	H
F-5	H	H	H	H	4274	4275	H
F-6	H	H	H	H	CH3	CH3	H
F-7	H	H	H	H	4276	4277	H
F-8	H	H	H	H	Ph	Ph	Ph
F-9	H	H	H	H	Ph	Ph	4278
F-10	H	H	H	H	Ph	Ph	CH3
F-11	H	H	H	H	Ph	Ph	H
F-12	H	H	H	H	Ph	Ph	H
F-13	H	H	H	H	Ph	Ph	H
F-14	X2 and X3 form a fused ring.	H	H	H	H	H
F-15	X2 and X3 form a fused ring.	H	H	Ph	Ph	H
F-16	X2 and X3 form a fused ring.	H	H	4279	4280	H
F-17	X2 and X3 form a fused ring.	H	H	4281	4282	H
F-18	X2 and X3 form a fused ring.	H	H	4283	4284	H
F-19	X2 and X3 form a fused ring.	H	H	CH3	CH3	H
F-20	X2 and X3 form a fused ring.	H	H	4285	4286	H
F-21	X2 and X3 form a fused ring.	H	H	Ph	Ph	Ph
F-22	X2 and X3 form a fused ring.	H	H	Ph	Ph	4287
F-23	X2 and X3 form a fused ring.	H	H	Ph	Ph	CH3
F-24	X2 and X3 form a fused ring.	H	H	Ph	Ph	H
F-25	X2 and X3 form a fused ring.	H	H	Ph	Ph	H
F-26	X2 and X4 form a fused ring.	H	H	Ph	Ph	H
	Compound No.	X16 = X26	X17 = X27	X18 = X28
	F-1	H	H	H
	F-2	H	H	H
	F-3	H	H	H
	F-4	H	H	H
	F-5	H	H	H
	F-6	H	H	H
	F-7	H	H	H
	F-8	H	H	Ph
	F-9	H	H	4288
	F-10	H	H	CH3
	F-11	Ph	Ph	H
	F-12	4289	4290	H
	F-13	CH3	CH3	H
	F-14	H	H	H
	F-15	H	H	H
	F-16	H	H	H
	F-17	H	H	H
	F-18	H	H	H
	F-19	H	H	H
	F-20	H	H	H
	F-21	H	H	Ph
	F-22	H	H	4291
	F-23	H	H	CH3
	F-24	Ph	Ph	H
	F-25	4292	4293	H
	F-26	CH3	CH3	H
Compound No.	X2	X3	X6	X7	X11 = X21	X14 = X24	X15 = X25	X16       X17
F-27	H	H	H	H	H	H	H	X16 and X17 form a fused ring.
F-28	H	H	H	H	Ph	Ph	H	X16 and X17 form a fused ring.
F-29	H	H	H	H	4294	4295	H	X16 and X17 form a fused ring.
F-30	H	H	H	H	4296	4297	H	X16 and X17 form a fused ring.
F-31	H	H	H	H	4298	4299	H	X16 and X17 form a fused ring.
F-32	H	H	H	H	CH3	CH3	H	X16 and X17 form a fused ring.
F-33	H	H	H	H	4300	4301	H	X16 and X17 form a fused ring.
F-34	H	H	H	H	Ph	Ph	Ph	X16 and X17 form a fused ring.
F-35	H	H	H	H	Ph	Ph	4302	X16 and X17 form a fused ring.
F-36	H	H	H	H	Ph	Ph	CH3	X16 and X17 form a fused ring.
F-37	H	H	H	H	Ph	Ph	H	X16 and X17 form a fused ring.
F-38	H	H	H	H	Ph	Ph	H	X16 and X17 form a fused ring.
F-39	H	H	H	H	Ph	Ph	H	X16 and X17 form a fused ring.
	Compound No.	X18 = X28	X26	X27
	F-27	H	H	H
	F-28	H	H	H
	F-29	H	H	H
	F-30	H	H	H
	F-31	H	H	H
	F-32	H	H	H
	F-33	H	H	H
	F-34	Ph	H	H
	F-35	4303	H	H
	F-36	CH3	H	H
	F-37	H	H	Ph
	F-38	H	H	4304
	F-39	H	H	CH3
Compound No.	X2	X3	X6	X7	X11 = X21	X14 = X24	X15 = X25	X16       X17
F-40	H	H	H	H	H	H	H	X16 and X17 form a fused ring.
F-41	H	H	H	H	Ph	Ph	H	X16 and X17 form a fused ring.
F-42	H	H	H	H	4305	4306	H	X16 and X17 form a fused ring.
F-43	H	H	H	H	4307	4308	H	X16 and X17 form a fused ring.
F-44	H	H	H	H	4309	4310	H	X16 and X17 form a fused ring.
F-45	H	H	H	H	CH3	CH3	H	X16 and X17 form a fused ring.
F-46	H	H	H	H	4311	4312	H	X16 and X17 form a fused ring.
F-47	H	H	H	H	Ph	Ph	Ph	X16 and X17 form a fused ring.
F-48	H	H	H	H	Ph	Ph	4313	X16 and X17 form a fused ring.
F-49	H	H	H	H	Ph	Ph	CH3	X16 and X17 form a fused ring.
	Compound No.	X18 = X28	X26       X27
	F-40	H	X26 and X27 form a fused ring.
	F-41	H	X26 and X27 form a fused ring.
	F-42	H	X26 and X27 form a fused ring.
	F-43	H	X26 and X27 form a fused ring.
	F-44	H	X26 and X27 form a fused ring.
	F-45	H	X26 and X27 form a fused ring.
	F-46	H	X26 and X27 form a fused ring.
	F-47	Ph	X26 and X27 form a fused ring.
	F-48	4314	X26 and X27 form a fused ring.
	F-49	CH3	X26 and X27 form a fused ring.
Compound No.	X2       X3	X6       X7	X11 = X21	X14 = X24	X15 = X25
F-50	X2 and X3 form a fused ring.	X6 and X7 form a fused ring.	H	H	H
F-51	X2 and X3 form a fused ring.	X6 and X7 form a fused ring.	Ph	Ph	H
F-52	X2 and X3 form a fused ring.	X6 and X7 form a fused ring.	4315	4316	H
F-53	X2 and X3 form a fused ring.	X6 and X7 form a fused ring.	4317	4318	H
F-54	X2 and X3 form a fused ring.	X6 and X7 form a fused ring.	4319	4320	H
F-55	X2 and X3 form a fused ring.	X6 and X7 form a fused ring.	CH3	CH3	H
F-56	X2 and X3 form a fused ring.	X6 and X7 form a fused ring.	4321	4322	H
F-57	X2 and X3 form a fused ring.	X6 and X7 form a fused ring.	Ph	Ph	Ph
F-58	X2 and X3 form a fused ring.	X6 and X7 form a fused ring.	Ph	Ph	4323
F-59	X2 and X3 form a fused ring.	X6 and X7 form a fused ring.	Ph	Ph	CH3
F-60	X2 and X3 form a fused ring.	X6 and X7 form a fused ring.	Ph	Ph	H
F-61	X2 and X3 form a fused ring.	X6 and X7 form a fused ring.	Ph	Ph	H
F-62	X2 and X3 form a fused ring.	X6 and X7 form a fused ring.	Ph	Ph	H
	Compound No.	X16 = X26	X17 = X27	X18 = X28
	F-50	H	H	H
	F-51	H	H	H
	F-52	H	H	H
	F-53	H	H	H
	F-54	H	H	H
	F-55	H	H	H
	F-56	H	H	H
	F-57	H	H	Ph
	F-58	H	H	4324
	F-59	H	H	CH3
	F-60	Ph	Ph	H
	F-61	4325	4326	H
	F-62	CH3	CH3	H
Compound No.	X2	X3	X6	X7	X11 = X21	X15	X16	X14 = X24	X25
F-63	X2 and X3 form a fused ring.	X6 and X7 form a fused ring.	H	X15 and X16 form a fused ring.	H	H
F-64	X2 and X3 form a fused ring.	X6 and X7 form a fused ring.	Ph	X15 and X16 form a fused ring.	Ph	H
F-65	X2 and X3 form a fused ring.	X6 and X7 form a fused ring.	4327	X15 and X16 form a fused ring.	4328	H
F-66	X2 and X3 form a fused ring.	X6 and X7 form a fused ring.	4329	X15 and X16 form a fused ring.	4330	H
F-67	X2 and X3 form a fused ring.	X6 and X7 form a fused ring.	4331	X15 and X16 form a fused ring.	4332	H
F-68	X2 and X3 form a fused ring.	X6 and X7 form a fused ring.	CH3	X15 and X16 form a fused ring.	CH3	H
F-69	X2 and X3 form a fused ring.	X6 and X7 form a fused ring.	4333	X15 and X16 form a fused ring.	4334	H
F-70	X2 and X3 form a fused ring.	X6 and X7 form a fused ring.	Ph	X15 and X16 form a fused ring.	Ph	Ph
F-71	X2 and X3 form a fused ring.	X6 and X7 form a fused ring.	Ph	X15 and X16 form a fused ring.	Ph	4335
F-72	X2 and X3 form a fused ring.	X6 and X7 form a fused ring.	Ph	X15 and X16 form a fused ring.	Ph	CH3
F-73	X2 and X3 form a fused ring.	X6 and X7 form a fused ring.	Ph	X15 and X16 form a fused ring.	Ph	H
F-74	X2 and X3 form a fused ring.	X6 and X7 form a fused ring.	Ph	X15 and X16 form a fused ring.	Ph	H
F-75	X2 and X3 form a fused ring.	X6 and X7 form a fused ring.	Ph	X15 and X16 form a fused ring.	Ph	H
	Compound No.	X26	X17 = X27	X18 = X28
	F-63	H	H	H
	F-64	H	H	H
	F-65	H	H	H
	F-66	H	H	H
	F-67	H	H	H
	F-68	H	H	H
	F-69	H	H	H
	F-70	H	H	Ph
	F-71	H	H	4336
	F-72	H	H	CH3
	F-73	Ph	Ph	H
	F-74	4337	4338	H
	F-75	CH3	CH3	H
Compound No.	X2	X3	X6	X7	X11 = X21	X15	X16	X17	X18	X14 = X24
F-76	X2 and X3 form a fused ring.	X6 and X7 form a fused ring.	H	X15 and X16 form a fused ring.	X17 and X18 form a fused ring.	H
F-77	X2 and X3 form a fused ring.	X6 and X7 form a fused ring.	Ph	X15 and X16 form a fused ring.	X17 and X18 form a fused ring.	Ph
F-78	X2 and X3 form a fused ring.	X6 and X7 form a fused ring	4339	X15 and X16 form a fused ring.	X17 and X18 form a fused ring.	4340
F-79	X2 and X3 form a fused ring.	X6 and X7 form a fused ring.	4341	X15 and X16 form a fused ring.	X17 and X18 form a fused ring.	4342
F-80	X2 and X3 form a fused ring.	X6 and X7 form a fused ring.	4343	X15 and X16 form a fused ring.	X17 and X18 form a fused ring.	4344
F-81	X2 and X3 form a fused ring.	X6 and X7 form a fused ring.	CH3	X15 and X16 form a fused ring.	X17 and X18 form a fused ring.	CH3
F-82	X2 and X3 form a fused ring.	X6 and X7 form a fused ring	4345	X15 and X16 form a fused ring.	X17 and X18 form a fused ring.	4346
F-83	X2 and X3 form a fused ring.	X6 and X7 form a fused ring.	Ph	X15 and X16 form a fused ring.	X17 and X18 form a fused ring.	Ph
F-84	X2 and X3 form a fused ring.	X6 and X7 form a fused ring.	Ph	X15 and X16 form a fused ring.	X17 and X18 form a fused ring.	Ph
F-85	X2 and X3 form a fused ring.	X6 and X7 form a fused ring.	Ph	X15 and X16 form a fused ring.	X17 and X18 form a fused ring.	Ph
F-86	X2 and X3 form a fused ring.	X6 and X7 form a fused ring.	Ph	X15 and X16 form a fused ring.	X17 and X18 form a fused ring.	Ph
F-87	X2 and X3 form a fused ring.	X6 and X7 form a fused ring.	Ph	X15 and X16 form a fused ring.	X17 and X18 form a fused ring.	Ph
F-88	X2 and X3 form a fused ring.	X6 and X7 form a fused ring.	Ph	X15 and X16 form a fused ring.	X17 and X18 form a fused ring.	Ph
	Compound No.	X25	X26	X27	X28
	F-76	H	H	H	H
	F-77	H	H	H	H
	F-78	H	H	H	H
	F-79	H	H	H	H
	F-80	H	H	H	H
	F-81	H	H	H	H
	F-82	H	H	H	H
	F-83	Ph	H	H	Ph
	F-84	4347	H	H	4348
	F-85	CH3	H	H	CH3
	F-86	H	Ph	Ph	H
	F-87	H	4349	4350	H
	F-88	H	CH3	CH3	H
Compound No.	X2	X3	X6	X7	X11 = X21	X15	X16	X17	X18
F-89	X2 and X3 form a fused ring.	X6 and X7 form a fused ring.	H	X15 and X16 form a fused ring.	H	H
F-90	X2 and X3 form a fused ring.	X6 and X7 form a fused ring.	Ph	X15 and X16 form a fused ring.	H	H
F-91	X2 and X3 form a fused ring.	X6 and X7 form a fused ring.	4351	X15 and X16 form a fused ring.	H	H
F-92	X2 and X3 form a fused ring.	X6 and X7 form a fused ring.	4352	X15 and X16 form a fused ring.	H	H
F-93	X2 and X3 form a fused ring.	X6 and X7 form a fused ring.	4353	X15 and X16 form a fused ring.	H	H
F-94	X2 and X3 form a fused ring.	X6 and X7 form a fused ring.	CH3	X15 and X16 form a fused ring.	H	H
F-95	X2 and X3 form a fused ring.	X6 and X7 form a fused ring.	4354	X15 and X16 form a fused ring.	H	H
F-96	X2 and X3 form a fused ring.	X6 and X7 form a fused ring.	Ph	X15 and X16 form a fused ring.	H	H
F-97	X2 and X3 form a fused ring.	X6 and X7 form a fused ring.	Ph	X15 and X16 form a fused ring.	4355	H
F-98	X2 and X3 form a fused ring.	X6 and X7 form a fused ring.	Ph	X15 and X16 form a fused ring.	CH3	H
F-99	X2 and X3 form a fused ring.	X6 and X7 form a fused ring.	Ph	X15 and X16 form a fused ring.	H	Ph
F-100	X2 and X3 form a fused ring.	X6 and X7 form a fused ring.	Ph	X15 and X16 form a fused ring.	H	4356
F-101	X2 and X3 form a fused ring.	X6 and X7 form a fused ring.	Ph	X15 and X16 form a fused ring.	H	CH3
	Compound No.	X14 = X24	X25	X26	X27	X28
	F-89	H	X25 and X26 form a fused ring.	H	H
	F-90	Ph	X25 and X26 form a fused ring.	H	H
	F-91	4357	X25 and X26 form a fused ring.	H	H
	F-92	4358	X25 and X26 form a fused ring.	H	H
	F-93	4359	X25 and X26 form a fused ring.	H	H
	F-94	CH3	X25 and X26 form a fused ring.	H	H
	F-95	4360	X25 and X26 form a fused ring.	H	H
	F-96	Ph	X25 and X26 form a fused ring.	H	Ph
	F-97	Ph	X25 and X26 form a fused ring.	H	4361
	F-98	Ph	X25 and X26 form a fused ring.	H	CH3
	F-99	Ph	X25 and X26 form a fused ring.	Ph	H
	F-100	Ph	X25 and X26 form a fused ring.	4362	H
	F-101	Ph	X25 and X26 form a fused ring.	CH3	H
Compound No.	X2       X3	X6       X7	X11 = X21	X14 = X24	X15 = X25
F-102	X2 and X3 form a fused ring.	X6 and X7 form a fused ring.	H	H	H
F-103	X2 and X3 form a fused ring.	X6 and X7 form a fused ring.	Ph	Ph	H
F-104	X2 and X3 form a fused ring.	X6 and X7 form a fused ring.	4363	4364	H
F-105	X2 and X3 form a fused ring.	X6 and X7 form a fused ring.	4365	4366	H
F-106	X2 and X3 form a fused ring.	X6 and X7 form a fused ring.	4367	4368	H
F-107	X2 and X3 form a fused ring.	X6 and X7 form a fused ring.	CH3	CH3	H
F-108	X2 and X3 form a fused ring.	X6 and X7 form a fused ring.	4369	4370	H
F-109	X2 and X3 form a fused ring.	X6 and X7 form a fused ring.	Ph	Ph	Ph
F-110	X2 and X3 form a fused ring.	X6 and X7 form a fused ring.	Ph	Ph	4371
F-111	X2 and X3 form a fused ring.	X6 and X7 form a fused ring.	Ph	Ph	CH3
	Compound No.	X16 = X26	X17 = X27	X18 = X28
	F-102	X16 and X17, X26 and X27 form fused rings.	H
	F-103	X16 and X17, X26 and X27 form fused rings.	H
	F-104	X16 and X17, X26 and X27 form fused rings.	H
	F-105	X16 and X17, X26 and X27 form fused rings.	H
	F-106	X16 and X17, X26 and X27 form fused rings.	H
	F-107	X16 and X17, X26 and X27 form fused rings.	H
	F-108	X16 and X17, X26 and X27 form fused rings.	H
	F-109	X16 and X17, X26 and X27 form fused rings.	Ph
	F-110	X16 and X17, X26 and X27 form fused rings.	4372
	F-111	X16 and X17, X26 and X27 form fused rings.	CH3
4373	“A and B form a fused ring” in	4374	means	4375
Com-
pound							X-	X-
No.	X2	X3	X6	X7	X32	X33	36	37	X11	X12
F-112	H	H	H	H	H	H	H	H	H	H
F-113	H	H	H	H	H	H	H	H	Ph	H
F-114	H	H	H	H	H	H	H	H	4376	H
F-115	H	H	H	H	H	H	H	H	4377	H
F-116	H	H	H	H	H	H	H	H	4378	H
F-117	H	H	H	H	H	H	H	H	CH3	H
F-118	H	H	H	H	H	H	H	H	4379	H
F-119	Ph	H	H	H	Ph	H	H	H	Ph	H
F-120	4380	H	H	H	4381	H	H	H	Ph	H
F-121	CH3	H	H	H	CH3	H	H	H	Ph	H
F-122	H	Ph	H	H	H	Ph	H	H	Ph	H
F-123	H	4382	H	H	H	4383	H	H	Ph	H
F-124	H	CH3	H	H	H	CH3	H	H	Ph	H
F-125	H	H	H	H	H	H	H	H	Ph	Ph
F-126	H	H	H	H	H	H	H	H	Ph	4384
F-127	H	H	H	H	H	H	H	H	Ph	CH3
	Com-
	pound
	No.	X13	X14	X21	X22	X23	X24
	F-112	H	H	H	H	H	H
	F-113	H	Ph	Ph	H	H	Ph
	F-114	H	4385	4386	H	H	4387
	F-115	H	4388	4389	H	H	4390
	F-116	H	4391	4392	H	H	4393
	F-117	H	CH3	CH3	H	H	CH3
	F-118	H	4394	4395	H	H	4396
	F-119	H	Ph	Ph	H	H	Ph
	F-120	H	Ph	Ph	H	H	Ph
	F-121	H	Ph	Ph	H	H	Ph
	F-122	H	Ph	Ph	H	H	Ph
	F-123	H	Ph	Ph	H	H	Ph
	F-124	H	Ph	Ph	H	H	Ph
	F-125	Ph	Ph	Ph	Ph	Ph	Ph
	F-126	4397	Ph	Ph	4398	4399	Ph
	F-127	CH3	Ph	Ph	CH3	CH3	Ph
Compound No.	X2	X3	X6	X7	X32	X33	X36	X37	X11
F-128	H	H	H	H	H	H	H	H	H
F-129	H	H	H	H	H	H	H	H	Ph
F-130	H	H	H	H	H	H	H	H	4400
F-131	H	H	H	H	H	H	H	H	4401
F-132	H	H	H	H	H	H	H	H	4402
F-133	H	H	H	H	H	H	H	H	CH3
F-134	H	H	H	H	H	H	H	H	4403
F-135	Ph	H	H	H	Ph	H	H	H	Ph
F-136	4404	H	H	H	4405	H	H	H	Ph
F-137	CH3	H	H	H	CH3	H	H	H	Ph
F-138	H	Ph	H	H	H	Ph	H	H	Ph
F-139	H	4406	H	H	H	4407	H	H	Ph
F-140	H	CH3	H	H	H	CH3	H	H	Ph
F-141	H	H	H	H	H	H	H	H	Ph
F-142	H	H	H	H	H	H	H	H	Ph
F-143	H	H	H	H	H	H	H	H	Ph
Compound No.	X12	X13	X14	X21	X22	X23	X24
F-128	X12 and X13 form a fused ring.	H	H	H	H	H
F-129	X12 and X13 form a fused ring.	Ph	Ph	H	H	Ph
F-130	X12 and X13 form a fused ring.	4408	4409	H	H	4410
F-131	X12 and X13 form a fused ring.	4411	4412	H	H	4413
F-132	X12 and X13 form a fused ring.	4414	4415	H	H	4416
F-133	X12 and X13 form a fused ring.	CH3	CH3	H	H	CH3
F-134	X12 and X13 form a fused ring.	4417	4418	H	H	4419
F-135	X12 and X13 form a fused ring.	Ph	Ph	H	H	Ph
F-136	X12 and X13 form a fused ring.	Ph	Ph	H	H	Ph
F-137	X12 and X13 form a fused ring.	Ph	Ph	H	H	Ph
F-138	X12 and X13 form a fused ring.	Ph	Ph	H	H	Ph
F-139	X12 and X13 form a fused ring.	Ph	Ph	H	H	Ph
F-140	X12 and X13 form a fused ring.	Ph	Ph	H	H	Ph
F-141	X12 and X13 form a fused ring.	Ph	Ph	Ph	Ph	Ph
F-142	X12 and X13 form a fused ring.	Ph	Ph	4420	4421	Ph
F-143	X12 and X13 form a fused ring.	Ph	Ph	CH3	CH3	Ph
Compound No.	X2	X3	X6	X7	X32	X33	X36	X37	X11
F-144	H	H	H	H	H	H	H	H	H
F-145	H	H	H	H	H	H	H	H	Ph
F-146	H	H	H	H	H	H	H	H	4422
F-147	H	H	H	H	H	H	H	H	4423
F-148	H	H	H	H	H	H	H	H	4424
F-149	H	H	H	H	H	H	H	H	CH3
F-150	H	H	H	H	H	H	H	H	4425
F-151	Ph	H	H	H	Ph	H	H	H	Ph
F-152	4426	H	H	H	4427	H	H	H	Ph
F-153	CH3	H	H	H	CH3	H	H	H	Ph
F-154	H	Ph	H	H	H	Ph	H	H	Ph
F-155	H	4428	H	H	H	4429	H	H	Ph
F-156	H	CH3	H	H	H	CH3	H	H	Ph
F-157	H	H	H	H	H	H	H	H	Ph
F-158	H	H	H	H	H	H	H	H	Ph
F-159	H	H	H	H	H	H	H	H	Ph
	Compound No.	X12	X13	X14	X21	X22	X23	X24
	F-144	H	H	H	X21 and X22 form a fused ring.	X23 and X24 form a fused ring.
	F-145	H	H	Ph	X21 and X22 form a fused ring.	X23 and X24 form a fused ring.
	F-146	H	H	4430	X21 and X22 form a fused ring.	X23 and X24 form a fused ring.
	F-147	H	H	4431	X21 and X22 form a fused ring.	X23 and X24 form a fused ring.
	F-148	H	H	4432	X21 and X22 form a fused ring.	X23 and X24 form a fused ring.
	F-149	H	H	CH3	X21 and X22 form a fused ring.	X23 and X24 form a fused ring.
	F-150	H	H	4433	X21 and X22 form a fused ring.	X23 and X24 form a fused ring.
	F-151	H	H	Ph	X21 and X22 form a fused ring.	X23 and X24 form a fused ring.
	F-152	H	H	Ph	X21 and X22 form a fused ring.	X23 and X24 form a fused ring.
	F-153	H	H	Ph	X21 and X22 form a fused ring.	X23 and X24 form a fused ring.
	F-154	H	H	Ph	X21 and X22 form a fused ring.	X23 and X24 form a fused ring.
	F-155	H	H	Ph	X21 and X22 form a fused ring.	X23 and X24 form a fused ring.
	F-156	H	H	Ph	X21 and X22 form a fused ring.	X23 and X24 form a fused ring.
	F-157	Ph	Ph	Ph	X21 and X22 form a fused ring.	X23 and X24 form a fused ring.
	F-158	4434	4435	Ph	X21 and X22 form a fused ring.	X23 and X24 form a fused ring.
	F-159	CH3	CH3	Ph	X21 and X22 form a fused ring.	X23 and X24 form a fused ring.
Compound No.	X2	X3	X6	X7	X32	X33	X36	X37	X11       X12
F-160	H	H	H	H	H	H	H	H	X11 and X12 form a fused ring.
F-161	Ph	H	H	H	Ph	H	H	H	X11 and X12 form a fused ring.
F-162	4436	H	H	H	4437	H	H	H	X11 and X12 form a fused ring.
F-163	CH3	H	H	H	CH3	H	H	H	X11 and X12 form a fused ring.
F-164	H	Ph	H	H	H	Ph	H	H	X11 and X12 form a fused ring.
F-165	H	4438	H	H	H	4439	H	H	X11 and X12 form a fused ring.
F-166	H	CH3	H	H	H	CH3	H	H	X11 and X12 form a fused ring.
	Compound No.	X13	X14	X21	X22	X23	X24
	F-160	X13 and X14 form a fused ring.	X21 and X22 form a fused ring.	X23 and X24 form a fused ring.
	F-161	X13 and X14 form a fused ring.	X21 and X22 form a fused ring.	X23 and X24 form a fused ring.
	F-162	X13 and X14 form a fused ring.	X21 and X22 form a fused ring.	X23 and X24 form a fused ring.
	F-163	X13 and X14 form a fused ring.	X21 and X22 form a fused ring.	X23 and X24 form a fused ring.
	F-164	X13 and X14 form a fused ring.	X21 and X22 form a fused ring.	X23 and X24 form a fused ring.
	F-165	X13 and X14 form a fused ring.	X21 and X22 form a fused ring.	X23 and X24 form a fused ring.
	F-166	X13 and X14 form a fused ring.	X21 and X22 form a fused ring.	X23 and X24 form a fused ring.
Compound No.	X2	X3	X6	X7	X32	X33	X36	X37	X11
F-167	H	H	H	H	H	H	H	H	H
F-168	H	H	H	H	H	H	H	H	Ph
F-169	H	H	H	H	H	H	H	H	4440
F-170	H	H	H	H	H	H	H	H	4441
F-171	H	H	H	H	H	H	H	H	4442
F-172	H	H	H	H	H	H	H	H	CH3
F-173	H	H	H	H	H	H	H	H	4443
F-174	Ph	H	H	H	Ph	H	H	H	Ph
F-175	4444	H	H	H	4445	H	H	H	Ph
F-176	CH3	H	H	H	CH3	H	H	H	Ph
F-177	H	Ph	H	H	H	Ph	H	H	Ph
F-178	H	4446	H	H	H	4447	H	H	Ph
F-179	H	CH3	H	H	H	CH3	H	H	Ph
F-180	H	H	H	H	H	H	H	H	Ph
F-181	H	H	H	H	H	H	H	H	Ph
F-182	H	H	H	H	H	H	H	H	Ph
	Compound No.	X12	X13	X14	X21	X22	X23	X24
	F-167	H	X13 and X14 form a fused ring.	X21 and X22 form a fused ring.	H	H
	F-168	H	X13 and X14 form a fused ring.	X21 and X22 form a fused ring.	H	Ph
	F-169	H	X13 and X14 form a fused ring.	X21 and X22 form a fused ring.	H	4448
	F-170	H	X13 and X14 form a fused ring.	X21 and X22 form a fused ring.	H	4449
	F-171	H	X13 and X14 form a fused ring.	X21 and X22 form a fused ring.	H	4450
	F-172	H	X13 and X14 form a fused ring.	X21 and X22 form a fused ring.	H	CH3
	F-173	H	X13 and X14 form a fused ring.	X21 and X22 form a fused ring.	H	4451
	F-174	H	X13 and X14 form a fused ring.	X21 and X22 form a fused ring.	H	Ph
	F-175	H	X13 and X14 form a fused ring.	X21 and X22 form a fused ring.	H	Ph
	F-176	H	X13 and X14 form a fused ring.	X21 and X22 form a fused ring.	H	Ph
	F-177	H	X13 and X14 form a fused ring.	X21 and X22 form a fused ring.	H	Ph
	F-178	H	X13 and X14 form a fused ring.	X21 and X22 form a fused ring.	H	Ph
	F-179	H	X13 and X14 form a fused ring.	X21 and X22 form a fused ring.	H	Ph
	F-180	Ph	X13 and X14 form a fused ring.	X21 and X22 form a fused ring.	Ph	Ph
	F-181	4452	X13 and X14 form a fused ring.	X21 and X22 form a fused ring.	4453	Ph
	F-182	CH3	X13 and X14 form a fused ring.	X21 and X22 form a fused ring.	CH3	Ph
Compound No.	X2	X3	X6	X7	X32	X33	X36	X37	X11
F-183	H	H	H	H	H	H	H	H	H
F-184	H	H	H	H	H	H	H	H	Ph
F-185	H	H	H	H	H	H	H	H	4454
F-186	H	H	H	H	H	H	H	H	4455
F-187	H	H	H	H	H	H	H	H	4456
F-188	H	H	H	H	H	H	H	H	CH3
F-189	H	H	H	H	H	H	H	H	4457
F-190	Ph	H	H	H	Ph	H	H	H	Ph
F-191	4458	H	H	H	4459	H	H	H	Ph
F-192	CH3	H	H	H	CH3	H	H	H	Ph
F-193	H	Ph	H	H	H	Ph	H	H	Ph
F-194	H	4460	H	H	H	4461	H	H	Ph
F-195	H	CH3	H	H	H	CH3	H	H	Ph
F-196	H	H	H	H	H	H	H	H	Ph
F-197	H	H	H	H	H	H	H	H	Ph
F-198	H	H	H	H	H	H	H	H	Ph
	Compound No.	X12	X13	X14	X21	X22	X23	X24
	F-183	H	X13 and X14 form a fused ring.	H	H	H	H
	F-184	H	X13 and X14 form a fused ring.	Ph	H	X23 and X24 form a fused ring.
	F-185	H	X13 and X14 form a fused ring.	4462	H	X23 and X24 form a fused ring.
	F-186	H	X13 and X14 form a fused ring.	4463	H	X23 and X24 form a fused ring.
	F-187	H	X13 and X14 form a fused ring.	4464	H	X23 and X24 form a fused ring.
	F-188	H	X13 and X14 form a fused ring.	CH3	H	X23 and X24 form a fused ring.
	F-189	H	X13 and X14 form a fused ring.	4465	H	X23 and X24 form a fused ring.
	F-190	H	X13 and X14 form a fused ring.	Ph	H	X23 and X24 form a fused ring.
	F-191	H	X13 and X14 form a fused ring.	Ph	H	X23 and X24 form a fused ring.
	F-192	H	X13 and X14 form a fused ring.	Ph	H	X23 and X24 form a fused ring.
	F-193	H	X13 and X14 form a fused ring.	Ph	H	X23 and X24 form a fused ring.
	F-194	H	X13 and X14 form a fused ring.	Ph	H	X23 and X24 form a fused ring.
	F-195	H	X13 and X14 form a fused ring.	Ph	H	X23 and X24 form a fused ring.
	F-196	Ph	X13 and X14 form a fused ring.	Ph	Ph	X23 and X24 form a fused ring.
	F-197	4466	X13 and X14 form a fused ring.	Ph	4467	X23 and X24 form a fused ring.
	F-198	CH3	X13 and X14 form a fused ring.	Ph	CH3	X23 and X24 form a fused ring.

[0287]

4468	“A and B form a fused ring” in	4469	means	4470
Compound No.	X2 = X32	X3 = X33	X6 = X36	X7 = X37	X11	X14	X15
G-1	H	H	H	H	H	H	H
G-2	H	H	H	H	Ph	Ph	H
G-3	H	H	H	H	4471	4472	H
G-4	H	H	H	H	4473	4474	H
G-5	H	H	H	H	4475	4476	H
G-6	H	H	H	H	CH3	CH3	H
G-7	H	H	H	H	4477	4478	H
G-8	H	H	H	H	Ph	Ph	Ph
G-9	H	H	H	H	Ph	Ph	4479
G-10	H	H	H	H	Ph	Ph	CH3
G-11	H	H	H	H	Ph	Ph	H
G-12	H	H	H	H	Ph	Ph	H
G-13	H	H	H	H	Ph	Ph	H
G-14	Ph	H	H	H	Ph	Ph	H
G-15	4480	H	H	H	Ph	Ph	H
G-16	CH3	H	H	H	Ph	Ph	H
Compound No.	X16	X17	X18	X21	X24
G-1	H	H	H	H	H
G-2	H	H	H	Ph	Ph
G-3	H	H	H	4481	4482
G-4	H	H	H	4483	4484
G-5	H	H	H	4485	4486
G-6	H	H	H	CH3	CH3
G-7	H	H	H	4487	4488
G-8	H	H	Ph	Ph	Ph
G-9	H	H	4489	Ph	Ph
G-10	H	H	CH3	Ph	Ph
G-11	Ph	Ph	H	Ph	Ph
G-12	4490	4491	H	Ph	Ph
G-13	CH3	CH3	H	Ph	Ph
G-14	H	H	H	Ph	Ph
G-15	H	H	H	Ph	Ph
G-16	H	H	H	Ph	Ph
	Compound No.	X25	X26	X27	X28
	G-1	H	H	H	H
	G-2	H	H	H	H
	G-3	H	H	H	H
	G-4	H	H	H	H
	G-5	H	H	H	H
	G-6	H	H	H	H
	G-7	H	H	H	H
	G-8	Ph	H	H	Ph
	G-9	4492	H	H	4493
	G-10	CH3	H	H	CH3
	G-11	H	Ph	Ph	H
	G-12	H	4494	4495	H
	G-13	H	CH3	CH3	H
	G-14	H	H	H	H
	G-15	H	H	H	H
	G-16	H	H	H	H
Compound
No.	X2 = X32	X3 = X33	X6 = X36	X7 = X37	X11	X14	X15	X16	X17
G-17	H	H	H	H	H	H	H	X16 and X17 form a fused ring.
G-18	H	H	H	H	Ph	Ph	H	X16 and X17 form a fused ring.
G-19	H	H	H	H	4496	4497	H	X16 and X17 form a fused ring.
G-20	H	H	H	H	4498	4499	H	X16 and X17 form a fused ring.
G-21	H	H	H	H	4500	4501	H	X16 and X17 form a fused ring.
G-22	H	H	H	H	CH3	CH3	H	X16 and X17 form a fused ring.
G-23	H	H	H	H	4502	4503	H	X16 and X17 form a fused ring.
G-24	H	H	H	H	Ph	Ph	Ph	X16 and X17 form a fused ring.
G-25	H	H	H	H	Ph	Ph	4504	X16 and X17 form a fused ring.
G-26	H	H	H	H	Ph	Ph	CH3	X16 and X17 form a fused ring.
G-27	Ph	H	H	H	Ph	Ph	H	X16 and X17 form a fused ring.
G-28	4505	H	H	H	Ph	Ph	H	X16 and X17 form a fused ring.
G-29	CH3	H	H	H	Ph	Ph	H	X16 and X17 form a fused ring.
	Compound
	No.	X18	X21	X24	X25	X26	X27	X28
	G-17	H	H	H	H	X26 and X27 form a fused ring	H
	G-18	H	Ph	Ph	H	X26 and X27 form a fused ring	H
	G-19	H	4506	4507	H	X26 and X27 form a fused ring	H
	G-20	H	4508	4509	H	X26 and X27 form a fused ring	H
	G-21	H	4510	4511	H	X26 and X27 form a fused ring	H
	G-22	H	CH3	CH3	H	X26 and X27 form a fused ring	H
	G-23	H	4512	4513	H	X26 and X27 form a fused ring	H
	G-24	Ph	Ph	Ph	Ph	X26 and X27 form a fused ring	H
	G-25	4514	Ph	Ph	4515	X26 and X27 form a fused ring	H
	G-26	CH3	Ph	Ph	CH3	X26 and X27 form a fused ring	H
	G-27	H	Ph	Ph	H	X26 and X27 form a fused ring	H
	G-28	H	Ph	Ph	H	X26 and X27 form a fused ring	H
	G-29	H	Ph	Ph	H	X26 and X27 form a fused ring	H
Compound No.	X2 = X32	X3 = X33	X6 = X36	X7 = X37	X11	X14	X15
G-30	H	H	H	H	H	H	H
G-31	H	H	H	H	Ph	Ph	H
G-32	H	H	H	H	4516	4517	H
G-33	H	H	H	H	4518	4519	H
G-34	H	H	H	H	4520	4521	H
G-35	H	H	H	H	CH3	CH3	H
G-36	H	H	H	H	4522	4523	H
G-37	H	H	H	H	Ph	Ph	Ph
G-38	H	H	H	H	Ph	Ph	4524
G-39	H	H	H	H	Ph	Ph	CH3
G-40	H	H	H	H	Ph	Ph	H
G-41	H	H	H	H	Ph	Ph	H
G-42	H	H	H	H	Ph	Ph	H
G-43	Ph	H	H	H	Ph	Ph	H
G-44	4525	H	H	H	Ph	Ph	H
G-45	CH3	H	H	H	Ph	Ph	H
Compound No.	X16       X17	X18	X21	X24	X25
G-30	X16 and X17 form a fused ring.	H	H	H	H
G-31	X16 and X17 form a fused ring.	H	Ph	Ph	H
G-32	X16 and X17 form a fused ring.	H	4526	4527	H
G-33	X16 and X17 form a fused ring.	H	4528	4529	H
G-34	X16 and X17 form a fused ring.	H	4530	4531	H
G-35	X16 and X17 form a fused ring.	H	CH3	CH3	H
G-36	X16 and X17 form a fused ring.	H	4532	4533	H
G-37	X16 and X17 form a fused ring.	Ph	Ph	Ph	Ph
G-38	X16 and X17 form a fused ring.	4534	Ph	Ph	4535
G-39	X16 and X17 form a fused ring.	CH3	Ph	Ph	CH3
G-40	X16 and X17 form a fused ring.	H	Ph	Ph	H
G-41	X16 and X17 form a fused ring.	H	Ph	Ph	H
G-42	X16 and X17 form a fused ring.	H	Ph	Ph	H
G-43	X16 and X17 form a fused ring.	H	Ph	Ph	H
G-44	X16 and X17 form a fused ring.	H	Ph	Ph	H
G-45	X16 and X17 form a fused ring.	H	Ph	Ph	H
	Compound No.	X26	X27	X28
	G-30	H	H	H
	G-31	H	H	H
	G-32	H	H	H
	G-33	H	H	H
	G-34	H	H	H
	G-35	H	H	H
	G-36	H	H	H
	G-37	H	H	Ph
	G-38	H	H	4536
	G-39	H	H	CH3
	G-40	Ph	Ph	H
	G-41	4537	4538	H
	G-42	CH3	CH3	H
	G-43	H	H	H
	G-44	H	H	H
	G-45	H	H	H
Compound
No.	X2 = X32	X3 = X33	X6 = X36	X7 = X37	X11	X14	X15	X16	X17
G-46	H	H	H	H	H	H	X15 and X16 form a fused ring.	H
G-47	H	H	H	H	Ph	Ph	X15 and X16 form a fused ring.	H
G-48	H	H	H	H	4539	4540	X15 and X16 form a fused ring.	H
G-49	H	H	H	H	4541	4542	X15 and X16 form a fused ring.	H
G-50	H	H	H	H	4543	4544	X15 and X16 form a fused ring.	H
G-51	H	H	H	H	CH3	CH3	X15 and X16 form a fused ring.	H
G-52	H	H	H	H	4545	4546	X15 and X16 form a fused ring.	H
G-53	H	H	H	H	Ph	Ph	X15 and X16 form a fused ring.	H
G-54	H	H	H	H	Ph	Ph	X15 and X16 form a fused ring.	H
G-55	H	H	H	H	Ph	Ph	X15 and X16 form a fused ring.	H
G-56	H	H	H	H	Ph	Ph	X15 and X16 form a fused ring.	Ph
G-57	H	H	H	H	Ph	Ph	X15 and X16 form a fused ring.	4547
G-58	H	H	H	H	Ph	Ph	X15 and X16 form a fused ring.	CH3
G-59	Ph	H	H	H	Ph	Ph	X15 and X16 form a fused ring.
G-60	4548	H	H	H	Ph	Ph	X15 and X16 form a fused ring.
G-61	CH3	H	H	H	Ph	Ph	X15 and X16 form a fused ring.
	Compound
	No.	X18	X21	X24	X25	X26	X27	X28
	G-46	H	H	H	H	H	X27 and X28 form a fused ring.
	G-47	H	Ph	Ph	H	H	X27 and X28 form a fused ring.
	G-48	H	4549	4550	H	H	X27 and X28 form a fused ring.
	G-49	H	4551	4552	H	H	X27 and X28 form a fused ring.
	G-50	H	4553	4554	H	H	X27 and X28 form a fused ring.
	G-51	H	CH3	CH3	H	H	X27 and X28 form a fused ring.
	G-52	H	4555	4556	H	H	X27 and X28 form a fused ring.
	G-53	Ph	Ph	Ph	Ph	H	X27 and X28 form a fused ring.
	G-54	4557	Ph	Ph	4558	H	X27 and X28 form a fused ring.
	G-55	CH3	Ph	Ph	CH3	H	X27 and X28 form a fused ring.
	G-56	H	Ph	Ph	H	Ph	X27 and X28 form a fused ring.
	G-57	H	Ph	Ph	H	4559	X27 and X28 form a fused ring.
	G-58	H	Ph	Ph	H	CH3	X27 and X28 form a fused ring.
	G-59	H	Ph	Ph	H	H	X27 and X28 form a fused ring.
	G-60	H	Ph	Ph	H	H	X27 and X28 form a fused ring.
	G-61	H	Ph	Ph	H	H	X27 and X28 form a fused ring.
Compound
No.	X2 = X32	X3 = X33	X6 = X36	X7 = X37	X11	X14	X15	X16	X17	X18
G-62	H	H	H	H	H	H	X15 and X16 form a fused ring.	X17 and X18 form a fused ring.
G-63	H	H	H	H	Ph	Ph	X15 and X16 form a fused ring.	X17 and X18 form a fused ring.
G-64	H	H	H	H	4560	4561	X15 and X16 form a fused ring.	X17 and X18 form a fused ring.
G-65	H	H	H	H	4562	4563	X15 and X16 form a fused ring.	X17 and X18 form a fused ring.
G-66	H	H	H	H	4564	4565	X15 and X16 form a fused ring.	X17 and X18 form a fused ring.
G-67	H	H	H	H	CH3	CH3	X15 and X16 form a fused ring.	X17 and X18 form a fused ring.
G-68	H	H	H	H	4566	4567	X15 and X16 form a fused ring.	X17 and X18 form a fused ring.
G-69	Ph	H	H	H	Ph	Ph	X15 and X16 form a fused ring.	X17 and X18 form a fused ring.
G-70	4568	H	H	H	Ph	Ph	X15 and X16 form a fused ring.	X17 and X18 form a fused ring.
G-71	CH3	H	H	H	Ph	Ph	X15 and X16 form a fused ring.	X17 and X18 form a fused ring.
	Compound
	No.	X21	X24	X25	X26	X27	X28
	G-62	H	H	X25 and X26 form a fused ring.	X27 and X28 form a fused ring.
	G-63	Ph	Ph	X25 and X26 form a fused ring.	X27 and X28 form a fused ring.
	G-64	4569	4570	X25 and X26 form a fused ring.	X27 and X28 form a fused ring.
	G-65	4571	4572	X25 and X26 form a fused ring.	X27 and X28 form a fused ring.
	G-66	4573	4574	X25 and X26 form a fused ring.	X27 and X28 form a fused ring.
	G-67	CH3	CH3	X25 and X26 form a fused ring.	X27 and X28 form a fused ring.
	G-68	4575	4576	X25 and X26 form a fused ring.	X27 and X28 form a fused ring.
	G-69	Ph	Ph	X25 and X26 form a fused ring.	X27 and X28 form a fused ring.
	G-70	Ph	Ph	X25 and X26 form a fused ring.	X27 and X28 form a fused ring.
	G-71	Ph	Ph	X25 and X26 form a fused ring.	X27 and X28 form a fused ring.
Compound No.	X2       X3	X6	X7	X32	X33	X36	X37	X11 = X21	X14 = X24
G-72	X2 and X3 form a fused ring.	H	H	H	H	H	H	H	H
G-73	X2 and X3 form a fused ring.	H	H	H	H	H	H	Ph	Ph
G-74	X2 and X3 form a fused ring.	H	H	H	H	H	H	4577	4578
G-75	X2 and X3 form a fused ring.	H	H	H	H	H	H	4579	4580
G-76	X2 and X3 form a fused ring.	H	H	H	H	H	H	4581	4582
G-77	X2 and X3 form a fused ring.	H	H	H	H	H	H	CH3	CH3
G-78	X2 and X3 form a fused ring.	H	H	H	H	H	H	4583	4584
G-79	X2 and X3 form a fused ring.	H	H	H	H	H	H	Ph	Ph
G-80	X2 and X3 form a fused ring.	H	H	H	H	H	H	Ph	Ph
G-81	X2 and X3 form a fused ring.	H	H	H	H	H	H	Ph	Ph
G-82	X2 and X3 form a fused ring.	H	H	H	H	H	H	Ph	Ph
G-83	X2 and X3 form a fused ring.	H	H	H	H	H	H	Ph	Ph
G-84	X2 and X3 form a fused ring.	H	H	H	H	H	H	Ph	Ph
G-85	X2 and X3 form a fused ring.	H	H	Ph	H	H	H	Ph	Ph
G-86	X2 and X3 form a fused ring.	H	H	4585	H	H	H	Ph	Ph
G-87	X2 and X3 form a fused ring.	H	H	CH3	H	H	H	Ph	Ph
	Compound No.	X15 = X25	X16 = X26	X17 = X27	X18 = X28
	G-72	H	H	H	H
	G-73	H	H	H	H
	G-74	H	H	H	H
	G-75	H	H	H	H
	G-76	H	H	H	H
	G-77	H	H	H	H
	G-78	H	H	H	H
	G-79	Ph	H	H	Ph
	G-80	4586	H	H	4587
	G-81	CH3	H	H	CH3
	G-82	H	Ph	Ph	H
	G-83	H	4588	4589	H
	G-84	H	CH3	CH3	H
	G-85	H			H
	G-86	H			H
	G-87	H			H
Compound No.	X2       X3	X6	X7	X32       X33	X36	X37	X11 = X21	X14 = X24
G-88	X2 and X3 form a fused ring.	H	H	X32 and X33 form a fused ring.	H	H	H	H
G-89	X2 and X3 form a fused ring.	H	H	X32 and X33 form a fused ring.	H	H	Ph	Ph
G-90	X2 and X3 form a fused ring.	H	H	X32 and X33 form a fused ring.	H	H	4590	4591
G-91	X2 and X3 form a fused ring.	H	H	X32 and X33 form a fused ring.	H	H	4592	4593
G-92	X2 and X3 form a fused ring.	H	H	X32 and X33 form a fused ring.	H	H	4594	4595
G-93	X2 and X3 form a fused ring.	H	H	X32 and X33 form a fused ring.	H	H	CH3	CH3
G-94	X2 and X3 form a fused ring.	H	H	X32 and X33 form a fused ring.	H	H	4596	4597
G-95	X2 and X3 form a fused ring.	H	H	X32 and X33 form a fused ring.	H	H	Ph	Ph
G-96	X2 and X3 form a fused ring.	H	H	X32 and X33 form a fused ring.	H	H	Ph	Ph
G-97	X2 and X3 form a fused ring.	H	H	X32 and X33 form a fused ring.	H	H	Ph	Ph
G-98	X2 and X3 form a fused ring.	H	H	X32 and X33 form a fused ring.	H	H	Ph	Ph
G-99	X2 and X3 form a fused ring.	H	H	X32 and X33 form a fused ring.	H	H	Ph	Ph
G-100	X2 and X3 form a fused ring.	H	H	X32 and X33 form a fused ring.	H	H	Ph	Ph
	Compound No.	X15 = X25	X16 = X26	X17 = X27	X18 = X28
	G-88	H	H	H	H
	G-89	H	H	H	H
	G-90	H	H	H	H
	G-91	H	H	H	H
	G-92	H	H	H	H
	G-93	H	H	H	H
	G-94	H	H	H	H
	G-95	Ph	H	H	Ph
	G-96	4598	H	H	4599
	G-97	CH3	H	H	CH3
	G-98	H	Ph	Ph	H
	G-99	H	4600	4601	H
	G-100	H	CH3	CH3	H

[0288]

4602	“A and B form a fused ring” in	4603	means	4604
Compound No.	X2	X3	X6	X7	X32       X33	X36	X37	X34 = X35	X11	X14
H-1	H	H	H	H	X2 and X3 form a fused ring.	H	H	H	H	H
H-2	H	H	H	H	X2 and X3 form a fused ring.	H	H	H	Ph	Ph
H-3	H	H	H	H	X2 and X3 form a fused ring.	H	H	H	4605	4606
H-4	H	H	H	H	X2 and X3 form a fused ring.	H	H	H	4607	4608
H-5	H	H	H	H	X2 and X3 form a fused ring.	H	H	H	4609	4610
H-6	H	H	H	H	X2 and X3 form a fused ring.	H	H	H	CH3	CH3
H-7	H	H	H	H	X2 and X3 form a fused ring.	H	H	H	4611	4612
H-8	H	H	H	H	X2 and X3 form a fused ring.	H	H	H	Ph	Ph
H-9	H	H	H	H	X2 and X3 form a fused ring.	H	H	H	Ph	Ph
H-10	H	H	H	H	X2 and X3 form a fused ring.	H	H	H	Ph	Ph
H-11	H	H	H	H	X2 and X3 form a fused ring.	H	H	H	Ph	Ph
H-12	H	H	H	H	X2 and X3 form a fused ring.	H	H	H	Ph	Ph
H-13	H	H	H	H	X2 and X3 form a fused ring.	H	H	H	Ph	Ph
H-14	Ph	H	H	H	X2 and X3 form a fused ring.	H	H	H	Ph	Ph
H-15	4613	H	H	H	X2 and X3 form a fused ring.	H	H	H	Ph	Ph
H-16	CH3	H	H	H	X2 and X3 form a fused ring.	H	H	H	Ph	Ph
	Compound No.	X15	X16	X17	X18
	H-1	H	H	H	H
	H-2	H	H	H	H
	H-3	H	H	H	H
	H-4	H	H	H	H
	H-5	H	H	H	H
	H-6	H	H	H	H
	H-7	H	H	H	H
	H-8	Ph	H	H	Ph
	H-9	4614	H	H	4615
	H-10	CH3	H	H	CH3
	H-11	H	Ph	Ph	H
	H-12	H	4616	4617	H
	H-13	H	CH3	CH3	H
	H-14	H	H	H	H
	H-15	H	H	H	H
	H-16	H	H	H	H
Compound No.	X2 = X32	X3 = X33	X6 = X36	X7 = X37	X34 = X35	X11	X14	X15
H-17	H	H	H	H	H	H	H	H
H-18	H	H	H	H	H	Ph	Ph	H
H-19	H	H	H	H	H	4618	4619	H
H-20	H	H	H	H	H	4620	4621	H
H-21	H	H	H	H	H	4622	4623	H
H-22	H	H	H	H	H	CH3	CH3	H
H-23	H	H	H	H	H	4624	4625	H
H-24	H	H	H	H	H	Ph	Ph	Ph
H-25	H	H	H	H	H	Ph	Ph	4626
H-26	H	H	H	H	H	Ph	Ph	CH3
H-27	H	H	H	H	H	Ph	Ph	H
H-28	H	H	H	H	H	Ph	Ph	H
H-29	H	H	H	H	H	Ph	Ph	H
H-30	Ph	H	H	H	H	Ph	Ph	H
H-31	4627	H	H	H	H	Ph	Ph	H
H-32	CH3	H	H	H	H	Ph	Ph	H
	Compound No.	X16	X17	X18
	H-17	H	H	H
	H-18	H	H	H
	H-19	H	H	H
	H-20	H	H	H
	H-21	H	H	H
	H-22	H	H	H
	H-23	H	H	H
	H-24	H	H	Ph
	H-25	H	H	4628
	H-26	H	H	CH3
	H-27	Ph	Ph	H
	H-28	4629	4630	H
	H-29	CH3	CH3	H
	H-30	H	H	H
	H-31	H	H	H
	H-32	H	H	H
Compound No.	X2 = X32	X3 = X33	X6 = X36	X7 = X37	X34 = X35	X11	X14
H-33	H	H	H	H		H	H
H-34	H	H	H	H		Ph	Ph
H-35	H	H	H	H		4631	4632
H-36	H	H	H	H		4633	4634
H-37	H	H	H	H		4635	4636
H-38	H	H	H	H		CH3	CH3
H-39	H	H	H	H	H	4637	4638
H-40	H	H	H	H	H	Ph	Ph
H-41	H	H	H	H	H	Ph	Ph
H-42	H	H	H	H	H	Ph	Ph
H-43	H	H	H	H	H	Ph	Ph
H-44	H	H	H	H	H	Ph	Ph
H-45	H	H	H	H	H	Ph	Ph
H-46	Ph	H	H	H	H	Ph	Ph
H-47	4639	H	H	H	H	Ph	Ph
H-48	CH3	H	H	H	H	Ph	Ph
	Compound No.	X15	X16	X17	X18
	H-33	X15 and X16 form a fused ring.	H	H
	H-34	X15 and X16 form a fused ring.	H	H
	H-35	X15 and X16 form a fused ring.	H	H
	H-36	X15 and X16 form a fused ring.	H	H
	H-37	X15 and X16 form a fused ring.	H	H
	H-38	X15 and X16 form a fused ring.	H	H
	H-39	X15 and X16 form a fused ring.	H	H
	H-40	X15 and X16 form a fused ring.	H	Ph
	H-41	X15 and X16 form a fused ring.	H	4640
	H-42	X15 and X16 form a fused ring.	H	CH3
	H-43	X15 and X16 form a fused ring.	Ph	H
	H-44	X15 and X16 form a fused ring.	4641	H
	H-45	X15 and X16 form a fused ring.	CH3	H
	H-46	X15 and X16 form a fused ring.		H
	H-47	X15 and X16 form a fused ring.		H
	H-48	X15 and X16 form a fused ring.		H
Compound No.	X2 = X32	X3 = X33	X6 = X36	X7 = X37	X34 = X35	X11	X14
H-49	H	H	H	H	H	H	H
H-50	H	H	H	H	H	Ph	Ph
H-51	H	H	H	H	H	4642	4643
H-52	H	H	H	H	H	4644	4645
H-53	H	H	H	H	H	4646	4647
H-54	H	H	H	H	H	CH3	CH3
H-55	H	H	H	H	H	4648	4649
H-56	H	H	H	H	H	Ph	Ph
H-57	H	H	H	H	H	Ph	Ph
H-58	H	H	H	H	H	Ph	Ph
H-59	H	H	H	H	H	Ph	Ph
H-60	H	H	H	H	H	Ph	Ph
H-61	H	H	H	H	H	Ph	Ph
H-62	Ph	H	H	H	H	Ph	Ph
H-63	4650	H	H	H	H	Ph	Ph
H-64	CH3	H	H	H	H	Ph	Ph
	Compound No.	X15	X16	X17	X18
	H-49	H	X16 and X17 form a fused ring.	H
	H-50	H	X16 and X17 form a fused ring.	H
	H-51	H	X16 and X17 form a fused ring.	H
	H-52	H	X16 and X17 form a fused ring.	H
	H-53	H	X16 and X17 form a fused ring.	H
	H-54	H	X16 and X17 form a fused ring.	H
	H-55	H	X16 and X17 form a fused ring.	H
	H-56	Ph	X16 and X17 form a fused ring.	Ph
	H-57	4651	X16 and X17 form a fused ring.	4652
	H-58	CH3	X16 and X17 form a fused ring.	CH3
	H-59	H	X16 and X17 form a fused ring.	H
	H-60	H	X16 and X17 form a fused ring.	H
	H-61	H	X16 and X17 form a fused ring.	H
	H-62	H	X16 and X17 form a fused ring.	H
	H-63	H	X16 and X17 form a fused ring.	H
	H-64	H	X16 and X17 form a fused ring.	H
Compound No.	X2 = X32	X3 = X33	X6 = X36	X7 = X37	X34 = X35	X11	X14
H-65	H	H	H	H	H	H	H
H-66	H	H	H	H	H	Ph	Ph
H-67	H	H	H	H	H	4653	4654
H-68	H	H	H	H	H	4655	4656
H-69	H	H	H	H	H	4657	4658
H-70	H	H	H	H	H	CH3	CH3
H-71	H	H	H	H	H	4659	4660
H-72	Ph	H	H	H	H	Ph	Ph
H-73	4661	H	H	H	H	Ph	Ph
H-74	CH3	H	H	H	H	Ph	Ph
	Compound No.	X15       X16	X17       X18
	H-65	X15 and X16 form a fused ring.	X17 and X18 form a fused ring.
	H-66	X15 and X16 form a fused ring.	X17 and X18 form a fused ring.
	H-67	X15 and X16 form a fused ring.	X17 and X18 form a fused ring.
	H-68	X15 and X16 form a fused ring.	X17 and X18 form a fused ring.
	H-69	X15 and X16 form a fused ring.	X17 and X18 form a fused ring.
	H-70	X15 and X16 form a fused ring.	X17 and X18 form a fused ring.
	H-71	X15 and X16 form a fused ring.	X17 and X18 form a fused ring.
	H-72	X15 and X16 form a fused ring.	X17 and X18 form a fused ring.
	H-73	X15 and X16 form a fused ring.	X17 and X18 form a fused ring.
	H-74	X15 and X16 form a fused ring.	X17 and X18 form a fused ring.
4662	“A and B form a fused ring” in	4663	means	4664
Compound No.	X2       X3	X6	X7	X32       X33	X36	X37	X34 = X35	X11	X14
H-75	X2 and X3 form a fused ring.	H	H	X32 and X33 form a fused ring.	H	H	H	H	H
H-76	X2 and X4 form a fused ring.	H	H	X32 and X33 form a fused ring.	H	H	H	Ph	Ph
H-77	X2 and X5 form a fused ring.	H	H	X32 and X33 form a fused ring.	H	H	H	4665	4666
H-78	X2 and X6 form a fused ring.	H	H	X32 and X33 form a fused ring.	H	H	H	4667	4668
H-79	X2 and X7 form a fused ring.	H	H	X32 and X33 form a fused ring.	H	H	H	4669	4670
H-80	X2 and X8 form a fused ring.	H	H	X32 and X33 form a fused ring.	H	H	H	CH3	CH3
H-81	X2 and X9 form a fused ring.	H	H	X32 and X33 form a fused ring.	H	H	H	4671	4672
H-82	X2 and X10 form a fused ring.	H	H	X32 and X33 form a fused ring.	H	H	H	Ph	Ph
H-83	X2 and X11 form a fused ring.	H	H	X32 and X33 form a fused ring.	H	H	H	Ph	Ph
H-84	X2 and X12 form a fused ring.	H	H	X32 and X33 form a fused ring.	H	H	H	Ph	Ph
H-85	X2 and X13 form a fused ring.	H	H	X32 and X33 form a fused ring.	H	H	H	Ph	Ph
H-86	X2 and X14 form a fused ring.	H	H	X32 and X33 form a fused ring.	H	H	H	Ph	Ph
H-87	X2 and X15 form a fused ring.	H	H	X32 and X33 form a fused ring.	H	H	H	Ph	Ph
	Compound No.	X15	X16	X17	X18
	H-75	H	H	H	H
	H-76	H	H	H	H
	H-77	H	H	H	H
	H-78	H	H	H	H
	H-79	H	H	H	H
	H-80	H	H	H	H
	H-81	H	H	H	H
	H-82	Ph	H	H	Ph
	H-83	4673	H	H	4674
	H-84	CH3	H	H	CH3
	H-85	H	Ph	Ph	H
	H-86	H	4675	4676	H
	H-87	H	CH3	CH3	H
4677	“A and B form a fused ring” in	4678	means	4679
Compound No.	X2       X3	X6	X7	X32	X33	X36	X37	X34 = X35	X11	X14
H-88	X2 and X3 form a fused ring.	H	H	H	H	H	H	H	H	H
H-89	X2 and X4 form a fused ring.	H	H	H	H	H	H	H	Ph	Ph
H-90	X2 and X5 form a fused ring.	H	H	H	H	H	H	H	4680	4681
H-91	X2 and X6 form a fused ring.	H	H	H	H	H	H	H	4682	4683
H-92	X2 and X7 form a fused ring.	H	H	H	H	H	H	H	4684	4685
H-93	X2 and X8 form a fused ring.	H	H	H	H	H	H	H	CH3	CH3
H-94	X2 and X9 form a fused ring.	H	H	H	H	H	H	H	4686	4687
H-95	X2 and X10 form a fused ring.	H	H	H	H	H	H	H	Ph	Ph
H-96	X2 and X11 form a fused ring.	H	H	H	H	H	H	H	Ph	Ph
H-97	X2 and X12 form a fused ring.	H	H	H	H	H	H	H	Ph	Ph
H-98	X2 and X13 form a fused ring.	H	H	H	H	H	H	H	Ph	Ph
H-99	X2 and X14 form a fused ring.	H	H	H	H	H	H	H	Ph	Ph
H-100	X2 and X15 form a fused ring.	H	H	H	H	H	H	H	Ph	Ph
H-101	X2 and X16 form a fused ring.	H	H	Ph	H	H	H	H	Ph	Ph
H-102	X2 and X17 form a fused ring.	H	H	4688	H	H	H	H	Ph	Ph
H-103	X2 and X18 form a fused ring.	H	H	CH3	H	H	H	H	Ph	Ph
	Compound No.	X15	X16	X17	X18
	H-88	H	H	H	H
	H-89	H	H	H	H
	H-90	H	H	H	H
	H-91	H	H	H	H
	H-92	H	H	H	H
	H-93	H	H	H	H
	H-94	H	H	H	H
	H-95	Ph	H	H	Ph
	H-96	4689	H	H	4690
	H-97	CH3	H	H	CH3
	H-98	H	Ph	Ph	H
	H-99	H	4691	4692	H
	H-100	H	CH3	CH3	H
	H-101	H	H	H	H
	H-102	H	H	H	H
	H-103	H	H	H	H

[0289]

4693	“A and B form a fused ring” in	4694	means	4695
Compound No.	X2	X3	X6	X7	X32	X33	X34 = X35	X36	X37
I-1	H	H	H	H	H	H	H	H	H
I-2	H	H	H	H	H	H	H	H	H
I-3	H	H	H	H	H	H	H	H	H
I-4	H	H	H	H	H	H	H	H	H
I-5	H	H	H	H	H	H	H	H	H
I-6	H	H	H	H	H	H	H	H	H
I-7	H	H	H	H	H	H	H	H	H
I-8	Ph	H	H	H	Ph	H	H	H	H
I-9	4696	H	H	H	4697	H	H	H	H
I-10	CH3	H	H	H	CH3	H	H	H	H
I-11	H	Ph	H	H	H	Ph	H	H	H
I-12	H	4698	H	H	H	4699	H	H	H
I-13	H	CH3	H	H	H	CH3	H	H	H
I-14	H	H	H	H	H	H	H	H	H
I-15	H	H	H	H	H	H	H	H	H
I-16	H	H	H	H	H	H	H	H	H
I-17	H	H	H	H	H	H	H	H	H
I-18	H	H	H	H	H	H	H	H	H
I-19	H	H	H	H	H	H	H	H	H
I-20	H	H	H	H	H	H	H	H	H
I-21	H	H	H	H	H	H	H	H	H
I-22	H	H	H	H	H	H	H	H	H
I-23	H	H	H	H	H	H	H	H	H
I-24	Ph	H	H	H	Ph	H	H	H	H
I-25	4700	H	H	H	4701	H	H	H	H
I-26	CH3	H	H	H	CH3	H	H	H	H
I-27	H	Ph	H	H	H	Ph	H	H	H
I-28	H	4702	H	H	H	4703	H	H	H
I-29	H	CH3	H	H	H	CH3	H	H	H
I-30	H	H	H	H	H	H	H	H	H
I-31	H	H	H	H	H	H	H	H	H
I-32	H	H	H	H	H	H	H	H	H
	Compound No.	X11	X12	X13	X14
	I-1	H	H	H	H
	I-2	Ph	H	H	Ph
	I-3	4704	H	H	4705
	I-4	4706	H	H	4707
	I-5	4708	H	H	4709
	I-6	CH3	H	H	CH3
	I-7	4710	H	H	4711
	I-8	Ph	H	H	Ph
	I-9	Ph	H	H	Ph
	I-10	Ph	H	H	Ph
	I-11	Ph	H	H	Ph
	I-12	Ph	H	H	Ph
	I-13	Ph	H	H	Ph
	I-14	Ph	Ph	Ph	Ph
	I-15	Ph	4712	4713	Ph
	I-16	Ph	CH3	CH3	Ph
	I-17	H	H	X13 and X14 form a fused ring.
	I-18	Ph	H	X13 and X14 form a fused ring.
	I-19	4714	H	X13 and X14 form a fused ring.
	I-20	4715	H	X13 and X14 form a fused ring.
	I-21	4716	H	X13 and X14 form a fused ring.
	I-22	CH3	H	X13 and X14 form a fused ring.
	I-23	4717	H	X13 and X14 form a fused ring.
	I-24	Ph	H	X13 and X14 form a fused ring.
	I-25	Ph	H	X13 and X14 form a fused ring.
	I-26	Ph	H	X13 and X14 form a fused ring.
	I-27	Ph	H	X13 and X14 form a fused ring.
	I-28	Ph	H	X13 and X14 form a fused ring.
	I-29	Ph	H	X13 and X14 form a fused ring.
	I-30	Ph	Ph	X13 and X14 form a fused ring.
	I-31	Ph	4718	X13 and X14 form a fused ring.
	I-32	Ph	CH3	X13 and X14 form a fused ring.
Compound No.	X2	X3	X6	X7	X32	X33	X36	X37
I-33	H	H	H	H	H	H	H	H
I-34	Ph	H	H	H	Ph	H	H	H
I-35	4719	H	H	H	4720	H	H	H
I-36	CH3	H	H	H	CH3	H	H	H
I-37	H	Ph	H	H	H	Ph	H	H
I-38	H	4721	H	H	H	4722	H	H
I-39	H	CH3	H	H	H	CH3	H	H
	Compound No.	X11       X12	X13       X14
	I-33	X11 and X12 form a fused ring.	X13 and X14 form a fused ring.
	I-34	X11 and X12 form a fused ring.	X13 and X14 form a fused ring.
	I-35	X11 and X12 form a fused ring.	X13 and X14 form a fused ring.
	I-36	X11 and X12 form a fused ring.	X13 and X14 form a fused ring.
	I-37	X11 and X12 form a fused ring.	X13 and X14 form a fused ring.
	I-38	X11 and X12 form a fused ring.	X13 and X14 form a fused ring.
	I-39	X11 and X12 form a fused ring.	X13 and X14 form a fused ring.
Compound No.	X2       X3	X6	X7	X32	X33	X34 = X35	X36	X37	X11
I-40	X2 and X3 form a fused ring.	H	H	H	H	H	H	H	H
I-41	X2 and X3 form a fused ring.	H	H	H	H	H	H	H	Ph
I-42	X2 and X3 form a fused ring.	H	H	H	H	H	H	H	4723
I-43	X2 and X3 form a fused ring.	H	H	H	H	H	H	H	4724
I-44	X2 and X3 form a fused ring.	H	H	H	H	H	H	H	4725
I-45	X2 and X3 form a fused ring.	H	H	H	H	H	H	H	CH3
I-46	X2 and X3 form a fused ring.	H	H	H	H	H	H	H	4726
I-47	X2 and X3 form a fused ring.	H	H	Ph	H	H	H	H	Ph
I-48	X2 and X3 form a fused ring.	H	H	4727	H	H	H	H	Ph
I-49	X2 and X3 form a fused ring.	H	H	CH3	H	H	H	H	Ph
I-50	X2 and X3 form a fused ring.	H	H	H	Ph	H	H	H	Ph
I-51	X2 and X3 form a fused ring.	H	H	H	4728	H	H	H	Ph
I-52	X2 and X3 form a fused ring.	H	H	H	CH3	H	H	H	Ph
I-53	X2 and X3 form a fused ring.	H	H	H	H	H	H	H	Ph
I-54	X2 and X3 form a fused ring.	H	H	H	H	H	H	H	Ph
I-55	X2 and X3 form a fused ring.	H	H	H	H	H	H	H	Ph
	Compound No.	X12	X13	X14
	I-40	H	H	H
	I-41	H	H	Ph
	I-42	H	H	4729
	I-43	H	H	4730
	I-44	H	H	4731
	I-45	H	H	CH3
	I-46	H	H	4732
	I-47	H	H	Ph
	I-48	H	H	Ph
	I-49	H	H	Ph
	I-50	H	H	Ph
	I-51	H	H	Ph
	I-52	H	H	Ph
	I-53	Ph	Ph	Ph
	I-54	4733	4734	Ph
	I-55	CH3	CH3	Ph
Compound No.	X2	X3	X6	X7	X32       X33	X34 = X35	X36	X37	X11
I-56	H	H	H	H	X32 and X33 form a fused ring.	H	H	H	H
I-57	H	H	H	H	X32 and X33 form a fused ring.	H	H	H	Ph
I-58	H	H	H	H	X32 and X33 form a fused ring.	H	H	H	4735
I-59	H	H	H	H	X32 and X33 form a fused ring.	H	H	H	4736
I-60	H	H	H	H	X32 and X33 form a fused ring.	H	H	H	4737
I-61	H	H	H	H	X32 and X33 form a fused ring.	H	H	H	CH3
I-62	H	H	H	H	X32 and X33 form a fused ring.	H	H	H	4738
I-63	Ph	H	H	H	X32 and X33 form a fused ring.	H	H	H	Ph
I-64	4739	H	H	H	X32 and X33 form a fused ring.	H	H	H	Ph
I-65	CH3	H	H	H	X32 and X33 form a fused ring.	H	H	H	Ph
I-66	H	H	H	H	X32 and X33 form a fused ring.	H	H	H	Ph
I-67	H	H	H	H	X32 and X33 form a fused ring.	H	H	H	Ph
I-68	H	H	H	H	X32 and X33 form a fused ring.	H	H	H	Ph
	Compound No.	X12	X13	X14
	I-56	H	H	H
	I-57	H	H	Ph
	I-58	H	H	4740
	I-59	H	H	4741
	I-60	H	H	4742
	I-61	H	H	CH3
	I-62	H	H	4743
	I-63	H	H	Ph
	I-64	H	H	Ph
	I-65	H	H	Ph
	I-66	Ph	Ph	Ph
	I-67	4744	4745	Ph
	I-68	CH3	CH3	Ph
Compound No.	X2       X3	X6	X7	X32       X33	X34 = X35	X36	X37	X11
I-69	X2 and X3 form a fused ring.	H	H	X32 and X33 form a fused ring.	H	H	H	H
I-70	X2 and X3 form a fused ring.	H	H	X32 and X33 form a fused ring.	H	H	H	Ph
I-71	X2 and X3 form a fused ring.	H	H	X32 and X33 form a fused ring.	H	H	H	4746
I-72	X2 and X3 form a fused ring.	H	H	X32 and X33 form a fused ring.	H	H	H	4747
I-73	X2 and X3 form a fused ring.	H	H	X32 and X33 form a fused ring.	H	H	H	4748
I-74	X2 and X3 form a fused ring.	H	H	X32 and X33 form a fused ring.	H	H	H	CH3
I-75	X2 and X3 form a fused ring.	H	H	X32 and X33 form a fused ring.	H	H	H	4749
I-76	X2 and X3 form a fused ring.	H	H	X32 and X33 form a fused ring.	H	H	H	Ph
I-77	X2 and X3 form a fused ring.	H	H	X32 and X33 form a fused ring.	H	H	H	Ph
I-78	X2 and X3 form a fused ring.	H	H	X32 and X33 form a fused ring.	H	H	H	Ph
	Compound No.	X12	X13	X14
	I-69	H	H	H
	I-70	H	H	Ph
	I-71	H	H	4750
	I-72	H	H	4751
	I-73	H	H	4752
	I-74	H	H	CH3
	I-75	H	H	4753
	I-76	Ph	Ph	Ph
	I-77	4754	4755	Ph
	I-78	CH3	CH3	Ph
Compound No.	X2      X3	X6	X7	X32	X33	X34 = X35	X36	X37
I-79	X2 and X3 form a fused ring.	H	H	H	H	H	H	H
I-80	X2 and X3 form a fused ring.	H	H	H	H	H	H	H
I-81	X2 and X3 form a fused ring.	H	H	H	H	H	H	H
I-82	X2 and X3 form a fused ring.	H	H	H	H	H	H	H
I-83	X2 and X3 form a fused ring.	H	H	H	H	H	H	H
I-84	X2 and X3 form a fused ring.	H	H	H	H	H	H	H
I-85	X2 and X3 form a fused ring.	H	H	H	H	H	H	H
I-86	X2 and X3 form a fused ring.	H	H	Ph	H	H	H	H
I-87	X2 and X3 form a fused ring.	H	H	4756	H	H	H	H
I-88	X2 and X3 form a fused ring.	H	H	CH3	H	H	H	H
I-89	X2 and X3 form a fused ring.	H	H	H	Ph	H	H	H
I-90	X2 and X3 form a fused ring.	H	H	H	4757	H	H	H
I-91	X2 and X3 form a fused ring.	H	H	H	CH3	H	H	H
I-92	X2 and X3 form a fused ring.	H	H	H	H	H	H	H
I-93	X2 and X3 form a fused ring.	H	H	H	H	H	H	H
I-94	X2 and X3 form a fused ring.	H	H	H	H	H	H	H
	Compound No.	X11	X12	X13	X14
	I-79	H	H	X13 and X14 form a fused ring.
	I-80	Ph	H	X13 and X14 form a fused ring.
	I-81	4758	H	X13 and X14 form a fused ring.
	I-82	4759	H	X13 and X14 form a fused ring.
	I-83	4760	H	X13 and X14 form a fused ring.
	I-84	CH3	H	X13 and X14 form a fused ring.
	I-85	4761	H	X13 and X14 form a fused ring.
	I-86	Ph	H	X13 and X14 form a fused ring.
	I-87	Ph	H	X13 and X14 form a fused ring.
	I-88	Ph	H	X13 and X14 form a fused ring.
	I-89	Ph	H	X13 and X14 form a fused ring.
	I-90	Ph	H	X13 and X14 form a fused ring.
	I-91	Ph	H	X13 and X14 form a fused ring.
	I-92	Ph	Ph	X13 and X14 form a fused ring.
	I-93	Ph	4762	X13 and X14 form a fused ring.
	I-94	Ph	CH3	X13 and X14 form a fused ring.
	4763	“A and B form a fused ring” in	4764	4765	means	4766
Compound No.	X2       X3	X6	X7	X32       X33	X34 = X35	X36	X37
I-95	X2 and X3 form a fused ring.	H	H	X32 and X33 form a fused ring.	H	H	H
I-96	X2 and X3 form a fused ring.	H	H	X32 and X33 form a fused ring.	H	H	H
I-97	X2 and X3 form a fused ring.	H	H	X32 and X33 form a fused ring.	H	H	H
I-98	X2 and X3 form a fused ring.	H	H	X32 and X33 form a fused ring.	H	H	H
I-99	X2 and X3 form a fused ring.	H	H	X32 and X33 form a fused ring.	H	H	H
I-100	X2 and X3 form a fused ring.	H	H	X32 and X33 form a fused ring.	H	H	H
I-101	X2 and X3 form a fused ring.	H	H	X32 and X33 form a fused ring.	H	H	H
I-102	X2 and X3 form a fused ring.	H	H	X32 and X33 form a fused ring.	H	H	H
I-103	X2 and X3 form a fused ring.	H	H	X32 and X33 form a fused ring.	H	H	H
I-104	X2 and X3 form a fused ring.	H	H	X32 and X33 form a fused ring.	H	H	H
	Compound No.	X11       X12	X13	X14
	I-95	X11 and X12 form a fused ring.		H
	I-96	X11 and X12 form a fused ring.		Ph
	I-97	X11 and X12 form a fused ring.		4767
	I-98	X11 and X12 form a fused ring.		4768
	I-99	X11 and X12 form a fused ring.		4769
	I-100	X11 and X12 form a fused ring.		CH3
	I-101	X11 and X12 form a fused ring.		4770
	I-102	X11 and X12 form a fused ring.	Ph	Ph
	I-103	X11 and X12 form a fused ring.	4771	Ph
	I-104	X11 and X12 form a fused ring.	CH4	Ph
4772	“A and B form a fused ring” in	4773	means	4774
Compound No.	X2	X3	X6	X7	X32       X33	X34 = X35	X36       X37	X11
I-105	H	H	H	H	X32 and X33 form a fused ring.	H	X36 and X37 form a fused ring.	H
I-106	H	H	H	H	X32 and X33 form a fused ring.	H	X36 and X37 form a fused ring.	Ph
I-107	H	H	H	H	X32 and X33 form a fused ring.	H	X36 and X37 form a fused ring.	4775
I-108	H	H	H	H	X32 and X33 form a fused ring.	H	X36 and X37 form a fused ring.	4776
I-109	H	H	H	H	X32 and X33 form a fused ring.	H	X36 and X37 form a fused ring.	4777
I-110	H	H	H	H	X32 and X33 form a fused ring.	H	X36 and X37 form a fused ring.	CH3
I-111	H	H	H	H	X32 and X33 form a fused ring.	H	X36 and X37 form a fused ring.	4778
I-112	H	Ph	H	H	X32 and X33 form a fused ring.	H	X36 and X37 form a fused ring.	Ph
I-113	H	4779	H	H	X32 and X33 form a fused ring.	H	X36 and X37 form a fused ring.	Ph
I-114	H	CH3	H	H	X32 and X33 form a fused ring.	H	X36 and X37 form a fused ring.	Ph
I-115	H	H	H	H	X32 and X33 form a fused ring.	H	X36 and X37 form a fused ring.	Ph
I-116	H	H	H	H	X32 and X33 form a fused ring.	H	X36 and X37 form a fused ring.	Ph
I-117	H	H	H	H	X32 and X33 forms fused ring.	H	X36 and X37 form a fused ring.	Ph
	Compound No.	X12	X13	X14
	I-105	H	H	H
	I-106	H	H	Ph
	I-107	H	H	4780
	I-108	H	H	4781
	I-109	H	H	4782
	I-110	H	H	CH3
	I-111	H	H	4783
	I-112	H	H	Ph
	I-113	H	H	Ph
	I-114	H	H	Ph
	I-115	Ph	Ph	Ph
	I-116	4784	4785	Ph
	I-117	CH3	CH3	Ph
Compound No.	X2       X3	X6       X7	X32	X33	X34 = X35	X36	X37
I-118	X2 and X3 form a fused ring.	X6 and X7 form a fused ring.	H	H	H	H	H
I-119	X2 and X3 form a fused ring.	X6 and X7 form a fused ring.	H	H	H	H	H
I-120	X2 and X3 form a fused ring.	X6 and X7 form a fused ring.	H	H	H	H	H
I-121	X2 and X3 form a fused ring.	X6 and X7 form a fused ring.	H	H	H	H	H
I-122	X2 and X3 form a fused ring.	X6 and X7 form a fused ring.	H	H	H	H	H
I-123	X2 and X3 form a fused ring.	X6 and X7 form a fused ring.	H	H	H	H	H
I-124	X2 and X3 form a fused ring.	X6 and X7 form a fused ring.	H	H	H	H	H
I-125	X2 and X3 form a fused ring.	X6 and X7 form a fused ring.	Ph	H	H	H	H
I-126	X2 and X3 form a fused ring.	X6 and X7 form a fused ring.	4786	H	H	H	H
I-127	X2 and X3 form a fused ring.	X6 and X7 form a fused ring.	CH3	H	H	H	H
I-128	X2 and X3 form a fused ring.	X6 and X7 form a fused ring.	H	Ph	H	H	H
I-129	X2 and X3 form a fused ring.	X6 and X7 form a fused ring.	H	4787	H	H	H
I-130	X2 and X3 form a fused ring.	X6 and X7 form a fused ring.	H	CH3	H	H	H
I-131	X2 and X3 form a fused ring.	X6 and X7 form a fused ring.	H	H	H	H	H
I-132	X2 and X3 form a fused ring.	X6 and X7 form a fused ring.	H	H	H	H	H
I-133	X2 and X3 form a fused ring.	X6 and X7 form a fused ring.	H	H	H	H	H
	Compound No.	X11	X12	X13	X14
	I-118	H	H	H	H
	I-119	Ph	H	H	Ph
	I-120	4788	H	H	4789
	I-121	4790	H	H	4791
	I-122	4792	H	H	4793
	I-123	CH3	H	H	CH3
	I-124	4794	H	H	4795
	I-125	Ph	H	H	Ph
	I-126	Ph	H	H	Ph
	I-127	Ph	H	H	Ph
	I-128	Ph	H	H	Ph
	I-129	Ph	H	H	Ph
	I-130	Ph	H	H	Ph
	I-131	Ph	Ph	Ph	Ph
	I-132	Ph	4796	4797	Ph
	I-133	Ph	CH3	CH3	Ph

[0290]

4798	4799
J-1	J-2
4800	4801
J-3	J-4
4802	4803
J-5	J-6
4804	4805
J-7	J-8
4806	4807	4808
J-9	J-10	J-11
4809	4810
J-12	J-13
4811	4812	4813
J-14	J-15	J-16
4814	4815	4816
J-17	J-18	J-19
4817	4818	4819
J-20	J-21	J-22
4820	4821
J-23	J-24
4822	4823	4824
J-25	J-26	J-27
4825	4826
J-28	J-29
4827	4828
J-30	J-31
4829	4830	4831
J-32	J-33	J-34
4832	4833	4834
J-35	J-36	J-37
4835	4836
J-38	J-39
4837	4838
J-40	J-41
4839	4840
J-42	J-43
4841	4842
J-44	J-45
4843
J-46

[0291] The above dopants, for example, the compounds of formula (VI) can be produced, for example, by the method described in J. Amer. Chem. Soc., 118, 2374 (1996). Specifically, as shown by the following scheme, the end compound can be produced by reacting a compound of formula (2) with a compound of formula (3) in the presence of aluminum chloride/sodium chloride, cobalt fluoride or thallium trifluoroacetate. 4844

[0292] It is noted that the fluoranthene derivatives of formulas (V), (2) and (3), can be produced, for example, by the method described in J. Amer. Chem. Soc., 118, 2374 (1996). Specifically, as shown by the following scheme, the end compound can be produced by reacting a compound of formula (4) with a compound of formula (5). 4845

[0293] Once the skeleton of formula (VI) is formed, exchange of substituents is effected by a conventional method, obtaining a compound having the desired substituent(s).

[0294] The compounds of formula (VI) are preferably compounds, dibenzo[f,f′]diindeno[1,2,3-cd:1′,2′,3′-lm]perylene derivatives in the following formula (VI′). 4846

[0295] In formula (VI′), X1 to X44 are as defined for X1 to X20 in formula (VI).

[0296] Preferably, X1 to X20 in formula (VI) and X1 to X44 in formula (VI′) are independently selected from among substituted or unsubstituted aryl, alkyl, alkenyl, alkoxy and aryloxy radicals.

[0297] Further preferably, at least one of X1 to X20 in formula (VI) and X1 to X44 in formula (VI′) is an ortho-substituted phenyl radical. Even more preferably, in formula (VI) or (VI′), either one or both of X1 and X4 and/or either one or both of X11 and X14 are ortho-substituted phenyl radicals. The introduction of a substituent at the ortho-position holds down the propensity for the compound to decompose upon sublimation purification and improves fluorescence.

[0298] The use of the ortho-substituted compound is effective for increasing the fluorescent luminance and holding down the concentration quenching of the EL device, thereby spreading the margin of the EL dopant and improving the freedom of design.

[0299] The introduction of an ortho-substituted phenyl group has several advantages. The ortho-substituted phenyl group introduced makes it possible to control the association of the perylene skeleton by virtue of its steric hindrance, to improve the solubility in solvents and to purify the compound to a high purity. For the same reason, sublimation purification becomes possible at a lower temperature and entails little decomposition. This is also advantageous in obtaining a high purity material. Using such a pure material, an organic EL device having a high emission efficiency is obtainable because the deactivation of excitons by impurities is minimized. Another reason accounting for the high efficiency is that the association between similar or distinct molecules in the light emitting layer is suppressed whereby concentration quenching is restrained.

[0300] Preferred examples of the compound of formula (VI′) are given below. 4847

[0301] The diindeno[1,2,3-cd:1′,2′,3′-lm]perylene derivative should preferably have a vibration structure in both an excitation spectrum and a fluorescence spectrum. The presence of such a vibration structure is ascertainable by the appearance of two or more peaks in each of the spectra.

[0302] More preferably, a host material obtained by doping the indenoperylene derivative has such a vibration structure.

[0303] The possession of a vibration structure leads to the manufacture of an organic EL device having improved temperature characteristics.

[0304] It is believed that a drop of EL luminous efficiency by temperature is due to thermal relaxation entailing a change of conformation in the excited state. Once a change of conformation in the excited state occurs, the overlap of molecular orbital function between the ground state and the excited state changes so that the fluorescence spectrum does not become a mirror image of the absorption spectrum. The fluorescence spectrum of a compound which can take a plurality of conformations in the excited state is the total of various vibration structures and thus becomes a broad spectrum apparently free of a vibration structure.

[0305] Accordingly, an organic compound which exhibits a vibration structure in the fluorescence spectrum and specifically, a compound whose vibration structure is a mirror image of the absorption spectrum experiences a minimal change of conformation in the excited state and therefore, when used as a luminescent material in an organic EL device, enables to produce a device having improved temperature characteristics as demonstrated by a minimal drop of EL luminous efficiency by temperature during driving.

[0306] For the same reason as above, the organic compound should preferably have a Stokes shift of up to 0.1 eV, especially up to 0.05 eV. The lower limit of Stokes shift is not critical although it is usually about 0.01 eV.

[0307] Another factor that governs the temperature characteristics of an organic EL device is the thermal excitation of carriers from the trap level. Especially in a doped light emitting layer, the dopant creates a trap level. Upon a temperature change, the hopping probability of carriers by thermal excitation changes. This sometimes results in changes of the carrier balance in the light emitting layer, leading to temperature dependent characteristics with a high efficiency. In contrast, the device of the invention has a minimized thermal change of the trapping of the light emitting layer, that is, minimized temperature dependence with a high efficiency.

[0308] In a preferred embodiment, the host material, especially at least one of the organic compounds of formulas (I) to (IV), in a light emitting layer has a greater electron affinity than an electron transporting layer and/or a hole transporting layer. If the host material in a light emitting layer has a greater electron affinity than an electron transporting layer and/or a hole transporting layer, the injection efficiency of electrons into the light emitting layer increases and electrons are blocked at the hole transporting layer interface, leading to an improvement in luminous efficiency and hence, device lifetime.

[0309] Others

[0310] The light emitting layer containing the host material and the dopant according to the invention has functions of injecting holes and electrons, transporting them, and recombining holes and electrons to create excitons. The use of relatively electronically neutral compounds in the light emitting layer in addition to the compounds of the invention enables easy and well-balanced injection and transportation of electrons and holes.

[0311] The host material may be used alone or in admixture of two or more. When a mixture of two or more host materials is used, the mix ratio is not critical. In a preferred embodiment, the light emitting layer contains 80 to 99.9%, more preferably 90 to 99.9%, even more preferably 95.0 to 99.5% by weight of the host material.

[0312] The thickness of the light emitting layer preferably ranges from the thickness corresponding to a single molecule layer to less than the thickness of an organic compound layer, for example, preferably from 1 to 85 nm, more preferably 5 to 60 nm, most preferably 5 to 50 nm.

[0313] Preferably the mix layer is formed by a co-deposition process of evaporating the compounds from distinct sources. If both the compounds have equal or very close vapor pressure or evaporation temperature, they may be pre-mixed in a common evaporation boat, from which they are evaporated together. The mix layer is preferably a uniform mixture of both the compounds although the compounds can be present in island form. The light emitting layer is generally formed to a predetermined thickness by evaporating an organic fluorescent material or coating a dispersion thereof in a resin binder.

[0314] One exemplary construction of the organic EL light emitting device fabricated using the inventive compounds has on a substrate, a hole injecting electrode, a hole injecting and transporting layer, a light emitting and electron injecting and transporting layer, and an electron injecting electrode in the described order. If desired, a protective electrode, an auxiliary electrode and a sealing layer are provided on the electron injecting electrode.

[0315] The organic EL device of the invention is not limited to the above exemplary construction and may have various other constructions. In another exemplary construction, the light emitting layer is provided singly and an electron injecting and transporting layer is interposed between the light emitting layer and the electron injecting electrode. Also, the light emitting layer may be mixed with the hole injecting and transporting layer, if desired.

[0316] The thicknesses of the light emitting layer, hole injecting and transporting layer, and electron injecting and transporting layer are not critical and vary with a particular formation technique. Usually a single layer is about 5 to 500 nm thick, especially about 10 to 300 nm thick.

[0317] The thicknesses of the hole injecting and transporting layer and electron injecting and transporting layer are equal to or range from {fraction (1/10)} to 10 times the thickness of the light emitting layer although they depend on the design of a recombination/light emitting region. When the electron or hole injecting and transporting layer is divided into an injecting layer and a transporting layer, preferably the injecting layer is at least 1 nm thick and the transporting layer is at least 1 nm thick. The upper limit of thickness is generally about 500 nm for the injecting layer and about 500 nm for the transporting layer. The same applies when two injecting and transporting layers are provided.

[0318] The hole injecting and transporting layer has functions of facilitating injection of holes from the hole injecting electrode, transporting them stably, and blocking electrons. The electron injecting and transporting layer has functions of facilitating injection of electrons from the electron injecting electrode, transporting them stably, and blocking holes. These layers are effective for increasing the number of holes and electrons injected into the light emitting layer and confining holes and electrons therein for optimizing the recombination region to improve light emission efficiency.

[0319] In the hole injecting and transporting layer, there may be used various organic compounds as described, for example, in JP-A 63-295695, 2-191694, 3-792, 5-234681, 5-239455, 5-299174, 7-126225, 7-126226, and 8-100172, and EPO 650955A1. Exemplary are tetraarylbenzidine compounds (triaryldiamines or triphenyldiamines: TPD), aromatic tertiary amines, hydrazone derivatives, carbazole derivatives, triazole derivatives, imidazole derivatives, oxadiazole derivatives having an amino group, and polythiophenes. Two or more of these compounds may be used, and on such combined use, they may be formed as separate layers or mixed.

[0320] Where the hole injecting and transporting layer is formed separately as a hole injecting layer and a hole transporting layer, two or more compounds are selected in a proper combination from the compounds commonly used in hole injecting and transporting layers. In this regard, it is preferred to laminate layers in such an order that a layer of a compound having a lower ionization potential may be disposed adjacent the hole injecting electrode (ITO). It is also preferred to use a compound having good thin film forming ability at the hole injecting electrode surface. The order of lamination also applies where a plurality of hole injecting and transporting layers are provided. Such an order of lamination is effective for lowering the drive voltage and preventing current leakage and the development and growth of dark spots. Since evaporation is utilized in the manufacture of devices, films as thin as about 1 to 10 nm can be formed uniform and pinhole-free, which restrains any change in color tone of light emission and a drop of efficiency by re-absorption even if a compound having a low ionization potential and absorption in the visible range is used in the hole injecting layer. Like the light emitting layer, the hole injecting and transporting layer may be formed by evaporating the above-mentioned compounds.

[0321] In the electron injecting and transporting layer, there may be used quinoline derivatives including organic metal complexes having 8-quinolinol or a derivative thereof as a ligand such as tris(8-quinolinolato)aluminum (Alq3), oxadiazole derivatives, perylene derivatives, pyridine derivatives, pyrimidine derivatives, quinoxaline derivatives, diphenylquinone derivatives, and nitro-substituted fluorene derivatives. The electron injecting and transporting layer can also serve as the light emitting layer. Like the light emitting layer, the electron injecting and transporting layer may be formed by evaporation or the like.

[0322] Where the electron injecting and transporting layer is formed separately as an electron injecting layer and an electron transporting layer, two or more compounds are selected in a proper combination from the compounds commonly used in electron injecting and transporting layers. In this regard, it is preferred to stack layers in such an order that a layer of a compound having a greater electron affinity may be disposed adjacent the electron injecting electrode. The order of stacking also applies where a plurality of electron injecting and transporting layers are provided.

[0323] In forming the hole injecting and transporting layer, the light emitting layer, and the electron injecting and transporting layer, vacuum evaporation is preferably used because homogeneous thin films are available. By utilizing vacuum evaporation, there is obtained a homogeneous thin film which is amorphous or has a crystal grain size of less than 0.1 μm. If the grain size is more than 0.1 μm, uneven light emission would take place and the drive voltage of the device must be increased with a substantial drop of hole injection efficiency.

[0324] The conditions for vacuum evaporation are not critical although a vacuum of 10−4 Pa or lower and a deposition rate of about 0.01 to 1 nm/sec are preferred. It is preferred to successively form layers in vacuum because the successive formation in vacuum can avoid adsorption of impurities on the interface between the layers, thus ensuring better performance. Also, the drive voltage of a device can be reduced and the development and growth of dark spots be restrained.

[0325] In the embodiment wherein the respective layers are formed by vacuum evaporation, where it is desired for a single layer to contain two or more compounds, preferably boats having the compounds received therein are individually temperature controlled to achieve co-deposition.

[0326] The electron injecting electrode is preferably made of metals, alloys or intermetallic compounds having a work function of up to 4 eV. With a work function of more than 4 eV, the electron injecting efficiency lowers and consequently, the light emission efficiency lowers. Examples of the metal having a work function of up to 4 eV of which the electron injecting electrode film is constructed include alkali metals such as Li, Na and K, alkaline earth metals such as Mg, Ca, Sr and Ba, rare earth metals such as La and Ce, and Al, In, Ag, Sn, Zn, and Zr. Examples of the film-forming alloy having a work function of up to 4 eV include Ag—Mg (Ag: 0.1 to 50 at %), Al—Li (Li: 0.01 to 12 at %), In—Mg (Mg: 50 to 80 at %), and Al—Ca (Ca: 0.01 to 20 at %). These materials may be present alone or in combination of two or more. Where two or more materials are combined, their mixing ratio is arbitrary. It is also acceptable that an oxide or halide of an alkali metal, alkaline earth metal or rare earth metal is thinly deposited and a supporting electrode (auxiliary electrode or wiring electrode) of aluminum etc. is used.

[0327] The electron injecting electrode may be formed by evaporation or sputtering.

[0328] The electron injecting electrode may have at least a sufficient thickness to effect electron injection, for example, a thickness of at least 0.1 nm. Although the upper limit is not critical, the electrode thickness is typically about 0.1 to about 500 nm.

[0329] The hole injecting electrode is preferably formed of such a material to such a thickness that the electrode may have a transmittance of at least 80% of emitted light. Illustratively, oxide transparent conductive thin films are preferred. For example, materials based on tin-doped indium oxide (ITO), zinc-doped indium oxide (IZO), indium oxide (In2O3), tin oxide (SnO2) or zinc oxide (ZnO) are preferable. These oxides may deviate somewhat from their stoichiometry. An appropriate proportion of SnO2 mixed with In2O3 is about 1 to 20% by weight, more preferably about 5 to 12% by weight. An appropriate proportion of ZnO2 mixed with In2O3 is about 12 to 32% by weight.

[0330] The hole injecting electrode should preferably have a light transmittance of at least 80%, especially at least 90% in the light emission band, typically from 350 to 800 nm, and especially at each light emission. Since the emitted light is generally taken out through the hole injecting electrode, with a lower transmittance, the light emitted by the light emitting layer would be attenuated through the electrode, failing to provide a luminance necessary as a light emitting device. It is noted that only the side from which the emitted light exits has a transmittance of at least 80%.

[0331] The hole injecting electrode has at least a sufficient thickness to effect hole injection, preferably a thickness of 50 to 500 nm, especially 50 to 300 nm. Although the upper limit of the electrode thickness is not critical, a too thick electrode would have the risk of separation. Too thin an electrode would have problems with respect to film strength during fabrication, hole transporting ability, and resistance value.

[0332] In depositing the hole injecting electrode, a sputtering process is preferred. The sputtering process may be a high-frequency sputtering process using an RF power supply although a dc sputtering process is preferably used when the ease of control of physical properties of the hole injecting electrode being deposited and the flatness of the deposited film are taken into account.

[0333] A protective film may be formed if necessary. The protective film may be formed using an inorganic material such as SiOx or an organic material such as Teflon. The protective film may be either transparent or opaque and have a thickness of about 50 to 1,200 nm. Apart from the reactive sputtering process mentioned above, the protective film may also be formed by an ordinary sputtering or evaporation process.

[0334] Further, a sealing layer is provided on the device in order to prevent the organic layers and electrodes from oxidation. In order to prevent the ingress of moisture, the sealing layer is formed by attaching a sealing plate such as a glass plate to the substrate with an adhesive resin layer such as a commercially available low moisture absorption photo-curable adhesive, epoxy base adhesive, silicone base adhesive, or crosslinking ethylene-vinyl acetate copolymer adhesive sheet. Metal plates and plastic plates may also be used instead of the glass plate.

[0335] Transparent or translucent materials such as glass, quartz and resins are used as the substrate when the emitted light exits from the substrate side. The substrate may be provided with a color filter film, a fluorescent material-containing color conversion film or a dielectric reflecting film for controlling the color of light emission. In the case of the inversely stacked layer structure, the substrate may be either transparent or opaque. For the opaque substrate, ceramic and other materials may be used.

[0336] The color filter film used herein may be a color filter as used in liquid crystal displays and the like. The properties of a color filter may be adjusted in accordance with the light emission of the organic EL device so as to optimize the extraction efficiency and chromatic purity.

[0337] It is also preferred to use a color filter capable of cutting external light of short wavelength which is otherwise absorbed by the EL device materials and fluorescence conversion layer, because the light resistance and display contrast of the device are improved.

[0338] An optical thin film such as a dielectric multilayer film may be used instead of the color filter.

[0339] Referring to FIG. 1, there is illustrated one exemplary construction of the organic EL device fabricated according to the invention. The organic EL device is shown in FIG. 1 as having on a substrate 1, a hole injecting electrode (or anode) 2, a hole injecting layer 3, a hole transporting layer 4, a light emitting layer 5, an electron injecting and transporting layer 6, an electron injecting electrode (or cathode) 7, and optionally, a protective electrode 8 in the described order. The organic EL device of the invention is not limited to the illustrated construction, and various other constructions are possible depending on the desired device function. For example, the order of lamination may be inverse to the above-described order. The hole injecting 3, the hole transporting layer 4 and the electron injecting and transporting layer 6 may be omitted or either one of them may be a common layer to the light emitting layer 5.

[0340] The organic EL device of the invention is generally of the dc or pulse drive type while it can be of the ac drive type. The applied voltage is generally about 2 to 30 volts.

EXAMPLE

[0341] Examples of the present invention are given below together with Comparative Examples for further illustrating the invention.

Example 1

[0342] On a glass substrate, a transparent ITO electrode thin film was deposited to a thickness of 100 nm by RF sputtering and patterned. The glass substrate having the transparent ITO electrode was subjected to ultrasonic washing with neutral detergent, acetone, and ethanol, pulled up from boiling ethanol, and dried. The transparent electrode surface was further cleaned with UV/ozone. Thereafter, the substrate was secured by a holder in a vacuum evaporation chamber, which was evacuated to a vacuum of 1×10−5 Pa or lower.

[0343] With the vacuum kept, N,N′-diphenyl-N,N′-bis[N-(4-methylphenyl)-N-phenyl-(4-aminophenyl)]-1,1′-biphenyl-4,4′-diamine was evaporated at a deposition rate of 0.1 nm/sec. to a thickness of 50 nm, forming a hole injecting layer.

[0344] Then, N,N,N′,N′-tetrakis(m-biphenyl)-1,1′-biphenyl-4,4′-diamine (TPD) was evaporated at a deposition rate of 0.1 nm/sec to a thickness of 20 nm, forming a hole transporting layer.

[0345] With the vacuum kept, the host material and dopant of the following structural formulas were evaporated in a weight ratio of 99:1 and at an overall deposition rate of 0.1 nm/sec to a thickness of 40 nm, forming a light emitting layer. 4848

[0346] Next, with the vacuum kept, tris(8-quinolinolato)aluminum was evaporated at a deposition rate of 0.1 nm/sec to a thickness of 20 nm, forming an electron transporting layer.

[0347] With the vacuum kept, LiF was evaporated at a deposition rate of 0.01 nm/sec to a thickness of 0.3 nm, forming an electron injecting electrode. Finally, aluminum was evaporated to a thickness of 150 nm to form a protective electrode, completing an organic EL device.

[0348] A DC voltage was applied across the organic EL device. Initially, the device was found to produce light emission to a luminance of 614 cd/m2 when operated at a current density of 10 mA/cm2 and a drive voltage of 5.9 volts. The current efficiency was 6.1 cd/A, the power efficiency was 3.3 lm/W, the chromaticity coordinates (x, y) were (0.65, 0.35), and the maximum luminance was 19,600 cd/m2. When the device was continuously driven by conducting a constant current of 50 mA/cm2, it exhibited an initial luminance of at least 3,200 cd/m2 and a luminance half-life period of more than 600 hours.

Example 2

[0349] An organic EL device was prepared as in Example 1 except that the host material in the light emitting layer was changed to the following compound. 4849

[0350] A DC voltage was applied across the organic EL device. Initially, the device was found to produce light emission to a luminance of 504 cd/m2 when operated at a current density of 10 mA/cm2 and a drive voltage of 5.9 volts. The current efficiency was 5.0 cd/A, the power efficiency was 2.7 lm/W, the chromaticity coordinates (x, y) were (0.64, 0.36), and the maximum luminance was 11,500 cd/m2. When the device was continuously driven by conducting a constant current of 50 mA/cm2, it exhibited an initial luminance of at least 2,170 cd/m2 and a luminance half-life period of more than 1,500 hours.

Example 3

[0351] An organic EL device was prepared as in Example 1 except that the host material in the light emitting layer was changed to the following compound. 4850

[0352] A DC voltage was applied across the organic EL device. Initially, the device was found to produce light emission to a luminance of 449 cd/m2 when operated at a current density of 10 mA/cm2 and a drive voltage of 5.9 volts. The current efficiency was 4.5 cd/A, the power efficiency was 2.4 lm/W, the chromaticity coordinates (x, y) were (0.66, 0.34), and the maximum luminance was 17,200 cd/m2. When the device was continuously driven by conducting a constant current of 50 mA/cm2, it exhibited an initial luminance of at least 2,440 cd/m2 and a luminance half-life period of more than 1,500 hours.

Example 4

[0353] An organic EL device was prepared as in Example 1 except that the host material in the light emitting layer was changed to the following compound. 4851

[0354] A DC voltage was applied across the organic EL device. Initially, the device was found to produce light emission to a luminance of 441 cd/m2 when operated at a current density of 10 mA/cm2 and a drive voltage of 5.9 volts. The current efficiency was 4.4 cd/A, the power efficiency was 2.3 lm/W, the chromaticity coordinates (x, y) were (0.65, 0.34), and the maximum luminance was 35,200 cd/m2. When the device was continuously driven by conducting a constant current of 50 mA/cm2, it exhibited an initial luminance of at least 2,400 cd/m2 and a luminance attenuation of up to 10% after 1,000 hours and up to 15% after 4,500 hours.

[0355] The host material and dopant used in this device were assessed for excitation and fluorescence spectra, from which a Stokes shift was computed. The host material and dopant had a Stokes shift of 0.06 eV and 0.03 eV, respectively. FIG. 2 shows excitation and fluorescence spectra of the host material and dopant. It is seen from these spectral curves that both the host material and dopant have vibration structures.

[0356] The temperature characteristics of the device were examined to find the following luminance change on 10 mA/cm2 constant current driving in various temperature ranges:

[0357] −40° C. to 20° C.: ≦10%

[0358] 20° C. to 60° C.: ≦3%

[0359] −40° C. to 60° C.: ≦13%.

[0360] After 500 hours of continuous driving at 85° C., the device exhibited a luminance change of up to 10% and a drive voltage change of less than 2 V.

Example 5

[0361] An organic EL device was prepared as in Example 1 except that the host material in the light emitting layer was changed to the following compound. 4852

[0362] A DC voltage was applied across the organic EL device. Initially, the device was found to produce light emission to a luminance of 296 cd/m2 when operated at a current density of 10 mA/cm2 and a drive voltage of 6.7 volts. The current efficiency was 3.0 cd/A, the power efficiency was 1.4 lm/W, the chromaticity coordinates (x, y) were (0.60, 0.38), and the maximum luminance was 16,500 cd/m2. When the device was continuously driven by conducting a constant current of 79 mA/cm2, it exhibited an initial luminance of at least 2,400 cd/m2 and a luminance half-life period of more than 300 hours.

Example 6

[0363] An organic EL device was prepared as in Example 1 except that the host material in the light emitting layer was changed to the following compound. 4853

[0364] A DC voltage was applied across the organic EL device. Initially, the device was found to produce light emission to a luminance of 267 cd/m2 when operated at a current density of 10 mA/cm2 and a drive voltage of 6.6 volts. The current efficiency was 2.7 cd/A, the power efficiency was 1.3 lm/W, the chromaticity coordinates (x, y) were (0.55, 0.37), and the maximum luminance was 12,860 cd/m2. When the device was continuously driven by conducting a constant current of 97 mA/cm2, it exhibited an initial luminance of at least 2,400 cd/m2 and a luminance half-life period of more than 300 hours.

Example 7

[0365] An organic EL device was prepared as in Example 1 except that the host material in the light emitting layer was changed to the following compound. 4854

[0366] A DC voltage was applied across the organic EL device. Initially, the device was found to produce light emission to a luminance of 260 cd/m2 when operated at a current density of 10 mA/cm2 and a drive voltage of 6.7 volts. The current efficiency was 2.6 cd/A, the power efficiency was 1.2 lm/W, the chromaticity coordinates (x, y) were (0.64, 0.36), and the maximum luminance was 8,780 cd/m2. When the device was continuously driven by conducting a constant current of 95 mA/cm2, it exhibited an initial luminance of at least 2,400 cd/m2 and a luminance half-life period of more than 300 hours.

Example 8

[0367] An organic EL device was prepared as in Example 1 except that the host material in the light emitting layer was changed to a mixture of the following compounds in a weight ratio of 9:1 (the former compound is the same as used in Example 4). 4855

[0368] The host material (mixture) and the dopant were evaporated in a weight ratio of 99:1 and at an overall deposition rate of 0.1 nm/sec to a thickness of 40 nm, forming a light emitting layer.

[0369] A DC voltage was applied across the organic EL device. Initially, the device was found to produce light emission to a luminance of 494 cd/m2 when operated at a current density of 10 mA/cm2 and a drive voltage of 5.9 volts. The current efficiency was 4.9 cd/A, the power efficiency was 2.6 lm/W, and the chromaticity coordinates (x, y) were (0.65, 0.34). When the device was continuously driven by conducting a constant current of 50 mA/cm2, it exhibited an initial luminance of at least 2,640 cd/m2 and a luminance attenuation of up to 10% after 2,000 hours.

Example 9

[0370] An organic EL device was prepared as in Example 8 except that the weight ratio of the host compounds in the light emitting layer was changed to 7.5:2.5.

[0371] A DC voltage was applied across the organic EL device. Initially, the device was found to produce light emission to a luminance of 510 cd/m2 when operated at a current density of 10 mA/cm2 and a drive voltage of 6 volts. The current efficiency was 5.1 cd/A, the power efficiency was 2.8 lm/W, and the chromaticity coordinates (x, y) were (0.65, 0.34). When the device was continuously driven by conducting a constant current of 50 mA/cm2, it exhibited an initial luminance of at least 2,330 cd/m2 and a luminance attenuation of up to 10% after 2,000 hours.

Example 10

[0372] An organic EL device was prepared as in Example 8 except that the weight ratio of the host compounds in the light emitting layer was changed to 5:5.

[0373] A DC voltage was applied across the organic EL device. Initially, the device was found to produce light emission to a luminance of 534 cd/m2 when operated at a current density of 10 mA/cm2 and a drive voltage of 5.9 volts. The current efficiency was 5.3 cd/A, the power efficiency was 2.8 lm/W, and the chromaticity coordinates (x, y) were (0.65, 0.35). When the device was continuously driven by conducting a constant current of 50 mA/cm2, it exhibited an initial luminance of at least 2,391 cd/m2 and a luminance attenuation of up to 10% after 2,000 hours.

Example 11

[0374] An organic EL device was prepared as in Example 1 except that the host material and the dopant in the light emitting layer were changed to the following compounds. 4856

[0375] The host material and the dopant were evaporated in a weight ratio of 99:1 and at an overall deposition rate of 0.1 nm/sec to a thickness of 40 nm, forming a light emitting layer. The dopant material had to be heated at 460° C. or higher for purification by sublimation.

[0376] A DC voltage was applied across the organic EL device. Initially, the device was found to produce light emission to a luminance of 505 cd/m2 when operated at a current density of 10 mA/cm2 and a drive voltage of 5.7 volts. The current efficiency was 5.1 cd/A, the power efficiency was 2.8 lm/W, and the chromaticity coordinates (x, y) were (0.65, 0.35). When the device was continuously driven by conducting a constant current of 50 mA/cm2, it exhibited an initial luminance of at least 2,330 cd/m2 and a luminance attenuation of up to 30% after 1,700 hours.

Example 12

[0377] An organic EL device was prepared as in Example 1 except that the host material and the dopant in the light emitting layer were changed to the following compounds. 4857

[0378] The host material and the dopant were evaporated in a weight ratio of 99:1 and at an overall deposition rate of 0.1 nm/sec to a thickness of 40 nm, forming a light emitting layer.

[0379] A DC voltage was applied across the organic EL device. Initially, the device was found to produce light emission to a luminance of 438 cd/m2 when operated at a current density of 10 mA/cm2 and a drive voltage of 6 volts. The current efficiency was 4.4 cd/A, the power efficiency was 2.3 lm/W, and the chromaticity coordinates (x, y) were (0.65, 0.35). When the device was continuously driven by conducting a constant current of 50 mA/cm2, it exhibited an initial luminance of at least 2,650 cd/m2 and a luminance attenuation of up to 10% after 2,300 hours.

Example 13

[0380] An organic EL device was prepared as in Example 1 except that the host material and the dopant in the light emitting layer were changed to the following compounds. 4858

[0381] The host material and the dopant were evaporated in a weight ratio of 99:1 and at an overall deposition rate of 0.1 nm/sec to a thickness of 40 nm, forming a light emitting layer.

[0382] The host material and dopant used in this device were assessed for excitation and fluorescence spectra, from which a Stokes shift was computed. The host material had a Stokes shift of 0.24 eV. It is seen from the spectral curves that both the host material and dopant have vibration structures.

[0383] The temperature characteristics of the device were examined to find the following luminance change in various temperature ranges:

[0384] −40° C. to 20° C.: ≦−4%

[0385] 20° C. to 60° C.: ≦−3%

[0386] −40° C. to 60° C.: ≦−7%.

Example 14

[0387] An organic EL device was prepared as in Example 1 except that the host material and the dopant in the light emitting layer were changed to the following compounds. 4859

[0388] The host material and the dopant were evaporated in a weight ratio of 99:1 and at an overall deposition rate of 0.1 nm/sec to a thickness of 40 nm, forming a light emitting layer. It is noted that the dopant material could be purified by sublimation at a temperature below 360° C.

[0389] A DC voltage was applied across the organic EL device. Initially, the device was found to produce light emission to a luminance of 660 cd/m2 when operated at a current density of 10 mA/cm2 and a drive voltage of 5.6 volts. The current efficiency was 6.6 cd/A, the power efficiency was 3.7 lm/W, and the chromaticity coordinates (x, y) were (0.65, 0.35). The maximum luminance was 55,000 cd/m2. When the device was continuously driven by conducting a constant current of 50 mA/cm2, it exhibited an initial luminance of at least 3,530 cd/m2 and a luminance attenuation of up to 10% after 500 hours.

Example 15

[0390] An organic EL device was prepared as in Example 1 except that the host material and the dopant in the light emitting layer were changed to the following compounds. 4860

[0391] The host material and the dopant were evaporated in a weight ratio of 99:1 and at an overall deposition rate of 0.1 nm/sec to a thickness of 40 nm, forming a light emitting layer. It is noted that the dopant material could be purified by sublimation at a temperature below 360° C.

[0392] A DC voltage was applied across the organic EL device. Initially, the device was found to produce light emission to a luminance of 764 cd/m2 when operated at a current density of 10 mA/cm2 and a drive voltage of 6 volts. The current efficiency was 7.6 cd/A, the power efficiency was 4.0 lm/W, and the chromaticity coordinates (x, y) were (0.65, 0.35). The maximum luminance was 24,500 cd/m2. When the device was continuously driven by conducting a constant current of 50 mA/cm2, it exhibited an initial luminance of at least 4,200 cd/m2 and a luminance attenuation of up to 10% after 500 hours.

Comparative Example 1

[0393] An organic EL device was prepared as in Example 1 except that the host material in the light emitting layer was changed to the following compound. 4861

[0394] A DC voltage was applied across the organic EL device. Initially, the device was found to produce light emission to a luminance of 160 cd/m2 when operated at a current density of 10 mA/cm2 and a drive voltage of 6.9 volts. The current efficiency was 1.6 cd/A, the power efficiency was 0.7 lm/W, the chromaticity coordinates (x, y) were (0.61, 0.37), and the maximum luminance was 9,570 cd/m2. When the device was continuously driven by conducting a constant current of 145 mA/cm2, it exhibited an initial luminance of at least 2,400 cd/m2 and a luminance half-life period of less than 300 hours.

Comparative Example 2

[0395] An organic EL device was prepared as in Example 4 except that the host material and the dopant in the light emitting layer were changed to the following compounds. 4862

[0396] The host material and the dopant were evaporated in a weight ratio of 97:3 and at an overall deposition rate of 0.1 nm/sec to a thickness of 40 nm, forming a light emitting layer.

[0397] The host material and dopant used in this device were assessed for excitation and fluorescence spectra, from which a Stokes shift was computed. The host material and dopant had a Stokes shift of 0.2 eV and 0.31 eV, respectively. FIG. 3 shows excitation and fluorescence spectra of the host material and dopant. It is seen from the spectral curves that the dopant does not have a vibration structure in the excitation spectrum, and the host material does not have a vibration structure in the fluorescence spectrum.

[0398] The temperature characteristics of the device were examined to find the following luminance change on 10 mA/cm2 constant current driving in various temperature ranges:

[0399] −40° C. to 20° C.: ≧−12%

[0400] 20° C. to 60° C.: ≧−9%

[0401] −40° C. to 60° C.: ≧−21%.

Comparative Example 3

[0402] An organic EL device was prepared as in Example 4 except that the host material and the dopant in the light emitting layer were changed to the following compounds. 4863

[0403] The host material and the dopant were evaporated in a weight ratio of 99:1 and at an overall deposition rate of 0.1 nm/sec to a thickness of 40 nm, forming a light emitting layer.

[0404] The host material and dopant used in this device were assessed for excitation and fluorescence spectra, from which a Stokes shift was computed. The host material and dopant had a Stokes shift of 0.2 eV and 0.31 eV, respectively. It is seen from the spectral curves that neither the host material nor the dopant has a vibration structure.

[0405] The temperature characteristics of the device were examined to find the following luminance change in various temperature ranges:

[0406] −40° C. to 20° C.: ≧31%

[0407] 20° C. to 60° C.: ≧18%

[0408] −40° C. to 60° C.: ≧49%.

[0409] There has been described an organic EL device which emits light to a satisfactory luminance, especially in a long wavelength region, is operated at a constant voltage, and has a sufficient durability to maintain satisfactory light emission performance over a long period of time, experience a minimal voltage rise during continuous operation, and undergo a minimal degradation on driving at elevated temperature. Especially when a red light emitting device is fabricated, it has a high chromatic purity because the host produces little light emission. Over a wide temperature region, the device produces a consistent luminance with minimal changes of efficiency. The device can produce linear luminance characteristics in proportion to current flow over a wide current region covering from the low current region for use in TFT driving to the high current region for use in simple matrix driving and thus provide a satisfactory tone display.

[0410] Although some preferred embodiments have been described, many modifications and variations may be made thereto in light of the above teachings. It is therefore to be understood that the invention may be practiced otherwise than as specifically described without departing from the scope of the appended claims.

[0411] This application is based on Japanese patent applications JP 2000-121724, filed Apr. 21, 2000, and JP 2001-121664, filed Apr. 19, 2001, the entire contents of each of which are hereby incorporated by reference, the same as if set forth at length.

Claims

1. An organic EL device comprising one or more organic layers between a pair of electrodes participating in at least a light emitting function, at least one of the organic layers containing at least one of organic compounds having basic skeletons of the following formulas (I) to (IV) and at least one organic compound having a skeleton of the following formula (V) at the same time: 4864 wherein Q1 to Q8 are independently hydrogen or substituted or unsubstituted alkyl, aryl, amino, heterocyclic or alkenyl radicals, 4865 wherein R1, R2, R3 and R4 are independently aryl, fluorene, carbazolyl, alkyl, alkoxy, aryloxy, amino or halogen radicals, at least one of R1, R2, R3 and R4 is aryl, r1, r2, r3 and r4 each are 0 or an integer of 1 to 5, with the proviso that r1, r2, r3 and r4 are not 0 at the same time, R5 and R6 are independently alkyl, alkoxy, amino, aryl or halogen radicals and may be the same or different, r5 and r6 each are 0 or an integer of 1 to 4, 4866 wherein A101 is a monophenylanthryl or diphenylanthryl radical and may be the same or different, L is hydrogen, a single bond or an n-valent linkage, and n is an integer of 1 to 4, Qn-L101  (IV)  wherein Q is a pyrazinyl radical having fused thereto a six-membered aromatic ring containing 0 to 2 nitrogen atoms and may be the same or different, n is 2 or 3, and L101 is a single bond or n-valent radical, 4867 wherein X1 to X10, L1 and L2 are independently hydrogen, halogen atoms, straight, branched or cyclic alkyl radicals which may have substituents, straight, branched or cyclic alkoxy radicals which may have substituents, straight, branched or cyclic alkylthio radicals which may have substituents, straight, branched or cyclic alkenyl radicals which may have substituents, straight, branched or cyclic alkenyloxy radicals which may have substituents, straight, branched or cyclic alkenylthio radicals which may have substituents, substituted or unsubstituted aralkyl radicals, substituted or unsubstituted aralkyloxy radicals, substituted or unsubstituted aralkylthio radicals, substituted or unsubstituted aryl radicals, substituted or unsubstituted aryloxy radicals, substituted or unsubstituted arylthio radicals, substituted or unsubstituted amino radicals, cyano, hydroxyl, —COOR1 radicals (wherein R1 is hydrogen, a substituted or unsubstituted straight, branched or cyclic alkyl radical, a substituted or unsubstituted straight, branched or cyclic alkenyl radical, a substituted or unsubstituted aralkyl radical or a substituted or unsubstituted aryl radical), —COR2 radicals (wherein R2 is hydrogen, a substituted or unsubstituted straight, branched or cyclic alkyl radical, a substituted or unsubstituted straight, branched or cyclic alkenyl radical, a substituted or unsubstituted aralkyl radical, a substituted or unsubstituted aryl radical or an amino radical), or —OCOR3 radicals (wherein R3 is a substituted or unsubstituted straight, branched or cyclic alkyl radical, a substituted or unsubstituted straight, branched or cyclic alkenyl radical, a substituted or unsubstituted aralkyl radical, or a substituted or unsubstituted aryl radical), or at least two adjoining radicals selected from X1 to X10, L1 and L2 may bond or fuse together to form a substituted or unsubstituted carbocyclic aliphatic ring, aromatic ring or fused aromatic ring with the carbon atoms to which they are attached, or L1 and L2 each may be a single bond. n is 1 or 2.

2. The organic EL device of claim 1 wherein the at least one of the organic layers contains a host material and a dopant, said host material comprises at least one compound selected from the organic compounds having basic skeletons of the formulas (I) to (IV) and said dopant comprises at least one compound selected from the organic compounds having a skeleton of the formula (V).

3. The organic EL device of claim 1 or 2 wherein in formula (V), at least two adjoining radicals selected from X1 to X10, L1 and L2 bond or fuse together to form a substituted or unsubstituted carbocyclic aliphatic ring, aromatic ring or fused aromatic ring with the carbon atoms to which they are attached.

4. The organic EL device of any one of claims 1 to 3 wherein the compound of formula (V) is a compound of the following formula (VI):

5. The organic EL device of claim 4 wherein the compound of formula (VI) is a compound of the following formula (VI′):

6. The organic EL device of claim 4 or 5 wherein X1 to X20 in formula (VI) and X1 to X44 in formula (VI′) are independently substituted or unsubstituted aryl, alkyl, alkenyl, alkoxy or aryloxy radicals.

7. The organic EL device of any one of claims 4 to 6 wherein at least one of X1 to X20 in formula (VI) and X1 to X44 in formula (VI′) is an ortho-substituted phenyl radical.

8. The organic EL device of any one of claims 4 to 7 wherein in formula (VI) or (VI′), either one or both of X1 and X4 and/or either one or both of X11 and X14 are ortho-substituted phenyl radicals.

9. The organic EL device of any one of claims 1 to 8 wherein said at least one of the organic layers contains at least one organic compound having a basic skeleton of the formula (I).

10. The organic EL device of any one of claims 1 to 9 wherein said at least one of the organic layers contains at least one organic compound having a basic skeleton of the formula (I) and at least one organic compound having a basic skeleton of the formula (II) at the same time.

11. The organic EL device of any one of claims 4 to 10 wherein at least one of the organic compounds has a vibration structure in both an excitation spectrum and a fluorescence spectrum.

12. The organic EL device of any one of claims 4 to 11 wherein at least one of the organic compounds has a Stokes shift of up to 0.1 eV.

13. The organic EL device of any one of claims 4 to 12 wherein the host material in a light emitting layer has a greater electron affinity than an electron transporting layer and/or a hole transporting layer.

14. The organic EL device of any one of claims 1 to 13 wherein the organic compound having a basic skeleton of the formula (I) is one wherein at least two of Q1 to Q8 are substituted or unsubstituted aryl radicals.

15. The organic EL device of claim 14 wherein the organic compound having a basic skeleton of the formula (I) is one wherein at least six of Q1 to Q8 are substituted or unsubstituted aryl radicals.

16. The organic EL device of claim 14 or 15 wherein the organic compound having a basic skeleton of the formula (I) is one wherein at least two of Q1, Q2, Q3 and Q4 are substituted or unsubstituted aryl radicals.

17. The organic EL device of any one of claims 14 to 16 wherein the organic compound having a basic skeleton of the formula (I) is one wherein at least four of Q1, Q2, Q3 and Q4 are substituted or unsubstituted aryl radicals.

18. The organic EL device of any one of claims 14 to 17 wherein at least two of the aryl radicals represented by Q1, Q2, Q3 and Q4 have aryl radicals substituted thereon.

19. The organic EL device of any one of claims 2 to 18 wherein the at least one of the organic layers contains 80 to 99.9% by weight of the host material.

20. An organic EL device wherein at least one of organic layers contains at least one organic compound having a basic skeleton of the formula (I) as set forth in claim 16 and at least one organic compound having a basic skeleton of the formula (IV′).

21. The organic EL device of any one of claims 1 to 20, further comprising at least one hole injecting and transporting layer.

22. The organic EL device of any one of claims 1 to 21, further comprising at least one electron injecting and transporting layer.

23. An organic EL device comprising one or more organic layers between a pair of electrodes participating in at least a light emitting function, wherein the one or more organic layers contain organic compounds, at least one of which has a vibration structure in both an excitation spectrum and a fluorescence spectrum.

24. An organic EL device comprising one or more organic layers between a pair of electrodes participating in at least a light emitting function, wherein the one or more organic layers contain organic compounds, at least one of which has a Stokes shift of up to 0.1 eV.

25. The organic EL device of claim 24 wherein a host material in a light emitting layer has a greater electron affinity than an electron transporting layer and/or a hole transporting layer.