Patent Grant
11469384
The present invention relates to compounds for use as emitters, and devices, such as organic light emitting diodes, including the same.
Opto-electronic devices that make use of organic materials are becoming increasingly desirable for a number of reasons. Many of the materials used to make such devices are relatively inexpensive, so organic opto-electronic devices have the potential for cost advantages over inorganic devices. In addition, the inherent properties of organic materials, such as their flexibility, may make them well suited for particular applications such as fabrication on a flexible substrate. Examples of organic opto-electronic devices include organic light emitting diodes/devices (OLEDs), organic phototransistors, organic photovoltaic cells, and organic photodetectors. For OLEDs, the organic materials may have performance advantages over conventional materials. For example, the wavelength at which an organic emissive layer emits light may generally be readily tuned with appropriate dopants.
OLEDs make use of thin organic films that emit light when voltage is applied across the device. OLEDs are becoming an increasingly interesting technology for use in applications such as flat panel displays, illumination, and backlighting. Several OLED materials and configurations are described in U.S. Pat. Nos. 5,844,363, 6,303,238, and 5,707,745, which are incorporated herein by reference in their entirety.
One application for phosphorescent emissive molecules is a full color display. Industry standards for such a display call for pixels adapted to emit particular colors, referred to as “saturated” colors. In particular, these standards call for saturated red, green, and blue pixels. Alternatively the OLED can be designed to emit white light. In conventional liquid crystal displays emission from a white backlight is filtered using absorption filters to produce red, green and blue emission. The same technique can also be used with OLEDs. The white OLED can be either a single EML device or a stack structure. Color may be measured using CIE coordinates, which are well known to the art.
One example of a green emissive molecule is tris(2-phenylpyridine) iridium, denoted Ir(ppy)3, which has the following structure:
In this, and later figures herein, we depict the dative bond from nitrogen to metal (here, Ir) as a straight line.
As used herein, the term “organic” includes polymeric materials as well as small molecule organic materials that may be used to fabricate organic opto-electronic devices. “Small molecule” refers to any organic material that is not a polymer, and “small molecules” may actually be quite large. Small molecules may include repeat units in some circumstances. For example, using a long chain alkyl group as a substituent does not remove a molecule from the “small molecule” class. Small molecules may also be incorporated into polymers, for example as a pendent group on a polymer backbone or as a part of the backbone. Small molecules may also serve as the core moiety of a dendrimer, which consists of a series of chemical shells built on the core moiety. The core moiety of a dendrimer may be a fluorescent or phosphorescent small molecule emitter. A dendrimer may be a “small molecule,” and it is believed that all dendrimers currently used in the field of OLEDs are small molecules.
As used herein, “top” means furthest away from the substrate, while “bottom” means closest to the substrate. Where a first layer is described as “disposed over” a second layer, the first layer is disposed further away from substrate. There may be other layers between the first and second layer, unless it is specified that the first layer is “in contact with” the second layer. For example, a cathode may be described as “disposed over” an anode, even though there are various organic layers in between.
As used herein, “solution processible” means capable of being dissolved, dispersed, or transported in and/or deposited from a liquid medium, either in solution or suspension form.
A ligand may be referred to as “photoactive” when it is believed that the ligand directly contributes to the photoactive properties of an emissive material. A ligand may be referred to as “ancillary” when it is believed that the ligand does not contribute to the photoactive properties of an emissive material, although an ancillary ligand may alter the properties of a photoactive ligand.
As used herein, and as would be generally understood by one skilled in the art, a first “Highest Occupied Molecular Orbital” (HOMO) or “Lowest Unoccupied Molecular Orbital” (LUMO) energy level is “greater than” or “higher than” a second HOMO or LUMO energy level if the first energy level is closer to the vacuum energy level. Since ionization potentials (IP) are measured as a negative energy relative to a vacuum level, a higher HOMO energy level corresponds to an IP having a smaller absolute value (an IP that is less negative). Similarly, a higher LUMO energy level corresponds to an electron affinity (EA) having a smaller absolute value (an EA that is less negative). On a conventional energy level diagram, with the vacuum level at the top, the LUMO energy level of a material is higher than the HOMO energy level of the same material. A “higher” HOMO or LUMO energy level appears closer to the top of such a diagram than a “lower” HOMO or LUMO energy level.
As used herein, and as would be generally understood by one skilled in the art, a first work function is “greater than” or “higher than” a second work function if the first work function has a higher absolute value. Because work functions are generally measured as negative numbers relative to vacuum level, this means that a “higher” work function is more negative. On a conventional energy level diagram, with the vacuum level at the top, a “higher” work function is illustrated as further away from the vacuum level in the downward direction. Thus, the definitions of HOMO and LUMO energy levels follow a different convention than work functions.
More details on OLEDs, and the definitions described above, can be found in U.S. Pat. No. 7,279,704, which is incorporated herein by reference in its entirety.
Disclosed herein is a series of metal complexes and their use as emitter dopants in organic electroluminescence devices. When used as emitter dopants in OLEDs, the complexes improve the performance of the OLEDs including device efficiency, emission peak line shape, and device lifetime.
A compound comprising a first ligand LA of
is disclosed. In Formula I, A is a 5-membered or 6-membered aromatic ring; RA represents mono to the maximum number of possible substitutions, or no substitution; Z1 and Z2 are each independently C or N; G is a fused ring structure consisting of six fused carbocyclic or heterocyclic rings; at least two of the six fused carbocyclic or heterocyclic rings in G are 5-membered rings; at least three of the six fused carbocyclic or heterocyclic rings in G are 6-membered rings; all of the 6-membered rings in G are aromatic rings; each ring of the six fused rings in G is fused to no more than two other rings; G can be further substituted by one or more substituent RB; each RA and RB is independently a hydrogen or a substituent selected from the group consisting of the general substituents defined herein; LA is complexed to a metal M to form a 5-membered chelate ring; M can be coordinated to other ligands; and LA can be linked with other ligands to form a tridentate, tetradentate, pentadentate, or hexadentate ligand.
An OLED comprising the compound of the present disclosure in an organic layer therein is also disclosed.
A consumer product comprising the OLED is also disclosed.
Generally, an OLED comprises at least one organic layer disposed between and electrically connected to an anode and a cathode. When a current is applied, the anode injects holes and the cathode injects electrons into the organic layer(s). The injected holes and electrons each migrate toward the oppositely charged electrode. When an electron and hole localize on the same molecule, an “exciton,” which is a localized electron-hole pair having an excited energy state, is formed. Light is emitted when the exciton relaxes via a photoemissive mechanism. In some cases, the exciton may be localized on an excimer or an exciplex. Non-radiative mechanisms, such as thermal relaxation, may also occur, but are generally considered undesirable.
The initial OLEDs used emissive molecules that emitted light from their singlet states (“fluorescence”) as disclosed, for example, in U.S. Pat. No. 4,769,292, which is incorporated by reference in its entirety. Fluorescent emission generally occurs in a time frame of less than 10 nanoseconds.
More recently, OLEDs having emissive materials that emit light from triplet states (“phosphorescence”) have been demonstrated. Baldo et al., “Highly Efficient Phosphorescent Emission from Organic Electroluminescent Devices,” Nature, vol. 395, 151-154, 1998; (“Baldo-I”) and Baldo et al., “Very high-efficiency green organic light-emitting devices based on electrophosphorescence,” Appl. Phys. Lett., vol. 75, No. 3, 4-6 (1999) (“Baldo-II”), are incorporated by reference in their entireties. Phosphorescence is described in more detail in U.S. Pat. No. 7,279,704 at cols. 5-6, which are incorporated by reference.
More examples for each of these layers are available. For example, a flexible and transparent substrate-anode combination is disclosed in U.S. Pat. No. 5,844,363, which is incorporated by reference in its entirety. An example of a p-doped hole transport layer is m-MTDATA doped with F4-TCNQ at a molar ratio of 50:1, as disclosed in U.S. Patent Application Publication No. 2003/0230980, which is incorporated by reference in its entirety. Examples of emissive and host materials are disclosed in U.S. Pat. No. 6,303,238 to Thompson et al., which is incorporated by reference in its entirety. An example of an n-doped electron transport layer is BPhen doped with Li at a molar ratio of 1:1, as disclosed in U.S. Patent Application Publication No. 2003/0230980, which is incorporated by reference in its entirety. U.S. Pat. Nos. 5,703,436 and 5,707,745, which are incorporated by reference in their entireties, disclose examples of cathodes including compound cathodes having a thin layer of metal such as Mg:Ag with an overlying transparent, electrically-conductive, sputter-deposited ITO layer. The theory and use of blocking layers is described in more detail in U.S. Pat. No. 6,097,147 and U.S. Patent Application Publication No. 2003/0230980, which are incorporated by reference in their entireties. Examples of injection layers are provided in U.S. Patent Application Publication No. 2004/0174116, which is incorporated by reference in its entirety. A description of protective layers may be found in U.S. Patent Application Publication No. 2004/0174116, which is incorporated by reference in its entirety.
The simple layered structure illustrated in
Structures and materials not specifically described may also be used, such as OLEDs comprised of polymeric materials (PLEDs) such as disclosed in U.S. Pat. No. 5,247,190 to Friend et al., which is incorporated by reference in its entirety. By way of further example, OLEDs having a single organic layer may be used. OLEDs may be stacked, for example as described in U.S. Pat. No. 5,707,745 to Forrest et al, which is incorporated by reference in its entirety. The OLED structure may deviate from the simple layered structure illustrated in
Unless otherwise specified, any of the layers of the various embodiments may be deposited by any suitable method. For the organic layers, preferred methods include thermal evaporation, ink-jet, such as described in U.S. Pat. Nos. 6,013,982 and 6,087,196, which are incorporated by reference in their entireties, organic vapor phase deposition (OVPD), such as described in U.S. Pat. No. 6,337,102 to Forrest et al., which is incorporated by reference in its entirety, and deposition by organic vapor jet printing (OVJP), such as described in U.S. Pat. No. 7,431,968, which is incorporated by reference in its entirety. Other suitable deposition methods include spin coating and other solution based processes. Solution based processes are preferably carried out in nitrogen or an inert atmosphere. For the other layers, preferred methods include thermal evaporation. Preferred patterning methods include deposition through a mask, cold welding such as described in U.S. Pat. Nos. 6,294,398 and 6,468,819, which are incorporated by reference in their entireties, and patterning associated with some of the deposition methods such as ink jet and organic vapor jet printing (OVJP). Other methods may also be used. The materials to be deposited may be modified to make them compatible with a particular deposition method. For example, substituents such as alkyl and aryl groups, branched or unbranched, and preferably containing at least 3 carbons, may be used in small molecules to enhance their ability to undergo solution processing. Substituents having 20 carbons or more may be used, and 3-20 carbons is a preferred range. Materials with asymmetric structures may have better solution processibility than those having symmetric structures, because asymmetric materials may have a lower tendency to recrystallize. Dendrimer substituents may be used to enhance the ability of small molecules to undergo solution processing.
Devices fabricated in accordance with embodiments of the present invention may further optionally comprise a barrier layer. One purpose of the barrier layer is to protect the electrodes and organic layers from damaging exposure to harmful species in the environment including moisture, vapor and/or gases, etc. The barrier layer may be deposited over, under or next to a substrate, an electrode, or over any other parts of a device including an edge. The barrier layer may comprise a single layer, or multiple layers. The barrier layer may be formed by various known chemical vapor deposition techniques and may include compositions having a single phase as well as compositions having multiple phases. Any suitable material or combination of materials may be used for the barrier layer. The barrier layer may incorporate an inorganic or an organic compound or both. The preferred barrier layer comprises a mixture of a polymeric material and a non-polymeric material as described in U.S. Pat. No. 7,968,146, PCT Pat. Application Nos. PCT/US2007/023098 and PCT/US2009/042829, which are herein incorporated by reference in their entireties. To be considered a “mixture”, the aforesaid polymeric and non-polymeric materials comprising the barrier layer should be deposited under the same reaction conditions and/or at the same time. The weight ratio of polymeric to non-polymeric material may be in the range of 95:5 to 5:95. The polymeric material and the non-polymeric material may be created from the same precursor material. In one example, the mixture of a polymeric material and a non-polymeric material consists essentially of polymeric silicon and inorganic silicon.
Devices fabricated in accordance with embodiments of the invention can be incorporated into a wide variety of electronic component modules (or units) that can be incorporated into a variety of electronic products or intermediate components. Examples of such electronic products or intermediate components include display screens, lighting devices such as discrete light source devices or lighting panels, etc. that can be utilized by the end-user product manufacturers. Such electronic component modules can optionally include the driving electronics and/or power source(s). Devices fabricated in accordance with embodiments of the invention can be incorporated into a wide variety of consumer products that have one or more of the electronic component modules (or units) incorporated therein. A consumer product comprising an OLED that includes the compound of the present disclosure in the organic layer in the OLED is disclosed. Such consumer products would include any kind of products that include one or more light source(s) and/or one or more of some type of visual displays. Some examples of such consumer products include flat panel displays, curved displays, computer monitors, medical monitors, televisions, billboards, lights for interior or exterior illumination and/or signaling, heads-up displays, fully or partially transparent displays, flexible displays, rollable displays, foldable displays, stretchable displays, laser printers, telephones, mobile phones, tablets, phablets, personal digital assistants (PDAs), wearable devices, laptop computers, digital cameras, camcorders, viewfinders, micro-displays (displays that are less than 2 inches diagonal), 3-D displays, virtual reality or augmented reality displays, vehicles, video walls comprising multiple displays tiled together, theater or stadium screen, a light therapy device, and a sign. Various control mechanisms may be used to control devices fabricated in accordance with the present invention, including passive matrix and active matrix. Many of the devices are intended for use in a temperature range comfortable to humans, such as 18 degrees C. to 30 degrees C., and more preferably at room temperature (20-25 degrees C.), but could be used outside this temperature range, for example, from −40 degree C. to +80 degree C.
The materials and structures described herein may have applications in devices other than OLEDs. For example, other optoelectronic devices such as organic solar cells and organic photodetectors may employ the materials and structures. More generally, organic devices, such as organic transistors, may employ the materials and structures.
The terms “halo,” “halogen,” and “halide” are used interchangeably and refer to fluorine, chlorine, bromine, and iodine.
The term “acyl” refers to a substituted carbonyl radical (C(O)—Rs).
The term “ester” refers to a substituted oxycarbonyl (—O—C(O)—Rs or —C(O)—O—Rs) radical.
The term “ether” refers to an —ORs radical.
The terms “sulfanyl” or “thio-ether” are used interchangeably and refer to a —SRs radical.
The term “sulfinyl” refers to a —S(O)—Rs radical.
The term “sulfonyl” refers to a —SO2—Rs radical.
The term “phosphino” refers to a —P(Rs)3 radical, wherein each R can be same or different.
The term “silyl” refers to a —Si(Rs)3 radical, wherein each Rs can be same or different.
In each of the above, Rs can be hydrogen or a substituent selected from the group consisting of deuterium, halogen, alkyl, cycloalkyl, heteroalkyl, heterocycloalkyl, arylalkyl, alkoxy, aryloxy, amino, silyl, alkenyl, cycloalkenyl, heteroalkenyl, alkynyl, aryl, heteroaryl, and combination thereof. Preferred Rs is selected from the group consisting of alkyl, cycloalkyl, aryl, heteroaryl, and combination thereof.
The term “alkyl” refers to and includes both straight and branched chain alkyl radicals. Preferred alkyl groups are those containing from one to fifteen carbon atoms and includes methyl, ethyl, propyl, 1-methylethyl, butyl, 1-methylpropyl, 2-methylpropyl, pentyl, 1-methylbutyl, 2-methylbutyl, 3-methylbutyl, 1,1-dimethylpropyl, 1,2-dimethylpropyl, 2,2-dimethylpropyl, and the like. Additionally, the alkyl group is optionally substituted.
The term “cycloalkyl” refers to and includes monocyclic, polycyclic, and spiro alkyl radicals. Preferred cycloalkyl groups are those containing 3 to 12 ring carbon atoms and includes cyclopropyl, cyclopentyl, cyclohexyl, bicyclo[3.1.1]heptyl, spiro[4.5]decyl, spiro[5.5]undecyl, adamantyl, and the like. Additionally, the cycloalkyl group is optionally substituted.
The terms “heteroalkyl” or “heterocycloalkyl” refer to an alkyl or a cycloalkyl radical, respectively, having at least one carbon atom replaced by a heteroatom. Optionally the at least one heteroatom is selected from O, S, N, P, B, Si and Se, preferably, 0, S or N. Additionally, the heteroalkyl or heterocycloalkyl group is optionally substituted.
The term “alkenyl” refers to and includes both straight and branched chain alkene radicals. Alkenyl groups are essentially alkyl groups that include at least one carbon-carbon double bond in the alkyl chain. Cycloalkenyl groups are essentially cycloalkyl groups that include at least one carbon-carbon double bond in the cycloalkyl ring. The term “heteroalkenyl” as used herein refers to an alkenyl radical having at least one carbon atom replaced by a heteroatom. Optionally the at least one heteroatom is selected from O, S, N, P, B, Si, and Se, preferably, O, S, or N. Preferred alkenyl, cycloalkenyl, or heteroalkenyl groups are those containing two to fifteen carbon atoms. Additionally, the alkenyl, cycloalkenyl, or heteroalkenyl group is optionally substituted.
The term “alkynyl” refers to and includes both straight and branched chain alkyne radicals. Preferred alkynyl groups are those containing two to fifteen carbon atoms. Additionally, the alkynyl group is optionally substituted.
The terms “aralkyl” or “arylalkyl” are used interchangeably and refer to an alkyl group that is substituted with an aryl group. Additionally, the aralkyl group is optionally substituted.
The term “heterocyclic group” refers to and includes aromatic and non-aromatic cyclic radicals containing at least one heteroatom. Optionally the at least one heteroatom is selected from O, S, N, P, B, Si, and Se, preferably, O, S, or N. Hetero-aromatic cyclic radicals may be used interchangeably with heteroaryl. Preferred hetero-non-aromatic cyclic groups are those containing 3 to 7 ring atoms which includes at least one hetero atom, and includes cyclic amines such as morpholino, piperidino, pyrrolidino, and the like, and cyclic ethers/thio-ethers, such as tetrahydrofuran, tetrahydropyran, tetrahydrothiophene, and the like. Additionally, the heterocyclic group may be optionally substituted.
The term “aryl” refers to and includes both single-ring aromatic hydrocarbyl groups and polycyclic aromatic ring systems. The polycyclic rings may have two or more rings in which two carbons are common to two adjoining rings (the rings are “fused”) wherein at least one of the rings is an aromatic hydrocarbyl group, e.g., the other rings can be cycloalkyls, cycloalkenyls, aryl, heterocycles, and/or heteroaryls. Preferred aryl groups are those containing six to thirty carbon atoms, preferably six to twenty carbon atoms, more preferably six to twelve carbon atoms. Especially preferred is an aryl group having six carbons, ten carbons or twelve carbons. Suitable aryl groups include phenyl, biphenyl, triphenyl, triphenylene, tetraphenylene, naphthalene, anthracene, phenalene, phenanthrene, fluorene, pyrene, chrysene, perylene, and azulene, preferably phenyl, biphenyl, triphenyl, triphenylene, fluorene, and naphthalene. Additionally, the aryl group is optionally substituted.
The term “heteroaryl” refers to and includes both single-ring aromatic groups and polycyclic aromatic ring systems that include at least one heteroatom. The heteroatoms include, but are not limited to O, S, N, P, B, Si, and Se. In many instances, O, S, or N are the preferred heteroatoms. Hetero-single ring aromatic systems are preferably single rings with 5 or 6 ring atoms, and the ring can have from one to six heteroatoms. The hetero-polycyclic ring systems can have two or more rings in which two atoms are common to two adjoining rings (the rings are “fused”) wherein at least one of the rings is a heteroaryl, e.g., the other rings can be cycloalkyls, cycloalkenyls, aryl, heterocycles, and/or heteroaryls. The hetero-polycyclic aromatic ring systems can have from one to six heteroatoms per ring of the polycyclic aromatic ring system. Preferred heteroaryl groups are those containing three to thirty carbon atoms, preferably three to twenty carbon atoms, more preferably three to twelve carbon atoms. Suitable heteroaryl groups include dibenzothiophene, dibenzofuran, dibenzoselenophene, furan, thiophene, benzofuran, benzothiophene, benzoselenophene, carbazole, indolocarbazole, pyridylindole, pyrrolodipyridine, pyrazole, imidazole, triazole, oxazole, thiazole, oxadiazole, oxatriazole, dioxazole, thiadiazole, pyridine, pyridazine, pyrimidine, pyrazine, triazine, oxazine, oxathiazine, oxadiazine, indole, benzimidazole, indazole, indoxazine, benzoxazole, benzisoxazole, benzothiazole, quinoline, isoquinoline, cinnoline, quinazoline, quinoxaline, naphthyridine, phthalazine, pteridine, xanthene, acridine, phenazine, phenothiazine, phenoxazine, benzofuropyridine, furodipyridine, benzothienopyridine, thienodipyridine, benzoselenophenopyridine, and selenophenodipyridine, preferably dibenzothiophene, dibenzofuran, dibenzoselenophene, carbazole, indolocarbazole, imidazole, pyridine, triazine, benzimidazole, 1,2-azaborine, 1,3-azaborine, 1,4-azaborine, borazine, and aza-analogs thereof. Additionally, the heteroaryl group is optionally substituted.
Of the aryl and heteroaryl groups listed above, the groups of triphenylene, naphthalene, anthracene, dibenzothiophene, dibenzofuran, dibenzoselenophene, carbazole, indolocarbazole, imidazole, pyridine, pyrazine, pyrimidine, triazine, and benzimidazole, and the respective aza-analogs of each thereof are of particular interest.
The terms alkyl, cycloalkyl, heteroalkyl, heterocycloalkyl, alkenyl, cycloalkenyl, heteroalkenyl, alkynyl, aralkyl, heterocyclic group, aryl, and heteroaryl, as used herein, are independently unsubstituted, or independently substituted, with one or more general substituents.
In many instances, the general substituents are selected from the group consisting of deuterium, halogen, alkyl, cycloalkyl, heteroalkyl, heterocycloalkyl, arylalkyl, alkoxy, aryloxy, amino, silyl, alkenyl, cycloalkenyl, heteroalkenyl, alkynyl, aryl, heteroaryl, acyl, carboxylic acid, ether, ester, nitrile, isonitrile, sulfanyl, sulfinyl, sulfonyl, phosphino, and combinations thereof.
In some instances, the preferred general substituents are selected from the group consisting of deuterium, fluorine, alkyl, cycloalkyl, heteroalkyl, alkoxy, aryloxy, amino, silyl, alkenyl, cycloalkenyl, heteroalkenyl, aryl, heteroaryl, nitrile, isonitrile, sulfanyl, and combinations thereof.
In some instances, the preferred general substituents are selected from the group consisting of deuterium, fluorine, alkyl, cycloalkyl, alkoxy, aryloxy, amino, silyl, aryl, heteroaryl, sulfanyl, and combinations thereof.
In yet other instances, the more preferred general substituents are selected from the group consisting of deuterium, fluorine, alkyl, cycloalkyl, aryl, heteroaryl, and combinations thereof.
The terms “substituted” and “substitution” refer to a substituent other than H that is bonded to the relevant position, e.g., a carbon or nitrogen. For example, when R′ represents mono-substitution, then one R′ must be other than H (i.e., a substitution). Similarly, when R′ represents di-substitution, then two of R′ must be other than H. Similarly, when R′ represents no substitution, R′, for example, can be a hydrogen for available valencies of ring atoms, as in carbon atoms for benzene and the nitrogen atom in pyrrole, or simply represents nothing for ring atoms with fully filled valencies, e.g., the nitrogen atom in pyridine. The maximum number of substitutions possible in a ring structure will depend on the total number of available valencies in the ring atoms.
As used herein, “combinations thereof” indicates that one or more members of the applicable list are combined to form a known or chemically stable arrangement that one of ordinary skill in the art can envision from the applicable list. For example, an alkyl and deuterium can be combined to form a partial or fully deuterated alkyl group; a halogen and alkyl can be combined to form a halogenated alkyl substituent; and a halogen, alkyl, and aryl can be combined to form a halogenated arylalkyl. In one instance, the term substitution includes a combination of two to four of the listed groups. In another instance, the term substitution includes a combination of two to three groups. In yet another instance, the term substitution includes a combination of two groups. Preferred combinations of substituent groups are those that contain up to fifty atoms that are not hydrogen or deuterium, or those which include up to forty atoms that are not hydrogen or deuterium, or those that include up to thirty atoms that are not hydrogen or deuterium. In many instances, a preferred combination of substituent groups will include up to twenty atoms that are not hydrogen or deuterium.
The “aza” designation in the fragments described herein, i.e. aza-dibenzofuran, aza-dibenzothiophene, etc. means that one or more of the C—H groups in the respective aromatic ring can be replaced by a nitrogen atom, for example, and without any limitation, azatriphenylene encompasses both dibenzo[f,h]quinoxaline and dibenzo[f,h]quinoline. One of ordinary skill in the art can readily envision other nitrogen analogs of the aza-derivatives described above, and all such analogs are intended to be encompassed by the terms as set forth herein.
As used herein, “deuterium” refers to an isotope of hydrogen. Deuterated compounds can be readily prepared using methods known in the art. For example, U.S. Pat. No. 8,557,400, Patent Pub. No. WO 2006/095951, and U.S. Pat. Application Pub. No. US 2011/0037057, which are hereby incorporated by reference in their entireties, describe the making of deuterium-substituted organometallic complexes. Further reference is made to Ming Yan, et al., Tetrahedron 2015, 71, 1425-30 and Atzrodt et al., Angew. Chem. Int. Ed. (Reviews) 2007, 46, 7744-65, which are incorporated by reference in their entireties, describe the deuteration of the methylene hydrogens in benzyl amines and efficient pathways to replace aromatic ring hydrogens with deuterium, respectively.
It is to be understood that when a molecular fragment is described as being a substituent or otherwise attached to another moiety, its name may be written as if it were a fragment (e.g. phenyl, phenylene, naphthyl, dibenzofuryl) or as if it were the whole molecule (e.g. benzene, naphthalene, dibenzofuran). As used herein, these different ways of designating a substituent or attached fragment are considered to be equivalent.
In some instance, a pair of adjacent substituents can be optionally joined or fused into a ring. The preferred ring is a five, six, or seven-membered carbocyclic or heterocyclic ring, includes both instances where the portion of the ring formed by the pair of substituents is saturated and where the portion of the ring formed by the pair of substituents is unsaturated. As used herein, “adjacent” means that the two substituents involved can be on the same ring next to each other, or on two neighboring rings having the two closest available substitutable positions, such as 2, 2′ positions in a biphenyl, or 1, 8 position in a naphthalene, as long as they can form a stable fused ring system.
A compound comprising a first ligand LA of
is disclosed. In Formula I, A is a 5-membered or 6-membered aromatic ring; RA represents mono to the maximum number of possible substitutions, or no substitution; Z1 and Z2 are each independently C or N; G is a fused ring structure consisting of six fused carbocyclic or heterocyclic rings; at least two of the six fused carbocyclic or heterocyclic rings in G are 5-membered rings; at least three of the six fused carbocyclic or heterocyclic rings in G are 6-membered rings; all of the 6-membered rings in G are aromatic rings; each ring of the six fused rings in G is fused to no more than two other rings; G can be further substituted by one or more substituent RB; each RA and RB is independently a hydrogen or a substituent selected from the group consisting of the general substituents defined herein; LA is complexed to a metal M to form a 5-membered chelate ring; M can be coordinated to other ligands; and LA can be linked with other ligands to form a tridentate, tetradentate, pentadentate, or hexadentate ligand.
In some embodiments of the compound, each RA and RB is independently a hydrogen or a substituent selected from the group consisting of the preferred general substituents defined herein.
In any of the preceding embodiments of the compound, Z′ can be C and Z2 is N or Z′ can be N and Z2 is C.
In some embodiments of the compound, ring A can be selected from the group consisting pyridine, pyrimidine, triazine, pyridazine, pyrazine, imidazole, pyrazole, and N-heterocyclic carbene. In some embodiments of the compound, ring A can be pyridine. In some embodiments of the compound, ring A can be substituted with one or more alkyl groups. In some embodiments of the compound, ring A can be substituted with one or more methyl groups.
In some embodiments of the compound, M is Ir or Pt.
The compound can be homoleptic or heteroleptic.
In some embodiments of the compound, G consists of two 5-membered rings and four 6-membered rings. In some embodiments, G consists of three 5-membered rings and three 6-membered rings.
In some embodiments of the compound, LA is selected from the Ligand Group A consisting of
where, each R1, R2 and R3 independently represents mono to the maximum number of possible substitutions, or no substitution; each R1, R2 and R3 is independently a hydrogen or a substituent selected from the group consisting of the general substituents defined herein; each Y1, Y2 and Y3 is independently selected from O, S, NRX, CRXRY or SiRXRY; each RX and RY is independently a hydrogen or a substituent selected from the group consisting of the preferred general substituents defined herein.
In some embodiments of the compound, the first ligand LA is selected from the group consisting of
LA1 through LA3483 based on a structure of Formula II
wherein for each ligand LA1 through LA3483, the variables R1A, R2A, and GY are defined as follow:
1-A1833
1-A3273
where G1 to G43 have the following structures, where each of Q1 and Q2 are independently selected from O and S:
RZ1 to RZ8 have the following structures:
In some embodiments of the compound, referred to herein as Compound Group A, having the first ligand LA, where LA is not necessarily limited to LA1 to LA3483, the compound has a formula of M(LA)x(LB)y(LC)z where LB and LC are each a bidentate ligand; and wherein x is 1, 2, or 3; y is 0, 1, or 2; z is 0, 1, or 2; and x+y+z is the oxidation state of the metal M.
In some embodiments, referred to herein as Compound Group A-Ir, where the compound has a formula of M(LA)x(LB)y(LC)z as defined above, the compound can have a formula selected from the group consisting of Ir(LA)3, Ir(LA)(LB)2, Ir(LA)2(LB), Ir(LA)2(LC), and Ir(LA)(LB)(LC); and LA, LB, and LC are different from each other.
In some embodiments, referred to herein as Compound Group A-Pt, where the compound has a formula of M(LA)x(LB)y(LC)z as defined above, the compound can have a formula of Pt(LA)(LB) where LA and LB can be same or different. In some of those embodiments, LA and LB can be connected to form a tetradentate ligand. In some of those embodiments, LA and LB can be connected at two places to form a macrocyclic tetradentate ligand.
In the compounds in Compound Group A, Compound Group A-Ir, Compound Group A-Pt, the ligands LB and LC can each be independently selected from the group consisting of:
where, each X1 to X13 are independently selected from the group consisting of carbon and nitrogen; X is selected from the group consisting of BR′, NR′, PR′, O, S, Se, C=O, S=O, SO2, CR′R″, SiR′R″, and GeR′R″; R′ and R″ can be fused or joined to form a ring; each Ra, Rb, Rc, and Rd can represent from mono substitution to the possible maximum number of possible substitutions, or no substitution; R′, R″, Ra, Rb, Rc, and Rd are each independently hydrogen or a substituent selected from the group consisting of the general substituents defined herein; and any two adjacent substitutents of Ra, Rb, Rc, and Rd can be fused or joined to form a ring or form a multidentate ligand. In some of these embodiments of the compound, LB and LC can each be independently selected from the group consisting of:
In the compounds in Compound Group A, Compound Group A-Ir, Compound Group A-Pt, the ligand LB can be selected from the group consisting of LB1 to LB263 having the following structures:
and
the ligand LC can be selected from the group consisting of LCj-I having structures based on a structure of
and LCj-II having structures based on a structure of
where j is an integer from 1 to 768, where for each Cj in LCj-I and LCj-II, R1 and R2 are defined as provided below:
where RD1 to RD192 have the following structures:
In some embodiments of the compounds defined above that includes LB, the compounds can be limited to those that have one of the following structures as LB:
In some embodiments of the compounds defined above that includes LB, the compounds can be limited to those that have one of the following structures as LB:
In some embodiments of the compound where ligand LA is selected from the group consisting of LA1 to LA3483 defined above, the ligands LB and LC can be selected from the groups and sub-groups defined above.
In some embodiments of the compound where ligand LA is selected from the group consisting of LA1 to LA3483 defined above, the compound can have a formula selected from the group consisting of Ir(LA)3, Ir(LA)(LB)2, Ir(LA)2(LB), Ir(LA)2(LC), and Ir(LA)(LB)(LC); and LA, LB, and LC are different from each other. In some embodiments, the compound can have a formula of Pt(LA)(LB) where LA and LB can be same or different. Where the compound has a formula of Pt(LA)(LB), LA and LB can be connected to form a tetradentate ligand. LA and LB can be connected at two places to form a macrocyclic tetradentate ligand.
In some embodiments of the compound where ligand LA is selected from the group consisting of LA1 to LA3483 defined above, the compound can be Compound Ax having the formula Ir(LAi), Compound By having the formula Ir(LAi)(LBk)2, Compound Cz-I having the formula Ir(LAi)2(LCj-I), or Compound Cz-II having the formula Ir(LAi)2(LCj-II); where x=i, y=2631+k−263, and z=7681+j−768; where i is an integer from 1 to 3483 and k is an integer from 1 to 263, and j is an integer from 1 to 768; where the corresponding LBk and LCj are as defined above.
In some embodiments of the Compounds Cz-I and Compounds Cz-II, the ligands LCj-I and LCj-II consist of only those ligands whose corresponding R1 and R2 are defined to be selected from the following structures:
In some embodiments of the Compounds Cz-I and Compounds Cz-II, the ligands LCj-I and LCj-II consist of only those ligands whose corresponding R1 and R2 are defined to be selected from the following structures:
In some embodiments of the Compounds Cz-I, the ligands LCj-I is selected from the group consisting of:
In some embodiments of the compound, the compound is selected from the group consisting of:
An organic light emitting device (OLED) incorporating the compound is also disclosed. The OLED comprises an anode, a cathode, and an organic layer disposed between the anode and the cathode. The organic layer comprises a compound comprising a first ligand LA of
where, A is a 5-membered or 6-membered aromatic ring; RA represents mono to the maximum number of possible substitutions, or no substitution; Z1 and Z2 are each independently C or N; G is a fused ring structure consisting of six fused carbocyclic or heterocyclic rings; at least two of the six fused carbocyclic or heterocyclic rings in G are 5-membered rings; at least three of the six fused carbocyclic or heterocyclic rings in G are 6-membered rings; all of the 6-membered rings in G are aromatic rings; each ring of the six fused rings in G is fused to no more than two other rings; G can be further substituted by one or more substituent RB; each RA and RB is independently a hydrogen or a substituent selected from the group consisting of the general substituents defined herein; LA is complexed to a metal M to form a 5-membered chelate ring; M can be coordinated to other ligands; and LA can be linked with other ligands to form a tridentate, tetradentate, pentadentate, or hexadentate ligand.
In some embodiments of the OLED, the compound is a sensitizer and the OLED further comprises an acceptor; and wherein the acceptor is selected from the group consisting of fluorescent emitter, delayed fluorescence emitter, and combination thereof.
A consumer product incorporating the inventive compound is also disclosed. The consumer product comprises the OLED defined above.
In some embodiments, the OLED has one or more characteristics selected from the group consisting of being flexible, being rollable, being foldable, being stretchable, and being curved. In some embodiments, the OLED is transparent or semi-transparent. In some embodiments, the OLED further comprises a layer comprising carbon nanotubes.
In some embodiments, the OLED further comprises a layer comprising a delayed fluorescent emitter. In some embodiments, the OLED comprises a RGB pixel arrangement or white plus color filter pixel arrangement. In some embodiments, the OLED is a mobile device, a hand held device, or a wearable device. In some embodiments, the OLED is a display panel having less than 10 inch diagonal or 50 square inch area. In some embodiments, the OLED is a display panel having at least 10 inch diagonal or 50 square inch area. In some embodiments, the OLED is a lighting panel.
In some embodiments, the compound can be an emissive dopant. In some embodiments, the compound can produce emissions via phosphorescence, fluorescence, thermally activated delayed fluorescence, i.e., TADF (also referred to as E-type delayed fluorescence; see, e.g., U.S. application Ser. No. 15/700,352, published on Mar. 14, 2019 as U.S. patent application publication No. 2019/0081248, which is hereby incorporated by reference in its entirety), triplet-triplet annihilation, or combinations of these processes. In some embodiments, the emissive dopant can be a racemic mixture, or can be enriched in one enantiomer. In some embodiments, the compound can be homoleptic (each ligand is the same). In some embodiments, the compound can be heteroleptic (at least one ligand is different from others).
When there are more than one ligand coordinated to a metal, the ligands can all be the same in some embodiments. In some other embodiments, at least one ligand is different from the other ligand(s). In some embodiments, every ligand can be different from each other. This is also true in embodiments where a ligand being coordinated to a metal can be linked with other ligands being coordinated to that metal to form a tridentate, tetradentate, pentadentate, or hexadentate ligands. Thus, where the coordinating ligands are being linked together, all of the ligands can be the same in some embodiments, and at least one of the ligands being linked can be different from the other ligand(s) in some other embodiments.
In some embodiments, the compound can be used as a phosphorescent sensitizer in an OLED where one or multiple layers in the OLED contains an acceptor in the form of one or more fluorescent and/or delayed fluorescence emitters. In some embodiments, the compound can be used as one component of an exciplex to be used as a sensitizer. As a phosphorescent sensitizer, the compound must be capable of energy transfer to the acceptor and the acceptor will emit the energy or further transfer energy to a final emitter. The acceptor concentrations can range from 0.001% to 100%. The acceptor could be in either the same layer as the phosphorescent sensitizer or in one or more different layers. In some embodiments, the acceptor is a TADF emitter. In some embodiments, the acceptor is a fluorescent emitter. In some embodiments, the emission can arise from any or all of the sensitizer, acceptor, and final emitter.
In some embodiments, the compound of the present disclosure is neutrally charged.
According to another aspect, a formulation comprising the compound described herein is also disclosed.
The OLED disclosed herein can be incorporated into one or more of a consumer product, an electronic component module, and a lighting panel. The organic layer can be an emissive layer and the compound can be an emissive dopant in some embodiments, while the compound can be a non-emissive dopant in other embodiments.
The organic layer can also include a host. In some embodiments, two or more hosts are preferred. In some embodiments, the hosts used may be a) bipolar, b) electron transporting, c) hole transporting or d) wide band gap materials that play little role in charge transport. In some embodiments, the host can include a metal complex. The host can be a triphenylene containing benzo-fused thiophene or benzo-fused furan. Any substituent in the host can be an unfused substituent independently selected from the group consisting of CnH2n+1, OCnH2n+1, OAr1, N(CnH2n+1)2, N(Ar1)(Ar2), CH═CH—CnH2n+1, Ar1—Ar2, and CnH2n—Ar1, or the host has no substitutions. In the preceding substituents n can range from 1 to 10; and Ar1 and Ar2 can be independently selected from the group consisting of benzene, biphenyl, naphthalene, triphenylene, carbazole, and heteroaromatic analogs thereof. The host can be an inorganic compound, for example, a Zn containing inorganic material e.g. ZnS.
The host can be a compound comprising at least one chemical group selected from the group consisting of triphenylene, carbazole, dibenzothiophene, dibenzofuran, dibenzoselenophene, azatriphenylene, azacarbazole, aza-dibenzothiophene, aza-dibenzofuran, and aza-dibenzoselenophene. The host can include a metal complex. The host can be, but is not limited to, a specific compound selected from the Host Group consisting of:
and combinations thereof.
Additional information on possible hosts is provided below.
According to some embodiments, an emissive region in an OLED is also disclosed. The emissive region comprises a compound comprising a first ligand LA of
where, A is a 5-membered or 6-membered aromatic ring; RA represents mono to the maximum number of possible substitutions, or no substitution; Z1 and Z2 are each independently C or N; G is a fused ring structure consisting of six fused carbocyclic or heterocyclic rings; at least two of the six fused carbocyclic or heterocyclic rings in G are 5-membered rings; at least three of the six fused carbocyclic or heterocyclic rings in G are 6-membered rings; all of the 6-membered rings in G are aromatic rings; each ring of the six fused rings in G is fused to no more than two other rings; G can be further substituted by one or more substituent RB; each RA and RB is independently a hydrogen or a substituent selected from the group consisting of the general substituents defined herein; LA is complexed to a metal M to form a 5-membered chelate ring; M can be coordinated to other ligands; and LA can be linked with other ligands to form a tridentate, tetradentate, pentadentate, or hexadentate ligand.
In some embodiments of the emissive region, the compound can be an emissive dopant or a non-emissive dopant.
In some embodiments of the emissive region, the emissive region further comprises a host, wherein the host contains at least one group selected from the group consisting of metal complex, triphenylene, carbazole, dibenzothiophene, dibenzofuran, dibenzoselenophene, azatriphenylene, aza-carbazole, aza-dibenzothiophene, aza-dibenzofuran, and aza-dibenzoselenophene.
In some embodiments of the emissive region, the emissive region further comprises a host, wherein the host is selected from the Host Group defined above.
In yet another aspect of the present disclosure, a formulation that comprises the novel compound disclosed herein is described. The formulation can include one or more components selected from the group consisting of a solvent, a host, a hole injection material, hole transport material, electron blocking material, hole blocking material, and an electron transport material, disclosed herein.
The present disclosure encompasses any chemical structure comprising the novel compound of the present disclosure, or a monovalent or polyvalent variant thereof. In other words, the inventive compound, or a monovalent or polyvalent variant thereof, can be a part of a larger chemical structure. Such chemical structure can be selected from the group consisting of a monomer, a polymer, a macromolecule, and a supramolecule (also known as supermolecule). As used herein, a “monovalent variant of a compound” refers to a moiety that is identical to the compound except that one hydrogen has been removed and replaced with a bond to the rest of the chemical structure. As used herein, a “polyvalent variant of a compound” refers to a moiety that is identical to the compound except that more than one hydrogen has been removed and replaced with a bond or bonds to the rest of the chemical structure. In the instance of a supramolecule, the inventive compound is can also be incorporated into the supramolecule complex without covalent bonds.
Combination with Other Materials
The materials described herein as useful for a particular layer in an organic light emitting device may be used in combination with a wide variety of other materials present in the device. For example, emissive dopants disclosed herein may be used in conjunction with a wide variety of hosts, transport layers, blocking layers, injection layers, electrodes and other layers that may be present. The materials described or referred to below are non-limiting examples of materials that may be useful in combination with the compounds disclosed herein, and one of skill in the art can readily consult the literature to identify other materials that may be useful in combination.
Conductivity Dopants:
A charge transport layer can be doped with conductivity dopants to substantially alter its density of charge carriers, which will in turn alter its conductivity. The conductivity is increased by generating charge carriers in the matrix material, and depending on the type of dopant, a change in the Fermi level of the semiconductor may also be achieved. Hole-transporting layer can be doped by p-type conductivity dopants and n-type conductivity dopants are used in the electron-transporting layer.
Non-limiting examples of the conductivity dopants that may be used in an OLED in combination with materials disclosed herein are exemplified below together with references that disclose those materials: EP01617493, EP01968131, EP2020694, EP2684932, US20050139810, US20070160905, US20090167167, US2010288362, WO06081780, WO2009003455, WO2009008277, WO2009011327, WO2014009310, US2007252140, US2015060804, US20150123047, and US2012146012.
HIL/HTL:
A hole injecting/transporting material to be used in the present invention is not particularly limited, and any compound may be used as long as the compound is typically used as a hole injecting/transporting material. Examples of the material include, but are not limited to: a phthalocyanine or porphyrin derivative; an aromatic amine derivative; an indolocarbazole derivative; a polymer containing fluorohydrocarbon; a polymer with conductivity dopants; a conducting polymer, such as PEDOT/PSS; a self-assembly monomer derived from compounds such as phosphonic acid and silane derivatives; a metal oxide derivative, such as MoOx; a p-type semiconducting organic compound, such as 1,4,5,8,9,12-Hexaazatriphenylenehexacarbonitrile; a metal complex, and a cross-linkable compounds.
Examples of aromatic amine derivatives used in HIL or HTL include, but not limit to the following general structures:
Each of Ar1 to Ar9 is selected from the group consisting of aromatic hydrocarbon cyclic compounds such as benzene, biphenyl, triphenyl, triphenylene, naphthalene, anthracene, phenalene, phenanthrene, fluorene, pyrene, chrysene, perylene, and azulene; the group consisting of aromatic heterocyclic compounds such as dibenzothiophene, dibenzofuran, dibenzoselenophene, furan, thiophene, benzofuran, benzothiophene, benzoselenophene, carbazole, indolocarbazole, pyridylindole, pyrrolodipyridine, pyrazole, imidazole, triazole, oxazole, thiazole, oxadiazole, oxatriazole, dioxazole, thiadiazole, pyridine, pyridazine, pyrimidine, pyrazine, triazine, oxazine, oxathiazine, oxadiazine, indole, benzimidazole, indazole, indoxazine, benzoxazole, benzisoxazole, benzothiazole, quinoline, isoquinoline, cinnoline, quinazoline, quinoxaline, naphthyridine, phthalazine, pteridine, xanthene, acridine, phenazine, phenothiazine, phenoxazine, benzofuropyridine, furodipyridine, benzothienopyridine, thienodipyridine, benzoselenophenopyridine, and selenophenodipyridine; and the group consisting of 2 to 10 cyclic structural units which are groups of the same type or different types selected from the aromatic hydrocarbon cyclic group and the aromatic heterocyclic group and are bonded to each other directly or via at least one of oxygen atom, nitrogen atom, sulfur atom, silicon atom, phosphorus atom, boron atom, chain structural unit and the aliphatic cyclic group. Each Ar may be unsubstituted or may be substituted by a substituent selected from the group consisting of deuterium, halogen, alkyl, cycloalkyl, heteroalkyl, heterocycloalkyl, arylalkyl, alkoxy, aryloxy, amino, silyl, alkenyl, cycloalkenyl, heteroalkenyl, alkynyl, aryl, heteroaryl, acyl, carboxylic acids, ether, ester, nitrile, isonitrile, sulfanyl, sulfinyl, sulfonyl, phosphino, and combinations thereof.
In one aspect, Ar1 to Ar9 is independently selected from the group consisting of:
wherein k is an integer from 1 to 20; X101 to X108 is C (including CH) or N; Z101 is NAr1, O, or S; Ar1 has the same group defined above.
Examples of metal complexes used in HIL or HTL include, but are not limited to the following general formula:
wherein Met is a metal, which can have an atomic weight greater than 40; (Y101-Y102) is a bidentate ligand, Y111 and Y102 are independently selected from C, N, O, P, and S; L101 is an ancillary ligand; k′ is an integer value from 1 to the maximum number of ligands that may be attached to the metal; and k′+k″ is the maximum number of ligands that may be attached to the metal.
In one aspect, (Y101-Y102) is a 2-phenylpyridine derivative. In another aspect, (Y101-Y102) is a carbene ligand. In another aspect, Met is selected from Ir, Pt, Os, and Zn. In a further aspect, the metal complex has a smallest oxidation potential in solution vs. Fc+/Fc couple less than about 0.6 V.
Non-limiting examples of the HIL and HTL materials that may be used in an OLED in combination with materials disclosed herein are exemplified below together with references that disclose those materials: CN102702075, DE102012005215, EP01624500, EP01698613, EP01806334, EP01930964, EP01972613, EP01997799, EP02011790, EP02055700, EP02055701, EP1725079, EP2085382, EP2660300, EP650955, JP07-073529, JP2005112765, JP2007091719, JP2008021687, JP2014-009196, KR20110088898, KR20130077473, TW201139402, U.S. Ser. No. 06/517,957, US20020158242, US20030162053, US20050123751, US20060182993, US20060240279, US20070145888, US20070181874, US20070278938, US20080014464, US20080091025, US20080106190, US20080124572, US20080145707, US20080220265, US20080233434, US20080303417, US2008107919, US20090115320, US20090167161, US2009066235, US2011007385, US20110163302, US2011240968, US2011278551, US2012205642, US2013241401, US20140117329, US2014183517, U.S. Pat. Nos. 5,061,569, 5,639,914, WO05075451, WO07125714, WO08023550, WO08023759, WO2009145016, WO2010061824, WO2011075644, WO2012177006, WO2013018530, WO2013039073, WO2013087142, WO2013118812, WO2013120577, WO2013157367, WO2013175747, WO2014002873, WO2014015935, WO2014015937, WO2014030872, WO2014030921, WO2014034791, WO2014104514, WO2014157018.
EBL:
An electron blocking layer (EBL) may be used to reduce the number of electrons and/or excitons that leave the emissive layer. The presence of such a blocking layer in a device may result in substantially higher efficiencies, and/or longer lifetime, as compared to a similar device lacking a blocking layer. Also, a blocking layer may be used to confine emission to a desired region of an OLED. In some embodiments, the EBL material has a higher LUMO (closer to the vacuum level) and/or higher triplet energy than the emitter closest to the EBL interface. In some embodiments, the EBL material has a higher LUMO (closer to the vacuum level) and/or higher triplet energy than one or more of the hosts closest to the EBL interface. In one aspect, the compound used in EBL contains the same molecule or the same functional groups used as one of the hosts described below.
Host:
The light emitting layer of the organic EL device of the present invention preferably contains at least a metal complex as light emitting material, and may contain a host material using the metal complex as a dopant material. Examples of the host material are not particularly limited, and any metal complexes or organic compounds may be used as long as the triplet energy of the host is larger than that of the dopant. Any host material may be used with any dopant so long as the triplet criteria is satisfied.
Examples of metal complexes used as host are preferred to have the following general formula:
wherein Met is a metal; (Y103-Y104) is a bidentate ligand, Y103 and Y104 are independently selected from C, N, O, P, and S; L101 is an another ligand; k′ is an integer value from 1 to the maximum number of ligands that may be attached to the metal; and k′+k″ is the maximum number of ligands that may be attached to the metal.
In one aspect, the metal complexes are:
wherein (O—N) is a bidentate ligand, having metal coordinated to atoms O and N.
In another aspect, Met is selected from Ir and Pt. In a further aspect, (Y103-Y104) is a carbene ligand.
In one aspect, the host compound contains at least one of the following groups selected from the group consisting of aromatic hydrocarbon cyclic compounds such as benzene, biphenyl, triphenyl, triphenylene, tetraphenylene, naphthalene, anthracene, phenalene, phenanthrene, fluorene, pyrene, chrysene, perylene, and azulene; the group consisting of aromatic heterocyclic compounds such as dibenzothiophene, dibenzofuran, dibenzoselenophene, furan, thiophene, benzofuran, benzothiophene, benzoselenophene, carbazole, indolocarbazole, pyridylindole, pyrrolodipyridine, pyrazole, imidazole, triazole, oxazole, thiazole, oxadiazole, oxatriazole, dioxazole, thiadiazole, pyridine, pyridazine, pyrimidine, pyrazine, triazine, oxazine, oxathiazine, oxadiazine, indole, benzimidazole, indazole, indoxazine, benzoxazole, benzisoxazole, benzothiazole, quinoline, isoquinoline, cinnoline, quinazoline, quinoxaline, naphthyridine, phthalazine, pteridine, xanthene, acridine, phenazine, phenothiazine, phenoxazine, benzofuropyridine, furodipyridine, benzothienopyridine, thienodipyridine, benzoselenophenopyridine, and selenophenodipyridine; and the group consisting of 2 to 10 cyclic structural units which are groups of the same type or different types selected from the aromatic hydrocarbon cyclic group and the aromatic heterocyclic group and are bonded to each other directly or via at least one of oxygen atom, nitrogen atom, sulfur atom, silicon atom, phosphorus atom, boron atom, chain structural unit and the aliphatic cyclic group. Each option within each group may be unsubstituted or may be substituted by a substituent selected from the group consisting of deuterium, halogen, alkyl, cycloalkyl, heteroalkyl, heterocycloalkyl, arylalkyl, alkoxy, aryloxy, amino, silyl, alkenyl, cycloalkenyl, heteroalkenyl, alkynyl, aryl, heteroaryl, acyl, carboxylic acids, ether, ester, nitrile, isonitrile, sulfanyl, sulfinyl, sulfonyl, phosphino, and combinations thereof.
In one aspect, the host compound contains at least one of the following groups in the molecule:
wherein R101 is selected from the group consisting of hydrogen, deuterium, halogen, alkyl, cycloalkyl, heteroalkyl, heterocycloalkyl, arylalkyl, alkoxy, aryloxy, amino, silyl, alkenyl, cycloalkenyl, heteroalkenyl, alkynyl, aryl, heteroaryl, acyl, carboxylic acids, ether, ester, nitrile, isonitrile, sulfanyl, sulfinyl, sulfonyl, phosphino, and combinations thereof, and when it is aryl or heteroaryl, it has the similar definition as Ar's mentioned above. k is an integer from 0 to 20 or 1 to 20. X101 to X108 are independently selected from C (including CH) or N. Z101 and Z102 are independently selected from NR101, O, or S.
Non-limiting examples of the host materials that may be used in an OLED in combination with materials disclosed herein are exemplified below together with references that disclose those materials: EP2034538, EP2034538A, EP2757608, JP2007254297, KR20100079458, KR20120088644, KR20120129733, KR20130115564, TW201329200, US20030175553, US20050238919, US20060280965, US20090017330, US20090030202, US20090167162, US20090302743, US20090309488, US20100012931, US20100084966, US20100187984, US2010187984, US2012075273, US2012126221, US2013009543, US2013105787, US2013175519, US2014001446, US20140183503, US20140225088, US2014034914, U.S. Pat. No. 7,154,114, WO2001039234, WO2004093207, WO2005014551, WO2005089025, WO2006072002, WO2006114966, WO2007063754, WO2008056746, WO2009003898, WO2009021126, WO2009063833, WO2009066778, WO2009066779, WO2009086028, WO2010056066, WO2010107244, WO2011081423, WO2011081431, WO2011086863, WO2012128298, WO2012133644, WO2012133649, WO2013024872, WO2013035275, WO2013081315, WO2013191404, WO2014142472, US20170263869, US20160163995, U.S. Pat. No. 9,466,803,
Additional Emitters:
One or more additional emitter dopants may be used in conjunction with the compound of the present disclosure. Examples of the additional emitter dopants are not particularly limited, and any compounds may be used as long as the compounds are typically used as emitter materials. Examples of suitable emitter materials include, but are not limited to, compounds which can produce emissions via phosphorescence, fluorescence, thermally activated delayed fluorescence, i.e., TADF (also referred to as E-type delayed fluorescence), triplet-triplet annihilation, or combinations of these processes.
Non-limiting examples of the emitter materials that may be used in an OLED in combination with materials disclosed herein are exemplified below together with references that disclose those materials: CN103694277, CN1696137, EB01238981, EP01239526, EP01961743, EP1239526, EP1244155, EP1642951, EP1647554, EP1841834, EP1841834B, EP2062907, EP2730583, JP2012074444, JP2013110263, JP4478555, KR1020090133652, KR20120032054, KR20130043460, TW201332980, U.S. Ser. No. 06/699,599, U.S. Ser. No. 06/916,554, US20010019782, US20020034656, US20030068526, US20030072964, US20030138657, US20050123788, US20050244673, US2005123791, US2005260449, US20060008670, US20060065890, US20060127696, US20060134459, US20060134462, US20060202194, US20060251923, US20070034863, US20070087321, US20070103060, US20070111026, US20070190359, US20070231600, US2007034863, US2007104979, US2007104980, US2007138437, US2007224450, US2007278936, US20080020237, US20080233410, US20080261076, US20080297033, US200805851, US2008161567, US2008210930, US20090039776, US20090108737, US20090115322, US20090179555, US2009085476, US2009104472, US20100090591, US20100148663, US20100244004, US20100295032, US2010102716, US2010105902, US2010244004, US2010270916, US20110057559, US20110108822, US20110204333, US2011215710, US2011227049, US2011285275, US2012292601, US20130146848, US2013033172, US2013165653, US2013181190, US2013334521, US20140246656, US2014103305, U.S. Pat. Nos. 6,303,238, 6,413,656, 6,653,654, 6,670,645, 6,687,266, 6,835,469, 6,921,915, 7,279,704, 7,332,232, 7,378,162, 7,534,505, 7,675,228, 7,728,137, 7,740,957, 7,759,489, 7,951,947, 8,067,099, 8,592,586, 8,871,361, WO06081973, WO06121811, WO07018067, WO07108362, WO07115970, WO07115981, WO08035571, WO2002015645, WO2003040257, WO2005019373, WO2006056418, WO2008054584, WO2008078800, WO2008096609, WO2008101842, WO2009000673, WO2009050281, WO2009100991, WO2010028151, WO2010054731, WO2010086089, WO2010118029, WO2011044988, WO2011051404, WO2011107491, WO2012020327, WO2012163471, WO2013094620, WO2013107487, WO2013174471, WO2014007565, WO2014008982, WO2014023377, WO2014024131, WO2014031977, WO2014038456. WO2014112450.
HBL:
A hole blocking layer (HBL) may be used to reduce the number of holes and/or excitons that leave the emissive layer. The presence of such a blocking layer in a device may result in substantially higher efficiencies and/or longer lifetime as compared to a similar device lacking a blocking layer. Also, a blocking layer may be used to confine emission to a desired region of an OLED. In some embodiments, the HBL material has a lower HOMO (further from the vacuum level) and/or higher triplet energy than the emitter closest to the HBL interface. In some embodiments, the HBL material has a lower HOMO (further from the vacuum level) and/or higher triplet energy than one or more of the hosts closest to the HBL interface.
In one aspect, compound used in HBL contains the same molecule or the same functional groups used as host described above.
In another aspect, compound used in HBL contains at least one of the following groups in the molecule:
wherein k is an integer from 1 to 20; L101 is an another ligand, k′ is an integer from 1 to 3.
ETL:
Electron transport layer (ETL) may include a material capable of transporting electrons. Electron transport layer may be intrinsic (undoped), or doped. Doping may be used to enhance conductivity. Examples of the ETL material are not particularly limited, and any metal complexes or organic compounds may be used as long as they are typically used to transport electrons.
In one aspect, compound used in ETL contains at least one of the following groups in the molecule:
wherein R101 is selected from the group consisting of hydrogen, deuterium, halogen, alkyl, cycloalkyl, heteroalkyl, heterocycloalkyl, arylalkyl, alkoxy, aryloxy, amino, silyl, alkenyl, cycloalkenyl, heteroalkenyl, alkynyl, aryl, heteroaryl, acyl, carboxylic acids, ether, ester, nitrile, isonitrile, sulfanyl, sulfinyl, sulfonyl, phosphino, and combinations thereof, when it is aryl or heteroaryl, it has the similar definition as Ar's mentioned above. Ar1 to Ar3 has the similar definition as Ar's mentioned above. k is an integer from 1 to 20. X101 to X108 is selected from C (including CH) or N.
In another aspect, the metal complexes used in ETL contains, but not limit to the following general formula:
wherein (O—N) or (N—N) is a bidentate ligand, having metal coordinated to atoms O, N or N, N; L101 is another ligand; k′ is an integer value from 1 to the maximum number of ligands that may be attached to the metal.
Non-limiting examples of the ETL materials that may be used in an OLED in combination with materials disclosed herein are exemplified below together with references that disclose those materials: CN103508940, EP01602648, EP01734038, EP01956007, JP2004-022334, JP2005149918, JP2005-268199, KR0117693, KR20130108183, US20040036077, US20070104977, US2007018155, US20090101870, US20090115316, US20090140637, US20090179554, US2009218940, US2010108990, US2011156017, US2011210320, US2012193612, US2012214993, US2014014925, US2014014927, US20140284580, U.S. Pat. Nos. 6,656,612, 8,415,031, WO2003060956, WO2007111263, WO2009148269, WO2010067894, WO2010072300, WO2011074770, WO2011105373, WO2013079217, WO2013145667, WO2013180376, WO2014104499, WO2014104535,
Charge Generation Layer (CGL)
In tandem or stacked OLEDs, the CGL plays an essential role in the performance, which is composed of an n-doped layer and a p-doped layer for injection of electrons and holes, respectively. Electrons and holes are supplied from the CGL and electrodes. The consumed electrons and holes in the CGL are refilled by the electrons and holes injected from the cathode and anode, respectively; then, the bipolar currents reach a steady state gradually. Typical CGL materials include n and p conductivity dopants used in the transport layers.
In any above-mentioned compounds used in each layer of the OLED device, the hydrogen atoms can be partially or fully deuterated. Thus, any specifically listed substituent, such as, without limitation, methyl, phenyl, pyridyl, etc. may be undeuterated, partially deuterated, and fully deuterated versions thereof. Similarly, classes of substituents such as, without limitation, alkyl, aryl, cycloalkyl, heteroaryl, etc. also may be undeuterated, partially deuterated, and fully deuterated versions thereof.
Experimental
Synthetic Procedure
2,6-dibromonaphthalene-1,5-diol (15 g, 47.2 mmol) was dissolved in 200 ml 1-methylpyrrolidin-2-one in a flask. The solution was purged with nitrogen for 15 min, then cooled in a brine/ice bath to less than 0° C. Sodium hydride (5.66 g, 142 mmol) was added in portions keeping the solution to less than 10° C. The solution was stirred for 10 min then iodomethane (14.75 ml, 236 mmol) was added in portions via syringe keeping the solution to less than 10° C. The reaction was stirred at room temperature overnight. The reaction was poured on to ice water, then transferred to a separatory funnel with ether and water. The aqueous was extracted with ether three times. The combined organics were washed three times with brine, dried with sodium sulfate, then filtered through a neutral alumina plug using ether and concentrated down to an orange solid. The orange solid was purified with silica gel using 75/25 hept/DCM to get 12.5 g of a light yellow solid for a 77% yield. GC/MS and NMR indicated it was the desired product.
2,6-dibromo-1,5-dimethoxynaphthalene (12.5 g, 36.1 mmol), (3-chloro-2-fluorophenyl)boronic acid (12.60 g, 72.3 mmol), potassium carbonate (24.96 g, 181 mmol), dioxane (240 ml) and water (120 ml) were combined in a flask. The solution was purged with nitrogen for 15 min then palladiumtetrakis (5.01 g, 4.34 mmol) was added. The reaction was heated in an oil bath to reflux overnight (˜16 hours). Another 3.5 g (3-chloro-2-fluorophenyl)boronic acid, and 2.0 g palladiumtetrakis were added the next morning. The reaction was heated to reflux for another 5 hours. The reaction was transferred to a separatory funnel with ethyl acetate and some DCM. The organic phase was washed with brine twice, dried with sodium sulfate, filtered and concentrated down to a brown solid. The brown solid was triturated with acetonitrile and filtered to remove a significant amount of the bis-byproduct as a precipitate. The filtrate was concentrated back down to a brown solid. The brown solid was purified with silica gel using 75/25 to 65/35 hept/DCM to get 5.8 g of a yellow solid. The yellow solid was purified with C18 columns using 90/10 acetonitrile/water. Fractions containing the desired product were concentrated down to a wet solid. The sample was transferred to a separatory funnel with ethyl acetate, washed with brine, dried with sodium sulfate, filtered, concentrated down to get 4.8 g of a white solid for a 33.4% yield. GC/MS and NMR indicated it was the desired product. HPLC indicated 99.9% purity.
2-bromo-6-(3-chloro-2-fluorophenyl)-1,5-dimethoxynaphthalene (9.75 g, 24.64 mmol), (2-fluorophenyl)boronic acid (4.14 g, 29.6 mmol), toluene (250 ml) and potassium phosphate monohydrate (17.02 g, 73.9 mmol) were combined in a flask. The solution was purged with nitrogen for 15 min then Pd2dba3 (0.677 g, 0.739 mmol) and dicyclohexyl(2′,6′-dimethoxy-[1,1′-biphenyl]-2-yl)phosphane (1.214 g, 2.96 mmol) were added. The reaction was heated in an oil bath to reflux under nitrogen overnight. The reaction was transferred to separatory funnel with ethyl acetate and water. The aqueous was extracted twice with ethyl acetate. The combined organics were washed once with water, twice with brine, dried with sodium sulfate, filtered, and concentrated down to a brown solid. The brown solid was purified with silica gel using 75/25 to 65/35 hept/DCM to get 8.25 g of a white solid for a 81% yield. GC/MS and NMR indicated it was the desired product.
2-(3-chloro-2-fluorophenyl)-6-(2-fluorophenyl)-1,5-dimethoxynaphthalene (7.8 g, 18.99 mmol) was dissolved in DCM (100 ml) upon warming in a flask under nitrogen. The reaction was placed in a water bath which caused the reaction to change to a suspension. 1 M boron tribromide (76 ml, 76 mmol) was added rapidly dropwise using an addition funnel. The reaction changed to a solution. The reaction was quenched with water to get a precipitate. The reaction was partially concentrated down to remove the DCM, then transferred to separatory funnel with ethyl acetate. The aqueous was extracted twice with ethyl acetate. The combined organic phases were washed twice with water, brine once, dried with sodium sulfate, filtered and concentrated down to get 7.15 g of a orange solid for a 98% yield. GC/MS and NMR indicated it was the desired product.
2-(3-chloro-2-fluorophenyl)-6-(2-fluorophenyl)naphthalene-1,5-diol (7.1 g, 18.55 mmol) was dissolved in 1-methylpyrrolidin-2-one (89 ml, 927 mmol) in a flask. The reaction was purged with nitrogen for 15 min, then potassium carbonate (12.82 g, 93 mmol) was added. The reaction was heated in an oil bath set at 100° C. under nitrogen for two days. The reaction was cooled, diluted with water and stirred for 30 minutes. A precipitate was filtered off and washed well with methanol. The solid was transferred to a flask and triturated with a mixture of DCM and ethyl acetate (500 ml total) with heating. The suspension was filtered off and washed with ethyl acetate to get 5.5 of a yellow solid. The sample was essentially dissolved in 600 ml DCE upon heating and came out of solution upon cooling. The suspension was partially concentrated down on the rotovap to about 200 ml then allowed to stand for an hour. A yellow ppt was collected, washed with some DCM, and dried in the vacuum oven for two hours to get 4.76 g of a yellow solid for a 74.9% yield. GC/MS and NMR indicated it was the desired product.
2-chloro-(bis-fused-dibenzofuran) (4.15 g, 12.11 mmol), 4,4,4′,4′,5,5,5′,5′-octamethyl-2,2′-bi(1,3,2-dioxaborolane) (6.15 g, 24.21 mmol), potassium acetate (3.56 g, 36.3 mmol) and DMF (120 ml) were combined in a flask. The reaction was purged with nitrogen for 15 min, then Pd2dba3 (0.222 g, 0.242 mmol) and dicyclohexyl(2′,6′-dimethoxy-[1,1′-biphenyl]-2-yl)phosphane (0.398 g, 0.969 mmol) were added. The reaction was heated in an oil bath set at 100° C. overnight (˜16 hours). Another 0.1 g Pd2dba3 and 0.2 g dicyclohexyl(2′,6′-dimethoxy[1,1′-biphenyl]-2-yl)phosphane were added and continued heating for another 3.5 hours. The product was used in situ for the next step.
The reaction was cooled, then 2-chloro-4-(2,2-dimethylpropyl-1,1-d2)-5-(methyl-d3)pyridine (2.455 g, 12.11 mmol), potassium phosphate monohydrate (7.71 g, 36.3 mmol), XPhos Gen 2 (0.285 g, 0.363 mmol) and 12 ml water were added. The reaction was heated in an oil bath set at 80° C. overnight (˜′ 6 hours). The reaction was diluted with water. Stirred for 30 min, then filtered off the precipitate. The precipitate was washed well with methanol, then ethyl acetate. The solid was purified with silica gel using DCM then 95/5 to 90/10 DCM/ethyl acetate to get 3.1 g of the desired product. The 3.1 g sample was triturated with a mixture of DCM and ethyl acetate on the rotovap for an hour, partially concentrated down then filtered off a nearly white ppt. Repeated the above trituration for 30 min using acetonitrile instead of ethyl acetate. The white precipitate was dried overnight in the vacuum oven to get 2.75 g of a white solid for a 47.9% yield. GC/MS and NMR indicated it was the desired product. HPLC indicated 99.9% purity.
Iridium complex (2.0 g, 2.331 mmol), 2-(2-bis-fused-dibenzofuran)-(4-(2,2-dimethylpropyl-1,1-d2)-5-(methyl-d3)pyridine (1.991 g, 4.20 mmol), DMF (90 ml) and 2-ethoxyethanol (90 ml) were combined in a flask. The reaction was purged with nitrogen for 15 min then heated to 90° C. using a J-Kem internal temperature controller for nine days. The reaction was concentrated down on the rotovap to a solid. The solid was cooled then diluted and filtered off with methanol. 2.3 g of a brown-yellow solid was recovered using DCM. The solid was purified with silica gel using 75/25 to 85/15 toluene/heptane to get 1.4 g of a yellow solid. The solid was dissolved in DCM in a flask, methanol was added, then partially concentrated down on the rotovap at 35° C. bath temperature. The precipitate was filtered off and dried for two hours in the vacuum oven to get 1.21 g of a bright yellow solid for a 47.9% yield. HPLC indicated greater than 99.9% purity. LC/MS (Mz=1118) indicated it is the desired product. 1.2 g of sample was sublimed on sublimator at 350° C. to get 0.95 g of a yellow solid. HPLC indicated 99.9% purity. NMR indicated it is the desired product.
1,4-dimethoxynapthalene (19.55 g, 104 mmol) was dissolved in DCM (300 ml) in a flask. N-bromosuccinimide (40.7 g, 229 mmol) was added. The reaction was placed under nitrogen and stirred at room temperature for two days. After two days, another 0.8 g NBS was added. Continued stirring another day. Sodium bisulfite solution was added to the reaction, stirred for 30 minutes, then transferred to a separatory funnel. The aqueous was extracted twice with DCM. The combined DCM were washed with water twice, dried with sodium sulfate, filtered and concentrated down to a green-brown solid. The green-brown solid was purified with silica gel using 75/25 hept/DCM to get 30.74 g of a white solid for an 86% yield. GC/MS and NMR indicated it is the desired product.
2,3-dibromo-1,4-dimethoxynaphthalene (14.6 g, 42.2 mmol), (3-chloro-2-fluorophenyl)boronic acid (14.71 g, 84 mmol), potassium carbonate (29.2 g, 211 mmol), dioxane (240 ml) and water (120 ml) were combined in a flask. The solution was purged with nitrogen for 15 min then palladiumtetrakis (4.88 g, 4.22 mmol) was added. The reaction was heated to reflux in an oil bath overnight (˜16 hours). Another 11 g (3-chloro-2-fluorophenyl)boronic acid, and 5.0 g palladiumtetrakis were added. The reaction was heated to reflux overnight. The reaction was transferred to a separatory funnel with ethyl acetate. The organic phase was washed twice with brine, dried with sodium sulfate, filtered and concentrated down to an yellow oil/solid mixture. The mixture was purified with silica gel using 75/25 to 65/35 hept/DCM to get 7.0 g of a white solid. The white solid was purified with C18 columns using 85/15 acetonitrile/water. Fractions containing the desired product were concentrated down to a wet solid. The sample was transferred to a separatory funnel with ethyl acetate, washed with brine, dried with sodium sulfate, filtered, concentrated down to get 6.84 g of a white solid for a 40.9% yield. GC/MS and NMR indicated it was the desired product. HPLC indicated 99.9% purity.
2-bromo-3-(3-chloro-2-fluorophenyl)-1,4-dimethoxynaphthalene (12.2 g, 30.8 mmol), (2-fluorophenyl)boronic acid (5.18 g, 37.0 mmol), toluene (250 ml) and potassium phosphate monohydrate (21.30 g, 93 mmol) were combined in a flask. The solution was purged with nitrogen for 15 min then Pd2dba3 (0.847 g, 0.925 mmol) and dicyclohexyl(2′,6′-dimethoxy-[1,1′-biphenyl]-2-yl)phosphane (1.519 g, 3.70 mmol) were added. The reaction was heated to reflux overnight. The reaction was transferred to a separatory funnel with ethyl acetate and water. The aqueous was extracted twice with ethyl acetate. The combined organics were washed once with water, twice with brine, dried with sodium sulfate, filtered concentrated down to a gold oil. The gold oil was purified with silica gel using 75/25 to 65/35 hept/DCM. Fractions containing two major close running product spots of the same molecular weight were combined to get 11.6 g of a white solid for a 92% yield. GC/MS showed only one product peak, but NMR indicated it was two isomer products.
2-(3-chloro-2-fluorophenyl)-3-(2-fluorophenyl)-1,4-dimethoxynaphthalene (10.8 g, 26.3 mmol) was dissolved in DCM (100 ml) in a flask and placed under nitrogen. The reaction was placed in a water bath, then 1 M boron tribromide (105 ml, 105 mmol) was added rapidly dropwise using an addition funnel. After four hours, the reaction was carefully quenched with water to get a precipitate. The reaction was partially concentrated down to remove the DCM, then transferred to separatory funnel with ethyl acetate. The aqueous was extracted twice with ethyl acetate. The combined organic phases were washed twice with water, brine once, dried with sodium sulfate, filtered and concentrated down to get 10.0 g of a dark red solid for a 99% yield. GC/MS and NMR indicated it is the desired product.
2-(3-chloro-2-fluorophenyl)-3-(2-fluorophenyl)naphthalene-1,4-diol (10.0 g, 26.1 mmol) was dissolved in 1-methylpyrrolidin-2-one (126 ml, 1306 mmol) in a flask. The reaction was purged with nitrogen for 15 min, then potassium carbonate (18.05 g, 131 mmol) was added. The reaction was heated in an oil bath set at 100° C. under nitrogen for two days. The reaction was cooled, diluted with water and stirred for 30 minutes. precipitate was filtered off and washed well with MeOH. The purple solid was triturated with a DCM/ethyl acetate mixture on the rotovap, partially concentrated down, filtered and dried overnight in the vacuum oven to get 6.65 g of a nearly white solid for a 74.3% yield. GC/MS and NMR indicated it is the desired product.
1,2-(2-chloro-fused-benz)furan)-3,4-(fused-benzofuran)-napthalene (3.5 g, 10.21 mmol), 4,4,4′,4′,5,5,5′,5′-octamethyl-2,2′-bi(1,3,2-dioxaborolane) (5.19 g, 20.42 mmol), potassium acetate (3.01 g, 30.6 mmol) and DMF (100 ml) were combined in a flask. The reaction was purged with nitrogen for 15 min, then Pd2dba3 (0.187 g, 0.204 mmol) and dicyclohexyl(2′,6′-dimethoxy-[1,1′-biphenyl]-2-yl)phosphane (0.335 g, 0.817 mmol) were added. The reaction was heated in an oil bath set at 100° C. overnight, then cooled over the weekend. Another 0.2 g Pd2dba3 and 0.4 g dicyclohexyl(2′,6′-dimethoxy-[1,1′-biphenyl]-2-yl)phosphane were added to the rxn. Resumed heating for another night. The product was used in situ for the next step.
The reaction was cooled, then 2-chloro-4-(2,2-dimethylpropyl-1,1-d2)-5-(methyl-d3)pyridine (2.070 g, 10.21 mmol), potassium phosphate monohydrate (6.50 g, 30.6 mmol) and 10 ml water were added. The reaction was purged with nitrogen for 15 min then XPhos Gen 2 (0.241 g, 0.306 mmol) was added. The reaction was heated in an oil bath set at 100° C. overnight. The reaction was diluted with water and stirred for 30 min. The precipitate was filtered off, washed with water then methanol to leave a gray solid. The gray solid was purified with silica gel using DCM then 95/5 DCM/ethyl acetate to get 1.9 g of a white solid for a 39.2% yield. GC/MS and NMR indicated it is the desired product. HPLC indicated >99.9% purity.
Iridium complex (1.4 g, 2.158 mmol) 2-(1,2-fused-benzofuran)-3,4-(fused-benzofuran)-napthalene)-4-(2,2-dimethylpropyl-1,1-d2)-5-(methyl-d3) pyridine (1.844 g, 3.88 mmol, DMF (45 ml) and 2-ethoxyethanol (45.0 ml) were combined in a flask. The reaction was purged with nitrogen for 15 min then heated to 90° C. using a J-Kem internal temperature controller for six days. The reaction was concentrated down on the rotovap to a solid. The solid was cooled then diluted and filtered off with methanol. 2.3 g of a brown-yellow solid was recovered using DCM. The solid was purified with silica gel using 75/25 toluene/heptane solvent system to get 1.4 g of a yellow solid. HPLC indicated 99.9% purity. The solid was dissolved in DCM, methanol was added, then partially concentrated down on the rotovap at 35° C. bath temperature. The precipitate was filtered off and dried overnight to get 1.21 g of a bright yellow solid for a 48.2% yield. HPLC indicated >99.9% purity. LC/MS (Mz=1152) indicated it is the desired product. 1.2 g of sample was sublimed at 340° C. to get 0.98 g of a yellow solid. HPLC indicated 99.9% purity. NMR indicated it is the desired product.
All example devices were fabricated by high vacuum (<10−7 Torr) thermal evaporation. The anode electrode was 800 Å of indium tin oxide (ITO). The cathode consisted of 10 Å of Liq (8-hydroxyquinoline lithium) followed by 1,000 Å of Al. All devices were encapsulated with a glass lid sealed with an epoxy resin in a nitrogen glove box (<1 ppm of H2O and O2) immediately after fabrication with a moisture getter incorporated inside the package. The organic stack of the device examples consisted of sequentially, from the ITO Surface: 100 Å of HAT-CN as the hole injection layer (HIL); 400 Å of HTM as a hole transporting layer (HTL); 50 Å of EBM as a electron blocking layer (EBL), emissive layer (EML) with thickness 400 Å. Emissive layer containing H-host (H1): E-host (H2) in 6:4 ratio and 12 weight % of green emitter. 350 Å of Liq (8-hydroxyquinoline lithium) doped with 40% of ETM as the ETL. Device structure is shown in Table 1. Table 1 shows the schematic device structure. The chemical structures of the materials used in the devices are shown below.
Upon fabrication, the devices were measured for their electro luminescence (EL) and current density-voltage-luminescence (JVL) characteristics and life-tested at DC 80 mA/cm2. LT95 at 1,000 nits was calculated from the DC 80 mA/cm2 life time data assuming an acceleration factor of 1.8. Device performance is shown in Table 2.
Upon fabrication Both example 1 and 2 shown very narrow EL spectrum. The FWHM(full width at half maximum) for example 1 is 50 nm, while FWHM for example 2 is 30 nm. Without being bound by any theories, the narrow spectrum is due to the very little geometry change between ground and excited state for example 1 and 2. Furthermore; the efficiency of example 1 and 2 shown high efficiency in the device. It reached 19.9% and 20.5% (at 10 mA/cm2) for example 1 and 2 respectively.
It is understood that the various embodiments described herein are by way of example only, and are not intended to limit the scope of the invention. For example, many of the materials and structures described herein may be substituted with other materials and structures without deviating from the spirit of the invention. The present invention as claimed may therefore include variations from the particular examples and preferred embodiments described herein, as will be apparent to one of skill in the art. It is understood that various theories as to why the invention works are not intended to be limiting.
This application claims priority under 35 U.S.C. § 119(e) to U.S. Provisional Application No. 62/754,879, filed on Nov. 2, 2018, the entire contents of which are incorporated herein by reference.
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| Number | Date | Country | |
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| 20200144519 A1 | May 2020 | US |
| Number | Date | Country | |
|---|---|---|---|
| 62754879 | Nov 2018 | US |
