Claims
- 1. Stabilized polymer compositions comprising an organic polymer and a stabilizing quantity of a reactive antioxidant compound having the formula ##STR18## or the formula ##STR19## wherein R.sub.1 and R.sub.2 are linear or branched alkyl radicals containing from 1 to 10 carbon atoms;
- R is a linear or branched alkylene radical containing from 1 to 10 carbon atoms, or is ##STR20## wherein R.sub.3, R.sub.4 and R.sub.5 are linear or branched alkylene radicals containing 3 to 10 carbon atoms;
- X is a linear or branched alkyl radical containing form 1 to 5 carbon atoms;
- Y is hydrogen, halogen, C.sub.1 -C.sub.4 acyloxy, C.sub.1 -C.sub.4 alkyloxy, amino, amino-xoy, or silyloxy;
- m is zero or 1; and
- n is 1, 2 or 3.
- 2. Stabilized polymer compositions comprising an organic polymer and a stabilizing quantity of a resinified antioxidant comprising the hydrolysis and condensation product of a compound having the formula ##STR21## or the formula ##STR22## wherein R.sub.1 and R.sub.2 are linear or branched alkyl radicals containing from 1 to 10 carbon atoms;
- R is a linear or branched alkylene radical containing from 1 to 10 carbon atoms, or is ##STR23## wherein R.sub.3, R.sub.4 and R.sub.5 are linear or branched alkylene radicals containing 3 to 10 arbon atoms;
- X is a linear or branched alkyl radical containing from 1 to 5 carbon atoms;
- Y is hydrogen, halogen, C.sub.1 -C.sub.4 acyloxy, C.sub.1 -C.sub.4 alkyloxy, amino, amino-xoy, or silyloxy;
- m is zero or 1; and
- n is 1, 2 or 3.
- 3. Stabilized polymer compositions as defined in claim 2, wherein, in said phenolic compound, R.sub.1 R.sub.2 are t-butyl, X is methyl, and Y is chlorine, methoxy or ethoxy.
- 4. Stabilized polymer compositions as defined in claim 2, wherein said phenolic compound is selected from the group consisting of ##STR24##
- 5. Stabilized polymer compositions as defined in claim 4, wherein said resinified antioxidant has the formula: ##STR25##
- 6. Stabilized polymer compositions as defined in claim 2, wherein said phenolic organic polymer is a polyolefin, a polydiolefin, or a polyether.
- 7. Stabilized polymer compositions as defined in claim 2, wherein said compound is resinified in the presence of said organic polymer.
- 8. Stabilized polymer compositions as defined in claim 2, wherein said compound is at least partially resinified before combination with said organic polymer.
- 9. Stabilized polymer compositions as defined in claim 2, wherein said resinified antioxidant is a granulated co-resinification product of said compound and a silicone varnish.
- 10. Stabilized polymer compositions as defined in claim 1, wherein said organic polymer is a polyolefin, a polydiolefin, or a polyether.
- 11. Stabilized polyme compositions as defined in claim 1, wherein said reactive antioxidant compound is fixed to a solid support containing surface hydroxyl groups, selected from diatomaceous earth, celite, silica gel, cement, glass, glass fibres, silico-aluminates or fumed silica.
- 12. Stabilized polymer compositions as defined in claim1, wherein said reactive antioxidant compound is present in an amount 0.01% to 5% by weight.
- 13. Stabilized polymer compositions as defined in claim 2, wherein said resinified antioxidant is present in an amount of from 0.01% to 5% by weight.
- 14. A process for stabilizing oganic polymers comprising:
- incorporating in said polymer 0.01% to 5% by weight of a phenolic antioxidant, said antioxidant having the formula ##STR26## of the formula ##STR27## wherein R.sub.1 and R.sub.2 are linear or branched alkyl radicals containing from 1 to 10 carbon atoms;
- R is a linear or branched alkylene radical containing from 1 to 10 carbon atoms, or is ##STR28## wherein R.sub.3, R.sub.4 and R.sub.5 are linear or branched alkylene radicals having 3 to 10 carbon atoms;
- X is a linear or branched alkyl radial containing from 1 to 5 carbon atoms;
- Y is hydrogen, halogen, C.sub.1 -C.sub.4 acyloxy, C.sub.1 -C.sub.4 alkyloxy, amino, amino-oxy, or silyloxy;
- m is zero or 1; and
- n is 1, 2 or 3;
- such that said antioxidant is inextractable from said polymer.
- 15. The process according to claim 14, wherein said antioxidant is incorporated into said polymer under conditions which cause the hydrolysis of the silyl function of said antioxidant and condensation to form inextractable, resinous products within the organic polymer.
- 16. The process according to claim 15, wherein said hydrolysis and condensation are carried out in the presence of a condensation catalyst selected from acid or basic agents, metal soaps, metal esters, or organo-metal compounds.
- 17. The process according to claim 16, wherein said condensation catalyst is lead naphthenate or tin dibutyllaurate.
- 18. The process according to claim 14, wherein the incorporation step involves partially resinifying said phenolic antioxidant prior to combination with the organic polymer and thereafter combining the partially resinified compound with the organic polymer under conditions which cause the further resinification of said compound to form inextractable, resinous structures within said polymer.
- 19. The process according to claim 18, wherein said hydrolysis and condensation are carried out in the presence of a condensation catalyst selected from acid or basic agents, metal soaps, metal esters, or organo-metal compouns.
- 20. The process according to claim 19, wherein said condensation catalyst is lead naphthenate or tin dibutyllaurate.
- 21. The process according to claim 14, wherein the incorporation step involves reacting said antioxidant with a solid support containing surface hydroxyl groups selected from the group consisting of diatomaceous earth, celite, silica gel, cement, glass, glass fibers, silico-aluminates and fumed silica; or, optionally.
- 22. The process according to claim 14, wherein the incorporation step involves co-resinifying said antioxidant compound with a silicone varnish to obtain a hard glass, particulating said glass to an average particle size of 1 micron or less, and adding said particulate glass to said organic polymer.
- 23. The process according to claim 14, wherein the incorporation step involves bonding chemically said antioxidant to said polymer.
- 24. The process according to claim 14, wherein said organic polymer is a polyolefin, a polydiolefin, or a polyether.
Priority Claims (1)
Number |
Date |
Country |
Kind |
21024 A/84 |
May 1984 |
ITX |
|
Parent Case Info
This is a division of application Ser. No. 733,524, filed May 13, 1985, now abandoned.
US Referenced Citations (3)
Number |
Name |
Date |
Kind |
4582870 |
Spivack et al. |
Apr 1986 |
|
4636573 |
Pastor et al. |
Jan 1987 |
|
4818779 |
Witucki et al. |
Apr 1989 |
|
Divisions (1)
|
Number |
Date |
Country |
Parent |
733524 |
May 1985 |
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