(1) Field of the Invention
The present application relates to a thermistor, and more particularly to an over-current protection device.
(2) Description of the Related Art
Over-current protection devices are used for protecting circuitries from damages resulted from over-heat or over-current. An over-current protection device usually contains two electrodes and a resistive material disposed therebetween. The resistive material has positive temperature coefficient (PTC) characteristic that the resistance thereof remains extremely low at room temperature and instantaneously increases to thousand times when the temperature reaches a critical temperature or the circuit has over-current, so as to suppress over-current and protect the cell or the circuit device. When the material gets back to the room temperature or over-current no longer exists, the over-current protection device returns to be of low resistance and as a consequence the circuitry can operate normally. In view of the reusable property, the PTC over-current protection devices can replace traditional fuses, and have been widely applied to high density circuits.
With lightweight and compact trends, electronic apparatuses are getting smaller. For a cell phone, a number of components have to be integrated into a limited space, in which an over-current protection device is usually secured to a protective circuit module (PCM) and its external lead will occupy a certain space. Therefore, it is desirable to have a thin-type protection device that does not take up much room. When the device is downsizing to form factor 0201, it is a great challenge on how to decrease the thickness of the protection device for surface-mount applications.
According to specification of 0201, a device has a length of 0.6±0.03 mm, a width of 0.3±0.03 mm and a thickness of 0.25±0.03 mm. In manufacturing, the length and width are doable, but the thickness is too thin to be achieved. Nowadays, the resistive material substrate of carbon black system can be at most pressed to 0.2 mm in thickness, and the resistive material substrate of ceramic filler system can obtain a thickness of 0.2-0.23 mm. If the resistive substrate is further engaged with insulating (prepreg) layers and internal and external circuits (electrodes) to form an over-current protection device as shown in U.S. Pat. No. 6,377,467, not only is the thickness out of specification but also the thickness may be equal to or larger than width. As a result, the devices may topple when they are subjected to packaging or other processes afterwards.
Moreover, the internal-and-external circuit design on a small size device sometimes has misalignment between the internal circuit and external circuit, and therefore the production yield will be negatively impacted.
U.S. Pat. No. 8,044,763 disclosed the use of low resistivity materials such as metal powders or metal carbides to make surface mountable devices (SMD), which is a breakthrough to the limitation of using carbon black as conductive fillers and significantly increase hold current per area to 0.16 A/mm2, or even up to 1 A/mm2. The hold current indicates the largest current of the device before trip. However, the mobile apparatuses had greatly advanced. It is demanded that the device be of smaller volume and more powerful, and thus more operating current is needed. Therefore, the upper limit of 1 A/mm2 would be unsatisfactory, and larger hold current per effective PTC area is desired for a protection device with smaller area and larger operating current.
Therefore, it is a great challenge to make a small device with large hold current, and preferably the device structure can be simplified to decrease the process steps and manufacturing cost.
The present application relates to an over-current protection device of thin-type, which is able to meet the demands of compact over-current protection devices with large hold current per area.
In accordance with an embodiment of the present application, an over-current protection device comprises a PTC material layer, a first electrode layer and a second electrode layer. The PTC material layer has a first surface, a second surface, a first lateral surface and a second lateral surface. The first surface is opposite to the second surface, and the first lateral surface is opposite to the second lateral surface. The first electrode layer is in physical contact with the first surface of the PTC material layer and extends to the first lateral surface. The second electrode layer is in physical contact with the first surface of the PTC material layer and extends to the second lateral surface. The second electrode layer is insulated from the first electrode layer by a first separation. The first electrode layer and the second electrode layer are substantially laterally symmetrical, and serve as interfaces for current flowing in and out of the over-current protection device when the device is in use.
In an embodiment, the over-current protection device further comprises a third electrode layer disposed on the second surface of the PTC material layer. The third electrode layer overlaps the first electrode layer and the second electrode layer in vertical, thereby forming an over-current protection device of an equivalent circuit including two PTC thermistors connected in series.
According to the present application, it is advantageous that the over-current protection devices can be made from the PTC substrate directly. That is, the devices need not include prepreg layers and external electrodes. As such, it merely needs to make separation such as a gap by, for example, etching an electrode layer of the PTC substrate to form the first electrode layer and the second electrode layer.
In an embodiment, the electrode layers comprise copper layers on which a portion is electroplated with tin and another portion without tin-electroplating is covered with solder mask. The tin-electroplated portion is used as an interface for reflow soldering. In addition to the thickness of the PTC material layer, the increase of thickness of the device is only attributed to copper electroplating, tin electroplating and solder masking. Therefore, the over-current protection device of thin-type can be obtained.
Because the over-current protection device needs not be subjected to pressing process and has no external circuit, misalignment between internal circuit and external circuit no longer exists, thereby increasing production yield.
In an embodiment, the value of the hold current of the over-current protection device divided by the PTC material area can be greater than 1 A/mm2 and up to 6.5 A/mm2, so as to meet the requirement of large current applications.
The present application will be described according to the appended drawings in which:
The making and using of the presently preferred illustrative embodiments are discussed in detail below. It should be appreciated, however, that the present application provides many applicable inventive concepts that can be embodied in a wide variety of specific contexts. The specific illustrative embodiments discussed are merely illustrative of specific ways to make and use the invention, and do not limit the scope of the invention.
The PTC material layer 11 contains crystalline polymer and conductive filler with resistivity less than 500 μΩ-cm. The resistivity of the PTC material layer is less than 0.2 Ω-cm. The crystalline polymer may comprise polyethylene, polypropylene, polyvinylfluoride, the mixture or the copolymer thereof. The conductive filler may comprise metal filler, metal carbide, metal boride, metal nitride or the mixture thereof. For example, the metal filler may be nickel, cobalt, copper, iron, tin, lead, silver, gold, platinum, or the alloy thereof. The ceramic filler may be titanium carbide, titanium carbide (TiC), tungsten carbide (WC), vanadium carbide (VC), zirconium carbide (ZrC), niobium carbide (NbC), tantalum carbide (TaC), molybdenum carbide (MoC), hafnium carbide (HfC), titanium boride (TiB2), vanadium boride (VB2), zirconium boride (ZrB2), niobium boride (NbB2), molybdenum boride (MoB2), hafnium boride (HfB2), or zirconium nitride (ZrN). Moreover, the conductive filler may be the mixture, alloy, solid solution or core-shell of the aforesaid metal and ceramic fillers.
The compositions of four examples are shown in Table 1. The conductive filler that may be metal or ceramic comprises 70%-96%, or preferably 75%-95% by weight of the PTC material layer 11. The conductive filler may comprise 85%-95% by weight of the PTC material layer 11 if tungsten carbide is selected.
HDPE1 employs TAISOX HDPE/9001 high density polyethylene, a product of Formosa Plastics Corporation, with a density of 0.951 g/cm3 and a melting point of 130° C. HDPE2 employs TAISOX HDPE/8010 high density polyethylene with a density of 0.956 g/cm3 and a melting point of 134° C. The nickel powder employs Atlantic Equipment Engineering (AEE) NI-102 with a form of flake, a particle size of 3 μm, and a resistivity ranging from 6 μΩ-cm to 15 μΩ-cm. The tungsten carbide employs AEE WP-301 with a resistivity around 80 μΩ-cm and a particle size of 1-5 μm. The titanium carbide employs AEE TI-301 with a resistivity ranging from 180 μΩ-cm to 250 μΩ-cm and a particle size of 1-5 μm. In practice, the size of the conductive filler is between 0.01 μm and 30 μm, and preferably between 0.1 μm and 10 μm. The aspect ratio of conductive filler is less than 500, or preferably less than 300.
The first electrode layer 12 and the second electrode layer 13 can be made from a planar metal plate in which a gap 15 is formed by laser trimming, chemical etching or mechanical machining. The first electrode layer 12 and the second electrode layer 13 can be made of nickel, copper, zinc, silver, gold, the alloy thereof or a multilayer containing the above materials. In addition, the gap 15 may be of rectangular, semi-circular, triangular or irregular shape or figure.
Normally, current flows through a path of less resistance. Therefore, the current will flow through the path including the first electrode layer 12, the PTC material layer 11, the third electrode layer 14, the PTC material layer 11 and the second electrode layer 13 in order. From circuit perspective, the equivalent circuit of the over-current protection device 10 comprises two PTC thermistors connected in series.
According to the present application, the over-current protection device can be manufactured from a PTC substrate directly, and the prepreg or external electrode layers are not needed. A separation can be easily made in an electrode on a side by etching to form a left electrode (e.g., the first electrode 12) and a right electrode (e.g., the second electrode 13). According to the thin-type design, the thickness of the over-current protection device can be equal to or less than 0.28 mm, or less than 0.26 mm, 0.24 mm, 0.22 mm or 0.20 mm in particular. Thus it complies with the requirements of the form factor 0201. According to the present application, the over-current protection device can effectively decrease its thickness and therefore it is suitable for being used in a variety of compact electronic apparatuses. It should be noted that the thin-type design is not limited to 0201 device. Given the simplified structure, the over-current protection device can be applied to 1210, 1206, 0805, 0603, and 0402 as well.
The above embodiments relate to SMD applications. Moreover, the over-current protection device can be further associated with external leads to form axial-type or radial-type over-current protection devices.
The aforesaid embodiments jointing with external leads are not limited to implementation in the over-current protection device 10, the device 20, 30, 40, 50 or 60 can be jointed with external leads in similar ways, so as to provide various applications.
The current flowing through the PTC material of SMD devices will generate heat due to the resistance thereof, the amount of heat is proportional to the area of the PTC material layer APTC. The heat is transferred from the PTC material layer to outside, i.e., the heat is transferred to the surface of the device through electrodes, and electrical conductors if any, and then the heat is dissipated to ambient environment. Accordingly, the heat dissipation relates to the total area of the electrodes and conductors. The ratio of the heat dissipation of the electrodes and conductors to the heat generation of the PTC material layer can be defined as heat dissipation factor F.
F=(A1+A2)/A3, where A1 is the total area of the electrodes, A2 is the total area of the conductors, and A3 is the total area of the PTC material layer. A3 is usually equal to APTC×the number of the PTC material layers.
The optional conductors, such as the conductive members 21 and 22 in
Referring to
The conductor may be of various shapes, and its area can be calculated as follows.
For a conductor of cylinder shape such as a circular through hole, A2=π×the diameter of the cylinder×the length of the cylinder (or the thickness of the device).
For a conductor in partial cylinder shape such as a semicircular or quadrant through hole, A2=the arc of the partial cylinder×the length of the partial cylinder (or the thickness of the device).
For a conductor on a full sidewall surface, A2=the width of the device×the thickness of the device.
As to the electrode layers 12 and 13 of composite structure in
The value R of hold current per PTC material area can be calculated as follows. R=hold current/APTC. For example, APTC of a 0201 device is approximately equal to 0.02 inch×0.01 inch=0.508 mm×0.254 mm=0.129 mm2.
The R values for devices of various form factors are recorded as Table 2. The compositions of the PTC material layer refer to Table 1, and the structures of the device refer to
The over-current protection device is usually secured to a test board as shown in
Table 3 shows the test results of 0201 device of the present application under different conductive line widths.
It is observed from Table 3 that the wider the test conductive line, the larger the hold current and R value are. When 0201 devices are tested on the boards with test conductive lines of 10 mil (0.254 mm) to 100 mil (2.54 mm), the hold current per PTC area can be up to 6 A/mm2. In practice, the hold current per PTC area is approximately between 1 and 6.5 A/mm2, or preferably between 1.5 and 6 A/mm2.
The device of the present application is of a simplified structure, and therefore needs not undergo complex process such as pressing. Moreover, there is no external circuit, so the misalignment event between internal and external electrodes no longer exists and therefore production yield can be increased. When the present application is applied to the compact devices, the hold current per PTC area can be increased and meet the requirements of large current applications.
The above-described embodiments of the present invention are intended to be illustrative only. Numerous alternative embodiments may be devised by persons skilled in the art without departing from the scope of the following claims.
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