The present application claims priority from Japanese patent application serial no. 2009-281104 filed on Dec. 11, 2009, the content of which is hereby incorporated by reference into this application.
1. Field of the Invention
The present invention relates to organic light-emitting diodes and light source devices including the organic light-emitting diodes.
2. Description of Related Art
JP-A 2003-86353 discloses a conventional art. The purpose of the conventional art is to provide a transparent substrate which can improve light extraction efficiency of organic electroluminescence (EL) elements at a low cost, and by using this, to provide organic EL elements with higher light extraction efficiency. The conventional art relates to an organic EL element in which: light-condensing structures (microlenses, microprisms, etc.) are disposed between a transparent substrate and a transparent electrode; and a light-condensing layer flattened with transparent resin having a higher refractive index than that of the light-condensing structures is provided.
The conventional art also discloses a method for manufacturing transparent substrates for organic EL, comprising the steps of: applying a transparent resin on a transparent substrate for organic EL; pressing the transparent resin against a member having a surface shape of a casting mold for the light-condensing structures and hardening it to form the light-condensing structures; further applying another transparent resin with a higher refractive index than that of the transparent resin on the substrate; and pressing the another transparent resin against a member with a flat surface and hardening it to flatten it.
In the conventional art, unfortunately, since reflection occurs on the interface between a transparent resin layer and an encapsulation glass in an organic light-emitting diode, there is a problem that is difficult to significantly improve light extraction efficiency.
In view of the foregoing, it is an objective of the present invention to provide an organic light-emitting diode with improved light extraction efficiency and a light source device including the organic light-emitting diode.
(I) According to one aspect of the present invention, there is provided an organic light-emitting diode having: a reflective electrode; an organic layer formed on the reflective electrode; a transparent electrode formed on the organic layer; a transparent resin layer formed on the transparent electrode; and an encapsulation glass formed on the transparent resin layer. Herein, the organic layer includes a light-emitting point. Cone- or pyramid-shaped transparent resin structures are provided in the transparent resin layer in such a manner that each of the cone- or pyramid-shaped transparent resin structures splays from the transparent resin layer toward the encapsulation glass in a normal direction of the encapsulation glass. A refractive index of the transparent resin layer is 1.3 times or more to 1.6 times or less as high as that of the cone- or pyramid-shaped transparent resin structures.
(II) According to another aspect of the present invention, there is provided a light source device including the above-described organic light-emitting diode.
In the above aspects (I) and (II) of the invention, the following modifications and changes can be made.
(i) The refractive index of the transparent resin layer is not less than 2.15 and not more than 2.25; and an apex angle (unit: degree) of a cross section including a normal line of the encapsulation glass of each of the cone- or pyramid-shaped transparent resin structures is “2(44.3x−18±5)”. Here, in the present invention, “x” represents a ratio between the refractive index of the transparent resin layer and the refractive index of the cone- or pyramid-shaped transparent resin structures.
(ii) The refractive index of the transparent resin layer is not less than 2.05 and not more than 2.15; and an apex angle (unit: degree) of a cross section including a normal line of the encapsulation glass of each of the cone- or pyramid-shaped transparent resin structures is “2(44.3x−17.8±5)”.
(iii) The refractive index of the transparent resin layer is not less than 1.95 and not more than 2.05; and an apex angle (unit: degree) of a cross section including a normal line of the encapsulation glass of each of the cone- or pyramid-shaped transparent resin structures is “2(39.5x−10.3±5)”.
(iv) The refractive index of the transparent resin layer is not less than 1.85 and not more than 1.95; and an apex angle (unit: degree) of a cross section including a normal line of the encapsulation glass of each of the cone- or pyramid-shaped transparent resin structures is “2(37.5x−5.7±5)”.
(v) The refractive index of the transparent resin layer is not less than 1.75 and not more than 1.85; and an apex angle (unit: degree) of a cross section including a normal line of the encapsulation glass of each of the cone- or pyramid-shaped transparent resin structures is “2(45.1x−12±5)”.
(vi) The refractive index of the transparent resin layer is not less than 1.65 and not more than 1.75; and an apex angle (unit: degree) of a cross section including a normal line of the encapsulation glass of each of the cone- or pyramid-shaped transparent resin structures is “2(48.9x−13.5±5)”.
(vii) The refractive index of the transparent resin layer is not less than 1.55 and not more than 1.65; and an apex angle (unit: degree) of a cross section including a normal line of the encapsulation glass of each of the cone- or pyramid-shaped transparent resin structures is “2(58x−20.7±5)”.
(viii) The light-emitting point emits light at an emission peak wavelength of λ (unit: nm); and the following relationship is satisfied: “(2m−155/180)λ/4/n/(cos 30°)≦ad≦(2m−155/180)λ/4/n/(cos 46°)”. Here, in the present invention, “ad” represents a height from an interface between the reflective electrode and the organic layer to the light-emitting point (“d” (unit: nm) represents a thickness of the organic layer, and “a” represents a value more than 0 but less than 1 (0<a<1)); “n” represents a refractive index of the organic layer; and “m” represents an integer equal to 1 or greater.
(ix) The light-emitting point emits light at an emission peak wavelength of λ (unit: nm); and the following relationship is satisfied: “(2m−155/180)λ/4/n/(cos 30°)≦ad≦(2m−155/180)λ/4/n/(cos 43°)”.
(x) The light-emitting point emits light at an emission peak wavelength of λ (unit: nm); and the following relationship is satisfied: “(2m−155/180)λ/4/n/(cos 30°)≦ad≦(2m−155/180)λ/4/n/(cos 45°)”.
(xi) The light-emitting point emits light at an emission peak wavelength of λ (unit: nm); and the following relationship is satisfied: “(2m−155/180)λ/4/n/(cos 28°)≦ad≦(2m−155/180)λ/4/n/(cos 43°)”.
(xii) the light-emitting point emits light at an emission peak wavelength of λ (unit: nm); and the following relationship is satisfied: “(2m−155/180)λ/4/n/(cos 28°)≦ad≦(2m−155/180)λ/4/n/(cos 44°)”.
(xiii) The light-emitting point emits light at an emission peak wavelength of λ (unit: nm); and the following relationship is satisfied: “(2m−155/180)λ/4/n/(cos 26°)≦ad≦(2m−155/180)λ/4/n/(cos 44°)”.
(xiv) the light-emitting point emits light at an emission peak wavelength of λ (unit: nm); and the following relationship is satisfied: “(2m−155/180)λ/4/n/(cos 24°)≦ad≦(2m−155/180)λ/4/n/(cos 43°)”.
(xv) The cone- or pyramid-shaped transparent resin structures are pyramid-shaped.
(xvi) The cone- or pyramid-shaped transparent resin structures are cone-shaped.
(xvii) The cone- or pyramid-shaped transparent resin structures are six-sided pyramid-shaped.
(xviii) Bases of the cone- or pyramid-shaped structures are closely packed on an interface between the encapsulation glass and the transparent resin layer.
(III) According to still another aspect of the present invention, there is provided an organic light-emitting diode having: a reflective electrode; an organic layer formed on the reflective electrode; a transparent electrode formed on the organic layer; a transparent resin layer formed on the transparent electrode; and an encapsulation glass formed on the transparent resin layer. Herein, the organic layer includes a light-emitting point. Cone- or pyramid-shaped transparent resin structures are provided in the transparent resin layer in such a manner that each of the cone- or pyramid-shaped transparent resin structures splays from the transparent resin layer toward the encapsulation glass in a normal direction of the encapsulation glass. A refractive index of the transparent resin layer is not less than 1.7, and is 1.1 times or more as high as that of the cone- or pyramid-shaped transparent resin structures.
According to the present invention, it is possible to provide an organic light-emitting diode with improved light extraction efficiency and a light source device including the same. Problems, configurations, and advantages other than those described above will be specifically set forth in the following description of embodiments.
First, problems in improving light extraction efficiency of an organic light-emitting diode will be described here.
Aluminum is generally used for the reflective electrode. For example, when the reflective electrode is used as a cathode, a layer called an electron transport layer is formed on the reflective electrode, and a layer called a hole transport layer is formed on the transparent electrode. A layer called a light-emitting layer is formed between the electron transport layer and the hole transport layer. The electrons and holes recombine within the region approximately 10 nm off either from the interface between the light-emitting layer and the electron transport layer or from the interface between the light-emitting layer and the hole transport layer, and the organic layer emits light. On which side of the light-emitting layer the light emission mainly occurs, on the hole transport layer side or on the electron transport layer side, can be arbitrarily designed since it depends on the mobility and other properties of the materials used. In the present specification, the interface where the light emission mainly occurs is called a “light-emitting point.”
Possible materials for the transparent resin layer, which joins the transparent electrode and the encapsulation glass, include adherent transparent resins, such as PET (polyethylene terephthalate), silicone resins, acrylic resins, polyimide resins, and epoxy resins. Also, refractive indexes can be controlled by dispersing fine particles with a high refractive index, such as fine particles of titanium oxide, in these base materials. The refractive index of the organic layer is usually about 1.8, that of the transparent electrode is about 2, that of the base material for the transparent resin layer is about 1.4 to 1.6, and that of the encapsulation glass is about 1.51.
The light emitted from the light-emitting point passes through the transparent electrode, the transparent resin layer, and the encapsulation glass, before being emitted outwardly. Unfortunately, however, the amount of light extracted outwardly can be very small due to reflection on the interface between the transparent electrode and the transparent resin layer, on the interface between the transparent resin layer and the encapsulation glass, and on the interface between the encapsulation glass and the atmosphere.
In order to reduce the reflectivity on the interface between the transparent electrode and the transparent resin layer, it is desirable that the refractive index of the transparent resin layer be high. However, a higher refractive index of the transparent resin layer inevitably means a higher reflectivity on the interface between the transparent resin layer and the encapsulation glass.
Conventionally, microprisms and other structures with a lower refractive index than that of the transparent resin layer have been disposed in the transparent resin layer to control the light distribution in the transparent resin layer and thus to improve light extraction efficiency. In the conventional art, however, the refractive index of the transparent resin, and the refractive index and the angle of inclination of microprisms are not defined, not only failing to define the configuration to achieve the highest efficiency, but also resulting in configurations with low efficiency.
The present invention has been made in view of the above mentioned problems and aims to provide a technology for obtaining high light extraction efficiency in an organic light-emitting diode in which: a reflective electrode, an organic layer including a light-emitting layer, a transparent electrode, a transparent resin layer, and an encapsulation glass are laminated in this order; and cone- or pyramid-shaped transparent resin structures with a lower refractivity index than that of the transparent resin layer are provided in the transparent resin layer, each of the cone- or pyramid-shaped transparent resin structures splaying toward the encapsulation glass.
The present invention will be described in further detail hereinafter by demonstrating specific embodiments. Since the following embodiments are to show specific examples of the present invention, the present invention is not to be considered limited to these embodiments, and various alterations and modifications can be made by those skilled in the art within the scope of the technical idea as disclosed in the present specification. In addition, like parts having like functions are designated by like reference numerals without repeating the description thereof.
In addition, cone-shaped transparent resin structures 107 are embedded in the transparent resin layer 106, with the circular bases bonded to the surface of the encapsulation glass 108. Each of the cone-shaped transparent resin structures 107 splays toward the encapsulation glass 108 in the normal direction of the encapsulation glass 108. It is desirable that the refractive index of the transparent resin layer 106 be 1.3 times or more to 1.6 times or less as high as that of the cone-shaped transparent resin structures 107. Here, the refractive index of each layer can be measured at room temperature by FilmTek 3000 (purchased from YA-MAN, Ltd.), an optical thin film measuring system, for example. The organic light-emitting diode in
PET (polyethylene terephthalate), silicone resins, acrylic resins, polyimide resins, and epoxy resins may be used for the cone-shaped transparent resin structures 107. Furthermore, by mixing transparent fine particles into a base material such as these resins, the refractive index thereof can be reduced. This is because microgaps occur between the base material resin and the fine particles. Materials with small absorption in the visible region and a refractive index of about 1.5 or less, such as silicon oxide and magnesium fluoride, are suitable for the transparent fine particles.
It is desirable that the fine particles be 80 nm or smaller in size so that the decrease in transmittance due to Rayleigh scattering can be minimized. For example, when silicon oxide with a refractive index of 1.5 is used in a resin-to-particle mixing volume ratio of about 1:9, the refractive index can be reduced to about 1.2. When magnesium fluoride with a refractive index of 1.38 is used in a resin-to-particle mixing volume ratio of about 2:8, the refractive index can be reduced to about 1.2.
As shown in
As shown by the ray path represented by “α” in
However, as shown by the ray path represented by “γ” in
Therefore, in order to maximize light extraction efficiency, the following parameters need to be optimized:
1) nLPL (refractive index of transparent resin layer 106);
2) npri (refractive index of cone-shaped transparent resin structures 107);
3) Light distribution in transparent resin layer 106 before light enters into cone-shaped transparent resin structures 107; and
4) Apex angle of cone-shaped transparent resin structures 107 (2θpri).
In the present embodiment, increasing the proportion of light represented by “β” leads to the maximization of light extraction efficiency. Therefore, what is important is light distribution in the transparent resin layer 106 before light enters into the cone-shaped transparent resin structures 107. This light distribution can be controlled by nLPL and interference conditions hereinafter described. Furthermore, the light distribution angle due to refraction in the cone-shaped transparent resin structures 107 can be controlled by the ratio of nLPL and npri, and by the apex angle of the cone-shaped transparent resin structures 107.
Next, interference conditions will be described.
Light emitted from a light source partly travels directly to the transparent electrode 105, as shown by the ray path represented by “A” in
The angle θcof (unit: degree) at which the light intensity becomes highest can be expressed by the following equation:
θcof=cos−1((2×b−φm/180)×λ/(4π×n×a×d))×180/π Eq. 1
where “b” is an integer equal to or greater than 1; “λ” represents a wavelength (unit: nm); “n” represents the refractive index of the organic layer 103; “d” represents the thickness of the organic layer 103 (unit: nm); “a” represents a value more than 0 but less than 1 (0<a<1); and “φm” is the phase difference due to reflection off the reflective electrode 102.
Although the value of θcof varies from about 140° to 160° depending on the wavelength and the angle of incidence, it is typically 155°. As shown by Eq. 1, θcof varies depending on “a”. In other words, θcof can be controlled by the distance from the interface between the reflective electrode 102 and the organic layer 103 to the light-emitting point 104. The amount of light to be extracted to the transparent resin layer 106 and the light distribution in the transparent resin layer 106 can be controlled by the direction of the light distribution angle at which θcof is set. The setting of θcof in a manner such as this is called the setting of an interference condition.
In addition, interference conditions can be set in a relatively highly flexible manner by controlling the thickness of the hole transport layer and other organic materials with a high mobility. Possible materials for the hole transport layer includes N,N′-bis(3-methylphenyl)-N,N′-diphenyl-[1,1′-biphenyl]-4,4′-diamine (TPD), and 4,4′-bis[N-(1-naphtyl)-N-phenyl-amino]biphenyl (α-NPD).
As shown in
Meanwhile, the relative value of light extraction efficiency with θpri being 90° corresponds to that when the cone-shaped transparent resin structures 107 are not disposed in the transparent resin layer 106. In other words, by setting conditions such that any relative value of light extraction efficiency above that when δpri is 90° can be obtained, light extraction efficiency can be improved compared to when the cone-shaped transparent resin structures 107 are not present.
As shown in
In addition, when solved for “a”, Eq. 1 indicates that the range of “a” which corresponds to θcof in the range from about 30° to 46° is from 0.56 to 0.70. Therefore, when the thickness of the organic layer 103 “d” is 150 nm, the distance from the interface between the reflective electrode 102 and the organic layer 103 to the center of the light-emitting point 104 is in the range from 84 to 105 nm.
As described above, light extraction efficiency can be improved by inserting the cone-shaped transparent resin structures 107 and by appropriately controlling: the relationship between the refractive index of the transparent resin layer 106 and that of the cone-shaped transparent resin structures 107; the apex angle of the cone-shaped transparent resin structures 107; and the position of the light-emitting point 104 in the organic layer 103.
Next, a relationship among the optimum θpri at which efficiency is maximized, the refractive index of the transparent resin layer 106 nLPL, and the refractive index of the cone-shaped transparent resin structures 107 npri will be described.
Optimum θpri=44.3x−18, when nLPL is 2.2;
Optimum θpri=44.3x−17.8, when nLPL is 2.1;
Optimum θpri=39.5x−10.3, when nLPL is 2.0;
Optimum θpri=37.5x−5.7, when nLPL is 1.9;
Optimum θpri=45.1x−12, when nLPL is 1.8;
Optimum θpri=48.9x−13.5, when nLPL is 1.7; and
Optimum θpri=58x−20.7, when nLPL is 1.6,
where nLPL/npri is x.
As shown in
θcof is in the range from about 0° to 53° with npri at 1.4;
θcof is in the range from about 0° to 51° with npri at 1.5;
θcof is in the range from about 0° to 50° with npri at 1.6;
θcof is in the range from about 0° to 49° with npri at 1.7; and
θcof is in the range from about 0° to 48° with npri at 1.8.
Furthermore, the relative value of light extraction efficiency becomes high with θcof in the range from 30° to 46° and reaches its peak value with θcof at 36.05°. In addition, when solved for “a”, Eq. 1 indicates that the range of “a” which corresponds to θcof in the range from about 30° to 46° is from 0.56 to 0.70. And, the distance from the electrode interface to the center of the light-emitting point 104 is in the range from 84 to 104.7 nm when the thickness of the organic layer 103 is 150 nm.
Moreover, within the range of θcof at which light extraction efficiency becomes higher than when the cone-shaped transparent resin structures 107 are not present, light extraction efficiency reaches its peak value when:
θpri is about 51° with npri at 1.4;
θpri is about 47° with npri at 1.5;
θpri is about 44° with npri at 1.6;
θpri is about 40° with npri at 1.7; and
θpri is about 35° with npri at 1.8.
On the other hand, when npri is 1, there is no discernible improvement in light extraction efficiency as compared to when the cone-shaped transparent resin structures 107 are not present. Herein, npri at 1 means that the cone-shaped transparent resin structures 107 are cone-shaped air or vacuum hollow structures.
As described so far, it is revealed that when nLPL is not less than 2.15 and not more than 2.25, light extraction efficiency can be improved by satisfying the following relationship:
The cross-sectional apex angle (unit: degree) of the cone-shaped transparent resin structures 107 2θpri in the normal direction of the glass substrate 101 is equal to “2(44.3x−18±5)”, i.e., “2θpri=2(44.3x−18±5)”, where nLPL/npri is x.
It is also revealed that light extraction efficiency can be improved by satisfying the following relationship:
“(2m−155/180)λ/4/n/(cos 30°)≦ad≦(2m−155/180)λ/4/n/(cos 46°)”,
where “ad” represents the height from the interface between the reflective electrode 102 and the organic layer 103 to the light-emitting point 104 (“d” (unit: nm) represents the thickness of the organic layer 103, and “a” represents a value more than 0 but less than 1 (0<a<1)); “n” represents the refractive index of the organic layer 103; and “m” represents an integer equal to 1 or greater.
As shown in
θcof is in the range from about 2° to 51° with npri at 1.4;
θcof is in the range from about 2° to 50° with npri at 1.5;
θcof is in the range from about 4° to 49° with npri at 1.6;
θcof is in the range from about 6° to 47° with npri at 1.7; and
θcof is in the range from about 14° to 45° with npri at 1.8.
Furthermore, the relative value of light extraction efficiency becomes high with θcof in the range from 30° to 43° and reaches its peak value with θcof at 36.05°. In addition, when solved for “a”, Eq. 1 indicates that the range of “a” which corresponds to θcof in the range from about 30° to 43° is from 0.56 to 0.66. And, the distance from the electrode interface to the center of the light-emitting point 104 is in the range from 84 to 99.5 nm when the thickness of the organic layer 103 “d” is 150 nm.
Moreover, within the range of θcof at which light extraction efficiency becomes higher than when the cone-shaped transparent resin structures 107 are not present, light extraction efficiency reaches its peak value when:
θpri is about 48° with npri at 1.4;
θpri is about 45° with npri at 1.5;
θpri is about 41° with npri at 1.6;
θpri is about 36° with npri at 1.7; and
θpri is about 34° with npri at 1.8.
On the other hand, when npri is 1, there is no discernible improvement in light extraction efficiency as compared to when the cone-shaped transparent resin structures 107 are not present.
As described above, it is revealed that when nLPL is not less than 2.05 and not more than 2.15, light extraction efficiency can be improved by satisfying the following relationship:
“2θpri=2(44.3x−17.8±5)”, where nLPL/npri is x.
It is also revealed that light extraction efficiency can be improved by satisfying the following relationship:
“(2m−155/180)λ/4/n/(cos 30°)≦ad≦(2m−155/180)λ/4/n/(cos 43°)”,
where “ad” represents the height from the interface between the reflective electrode 102 and the organic layer 103 to the light-emitting point 104 (“d” (unit: nm) represents the thickness of the organic layer 103, and “a” represents a value more than 0 but less than 1 (0<a<1)); “n” represents the refractive index of the organic layer 103; and “m” represents an integer equal to 1 or greater.
As shown in
θcof is in the range from about 0° to 51° with npri at 1.2;
θcof is in the range from about 0° to 51° with npri at 1.3;
θcof is in the range from about 0° to 51° with npri at 1.4;
θcof is in the range from about 0° to 49° with npri at 1.5;
θcof is in the range from about 0° to 47° with npri at 1.6;
θcof is in the range from about 16° to 44° with npri at 1.7; and
θcof is in the range from about 28° to 38° with npri at 1.8.
Furthermore, the relative value of light extraction efficiency becomes high with θcof in the range from 30° to 45° and reaches its peak value with θcof at 36.05°. In addition, when solved for “a”, Eq. 1 indicates that the range of “a” which corresponds to θcof in the range from about 30° to 45° is from 0.56 to 0.69. And, the distance from the electrode interface to the center of the light-emitting point 104 is in the range from 84 to 102.9 nm when the thickness of the organic layer 103 “d” is 150 nm.
Moreover, within the range of θcof at which light extraction efficiency becomes higher than when the cone-shaped transparent resin structures 107 are not present, light extraction efficiency reaches its peak value when:
θpri is about 56° with npri at 1.2;
θpri is about 50° with npri at 1.3;
θpri is about 46° with npri at 1.4;
θpri is about 42° with npri at 1.5;
θpri is about 39° with npri at 1.6;
θpri is about 36° with npri at 1.7; and
θpri is about 34° with npri at 1.8.
On the other hand, when npri is 1, there is no discernible improvement in light extraction efficiency as compared to when the cone-shaped transparent resin structures 107 are not present.
As described above, it is revealed that when nLPL is not less than 1.95 and not more than 2.05, light extraction efficiency can be improved by satisfying the following relationship:
“2θpri=2(39.5x−10.3±5)”, where nLPL/npri is x.
It is also revealed that light extraction efficiency can be improved by satisfying the following relationship:
“(2m−155/180)λ/4/n/(cos 30°)≦ad≦(2m−155/180)λ/4/n/(cos 45°)”,
where “ad” represents the height from the interface between the reflective electrode 102 and the organic layer 103 to the light-emitting point 104 (“d” (unit: nm) represents the thickness of the organic layer 103, and “a” represents a value more than 0 but less than 1 (0<a<1)); “n” represents the refractive index of the organic layer 103; and “m” represents an integer equal to 1 or greater.
As shown in
θcof is in the range from about 0° to 49° with npri at 1.4;
θcof is in the range from about 3° to 47° with npri at 1.5;
θcof is in the range from about 17° to 44° with npri at 1.6; and
θcof is in the range from about 28° to 38° with npri at 1.7.
Furthermore, the relative value of light extraction efficiency becomes high with θcof in the range from 28° to 43° and reaches its peak value with θcof at 36.05°. In addition, when solved for “a”, Eq. 1 indicates that the range of “a” which corresponds to θcof in the range from about 28° to 43° is from 0.55 to 0.66. And, the distance from the electrode interface to the center of the light-emitting point 104 is in the range from 82.4 to 99.5 nm when the thickness of the organic layer 103 “d” is 150 nm.
Moreover, within the range of θcof at which light extraction efficiency becomes higher than when the cone-shaped transparent resin structures 107 are not present, light extraction efficiency reaches its peak value when:
θpri is about 45° with npri at 1.4;
θpri is about 42° with npri at 1.5;
θpri is about 39° with npri at 1.6; and
θpri is about 36° with npri at 1.7.
On the other hand, in the cases that npri is 1 and 1.8, there is no discernible improvement in light extraction efficiency as compared to when the cone-shaped transparent resin structures 107 are not present.
As described above, it is revealed that when nLPL is not less than 1.85 and not more than 1.95, light extraction efficiency can be improved by satisfying the following relationship:
“2θpri=2(37.5x−5.7±5)”, where nLPL/npri is x.
It is also revealed that light extraction efficiency can be improved by satisfying the following relationship:
“(2m−155/180)λ/4/n/(cos 28°)≦ad≦(2m−155/180)44/n/(cos 43°)”,
where “ad” represents the height from the interface between the reflective electrode 102 and the organic layer 103 to the light-emitting point 104 (“d” (unit: nm) represents the thickness of the organic layer 103, and “a” represents a value more than 0 but less than 1 (0<a<1)); “n” represents the refractive index of the organic layer 103; and “m” represents an integer equal to 1 or greater.
As shown in
θcof is in the range from about 6° to 49° with npri at 1.2;
θcof is in the range from about 2° to 49° with npri at 1.3;
θcof is in the range from about 9° to 47° with npri at 1.4;
θcof is in the range from about 18° to 43° with npri at 1.5; and
θcof is in the range from about 27° to 38° with npri at 1.6.
Furthermore, the relative value of light extraction efficiency becomes high with θcof in the range from 28° to 44° and reaches its peak value with θcof at 36.05°. In addition, when solved for “a”, Eq. 1 indicates that the range of “a” which corresponds to θcof in the range from about 28° to 44° is from 0.55 to 0.67. And, the distance from the electrode interface to the center of the light-emitting point 104 is in the range from 82.4 to 101.2 nm when the thickness of the organic layer 103 “d” is 150 nm.
Moreover, within the range of θcof at which light extraction efficiency becomes higher than when the cone-shaped transparent resin structures 107 are not present, light extraction efficiency reaches its peak value when:
θpri is about 56° with npri at 1.2;
θpri is about 50° with npri at 1.3;
θpri is about 46° with npri at 1.4;
θpri is about 42° with npri at 1.5; and
θpri is about 39° with npri at 1.6.
On the other hand, in the cases that npri is 1 and 1.7, there is no discernible improvement in light extraction efficiency as compared to when the cone-shaped transparent resin structures 107 are not present.
As described above, it is revealed that when nLPL is not less than 1.75 and not more than 1.85, light extraction efficiency can be improved by satisfying the following relationship:
“2θpri=2(45.1x−12±5)”, where nLPL/npri is x.
It is also revealed that light extraction efficiency can be improved by satisfying the following relationship:
“(2m−155/180)λ/4/n/(cos 28°)≦ad≦(2m−155/180)λ/4/n/(cos 44°)”,
where “ad” represents the height from the interface between the reflective electrode 102 and the organic layer 103 to the light-emitting point 104 (“d” (unit: nm) represents the thickness of the organic layer 103, and “a” represents a value more than 0 but less than 1 (0<a<1)); “n” represents the refractive index of the organic layer 103; and “m” represents an integer equal to 1 or greater.
As shown in
θcof is in the range from about 8° to 48° with npri at 1.2;
θcof is in the range from about 10° to 47° with npri at 1.3;
θcof is in the range from about 17° to 44° with npri at 1.4; and
θcof is in the range from about 24° to 39° with npri at 1.5.
Furthermore, the relative value of light extraction efficiency becomes high with θcof in the range from 26° to 44° and reaches its peak value with θcof at 36.05°. In addition, when solved for “a”, Eq. 1 indicates that the range of “a” which corresponds to θcof in the range from about 26° to 44° is from 0.54 to 0.67. And, the distance from the electrode interface to the center of the light-emitting point 104 is in the range from 81 to 101.2 nm when the thickness of the organic layer 103 “d” is 150 nm.
Moreover, within the range of θcof at which light extraction efficiency becomes higher than when the cone-shaped transparent resin structures 107 are not present, light extraction efficiency reaches its peak value when:
θpri is about 56° with npri at 1.2;
θpri is about 50° with npri at 1.3;
θpri is about 46° with npri at 1.4; and
θpri is about 42° with npri at 1.5.
On the other hand, in the cases that npri is 1 and 1.6, there is no discernible improvement in light extraction efficiency as compared to when the cone-shaped transparent resin structures 107 are not present.
As described above, it is revealed that when nLPL is not less than 1.65 and not more than 1.75, light extraction efficiency can be improved by satisfying the following relationship:
“2θpri=2(48.9x−13.5±5)”, where nLPL/npri is x.
It is also revealed that light extraction efficiency can be improved by satisfying the following relationship:
“(2m−155/180)λ/4/n/(cos 26°)≦ad≦(2m−155/180)λ/4/n/(cos 44°)”,
where “ad” represents the height from the interface between the reflective electrode 102 and the organic layer 103 to the light-emitting point 104 (“d” (unit: nm) represents the thickness of the organic layer 103, and “a” represents a value more than 0 but less than 1 (0<a<1)); “n” represents the refractive index of the organic layer 103; and “m” represents an integer equal to 1 or greater.
As shown in
θcof is in the range from about 12° to 46° with npri at 1.2;
θcof is in the range from about 16° to 44° with npri at 1.3; and
θcof is in the range from about 22° to 40° with npri at 1.4.
Furthermore, the relative value of light extraction efficiency becomes high with θcof in the range from 24° to 43° and reaches its peak value with θcof at 36.05°. In addition, when solved for “a”, Eq. 1 indicates that the range of “a” which corresponds to θcof in the range from about 24° to 43° is from 0.53 to 0.66. And, the distance from the electrode interface to the center of the light-emitting point 104 is in the range from 79.6 to 99.5 nm when the thickness of the organic layer 103 “d” is 150 nm.
Moreover, within the range of θcof at which light extraction efficiency becomes higher than when the cone-shaped transparent resin structures 107 are not present, light extraction efficiency reaches its peak value when:
θpri is about 57° with npri at 1.2;
θpri is about 50° with npri at 1.3; and
θpri is about 46° with npri at 1.4.
On the other hand, in the cases that npri is 1 and 1.5, there is no discernible improvement in light extraction efficiency as compared to when the cone-shaped transparent resin structures 107 are not present.
As described above, it is revealed that when nLPL is not less than 1.55 and not more than 1.65, light extraction efficiency can be improved by satisfying the following relationship:
“2θpri=2(58x−20.7±5)”, where nLPL/npri is x.
It is also revealed that light extraction efficiency can be improved by satisfying the following relationship:
“(2m−155/180)λ/4/n/(cos 24°)≦ad≦(2m−155/180)λ/4/n/(cos 43°)”,
where “ad” represents the height from the interface between the reflective electrode 102 and the organic layer 103 to the light-emitting point 104 (“d” (unit: nm) represents the thickness of the organic layer 103, and “a” represents a value more than 0 but less than 1 (0<a<1)); “n” represents the refractive index of the organic layer 103; and “m” represents an integer equal to 1 or greater.
In summary, light extraction efficiency can be improved as compared to when the cone-shaped resin structures 107 are not present by appropriately setting interference conditions and controlling the relationship between nLPL, which is the refractive index of the transparent resin layer 106, and npri, which is the refractive index of the cone-shaped transparent resin structures 107.
Another embodiment of the present invention will be described in detail hereinafter with reference to
As already described in
Yet another embodiment of the present invention will be described in detail hereinafter with reference to
As described in the second embodiment, the maximum light extraction efficiency can be obtained by setting θpri
Although the invention has been described with respect to the specific embodiments for complete and clear disclosure, the appended claims are not to be thus limited but are to be construed as embodying all modifications and alternative constructions that may occur to one skilled in the art which fairly fall within the basic teaching herein set forth.
Number | Date | Country | Kind |
---|---|---|---|
2009-281104 | Dec 2009 | JP | national |