Claims
- 1. A material adapted for use in a guest-host liquid crystal device which comprises a solution of a liquid crystal host material and a pleochroic dye dissolved in said host to an extent to adapt said material for said use, wherein the pleochroic dye comprises at least one anthraquinone compound free from water solubilizing and ionic substituents and having the formula: ##STR33## wherein: X.sup.2 and X.sup.3 are selected from OH and --SR.sup.2
- provided that
- when X.sup.2 is OH X.sup.3 is --SR.sup.2 and when X.sup.3 is OH X.sup.2 is --SR.sup.2 ;
- each Q is C.sub.1-20 -alkyl and adjacent to an OH group; and R.sup.1 and R.sup.2 are different and selected from alkyl, mono- or bi-cyclic aryl and cycloalkyl.
- 2. A material as claimed in claim 1 in which the anthraquinone dye has the formula: ##STR34## wherein: L and M are H or CH.sub.2 K.sup.1 ;
- X.sup.4 and X.sup.5 are OH or SR.sup.2,
- provided that
- when X.sup.4 is OH X.sup.5 is SR.sup.2, L is CH.sub.2 K.sup.2 and M is H; and
- when X.sup.5 is OH X.sup.4 is SR.sup.2, M is CH.sub.2 K.sup.2 and L is H;
- K.sup.1 and K.sup.2 are C.sub.1-20 -alkyl;
- R.sup.1 is mono- or bi-cyclic aryl; and
- R.sup.2 is different from R.sup.1 and selected from C.sub.1-20 -alkyl,
- mono- or bi-cyclic aryl and
- C.sub.4-8 -cycloalkyl.
- 3. A material as claimed in claim 1 in which the anthraquinone compound is such that at least one of the alkyl, aryl and cycloalkyl radicals represented by R.sub.1 and R.sub.2 carries a non-ionic substituent.
- 4. A material as claimed inc claim 3 in which the anthraquinone compound is such that the radicals R.sub.1 and R.sub.2 are aryl radicals and there is a substituent on at least one of the aryl radicals selected from C.sub.1-10 -alkyl, C.sub.4-8 -cycloalkyl and phenyl.
- 5. A material as claimed in claim 1 in which the dye comprises a mixture comprising at least one unsymmetrical di(substituted thio)anthraquinone having the formula specified in claim 1, in which the two substituted thio groups are different, and at least one symmetrical di(substituted thio)anthraquinone having the same overall general formula as specified in claim 1 but in which the two substituted thio groups are identical.
- 6. A material as claimed in claim 5 in which the said mixture comprises at least 50% by weight of the unsymmetrical di(substituted thio)anthraquinone.
- 7. A material as claimed in claim 1 in which the product of the molar extinction of the pleochroic dye and the solubility of that dye in moles/liter is at least 500 cm.sup.-1.
- 8. A material as claimed in claim 1 in which one of the groups R.sup.1 and R.sup.2 is phenyl and the other is 4-alkylphenyl.
- 9. A material as claimed in claim 1 in which the groups K.sup.1 and K.sup.2 are identical n-alkyl groups having from three to twelve carbon atoms.
- 10. A material as claimed in claim 8 in which the alkyl group contained in the 4-alkylphenyl group has a branched chain and from 3 to 8 carbon atoms.
- 11. A material as claimed in claim 10 in which the alkyl group contained in the 4-alkylphenyl group is t-butyl.
- 12. A material as claimed in claim 1 in which the dye comprises the compound 1,8-dihydroxy-2,7-di-n-heptyl-4-phenythio-5-(4-t-butylphenylthio)anthraquinone.
- 13. A material as claimed in claim 1 and wherein for each compound contained in the dye the product of molar extinction coefficient and the solutibility of the dye in moles per liter is at least 500 cm.sup.-1.
- 14. A material as claimed in claim 1 and wherein each compound contained in the pleochroic dye forms between 0.85 and 10 percent by weight of the material.
- 15. A material as claimed in claim 1 and wherein each compound contained in the pleochroic dye forms between 0.5 and 5 percent by weight of the material.
- 16. A material as claimed in claim 1 and wherein the pleochroic dye comprises a mixture of dyes of a different colour, at least one of which is a dye compound of the formula as defined in claim 1.
- 17. A material as claimed in claim 16 and wherein the pleochroic dye includes a mixture of a blue dye, a purple dye and a yellow dye, the purple dye being a compound of said formula 1.
- 18. A material as claimed in claim 17 and wherein the mixture also includes any orange dye and comprises a neutral coloured mixture.
- 19. A material as claimed in claim 16 and wherein the pleochroic dye comprises a neutral coloured mixture of a yellow dye, a red or purple/red dye and a blue dye at least one of which is a compound of said formula.
- 20. A material as claimed in claim 1 and wherein the liquid crystal material comprises mainly 4-n-alkyl-or alkoxy-4'-cyanobiphenyl compounds.
- 21. A material as claimed in claim 1 and wherein the liquid crystal material comprises mainly 1-(4'-cyanophenyl)-4-n-alkylcyclohexane compounds.
- 22. A material as claimed in claim 1 and wherein the liquid crystal material is suitable for a cholesteric to nematic phase change effect device and comprises a nematic liquid crystal material together with a chiral agent.
- 23. A material as claimed in claim 20 and wherein the liquid crystal material is suitable for a cholesteric to nematic phase change effect device and comprises a nematic liquid crystal material together with a chiral agent.
- 24. A material as claimed in claim 21 and wherein the liquid crystal material is suitable for a cholesteric to nematic phase change effect device and comprises a nematic liquid crystal material together with a chiral agent.
- 25. A liquid crystal electro-optical device including two electrically insulating substrates at least one of which is optically transparent, electrodes on the inner surfaces of the substrates and a film of dielectric material contained between the substrates, wherein the improvement comprises the dielectric material being a dyed liquid crystal material as claimed in claim 1.
- 26. A liquid crystal device as claimed in claim 25 and wherein the device is a cholesteric to nematic phase change effect device.
- 27. A liquid crystal device as claimed in claim 25 and wherein the device is a Freedericksz effect device.
- 28. A liquid crystal device as claimed in claim 25 and wherein the device is a twisted nematic effect device.
Priority Claims (5)
Number |
Date |
Country |
Kind |
8105959 |
Feb 1981 |
GBX |
|
8105961 |
Feb 1981 |
GBX |
|
8106995 |
Mar 1981 |
GBX |
|
8219530 |
Sep 1981 |
GBX |
|
8223855 |
Aug 1982 |
GBX |
|
Parent Case Info
This Application is continuation-in-part of copending U.S. patent application Ser. No. 352,060 filed Feb. 24, 1982 by the present Applicants.
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Non-Patent Literature Citations (2)
Entry |
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Continuation in Parts (1)
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Number |
Date |
Country |
Parent |
352060 |
Feb 1982 |
|