ORGANIC ELECTROLUMINESCENT MATERIALS AND DEVICES

Description

In some embodiments, when the compound has formula Ir(L_Ai-m-X)₃, i is an integer from 1 to 4524; m is an integer from 1 to 108; and the compound is selected from the group consisting of Ir(L_A1-1-1)₃to Ir(L_A4524-108-4)₃;

when the compound has formula Ir(L_Ai-m-X)(L_Bk)₂, i is an integer from 1 to 4542; m is an integer from 1 to 108; k is an integer from 1 to 324; and the compound is selected from the group consisting of Ir(L_A1-1-1)(L_B1)₂to Ir(L_A4542-108-4)(L_B324)₂;

when the compound has formula Ir(L_Ai-m-X)₂(L_Bk), i is an integer from 1 to 4542; m is an integer from 1 to 108; k is an integer from 1 to 324; and the compound is selected from the group consisting of Ir(L_A1-1-1)₂(L_B1) to Ir(L_A4542-108-4)₂(L_B324);

when the compound has formula Ir(L_Ai-m-X)₂(L_Cj-I), i is an integer from 1 to 4542; m is an integer from 1 to 108;j is an integer from 1 to 1416; and the compound is selected from the group consisting of Ir(L_A1-1-1)₂(L_C1-I) to Ir(L_A4542-108-4)₂(L_C1416-I); and when the compound has formula Ir(L_Ai-m-X)₂(L_Cj-II), i is an integer from 1 to 4542; m is an integer from 1 to 108;j is an integer from 1 to 1416; and the compound is selected from the group consisting of Ir(L_A1-1-1)₂(L_C1-II) to Ir(L_A4542-108-4)₂(L_C1416-II);

wherein each L_Bkis defined by the structures in the following LIST 8:

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wherein each L_Cj-Ihas a structure based on formula

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and

each L_Cj-IIhas a structure based on formula

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wherein for each L_Cjin L_Cj-Iand L_Cj-II, R²⁰¹and R²⁰²are each independently defined in the following LIST 9:

L_Cj
R²⁰¹
R²⁰²
L_Cj
R²⁰¹
R²⁰²
L_Cj
R²⁰¹
R²⁰²
L_Cj
R²⁰¹
R²⁰²

L_C1
R^D1
R^D1
L_C193
R^D1
R^D3
L_C385
R^D17
R^D40
L_C577
R^D143
R^D120

L_C2
R^D2
R^D2
L_C194
R^D1
R^D4
L_C386
R^D17
R^D41
L_C578
R^D143
R^D133

L_C3
R^D3
R^D3
L_C195
R^D1
R^D5
L_C387
R^D17
R^D42
L_C579
R^D143
R^D134

L_C4
R^D4
R^D4
L_C196
R^D1
R^D9
L_C388
R^D17
R^D43
L_C580
R^D143
R^D135

L_C5
R^D5
R^D5
L_C197
R^D1
R^D10
L_C389
R^D17
R^D48
L_C581
R^D143
R^D136

L_C6
R^D6
R^D6
L_C198
R^D1
R^D17
L_C390
R^D17
R^D49
L_C582
R^D143
R^D143

L_C7
R^D7
R^D7
L_C199
R^D1
R^D18
L_C391
R^D17
R^D50
L_C583
R^D143
R^D144

L_C8
R^D8
R^D8
L_C200
R^D1
R^D20
L_C392
R^D17
R^D54
L_C584
R^D143
R^D145

L_C9
R^D9
R^D9
L_C201
R^D1
R^D22
L_C393
R^D17
R^D55
L_C585
R^D143
R^D146

L_C10
R^D10
R^D10
L_C202
R^D1
R^D37
L_C394
R^D17
R^D58
L_C586
R^D143
R^D147

L_C11
R^D11
R^D11
L_C203
R^D1
R^D40
L_C395
R^D17
R^D59
L_C587
R^D143
R^D149

L_C12
R^D12
R^D12
L_C204
R^D1
R^D41
L_C396
R^D17
R^D78
L_C588
R^D143
R^D151

L_C13
R^D13
R^D13
L_C205
R^D1
R^D42
L_C397
R^D17
R^D79
L_C589
R^D143
R^D154

L_C14
R^D14
R^D14
L_C206
R^D1
R^D43
L_C398
R^D17
R^D81
L_C590
R^D143
R^D155

L_C15
R^D15
R^D15
L_C207
R^D1
R^D48
L_C399
R^D17
R^D87
L_C591
R^D143
R^D161

L_C16
R^D16
R^D16
L_C208
R^D1
R^D49
L_C400
R^D17
R^D88
L_C592
R^D144
R^D3

L_C17
R^D17
R^D17
L_C209
R^D1
R^D50
L_C401
R^D17
R^D89
L_C593
R^D144
R^D5

L_C18
R^D18
R^D18
L_C210
R^D1
R^D54
L_C402
R^D17
R^D93
L_C594
R^D144
R^D17

L_C19
R^D19
R^D19
L_C211
R^D1
R^D55
L_C403
R^D17
R^D116
L_C595
R^D144
R^D18

L_C20
R^D20
R^D20
L_C212
R^D1
R^D58
L_C404
R^D17
R^D117
L_C596
R^D144
R^D20

L_C21
R^D21
R^D21
L_C213
R^D1
R^D59
L_C405
R^D17
R^D118
L_C597
R^D144
R^D22

L_C22
R^D22
R^D22
L_C214
R^D1
R^D78
L_C406
R^D17
R^D119
L_C598
R^D144
R^D37

L_C23
R^D23
R^D23
L_C215
R^D1
R^D79
L_C407
R^D17
R^D120
L_C599
R^D144
R^D40

L_C24
R^D24
R^D24
L_C216
R^D1
R^D81
L_C408
R^D17
R^D133
L_C600
R^D144
R^D41

L_C25
R^D25
R^D25
L_C217
R^D1
R^D87
L_C409
R^D17
R^D134
L_C601
R^D144
R^D42

L_C26
R^D26
R^D26
L_C218
R^D1
R^D88
L_C410
R^D17
R^D135
L_C602
R^D144
R^D43

L_C27
R^D27
R^D27
L_C219
R^D1
R^D89
L_C411
R^D17
R^D136
L_C603
R^D144
R^D48

L_C28
R^D28
R^D28
L_C220
R^D1
R^D93
L_C412
R^D17
R^D143
L_C604
R^D144
R^D49

L_C29
R^D29
R^D29
L_C221
R^D1
R^D116
L_C413
R^D17
R^D144
L_C605
R^D144
R^D54

L_C30
R^D30
R^D30
L_C222
R^D1
R^D117
L_C414
R^D17
R^D145
L_C606
R^D144
R^D58

L_C31
R^D31
R^D31
L_C223
R^D1
R^D118
L_C415
R^D17
R^D146
L_C607
R^D144
R^D59

L_C32
R^D32
R^D32
L_C224
R^D1
R^D119
L_C416
R^D17
R^D147
L_C608
R^D144
R^D78

L_C33
R^D33
R^D33
L_C225
R^D1
R^D120
L_C417
R^D17
R^D149
L_C609
R^D144
R^D79

L_C34
R^D34
R^D34
L_C226
R^D1
R^D133
L_C418
R^D17
R^D151
L_C610
R^D144
R^D81

L_C35
R^D35
R^D35
L_C227
R^D1
R^D134
L_C419
R^D17
R^D154
L_C611
R^D144
R^D87

L_C36
R^D36
R^D36
L_C228
R^D1
R^D135
L_C420
R^D17
R^D155
L_C612
R^D144
R^D88

L_C37
R^D37
R^D37
L_C229
R^D1
R^D136
L_C421
R^D17
R^D161
L_C613
R^D144
R^D89

L_C38
R^D38
R^D38
L_C230
R^D1
R^D143
L_C422
R^D17
R^D175
L_C614
R^D144
R^D93

L_C39
R^D39
R^D39
L_C231
R^D1
R^D144
L_C423
R^D50
R^D3
L_C615
R^D144
R^D116

L_C40
R^D40
R^D40
L_C232
R^D1
R^D145
L_C424
R^D50
R^D5
L_C616
R^D144
R^D117

L_C41
R^D41
R^D41
L_C233
R^D1
R^D146
L_C425
R^D50
R^D18
L_C617
R^D144
R^D118

L_C42
R^D42
R^D42
L_C234
R^D1
R^D147
L_C426
R^D50
R^D20
L_C618
R^D144
R^D119

L_C43
R^D43
R^D43
L_C235
R^D1
R^D149
L_C427
R^D50
R^D22
L_C619
R^D144
R^D120

L_C44
R^D44
R^D44
L_C236
R^D1
R^D151
L_C428
R^D50
R^D37
L_C620
R^D144
R^D133

L_C45
R^D45
R^D45
L_C237
R^D1
R^D154
L_C429
R^D50
R^D40
L_C621
R^D144
R^D134

L_C46
R^D46
R^D46
L_C238
R^D1
R^D155
L_C430
R^D50
R^D41
L_C622
R^D144
R^D135

L_C47
R^D47
R^D47
L_C239
R^D1
R^D161
L_C431
R^D50
R^D42
L_C623
R^D144
R^D136

L_C48
R^D48
R^D48
L_C240
R^D1
R^D175
L_C432
R^D50
R^D43
L_C624
R^D144
R^D145

L_C49
R^D49
R^D49
L_C241
R^D4
R^D3
L_C433
R^D50
R^D48
L_C625
R^D144
R^D146

L_C50
R^D50
R^D50
L_C242
R^D4
R^D5
L_C434
R^D50
R^D49
L_C626
R^D144
R^D147

L_C51
R^D51
R^D51
L_C243
R^D4
R^D9
L_C435
R^D50
R^D54
L_C627
R^D144
R^D149

L_C52
R^D52
R^D52
L_C244
R^D4
R^D10
L_C436
R^D50
R^D55
L_C628
R^D144
R^D151

L_C53
R^D53
R^D53
L_C245
R^D4
R^D17
L_C437
R^D50
R^D58
L_C629
R^D144
R^D154

L_C54
R^D54
R^D54
L_C246
R^D4
R^D18
L_C438
R^D50
R^D59
L_C630
R^D144
R^D155

L_C55
R^D55
R^D55
L_C247
R^D4
R^D20
L_C439
R^D50
R^D78
L_C631
R^D144
R^D161

L_C56
R^D56
R^D56
L_C248
R^D4
R^D22
L_C440
R^D50
R^D79
L_C632
R^D144
R^D175

L_C57
R^D57
R^D57
L_C249
R^D4
R^D37
L_C441
R^D50
R^D81
L_C633
R^D145
R^D3

L_C58
R^D58
R^D58
L_C250
R^D4
R^D40
L_C442
R^D50
R^D87
L_C634
R^D145
R^D5

L_C59
R^D59
R^D59
L_C251
R^D4
R^D41
L_C443
R^D50
R^D88
L_C635
R^D145
R^D17

L_C60
R^D60
R^D60
L_C252
R^D4
R^D42
L_C444
R^D50
R^D89
L_C636
R^D145
R^D18

L_C61
R^D61
R^D61
L_C253
R^D4
R^D43
L_C445
R^D50
R^D93
L_C637
R^D145
R^D20

L_C62
R^D62
R^D62
L_C254
R^D4
R^D48
L_C446
R^D50
R^D116
L_C638
R^D145
R^D22

L_C63
R^D63
R^D63
L_C255
R^D4
R^D49
L_C447
R^D50
R^D117
L_C639
R^D145
R^D37

L_C64
R^D64
R^D64
L_C256
R^D4
R^D50
L_C448
R^D50
R^D118
L_C640
R^D145
R^D40

L_C65
R^D65
R^D65
L_C257
R^D4
R^D54
L_C449
R^D50
R^D119
L_C641
R^D145
R^D41

L_C66
R^D66
R^D66
L_C258
R^D4
R^D55
L_C450
R^D50
R^D120
L_C642
R^D145
R^D42

L_C67
R^D67
R^D67
L_C259
R^D4
R^D58
L_C451
R^D50
R^D133
L_C643
R^D145
R^D43

L_C68
R^D68
R^D68
L_C260
R^D4
R^D59
L_C452
R^D50
R^D134
L_C644
R^D145
R^D48

L_C69
R^D69
R^D69
L_C261
R^D4
R^D78
L_C453
R^D50
R^D135
L_C645
R^D145
R^D49

L_C70
R^D70
R^D70
L_C262
R^D4
R^D79
L_C454
R^D50
R^D136
L_C646
R^D145
R^D54

L_C71
R^D71
R^D71
L_C263
R^D4
R^D81
L_C455
R^D50
R^D143
L_C647
R^D145
R^D58

L_C72
R^D72
R^D72
L_C264
R^D4
R^D87
L_C456
R^D50
R^D144
L_C648
R^D145
R^D59

L_C73
R^D73
R^D73
L_C265
R^D4
R^D88
L_C457
R^D50
R^D145
L_C649
R^D145
R^D78

L_C74
R^D74
R^D74
L_C266
R^D4
R^D89
L_C458
R^D50
R^D146
L_C650
R^D145
R^D79

L_C75
R^D75
R^D75
L_C267
R^D4
R^D93
L_C459
R^D50
R^D147
L_C651
R^D145
R^D81

L_C76
R^D76
R^D76
L_C268
R^D4
R^D116
L_C460
R^D50
R^D149
L_C652
R^D145
R^D87

L_C77
R^D77
R^D77
L_C269
R^D4
R^D117
L_C461
R^D50
R^D151
L_C653
R^D145
R^D88

L_C78
R^D78
R^D78
L_C270
R^D4
R^D118
L_C462
R^D50
R^D154
L_C654
R^D145
R^D89

L_C79
R^D79
R^D79
L_C271
R^D4
R^D119
L_C463
R^D50
R^D155
L_C655
R^D145
R^D93

L_C80
R^D80
R^D80
L_C272
R^D4
R^D120
L_C464
R^D50
R^D161
L_C656
R^D145
R^D116

L_C81
R^D81
R^D81
L_C273
R^D4
R^D133
L_C465
R^D50
R^D175
L_C657
R^D145
R^D117

L_C82
R^D82
R^D82
L_C274
R^D4
R^D134
L_C466
R^D55
R^D3
L_C658
R^D145
R^D118

L_C83
R^D83
R^D83
L_C275
R^D4
R^D135
L_C467
R^D55
R^D5
L_C659
R^D145
R^D119

L_C84
R^D84
R^D84
L_C276
R^D4
R^D136
L_C468
R^D55
R^D18
L_C660
R^D145
R^D120

L_C85
R^D85
R^D85
L_C277
R^D4
R^D143
L_C469
R^D55
R^D20
L_C661
R^D145
R^D133

L_C86
R^D86
R^D86
L_C278
R^D4
R^D144
L_C470
R^D55
R^D22
L_C662
R^D145
R^D134

L_C87
R^D87
R^D87
L_C279
R^D4
R^D145
L_C471
R^D55
R^D37
L_C663
R^D145
R^D135

L_C88
R^D88
R^D88
L_C280
R^D4
R^D146
L_C472
R^D55
R^D40
L_C664
R^D145
R^D136

L_C89
R^D89
R^D89
L_C281
R^D4
R^D147
L_C473
R^D55
R^D41
L_C665
R^D145
R^D146

L_C90
R^D90
R^D90
L_C282
R^D4
R^D149
L_C474
R^D55
R^D42
L_C666
R^D145
R^D147

L_C91
R^D91
R^D91
L_C283
R^D4
R^D151
L_C475
R^D55
R^D43
L_C667
R^D145
R^D149

L_C92
R^D92
R^D92
L_C284
R^D4
R^D154
L_C476
R^D55
R^D48
L_C668
R^D145
R^D151

L_C93
R^D93
R^D93
L_C285
R^D4
R^D155
L_C477
R^D55
R^D49
L_C669
R^D145
R^D154

L_C94
R^D94
R^D94
L_C286
R^D4
R^D161
L_C478
R^D55
R^D54
L_C670
R^D145
R^D155

L_C95
R^D95
R^D95
L_C287
R^D4
R^D175
L_C479
R^D55
R^D58
L_C671
R^D145
R^D161

L_C96
R^D96
R^D96
L_C288
R^D9
R^D3
L_C480
R^D55
R^D59
L_C672
R^D145
R^D175

L_C97
R^D97
R^D97
L_C289
R^D9
R^D5
L_C481
R^D55
R^D78
L_C673
R^D146
R^D3

L_C98
R^D98
R^D98
L_C290
R^D9
R^D10
L_C482
R^D55
R^D79
L_C674
R^D146
R^D5

L_C99
R^D99
R^D99
L_C291
R^D9
R^D17
L_C483
R^D55
R^D81
L_C675
R^D146
R^D17

L_C100
R^D100
R^D100
L_C292
R^D9
R^D18
L_C484
R^D55
R^D87
L_C676
R^D146
R^D18

L_C101
R^D101
R^D101
L_C293
R^D9
R^D20
L_C485
R^D55
R^D88
L_C677
R^D146
R^D20

L_C102
R^D102
R^D102
L_C294
R^D9
R^D22
L_C486
R^D55
R^D89
L_C678
R^D146
R^D22

L_C103
R^D103
R^D103
L_C295
R^D9
R^D37
L_C487
R^D55
R^D93
L_C679
R^D146
R^D37

L_C104
R^D104
R^D104
L_C296
R^D9
R^D40
L_C488
R^D55
R^D116
L_C680
R^D146
R^D40

L_C105
R^D105
R^D105
L_C297
R^D9
R^D41
L_C489
R^D55
R^D117
L_C681
R^D146
R^D41

L_C106
R^D106
R^D106
L_C298
R^D9
R^D42
L_C490
R^D55
R^D118
L_C682
R^D146
R^D42

L_C107
R^D107
R^D107
L_C299
R^D9
R^D43
L_C491
R^D55
R^D119
L_C683
R^D146
R^D43

L_C108
R^D108
R^D108
L_C300
R^D9
R^D48
L_C492
R^D55
R^D120
L_C684
R^D146
R^D48

L_C109
R^D109
R^D109
L_C301
R^D9
R^D49
L_C493
R^D55
R^D133
L_C685
R^D146
R^D49

L_C110
R^D110
R^D110
L_C302
R^D9
R^D50
L_C494
R^D55
R^D134
L_C686
R^D146
R^D54

L_C111
R^D111
R^D111
L_C303
R^D9
R^D54
L_C495
R^D55
R^D135
L_C687
R^D146
R^D58

L_C112
R^D112
R^D112
L_C304
R^D9
R^D55
L_C496
R^D55
R^D136
L_C688
R^D146
R^D59

L_C113
R^D113
R^D113
L_C305
R^D9
R^D58
L_C497
R^D55
R^D143
L_C689
R^D146
R^D78

L_C114
R^D114
R^D114
L_C306
R^D9
R^D59
L_C498
R^D55
R^D144
L_C690
R^D146
R^D79

L_C115
R^D115
R^D115
L_C307
R^D9
R^D78
L_C499
R^D55
R^D145
L_C691
R^D146
R^D81

L_C116
R^D116
R^D116
L_C308
R^D9
R^D79
L_C500
R^D55
R^D146
L_C692
R^D146
R^D87

L_C117
R^D117
R^D117
L_C309
R^D9
R^D81
L_C501
R^D55
R^D147
L_C693
R^D146
R^D88

L_C118
R^D118
R^D118
L_C310
R^D9
R^D87
L_C502
R^D55
R^D149
L_C694
R^D146
R^D89

L_C119
R^D119
R^D119
L_C311
R^D9
R^D88
L_C503
R^D55
R^D151
L_C695
R^D146
R^D93

L_C120
R^D120
R^D120
L_C312
R^D9
R^D89
L_C504
R^D55
R^D154
L_C696
R^D146
R^D117

L_C121
R^D121
R^D121
L_C313
R^D9
R^D93
L_C505
R^D55
R^D155
L_C697
R^D146
R^D118

L_C122
R^D122
R^D122
L_C314
R^D9
R^D116
L_C506
R^D55
R^D161
L_C698
R^D146
R^D119

L_C123
R^D123
R^D123
L_C315
R^D9
R^D117
L_C507
R^D55
R^D175
L_C699
R^D146
R^D120

L_C124
R^D124
R^D124
L_C316
R^D9
R^D118
L_C508
R^D116
R^D3
L_C700
R^D146
R^D133

L_C125
R^D125
R^D125
L_C317
R^D9
R^D119
L_C509
R^D116
R^D5
L_C701
R^D146
R^D134

L_C126
R^D126
R^D126
L_C318
R^D9
R^D120
L_C510
R^D116
R^D17
L_C702
R^D146
R^D135

L_C127
R^D127
R^D127
L_C319
R^D9
R^D133
L_C511
R^D116
R^D18
L_C703
R^D146
R^D136

L_C128
R^D128
R^D128
L_C320
R^D9
R^D134
L_C512
R^D116
R^D20
L_C704
R^D146
R^D146

L_C129
R^D129
R^D129
L_C321
R^D9
R^D135
L_C513
R^D116
R^D22
L_C705
R^D146
R^D147

L_C130
R^D130
R^D130
L_C322
R^D9
R^D136
L_C514
R^D116
R^D37
L_C706
R^D146
R^D149

L_C131
R^D131
R^D131
L_C323
R^D9
R^D143
L_C515
R^D116
R^D40
L_C707
R^D146
R^D151

L_C132
R^D132
R^D132
L_C324
R^D9
R^D144
L_C516
R^D116
R^D41
L_C708
R^D146
R^D154

L_C133
R^D133
R^D133
L_C325
R^D9
R^D145
L_C517
R^D116
R^D42
L_C709
R^D146
R^D155

L_C134
R^D134
R^D134
L_C326
R^D9
R^D146
L_C518
R^D116
R^D43
L_C710
R^D146
R^D161

L_C135
R^D135
R^D135
L_C327
R^D9
R^D147
L_C519
R^D116
R^D48
L_C711
R^D146
R^D175

L_C136
R^D136
R^D136
L_C328
R^D9
R^D149
L_C520
R^D116
R^D49
L_C712
R^D133
R^D3

L_C137
R^D137
R^D137
L_C329
R^D9
R^D151
L_C521
R^D116
R^D54
L_C713
R^D133
R^D5

L_C138
R^D138
R^D138
L_C330
R^D9
R^D154
L_C522
R^D116
R^D58
L_C714
R^D133
R^D3

L_C139
R^D139
R^D139
L_C331
R^D9
R^D155
L_C523
R^D116
R^D59
L_C715
R^D133
R^D18

L_C140
R^D140
R^D140
L_C332
R^D9
R^D161
L_C524
R^D116
R^D78
L_C716
R^D133
R^D20

L_C141
R^D141
R^D141
L_C333
R^D9
R^D175
L_C525
R^D116
R^D79
L_C717
R^D133
R^D22

L_C142
R^D142
R^D142
L_C334
R^D10
R^D3
L_C526
R^D116
R^D81
L_C718
R^D133
R^D37

L_C143
R^D143
R^D143
L_C335
R^D10
R^D5
L_C527
R^D116
R^D87
L_C719
R^D133
R^D40

L_C144
R^D144
R^D144
L_C336
R^D10
R^D17
L_C528
R^D116
R^D88
L_C720
R^D133
R^D41

L_C145
R^D145
R^D145
L_C337
R^D10
R^D18
L_C529
R^D116
R^D89
L_C721
R^D133
R^D42

L_C146
R^D146
R^D146
L_C338
R^D10
R^D20
L_C530
R^D116
R^D93
L_C722
R^D133
R^D43

L_C147
R^D147
R^D147
L_C339
R^D10
R^D22
L_C531
R^D116
R^D117
L_C723
R^D133
R^D48

L_C148
R^D148
R^D148
L_C340
R^D10
R^D37
L_C532
R^D116
R^D118
L_C724
R^D133
R^D49

L_C149
R^D149
R^D149
L_C341
R^D10
R^D40
L_C533
R^D116
R^D119
L_C725
R^D133
R^D54

L_C150
R^D150
R^D150
L_C342
R^D10
R^D41
L_C534
R^D116
R^D120
L_C726
R^D133
R^D58

L_C151
R^D151
R^D151
L_C343
R^D10
R^D42
L_C535
R^D116
R^D133
L_C727
R^D133
R^D59

L_C152
R^D152
R^D152
L_C344
R^D10
R^D43
L_C536
R^D116
R^D134
L_C728
R^D133
R^D78

L_C153
R^D153
R^D153
L_C345
R^D10
R^D48
L_C537
R^D116
R^D135
L_C729
R^D133
R^D79

L_C154
R^D154
R^D154
L_C346
R^D10
R^D49
L_C538
R^D116
R^D136
L_C730
R^D133
R^D81

L_C155
R^D155
R^D155
L_C347
R^D10
R^D50
L_C539
R^D116
R^D143
L_C731
R^D133
R^D87

L_C156
R^D156
R^D156
L_C348
R^D10
R^D54
L_C540
R^D116
R^D144
L_C732
R^D133
R^D88

L_C157
R^D157
R^D157
L_C349
R^D10
R^D55
L_C541
R^D116
R^D145
L_C733
R^D133
R^D89

L_C158
R^D158
R^D158
L_C350
R^D10
R^D58
L_C542
R^D116
R^D146
L_C734
R^D133
R^D93

L_C159
R^D159
R^D159
L_C351
R^D10
R^D59
L_C543
R^D116
R^D147
L_C735
R^D133
R^D117

L_C160
R^D160
R^D160
L_C352
R^D10
R^D78
L_C544
R^D116
R^D149
L_C736
R^D133
R^D118

L_C161
R^D161
R^D161
L_C353
R^D10
R^D79
L_C545
R^D116
R^D151
L_C737
R^D133
R^D119

L_C162
R^D162
R^D162
L_C354
R^D10
R^D81
L_C546
R^D116
R^D154
L_C738
R^D133
R^D120

L_C163
R^D163
R^D163
L_C355
R^D10
R^D87
L_C547
R^D116
R^D155
L_C739
R^D133
R^D133

L_C164
R^D164
R^D164
L_C356
R^D10
R^D88
L_C548
R^D116
R^D161
L_C740
R^D133
R^D134

L_C165
R^D165
R^D165
L_C357
R^D10
R^D89
L_C549
R^D116
R^D175
L_C741
R^D133
R^D135

L_C166
R^D166
R^D166
L_C358
R^D10
R^D93
L_C550
R^D143
R^D3
L_C742
R^D133
R^D136

L_C167
R^D167
R^D167
L_C359
R^D10
R^D116
L_C551
R^D143
R^D5
L_C743
R^D133
R^D146

L_C168
R^D168
R^D168
L_C360
R^D10
R^D117
L_C552
R^D143
R^D17
L_C744
R^D133
R^D147

L_C169
R^D169
R^D169
L_C361
R^D10
R^D118
L_C553
R^D143
R^D18
L_C745
R^D133
R^D149

L_C170
R^D170
R^D170
L_C362
R^D10
R^D119
L_C554
R^D143
R^D20
L_C746
R^D133
R^D151

L_C171
R^D171
R^D171
L_C363
R^D10
R^D120
L_C555
R^D143
R^D22
L_C747
R^D133
R^D154

L_C172
R^D172
R^D172
L_C364
R^D10
R^D133
L_C556
R^D143
R^D37
L_C748
R^D133
R^D155

L_C173
R^D173
R^D173
L_C365
R^D10
R^D134
L_C557
R^D143
R^D40
L_C749
R^D133
R^D161

L_C174
R^D174
R^D174
L_C366
R^D10
R^D135
L_C558
R^D143
R^D41
L_C750
R^D133
R^D175

L_C175
R^D175
R^D175
L_C367
R^D10
R^D136
L_C559
R^D143
R^D42
L_C751
R^D175
R^D3

L_C176
R^D176
R^D176
L_C368
R^D10
R^D143
L_C560
R^D143
R^D43
L_C752
R^D175
R^D5

L_C177
R^D177
R^D177
L_C369
R^D10
R^D144
L_C561
R^D143
R^D48
L_C753
R^D175
R^D18

L_C178
R^D178
R^D178
L_C370
R^D10
R^D145
L_C562
R^D143
R^D49
L_C754
R^D175
R^D20

L_C179
R^D179
R^D179
L_C371
R^D10
R^D146
L_C563
R^D143
R^D54
L_C755
R^D175
R^D22

L_C180
R^D180
R^D180
L_C372
R^D10
R^D147
L_C564
R^D143
R^D58
L_C756
R^D175
R^D37

L_C181
R^D181
R^D181
L_C373
R^D10
R^D149
L_C565
R^D143
R^D59
L_C757
R^D175
R^D40

L_C182
R^D182
R^D182
L_C374
R^D10
R^D151
L_C566
R^D143
R^D78
L_C758
R^D175
R^D41

L_C183
R^D183
R^D183
L_C375
R^D10
R^D154
L_C567
R^D143
R^D79
L_C759
R^D175
R^D42

L_C184
R^D184
R^D184
L_C376
R^D10
R^D155
L_C568
R^D143
R^D81
L_C760
R^D175
R^D43

L_C185
R^D185
R^D185
L_C377
R^D10
R^D161
L_C569
R^D143
R^D87
L_C761
R^D175
R^D48

L_C186
R^D186
R^D186
L_C378
R^D10
R^D175
L_C570
R^D143
R^D88
L_C762
R^D175
R^D49

L_C187
R^D187
R^D187
L_C379
R^D17
R^D3
L_C571
R^D143
R^D89
L_C763
R^D175
R^D54

L_C188
R^D188
R^D188
L_C380
R^D17
R^D5
L_C572
R^D143
R^D93
L_C764
R^D175
R^D58

L_C189
R^D189
R^D189
L_C381
R^D17
R^D18
L_C573
R^D143
R^D116
L_C765
R^D175
R^D59

L_C190
R^D190
R^D190
L_C382
R^D17
R^D20
L_C574
R^D143
R^D117
L_C766
R^D175
R^D78

L_C191
R^D191
R^D191
L_C383
R^D17
R^D22
L_C575
R^D143
R^D118
L_C767
R^D175
R^D79

L_C192
R^D192
R^D192
L_C384
R^D17
R^D37
L_C576
R^D143
R^D119
L_C768
R^D175
R^D81

L_C769
R^D193
R^D193
L_C877
R^D1
R^D193
L_C985
R^D4
R^D193
L_C1093
R^D9
R^D193

L_C770
R^D194
R^D194
L_C878
R^D1
R^D194
L_C986
R^D4
R^D194
L_C1094
R^D9
R^D194

L_C771
R^D195
R^D195
L_C879
R^D1
R^D195
L_C987
R^D4
R^D195
L_C1095
R^D9
R^D195

L_C772
R^D196
R^D196
L_C880
R^D1
R^D196
L_C988
R^D4
R^D196
L_C1096
R^D9
R^D196

L_C773
R^D197
R^D197
L_C881
R^D1
R^D197
L_C989
R^D4
R^D197
L_C1097
R^D9
R^D197

L_C774
R^D198
R^D198
L_C882
R^D1
R^D198
L_C990
R^D4
R^D198
L_C1098
R^D9
R^D198

L_C775
R^D199
R^D199
L_C883
R^D1
R^D199
L_C991
R^D4
R^D199
L_C1099
R^D9
R^D199

L_C776
R^D200
R^D200
L_C884
R^D1
R^D200
L_C992
R^D4
R^D200
L_C1100
R^D9
R^D200

L_C777
R^D201
R^D201
L_C885
R^D1
R^D201
L_C993
R^D4
R^D201
L_C1101
R^D9
R^D201

L_C778
R^D202
R^D202
L_C886
R^D1
R^D202
L_C994
R^D4
R^D202
L_C1102
R^D9
R^D202

L_C779
R^D203
R^D203
L_C887
R^D1
R^D203
L_C995
R^D4
R^D203
L_C1103
R^D9
R^D203

L_C780
R^D204
R^D204
L_C888
R^D1
R^D204
L_C996
R^D4
R^D204
L_C1104
R^D9
R^D204

L_C781
R^D205
R^D205
L_C889
R^D1
R^D205
L_C997
R^D4
R^D205
L_C1105
R^D9
R^D205

L_C782
R^D206
R^D206
L_C890
R^D1
R^D206
L_C998
R^D4
R^D206
L_C1106
R^D9
R^D206

L_C783
R^D207
R^D207
L_C891
R^D1
R^D207
L_C999
R^D4
R^D207
L_C1107
R^D9
R^D207

L_C784
R^D208
R^D208
L_C892
R^D1
R^D208
L_C1000
R^D4
R^D208
L_C1108
R^D9
R^D208

L_C785
R^D209
R^D209
L_C893
R^D1
R^D209
L_C1001
R^D4
R^D209
L_C1109
R^D9
R^D209

L_C786
R^D210
R^D210
L_C894
R^D1
R^D210
L_C1002
R^D4
R^D210
L_C1110
R^D9
R^D210

L_C787
R^D211
R^D211
L_C895
R^D1
R^D211
L_C1003
R^D4
R^D211
L_C1111
R^D9
R^D211

L_C788
R^D212
R^D212
L_C896
R^D1
R^D212
L_C1004
R^D4
R^D212
L_C1112
R^D9
R^D212

L_C789
R^D213
R^D213
L_C897
R^D1
R^D213
L_C1005
R^D4
R^D213
L_C1113
R^D9
R^D213

L_C790
R^D214
R^D214
L_C898
R^D1
R^D214
L_C1006
R^D4
R^D214
L_C1114
R^D9
R^D214

L_C791
R^D215
R^D215
L_C899
R^D1
R^D215
L_C1007
R^D4
R^D215
L_C1115
R^D9
R^D215

L_C792
R^D216
R^D216
L_C900
R^D1
R^D216
L_C1008
R^D4
R^D216
L_C1116
R^D9
R^D216

L_C793
R^D217
R^D217
L_C901
R^D1
R^D217
L_C1009
R^D4
R^D217
L_C1117
R^D9
R^D217

L_C794
R^D218
R^D218
L_C902
R^D1
R^D218
L_C1010
R^D4
R^D218
L_C1118
R^D9
R^D218

L_C795
R^D219
R^D219
L_C903
R^D1
R^D219
L_C1011
R^D4
R^D219
L_C1119
R^D9
R^D219

L_C796
R^D220
R^D220
L_C904
R^D1
R^D220
L_C1012
R^D4
R^D220
L_C1120
R^D9
R^D220

L_C797
R^D221
R^D221
L_C905
R^D1
R^D221
L_C1013
R^D4
R^D221
L_C1121
R^D9
R^D221

L_C798
R^D222
R^D222
L_C906
R^D1
R^D222
L_C1014
R^D4
R^D222
L_C1122
R^D9
R^D222

L_C799
R^D223
R^D223
L_C907
R^D1
R^D223
L_C1015
R^D4
R^D223
L_C1123
R^D9
R^D223

L_C800
R^D224
R^D224
L_C908
R^D1
R^D224
L_C1016
R^D4
R^D224
L_C1124
R^D9
R^D224

L_C801
R^D225
R^D225
L_C909
R^D1
R^D225
L_C1017
R^D4
R^D225
L_C1125
R^D9
R^D225

L_C802
R^D226
R^D226
L_C910
R^D1
R^D226
L_C1018
R^D4
R^D226
L_C1126
R^D9
R^D226

L_C803
R^D227
R^D227
L_C911
R^D1
R^D227
L_C1019
R^D4
R^D227
L_C1127
R^D9
R^D227

L_C804
R^D228
R^D228
L_C912
R^D1
R^D228
L_C1020
R^D4
R^D228
L_C1128
R^D9
R^D228

L_C805
R^D229
R^D229
L_C913
R^D1
R^D229
L_C1021
R^D4
R^D229
L_C1129
R^D9
R^D229

L_C806
R^D230
R^D230
L_C914
R^D1
R^D230
L_C1022
R^D4
R^D230
L_C1130
R^D9
R^D230

L_C807
R^D231
R^D231
L_C915
R^D1
R^D231
L_C1023
R^D4
R^D231
L_C1131
R^D9
R^D231

L_C808
R^D232
R^D232
L_C916
R^D1
R^D232
L_C1024
R^D4
R^D232
L_C1132
R^D9
R^D232

L_C809
R^D233
R^D233
L_C917
R^D1
R^D233
L_C1025
R^D4
R^D233
L_C1133
R^D9
R^D233

L_C810
R^D234
R^D234
L_C918
R^D1
R^D234
L_C1026
R^D4
R^D234
L_C1134
R^D9
R^D234

L_C811
R^D235
R^D235
L_C919
R^D1
R^D235
L_C1027
R^D4
R^D235
L_C1135
R^D9
R^D235

L_C812
R^D236
R^D236
L_C920
R^D1
R^D236
L_C1028
R^D4
R^D236
L_C1136
R^D9
R^D236

L_C813
R^D237
R^D237
L_C921
R^D1
R^D237
L_C1029
R^D4
R^D237
L_C1137
R^D9
R^D237

L_C814
R^D238
R^D238
L_C922
R^D1
R^D238
L_C1030
R^D4
R^D238
L_C1138
R^D9
R^D238

L_C815
R^D239
R^D239
L_C923
R^D1
R^D239
L_C1031
R^D4
R^D239
L_C1139
R^D9
R^D239

L_C816
R^D240
R^D240
L_C924
R^D1
R^D240
L_C1032
R^D4
R^D240
L_C1140
R^D9
R^D240

L_C817
R^D241
R^D241
L_C925
R^D1
R^D241
L_C1033
R^D4
R^D241
L_C1141
R^D9
R^D241

L_C818
R^D242
R^D242
L_C926
R^D1
R^D242
L_C1034
R^D4
R^D242
L_C1142
R^D9
R^D242

L_C819
R^D243
R^D243
L_C927
R^D1
R^D243
L_C1035
R^D4
R^D243
L_C1143
R^D9
R^D243

L_C820
R^D244
R^D244
L_C928
R^D1
R^D244
L_C1036
R^D4
R^D244
L_C1144
R^D9
R^D244

L_C821
R^D245
R^D245
L_C929
R^D1
R^D245
L_C1037
R^D4
R^D245
L_C1145
R^D9
R^D245

L_C822
R^D246
R^D246
L_C930
R^D1
R^D246
L_C1038
R^D4
R^D246
L_C1146
R^D9
R^D246

L_C823
R^D17
R^D193
L_C931
R^D50
R^D193
L_C1039
R^D145
R^D193
L_C1147
R^D168
R^D193

L_C824
R^D17
R^D194
L_C932
R^D50
R^D194
L_C1040
R^D145
R^D194
L_C1148
R^D168
R^D194

L_C825
R^D17
R^D195
L_C933
R^D50
R^D195
L_C1041
R^D145
R^D195
L_C1149
R^D168
R^D195

L_C826
R^D17
R^D196
L_C934
R^D50
R^D196
L_C1042
R^D145
R^D196
L_C1150
R^D168
R^D196

L_C827
R^D17
R^D197
L_C935
R^D50
R^D197
L_C1043
R^D145
R^D197
L_C1151
R^D168
R^D197

L_C828
R^D17
R^D198
L_C936
R^D50
R^D198
L_C1044
R^D145
R^D198
L_C1152
R^D168
R^D198

L_C829
R^D17
R^D199
L_C937
R^D50
R^D199
L_C1045
R^D145
R^D199
L_C1153
R^D168
R^D199

L_C830
R^D17
R^D200
L_C938
R^D50
R^D200
L_C1046
R^D145
R^D200
L_C1154
R^D168
R^D200

L_C831
R^D17
R^D201
L_C939
R^D50
R^D201
L_C1047
R^D145
R^D201
L_C1155
R^D168
R^D201

L_C832
R^D17
R^D202
L_C940
R^D50
R^D202
L_C1048
R^D145
R^D202
L_C1156
R^D168
R^D202

L_C833
R^D17
R^D203
L_C941
R^D50
R^D203
L_C1049
R^D145
R^D203
L_C1157
R^D168
R^D203

L_C834
R^D17
R^D204
L_C942
R^D50
R^D204
L_C1050
R^D145
R^D204
L_C1158
R^D168
R^D204

L_C835
R^D17
R^D205
L_C943
R^D50
R^D205
L_C1051
R^D145
R^D205
L_C1159
R^D168
R^D205

L_C836
R^D17
R^D206
L_C944
R^D50
R^D206
L_C1052
R^D145
R^D206
L_C1160
R^D168
R^D206

L_C837
R^D17
R^D207
L_C945
R^D50
R^D207
L_C1053
R^D145
R^D207
L_C1161
R^D168
R^D207

L_C838
R^D17
R^D208
L_C946
R^D50
R^D208
L_C1054
R^D145
R^D208
L_C1162
R^D168
R^D208

L_C839
R^D17
R^D209
L_C947
R^D50
R^D209
L_C1055
R^D145
R^D209
L_C1163
R^D168
R^D209

L_C840
R^D17
R^D210
L_C948
R^D50
R^D210
L_C1056
R^D145
R^D210
L_C1164
R^D168
R^D210

L_C841
R^D17
R^D211
L_C949
R^D50
R^D211
L_C1057
R^D145
R^D211
L_C1165
R^D168
R^D211

L_C842
R^D17
R^D212
L_C950
R^D50
R^D212
L_C1058
R^D145
R^D212
L_C1166
R^D168
R^D212

L_C843
R^D17
R^D213
L_C951
R^D50
R^D213
L_C1059
R^D145
R^D213
L_C1167
R^D168
R^D213

L_C844
R^D17
R^D214
L_C952
R^D50
R^D214
L_C1060
R^D145
R^D214
L_C1168
R^D168
R^D214

L_C845
R^D17
R^D215
L_C953
R^D50
R^D215
L_C1061
R^D145
R^D215
L_C1169
R^D168
R^D215

L_C846
R^D17
R^D216
L_C954
R^D50
R^D216
L_C1062
R^D145
R^D216
L_C1170
R^D168
R^D216

L_C847
R^D17
R^D217
L_C955
R^D50
R^D217
L_C1063
R^D145
R^D217
L_C1171
R^D168
R^D217

L_C848
R^D17
R^D218
L_C956
R^D50
R^D218
L_C1064
R^D145
R^D218
L_C1172
R^D168
R^D218

L_C849
R^D17
R^D219
L_C957
R^D50
R^D219
L_C1065
R^D145
R^D219
L_C1173
R^D168
R^D219

L_C850
R^D17
R^D220
L_C958
R^D50
R^D220
L_C1066
R^D145
R^D220
L_C1174
R^D168
R^D220

L_C851
R^D17
R^D221
L_C959
R^D50
R^D221
L_C1067
R^D145
R^D221
L_C1175
R^D168
R^D221

L_C852
R^D17
R^D222
L_C960
R^D50
R^D222
L_C1068
R^D145
R^D222
L_C1176
R^D168
R^D222

L_C853
R^D17
R^D223
L_C961
R^D50
R^D223
L_C1069
R^D145
R^D223
L_C1177
R^D168
R^D223

L_C854
R^D17
R^D224
L_C962
R^D50
R^D224
L_C1070
R^D145
R^D224
L_C1178
R^D168
R^D224

L_C855
R^D17
R^D225
L_C963
R^D50
R^D225
L_C1071
R^D145
R^D225
L_C1179
R^D168
R^D225

L_C856
R^D17
R^D226
L_C964
R^D50
R^D226
L_C1072
R^D145
R^D226
L_C1180
R^D168
R^D226

L_C857
R^D17
R^D227
L_C965
R^D50
R^D227
L_C1073
R^D145
R^D227
L_C1181
R^D168
R^D227

L_C858
R^D17
R^D228
L_C966
R^D50
R^D228
L_C1074
R^D145
R^D228
L_C1182
R^D168
R^D228

L_C859
R^D17
R^D229
L_C967
R^D50
R^D229
L_C1075
R^D145
R^D229
L_C1183
R^D168
R^D229

L_C860
R^D17
R^D230
L_C968
R^D50
R^D230
L_C1076
R^D145
R^D230
L_C1184
R^D168
R^D230

L_C861
R^D17
R^D231
L_C969
R^D50
R^D231
L_C1077
R^D145
R^D231
L_C1185
R^D168
R^D231

L_C862
R^D17
R^D232
L_C970
R^D50
R^D232
L_C1078
R^D145
R^D232
L_C1186
R^D168
R^D232

L_C863
R^D17
R^D233
L_C971
R^D50
R^D233
L_C1079
R^D145
R^D233
L_C1187
R^D168
R^D233

L_C864
R^D17
R^D234
L_C972
R^D50
R^D234
L_C1080
R^D145
R^D234
L_C1188
R^D168
R^D234

L_C865
R^D17
R^D235
L_C973
R^D50
R^D235
L_C1081
R^D145
R^D235
L_C1189
R^D168
R^D235

L_C866
R^D17
R^D236
L_C974
R^D50
R^D236
L_C1082
R^D145
R^D236
L_C1190
R^D168
R^D236

L_C867
R^D17
R^D237
L_C975
R^D50
R^D237
L_C1083
R^D145
R^D237
L_C1191
R^D168
R^D237

L_C868
R^D17
R^D238
L_C976
R^D50
R^D238
L_C1084
R^D145
R^D238
L_C1192
R^D168
R^D238

L_C869
R^D17
R^D239
L_C977
R^D50
R^D239
L_C1085
R^D145
R^D239
L_C1193
R^D168
R^D239

L_C870
R^D17
R^D240
L_C978
R^D50
R^D240
L_C1086
R^D145
R^D240
L_C1194
R^D168
R^D240

L_C871
R^D17
R^D241
L_C979
R^D50
R^D241
L_C1087
R^D145
R^D241
L_C1195
R^D168
R^D241

L_C872
R^D17
R^D242
L_C980
R^D50
R^D242
L_C1088
R^D145
R^D242
L_C1196
R^D168
R^D242

L_C873
R^D17
R^D243
L_C981
R^D50
R^D243
L_C1089
R^D145
R^D243
L_C1197
R^D168
R^D243

L_C874
R^D17
R^D244
L_C982
R^D50
R^D244
L_C1090
R^D145
R^D244
L_C1198
R^D168
R^D244

L_C875
R^D17
R^D245
L_C983
R^D50
R^D245
L_C1091
R^D145
R^D245
L_C1199
R^D168
R^D245

L_C876
R^D17
R^D246
L_C984
R^D50
R^D246
L_C1092
R^D145
R^D246
L_C1200
R^D168
R^D246

L_C1201
R^D10
R^D193
L_C1255
R^D55
R^D193
L_C1309
R^D37
R^D193
L_C1363
R^D143
R^D193

L_C1202
R^D10
R^D194
L_C1256
R^D55
R^D194
L_C1310
R^D37
R^D194
L_C1364
R^D143
R^D194

L_C1203
R^D10
R^D195
L_C1257
R^D55
R^D195
L_C1311
R^D37
R^D195
L_C1365
R^D143
R^D195

L_C1204
R^D10
R^D196
L_C1258
R^D55
R^D196
L_C1312
R^D37
R^D196
L_C1366
R^D143
R^D196

L_C1205
R^D10
R^D197
L_C1259
R^D55
R^D197
L_C1313
R^D37
R^D197
L_C1367
R^D143
R^D197

L_C1206
R^D10
R^D198
L_C1260
R^D55
R^D198
L_C1314
R^D37
R^D198
L_C1368
R^D143
R^D198

L_C1207
R^D10
R^D199
L_C1261
R^D55
R^D199
L_C1315
R^D37
R^D199
L_C1369
R^D143
R^D199

L_C1208
R^D10
R^D200
L_C1262
R^D55
R^D200
L_C1316
R^D37
R^D200
L_C1370
R^D143
R^D200

L_C1209
R^D10
R^D201
L_C1263
R^D55
R^D201
L_C1317
R^D37
R^D201
L_C1371
R^D143
R^D201

L_C1210
R^D10
R^D202
L_C1264
R^D55
R^D202
L_C1318
R^D37
R^D202
L_C1372
R^D143
R^D202

L_C1211
R^D10
R^D203
L_C1265
R^D55
R^D203
L_C1319
R^D37
R^D203
L_C1373
R^D143
R^D203

L_C1212
R^D10
R^D204
L_C1266
R^D55
R^D204
L_C1320
R^D37
R^D204
L_C1374
R^D143
R^D204

L_C1213
R^D10
R^D205
L_C1267
R^D55
R^D205
L_C1321
R^D37
R^D205
L_C1375
R^D143
R^D205

L_C1214
R^D10
R^D206
L_C1268
R^D55
R^D206
L_C1322
R^D37
R^D206
L_C1376
R^D143
R^D206

L_C1215
R^D10
R^D207
L_C1269
R^D55
R^D207
L_C1323
R^D37
R^D207
L_C1377
R^D143
R^D207

L_C1216
R^D10
R^D208
L_C1270
R^D55
R^D208
L_C1324
R^D37
R^D208
L_C1378
R^D143
R^D208

L_C1217
R^D10
R^D209
L_C1271
R^D55
R^D209
L_C1325
R^D37
R^D209
L_C1379
R^D143
R^D209

L_C1218
R^D10
R^D210
L_C1272
R^D55
R^D210
L_C1326
R^D37
R^D210
L_C1380
R^D143
R^D210

L_C1219
R^D10
R^D211
L_C1273
R^D55
R^D211
L_C1327
R^D37
R^D211
L_C1381
R^D143
R^D211

L_C1220
R^D10
R^D212
L_C1274
R^D55
R^D212
L_C1328
R^D37
R^D212
L_C1382
R^D143
R^D212

L_C1221
R^D10
R^D213
L_C1275
R^D55
R^D213
L_C1329
R^D37
R^D213
L_C1383
R^D143
R^D213

L_C1222
R^D10
R^D214
L_C1276
R^D55
R^D214
L_C1330
R^D37
R^D214
L_C1384
R^D143
R^D214

L_C1223
R^D10
R^D215
L_C1277
R^D55
R^D215
L_C1331
R^D37
R^D215
L_C1385
R^D143
R^D215

L_C1224
R^D10
R^D216
L_C1278
R^D55
R^D216
L_C1332
R^D37
R^D216
L_C1386
R^D143
R^D216

L_C1225
R^D10
R^D217
L_C1279
R^D55
R^D217
L_C1333
R^D37
R^D217
L_C1387
R^D143
R^D217

L_C1226
R^D10
R^D218
L_C1280
R^D55
R^D218
L_C1334
R^D37
R^D218
L_C1388
R^D143
R^D218

L_C1227
R^D10
R^D219
L_C1281
R^D55
R^D219
L_C1335
R^D37
R^D219
L_C1389
R^D143
R^D219

L_C1228
R^D10
R^D220
L_C1282
R^D55
R^D220
L_C1336
R^D37
R^D220
L_C1390
R^D143
R^D220

L_C1229
R^D10
R^D221
L_C1283
R^D55
R^D221
L_C1337
R^D37
R^D221
L_C1391
R^D143
R^D221

L_C1230
R^D10
R^D222
L_C1284
R^D55
R^D222
L_C1338
R^D37
R^D222
L_C1392
R^D143
R^D222

L_C1231
R^D10
R^D223
L_C1285
R^D55
R^D223
L_C1339
R^D37
R^D223
L_C1393
R^D143
R^D223

L_C1232
R^D10
R^D224
L_C1286
R^D55
R^D224
L_C1340
R^D37
R^D224
L_C1394
R^D143
R^D224

L_C1233
R^D10
R^D225
L_C1287
R^D55
R^D225
L_C1341
R^D37
R^D225
L_C1395
R^D143
R^D225

L_C1234
R^D10
R^D226
L_C1288
R^D55
R^D226
L_C1342
R^D37
R^D226
L_C1396
R^D143
R^D226

L_C1235
R^D10
R^D227
L_C1289
R^D55
R^D227
L_C1343
R^D37
R^D227
L_C1397
R^D143
R^D227

L_C1236
R^D10
R^D228
L_C1290
R^D55
R^D228
L_C1344
R^D37
R^D228
L_C1398
R^D143
R^D228

L_C1237
R^D10
R^D229
L_C1291
R^D55
R^D229
L_C1345
R^D37
R^D229
L_C1399
R^D143
R^D229

L_C1238
R^D10
R^D230
L_C1292
R^D55
R^D230
L_C1346
R^D37
R^D230
L_C1400
R^D143
R^D230

L_C1239
R^D10
R^D231
L_C1293
R^D55
R^D231
L_C1347
R^D37
R^D231
L_C1401
R^D143
R^D231

L_C1240
R^D10
R^D232
L_C1294
R^D55
R^D232
L_C1348
R^D37
R^D232
L_C1402
R^D143
R^D232

L_C1241
R^D10
R^D233
L_C1295
R^D55
R^D233
L_C1349
R^D37
R^D233
L_C1403
R^D143
R^D233

L_C1242
R^D10
R^D234
L_C1296
R^D55
R^D234
L_C1350
R^D37
R^D234
L_C1404
R^D143
R^D234

L_C1243
R^D10
R^D235
L_C1297
R^D55
R^D235
L_C1351
R^D37
R^D235
L_C1405
R^D143
R^D235

L_C1244
R^D10
R^D236
L_C1298
R^D55
R^D236
L_C1352
R^D37
R^D236
L_C1406
R^D143
R^D236

L_C1245
R^D10
R^D237
L_C1299
R^D55
R^D237
L_C1353
R^D37
R^D237
L_C1407
R^D143
R^D237

L_C1246
R^D10
R^D238
L_C1300
R^D55
R^D238
L_C1354
R^D37
R^D238
L_C1408
R^D143
R^D238

L_C1247
R^D10
R^D239
L_C1301
R^D55
R^D239
L_C1355
R^D37
R^D239
L_C1409
R^D143
R^D239

L_C1248
R^D10
R^D240
L_C1302
R^D55
R^D240
L_C1356
R^D37
R^D240
L_C1410
R^D143
R^D240

L_C1249
R^D10
R^D241
L_C1303
R^D55
R^D241
L_C1357
R^D37
R^D241
L_C1411
R^D143
R^D241

L_C1250
R^D10
R^D242
L_C1304
R^D55
R^D242
L_C1358
R^D37
R^D242
L_C1412
R^D143
R^D242

L_C1251
R^D10
R^D243
L_C1305
R^D55
R^D243
L_C1359
R^D37
R^D243
L_C1413
R^D143
R^D243

L_C1252
R^D10
R^D244
L_C1306
R^D55
R^D244
L_C1360
R^D37
R^D244
L_C1414
R^D143
R^D244

L_C1253
R^D10
R^D245
L_C1307
R^D55
R^D245
L_C1361
R^D37
R^D245
L_C1415
R^D143
R^D245

L_C1254
R^D10
R^D246
L_C1308
R^D55
R^D246
L_C1362
R^D37
R^D246
L_C1416
R^D143
R^D246

wherein R^D1to R^D246have the structures of the following LIST 10:

embedded image

Claims

1. A compound comprising a ligand LA having a structure of
2. The compound of claim 1, wherein each of RA, RB, and RC is independently a hydrogen or a substituent selected from the group consisting of deuterium, fluorine, alkyl, cycloalkyl, heteroalkyl, alkoxy, aryloxy, amino, silyl, boryl, alkenyl, cycloalkenyl, heteroalkenyl, aryl, heteroaryl, nitrile, isonitrile, sulfanyl, and combinations thereof.
3. The compound of either of claim 1 or claim 2, wherein each of X1, X2, X3, X4, X5, X6, X7, and X8 is C; or at least one of X1, X2, X3, X4, X5, X6, X7, and X8 is N.
4. The compound of claim 1, wherein one of X1 and X2 is N; or one of X3 and X4 is N.
5. The compound of claim 1, wherein at least one of Y1′ and Y2′ is selected from the group consisting of O, S, and Se.
6. The compound of claim 1, wherein X3 and X4 are C, and two RC are joined to form a ring system fused with ring C.
7. The compound of claim 6, wherein the ring system comprises one ring fused to ring C; or at least two rings fused to ring C; or at least three rings fused to ring C.
8. The compound of claim 1, wherein LA has a structure of
9. The compound of claim 1, wherein the ligand LA is selected from the group consisting of the structures of:
10. The compound of claim 1, wherein the ligand LA is selected from the group consisting of LAi-m-X, wherein i is an integer from 1 to 4524, m is an integer from 1 to 108, and X is from 1 to 4, with 1 being for O, 2 for S, 3 for Se, and 4 for NCH3, wherein each of LAi-1-X to LAi-108-X has the structure defined as follows:
11. The compound of claim 1, wherein the compound has a formula of M(LA)p(LB)q(LC)r wherein LB and LC are each a bidentate ligand; and wherein p is 1, 2, or 3; q is 0, 1, or 2; r is 0, 1, or 2; and p+q+r is the oxidation state of the metal M.
12. The compound of claim 11, wherein the compound has a formula selected from the group consisting of Ir(LA)3, Ir(LA)(LB)2, Ir(LA)2(LB), Ir(LA)2(LC), and Ir(LA)(LB)(LC); and wherein LA, LB, and LC are different from each other; or a formula of Pt(LA)(LB); and wherein LA and LB can be same or different.
13. The compound of claim 11, wherein LB and LC are each independently selected from the group consisting of:
14. The compound of claim 10, wherein when the compound has formula Ir(LAi-m-X)3, i is an integer from 1 to 4524; m is an integer from 1 to 108; and the compound is selected from the group consisting of Ir(LA1-1-1)3 to Ir(LA4524-108-4)3; when the compound has formula Ir(LAi-m-X)(LBk)2, i is an integer from 1 to 4542; m is an integer from 1 to 108; k is an integer from 1 to 324; and the compound is selected from the group consisting of Ir(LA1-1-1)(LB1)2 to Ir(LA4542-108-4)(LB270)2Ir(LA4542-108-4)(LB324)2;when the compound has formula Ir(LAi-m-X)2(LBk), i is an integer from 1 to 4542; m is an integer from 1 to 108; k is an integer from 1 to 324; and the compound is selected from the group consisting of Ir(LA1-1-1)2(LB1) to Ir(LA4542-108-4)2(LB324);when the compound has formula Ir(LAi-m-X)2(LCj-I), i is an integer from 1 to 4542; m is an integer from 1 to 108;j is an integer from 1 to 1416; and the compound is selected from the group consisting of Ir(LA1-1-1)2(LC1-I) to Ir(LA4542-108-4)2(LC1416-I); andwhen the compound has formula Ir(LAi-m-X)2(LCj-II), i is an integer from 1 to 4542; m is an integer from 1 to 108;j is an integer from 1 to 1416; and the compound is selected from the group consisting of Ir(LA1-1-1)2(LC1-II) to Ir(LA4542-108-4)2(LC1416-II);wherein each LBk from LB1 to LB324 has the structure defined as follows:
15. The compound of claim 14, wherein the compound is selected from the group consisting of:
16. The compound of claim 11, wherein the compound has a structure of Formula III,
17. An organic light emitting device (OLED) comprising: an anode;a cathode; andan organic layer disposed between the anode and the cathode, wherein the organic layer comprises a compound according to claim 1.
18. The OLED of claim 17, wherein the organic layer further comprises a host, wherein host comprises at least one chemical moiety selected from the group consisting of triphenylene, carbazole, indolocarbazole, dibenzothiophene, dibenzofuran, dibenzoselenophene, 5,9-dioxa-13b-boranaphtho[3,2,1-de]anthracene, aza-triphenylene, aza-carbazole, aza-indolocarbazole, aza-dibenzothiophene, aza-dibenzofuran, aza-dibenzoselenophene, and aza-(5,9-dioxa-13b-boranaphtho[3,2,1-de]anthracene).
19. The OLED of claim 18, wherein the host is selected from the group consisting of:
20. A consumer product comprising an organic light-emitting device comprising: an anode;a cathode; andan organic layer disposed between the anode and the cathode, wherein the organic layer comprises a compound according to claim 1.

Provisional Applications (4)

Number	Date	Country
63192228	May 2021	US
63168419	Mar 2021	US
63154188	Feb 2021	US
63117727	Nov 2020	US

ORGANIC ELECTROLUMINESCENT MATERIALS AND DEVICES

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Date Filed

Date Published

Inventors

Original Assignees

CPC

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Abstract

Description

Claims

Provisional Applications (4)