The invention relates to an oxidation furnace for the oxidative treatment of fibers, in particular for producing carbon fibers, comprising
In such commercially available oxidation furnaces, the blowing-in device comprises, for example, a plurality of blowing-in boxes from which the working atmosphere enters the process space. The process air drawn in by the primary suction device is conveyed by means of a circulation device in a circuit to the primary blowing-in device and in the process subjected to conditioning.
When the primary suction device is arranged at the end of the oxidation furnace opposite to the blowing-in end, this is referred to in the technical field as an oxidation furnace operating according to the “end-to-end” principle. This means that the process air is conveyed through the process space from end to the other end of the oxidation furnace. Such “end-to-end” oxidation furnaces are known, for example, from EP 0 848 090 B1. The advantage of such “end-to-end” oxidation furnaces is that quite homogeneous flow around and onto the fibers can be achieved over the entire process space using only one circulation device; the outlay for construction is comparatively low.
However, in “end-to-end” oxidation furnaces, there are considerably difficulties in preventing both contaminated process air from getting from the outside into the surroundings of the oxidation furnace through the passage regions at the blowing-in end of the housing and also cold air from the surroundings of the oxidation furnace from flowing in an undesirable way into the process space.
During operation, a pressure gradient is established over the height of the oxidation furnace, arising from superimposition of the subatmospheric pressure in the process space by the flowing process air and the thermal pressure gradient due to the ascending of hot process air. Owing to the resulting pressure gradient, harmful air travels outward through the passage regions in the upper part of the oxidation furnace and, secondly, cold air is drawn in from the furnace surroundings through passage regions in the lower part of the oxidation furnace.
It is an object of the invention to provide an oxidation furnace of the type mentioned at the outset, in which such undesirable flows are reliably prevented.
This object is achieved in an oxidation furnace of the type mentioned at the outset by
The invention is based on the recognition that a type of counter flow can be built up by means of a secondary gas flow which defines a second blown-in flow in addition to the primary gas flow, by means of which counter flow the abovementioned pressure gradient can be effectively homogenized so that there is no longer a pressure gradient at the blowing-in end and a flow seal has been produced so that harmful air no longer flows in an outward direction and cold air from the furnace surroundings no longer flows into the interior space of the furnace.
This is achieved particularly when the blown-in secondary gas partly flows in the direction toward the process space and partly in the direction away from the process space. It is particularly advantageous for these proportions of the substreams of the secondary gas which flow in the direction toward the process space and in the direction away from the process space to be adjustable. This can be achieved by the pressure drop coefficient of both the flow paths being influenced and the pressure drop in both flow directions being adjustable thereby.
It is particularly advantageous for the pressure drop coefficient of both the flow paths of the secondary gas to be adjustable in each subspace since the flow conditions in the vertically superposed subspaces are different.
Such adjustability of the pressure drop coefficient can advantageously be achieved by the flow sealing device comprising a secondary gas diversion device by means of which the secondary gas stream is diverted in such a way that secondary gas partly flows in the direction toward the process space and partly flows in the direction away from the process space. In this case, the proportions of the substreams in the total volume flow of the secondary gas should, in particular, be adjustable.
It is advantageous for the secondary gas diversion device to comprise a transfer guide device on the secondary blowing-in device and a diversion element, forming a flow channel between the transfer guide device and the diversion element.
It is particularly advantageous for the diversion element to be movable and the flow channel to be able to be altered.
To be able to set the flow conditions over the height of the oxidation furnace, it is advantageous for primary gas to be able to be blown by means of the primary gas blowing-in device into each subspace and secondary gas to be able to be blown by means of the secondary blowing-in device into each subspace.
A secondary gas diversion device is preferably also provided in each subspace.
An advantageous solution for introduction of the primary gas and of the secondary gas is for the primary blowing-in device to comprise one or more primary blowing-in boxes and the secondary blowing-in device to comprise one or more secondary blowing-in boxes.
A primary blowing-in box and a secondary blowing-in box which are arranged directly next to one another in the same subspace and blow primary gas or secondary gas, respectively, in opposite directions are advantageous.
To prevent the part of the secondary gas which flows away from the process space from getting out to the outside, it is advantageous for a secondary suction device by means of which this substream of the secondary gas can be sucked away to be present.
It is also advantageous for a fresh gas feed device by means of which fresh gas can be blown into the interior space to be present at the blowing-in end of the housing, with the fresh gas feed device being arranged, in particular, on the side of the secondary suction device opposite the process space.
In the following, a working example of the invention will be explained in more detail with the aid of the drawings. The drawings show:
At its end faces, the housing 12 has in each case an end wall 16a, 16b, with the end wall 16a having passage openings in the form of horizontal inlet slits 18 and outlet slits 20 which alternate from the bottom upward and the opposite end wall 16b having passage openings in the form of horizontal outlet slits 20 and inlet slits 18 which alternate from the bottom upward; in the interest of clarity, these are not all provided with a reference symbol. Through the inlet and outlet slits 18 and 20, respectively, fibers 22 are conveyed into the interior space 14 and out from this again. The inlet and outlet slits 18, 20 generally form passage regions of the housing 12 for the carbon fibers 22. Apart from these passage openings, the housing 12 of the oxidation furnace 10 is gastight.
The interior space 14 is in turn divided into three regions in the longitudinal direction and comprises a first prechamber 24 which is arranged directly next to the end wall 16a, a second prechamber 26 which is directly adjacent to the opposite end wall 16b and also a process space 28 located between the prechambers 24, 26.
The prechambers 24 and 26 thus effectively form an inlet and outlet lock for the fibers 22 into the interior space 14 or the process space 28.
The fibers 22 to be treated are fed parallel to one another as a type of fiber carpet 30 into the interior space 14 of the oxidation furnace 10. For this purpose, the fibers 22 travel from a first deflection region 32 located next to the end wall 16b outside the furnace housing 12 and through the uppermost inlet slit 18 in the end wall 16b into the prechamber 26. The fibers 22 are then conveyed through the process space 28 and through the opposite prechamber 24 to a second deflection region 34 located next to the end wall 16a outside the furnace housing 12, and back again from there.
Overall, the fibers 22 travel through the process space 28 in a serpentine manner via deflection rollers 36 which are arranged successively from the top downward and of which only two are provided with a reference symbol. Between the deflection rollers 36, the fiber carpet 30 formed by the plurality of fibers 22 running parallel to one another in each case spans a plane, with a subspace 38 of the interior space 14 being in each case defined above and below these planes. In the working example shown in
After passing through all of the process space 28, the fibers 22 leave the oxidation furnace 10 through the lowermost outward slit 22 in the end wall 16b in the case of the present working example. Before reaching the uppermost inlet slit 18 in the end wall 16b and after leaving the oxidation furnace 10 through the lowermost outlet slit 20 in the end wall 16b, the fibers 22 are conveyed outside the furnace housing 12 over further guide rollers which are not shown individually.
Under process conditions, a hot working atmosphere 40, which is built up by an atmosphere device 42, flows through the process space 28. Expressed in general terms, a hot working atmosphere 40 can be generated by means of the atmosphere device 42 and blown into the process space 28, and under process conditions flows through the process space 28. In practice, the working atmosphere is air, for which reason the term air will hereinafter also be chosen synonymously for all gases which contribute to the atmosphere management of the oxidation furnace and the terms process air, circulating air, exhaust air, fresh air and the like will be employed; however, other gases can also be conveyed through the process space 28.
In the present working example, the oxidation furnace 10 is configured according to the “end-to-end” principle and defines a blowing-in end 44 having a blowing-in device 46 and a suction end 48 having a primary suction device 50, between which the working atmosphere 40 flows in a main or process flow direction 52 through the process space 28. The blowing-in end 44 is located at the end of the oxidation furnace having the end wall 16b, and the suction end 48 is located at the opposite end having the end wall 16a. Furthermore, all arrows which can be seen in the figures in each case indicate flows or flow directions.
Between the primary suction device 50 and the blowing-in device 46, the working atmosphere 40 is conveyed through a circulation conduit 54 having a blower 56 and flows through a conditioning device 58 which is shown by way of example as heat exchanger 60 since, in particular, the temperature of the working atmosphere is set by means of the conditioning device 58. Upstream of the conditioning device 58, an exhaust air conduit 62 having a valve which is not shown individually branches off from the circulation conduit 54, so that a proportion of the circulated working atmosphere 40 can be discharged via this exhaust air conduit.
In order to maintain the air management of the oxidation furnace 10, the proportion of the exhaust gas volume which flows out can be compensated for by a fresh air feed device 64 which is provided at the blowing-in end 44 of the oxidation furnace 10 and there in the prechamber 24. The fresh air feed device 64 comprises a plurality of feed channels 66 which are supplied with fresh air and are arranged in the subspaces 38 and of which only one bears a reference symbol. The feed channels 66 extend transversely to the process flow direction 52 and thus transversely to the longitudinal direction of the furnace.
All components referred to here and in the following as plate or the like can be made of metal and thus optionally be a structural plate or else can be made of a nonmetallic material; the term “plate” is intended to define in principle the relatively thin structure of such components.
The gases discharged via the exhaust air conduit 62, which can also contain toxic constituents, are fed to a thermal after-combustion. The possible recovered heat can be used at least for pretreating the fresh air fed to the oxidation furnace 10.
The air goes via the circulation conduit 54 to the blowing-in device 46. This transfers the now circulated and conditioned air as process air into the process space 28. During the serpentine passage of the fibers 22 through the process space 28, hot, oxygen-containing process air flows around the fibers 22 and the latter are oxidized.
The blowing-in device 46 comprises a blowing-in box 72 in each subspace 38; only the blowing-in box 72 in the subspace 38.3 is provided with a reference symbol in
The blowing-in boxes 72 are divided by a dividing wall 74 into a primary blowing-in box 76 and a secondary blowing-in box 78. The circulation conduit 54 branches out into two supply arms 54a, 54b of which one is connected to the primary box 76 and the other is connected to the secondary box 78 so that the primary box 76 and the secondary box 78 are supplied with circulated air.
The primary boxes 76 each have a hydrodynamically open primary outlet window 80 which extends transverse to the longitudinal direction of the furnace and through which primary gas, i.e. in the present case primary air, flows into the process space 28. These primary outlet windows 80 of the blowing-in device 46 point in the direction of the primary suction device 50 opposite. A primary blowing-in device 46a is formed in this way.
Hydrodynamically open means that a gas flow can pass through the windows described here and in the following. For this purpose, the windows can, for example, be formed by a respective wall being omitted. However, if desired, a wall can also be provided with flow passages.
In addition, the secondary boxes 78 of the blowing-in boxes 72 have a hydrodynamically open secondary outlet window 82 which is located on the side opposite the primary outlet window 80 and consequently faces in the direction of the end wall 16a and through which secondary gas, i.e. secondary air in the present case, flows into the prechamber 24 of the oxidation furnace 10 in the direction opposite to the process flow direction 52. This forms, expressed in general terms, a secondary blowing-in device 46b through which secondary gas can be blown on the side of the primary blowing-in device 46a opposite the process space 28 into the subspaces 38.
In a modification which is not shown individually, the primary blowing-in device 46a and the secondary blowing-in device 46b can each be formed by separate blowing-in boxes having appropriate primary and secondary outlet windows rather than by the primary boxes 76 and the secondary boxes 78 which share the dividing wall 74.
The volume flow ratio between primary air and secondary air is influenced by the position of the respective dividing wall 74 in the blowing-in boxes 72 when these are supplied by the joint blower 56. When the primary boxes 76 and the secondary boxes 78 are each supplied by a dedicated blower, the position of the dividing wall 74 is immaterial. In practice, a ratio of 65%-70% via the primary blowing-in boxes 76 and 35%-30% via the secondary blowing-in boxes 78 has been found to be advantageous.
The secondary blowing-in device 46b is part of a flow sealing device 84 by means of which exit of polluted process air from the oxidation furnace 10 is prevented.
This flow sealing device 84 additionally comprises a secondary suction device 86 which in each subspace 38 has a secondary section box 88 which is arranged at a distance from the secondary blowing-in chamber 78 in the respective subspace 38. Of these secondary suction boxes 88, only the suction box 88 in the subspace 38.3 is provided with a reference symbol in
The secondary suction boxes 88 each have a hydrodynamically open suction window 92 on the side opposite the secondary blowing-in device 46b, and this window consequently faces in the direction of the end wall 16a of the housing 12. Air can be sucked out of the interior space 14 through the secondary suction boxes 88. For this purpose, the secondary suction boxes 88 are connected in each case via a valve 94 to a suction conduit 96 which opens into the circulation conduit 54 upstream of the blower 56 and in the present working example also upstream of the conditioning device 58. The suction volume flow for each suction box 88 can be set via the respective valve 94.
In a modification which is not shown individually, the valves 94 can also be omitted.
The flow sealing device 84 further comprises a flow guide device by means of which the flow ratios in the flow spaces 90 between the secondary blowing-in devices 46b and the secondary suction device 86 can be set.
The flow guide device 98 comprises, in each subspace 38, a secondary gas diversion device 100 by means of which the secondary gas stream is diverted in such a way that secondary gas partly flows in the direction toward the process space 28 and partly flows in the direction away from the process space 28. Each secondary gas diversion device 100 in turn comprises a transfer guide device 102 at the secondary outlet window 82 of the secondary blowing-in chamber 78 and a diversion element 104 against which the secondary air from the secondary blowing-in chamber 78 flows.
The diversion element 104 is movable so that the distance between the transfer guide device 102 and the diversion element 104 can be altered and can be set for each subspace 38.
In the working example shown here, the transfer guide device 102 comprises two guide plates 106 which are installed top and bottom on the secondary outlet window 82 and have free outer peripheries 108 which converge in the exit direction of the secondary air and whose surfaces facing one another are characterized as inner surfaces 106a and whose surfaces facing away from one another are characterized as outer surface 106b. In this way, an outlet gap 110 for the secondary air is formed between the free edges 108 of the guide plates 106. The secondary air exiting from the secondary outlet window 82 is bundled together by the respective inner surfaces 106a of the guide plates 106. The two guide plates 106 run, in the present working example, at an angle of 45° to a horizontal plane.
The diversion element 104 defines inclined flow surfaces 112 which are each arranged in the horizontal direction opposite the guide plates 116 and between which an impingement surface 114 runs. In the present working example, the inclined flow surfaces 112 run parallel to the outer surfaces 106a of the guide plates 106; the impingement surface 114 runs vertically.
The diversion element 104 is configured as push-on component 116 which has a shape complementary to a secondary suction box 88, so that it can be pushed onto the secondary suction box 88 and moved on this.
This forms, in each subspace 38, an alterable flow channel 118 through which secondary air can flow in the upward direction and downward in the direction of the respective fiber carpets 30 running there, with the flow cross section of this flow channel being able to be adjusted.
The oxidation furnace 10 and its flow sealing device 84 then function as follows:
Primary air is blown in the process flow direction 50 into the process space 28 by means of the primary blowing-in device 46a and the primary blowing-in chamber 76 thereof. At the same time, secondary air is blown in the opposite direction into the flow spaces 90 of the flow sealing device 84 by means of the secondary blowing-in device 46b and the secondary blowing-in boxes 78 thereof. The transfer volume stream of the primary blowing-in device 46a and the transfer volume stream of the secondary blowing-in device 46b have a constant ratio in each blowing-in box 72 and can be set structurally via the position of the dividing wall 74 in the blowing-in box 72; in practice, this ratio is from 3:1 to 3:2.
The free spaces below above the blowing-in boxes 72 and the free spaces below and above the diversion elements 104 and the secondary suction boxes 88 form flow passages 120 and 122, respectively; only the two flow passages 120, 122 at the subspace 38.3 are provided with reference symbols in
The secondary air blown into the flow channels 118 is divided by the secondary gas diversion device 100 and flows, in each subspace 38, upward and downward in the flow channel 118 and then into the flow passages 120 and 122 there.
Part of the secondary air then flows in the flow passages 120 into the process space 22. Another part of the secondary air flows in the flow passages 122 in the opposite direction in the direction of the end wall 16a of the housing 12 to the suction windows 92 of the secondary suction boxes 88. These volume streams which flow through the flow passages 122 in the direction of the end wall 16a are drawn off by means of the secondary suction device 86 and the secondary suction boxes 88 thereof and recirculated into the circulation conduit 54.
In the lowermost subspace 38.1, the diversion element 104 is, for example, positioned so that there is a large distance to the transfer guide device 102, in which the flow channel 118 has no guiding or diverting effect on the secondary air there. As a result, the secondary air is divided half-and-half in the subspace 38.1 into the substreams through the flow passages 120 and 122, with the pressure drop in both substreams being equal.
In the upward direction, the diversion elements 104 in the individual subspaces 38 are successively positioned ever closer to the respective transfer guide device 102, so that the flow channel 118 resulting in each case in each subspace 38 becomes ever narrower in the upward direction. This can be seen readily in
As a result of the forced flow directions, the respective dynamic pressure of the secondary air in the subspaces 38 acts against the positive internal pressure of the oxidation furnace 10, with the pressure drop coefficient toward the outside increasing successively from the bottom upward from subspace 38 to subspace 38.
The flow channel 118 can consequently be altered by means of the movable diversion element 104 in such a way that the pressure drop coefficient of both flow paths is influenced and the pressure drop in both flow directions can be set thereby.
In this way, the volume flow division can be controlled and the pressure gradient over the height of the oxidation furnace 10, which results from the superimposition of the subatmospheric pressure in the process space due to the flowing process air and the thermal pressure gradient, can be homogenized. This prevents harmful air getting to the outside through inlet and outlet slits 18, 20 in the upper region of the oxidation furnace 10 and also prevents cold air being sucked in from the furnace surroundings through inlet and outlet slits 18, 20 in the lower region of the oxidation furnace 10.
A flow seal is thus formed.
A corresponding flow sealing device 84 can also be used in an oxidation furnace whose air management is operated according to the “end-to-end center” principle.
In modifications which are not shown individually, secondary air can, for example, also be blown in through separate blowing-in nozzles which are arranged in the subspaces 38 and whose transfer direction, transfer pressure and transfer volume flow can be set appropriately, with, in particular, the transfer pressure and the transfer volume flow being increased from the bottom upward.
In the working example shown in
In the working example shown in
In this working example, too, there are the inclined flow plates 124 which here no longer run parallel to the guide plates 106 but instead run more steeply relatively to a horizontal plane. At the ends which in each case face the dividing plate 128, the flow plates 124 each have a pivotable flow flap 130 which can be adjusted between a first closure position in which the free ends thereof rest against the dividing plate 128 and a second closure position in which the free ends thereof rest against the free ends of the guide plates 106.
In the first closure position, the flow path between the flow plates 124 and the outer surface 126 of the secondary suction box 88 is shut off, while in the second closure position the flow path between the guide plates 106 and the flow plates 124 is shut off. The flow proportions of the secondary air can be set as a function of the setting of the flow flaps 130.
In the working example shown in
The working example shown in
In the working example shown in
In the working example shown in
The working example shown in
In the working example shown in
In the working example shown in
A hollow guide box 156 is movably mounted between the flow wedges 150 and the guide plates 106; this hollow guide box has an upper wall and a lower wall 158 or 160, respectively, which in turn have a closed section 158a or 160a and a section 158b or 160b provided with flow passages. The sections 158b and 160b provided with flow passages have an extension in the horizontal direction which corresponds to the spacing between the flow wedges 150 and the secondary suction box 88. The end face of the guide box 156 in the direction of the blowing-in boxes 72 is open, while the end face of the guide box 156 is closed by an end wall 162 in the direction toward the secondary suction box 88.
At a first maximum setting of the guide box 156, the end wall 162 thereof is flush with the vertical guide surfaces 154 of the flow wedges 150, as a result of which only a flow path for the secondary air through the wall sections 158b and 160b provided with flow passages and further between the guide plates 106 and the inclined guide surfaces 152 of the flow wedges 150 is possible. Flow of the secondary air past the flow wedges 150 in the direction toward the secondary suction box 88 is prevented by the closed end wall 162 of the guide box 156. This can be seen in
At a second maximum setting of the guide box 156, the end wall 162 thereof rests against the outer surface 126 of the secondary suction box 88, so that only a flow path for the secondary air through the wall sections 158b and 160b provided with flow passages and further between the vertical guide surfaces 154 of the flow wedges 150 and the outer surface 126 of the secondary suction box 88 is possible. Flow of the secondary air between the guide plates 106 and the inclined guide surfaces 152 of the flow wedges 150 is prevented by the closed wall sections 158a and 160a of the guide box 150. This is shown in
Number | Date | Country | Kind |
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10 2016 116 057.1 | Aug 2016 | DE | national |
Filing Document | Filing Date | Country | Kind |
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PCT/EP2017/071554 | 8/28/2017 | WO | 00 |